CN1113919A - highly rigid composite resin material - Google Patents
highly rigid composite resin material Download PDFInfo
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- CN1113919A CN1113919A CN 94106424 CN94106424A CN1113919A CN 1113919 A CN1113919 A CN 1113919A CN 94106424 CN94106424 CN 94106424 CN 94106424 A CN94106424 A CN 94106424A CN 1113919 A CN1113919 A CN 1113919A
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- prescription
- resin
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Abstract
Owing to the addition of excellent epoxy resin and polyacrylate and substituting of mixture of multiple inorganic elements for calcium carbonate used as the filler of the produced resin, so the strength of said resin is increased and shock resistance is reinforced. The good fluidity and fire retardant chlorinated polyethylene and polyvinyl alcohol are added in said material, so said material features fire-retardant and good working fluidity. The organic and inorganic metallic salts are added in to make the material resist light, heat and ageing and the service life of member is increased. Said material can be used in outdoor member.
Description
The present invention relates to a kind of novel high polymer composite resin material.It is widely used among the multiple products such as plastics tubing, rod, plate, section bar.
As everyone knows, because the composite high-molecular resin can replace steel, timber to make member, so be widely used, development rapidly.In the plastic prod, to make the highest to the requirement of plastics, the existing plastic material of section bar, consider multiple factor, use polyvinyl chloride to be basic resin mostly, its composition is various, goods are countless, in the section bar of excellent property is produced, be widely used just like following two kinds of prescriptions:
Composition of raw materials one prescription two
Polyvinyl chloride (CDE-3) 100-
CDE modified polyvinyl chloride-100
Tribasic property Tai-Ace S 150 3 3.5～4
Dibasicity aluminum phosphite 2-
Alkali lead stearate-0.5～1
Lead stearate 0.5～1-
Barium stearate 0.6～1-
Paraffin wax 0.8～1.2-
Lubricant (paraffin wax or stearic acid) is a small amount of
Lime carbonate (compound) 50～60 2～4
Titanium dioxide TiO
2-4
Coupling agent TC-1 trace trace
Mineral oil trace trace
Above-mentioned the first two component is a material matrix; Alkali components such as lead, barium are light, thermo-stabilizer; Lime carbonate is mineral filler.The product that utilizes this prescription to produce is being made longer member, or uses when the bigger place of surging force, shows all relatively poor shortcoming of rigidity intensity, and ageing-resistant, radiation resistance is bad thereby limited its use range.
The objective of the invention is to avoid above-mentioned shortcoming, and a kind of rigidity intensity height, anti-aging, radiation hardness and inexpensive resin formula are provided, this resin material can be widely used in building material industry, and outdoor goods.
The present invention can use following measure and realize, for improving the performance of high molecular resin composite material, the most basic is to solve from the selection of raw material and auxiliary material with at its blend proportion.Consider from raw material sources and economic aspect, we still adopt polyvinyl chloride is base material, choosing adds good Resins, epoxy, PAE-polyacrylate in order to gain in strength, the EVA-polyvinyl alcohol of the CDE-chlorinatedpolyethylene of fire-retardant in addition again, good fluidity, fire-retardant, good toughness, aspect photostabilizer, adopt organic and inorganic, zinc, tin class material.Organic and inorganic salt plumbous, barium is used in the thermo-stabilizer aspect.On filler material, forget a large amount of lime carbonate commonly used and replaced multiple inorganic elements mixture, wherein some component also has porousness, and light weight so improved the rigidity of material significantly, has improved the uvioresistant absorptive function and has reduced cost.Its prescription is as follows:
Prescription one (resin and stablizer part):
Material name prescription (% Wt) brief description
PVC-polyvinyl chloride (PVC) RESINS 70～80 base resins
ABS-resin 3～8
Resins, epoxy thermosetting powder 0.5～2
CDE-chlorinatedpolyethylene 1～4 strengthens resin
EVA-polyvinyl alcohol 1～4
PAE-polyacrylate 0.5～1
Active zinc flower 1～4
Two maleics acid dibutyl tin 0.5
Toxilic acid dibutyl tin 0.5 photostabilizer
Dihydroxy benaophenonel 0.5
Dihydroxyl 4,4 dimethoxy-benzophenones 0.5
Tribasic lead sulfate 1～4
Dibasic lead phosphite 1～2
Alkali lead stearate 0.5 thermo-stabilizer
Lead stearate 0.5
Barium stearate 0.5
Prescription two (filler and other parts):
Material name prescription (%Wt) brief description
3CaOAl
2O
36H
2O-calcium aluminate 20
Na
2OAl
2O
32SiO
2NH
2O-titanium sodalite 15
CaOTiO
2-calcium titanate 10
CaOAl
2O
32SiO
2NH
2O-calcium drenches stone 2 uv-absorbing
CaCO
3-calcite 5 is filled
Fe
2O
3-rhombohedral iron ore 5 strengthens
Al
2O
3H
2The O-pine is aluminium stone 3 more
Na
2CO
3-yellow soda ash 1
TiO
2-titanium dioxide 4
SiO
2-silica 15
Electrolytic etching of metal aluminium aluminium ground-slag 5～10 ultraviolet shieldings
Silicate cement 5～10 strengthens
Paraffin wax 1 is lubricated
Mineral oil 0.5
The coupling of coupling agent-101 1.5 molecule
Coupling agent-105 1
With the raw material of prescription one ratio preparation, behind the thorough mixing, granulation.With the raw material of prescription two ratios preparation, thorough mixing, oven dry, control size is more than 300 orders.Then, press resin (prescription one) 55%, stopping composition (prescription two) 45%(weight ratio), add an amount of pigment and an amount of active oxidation aluminium powder simultaneously, it is even fully to be mixed, controlled temperature under 170～180 ℃, granulation.Just become the raw material of making various rods, pipe, plate, section bar.This material is tested through reality, the low temperature impact strength: 1 meter HI high impact section bar of 1 kilogram of weight, and fragmentation≤1 ‰ (10 ± 1 ℃), flexural strength is 900 kilograms per centimeter
2(23 ± 2 ℃), tensile strength: 500 kilograms per centimeter
2Certainly put out in 10～15 seconds during (23 ± 2 ℃) burning, can all absorb the ultraviolet ray of 300～400mm scope, percent thermal shrinkage 2 ‰ (100 ± 3 ℃) meets national GB5237-85 standard fully.
The present invention has the following advantages compared to existing technology:
This high rigid resin material except that the advantage with general plastic prod, proves through production practice that this product is high-and low-temperature resistance more, anti-illumination, and radioprotective, the ageing-resistant life-span is long, so can be used in outdoor products.Replace the mineral filler lime carbonate used always because this product uses porous and has active filler, this product has strengthened intensity, has reduced cost.Particularly this product rigidity is good, and the intensity height has strong shock-resistance, is subjected to impulse force stronger in manufacturing, in the section bar that stress ratio is concentrated, more shows its superiority.
Embodiments of the invention are described as follows:
With the raw material purchased in following ratio mixing, and granulation.
Prescription one (resin and stablizer part):
Material name prescription (% Wt) brief description
PVC-polyvinyl chloride (PVC) RESINS 80 base resins
ABS-resin 5
Resins, epoxy thermosetting powder 0.5
CDE-chlorinatedpolyethylene 1.5 strengthens resin
EVA-polyvinyl alcohol 2.5
PAE-polyacrylate 0.5
Active zinc flower 3
Two maleics acid dibutyl tin 0.5
Toxilic acid dibutyl tin 0.5 photostabilizer
Dihydroxy benaophenonel 0.5
Dihydroxyl 4,4 dimethoxy-benzophenones 0.5
Tribasic lead sulfate 2
Dibasic lead phosphite 1.5
Alkali lead stearate 0.5 thermo-stabilizer
Lead stearate 0.5
Barium stearate 0.5
Press surface compositions preparation filler then, abundant mixing is dried stand-byly, and control size is more than 300 orders.
Prescription two (filler and other parts):
Material name prescription (%Wt) brief description
3CaOAl
2O
36H
2O-calcium aluminate 20
Na
2OAl
2O
32SiO
2NH
2O-titanium sodalite 15
CaOTiO
2-calcium titanate 10
CaOAl
2O
32SiO
2NH
2O-calcium drenches stone 2 uv-absorbing
CaCO
3-calcite 5 is filled
Fe
2O
3-rhombohedral iron ore 5 strengthens
Al
2O
3H
2The O-pine is aluminium stone 3 more
Na
2CO
3-yellow soda ash 1
TiO
2-titanium dioxide 4
SiO
2-silica 15
Electrolytic etching of metal aluminium aluminium ground-slag 8 ultraviolet shieldings
Silicate cement 8 strengthens
Paraffin wax 1 is lubricated
Mineral oil 0.5
The coupling of coupling agent-101 1.5 molecule
Coupling agent-105 1
To fill a prescription again one and the prescription two thorough mixing, in 180 ℃ of following granulations.
Claims (1)
1, a kind of highly rigid composite resin material is made of raw material and auxiliary material, it is characterized in that, the prescription of material is made of following two prescriptions:
Prescription one is resin and stablizer part: base resin adopts PVC-polyvinyl chloride (PVC) RESINS 70～80%; Strengthening resin uses: ABS-resin 3～8%, Resins, epoxy thermosetting powder 0.5～2%, CDE-chlorinatedpolyethylene 1～4%, EVA-polyvinyl alcohol 1～4%, PAE-polyacrylic resin 0.5～1%; Photostabilizer active zinc flower 1～4%, two maleics acid dibutyl tin 0.5%, toxilic acid dibutyl tin 0.5%, dihydroxy benaophenonel 0.5%, dihydroxyl 4,4 dimethoxy-benzophenones 0.5%; Thermo-stabilizer adds tribasic lead sulfate 1～4%, dibasic lead phosphite 1～2%, alkali lead stearate 0.5%, lead stearate 0.5% and barium stearate 0.5%.
The filler part of its prescription two: uv-absorbing filler 3CaOAl
2O
36H
2O-calcium aluminate 20%, Na
2OAl
2O
32SiO
2NH
2O-titanium sodalite 15%, CaOTO
2-calcium titanate 10%, CaOAl
2O
32SiO
2NH
2O-calcium drenches stone 2%; Stopping composition CaCO
3-calcite 5%; Strengthen and use Fe
2O
3-rhombohedral iron ore 5%, Al
2O
3H
2The O-pine is aluminium stone 3% more, Na
2CO
3-yellow soda ash 1%, TiO
2-titanium dioxide 4% and SiO
2-silica 1 5%; Electrolytic etching of metal aluminium aluminium ground-slag 5～10% is adopted in the ultraviolet shielding effect, strengthens material and is silicate cement 5～10%; The paraffin 1% that adds lubricate again, mineral oil 0.5%; And the coupling agent-101 1.5% of molecule coupled action, coupling agent-105 1% have been added.
Will be in the raw material of prescription one ratio preparation, behind the thorough mixing, granulation; With the system raw material that prescription two ratios are joined, thorough mixing, oven dry, control size is more than 300 orders.Then, by prescription one 55%, fill a prescription 2 45%, add an amount of pigment and an amount of active oxidation aluminium powder simultaneously, it is even fully to be mixed, and controlled temperature is under 170～180 ℃, and high rigid resin material has just been made in granulation.
(above-mentioned " % " is all weight percent)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 94106424 CN1113919A (en) | 1994-06-23 | 1994-06-23 | highly rigid composite resin material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 94106424 CN1113919A (en) | 1994-06-23 | 1994-06-23 | highly rigid composite resin material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1113919A true CN1113919A (en) | 1995-12-27 |
Family
ID=5032565
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 94106424 Pending CN1113919A (en) | 1994-06-23 | 1994-06-23 | highly rigid composite resin material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1113919A (en) |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1095491C (en) * | 1999-01-08 | 2002-12-04 | 周兴国 | Preparation method for anti-soaking/leaking heat-insulated solidified-binding gum |
| CN1311249C (en) * | 2004-07-06 | 2007-04-18 | 长兴化学工业股份有限公司 | Optical film having ultraviolet ray obseption ability |
| CN1320050C (en) * | 2004-02-09 | 2007-06-06 | 上海达凯塑胶有限公司 | Rolled substrate for high temperature resistant smart card and method for making same |
| CN100451078C (en) * | 2005-08-11 | 2009-01-14 | 中国石油天然气集团公司 | Silver coloured perchloro polyethylene external corrusion resistant paint and its manufacturing method |
| CN101555339B (en) * | 2009-05-21 | 2011-02-16 | 中国科学院长春应用化学研究所 | Method for preparing compound material of modified polyvinyl chloride resin and thermosetting resin |
| CN102140212A (en) * | 2011-04-07 | 2011-08-03 | 浙江盛丰塑胶有限公司 | Production process of semi-rigid polyvinyl chloride portrait calendered film |
| CN102344622A (en) * | 2010-08-03 | 2012-02-08 | 苏州富通电器塑业有限公司 | Outdoor high-molecular co-extrusion floor and its preparation method |
| CN102850713A (en) * | 2012-09-24 | 2013-01-02 | 吴江市信许塑料鞋用配套有限公司 | Preparation method of high-temperature resistant insulating sole material |
| CN103992602A (en) * | 2014-05-22 | 2014-08-20 | 安徽嘉木橡塑工业有限公司 | Thermal conductive plastic composite |
| CN104250408A (en) * | 2013-06-27 | 2014-12-31 | 蓝星（北京）特种纤维技术研发中心有限公司 | Pvc composite resin composition and preparation method thereof |
| CN104312039A (en) * | 2014-10-14 | 2015-01-28 | 上海远洲管业科技股份有限公司 | Preparation method of heat-fusible modified polyvinyl chloride (PVC) pipe |
| CN108342031A (en) * | 2018-03-27 | 2018-07-31 | 江苏凤腾塑料有限公司 | A kind of shock resistance high transparency PVC |
| CN109337230A (en) * | 2018-08-27 | 2019-02-15 | 海宁市怡球塑业有限公司 | A kind of flame retardant plastics profile |
| CN110789101A (en) * | 2019-09-26 | 2020-02-14 | 安徽自动化仪表有限公司 | Production process of special corrosion-resistant low-weight composite material for cable bridge |
| CN114316470A (en) * | 2021-12-31 | 2022-04-12 | 无锡市弘远塑业科技有限公司 | Rigidity improving method suitable for high-filling PVC material |
-
1994
- 1994-06-23 CN CN 94106424 patent/CN1113919A/en active Pending
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1095491C (en) * | 1999-01-08 | 2002-12-04 | 周兴国 | Preparation method for anti-soaking/leaking heat-insulated solidified-binding gum |
| CN1320050C (en) * | 2004-02-09 | 2007-06-06 | 上海达凯塑胶有限公司 | Rolled substrate for high temperature resistant smart card and method for making same |
| CN1311249C (en) * | 2004-07-06 | 2007-04-18 | 长兴化学工业股份有限公司 | Optical film having ultraviolet ray obseption ability |
| CN100451078C (en) * | 2005-08-11 | 2009-01-14 | 中国石油天然气集团公司 | Silver coloured perchloro polyethylene external corrusion resistant paint and its manufacturing method |
| CN101555339B (en) * | 2009-05-21 | 2011-02-16 | 中国科学院长春应用化学研究所 | Method for preparing compound material of modified polyvinyl chloride resin and thermosetting resin |
| CN102344622B (en) * | 2010-08-03 | 2013-08-14 | 苏州富通电器塑业有限公司 | Outdoor high-molecular co-extrusion floor and its preparation method |
| CN102344622A (en) * | 2010-08-03 | 2012-02-08 | 苏州富通电器塑业有限公司 | Outdoor high-molecular co-extrusion floor and its preparation method |
| CN102140212B (en) * | 2011-04-07 | 2013-03-06 | 浙江盛丰塑胶有限公司 | Production process of semi-rigid polyvinyl chloride portrait calendered film |
| CN102140212A (en) * | 2011-04-07 | 2011-08-03 | 浙江盛丰塑胶有限公司 | Production process of semi-rigid polyvinyl chloride portrait calendered film |
| CN102850713A (en) * | 2012-09-24 | 2013-01-02 | 吴江市信许塑料鞋用配套有限公司 | Preparation method of high-temperature resistant insulating sole material |
| CN104250408A (en) * | 2013-06-27 | 2014-12-31 | 蓝星（北京）特种纤维技术研发中心有限公司 | Pvc composite resin composition and preparation method thereof |
| CN104250408B (en) * | 2013-06-27 | 2016-08-24 | 蓝星（北京）特种纤维技术研发中心有限公司 | Pvc composite resin composition and preparation method thereof |
| CN103992602A (en) * | 2014-05-22 | 2014-08-20 | 安徽嘉木橡塑工业有限公司 | Thermal conductive plastic composite |
| CN104312039A (en) * | 2014-10-14 | 2015-01-28 | 上海远洲管业科技股份有限公司 | Preparation method of heat-fusible modified polyvinyl chloride (PVC) pipe |
| CN108342031A (en) * | 2018-03-27 | 2018-07-31 | 江苏凤腾塑料有限公司 | A kind of shock resistance high transparency PVC |
| CN109337230A (en) * | 2018-08-27 | 2019-02-15 | 海宁市怡球塑业有限公司 | A kind of flame retardant plastics profile |
| CN110789101A (en) * | 2019-09-26 | 2020-02-14 | 安徽自动化仪表有限公司 | Production process of special corrosion-resistant low-weight composite material for cable bridge |
| CN114316470A (en) * | 2021-12-31 | 2022-04-12 | 无锡市弘远塑业科技有限公司 | Rigidity improving method suitable for high-filling PVC material |
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| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |