CN111392931A - Preparation method and equipment of micromolecular water - Google Patents

Preparation method and equipment of micromolecular water Download PDF

Info

Publication number
CN111392931A
CN111392931A CN201910001085.8A CN201910001085A CN111392931A CN 111392931 A CN111392931 A CN 111392931A CN 201910001085 A CN201910001085 A CN 201910001085A CN 111392931 A CN111392931 A CN 111392931A
Authority
CN
China
Prior art keywords
water
box
microwave
small molecule
turnover box
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910001085.8A
Other languages
Chinese (zh)
Inventor
郭山
罗国春
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guizhou Luobeiluo Biotechnology Co ltd
Original Assignee
Guizhou Luobeiluo Biotechnology Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guizhou Luobeiluo Biotechnology Co ltd filed Critical Guizhou Luobeiluo Biotechnology Co ltd
Priority to CN201910001085.8A priority Critical patent/CN111392931A/en
Publication of CN111392931A publication Critical patent/CN111392931A/en
Pending legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/30Treatment of water, waste water, or sewage by irradiation
    • C02F1/302Treatment of water, waste water, or sewage by irradiation with microwaves
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/68Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Toxicology (AREA)
  • Medicinal Chemistry (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)

Abstract

The invention discloses a preparation method of micromolecule water, which is characterized by comprising the following steps: the method comprises the following steps: (1) atomizing water by using an atomizer; (2) irradiating the atomized water by microwaves at the temperature of 30-40 ℃ under normal pressure to generate resonance, easily breaking hydrogen bonds of large molecular groups to form small molecular group water, and forming relatively stable small molecular group water by association of 5-6 water molecules. (3) Forming ions by utilizing air in the nature through an ion generator, and introducing the ions into the small molecular water through an ion flow guider to be fully neutralized to form a stable small molecular water product; the invention has the beneficial effects that: the preparation process is simple and convenient, energy is saved in the preparation process, the preparation process is more environment-friendly, the prepared micromolecule water is more stable, and the reducibility rate is reduced.

Description

Preparation method and equipment of micromolecular water
Technical Field
The invention relates to the field of small molecular water preparation, in particular to a preparation method of small molecular water and equipment thereof.
Background
Liquid water in nature does not exist in the form of a single molecule but exists in the form of a small molecular group (cluster). The water molecular groups are divided into different sizes. The small molecular group water has strong osmotic power, dissolving power, metabolizing power, emulsifying power, diffusing power, cleaning power and the like. The water molecules have stronger hydrogen bonds, and the oxygen atoms in each water molecule are combined with the oxygen atoms by two covalent bonds and two hydrogen bonds. Because the oxygen atom in the water molecule has strong electronegativity and small radius (0.099-0.138nm), the oxygen atom in one water molecule and the hydrogen atom in another water molecule attract each other, namely, a strong electrostatic attraction effect is generated between the two molecules, and the electrostatic attraction effect between the molecules is a hydrogen bond. Hydrogen bonding increases the binding force between water molecules. The bond energy of hydrogen bonds is much smaller than the bond energy of covalent bonds. In natural water, many water molecules are generally bound together by hydrogen bonds to form a ring-like or linear chain-like structure, which becomes a cluster of associated molecules. The existence of hydrogen bonds in water causes water to form a unique and variable structure, and any action on water can be relayed to thousands of atoms. Under various external actions such as temperature, pressure or magnetic field, the water structure changes. This change requires power consumption. The breaking of hydrogen bonds is a water structural change.
Disclosure of Invention
The purpose of the invention is as follows: the invention aims to provide a preparation device of micromolecule water, which utilizes water atomization to produce micromolecule water, has higher efficiency, utilizes separation to neutralize the micromolecule water and effectively slows down the reducibility of the micromolecule water.
The technical scheme is as follows: a preparation method of small molecular water is characterized by comprising the following steps: the method comprises the following steps:
(1) atomizing water by using an atomizer;
(2) irradiating the atomized water by microwaves at the temperature of 30-40 ℃ under normal pressure to generate resonance, easily breaking hydrogen bonds of large molecular groups to form small molecular group water, and forming relatively stable small molecular group water by association of 5-6 water molecules.
(3) And the ions are formed by utilizing the air in the nature through an ion generator and are introduced into the micromolecular water through an ion guider to be fully neutralized to form a stable micromolecular water product.
Specifically, the microwave is an ultra-microwave which is between an ultra-microwave and an infrared microwave.
Specifically, the frequency of the microwave is 60.53Hz-66.74 Hz.
Specifically, the irradiation time is 200-.
The reactor comprises a reactor, wherein a control box is arranged at the lower end of the reactor, and a connector is arranged at the joint of the control box and the reactor; the microwave generator is arranged at the periphery of the connector, the turnover box is arranged at the lower end of the control box, a water outlet pipe is arranged on one side of the turnover box, and the water outlet pipe is provided with a neutralizing box; a raw material pipe is arranged at one end of the turnover box, which is far away from the water outlet, and a filter is arranged between the raw material pipe and the turnover box; a raw material box is arranged at the lower end of the turnover box and is communicated with the turnover box through a guide pipe; the raw material box is communicated with the reactor through a connecting pipe, and an atomizer is arranged on the connecting pipe; and a controller is arranged on one side of the turnover box and is movably connected with the turnover box.
Specifically, an ion generator is arranged at the upper end of the neutralizing tank and is communicated with the neutralizing tank.
Specifically, the position of the water outlet pipe far away from the neutralization box and the turnover box is provided with monitoring equipment, and the monitoring equipment is electrically connected with the controller.
The reactor comprises a reactor, a controller, a flow guide pipe, a reactor and a control box, wherein the number of the microwave generators is six, the microwave generators are ultramicro generators, the microwave generators are electrically connected with the controller, and the flow guide pipe is arranged on the microwave generators and is communicated with the reactor and the control box.
Specifically, the atomizer is electrically connected with the controller.
Specifically, the conduit is provided with an electromagnetic valve, the electromagnetic valve is an induction electromagnetic valve, and the electromagnetic valve is in wireless signal connection with the controller.
Has the advantages that: the invention has the advantages that: the invention has the advantages that the preparation process is simple and convenient, energy is saved in the preparation process, the preparation process is more environment-friendly, the prepared micromolecular water is more stable, the reducing rate is reduced, the efficiency is more efficient when the micromolecular water is produced by water atomization, the micromolecular water is neutralized by utilizing the separation function, the reducing property of the micromolecular water is effectively slowed down, and the reducing rate of the micromolecular water is reduced; the air ions comprehensively cancel or weaken the intermolecular force on the opposite ends, so that the micromolecular water is relatively stable and is easier to use and store.
Drawings
FIG. 1 is a schematic structural diagram of a small molecule water device;
FIG. 2 is a superconducting Fourier transform nuclear magnetic resonance spectrum.
Detailed Description
Example 1
As shown in fig. 1, a preparation device of small molecule water, comprising an atomizer 1, a raw material tank 2, a turnover box 3, a neutralization box 4, a monitoring device 5, a water outlet pipe 6, an ion generator 7, a control box 8, a support 9, a reactor 10, a flow guide pipe 11, a connecting pipe 12, a controller 13, a guide pipe 14, a raw material pipe 15, a filter 16, an electromagnetic valve 17, and a connector 18, wherein the reactor 10 is arranged in a cylindrical structure, the lower end of the reactor 10 is provided with the control box 8, the space between the control box 8 and the reactor 10 is provided with the connector 18 through the connection pipe 18, the periphery of the connector 18 is provided with a microwave generator 19, the microwave generator 19 is an ultra-microwave generator, the flow guide pipe 11 is arranged on the microwave generator 19, the flow guide pipe 11 is communicated with the reactor 10 and the control box 8, the turnover box 3 is arranged at the lower end of the control box 8, the other end is provided with a raw material pipe 15, the water outlet pipe 6 is provided with a neutralization box 4, the upper end of the neutralization box 4 is provided with an ion generator 7, and a monitoring device 5 is arranged on the water outlet pipe 6 far away from the neutralization box 4 and the turnover box 3; a filter 16 is arranged on the raw material pipe 15, a raw material box 2 is arranged at the lower end of the turnover box 3, the raw material box 2 is communicated with the turnover box 3 through a guide pipe 14, an electromagnetic valve 17 is arranged on the guide pipe 14, the electromagnetic valve 17 is an induction electromagnetic valve, a support 9 is arranged on the outer side of the raw material box 2, the support 9 is fixedly connected with the raw material box 2, the turnover box 3 and the control box 8, a controller 13 is arranged on one side of the turnover box 3, the controller 13 is movably connected with the turnover box 3, the controller 13 is electrically connected with a microwave generator 19, and the electromagnetic valve 17 on the guide pipe 14 is in wireless signal connection with the controller 13; the monitoring device 5 arranged on the water outlet pipe 6 is electrically connected with the controller 13, the raw material tank 2 is communicated with the reactor 10 through a connecting pipe 12, the atomizer 1 is arranged on the connecting pipe 12, and the atomizer 1 is electrically connected with the controller 13.
A preparation method of small molecule water comprises the following steps: (1) atomizing water by using an atomizer;
(2) and irradiating the atomized water by using microwaves at the temperature of 30 ℃ and under the normal pressure to generate resonance, so that the hydrogen bonds of the macromolecular groups can be easily broken to form small molecular group water, and the small molecular group water is formed by association of 5-6 water molecules to form relatively stable small molecular group water.
(3) And the ions are formed by utilizing the air in the nature through an ion generator and are introduced into the micromolecular water through an ion guider to be fully neutralized to form a stable micromolecular water product.
Preferably, the microwave is an ultra-microwave, which is in the range of ultra-microwave to infrared microwave.
Preferably, the frequency of the microwave is 60.53 Hz.
Preferably, the irradiation time is 200 milliseconds.
Example 2
A preparation method of small molecule water comprises the following steps: (1) atomizing water by using an atomizer;
(2) and irradiating the atomized water by using microwaves at the temperature of 35 ℃ and under the normal pressure to generate resonance, so that the hydrogen bonds of the macromolecular groups can be easily broken to form small molecular group water, and the small molecular group water is formed by association of 5-6 water molecules to form relatively stable small molecular group water.
(3) And the ions are formed by utilizing the air in the nature through an ion generator and are introduced into the micromolecular water through an ion guider to be fully neutralized to form a stable micromolecular water product.
Preferably, the microwave is an ultra-microwave, which is in the range of ultra-microwave to infrared microwave.
Preferably, the frequency of the microwave is 61.75 Hz.
Preferably, the irradiation time is 220 milliseconds.
Example 3
1) Atomizing water by using an atomizer; (2) and irradiating the atomized water by using microwaves at the temperature of 36 ℃ under normal pressure to generate resonance, easily breaking hydrogen bonds of large molecular groups to form small molecular group water, and forming relatively stable small molecular group water by combining 5-6 water molecules. (3) And the ions are formed by utilizing the air in the nature through an ion generator and are introduced into the micromolecular water through an ion guider to be fully neutralized to form a stable micromolecular water product.
Specifically, the microwave is an ultra-microwave which is between an ultra-microwave and an infrared microwave.
Specifically, the frequency of the microwave is 62.84 Hz.
Specifically, the irradiation time is 250 milliseconds.
Example 4
1) Atomizing water by using an atomizer; (2) and irradiating the atomized water by using microwaves at the temperature of 38 ℃ under normal pressure to generate resonance, so that the hydrogen bonds of the macromolecular groups can be easily broken to form small molecular group water, and the small molecular group water is formed by association of 5-6 water molecules to form relatively stable small molecular group water. (3) And the ions are formed by utilizing the air in the nature through an ion generator and are introduced into the micromolecular water through an ion guider to be fully neutralized to form a stable micromolecular water product.
Preferably, the microwave is an ultra-microwave, which is in the range of ultra-microwave to infrared microwave.
Preferably, the frequency of the microwave is 64.84 Hz.
Preferably, the irradiation time is 500 milliseconds.
Example 5
1) Atomizing water by using an atomizer; (2) and irradiating the atomized water by using microwaves at the temperature of 40 ℃ and under normal pressure to generate resonance, so that the hydrogen bonds of the macromolecular groups can be easily broken to form small molecular group water, and the small molecular group water is formed by association of 5-6 water molecules to form relatively stable small molecular group water. (3) And the ions are formed by utilizing the air in the nature through an ion generator and are introduced into the micromolecular water through an ion guider to be fully neutralized to form a stable micromolecular water product.
Preferably, the microwave is an ultra-microwave, which is in the range of ultra-microwave to infrared microwave.
Preferably, the frequency of the microwave is 66.74 Hz.
Preferably, the irradiation time is 800 milliseconds.
As can be seen from the data in the test report of fig. 2, the conversion from small molecule water is highest at a frequency of 64.84 Hz.

Claims (10)

1. A preparation method of small molecular water is characterized by comprising the following steps: the method comprises the following steps:
(1) atomizing water by using an atomizer;
(2) irradiating the atomized water by microwaves at the temperature of 30-40 ℃ under normal pressure to generate resonance, easily breaking hydrogen bonds of large molecular groups to form small molecular group water, and forming relatively stable small molecular group water by association of 5-6 water molecules.
(3) And the ions are formed by utilizing the air in the nature through an ion generator and are introduced into the micromolecular water through an ion guider to be fully neutralized to form a stable micromolecular water product.
2. The method and the device for preparing the small molecule water according to claim 1 are characterized in that: the microwave is an ultra-micro wave which is between the ultra-micro wave and the infrared microwave.
3. The method and the device for preparing the small molecule water according to claim 1 are characterized in that: the frequency of the microwave is 60.53Hz-66.74 Hz.
4. The method and the device for preparing the small molecule water according to claim 1 are characterized in that: the irradiation time was 200 and 800 milliseconds.
5. A preparation equipment of small molecule water is characterized in that: the device comprises a reactor, wherein a control box is arranged at the lower end of the reactor, and a connector is arranged at the joint of the control box and the reactor; the microwave generator is arranged at the periphery of the connector, the turnover box is arranged at the lower end of the control box, a water outlet pipe is arranged on one side of the turnover box, and the water outlet pipe is provided with a neutralizing box; a raw material pipe is arranged at one end of the turnover box, which is far away from the water outlet, and a filter is arranged between the raw material pipe and the turnover box; a raw material box is arranged at the lower end of the turnover box and is communicated with the turnover box through a guide pipe; the raw material box is communicated with the reactor through a connecting pipe, and an atomizer is arranged on the connecting pipe; and a controller is arranged on one side of the turnover box and is movably connected with the turnover box.
6. The apparatus for preparing small molecule water according to claim 1, wherein: and an ion generator is arranged at the upper end of the neutralizing tank and is communicated with the neutralizing tank.
7. The apparatus for preparing small molecule water according to claim 1, wherein: and monitoring equipment is arranged on the water outlet pipe far away from the neutralization box and the turnover box and is electrically connected with the controller.
8. The apparatus for preparing small molecule water according to claim 1, wherein: the microwave generator is six, the microwave generator is an ultra-microwave generator, the microwave generator is electrically connected with the controller, and the microwave generator is provided with a flow guide pipe which is communicated with the reactor and the control box.
9. The apparatus for preparing small molecule water according to claim 1, wherein: the atomizer is electrically connected with the controller.
10. The apparatus for preparing small molecule water according to claim 1, wherein: the guide pipe is provided with an electromagnetic valve which is an induction electromagnetic valve, and the electromagnetic valve is in wireless signal connection with the controller.
CN201910001085.8A 2019-01-02 2019-01-02 Preparation method and equipment of micromolecular water Pending CN111392931A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910001085.8A CN111392931A (en) 2019-01-02 2019-01-02 Preparation method and equipment of micromolecular water

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910001085.8A CN111392931A (en) 2019-01-02 2019-01-02 Preparation method and equipment of micromolecular water

Publications (1)

Publication Number Publication Date
CN111392931A true CN111392931A (en) 2020-07-10

Family

ID=71426361

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910001085.8A Pending CN111392931A (en) 2019-01-02 2019-01-02 Preparation method and equipment of micromolecular water

Country Status (1)

Country Link
CN (1) CN111392931A (en)

Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06126287A (en) * 1992-10-16 1994-05-10 Taisho Pharmaceut Co Ltd Averagely small cluster water
JP2008115145A (en) * 2006-11-07 2008-05-22 Kazuhiko Kato Method of manufacturing functional water
US20090134098A1 (en) * 2007-11-26 2009-05-28 Eng3 Corporation Systems, devices, and methods for directly energizing water molecule composition
CN101624220A (en) * 2009-08-20 2010-01-13 郭金刚 Composite material for preparing micromolecular water and preparation method thereof
CN201832242U (en) * 2010-09-30 2011-05-18 安徽皖投力天世纪空气净化系统工程有限公司 Novel plasma health and cosmetology integrated machine
US20120056167A1 (en) * 2009-03-03 2012-03-08 The University Of Western Ontario Method for fabrication of layered heterojunction polymeric devices
CN103058430A (en) * 2012-12-18 2013-04-24 华南理工大学 Preparation method of high energy water with small molecules
CN104402153A (en) * 2014-11-28 2015-03-11 华南理工大学 Method for preparing stable small-molecular water by utilizing microwave-ultrasonic wave
CN104803439A (en) * 2014-01-23 2015-07-29 深圳市同盛绿色科技有限公司 Water treatment apparatus and water nanocrystallization method
CN204778966U (en) * 2015-07-04 2015-11-18 太和昇(厦门)科技有限公司 Cask formula anion activated water device
US20180140763A1 (en) * 2013-06-21 2018-05-24 Taipei Medical University Apparatus and process for preparation of small water cluster and small molecular cluster water prepared therefrom
TWM564591U (en) * 2017-06-01 2018-08-01 臺北醫學大學 Container for production of small water cluster
CN108423742A (en) * 2017-02-13 2018-08-21 陈罘杲 A kind of laser field-effect subset cluster water quality machine

Patent Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06126287A (en) * 1992-10-16 1994-05-10 Taisho Pharmaceut Co Ltd Averagely small cluster water
JP2008115145A (en) * 2006-11-07 2008-05-22 Kazuhiko Kato Method of manufacturing functional water
US20090134098A1 (en) * 2007-11-26 2009-05-28 Eng3 Corporation Systems, devices, and methods for directly energizing water molecule composition
US20120056167A1 (en) * 2009-03-03 2012-03-08 The University Of Western Ontario Method for fabrication of layered heterojunction polymeric devices
CN101624220A (en) * 2009-08-20 2010-01-13 郭金刚 Composite material for preparing micromolecular water and preparation method thereof
CN201832242U (en) * 2010-09-30 2011-05-18 安徽皖投力天世纪空气净化系统工程有限公司 Novel plasma health and cosmetology integrated machine
CN103058430A (en) * 2012-12-18 2013-04-24 华南理工大学 Preparation method of high energy water with small molecules
US20180140763A1 (en) * 2013-06-21 2018-05-24 Taipei Medical University Apparatus and process for preparation of small water cluster and small molecular cluster water prepared therefrom
CN104803439A (en) * 2014-01-23 2015-07-29 深圳市同盛绿色科技有限公司 Water treatment apparatus and water nanocrystallization method
CN104402153A (en) * 2014-11-28 2015-03-11 华南理工大学 Method for preparing stable small-molecular water by utilizing microwave-ultrasonic wave
CN204778966U (en) * 2015-07-04 2015-11-18 太和昇(厦门)科技有限公司 Cask formula anion activated water device
CN108423742A (en) * 2017-02-13 2018-08-21 陈罘杲 A kind of laser field-effect subset cluster water quality machine
TWM564591U (en) * 2017-06-01 2018-08-01 臺北醫學大學 Container for production of small water cluster

Non-Patent Citations (6)

* Cited by examiner, † Cited by third party
Title
刘新民 等: "《学科教学详解 初中化学》", 31 July 2015 *
张愈 等: "《中国疗养康复大辞典》", 31 May 1993 *
樊行雪 等: "《大学化学原理及应用》", 31 July 2000 *
王建华等: "微波对水分子团簇结构影响的探究", 《菏泽学院学报》 *
田静: "无锡风尚环境科技有限公司-上善若水,以水惠民", 《海峡科技与产业》 *
陆江: "从核磁共振看长寿村和小分子水的奥秘", 《家庭医学(下半月)》 *

Similar Documents

Publication Publication Date Title
CN204992728U (en) Ultrasonic wave wireless charging device
CN111392931A (en) Preparation method and equipment of micromolecular water
CN103945627A (en) Handheld large-area low-temperature plasma generator
CN104069978A (en) Ultrasonic atomization device and atomization method
CN102602912A (en) Synthesizing device for continuously producing carbon nano pipe with shape of crystal whisker
CN201660474U (en) Electronic scale inhibition and scale removal device
CN106673149B (en) High-efficient micro molecule group water preparation device
CN105152452A (en) Micromolecule water production method
CN108529707B (en) Combined test device and method for concentrating and flash-evaporating wastewater by using hot air
CN102375110A (en) Comprehensive automatic control console for alternating-current voltage withstand test
CN201726585U (en) Microwave surface wave plasma torch
CN205253504U (en) Unimodule dual -frenquency supersonic generator
CN104692500A (en) Device and method of improving water activity
CN202236487U (en) Ultrasonic atomizing air refresher
CN105498644A (en) Electrically controlled mechanical equipment for chemical synthesis
CN203178148U (en) Membrane life-test rack
CN201765300U (en) Integrated automatic console for alternating current pressure resistant test
CN201720438U (en) Whirlwind atomizing device used in production line for solar energy electric plate used ultra-fine aluminium powder
CN110172361A (en) Variable ratio frequency changer ultrasonic emulsion breaking processing equipment and crude oil dehydrating system
CN204824285U (en) Exoelectric normal atmospheric temperature water treatment facilities of high -speed fine liquid drop
CN201435285Y (en) Fluid treatment device for pipeline
CN203019716U (en) Sprayer of crimping device
CN201613642U (en) Plastic straight wire bending device
CN102633330A (en) Electromagnetic water treatment device for edible fungi
CN206008433U (en) A kind of exhaust-gas treatment recycling control system

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
CB02 Change of applicant information
CB02 Change of applicant information

Address after: 550000 third floor, No. 93 boiler plant, Xincun group, Erge village, Yunguan Township, Nanming District, Guiyang City, Guizhou Province [Yunguan Township]

Applicant after: Guizhou luobeiluo Biotechnology Co.,Ltd.

Address before: 551600 Building 9, Tongxin Avenue standardization plant, Dafang County Development Zone, Bijie City, Guizhou Province

Applicant before: Guizhou luobeiluo Biotechnology Co.,Ltd.

RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20200710