CN111354746A - Optoelectronic integrated circuit - Google Patents

Optoelectronic integrated circuit Download PDF

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Publication number
CN111354746A
CN111354746A CN201811563051.XA CN201811563051A CN111354746A CN 111354746 A CN111354746 A CN 111354746A CN 201811563051 A CN201811563051 A CN 201811563051A CN 111354746 A CN111354746 A CN 111354746A
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layer
waveguide
integrated circuit
optoelectronic integrated
detection device
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尹晓雪
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Xian Keruisheng Innovative Technology Co Ltd
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F39/00Integrated devices, or assemblies of multiple devices, comprising at least one element covered by group H10F30/00, e.g. radiation detectors comprising photodiode arrays
    • H10F39/10Integrated devices
    • H10F39/103Integrated devices the at least one element covered by H10F30/00 having potential barriers, e.g. integrated devices comprising photodiodes or phototransistors
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/10Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings of the optical waveguide type
    • G02B6/12Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings of the optical waveguide type of the integrated circuit kind
    • G02B6/12004Combinations of two or more optical elements
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F77/00Constructional details of devices covered by this subclass
    • H10F77/30Coatings
    • H10F77/306Coatings for devices having potential barriers

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
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Abstract

The invention relates to a photoelectric integrated circuit, comprising a photoelectric conversion region and a semiconductor device region; the photoelectric conversion region comprises a light-emitting device, a waveguide device and a detection device, wherein the light-emitting device, the waveguide device and the detection device are prepared on the same silicon-based substrate, and the light-emitting device, the waveguide device and the detection device are sequentially connected; the semiconductor device region comprises a semiconductor device, and the semiconductor device is connected with the detection device. According to the embodiment of the invention, the same-layer monolithic photoelectric integration is realized by arranging the compressive strain materials on the surface of the PMOS and the surface of the waveguide device, arranging the tensile strain materials on the surface of the NMOS and the surface of the detection device and modulating the forbidden band widths of the waveguide device and the detection device through strain.

Description

光电集成电路Optoelectronic integrated circuits

技术领域technical field

本发明属于半导体技术领域,具体涉及一种光电集成电路。The invention belongs to the technical field of semiconductors, and particularly relates to an optoelectronic integrated circuit.

背景技术Background technique

光纤通信的发展极其迅速,至1991年底,全球已敷设光缆563万千米,到1995年已超过1100万千米。光纤通信在单位时间内能传输的信息量大。一对单模光纤可同时开通35000个电话,而且它还在飞速发展。光纤通信的建设费用正随着使用数量的增大而降低,同时它具有体积小,重量轻,使用金属少,抗电磁干扰、抗辐射性强,保密性好,频带宽,抗干扰性好,防窃听、价格便宜等优点。The development of optical fiber communication is extremely rapid. By the end of 1991, 5.63 million kilometers of optical cables had been laid in the world, and by 1995, it had exceeded 11 million kilometers. Optical fiber communication can transmit a large amount of information per unit time. A pair of single-mode fibers can open 35,000 calls simultaneously, and it's growing rapidly. The construction cost of optical fiber communication is decreasing with the increase of the number of use. At the same time, it has the advantages of small size, light weight, less metal used, strong anti-electromagnetic interference and radiation resistance, good confidentiality, wide frequency band, and good anti-interference performance. Anti-eavesdropping, cheap and other advantages.

光电集成电路(optoelectronic integrated circuit,简称OEIC),是指把光器件和电器件集成为有某种光电功能的模块或组件,其可以将光纤通信直接应用于芯片级,是推动光纤通信进一步发展的核心技术。一般而言,用分立器件的管心集成在一起的称为光电混合集成模块,在技术上已较为成熟,而用光和电的元器件集成在同一块半导体基片上的,称为单片集成模块,它是光电集成的发展方向。Optoelectronic integrated circuit (OEIC) refers to the integration of optical devices and electrical devices into modules or components with certain optoelectronic functions, which can directly apply optical fiber communication to the chip level and promote the further development of optical fiber communication. Core Technology. Generally speaking, the integration of the cores of discrete devices is called an optoelectronic hybrid integrated module, which is relatively mature in technology, while the integration of optical and electrical components on the same semiconductor substrate is called monolithic integration. Module, which is the development direction of optoelectronic integration.

然而,目前同一块半导体基片上的光电集成电路,由于探测器件、波导器件的能带调制问题使得光电集成存在很大难度。However, in the current optoelectronic integrated circuits on the same semiconductor substrate, the problem of energy band modulation of detection devices and waveguide devices makes optoelectronic integration very difficult.

发明内容SUMMARY OF THE INVENTION

为了解决现有技术中存在的上述问题,本发明提供了一种光电集成电路。本发明要解决的技术问题通过以下技术方案实现:In order to solve the above problems existing in the prior art, the present invention provides an optoelectronic integrated circuit. The technical problem to be solved by the present invention is realized by the following technical solutions:

本发明实施例提供了一种光电集成电路,包括光电转换区和半导体器件区;其中,An embodiment of the present invention provides an optoelectronic integrated circuit, including a photoelectric conversion region and a semiconductor device region; wherein,

所述光电转换区包括发光器件、波导器件及探测器件,所述发光器件、所述波导器件及所述探测器件制备于同一硅基衬底上,且所述发光器件、所述波导器件及所述探测器件依次相连;The photoelectric conversion region includes a light-emitting device, a waveguide device, and a detection device. The light-emitting device, the waveguide device, and the detection device are prepared on the same silicon-based substrate, and the light-emitting device, the waveguide device, and the detection device are fabricated. The detection devices are connected in sequence;

所述半导体器件区包括半导体器件,且所述半导体器件与所述探测器件相连。The semiconductor device region includes a semiconductor device, and the semiconductor device is connected to the detection device.

在本发明的一个实施例中,所述发光器件为PIN二极管,所述PIN二极管包括第一GeSn合金层、第一Ge层和第一Si层,所述第一GeSn合金层、所述第一Ge层和所述第一Si层依次层叠于所述硅基衬底上。In an embodiment of the present invention, the light-emitting device is a PIN diode, the PIN diode includes a first GeSn alloy layer, a first Ge layer and a first Si layer, the first GeSn alloy layer, the first A Ge layer and the first Si layer are sequentially stacked on the silicon-based substrate.

在本发明的一个实施例中,所述波导器件包括SiO2层、第二GeSn合金层、Si覆盖层及压应力层;其中,In an embodiment of the present invention, the waveguide device includes a SiO 2 layer, a second GeSn alloy layer, a Si cover layer and a compressive stress layer; wherein,

所述SiO2层位于所述波导器件的两侧,且与所述发光器件、所述探测器件相连以形成隔离;The SiO 2 layer is located on both sides of the waveguide device, and is connected with the light-emitting device and the detection device to form isolation;

所述第二GeSn合金层、所述Si覆盖层及所述压应力层依次层叠于所述硅基衬底上。The second GeSn alloy layer, the Si cover layer and the compressive stress layer are sequentially stacked on the silicon-based substrate.

在本发明的一个实施例中,所述压应力层为SiN膜,且厚度为10~20nm。In an embodiment of the present invention, the compressive stress layer is a SiN film and has a thickness of 10-20 nm.

在本发明的一个实施例中,所述波导器件为H型结构。In an embodiment of the present invention, the waveguide device is an H-type structure.

在本发明的一个实施例中,所述探测器件包括第三GeSn合金层、第二Ge层、第二Si层及张应力层,所述第三GeSn合金层、所述第二Ge层、所述第二Si层和所述张应力层依次层叠于所述硅基衬底上。In an embodiment of the present invention, the detection device includes a third GeSn alloy layer, a second Ge layer, a second Si layer and a tensile stress layer, the third GeSn alloy layer, the second Ge layer, the The second Si layer and the tensile stress layer are sequentially stacked on the silicon-based substrate.

在本发明的一个实施例中,所述压应力层为SiN膜,且厚度为10~20nm。In an embodiment of the present invention, the compressive stress layer is a SiN film and has a thickness of 10-20 nm.

在本发明的一个实施例中,所述半导体器件为CMOS器件。In one embodiment of the present invention, the semiconductor device is a CMOS device.

在本发明的一个实施例中,所述CMOS器件的NMOS与所述探测器件相连,且在所述NMOS表面设置有张应力层,所述张应力层厚度为10~20nm。In an embodiment of the present invention, the NMOS of the CMOS device is connected to the detection device, and a tensile stress layer is provided on the surface of the NMOS, and the thickness of the tensile stress layer is 10-20 nm.

在本发明的一个实施例中,所述CMOS器件的PMOS表面设置有压应力层,所述压应力层厚度为10~20nm。In an embodiment of the present invention, a compressive stress layer is provided on the PMOS surface of the CMOS device, and the thickness of the compressive stress layer is 10-20 nm.

与现有技术相比,本发明的有益效果:Compared with the prior art, the beneficial effects of the present invention:

1、通过将发光器件、波导器件和探测器件与半导体器件集成在同一硅基材料上,实现单片光电集成,完成芯片级的光信号传输;1. By integrating light-emitting devices, waveguide devices and detection devices with semiconductor devices on the same silicon-based material, monolithic optoelectronic integration is achieved, and chip-level optical signal transmission is completed;

2、在波导器件和探测器件表面设置应力膜,实现对波导器件和探测器件的应力调制,能够较为灵活地控制波导器件和探测器件的禁带宽度,提高光电转换效率;2. A stress film is arranged on the surface of the waveguide device and the detection device to realize the stress modulation of the waveguide device and the detection device, which can flexibly control the band gap of the waveguide device and the detection device, and improve the photoelectric conversion efficiency;

2、本发明的制备工艺与传统硅基工艺兼容,工艺简单且成本较低。2. The preparation process of the present invention is compatible with the traditional silicon-based process, the process is simple and the cost is low.

附图说明Description of drawings

图1(a)-图1(b)为本发明实施例提供的一种光电集成电路的结构示意图;1(a)-FIG. 1(b) are schematic structural diagrams of an optoelectronic integrated circuit provided by an embodiment of the present invention;

图2为本发明实施提供的SiO2层厚度对光信号的透射度的关系示意图;2 is a schematic diagram of the relationship between the thickness of the SiO 2 layer and the transmittance of the optical signal provided by the implementation of the present invention;

图3为本发明实施例提供的波导器件的俯视结构示意图;FIG. 3 is a schematic top-view structural diagram of a waveguide device provided by an embodiment of the present invention;

图4为本发明实施例提供的波导器件的过渡波导形状对光信号透射效果的影响示意图;FIG. 4 is a schematic diagram of the influence of the transition waveguide shape of the waveguide device provided by the embodiment of the present invention on the transmission effect of the optical signal;

图5为本发明实施例提供的一种波导器件在SiN膜下的应力受力示意图;FIG. 5 is a schematic diagram of stress and force of a waveguide device under SiN film provided by an embodiment of the present invention;

图6为本发明实施例提供的探测器件在SiN膜下的应力受力示意图;6 is a schematic diagram of the stress and force of the detection device provided by the embodiment of the present invention under the SiN film;

图7a~7u为本发明实施例提供的一种光电集成电路的制备方法的工艺示意图。7a-7u are schematic process diagrams of a method for fabricating an optoelectronic integrated circuit according to an embodiment of the present invention.

具体实施方式Detailed ways

下面结合具体实施例对本发明做进一步详细的描述,但本发明的实施方式不限于此。The present invention will be described in further detail below with reference to specific embodiments, but the embodiments of the present invention are not limited thereto.

实施例一Example 1

本发明的光电集成电路可以包括有光电转换器件及与该光电转换器件相连的其他半导体器件。其中,光电转化器件主要包括发光器件、波导器件和探测器件,发光器件用于发出芯片级的光信号,波导器件用于为该光信号提供传输通道,而探测器件用于接收该光信号并将该光信号转化为电信号以整体实现光电转换。光电转换器件相连的半导体器件,可以是CMOS器件、TFT器件、FinFET器件等,可以根据实际电路需求进行设置,此处不做任何限制。The optoelectronic integrated circuit of the present invention may include a photoelectric conversion device and other semiconductor devices connected to the photoelectric conversion device. Among them, the photoelectric conversion device mainly includes a light-emitting device, a waveguide device and a detection device. The light-emitting device is used to emit a chip-level optical signal, the waveguide device is used to provide a transmission channel for the optical signal, and the detection device is used to receive the optical signal. The optical signal is converted into an electrical signal to realize photoelectric conversion as a whole. The semiconductor device connected to the photoelectric conversion device may be a CMOS device, a TFT device, a FinFET device, etc., and may be set according to actual circuit requirements, and no limitation is imposed here.

具体地,请参见图1,图1(a)-图1(b)为本发明实施例提供的一种光电集成电路的结构示意图,以半导体器件为CMOS器件为例进行说明。该光电集成电路包括光电转换区和半导体器件区;其中,光电转换区包括发光器件、波导器件及探测器件,发光器件、波导器件及探测器件制备于同一硅基衬底上,且发光器件、波导器件及探测器件依次相连;半导体器件区包括半导体器件,且半导体器件与探测器件相连。Specifically, please refer to FIG. 1 . FIGS. 1( a ) to 1 ( b ) are schematic structural diagrams of an optoelectronic integrated circuit provided by an embodiment of the present invention, and the semiconductor device is a CMOS device as an example for description. The optoelectronic integrated circuit includes a photoelectric conversion region and a semiconductor device region; wherein, the photoelectric conversion region includes a light-emitting device, a waveguide device and a detection device, the light-emitting device, the waveguide device and the detection device are prepared on the same silicon-based substrate, and the light-emitting device, the waveguide The device and the detection device are connected in sequence; the semiconductor device region includes the semiconductor device, and the semiconductor device is connected with the detection device.

发光器件为PIN二极管,PIN二极管包括层叠于所述硅基衬底上的GeSn合金层010、Ge层011和Si层012。其中,硅基衬底可以包括Si衬底001和p型Si外延层002。The light-emitting device is a PIN diode, and the PIN diode includes a GeSn alloy layer 010, a Ge layer 011 and a Si layer 012 stacked on the silicon-based substrate. The silicon-based substrate may include a Si substrate 001 and a p-type Si epitaxial layer 002 .

波导器件包括SiO2层014、GeSn合金层010、Si覆盖层015及压应力层018。GeSn合金层010、Si覆盖层015及压应力层018依次层叠于硅基衬底上。其中,SiO2层014位于波导器件的两侧,且与发光器件、探测器件相连以形成隔离。这层隔离对有源器件与无源器件进行了隔离,而且起电隔离作用,防止两端光电器件器件产生寄生效应。需要重点强调的是,SiO2隔离层在不同厚度下的透射度见图2所示,图2为本发明实施提供的SiO2层厚度对光信号的透射度的关系示意图,由图2中可以看出,波长越长受界面的影响越小;20nm厚的SiO2隔离层对光传输的影响基本与没有隔离层时一致,当SiO2隔离层逐渐加厚时,透射率逐渐减小,而且增加相同的越厚透射率却减小的更多。也就是说,隔离层的厚度与透射度之间并不是线性关系,而是随着厚度的增加,透射度减小的更多。上述结论是因为随着厚度的增加,SiO2的散射损耗和反射都越来越大导致耦合损耗增大。波长在1.75μm左右时,无SiO2层和20nm厚SiO2层的器件与波导之间的耦合效率基本为84%~85%,而SiO2厚度为50nm厚的耦合效率基本为81%~82%。The waveguide device includes a SiO 2 layer 014 , a GeSn alloy layer 010 , a Si capping layer 015 and a compressive stress layer 018 . The GeSn alloy layer 010, the Si capping layer 015 and the compressive stress layer 018 are sequentially stacked on the silicon-based substrate. Among them, the SiO 2 layer 014 is located on both sides of the waveguide device, and is connected with the light-emitting device and the detection device to form isolation. This layer of isolation isolates the active device from the passive device, and acts as an electrical isolation to prevent parasitic effects of the optoelectronic devices at both ends. It should be emphasized that the transmittance of the SiO 2 isolation layer under different thicknesses is shown in Figure 2. Figure 2 is a schematic diagram of the relationship between the thickness of the SiO 2 layer and the transmittance of the optical signal provided by the implementation of the present invention. It can be seen that the longer the wavelength is, the less the influence of the interface is; the influence of the 20nm-thick SiO2 isolation layer on the light transmission is basically the same as that without the isolation layer. When the SiO2 isolation layer is gradually thickened, the transmittance gradually decreases, and Increase the same thicker transmittance but decrease more. That is to say, there is no linear relationship between the thickness of the isolation layer and the transmittance, but the transmittance decreases more as the thickness increases. The above conclusion is because with the increase of thickness, the scattering loss and reflection of SiO2 are both larger and larger, which leads to the increase of coupling loss. When the wavelength is about 1.75μm, the coupling efficiency between the device and the waveguide without SiO2 layer and 20nm thick SiO2 layer is basically 84%~85%, while the coupling efficiency with 50nm thick SiO2 layer is basically 81%~82%. %.

另外,Si覆盖层015为α-Si材料,添加覆盖层能够减小耦合损耗,这与光纤与器件耦合的情况基本一致,相对侧墙设计更能够减小损耗。In addition, the Si cover layer 015 is made of α-Si material, and the addition of the cover layer can reduce the coupling loss, which is basically the same as the coupling between the optical fiber and the device, and can reduce the loss more than the sidewall design.

进一步地,波导器件为H型结构。这里需要重点描述的是,如图3所示,图3为本发明实施例提供的波导器件的俯视结构示意图,与发光器件连接的波导器件锥形过渡波导的形状和长度中,不同侧面的过渡波导,可以为凹型、凸型。从图4的仿真结果中看到,凹型过渡波导增大传输损耗,凸型过渡波导在定过渡长度传输中有优势,在实际应用允许的情况下,尽量选取较长的过渡波长。另外,锥形过渡波导长度(L)越长,其在传播方向的变化尺寸越小,但是并不是线性增加,随着长度的增加,损耗减小就越来越少,因此对光的传输损耗影响也就越小。其中,锥形过渡波导长度L分别选取5μm~15μm,优选选择10μm。Further, the waveguide device has an H-type structure. What needs to be emphasized here is that, as shown in FIG. 3 , which is a schematic top-view structure of a waveguide device provided by an embodiment of the present invention, in the shape and length of the tapered transition waveguide of the waveguide device connected to the light-emitting device, the transitions on different sides The waveguide can be concave or convex. It can be seen from the simulation results in Fig. 4 that the concave transition waveguide increases the transmission loss, and the convex transition waveguide has advantages in transmission with a fixed transition length. When practical applications allow, try to select a longer transition wavelength. In addition, the longer the length (L) of the tapered transition waveguide, the smaller the change size in the propagation direction, but it does not increase linearly. As the length increases, the loss decreases less and less, so the light transmission loss The impact is also smaller. Among them, the length L of the tapered transition waveguide is selected from 5 μm to 15 μm, preferably 10 μm.

探测器件包括GeSn合金层010、Ge层011、Si层012及张应力层019,GeSn合金层010、Ge层011、Si层012及张应力层019依次层叠于所述硅基衬底上。其中,压应力层为SiN膜,且厚度可以为10~20nm。The detection device includes a GeSn alloy layer 010, a Ge layer 011, a Si layer 012, and a tensile stress layer 019. The GeSn alloy layer 010, the Ge layer 011, the Si layer 012, and the tensile stress layer 019 are sequentially stacked on the silicon-based substrate. Wherein, the compressive stress layer is a SiN film, and the thickness can be 10-20 nm.

对压应力膜和张应力膜进行重点描述如下:The compressive stress film and the tensile stress film are mainly described as follows:

请参见图5,图5为本发明实施例提供的一种波导器件在SiN膜下的应力受力示意图。波导包裹在SiN膜018内,在SiN膜018的作用下波导两侧受到压应力,禁带宽度增大;其中,压应力与禁带宽度的关系如下:Please refer to FIG. 5. FIG. 5 is a schematic diagram of stress and force of a waveguide device under a SiN film according to an embodiment of the present invention. The waveguide is wrapped in the SiN film 018. Under the action of the SiN film 018, both sides of the waveguide are subjected to compressive stress, and the band gap increases. The relationship between the compressive stress and the band gap is as follows:

Fwg=0.6+0.03×Eg-0.02×Eg2 F wg =0.6+0.03×Eg-0.02×Eg 2

其中,Fw#为波导在SiN膜018的作用下受到的压应力,Eg为波导的禁带宽度。Among them, F w# is the compressive stress received by the waveguide under the action of the SiN film 018, and Eg is the forbidden band width of the waveguide.

在其他工艺条件不变的情况下,反应温度越高,形成氮化硅薄膜压应力越大,且呈一定的线性关系。在其他工艺条件不变的情况下,反应压强越高,形成氮化硅薄膜压应力越小。在其他工艺条件不变的情况下,低频功率越大,形成氮化硅薄膜压应力越大。Under the condition that other process conditions remain unchanged, the higher the reaction temperature is, the greater the compressive stress of the silicon nitride film is formed, and there is a certain linear relationship. Under the condition that other process conditions remain unchanged, the higher the reaction pressure is, the smaller the compressive stress of the silicon nitride film is formed. Under the condition that other process conditions remain unchanged, the greater the low frequency power, the greater the compressive stress of the silicon nitride film formed.

其中,设Fwg为氮化硅压应力膜使所述波导结构中产生的压应力大小,则Fwg和温度T2的关系满足:Wherein, let Fwg be the size of the compressive stress generated in the waveguide structure caused by the silicon nitride compressive stress film, then the relationship between Fwg and temperature T 2 satisfies:

Fwg=-1.0×Twg-463.6F wg = -1.0×T wg -463.6

其中,Fwg的单位为Pa,Twg的单位为摄氏度。Wherein, the unit of F wg is Pa, and the unit of T wg is Celsius.

优选地,温度的取值范围为340℃~360℃。Preferably, the temperature ranges from 340°C to 360°C.

具体地,在其他工艺条件不变的情况下,压强越高,SiN膜018使所述波导结构中产生的压应力越小。Specifically, under the condition that other process conditions remain unchanged, the higher the pressure, the smaller the compressive stress generated in the waveguide structure caused by the SiN film 018.

其中,压应力Fwg大小和压强Pwg的关系满足:Among them, the relationship between the compressive stress F wg and the pressure P wg satisfies:

Fwg=1.03×Pwg-1365.5F wg =1.03×P wg -1365.5

其中,Pwg的单位为mTorr。The unit of P wg is mTorr.

优选地,压强的取值为500mTorr。Preferably, the value of the pressure is 500 mTorr.

具体地,功率为低频功率,在其他工艺条件不变的情况下,功率越大,SiN膜018使所述波导结构中产生的压应力越大。Specifically, the power is low-frequency power. Under the condition that other process conditions remain unchanged, the greater the power, the greater the compressive stress generated in the waveguide structure caused by the SiN film 018.

其中,压应力Fwg大小和第一功率Rwg的关系满足:Among them, the relationship between the compressive stress F wg and the first power R wg satisfies:

Fwg=0.7×Rwg-813.4F wg =0.7×R wg -813.4

其中,Rwg的单位为W。Wherein, the unit of R wg is W.

优选地,第一功率Rwg的大小为150W。Preferably, the magnitude of the first power R wg is 150W.

具体地,在其他工艺条件不变的情况下,硅烷(SiH4)和氨气(NH3)的气体流量比X与压应力的关系如下:Specifically, under the condition that other process conditions remain unchanged, the relationship between the gas flow ratio X of silane (SiH 4 ) and ammonia (NH 3 ) and the compressive stress is as follows:

Fwg=265.4×Xwg 2-168×Xwg-560F wg =265.4×X wg 2 -168×X wg -560

优选地,Xwg为2。Preferably, X wg is 2.

请参见图6,图6为本发明实施例提供的探测器件在SiN膜下的应力受力示意图。SiN膜019为张应力膜,探测器包裹在SiN膜019,在张应力膜的作用下,探测器两侧收到张应力,禁带宽度减小。Referring to FIG. 6 , FIG. 6 is a schematic diagram of stress and force under the SiN film of the detection device provided by the embodiment of the present invention. The SiN film 019 is a tensile stress film, and the detector is wrapped in the SiN film 019. Under the action of the tensile stress film, the two sides of the detector receive tensile stress, and the forbidden band width is reduced.

其中,张应力与禁带宽度的关系如下:Among them, the relationship between tensile stress and forbidden band width is as follows:

Fts=0.6-0.1×EgF ts =0.6-0.1×Eg

其中,Fts为探测器在张应力膜的作用下受到的张应力,Eg为探测器的禁带宽度。Among them, F ts is the tensile stress received by the detector under the action of the tensile stress film, and Eg is the forbidden band width of the detector.

具体地,其他工艺条件不变的情况下,反应温度越高,形成张应力膜使所述探测器结构中产生的张应力越大,且呈一定的线性关系。Specifically, under the condition that other process conditions remain unchanged, the higher the reaction temperature, the greater the tensile stress generated in the detector structure due to the formation of the tensile stress film, and has a certain linear relationship.

其中,设Fts为氮化硅张应力膜使所述探测器结构中产生的张应力大小,则Fts和温度Tts的关系满足:Wherein, let F ts be the tensile stress generated by the silicon nitride tensile stress film in the detector structure, then the relationship between F ts and temperature T ts satisfies:

Fts=1.2×Tts-34.1F ts =1.2×T ts -34.1

其中,Fts的单位为Pa,Tts的单位为摄氏度。Among them, the unit of F ts is Pa, and the unit of T ts is Celsius.

优选地,温度的取值范围为240℃~280℃。Preferably, the temperature ranges from 240°C to 280°C.

具体地,在其他工艺条件不变的情况下,压强越高,氮化硅张应力膜使所述探测器结构中产生的张应力越大。Specifically, under the condition that other process conditions remain unchanged, the higher the pressure, the greater the tensile stress generated in the detector structure by the silicon nitride tensile stress film.

其中,张应力Fts大小和压强Pts的关系满足:Among them, the relationship between the tensile stress F ts and the pressure P ts satisfies:

Fts=0.3×Pts-28.5F ts =0.3×P ts -28.5

其中,Pts的单位为mTorr。Among them, the unit of P ts is mTorr.

优选地,压强的取值为500mTorr。Preferably, the value of the pressure is 500 mTorr.

具体地,功率为射频功率,在其他工艺条件不变的情况下,功率越大,氮化硅张应力膜使所述探测器结构中产生的张应力越大。Specifically, the power is radio frequency power. Under the condition that other process conditions remain unchanged, the greater the power, the greater the tensile stress generated in the detector structure by the silicon nitride tensile stress film.

其中,张应力Fts大小和功率Rts的关系满足:Among them, the relationship between the tensile stress F ts and the power R ts satisfies:

Fts=0.7×Rts-813.4F ts =0.7×R ts -813.4

其中,Rts的单位为W。Among them, the unit of R ts is W.

优选地,功率Rts的大小为200W。Preferably, the magnitude of the power R ts is 200W.

具体地,硅烷(SiH4)和氨气(NH3)的气体流量比为0.75。Specifically, the gas flow ratio of silane (SiH 4 ) and ammonia gas (NH 3 ) was 0.75.

本实施例,通过将压应变材料设置于PMOS表面和所述波导器件表面,张应变材料设置于NMOS表面和所述探测器件表面,通过应变调制波导器件和探测器件的禁带宽度,实现同层单片光电集成,并简化工艺,实现与现有硅基工艺兼容且工艺简单的光电集成电路的制程。In this embodiment, the compressive strain material is arranged on the surface of the PMOS and the surface of the waveguide device, and the tensile strain material is arranged on the surface of the NMOS and the detection device, and the band gap width of the waveguide device and the detection device is modulated by strain to realize the same layer Monolithic optoelectronic integration, simplifying the process, and realizing the manufacturing process of the optoelectronic integrated circuit which is compatible with the existing silicon-based process and has a simple process.

实施例二Embodiment 2

请参见图7a~图7u,图7a~7u为本发明实施例提供的一种光电集成电路的制备方法的工艺示意图。本实施在上述实施例的基础上,对该制备方法进行详细描述。Please refer to FIG. 7a to FIG. 7u. FIGS. 7a to 7u are schematic process diagrams of a method for fabricating an optoelectronic integrated circuit according to an embodiment of the present invention. In this implementation, the preparation method is described in detail on the basis of the above-mentioned embodiment.

S101、如图7a,选取Si衬底001,生长p型Si外延层002,掺杂浓度为1016cm-3量级。S101 , as shown in FIG. 7 a , a Si substrate 001 is selected, and a p-type Si epitaxial layer 002 is grown, and the doping concentration is in the order of 10 16 cm −3 .

S102、如图7b,利用干法刻蚀工艺刻槽,并在低温等离子体增强化学气相淀积(LPCVD)的条件下淀积10~20nm的SiO2层003,沟槽隔离光电集成区域以及CMOS器件区域。S102, as shown in Figure 7b, a dry etching process is used to etch a groove, and a 10-20 nm SiO2 layer 003 is deposited under the condition of low temperature plasma enhanced chemical vapor deposition (LPCVD), and the trench isolates the optoelectronic integration region and the CMOS device area.

S103、如图7c,用光刻胶004层遮挡光电集成区域以及NMOS区域。S103 , as shown in FIG. 7 c , a photoresist 004 layer is used to shield the photoelectric integration region and the NMOS region.

S104、如图7d,低温(200-300℃)下进行P离子注入掺杂形成CMOS中浓度为1016cm-3量级的N阱区005,厚度为400nm。S104 , as shown in FIG. 7d , perform P ion implantation and doping at a low temperature (200-300° C.) to form an N-well region 005 with a concentration of 10 16 cm −3 in CMOS and a thickness of 400 nm.

S105、如图2e,涂覆光刻胶,曝光PMOS源漏区域。S105, as shown in FIG. 2e, coating photoresist, and exposing the source and drain regions of the PMOS.

S106、如图7f,在200-300℃下,两次B离子注入,形成浓度1020cm-3量级的PMOS源漏区006。S106 , as shown in FIG. 7 f , at 200-300° C., B ions are implanted twice to form PMOS source and drain regions 006 with a concentration of 10 20 cm −3 level.

S107、如图7g,曝光NMOS源漏区域,在200~300℃下,两次P离子注入,形成浓度1020cm-3的NMOS源漏区007,然后将注入后的硅片在快速退火(RTP)装置中,对NMOS和PMOS源漏区同时进行高温退火。快速退火装置能够迅速达到1000℃左右的高温并在设定温度保持数秒。这种状态对于阻止结构的扩展以及控制源漏区杂质的扩散都极其重要。S107. As shown in Figure 7g, the NMOS source and drain regions are exposed, and at 200-300 °C, P ions are implanted twice to form NMOS source and drain regions 007 with a concentration of 10 20 cm -3 , and then the implanted silicon wafer is rapidly annealed ( In the RTP) device, high temperature annealing is performed on the NMOS and PMOS source and drain regions at the same time. Rapid annealing equipment can quickly reach a high temperature of around 1000 ° C and maintain the set temperature for several seconds. This state is extremely important for preventing the expansion of the structure and controlling the diffusion of impurities in the source and drain regions.

S108、如图7h,干法刻蚀光电集成区域,留下厚度300nm的p+Si层008。S108, as shown in Figure 7h, dry etching the photoelectric integration region, leaving a p+Si layer 008 with a thickness of 300 nm.

S109、如图7i,330℃下,在Si层008上利用化学气相沉积外延生长厚度为50nm的p++掺杂Ge层009,掺杂浓度为1020cm-3量级;S109, as shown in Figure 7i, at 330°C, a p++ doped Ge layer 009 with a thickness of 50 nm is epitaxially grown on the Si layer 008 by chemical vapor deposition, and the doping concentration is on the order of 10 20 cm -3 ;

S110、如图7j,在350℃温度下,在上述材料表面利用减压CVD工艺生长250nm的本征GeSn合金层010,考虑到实际工艺因素以及Sn在Ge中的固溶度,控制Sn组份为3%~5%。S110, as shown in Figure 7j, at a temperature of 350 °C, a 250 nm intrinsic GeSn alloy layer 010 is grown on the surface of the above-mentioned material by a decompression CVD process. Considering the actual process factors and the solid solubility of Sn in Ge, the composition of Sn is controlled. 3% to 5%.

S111、如图7k,在160℃下在GeSn层上利用化学气相沉积外延生长厚度为100nm的n+掺杂Ge层011,掺杂浓度为3×1019cm-3量级。S111, as shown in Figure 7k, an n+ doped Ge layer 011 with a thickness of 100 nm is epitaxially grown on the GeSn layer at 160°C by chemical vapor deposition, and the doping concentration is on the order of 3×10 19 cm −3 .

S112、如图7l,在275℃~325℃下在外延层上利用化学气相沉积外延生长厚度为100nm的n++掺杂Si层012,掺杂浓度为1020cm-3量级。S112, as shown in FIG. 71, the n++ doped Si layer 012 with a thickness of 100 nm is epitaxially grown on the epitaxial layer by chemical vapor deposition at 275°C to 325°C, and the doping concentration is in the order of 10 20 cm −3 .

S113、如图7m,利用低温等离子体增强化学气相淀积(LPCVD)的方法在表面淀积10nm的SiO2层013。S113 , as shown in FIG. 7m , a 10 nm SiO 2 layer 013 is deposited on the surface by using a low temperature plasma enhanced chemical vapor deposition (LPCVD) method.

S114、如图7n(a)和图7n(b),首先利用干法刻蚀工艺通入HF刻蚀SiO2氧化层和n++掺杂Si层;其次采用1:2.5:10的HF:HNO3:CH3COOH刻蚀n+掺杂Ge层。其中,图7n(a)为截面图,图7n(b)为俯视图。S114, as shown in Figure 7n(a) and Figure 7n(b), first use dry etching process to etch the SiO 2 oxide layer and the n++ doped Si layer; secondly, use 1:2.5:10 HF: HNO3 : CH3COOH etching of n+ doped Ge layer. 7n(a) is a cross-sectional view, and FIG. 7n(b) is a plan view.

S115、如图7o(a)和图7o(b),通入SiH4和O2淀积20nm厚的SiO2隔离层014,然后利用干法刻蚀工艺刻蚀成图中所示,这层SiO2隔离层对有源器件与无源器件进行了隔离,而且起到一定的电隔离作用,防止两端光电器件器件产生寄生效应。其中,图7o(a)为截面图,图7o(b)为俯视图。S115, as shown in Figure 7o(a) and Figure 7o(b), pass SiH 4 and O 2 to deposit a 20nm thick SiO 2 isolation layer 014, and then use a dry etching process to etch to form as shown in the figure, this layer The SiO 2 isolation layer isolates the active device and the passive device, and plays a certain electrical isolation function to prevent the parasitic effect of the optoelectronic devices at both ends. 7o(a) is a cross-sectional view, and FIG. 7o(b) is a top view.

S116、如图7p(a)和图7p(b),在上述波导的基础上添加α-Si覆盖层015,添加覆盖层能够减小耦合损耗,这与光纤与器件耦合的情况基本一致,而且相对侧墙设计更能够减小损耗,因此需要添加覆盖层。其中,图7p(a)为截面图,图7p(b)为俯视图。S116, as shown in Figure 7p(a) and Figure 7p(b), add α-Si cover layer 015 on the basis of the above-mentioned waveguide, adding the cover layer can reduce the coupling loss, which is basically consistent with the coupling between the fiber and the device, and The sidewall design is more able to reduce losses, so a cover layer needs to be added. 7p(a) is a cross-sectional view, and FIG. 7p(b) is a plan view.

S117、如图7q(a)和图7q(b),多晶硅淀积并光刻出栅区016。将硅片转入低压化学气相淀积设备,在温度为575℃~650℃,压强为0.2~1.0Torr的条件下,向该设备的工艺腔中通入纯硅烷或者含量为20%~30%的硅烷和氮气的混合气体,通过硅烷分解,在硅片表面淀积多晶硅栅,淀积的多晶硅栅厚度为50~60nm。其中,图7q(a)为截面图,图7q(b)为俯视图。S117, as shown in FIG. 7q(a) and FIG. 7q(b), polysilicon is deposited and the gate region 016 is photoetched. Transfer the silicon wafer to the low-pressure chemical vapor deposition equipment, under the conditions of temperature of 575℃~650℃ and pressure of 0.2~1.0 Torr, pure silane or the content of 20%~30% is introduced into the process chamber of the equipment The mixed gas of silane and nitrogen is decomposed by silane, and polysilicon gate is deposited on the surface of the silicon wafer, and the thickness of the deposited polysilicon gate is 50-60 nm. 7q(a) is a cross-sectional view, and FIG. 7q(b) is a plan view.

需要说明的是,该S117也可以在S107之后完成,此处不做任何限制。It should be noted that this S117 can also be completed after S107, and no limitation is imposed here.

S118、如图7r(a)和图7r(b),利用电子束蒸发淀积70~80nm厚的铝(Al)017,形成源漏区欧姆接触;利用刻蚀工艺刻选择性蚀掉指定区域的金属Al,形成电极。图7r(a)为截面图,图7r(b)为俯视图。S118, as shown in Figure 7r(a) and Figure 7r(b), use electron beam evaporation to deposit aluminum (Al) 017 with a thickness of 70-80 nm to form ohmic contacts in the source and drain regions; use an etching process to selectively etch away designated areas metal Al to form electrodes. Fig. 7r(a) is a cross-sectional view, and Fig. 7r(b) is a plan view.

S119、如图7s(a)和图7s(b),光波导区、PMOS区淀积压应力SiN膜018,在340℃~360℃温度下,采用等离子体增强型化学汽相淀积(PECVD),工艺条件为500mTorr的压强,施加一个低频功率源,150W的低频功率,反应气体硅烷(SiH4)/氨气(NH3)流量比为2,淀积10~20nm厚的SiN膜018,利用低频功率源引入高能粒子轰击,导致原子/离子结合或重新分布,即使得SiN膜变得具有压缩性,发生伸张/膨胀,从而在SiN膜中产生本征压应力,利用刻蚀工艺刻选择性蚀掉指定区域的SiN膜,氮化硅膜包裹着波导;在其他工艺条件不变的情况下,反应温度越高,形成氮化硅薄膜压应力越大,且呈一定的线性关系。在其他工艺条件不变的情况下,反应压强越高,形成氮化硅薄膜压应力越小。在其他工艺条件不变的情况下,低频功率越大,形成氮化硅薄膜压应力越大。其中,图7s(a)为截面图,图7s(b)为俯视图。S119, as shown in Fig. 7s(a) and Fig. 7s(b), the compressive stress SiN film 018 is deposited in the optical waveguide region and the PMOS region, and the plasma-enhanced chemical vapor deposition (PECVD) is used at a temperature of 340℃~360℃. , the process conditions are 500mTorr pressure, apply a low frequency power source, 150W low frequency power, the reaction gas silane (SiH4)/ammonia (NH3) flow ratio is 2, deposit 10 ~ 20nm thick SiN film 018, use the low frequency power The source introduces high-energy particle bombardment, resulting in atom/ion combination or redistribution, that is, the SiN film becomes compressible and stretched/expanded, thereby generating intrinsic compressive stress in the SiN film, which is selectively etched away by the etching process The SiN film in the designated area and the silicon nitride film wrap the waveguide; under the condition that other process conditions remain unchanged, the higher the reaction temperature is, the greater the compressive stress of the silicon nitride film is formed, and there is a certain linear relationship. Under the condition that other process conditions remain unchanged, the higher the reaction pressure is, the smaller the compressive stress of the silicon nitride film is formed. Under the condition that other process conditions remain unchanged, the greater the low frequency power, the greater the compressive stress of the silicon nitride film formed. Among them, Fig. 7s(a) is a cross-sectional view, and Fig. 7s(b) is a plan view.

S120、如图7t(a)和图7t(b),光探测区、NMOS区淀积张应力SiN膜019,工艺条件为1500mTorr的压强,200W的射频功率,240℃~280℃下,利用等离子体增强型化学汽相淀积(PECVD),反应气体硅烷(SiH4)/氨气(NH3)流量比为0.75;探测器部分包裹一层10~20nm厚的张应力SiN膜019,使该膜具有很好的一致性,利用刻蚀工艺刻选择性蚀掉指定区域的SiN膜,氮化硅膜包裹着探测器部分;在其他工艺条件不变的情况下,反应温度越高,形成氮化硅薄膜张应力越大,且呈一定的线性关系。在其他工艺条件不变的情况下,反应压强越高,形成氮化硅薄膜张应力越大,且呈一定的线性关系。在其他工艺条件不变的情况下,射频功率越大,形成氮化硅薄膜张应力越大。其中,图7t(a)为截面图,图7t(b)为俯视图。S120, as shown in Figure 7t(a) and Figure 7t(b), a tensile stress SiN film 019 is deposited in the photodetection area and the NMOS area, and the process conditions are 1500mTorr pressure, 200W RF power, 240 ℃ ~ 280 ℃, using plasma Volume-enhanced chemical vapor deposition (PECVD), the reaction gas silane (SiH4)/ammonia (NH3) flow ratio is 0.75; the detector part is wrapped with a 10-20nm thick tensile stress SiN film 019, so that the film has Very good consistency, the SiN film in the designated area is selectively etched by the etching process, and the silicon nitride film wraps the detector part; under the condition that other process conditions remain unchanged, the higher the reaction temperature, the formation of silicon nitride The larger the tensile stress of the film, the greater the linear relationship. Under the condition that other process conditions remain unchanged, the higher the reaction pressure is, the greater the tensile stress of the silicon nitride film is formed, and there is a certain linear relationship. Under the condition that other process conditions remain unchanged, the greater the RF power, the greater the tensile stress of the silicon nitride film formed. 7t(a) is a cross-sectional view, and FIG. 7t(b) is a plan view.

S121、如图7u(a)和图7u(b),利用电子束蒸发淀积10~20nm厚的铝(Al)020,形成金属接触;利用刻蚀工艺刻选择性蚀掉指定区域的金属Al,形成电极。其中,图7u(a)为截面图,图7u(b)为俯视图。S121, as shown in Figure 7u(a) and Figure 7u(b), use electron beam evaporation to deposit aluminum (Al) 020 with a thickness of 10-20 nm to form a metal contact; use an etching process to selectively etch away the metal Al in the designated area , forming electrodes. 7u(a) is a cross-sectional view, and FIG. 7u(b) is a top view.

以上内容是结合具体的优选实施方式对本发明所作的进一步详细说明,不能认定本发明的具体实施只局限于这些说明。对于本发明所属技术领域的普通技术人员来说,在不脱离本发明构思的前提下,还可以做出若干简单推演或替换,都应当视为属于本发明的保护范围。The above content is a further detailed description of the present invention in combination with specific preferred embodiments, and it cannot be considered that the specific implementation of the present invention is limited to these descriptions. For those of ordinary skill in the technical field of the present invention, without departing from the concept of the present invention, some simple deductions or substitutions can be made, which should be regarded as belonging to the protection scope of the present invention.

Claims (10)

1.一种光电集成电路,其特征在于,包括光电转换区和半导体器件区;其中,1. An optoelectronic integrated circuit, comprising a photoelectric conversion region and a semiconductor device region; wherein, 所述光电转换区包括发光器件、波导器件及探测器件,所述发光器件、所述波导器件及所述探测器件制备于同一硅基衬底上,且所述发光器件、所述波导器件及所述探测器件依次相连;The photoelectric conversion region includes a light-emitting device, a waveguide device, and a detection device. The light-emitting device, the waveguide device, and the detection device are prepared on the same silicon-based substrate, and the light-emitting device, the waveguide device, and the detection device are fabricated. The detection devices are connected in sequence; 所述半导体器件区包括半导体器件,且所述半导体器件与所述探测器件相连。The semiconductor device region includes a semiconductor device, and the semiconductor device is connected to the detection device. 2.根据权利要求1所述的光电集成电路,其特征在于,所述发光器件为PIN二极管,所述PIN二极管包括第一GeSn合金层、第一Ge层和第一Si层,所述第一GeSn合金层、所述第一Ge层和所述第一Si层依次层叠于所述硅基衬底上。2 . The optoelectronic integrated circuit according to claim 1 , wherein the light-emitting device is a PIN diode, and the PIN diode comprises a first GeSn alloy layer, a first Ge layer and a first Si layer, and the first A GeSn alloy layer, the first Ge layer and the first Si layer are sequentially stacked on the silicon-based substrate. 3.根据权利要求2所述的光电集成电路,其特征在于,所述波导器件包括SiO2层、第二GeSn合金层、Si覆盖层及压应力层;其中,3. The optoelectronic integrated circuit according to claim 2, wherein the waveguide device comprises a SiO2 layer, a second GeSn alloy layer, a Si cover layer and a compressive stress layer; wherein, 所述SiO2层位于所述波导器件的两侧,且与所述发光器件、所述探测器件相连以形成隔离;The SiO 2 layer is located on both sides of the waveguide device, and is connected with the light-emitting device and the detection device to form isolation; 所述第二GeSn合金层、所述Si覆盖层及所述压应力层依次层叠于所述硅基衬底上。The second GeSn alloy layer, the Si cover layer and the compressive stress layer are sequentially stacked on the silicon-based substrate. 4.根据权利要求3所述的光电集成电路,其特征在于,所述压应力层为SiN膜,且厚度为10~20nm。4 . The optoelectronic integrated circuit according to claim 3 , wherein the compressive stress layer is a SiN film and has a thickness of 10-20 nm. 5 . 5.根据权利要求2所述的光电集成电路,其特征在于,所述波导器件为H型结构。5. The optoelectronic integrated circuit according to claim 2, wherein the waveguide device has an H-type structure. 6.根据权利要求1所述的光电集成电路,其特征在于,所述探测器件包括第三GeSn合金层、第二Ge层、第二Si层及张应力层,所述第三GeSn合金层、所述第二Ge层、所述第二Si层和所述张应力层依次层叠于所述硅基衬底上。6 . The optoelectronic integrated circuit according to claim 1 , wherein the detection device comprises a third GeSn alloy layer, a second Ge layer, a second Si layer and a tensile stress layer, the third GeSn alloy layer, The second Ge layer, the second Si layer and the tensile stress layer are sequentially stacked on the silicon-based substrate. 7.根据权利要求6所述的光电集成电路,其特征在于,所述压应力层为SiN膜,且厚度为10~20nm。7 . The optoelectronic integrated circuit according to claim 6 , wherein the compressive stress layer is a SiN film and has a thickness of 10-20 nm. 8 . 8.根据权利要求1所述的光电集成电路,其特征在于,所述半导体器件为CMOS器件。8. The optoelectronic integrated circuit according to claim 1, wherein the semiconductor device is a CMOS device. 9.根据权利要求8所述的光电集成电路,其特征在于,所述CMOS器件的NMOS与所述探测器件相连,且在所述NMOS表面设置有张应力层,所述张应力层厚度为10~20nm。9 . The optoelectronic integrated circuit according to claim 8 , wherein the NMOS of the CMOS device is connected to the detection device, and a tensile stress layer is provided on the surface of the NMOS, and the thickness of the tensile stress layer is 10 . ~20nm. 10.根据权利要求9所述的光电集成电路,其特征在于,所述CMOS器件的PMOS表面设置有压应力层,所述压应力层厚度为10~20nm。10 . The optoelectronic integrated circuit according to claim 9 , wherein a compressive stress layer is provided on the PMOS surface of the CMOS device, and the thickness of the compressive stress layer is 10-20 nm. 11 .
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4425581A1 (en) * 2023-03-02 2024-09-04 AIT Austrian Institute of Technology GmbH Optoelectronic emitting device, receiving device and switching circuit

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4425581A1 (en) * 2023-03-02 2024-09-04 AIT Austrian Institute of Technology GmbH Optoelectronic emitting device, receiving device and switching circuit

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