CN111393990A - Modified silicon waterproof coating - Google Patents

Modified silicon waterproof coating Download PDF

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Publication number
CN111393990A
CN111393990A CN202010373919.0A CN202010373919A CN111393990A CN 111393990 A CN111393990 A CN 111393990A CN 202010373919 A CN202010373919 A CN 202010373919A CN 111393990 A CN111393990 A CN 111393990A
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CN
China
Prior art keywords
parts
waterproof coating
agent
nano
film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202010373919.0A
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Chinese (zh)
Inventor
林同起
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shandong Fress New Material Technology Co ltd
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Shandong Fress New Material Technology Co ltd
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Publication date
Application filed by Shandong Fress New Material Technology Co ltd filed Critical Shandong Fress New Material Technology Co ltd
Priority to CN202010373919.0A priority Critical patent/CN111393990A/en
Publication of CN111393990A publication Critical patent/CN111393990A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04Polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1656Antifouling paints; Underwater paints characterised by the film-forming substance
    • C09D5/1662Synthetic film-forming substance
    • C09D5/1675Polyorganosiloxane-containing compositions
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1687Use of special additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a modified silicon waterproof coating which comprises the following raw materials in parts by weight: 60-80 parts of organic silicon rubber, 12-16 parts of curing agent, 30-50 parts of silica gel, 8-12 parts of coupling agent, 16-20 parts of nano silicon dioxide, 18-22 parts of nano aluminum oxide, 7-11 parts of pigment and filler, 4-8 parts of film-forming assistant, 6-10 parts of flatting agent, 35-55 parts of light calcium carbonate, 35-55 parts of talcum powder, 20-24 parts of emulsifier and 12-16 parts of titanium dioxide. The invention is nontoxic, tasteless, non-inflammable, safe and reliable, has long service life, can still maintain the performance at low temperature, has better hydrophobicity, can form a rough surface needle-shaped structure on the surface, prevents sewage and dirt from remaining and has certain self-cleaning function.

Description

Modified silicon waterproof coating
Technical Field
The invention relates to the technical field of waterproof coatings, in particular to a modified silicon waterproof coating.
Background
The waterproof coating is a coating which can prevent rainwater or underground water from leaking through a coating film formed by the coating, and the waterproof coating can be divided into the following components according to the coating state and form: emulsion, solvent, reactive and modified asphalts. There are two broad categories of waterproof materials on the market: one is waterproof polyurethane paint. Such materials are generally made from polyurethane and coal tar as raw materials. The volatile tar gas has high toxicity and is not easy to remove, so the volatile tar gas is prohibited to be used in China in 2000. The polyurethane waterproof paint is sold by replacing coal tar with asphalt as raw material. However, when such a coating material is used, it is generally diluted with an organic solvent containing toluene, xylene, etc., and thus it also has toxicity; another class is polymer cement based waterproofing coatings. It is composed of emulsion synthesized by several water-base polymers and high-quality cement mixed with various additives, and the flexibility of polymer (resin) and rigidity of cement are combined into one body, so that it is excellent in impermeability and stability. Its advantages are convenient construction, low cost, short construction period, no poison and environmental protection. Thus, polymer cement-based has become a leading element of the waterproof coating market.
Various coatings are available in the market at present, in order to reduce cost, materials such as silicon tar, potassium silicate, sodium silicate and lithium silicate are selected as silicon components, the permeability of the product is low, the volatility is strong, the actual drying after a coating film is formed is difficult to realize, the product is easy to carbonize into black powder after high temperature, and the environmental protection performance is poor, so that a modified silicon waterproof coating is provided to solve the problems.
Disclosure of Invention
The invention aims to solve the defects in the prior art and provides a modified silicon waterproof coating.
In order to achieve the purpose, the invention adopts the following technical scheme:
the modified silicon waterproof coating comprises the following raw materials in parts by weight: 60-80 parts of organic silicon rubber, 12-16 parts of curing agent, 30-50 parts of silica gel, 8-12 parts of coupling agent, 16-20 parts of nano silicon dioxide, 18-22 parts of nano aluminum oxide, 7-11 parts of pigment and filler, 4-8 parts of film-forming assistant, 6-10 parts of flatting agent, 35-55 parts of light calcium carbonate, 35-55 parts of talcum powder, 20-24 parts of emulsifier and 12-16 parts of titanium dioxide.
Preferably, the feed comprises the following raw materials in parts by weight: 65-75 parts of organic silicon rubber, 13-15 parts of curing agent, 35-45 parts of silica gel, 9-11 parts of coupling agent, 17-19 parts of nano silicon dioxide, 19-21 parts of nano aluminum oxide, 8-10 parts of pigment and filler, 5-7 parts of film-forming assistant, 7-9 parts of flatting agent, 40-50 parts of light calcium carbonate, 40-50 parts of talcum powder, 21-23 parts of emulsifier and 13-15 parts of titanium dioxide.
Preferably, the feed comprises the following raw materials in parts by weight: 70 parts of organic silicon rubber, 14 parts of curing agent, 40 parts of silica gel, 10 parts of coupling agent, 18 parts of nano silicon dioxide, 20 parts of nano aluminum oxide, 9 parts of pigment and filler, 6 parts of film-forming assistant, 8 parts of flatting agent, 45 parts of light calcium carbonate, 45 parts of talcum powder, 22 parts of emulsifier and 14 parts of titanium dioxide.
Compared with the prior art, the invention has the beneficial effects that:
1. the invention has good water resistance, permeability, film forming property, high elasticity, cohesiveness, water resistance, humidity resistance and low temperature resistance;
2. the invention has strong adaptability to the deformation of the base layer, has high film forming speed, can permeate into the substrate and is firmly bonded with the substrate;
in conclusion, the invention has the advantages of no toxicity, no odor, no combustion, safety, reliability, long service life, capability of maintaining the performance at low temperature, better hydrophobicity, capability of forming a rough surface needle-shaped structure on the surface, incapability of retaining sewage and dirt and certain self-cleaning function.
Detailed Description
The present invention will be further illustrated with reference to the following specific examples.
Example 1
The modified silicon waterproof coating comprises the following raw materials in parts by weight: 60-80 parts of organic silicon rubber, 12-16 parts of curing agent, 30-50 parts of silica gel, 8-12 parts of coupling agent, 16-20 parts of nano silicon dioxide, 18-22 parts of nano aluminum oxide, 7-11 parts of pigment and filler, 4-8 parts of film-forming assistant, 6-10 parts of flatting agent, 35-55 parts of light calcium carbonate, 35-55 parts of talcum powder, 20-24 parts of emulsifier and 12-16 parts of titanium dioxide.
Example 2
The modified silicon waterproof coating comprises the following raw materials in parts by weight: 65-75 parts of organic silicon rubber, 13-15 parts of curing agent, 35-45 parts of silica gel, 9-11 parts of coupling agent, 17-19 parts of nano silicon dioxide, 19-21 parts of nano aluminum oxide, 8-10 parts of pigment and filler, 5-7 parts of film-forming assistant, 7-9 parts of flatting agent, 40-50 parts of light calcium carbonate, 40-50 parts of talcum powder, 21-23 parts of emulsifier and 13-15 parts of titanium dioxide.
Example 3
The modified silicon waterproof coating comprises the following raw materials in parts by weight: 70 parts of organic silicon rubber, 14 parts of curing agent, 40 parts of silica gel, 10 parts of coupling agent, 18 parts of nano silicon dioxide, 20 parts of nano aluminum oxide, 9 parts of pigment and filler, 6 parts of film-forming assistant, 8 parts of flatting agent, 45 parts of light calcium carbonate, 45 parts of talcum powder, 22 parts of emulsifier and 14 parts of titanium dioxide.
The invention has good waterproofness, permeability, film forming property, high elasticity, cohesiveness, water resistance, humidity resistance and low temperature resistance, strong adaptability to base deformation, fast film forming speed, capability of permeating into a base and firmly adhering with the base, no toxicity, no odor, no combustion, safety, reliability, long service life, capability of still keeping performance at low temperature, better hydrophobicity, capability of forming a rough surface needle-shaped structure on the surface, incapability of retaining sewage and dirt and certain self-cleaning function.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered to be within the technical scope of the present invention, and the technical solutions and the inventive concepts thereof according to the present invention should be equivalent or changed within the scope of the present invention.

Claims (3)

1. The modified silicon waterproof coating is characterized by comprising the following raw materials in parts by weight: 60-80 parts of organic silicon rubber, 12-16 parts of curing agent, 30-50 parts of silica gel, 8-12 parts of coupling agent, 16-20 parts of nano silicon dioxide, 18-22 parts of nano aluminum oxide, 7-11 parts of pigment and filler, 4-8 parts of film-forming assistant, 6-10 parts of flatting agent, 35-55 parts of light calcium carbonate, 35-55 parts of talcum powder, 20-24 parts of emulsifier and 12-16 parts of titanium dioxide.
2. The modified silicon waterproof coating as claimed in claim 1, which is characterized by comprising the following raw materials in parts by weight: 65-75 parts of organic silicon rubber, 13-15 parts of curing agent, 35-45 parts of silica gel, 9-11 parts of coupling agent, 17-19 parts of nano silicon dioxide, 19-21 parts of nano aluminum oxide, 8-10 parts of pigment and filler, 5-7 parts of film-forming assistant, 7-9 parts of flatting agent, 40-50 parts of light calcium carbonate, 40-50 parts of talcum powder, 21-23 parts of emulsifier and 13-15 parts of titanium dioxide.
3. The modified silicon waterproof coating as claimed in claim 1, which is characterized by comprising the following raw materials in parts by weight: 70 parts of organic silicon rubber, 14 parts of curing agent, 40 parts of silica gel, 10 parts of coupling agent, 18 parts of nano silicon dioxide, 20 parts of nano aluminum oxide, 9 parts of pigment and filler, 6 parts of film-forming assistant, 8 parts of flatting agent, 45 parts of light calcium carbonate, 45 parts of talcum powder, 22 parts of emulsifier and 14 parts of titanium dioxide.
CN202010373919.0A 2020-05-06 2020-05-06 Modified silicon waterproof coating Pending CN111393990A (en)

Priority Applications (1)

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CN202010373919.0A CN111393990A (en) 2020-05-06 2020-05-06 Modified silicon waterproof coating

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Application Number Priority Date Filing Date Title
CN202010373919.0A CN111393990A (en) 2020-05-06 2020-05-06 Modified silicon waterproof coating

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112048244A (en) * 2020-09-18 2020-12-08 广东思泉新材料股份有限公司 Modified nano-alumina enhanced heat dissipation waterproof coating and coating, and preparation method thereof
CN116535905A (en) * 2023-05-26 2023-08-04 江苏防排工匠建材科技有限公司 Extreme low temperature resistant waterproof material and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1670098A (en) * 2005-02-25 2005-09-21 华南理工大学 Bicomponent normal temperature crosslinked aqueous organosilicon rubber waterproof paint and method for preparing same
CN106189823A (en) * 2016-07-20 2016-12-07 芜湖昊轩环保新材料有限公司 Silicon rubber waterproof coating and preparation method thereof
CN108300293A (en) * 2016-08-31 2018-07-20 天津市仕翔电气科技有限公司 A kind of long-acting super-hydrophobic anti-pollution flashover coating of novel RTV slow-releases

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1670098A (en) * 2005-02-25 2005-09-21 华南理工大学 Bicomponent normal temperature crosslinked aqueous organosilicon rubber waterproof paint and method for preparing same
CN106189823A (en) * 2016-07-20 2016-12-07 芜湖昊轩环保新材料有限公司 Silicon rubber waterproof coating and preparation method thereof
CN108300293A (en) * 2016-08-31 2018-07-20 天津市仕翔电气科技有限公司 A kind of long-acting super-hydrophobic anti-pollution flashover coating of novel RTV slow-releases

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112048244A (en) * 2020-09-18 2020-12-08 广东思泉新材料股份有限公司 Modified nano-alumina enhanced heat dissipation waterproof coating and coating, and preparation method thereof
CN116535905A (en) * 2023-05-26 2023-08-04 江苏防排工匠建材科技有限公司 Extreme low temperature resistant waterproof material and preparation method thereof

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Application publication date: 20200710

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