CN111301048B - Suspended quicksand for decoration - Google Patents
Suspended quicksand for decoration Download PDFInfo
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- CN111301048B CN111301048B CN201911331868.9A CN201911331868A CN111301048B CN 111301048 B CN111301048 B CN 111301048B CN 201911331868 A CN201911331868 A CN 201911331868A CN 111301048 B CN111301048 B CN 111301048B
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- quicksand
- paillette
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C5/00—Processes for producing special ornamental bodies
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Abstract
The invention discloses suspended quicksand for decoration, and relates to the technical field of decorative articles. The invention relates to suspended quicksand for decoration, which comprisesThe quick-acting sand comprises tablets and quick-acting sand oil, wherein the quick-acting sand oil comprises the following raw materials in percentage by mass: 1-5% of BP2400, 5-10% of TDTM, 5-10% of isooctyl palmitate, 70-80% of No. 26 white oil and 5-8% of squalane, wherein the kinematic viscosity of the quicksand oil is 32-35 mm2And s. The invention discloses suspended quicksand for decoration, which is prepared by reasonably proportioning the formula of quicksand oil, and when the quicksand oil is matched with paillettes for use, the paillette moving speed is moderate, so that a better 'quicksand' effect is ensured to a certain extent, and the ornamental effect is better.
Description
Technical Field
The invention relates to the technical field of decorative articles, in particular to suspended quicksand for decoration.
Background
"quicksand", the fashion element of present wide application, in the surface wide application of objects such as eye shadow box, cell-phone shell, for example current publication number is "CN 208461890U", "CN 208337665U" the Chinese utility model patent all discloses a cell-phone shell, also added the quicksand element on the cell-phone shell, the current publication number is "CN 209547327U", "CN 208286606U" the Chinese utility model patent all discloses a cosmetic powder box, all set up airtight cavity on the powder box for holding external quicksand ornaments.
In the prior art, the application of the quicksand is reported more, but the quicksand itself is hardly reported. The flowing sand generally comprises flowing sand oil and bright sheets soaked in the flowing sand in the application process, when a user turns over and moves objects, the bright sheets move in the flowing sand oil to form the effect of the flowing sand, and if the bright sheets move too fast or too slow, the effect of the flowing sand is lost, so that the ornamental value is lost.
When the paillette moves in the quicksand oil, the paillette is subjected to the combined action of gravity and buoyancy, so that the problem that the paillette moves too fast or too slow is solved, the quicksand oil needs to be reasonably blended, the flowability and viscosity of the quicksand oil need to be in proper ranges, when the quicksand oil and the paillette are matched, a good ornamental effect can be achieved, and the report of the formula of the quicksand oil is not found in the prior art.
Disclosure of Invention
Aiming at the problems, the invention aims to disclose a suspended quicksand for decoration, which is prepared by reasonably proportioning the formula of the quicksand oil, so that the quicksand oil with proper viscosity is obtained, and when the quicksand oil is matched with paillettes for use, the paillette moving speed is moderate, so that a better 'quicksand' effect is ensured to a certain extent, and the ornamental effect is better.
Specifically, the suspended quicksand for decoration comprises bright pieces and quicksand oil, wherein the quicksand oil comprises the following raw materials in percentage by mass: 1-5% of BP2400, 5-10% of TDTM, 5-10% of isooctyl palmitate, 70-80% of No. 26 white oil and 5-8% of squalane.
Further, the kinematic viscosity of the quicksand oil is 32-35 mm2/s。
After the inventor researches the formula of the quicksand oil, the inventor discovers that under the raw material formula of the invention, the quicksand oil has moderate viscosity, is matched with paillettes for use, has moderate moving speed, and can react to external changes in time, so that the quicksand effect is good.
Further, the paillette is made of one or more of PET, OPP, aluminum and laser materials.
Further, the maximum length size of the paillette is 0.1-3 mm.
Further, the paillette comprises a small paillette, a middle paillette and a large paillette, wherein the maximum length of the small paillette is 0.1-0.5mm, the maximum length of the middle paillette is 0.5-1.5mm, and the maximum length of the large paillette is 1.5-3 mm.
Further, the mass ratio of the small paillette to the middle paillette to the large paillette is 2:2: 1.
Through configuring little spangles, well spangles and big spangles, can embody the stereovision for whole looks abundanter, the sight is more strong, and when flowing, because there is different velocities of motion between the spangles of equidimension not, more can embody this sight and admire effect of "quicksand".
21, the surface of the small paillette is coated with a transparent protective layer, and the transparent protective layer comprises the following raw materials in parts by weight: 25-40 parts of polycarbonate, 10-15 parts of polyurethane, 1-3 parts of compatilizer, 0.5-1 part of stabilizer and 0.2-0.8 part of methyl cellulose.
Further, the compatilizer is styrene maleic anhydride copolymer.
In the prior art, the bright sheet preparation step comprises the processes of vacuum plating, high-temperature coating and printing, material striping, powder cutting, powder sieving and removing and the like.
Further, the coating method of the transparent protective layer comprises the following steps: adding 25-40 parts of polycarbonate and 10-15 parts of polyurethane into a stirring kettle, heating the stirring kettle to 85 ℃, stirring until the polycarbonate and the polyurethane are uniformly mixed, heating to 145 ℃, adding 1-3 parts of compatilizer, 0.5-1 part of stabilizer and 0.2-0.8 part of methyl cellulose, continuously stirring and uniformly mixing, keeping the temperature and standing for 2 hours, coating while hot, finishing coating, and cooling to room temperature to perform the next step.
The transparent protective layer is coated on the surface of the small paillette, on one hand, the transparent protective layer does not influence the ornamental effect of the small paillette, on the other hand, the transparent protective layer protects the small paillette and separates the small paillette from the small paillette, so that the attraction between the small paillettes is reduced, the agglomeration between the small paillettes is reduced to a certain degree, the small paillettes are better dispersed in the quicksand oil, and the quicksand effect is ensured.
Further, the stabilizer is prepared by wrapping anatase type nano titanium dioxide by rodlike ordered mesoporous nano silicon dioxide, loading an ultraviolet absorbent and then modifying by gamma-methacryloxypropyltrimethoxysilane.
The nano titanium dioxide has good ultraviolet absorption function, and can improve the ultraviolet resistance of the transparent protective film when being added into the transparent protective film, but the nano titanium dioxide is easy to pulverize, so that the nano titanium dioxide is wrapped with the nano silicon dioxide layer, on one hand, the agglomeration of the nano titanium dioxide can be reduced, the nano titanium dioxide can be better dispersed in the matrix of the transparent protective film, on the other hand, the nano silicon dioxide layer can improve the pulverization resistance of the nano titanium dioxide, but the ultraviolet absorption capability of the nano titanium dioxide is reduced after the nano silicon dioxide layer is wrapped, therefore, the nano silicon dioxide layer adopts the rod-shaped ordered mesoporous nano silicon dioxide, the ultraviolet absorbent is loaded by utilizing the ordered mesopores of the nano silicon dioxide, the ultraviolet absorption capability of the nano titanium dioxide is reduced, and meanwhile, the rod-shaped structure is adopted, the structure of the rod-shaped combined ordered mesopore has larger specific surface area, and can increase the specific surface area of the nano silicon dioxide layer to a certain extent, so that the nano silicon dioxide layer can load more ultraviolet absorbers, and in addition, because the surfaces of the nano silicon dioxide and the nano titanium dioxide both contain a large amount of oxygen-containing groups, the gamma-methacryloxypropyl trimethoxy silane is used for modifying the nano silicon dioxide layer, the oleophylic property of the stabilizer is increased, so that the nano silicon dioxide layer can be better fused with a matrix of a transparent protective film in the using process, and can be better dispersed in the matrix of the transparent protective film.
Further, the ultraviolet absorbent is 2- (2 ' -hydroxy-3 ', 5 ' -di-tert-phenyl) -5-chlorobenzotriazole chloride.
Further, the preparation method of the stabilizer comprises the following steps: weighing hexadecyl methyl ammonium bromide, stirring and dissolving the hexadecyl methyl ammonium bromide in 25 times of hexadecyl methyl ammonium bromide deionized water, then adding absolute ethyl alcohol, uniformly stirring, adding nano titanium dioxide according to a solid-to-liquid ratio of 15g/ml, ultrasonically dispersing, then dropwise adding tetraethoxysilane at a speed of 15d/min, stirring for 2 hours after dropwise adding is completed, transferring reaction liquid into a reaction kettle for sealing, continuously and slowly stirring, preserving heat and aging for 2 days at 70 ℃, taking out the reaction liquid after reaction is completed, filtering, washing with deionized water, drying the solid at 100 ℃, placing the solid in a muffle furnace, increasing the temperature to 550 ℃ at a speed of 2 ℃/mi, preserving heat and calcining for 5 hours, cooling along with the furnace to obtain TiO2/SiO2Particles, wherein the molar mass ratio of hexadecyl methyl ammonium bromide to absolute ethyl alcohol to ethyl orthosilicate is 0.1:15: 1; dissolving 2- (2 ' -hydroxy-3 ', 5 ' -di-tert-phenyl) -5-chlorobenzotriazole chloride in toluene solution under stirring, and adding the prepared TiO according to the solid-to-liquid ratio of 20g/ml2/SiO2Treating the particles under the ultrasonic condition of 25KHz and 125W for 5 hours to enable TiO to be formed on one hand2/SiO2The particles are dispersed in the solution, and on the other hand, the ultrasonic can accelerate the SiO2Allowing air in the holes to escape to promote liquid to fill the holes, adding gamma-methacryloxypropyl trimethoxysilane, continuing to ultrasonically mix for 5min, heating to 75 ℃, keeping the temperature, reacting for 6h to make the gamma-methacryloxypropyl trimethoxysilane graft and coat on the TiO2/SiO2Filtering the particles after the reaction is finished, drying the solid by hot air at 40 ℃ to separate out the 2- (2 ' -hydroxy-3 ', 5 ' -di-tert-phenyl) -5-chlorinated benzotriazole loaded on the TiO2/SiO2And obtaining the stabilizing agent in the pores of the particles.
The invention has the beneficial effects that:
1. the invention discloses suspended quicksand for decoration, which is prepared by reasonably proportioning the formula of quicksand oil, and when the quicksand oil is matched with paillettes for use, the paillette moving speed is moderate, so that a better 'quicksand' effect is ensured to a certain extent, and the ornamental effect is better.
2. The surface of the small paillette is coated with the transparent protective layer, the small paillette is protected by the transparent protective layer, the small paillette and the small paillette are separated, agglomeration among the small paillettes is reduced to a certain degree, the small paillette is better dispersed in the quicksand oil, meanwhile, the transparent protective layer also plays a role in protecting the small paillette, and the small paillette can be prevented from being aged, decolored or damaged by heating, light, collision and the like, so that the service life of the quicksand is prolonged to a certain degree.
Detailed Description
The present invention will be described in detail with reference to specific examples below:
the suspended quicksand paillette and quicksand oil for decoration are provided by the invention, wherein the kinematic viscosity of the quicksand oil is 32-35 mm2The paillette comprises a small paillette, a middle paillette and a large paillette, the mass ratio of the small paillette to the middle paillette to the large paillette is 2:2:1, the maximum length of the small paillette is 0.1-0.5mm, the maximum length of the middle paillette is 0.5-1.5mm, the maximum length of the large paillette is 1.5-3mm, the surface of the small paillette is coated with a transparent protective layer, and the transparent coating layer is made of polycarbonate, polyurethane, a compatilizer and a stabilizerThe stabilizer is prepared by coating anatase type nano titanium dioxide by rodlike ordered mesoporous nano silicon dioxide, loading an ultraviolet absorbent and then modifying by gamma-methacryloxypropyl trimethoxy silane. The preparation method of the specific stabilizer comprises the following steps:
weighing hexadecyl methyl ammonium bromide, stirring and dissolving the hexadecyl methyl ammonium bromide in 25 times of hexadecyl methyl ammonium bromide deionized water, then adding absolute ethyl alcohol, uniformly stirring, adding nano titanium dioxide according to a solid-to-liquid ratio of 15g/ml, ultrasonically dispersing, then dropwise adding tetraethoxysilane at a speed of 15d/min, stirring for 2 hours after dropwise adding is completed, transferring reaction liquid into a reaction kettle for sealing, continuously and slowly stirring, preserving heat and aging for 2 days at 70 ℃, taking out the reaction liquid after reaction is completed, filtering, washing with deionized water, drying the solid at 100 ℃, placing the solid in a muffle furnace, increasing the temperature to 550 ℃ at a speed of 2 ℃/mi, preserving heat and calcining for 5 hours, cooling along with the furnace to obtain TiO2/SiO2Particles, wherein the molar mass ratio of hexadecyl methyl ammonium bromide to absolute ethyl alcohol to ethyl orthosilicate is 0.1:15: 1; dissolving 2- (2 ' -hydroxy-3 ', 5 ' -di-tert-phenyl) -5-chlorobenzotriazole chloride in toluene solution under stirring, and adding the prepared TiO according to the solid-to-liquid ratio of 20g/ml2/SiO2Treating the particles under the ultrasonic condition of 25KHz and 125W for 5 hours to enable TiO to be formed on one hand2/SiO2The particles are dispersed in the solution, and on the other hand, the ultrasonic can accelerate the SiO2Allowing air in the holes to escape to promote liquid to fill the holes, adding gamma-methacryloxypropyl trimethoxysilane, continuing to ultrasonically mix for 5min, heating to 75 ℃, keeping the temperature, reacting for 6h to make the gamma-methacryloxypropyl trimethoxysilane graft and coat on the TiO2/SiO2Filtering the particles after the reaction is finished, drying the solid by hot air at 40 ℃ to separate out the 2- (2 ' -hydroxy-3 ', 5 ' -di-tert-phenyl) -5-chlorinated benzotriazole loaded on the TiO2/SiO2And obtaining the stabilizing agent in the pores of the particles.
The stabilizer prepared by the invention is used in the transparent protective film of the small paillette, and in the preparation process of the small paillette, after the high-temperature coating and printing step and before the material striping step, the stabilizer is coated, and the specific operation steps are as follows:
adding 25-40 parts of polycarbonate, 10-15 parts of polyurethane, preferably 30 parts of polycarbonate and 12 parts of polyurethane into a stirring kettle, heating the stirring kettle to 85 ℃, stirring until the polycarbonate and the polyurethane are uniformly mixed, heating to 145 ℃, adding 1-3 parts of, preferably 2 parts of styrene maleic anhydride copolymer, 0.5-1 part of, preferably 0.8 part of stabilizer and 0.2-0.8 part of, preferably 0.6 part of methyl cellulose, continuously stirring and uniformly mixing, keeping the temperature and standing for 2 hours, coating while hot, finishing coating, and cooling to room temperature to perform the next step.
The quicksand oil and the sequins are placed in the closed cavity to form decorative quicksand, and the method comprises the following steps:
example one
The quicksand oil in the embodiment comprises the following raw materials in percentage by mass: 1% BP2400, 10% TDTM, 8% isooctyl palmitate, 75% No. 26 white oil, 6% squalane.
The raw materials are respectively weighed according to the formula and poured into a batching pot, stirred and mixed uniformly at the speed of 500rpm, and then placed into a centrifugal defoaming machine for centrifugal defoaming for 10min at the speed of 500rpm, so as to obtain the quicksand oil. The kinematic viscosity of the quicksand oil is 35mm by detection2/s。
The small paillette, the middle paillette and the large paillette in the embodiment are all made of PET materials, and the surface of the small paillette is coated with a transparent protective film, wherein the small paillette and the middle paillette are mainly selected from circles, and the large paillette is selected from a pentagram, an apple shape and a heart shape.
Respectively placing 1g of small paillette, 1g of middle paillette and 0.5g of large paillette in a first cavity of the eye shadow box with the publication number of CN209547327U, then injecting full quicksand oil into the first cavity through a through hole on the top box and the bottom box, and then plugging the through hole by a rubber plug to obtain the eye shadow box with quicksand decoration.
Similarly, the same method can be adopted on other objects to obtain the object with the quicksand decoration.
Example two
The quicksand oil in the embodiment comprises the following raw materials in percentage by mass: 4% BP2400, 8% TDTM, 10% isooctyl palmitate, 70% No. 26 white oil, 8% squalane.
The raw materials are respectively weighed according to the formula and poured into a batching pot, stirred and mixed uniformly at the speed of 500rpm, and then placed into a centrifugal defoaming machine for centrifugal defoaming for 10min at the speed of 500rpm, so as to obtain the quicksand oil. The kinematic viscosity of the quicksand oil is 33mm through detection2/s。
The small paillette, the middle paillette and the large paillette in the embodiment are all made of PET materials, and the surface of the small paillette is not coated with a transparent protective film, wherein the small paillette and the middle paillette are mainly selected from circles, and the large paillette is selected from a pentagram, an apple shape and a heart shape.
And respectively placing 1g of small paillette, 1g of middle paillette and 0.5g of large paillette in a first cavity of the eye shadow box with the publication number of CN209547327U, filling quicksand oil into the first cavity through a through hole on the top and bottom box, and plugging the through hole by using a rubber plug to obtain the eye shadow box with quicksand decoration.
EXAMPLE III
The quicksand oil in the embodiment comprises the following raw materials in percentage by mass: 5% BP2400, 5% TDTM, 5% isooctyl palmitate, 80% No. 26 white oil, 5% squalane.
The raw materials are respectively weighed according to the formula and poured into a batching pot, stirred and mixed uniformly at the speed of 500rpm, and then placed into a centrifugal defoaming machine for centrifugal defoaming for 10min at the speed of 500rpm, so as to obtain the quicksand oil. The kinematic viscosity of the quicksand oil is 32mm through detection2/s。
In this embodiment, the small paillette is made of aluminum, the middle paillette is made of OPP, the large paillette is made of laser, and the surface of the small paillette is coated with a transparent protective film, wherein the small paillette and the middle paillette are mainly selected from circles, and the large paillette is selected from a pentagram, an apple shape and a heart shape.
And respectively placing 1g of small paillette, 1g of middle paillette and 0.5g of large paillette in a first cavity of the eye shadow box with the publication number of CN209547327U, filling quicksand oil into the first cavity through a through hole on the top and bottom box, and plugging the through hole by using a rubber plug to obtain the eye shadow box with quicksand decoration.
The quicksand on the eye shadow boxes prepared in the first, second and third examples and the quicksand on the existing eye shadow boxes were subjected to performance tests, and the test results are as follows:
according to the comparison, the quicksand oil disclosed by the invention is moderate in viscosity, can better reflect the quicksand effect, and is better dispersed among the small paillettes through the arrangement of the transparent protective layer, so that the quicksand effect is ensured to a certain extent, and the transparent protective layer can play a role in protecting the small paillettes to a certain extent, so that the service life of the quicksand oil is prolonged.
Although the present invention has been described in detail with reference to the preferred embodiments, it will be understood by those skilled in the art that various changes may be made and equivalents may be substituted without departing from the spirit and scope of the invention as defined in the appended claims. The techniques, shapes, and configurations not described in detail in the present invention are all known techniques.
Claims (7)
1. The suspended quicksand for decoration comprises bright pieces and quicksand oil, and is characterized in that the quicksand oil comprises the following raw materials in percentage by mass: 1-5% of BP2400, 5-10% of TDTM, 5-10% of isooctyl palmitate, 70-80% of No. 26 white oil and 5-8% of squalane;
the paillette comprises a small paillette, a middle paillette and a large paillette, wherein the maximum length of the small paillette is 0.1-0.5mm, the maximum length of the middle paillette is 0.5-1.5mm, the maximum length of the large paillette is 1.5-3mm, the surface of the small paillette is coated with a transparent protective layer, and the transparent protective layer comprises the following raw materials in parts by weight: 25 to 40 portions of polycarbonate, 10 to 15 portions of polyurethane, 1 to 3 portions of compatilizer, 0.5 to 1 portion of stabilizer, 0.2 to 0.8 portion of methyl cellulose,
the stabilizer is prepared by coating anatase type nano titanium dioxide by rodlike ordered mesoporous nano silicon dioxide, loading an ultraviolet absorbent and then modifying by gamma-methacryloxypropyltrimethoxysilane.
2. The suspended quicksand for decoration as claimed in claim 1, wherein the kinematic viscosity of the quicksand oil is 32-35 mm2/s。
3. The suspended quicksand for decoration as claimed in claim 1, wherein the spangle is made of one or more of PET, OPP, aluminum and laser materials.
4. A decorative floating quicksand as claimed in claim 3, wherein said spangles have a maximum length dimension of 0.1-3 mm.
5. The suspended quicksand for decoration as claimed in claim 4, wherein the mass ratio of the small paillette, the middle paillette and the large paillette is 2:2: 1.
6. A decorative suspended quicksand as claimed in claim 5, wherein said compatibilizer is a styrene maleic anhydride copolymer.
7. The decorative suspended quicksand as claimed in claim 6, wherein said ultraviolet absorber is 2- (2 ' -hydroxy-3 ', 5 ' -di-tert-phenyl) -5-chlorobenzotriazole.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911331868.9A CN111301048B (en) | 2019-12-21 | 2019-12-21 | Suspended quicksand for decoration |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911331868.9A CN111301048B (en) | 2019-12-21 | 2019-12-21 | Suspended quicksand for decoration |
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| Publication Number | Publication Date |
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| CN111301048A CN111301048A (en) | 2020-06-19 |
| CN111301048B true CN111301048B (en) | 2022-03-22 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201911331868.9A Active CN111301048B (en) | 2019-12-21 | 2019-12-21 | Suspended quicksand for decoration |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2683223Y (en) * | 2003-11-04 | 2005-03-09 | 林嘉彦 | Elastic ball |
| CN101972214A (en) * | 2010-09-28 | 2011-02-16 | 浙江美雪化妆品有限公司 | Lip gloss |
| CN204820557U (en) * | 2015-08-06 | 2015-12-02 | 绍兴县鼎合薄膜有限公司 | Spangle |
| CN207207579U (en) * | 2017-08-22 | 2018-04-10 | 广州宏信塑胶工业有限公司 | Decoration electroplates paillette with PVC |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR910009597B1 (en) * | 1988-11-23 | 1991-11-23 | 육근묵 | Sand picture and making method there of |
-
2019
- 2019-12-21 CN CN201911331868.9A patent/CN111301048B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2683223Y (en) * | 2003-11-04 | 2005-03-09 | 林嘉彦 | Elastic ball |
| CN101972214A (en) * | 2010-09-28 | 2011-02-16 | 浙江美雪化妆品有限公司 | Lip gloss |
| CN204820557U (en) * | 2015-08-06 | 2015-12-02 | 绍兴县鼎合薄膜有限公司 | Spangle |
| CN207207579U (en) * | 2017-08-22 | 2018-04-10 | 广州宏信塑胶工业有限公司 | Decoration electroplates paillette with PVC |
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| CN111301048A (en) | 2020-06-19 |
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