CN111403641A - High-sealing battery pack - Google Patents

High-sealing battery pack Download PDF

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Publication number
CN111403641A
CN111403641A CN202010317913.1A CN202010317913A CN111403641A CN 111403641 A CN111403641 A CN 111403641A CN 202010317913 A CN202010317913 A CN 202010317913A CN 111403641 A CN111403641 A CN 111403641A
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CN
China
Prior art keywords
rubber
battery pack
styrene
sealing
butadiene
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202010317913.1A
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Chinese (zh)
Inventor
焦胜涛
焦永邦
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanghai Bangchang Trading Co ltd
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Shanghai Bangchang Trading Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shanghai Bangchang Trading Co ltd filed Critical Shanghai Bangchang Trading Co ltd
Priority to CN202010317913.1A priority Critical patent/CN111403641A/en
Publication of CN111403641A publication Critical patent/CN111403641A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings; Jackets or wrappings
    • H01M50/183Sealing members
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/20Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2220/00Batteries for particular applications
    • H01M2220/20Batteries in motive systems, e.g. vehicle, ship, plane
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Sealing Battery Cases Or Jackets (AREA)
  • Battery Mounting, Suspending (AREA)

Abstract

The invention discloses a high-sealing battery pack which comprises a battery pack box body and a plurality of electric core groups arranged in the box body, wherein a sealant is coated on the box body, a sealing device is arranged at the periphery of each electric core group, the sealant and the sealing device are both compositions of styrene copolymers and liquid softeners, styrene thermoplastic elastic hydrogen additives are formed by one or more groups of styrene copolymers, styrene-butadiene-styrene copolymers and styrene-isopropene/butadiene-styrene copolymers, the melt viscosity of the hydrogen additives η 1 and η 2, namely the combination of 2-15 viscosity ratio of melt viscosity η 1 at η 1/η 2: 140 ℃ and melt viscosity η 2 at 180 ℃, the liquid softeners, inorganic filling materials and replenishers are added in an auxiliary mode, the sealing requirement of IP68 is met, the flame retardant grade of U L94V 0 is high in thixotropy, size deviation is avoided, and the battery pack is free from prime coating, directly bonded and can be repaired for multiple times.

Description

High-sealing battery pack
Technical Field
The invention relates to the technical field of battery pack design, in particular to a high-sealing battery pack.
Background
According to the national standards for battery packs, materials suitable for sealing the battery pack shell need to pass tests of U L94V 0 flame retardant grade and IP 67/68 waterproof grade.
Disclosure of Invention
The invention aims to provide a high-sealing battery pack, which effectively solves the technical problem.
In order to effectively solve the technical problems, the technical scheme adopted by the invention is as follows:
the high-sealing battery pack comprises a battery pack box body and a plurality of electric core groups arranged in the box body, wherein a sealant is coated on the box body, a sealing device is arranged at the periphery of each electric core group, the sealant and the sealing device are both compositions of styrene copolymers and liquid softeners, and the styrene thermoplastic elastic hydrogen additives are styrene thermoplastic elastic hydrogen additives consisting of one or more groups of styrene-isopropenyl copolymers, styrene-butadiene-styrene copolymers and styrene-isopropenyl/butadiene-styrene copolymers, and the melt viscosities of the hydrogen additives η 1 and η 2, namely the combination of the viscosity ratio of η 1/η 2: 140 ℃ melt viscosity η 1 to 180 ℃ melt viscosity η 2, and the liquid softeners, inorganic filling materials and extenders are added in an auxiliary mode.
Particularly, the sealant is coated on the battery pack box body by using dynamic mixing equipment, and is assembled and sealed after vulcanization.
Specifically, the sealing device is molded by using a single-screw extruder, a twin-screw extruder, a kneader, a mixer, or various mixing devices, and melt-kneaded at 150 to 200 ℃ in the mixing devices, wherein the screw rotation speed of the twin-screw extruder is 50 to 500rpm, and the kneading temperature is 150 to 200 ℃.
Particularly, the sealant comprises a thermoplastic elastic material and an elastic polymer with the following glass transfer point of below 25 ℃; specifically, the rubber composition comprises natural rubber, isoprene rubber, butadiene rubber, 1, 2-butadiene rubber, styrene-butadiene rubber, acrylonitrile-butadiene rubber, vinyl chloride rubber, butadiene rubber, diene rubber such as ethylene-propylene-diene rubber, and hydrogen additives thereof; ethylene-propylene rubber, ethylene-butylene rubber, ethylene dichloride, propylene rubber, fluororubber, polyethylene rubber, polypropylene rubber-based olefinic rubber; rubber dioxides, rubber polysulfides, silicone rubber and polyurethane rubber.
Particularly, the battery pack comprises a heat conduction element, the sealing device comprises sealing parts which are oppositely arranged at two ends of the heat conduction element along the width direction of the battery pack, the battery pack further comprises a fixing part connected with the sealing parts, and the sealing parts, the fixing part and the heat conduction element are fixedly connected.
Specifically, the extender is an extender other than carbon black and silicon, and contains an antioxidant, a pigment, a plasticizer, a thixotropic agent, an ultraviolet absorber, a flame retardant, a solvent, a surfactant, a dispersant, a dehydrating agent, an antirust agent, an adhesive, an antistatic agent and a filler;
the antioxidant comprises a combination of a phenol antioxidant such as sulfuric ester, acrylic ester, tetraenoic ester and the like and a TNPP phosphorus antioxidant.
The high-sealing battery pack has the advantages that the adopted sealing material meets the sealing grade requirement of IP68, after high temperature and high humidity, cold and hot shock and high temperature continuous aging for 1000 hours, the high-sealing battery pack still can meet the IP68 requirement, has excellent flame retardance, can easily pass a U L V0 test, can meet the long-term high-standard sealing requirement, has reliable safety, high thixotropy and high width ratio ranging from 0.5 to 0.7, meets a large-size battery pack, can effectively cover the size deviation of a shell, has good adhesion to SMC and Al materials, can not use a primer, reduces the complexity of the process, and has good rebound resilience and aging performance.
The present invention will be described in detail with reference to the accompanying drawings.
Drawings
Fig. 1 is a schematic view of the constitution of a high-sealability battery pack according to the present invention.
Fig. 2 is a schematic view of the internal structure of the high-sealability battery pack according to the present invention.
Detailed Description
Example 1:
as shown in fig. 1 and 2, the high-sealability battery pack includes a battery pack case 10 and a plurality of electric core groups 30 disposed in the case 10, wherein the case 10 is coated with a sealant 20, a sealing device 32 is disposed at the periphery of the electric core groups 30, the sealant 20 and the sealing device 32 are both a composition of a styrene-based copolymer and a liquid softener, the styrene-based thermoplastic elastomeric hydrogen additive is a combination of one or more groups of a styrene-based copolymer, a styrene-butadiene-styrene copolymer and a styrene-isopropene/butadiene-styrene copolymer, the melt viscosities of the hydrogen additives η 1 and η 2, namely, the viscosity ratio of the melt viscosity of η 1/η 2: 140 ℃ η 1 to the melt viscosity of 180 ℃ η 2 is 2-15, and the liquid softener, an inorganic filling material and an extender are added in an auxiliary manner.
The applicant states that a new method, which is generated by combining some steps of the above-mentioned embodiment with the technical solution of the summary part of the invention based on the above-mentioned embodiment, is also one of the description scope of the present invention, and other embodiments of these steps are not listed in the present application for the sake of brevity.
The specific design scheme of this example is as follows:
the sealant 20 is coated on the battery pack case 10 by using a dynamic mixing device, and is assembled and sealed after being vulcanized. The sealing device 32 is molded by using a single-screw extruder, a twin-screw extruder, a kneader, a mixer, or various mixing devices, and melt-kneaded at 150 to 200 ℃ with a screw rotation number of 50 to 500rpm and a kneading temperature of 150 to 200 ℃. The sealant 20 comprises a thermoplastic elastic material, including an elastic polymer with a glass transition point below room temperature of below 25 ℃; specifically, the rubber composition comprises natural rubber, isoprene rubber, butadiene rubber, 1, 2-butadiene rubber, styrene-butadiene rubber, acrylonitrile-butadiene rubber, vinyl chloride rubber, butadiene rubber, diene rubber such as ethylene-propylene-diene rubber, and hydrogen additives thereof; ethylene-propylene rubber, ethylene-butylene rubber, ethylene dichloride, propylene rubber, fluororubber, polyethylene rubber, polypropylene rubber-based olefinic rubber; rubber dioxides, rubber polysulfides, silicone rubber and polyurethane rubber. The battery pack comprises a heat guiding element 34, the sealing device 32 comprises sealing members 62 which are oppositely arranged at two ends of the heat guiding element 34 along the width direction of the battery pack, the battery pack further comprises a fixing member 43 which is connected with the sealing members 62, and the sealing members 62, the fixing member 43 and the heat guiding element 34 are fixedly connected. The replenisher is replenisher except carbon black and silicon, and contains an anti-aging agent, an antioxidant, a pigment, a plasticizer, a thixotropic agent, an ultraviolet absorbent, a flame retardant, a solvent, a surfactant, a dispersing agent, a dehydrating agent, an antirust agent, an adhesive, a charge preventing agent and a filler; the antioxidant comprises a combination of a phenol antioxidant such as sulfuric ester, acrylic ester, tetraenoic ester and the like and a TNPP phosphorus antioxidant.
The technical route different from the prior art in the embodiment is as follows:
the adopted sealing material meets the requirement of IP68 on sealing grade, and after the sealing material is subjected to high temperature and high humidity, cold and hot shock and high temperature continuous aging for 1000h, the sealing material still can meet the requirement of IP68, has excellent flame retardance, can easily pass a U L V0 test, can meet the requirement of long-term high-standard sealing, has reliable safety, high thixotropy and high width ratio within the range of 0.5-0.7, meets a large-size battery pack, can effectively cover the size deviation of a shell, has good adhesion to SMC and Al materials, can avoid using a base coat, reduces the complexity of the process, and has good rebound resilience and aging performance.
The applicant further states that the present invention is described in the above embodiments to explain the implementation method and device structure of the present invention, but the present invention is not limited to the above embodiments, i.e. it is not meant to imply that the present invention must rely on the above methods and structures to implement the present invention. It should be understood by those skilled in the art that any modifications to the present invention, the addition of equivalent alternatives to the embodiments of the present invention and steps, the selection of specific modes, etc., are within the scope of the present invention and the disclosure.
The present invention is not limited to the above embodiments, and all embodiments adopting the similar structure and method to achieve the object of the present invention are within the protection scope of the present invention.

Claims (6)

1. The high-sealing battery pack is characterized by comprising a battery pack box body and a plurality of electric core groups arranged in the box body, wherein the box body is coated with a sealing adhesive, a sealing device is arranged at the periphery of each electric core group, the sealing adhesive and the sealing device are both compositions of styrene copolymers and liquid softeners, each styrene thermoplastic elastic hydrogen additive is composed of one or more groups of styrene copolymers, styrene-butadiene-styrene copolymers and styrene-isopropene/butadiene-styrene copolymers, the melt viscosity of the hydrogen additives η 1 and η 2, namely the combination of 2-15 viscosity ratios of η 1/η 2: 140 ℃ melt viscosity η 1 to 180 ℃ melt viscosity η 2, and the liquid softeners, inorganic filling materials and replenishers are added in an auxiliary mode.
2. The high-sealability battery pack according to claim 1,
the sealant is coated on the battery pack box body by using dynamic mixing equipment, and is assembled and sealed after vulcanization.
3. The high-sealability battery pack according to claim 1,
the sealing device is molded by using a single-shaft extruder, a double-shaft extruder, a kneader, a mixer or various mixing devices, and melt-kneading is performed in the mixing devices at 150-200 ℃, wherein the screw rotation number of the double-shaft extruder is 50-500 rpm, and the kneading temperature is 150-200 ℃.
4. The high-sealability battery pack according to claim 1,
the sealant comprises a thermoplastic elastic material and an elastic polymer with the following glass transfer point of below 25 ℃; specifically, the rubber composition comprises natural rubber, isoprene rubber, butadiene rubber, 1, 2-butadiene rubber, styrene-butadiene rubber, acrylonitrile-butadiene rubber, vinyl chloride rubber, butadiene rubber, diene rubber such as ethylene-propylene-diene rubber, and hydrogen additives thereof; ethylene-propylene rubber, ethylene-butylene rubber, ethylene dichloride, propylene rubber, fluororubber, polyethylene rubber, polypropylene rubber-based olefinic rubber; rubber dioxides, rubber polysulfides, silicone rubber and polyurethane rubber.
5. The high-sealability battery pack according to claim 1,
the battery pack comprises a heat conduction element, the sealing device comprises sealing pieces which are oppositely arranged at two ends of the heat conduction element along the width direction of the battery pack, the battery pack further comprises a fixing piece connected with the sealing pieces, and the sealing pieces, the fixing piece and the heat conduction element are fixedly connected.
6. The high-sealability battery pack according to claim 1,
the replenisher is replenisher except carbon black and silicon, and contains an anti-aging agent, an antioxidant, a pigment, a plasticizer, a thixotropic agent, an ultraviolet absorbent, a flame retardant, a solvent, a surfactant, a dispersing agent, a dehydrating agent, an antirust agent, an adhesive, a charge preventing agent and a filler;
the antioxidant comprises a combination of a phenol antioxidant such as sulfuric ester, acrylic ester, tetraenoic ester and the like and a TNPP phosphorus antioxidant.
CN202010317913.1A 2020-04-21 2020-04-21 High-sealing battery pack Pending CN111403641A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202010317913.1A CN111403641A (en) 2020-04-21 2020-04-21 High-sealing battery pack

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202010317913.1A CN111403641A (en) 2020-04-21 2020-04-21 High-sealing battery pack

Publications (1)

Publication Number Publication Date
CN111403641A true CN111403641A (en) 2020-07-10

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CN202010317913.1A Pending CN111403641A (en) 2020-04-21 2020-04-21 High-sealing battery pack

Country Status (1)

Country Link
CN (1) CN111403641A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115360474A (en) * 2021-05-17 2022-11-18 丰田自动车株式会社 Electricity storage module

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1306039A (en) * 2000-01-14 2001-08-01 住友橡胶工业株式会社 Low elastic macromolecule compsns. and sealing material using same
CN103194032A (en) * 2012-10-08 2013-07-10 东莞市技塑塑胶科技有限公司 SEBS thermoplastic high-elasticity earphone cord coating special-purpose material and preparation method thereof
CN105501433A (en) * 2015-11-30 2016-04-20 哈尔滨飞机工业集团有限责任公司 Method for preventing drift motion of shimmy damper side plate with sealant
CN108400269A (en) * 2018-05-14 2018-08-14 常州格力博有限公司 Battery pack
JP2019119882A (en) * 2017-12-27 2019-07-22 積水フーラー株式会社 Hot-melt composition

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1306039A (en) * 2000-01-14 2001-08-01 住友橡胶工业株式会社 Low elastic macromolecule compsns. and sealing material using same
CN103194032A (en) * 2012-10-08 2013-07-10 东莞市技塑塑胶科技有限公司 SEBS thermoplastic high-elasticity earphone cord coating special-purpose material and preparation method thereof
CN105501433A (en) * 2015-11-30 2016-04-20 哈尔滨飞机工业集团有限责任公司 Method for preventing drift motion of shimmy damper side plate with sealant
JP2019119882A (en) * 2017-12-27 2019-07-22 積水フーラー株式会社 Hot-melt composition
CN108400269A (en) * 2018-05-14 2018-08-14 常州格力博有限公司 Battery pack

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115360474A (en) * 2021-05-17 2022-11-18 丰田自动车株式会社 Electricity storage module
CN115360474B (en) * 2021-05-17 2024-03-01 丰田自动车株式会社 Power storage module

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Application publication date: 20200710

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