CN111393898A - Preparation method of silk-screen laser silver ink and silk-screen laser silver ink - Google Patents

Preparation method of silk-screen laser silver ink and silk-screen laser silver ink Download PDF

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Publication number
CN111393898A
CN111393898A CN202010336450.3A CN202010336450A CN111393898A CN 111393898 A CN111393898 A CN 111393898A CN 202010336450 A CN202010336450 A CN 202010336450A CN 111393898 A CN111393898 A CN 111393898A
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silver
laser
silk
silver paste
ink
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CN202010336450.3A
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司徒羡添
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Shenzhen Inktop Ink Technology Co ltd
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Shenzhen Inktop Ink Technology Co ltd
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Priority to CN202010336450.3A priority Critical patent/CN111393898A/en
Publication of CN111393898A publication Critical patent/CN111393898A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/033Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Powder Metallurgy (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The invention discloses a preparation method of silk-screen laser silver ink and the silk-screen laser silver ink, which are used for preparing mixed silver paste, wherein the mixed silver paste comprises laser silver paste and non-floating silver element type imitation electroplating silver paste; and mixing the mixed silver paste with resin, an auxiliary agent and a solvent to obtain the silk-screen laser silver ink. According to the invention, the silk-screen laser silver ink is prepared by mixing the non-floating silver element type imitation electroplating silver paste and the laser silver paste, and the edge of the non-floating silver element type imitation electroplating silver paste is regular round or oval, so that light can be reflected well when irradiating the edge of the silver paste particles, and the overall white brightness of the silk-screen laser silver ink is enhanced to a great extent.

Description

Preparation method of silk-screen laser silver ink and silk-screen laser silver ink
Technical Field
The invention relates to the field of ink preparation processes, in particular to a preparation method of silk-screen laser silver ink and the silk-screen laser silver ink.
Background
The silk-screen laser silver printing ink mainly comprises resin, laser silver paste, a solvent and an auxiliary agent, wherein the main factors influencing the silk-screen laser effect and brightness are the resin and the laser silver paste.
At present, the resin in the silk-screen laser silver ink is generally low-solid and high-viscosity resin, so that the laser effect can be improved as much as possible on the premise of ensuring the performance of the ink. Because laser silver thick liquid is the micron order granule that can produce the light diffraction, thereby has done special treatment on its surface in order to guarantee the diffraction effect of light, so, in order to avoid destroying the diffraction effect of laser silver thick liquid, numerous producers have all adopted high frequency vibration rubbing crusher to smash laser silver thick liquid at the in-process of producing silk screen printing laser silver-colored printing ink, nevertheless, it has irregular edge shape all to have the surface brightness that leads to laser silver-colored printing ink after the membrane is not enough to smash through the vibration, and the color and luster is dark relatively.
Disclosure of Invention
The invention mainly aims to provide a preparation method of silk-screen laser silver ink, and aims to solve the technical problems that the silk-screen laser silver ink prepared by the existing processing mode is insufficient in surface brightness and dark in color.
In order to achieve the purpose, the invention provides a preparation method of silk-screen laser silver ink, which comprises the following steps:
preparing mixed silver paste, wherein the mixed silver paste comprises laser silver paste and non-floating silver element type imitation electroplating silver paste;
and mixing the mixed silver paste with resin, an auxiliary agent and a solvent to obtain the silk-screen laser silver ink.
Further, in the mixed silver paste, the ratio of the laser silver paste to the silver element type imitation electroplating silver paste is 3: 1.
further, the particle size of the laser silver paste is the same as that of the silver element type imitation electroplating silver paste, and the radius-thickness ratio of the laser silver paste is the same as that of the silver element type imitation electroplating silver paste.
Further, the solids content of the resin is less than or equal to 15%.
Further, after the step of mixing the mixed silver paste with resin, an additive and a solvent to obtain the silk-screen laser silver ink, the method further comprises the following steps:
and adding a curing agent and a diluent which account for 15% of the total weight in the silk-screen laser silver ink.
Further, the ratio between the curing agent and the diluent is 1: 2.
in addition, the invention also provides the silk-screen laser silver ink prepared by the preparation method of the silk-screen laser silver ink.
Further, in the silk-screen laser silver printing ink, the ratio of the laser silver paste to the non-floating silver element type imitation electroplating silver paste is 3: 1.
further, the particle size of the laser silver paste is the same as that of the silver element type imitation electroplating silver paste, and the radius-thickness ratio of the laser silver paste is the same as that of the silver element type imitation electroplating silver paste.
Further, the solid content of the resin in the silk-screen laser silver ink is less than or equal to 15%.
The preparation method of the silk-screen laser silver ink and the silk-screen laser silver ink provided by the invention are characterized in that mixed silver paste is prepared, wherein the mixed silver paste comprises laser silver paste and non-floating silver element type imitation electroplating silver paste; and mixing the mixed silver paste with resin, an auxiliary agent and a solvent to obtain the silk-screen laser silver ink. According to the invention, the non-floating silver element type imitation electroplating silver paste and the laser silver paste are mixed to prepare the silk-screen laser silver ink, and the edge of the non-floating silver element type imitation electroplating silver paste is regular round or oval, so that light can be reflected well when irradiating the edge of the silver paste particles, and the overall white brightness of the silk-screen laser silver ink is enhanced to a great extent.
Drawings
FIG. 1 is a schematic flow chart of an embodiment of a method for preparing silk-screen laser silver ink according to the present invention;
FIG. 2 is a schematic flow chart of another embodiment of a method for preparing laser silver ink for screen printing according to the present invention;
FIG. 3 is a schematic diagram illustrating a printing effect of a laser screen printing silver ink in an embodiment of a method for preparing a laser screen printing silver ink according to the present invention;
fig. 4 is a schematic diagram of a printing effect of the silk-screen laser silver ink in another embodiment of the preparation method of the silk-screen laser silver ink.
The implementation, functional features and advantages of the objects of the present invention will be further explained with reference to the accompanying drawings.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below in conjunction with the embodiments of the present invention, and it should be understood that the specific embodiments described herein are only used for explaining the present invention, and are only a part of the embodiments of the present invention, rather than all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
In addition, technical solutions between various embodiments may be combined with each other, but must be realized by a person skilled in the art, and when the technical solutions are contradictory or cannot be realized, such a combination should not be considered to exist, and is not within the protection scope of the present invention.
The invention provides a preparation method of silk-screen laser silver ink and the silk-screen laser silver ink prepared based on the preparation method.
Referring to fig. 1, fig. 1 is a schematic flow chart of a first embodiment of a method for preparing silk-screen laser silver ink according to the present invention.
Embodiments of the present invention provide embodiments of a method for preparing laser-silk-screen silver ink, and it should be noted that, although a logical sequence is shown in a flowchart, in some cases, the steps shown or described may be performed in a different sequence than here.
The preparation method of the silk-screen laser silver ink comprises the following steps:
step S100, preparing mixed silver paste, wherein the mixed silver paste comprises laser silver paste and non-floating silver element type imitation electroplating silver paste.
Further, in the mixed silver paste, the ratio of the laser silver paste to the silver element type imitation electroplating silver paste is 3: 1.
further, the particle size of the laser silver paste is the same as that of the silver element type imitation electroplating silver paste, and the radius-thickness ratio of the laser silver paste is the same as that of the silver element type imitation electroplating silver paste.
In this embodiment, according to 3: 1, and mixing the laser silver paste and the non-floating silver element type imitation electroplating silver paste with the same particle size and diameter-thickness ratio to obtain the mixed silver paste.
It should be noted that, in this embodiment, the laser silver paste may specifically use shenzhen color BCS-4010-10 (one type of laser silver paste, the average particle size is 10um (micrometer)), the content of BCS-4010-10 accounts for 20% to 25% of the finally prepared silk-screen laser silver ink, the non-floating silver element type imitation electroplating silver paste may specifically use titanium-containing silver element type aluminum silver paste TY6210 (the average particle size is 10um, which is the same as the average particle size of BCS-4010-10, and the diameter-thickness ratio of which is the same as that of BCS-4010-10), and the content of TY6210 accounts for 5% to 10% of the finally prepared silk-screen laser silver ink.
Specifically, for example, BCS-4010-10 with the content ratio of 22.50% is selected and mixed with TY6210 with the content ratio of 7.50% to obtain the mixed silver paste.
And step S200, mixing the mixed silver paste with resin, an auxiliary agent and a solvent to obtain the silk-screen laser silver ink.
Further, the solids content of the resin is less than or equal to 15%.
It should be noted that, in this embodiment, the resin may specifically be glass mirror resin, PC mirror resin, or metal mirror resin, where solid content of the glass mirror resin, the PC mirror resin, or the metal mirror resin is 10%; in addition, the auxiliary agent can specifically select a defoaming agent with the content accounting for 0.8% of the finally prepared silk-screen laser silver ink, the solvent can specifically select isophorone, a white water prevention solvent or a DBE solvent correspondingly, and the total content of the defoaming agent and the isophorone, the white water prevention solvent or the DBE solvent respectively accounts for 10% -15% of the finally prepared silk-screen laser silver ink.
Specifically, for example, when a glass mirror resin with a solid content of 10% and a content of 60% is selected and mixed with the prepared mixed silver paste, a defoaming agent with a content of 0.8% and isophorone with a content of 9.20% are simultaneously selected and mixed with the prepared mixed silver paste to prepare the silk-screen laser silver ink, as shown in fig. 3, the printing effect of the prepared silk-screen laser silver ink is obtained, a transparent substrate-glass is used, the prepared silk-screen laser silver ink is printed on the back of the glass in a mode of 'back printing and front effect viewing', the whole printing effect is observed from the front, in fig. 3, the upper narrow and long area represents a glass substrate, the lower wide and short area represents a printing layer of the silk-screen laser silver ink, in the printing layer of the silk-screen laser silver ink, a white line segment represents silver element type aluminum particles in the mixed silver paste, the black line represents the laser silver particles.
Or when the PC mirror resin with the content of 60% and the solid content of 10% is selected and mixed with the prepared mixed silver paste, simultaneously the defoaming agent with the content of 0.8% and the white water imitating solvent with the content of 9.20% are selected and mixed with the prepared mixed silver paste to prepare the silk-screen laser silver ink, the whole printing effect of the silk-screen laser silver ink prepared from the PC mirror resin, the mixed silver paste and other additives and solvents is also shown in figure 3, the mode of back printing and front effect observation is also adopted, the difference is only that the used base materials are different, and when the effect of the silk-screen laser silver ink prepared from the PC mirror resin, the mixed silver paste and other additives and solvents is checked, a transparent composite board is selected as the base material.
Or, when the metal mirror resin with the solid content of 10% and the content of 60% is selected and mixed with the prepared mixed silver paste, the defoamer with the content of 0.8% and the DEB solvent with the content of 9.20% are simultaneously selected and mixed with the prepared mixed silver paste to prepare the silk-screen laser silver ink, as shown in fig. 4, the printing effect of the prepared silk-screen laser silver ink is obtained, a non-transparent substrate, namely stainless steel, is used, the prepared silk-screen laser silver ink is printed on the front surface of the stainless steel in a mode of 'front printing and front effect viewing', the whole printing effect is also observed from the front surface, in fig. 4, the upper wide and short area represents the printing layer of the silk-screen laser silver ink, the lower narrow and long area represents the stainless steel substrate, similarly, in the laser printing layer of the silk-screen silver ink, the white line segment represents the aluminum particles in the mixed silver paste, the black line represents the laser silver particles.
In this embodiment, a method for preparing a mixed silver paste is provided, wherein the mixed silver paste comprises a laser silver paste and a non-floating silver element type imitation electroplating silver paste; and mixing the mixed silver paste with resin, an auxiliary agent and a solvent to obtain the silk-screen laser silver ink. According to the invention, the screen printing laser silver ink is prepared by mixing the non-floating silver element type imitation electroplating silver paste and the laser silver paste, and the edge of the non-floating silver element type imitation electroplating silver paste is regular round or oval, so that light can be well reflected when irradiating the edge of the silver paste particle, and the overall white brightness of the screen printing laser silver ink is greatly enhanced.
In addition, select for use the high-viscosity resin of low solid content, can obtain better silver row effect to the radium-shine silver printing ink of silk screen printing that the messenger prepared obtains reaches better brightness, in addition, select for use with the imitative electroplating silver thick liquid of non-superficial type silver first type of the same particle size and footpath thickness ratio of radium-shine silver thick liquid, and mix this radium-shine silver thick liquid and the imitative electroplating silver thick liquid of this silver first type according to certain proportion, can demonstrate good radium-shine effect, can promote the brightness in white of printing ink again.
Further, based on the first embodiment of the preparation method of the silk-screen laser silver ink of the present invention, a second embodiment of the preparation method of the silk-screen laser silver ink of the present invention is provided, please refer to fig. 2, and fig. 2 is a schematic flow diagram of the preparation method of the silk-screen laser silver ink of the second embodiment of the present invention.
In the step S200, after the mixed silver paste is mixed with the resin, the additive and the solvent to obtain the laser-printed silver ink, the preparation method of the laser-printed silver ink further includes:
and step S300, adding a curing agent and a diluent which account for 15% of the total amount in the silk-screen laser silver ink.
Further, the ratio between the curing agent and the diluent is 1: 2.
based on the printing effect consideration of the prepared silk-screen laser silver ink, a curing agent and a diluent can be added into the prepared silk-screen laser silver ink.
In this embodiment, the total amount of the curing agent and the diluent added to the prepared silk-screen laser silver ink accounts for 15% of the total content of the silk-screen laser silver ink, and the ratio of the content of the curing agent to the content of the diluent is 1:2, and the curing agent may specifically be TDI curing agent.
Specifically, for example, after the screen printing laser silver ink is prepared by selecting the PC mirror resin and the mixed silver paste as well as other additives and solvents, the TDI curing agent accounting for 5% of the total content of the screen printing laser silver ink and the diluent accounting for 10% of the total content of the screen printing laser silver ink are added into the screen printing laser silver ink.
In this embodiment, according to the content of the prepared whole screen printing laser silver ink, a curing agent and a diluent are added to the screen printing laser silver ink, wherein the total amount of the curing agent and the diluent accounts for 15%, and the ratio of the curing agent to the diluent is 1:2, the silk-screen laser silver ink can have a good printing effect on various substrates (such as glass, composite plates and metal) finally.
The invention also provides the silk-screen laser silver ink prepared by the preparation method of the silk-screen laser silver ink.
Further, in the silk-screen laser silver printing ink, the ratio of the laser silver paste to the non-floating silver element type imitation electroplating silver paste is 3: 1, the particle size of the laser silver paste is the same as that of the silver element type imitation electroplating silver paste, the diameter-thickness ratio of the laser silver paste is also the same as that of the silver element type imitation electroplating silver paste, and in addition, the solid content of resin in the silk-screen laser silver ink is less than or equal to 15%.
In this embodiment, the surface brightness and the color of the silk-screen laser silver ink prepared by the traditional preparation method are insufficient, and the silk-screen laser silver ink prepared by mixing the non-floating silver element type imitation electroplating silver paste and the laser silver paste is gray and dark, and the edge of the non-floating silver element type imitation electroplating silver paste is regular round or oval, so that light can be well reflected when irradiating the edge of the silver paste particle, and the overall white brightness of the silk-screen laser silver ink is greatly enhanced. In addition, the resin with low solid content and high viscosity is selected in the silk-screen laser silver ink, so that a better silver row effect can be obtained, and the prepared silk-screen laser silver ink achieves better brightness.
It should be noted that, in this document, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or system that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or system. Without further limitation, an element defined by the phrase "comprising an … …" does not exclude the presence of other like elements in a process, method, article, or system that comprises the element.
The above-mentioned serial numbers of the embodiments of the present invention are merely for description and do not represent the merits of the embodiments.
The above description is only a preferred embodiment of the present invention, and not intended to limit the scope of the present invention, and all modifications of equivalent structures and equivalent processes, which are made by using the contents of the present specification and the accompanying drawings, or directly or indirectly applied to other related technical fields, are included in the scope of the present invention.

Claims (10)

1. A preparation method of silk-screen laser silver ink is characterized by comprising the following steps:
preparing mixed silver paste, wherein the mixed silver paste comprises laser silver paste and non-floating silver element type imitation electroplating silver paste;
and mixing the mixed silver paste with resin, an auxiliary agent and a solvent to obtain the silk-screen laser silver ink.
2. The method for preparing the silk-screen laser silver ink according to claim 1, wherein in the mixed silver paste, the ratio of the laser silver paste to the silver element type imitation electroplating silver paste is 3: 1.
3. the method for preparing silk-screen laser silver ink according to any one of claims 1 and 2, wherein the particle size of the laser silver paste is the same as that of the silver element type imitation electroplating silver paste, and the diameter-thickness ratio of the laser silver paste is the same as that of the silver element type imitation electroplating silver paste.
4. The method for preparing laser silver ink for screen printing according to claim 1, wherein the solid content of the resin is less than or equal to 15%.
5. The method for preparing the laser silver ink for screen printing according to claim 1, wherein after the step of mixing the mixed silver paste with the resin, the auxiliary agent and the solvent to obtain the laser silver ink for screen printing, the method further comprises the following steps:
and adding a curing agent and a diluent which account for 15% of the total weight in the silk-screen laser silver ink.
6. The preparation method of the laser screen printing silver ink according to claim 5, wherein the ratio of the curing agent to the diluent is 1: 2.
7. the silk-screen laser silver ink is characterized by being prepared based on the preparation method of the silk-screen laser silver ink as claimed in any one of claims 1 to 6.
8. The laser screen printing silver ink of claim 7, wherein in the laser screen printing silver ink, the ratio of laser silver paste to non-floating silver element type imitation electroplating silver paste is 3: 1.
9. the screen printing laser silver ink of claim 8, wherein the particle size of the laser silver paste is the same as that of the silver element type imitation electroplating silver paste, and the radius-thickness ratio of the laser silver paste is the same as that of the silver element type imitation electroplating silver paste.
10. The laser screen printing silver ink of claim 7, wherein the solid content of the resin in the laser screen printing silver ink is less than or equal to 15%.
CN202010336450.3A 2020-04-24 2020-04-24 Preparation method of silk-screen laser silver ink and silk-screen laser silver ink Pending CN111393898A (en)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1621586A1 (en) * 2001-09-06 2006-02-01 Toyo Aluminium Kabushiki Kaisha Aluminum flake pigment, coating composition containing the same, ink composition, and coating film obtained therefrom
CN105001709A (en) * 2015-07-08 2015-10-28 合肥旭阳铝颜料有限公司 Laser mirror ink

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1621586A1 (en) * 2001-09-06 2006-02-01 Toyo Aluminium Kabushiki Kaisha Aluminum flake pigment, coating composition containing the same, ink composition, and coating film obtained therefrom
CN105001709A (en) * 2015-07-08 2015-10-28 合肥旭阳铝颜料有限公司 Laser mirror ink

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
刘国杰主编: "《现代涂料工艺新技术》", 30 April 2000 *
张学敏等编著: "《涂料与涂装技术》", 31 January 2006 *

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