CN111286747A - Built-in ultrasonic electrolysis system oxyhydrogen device - Google Patents
Built-in ultrasonic electrolysis system oxyhydrogen device Download PDFInfo
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- CN111286747A CN111286747A CN201811505416.3A CN201811505416A CN111286747A CN 111286747 A CN111286747 A CN 111286747A CN 201811505416 A CN201811505416 A CN 201811505416A CN 111286747 A CN111286747 A CN 111286747A
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/70—Assemblies comprising two or more cells
- C25B9/73—Assemblies comprising two or more cells of the filter-press type
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
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- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
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- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
The invention relates to an electrolytic hydrogen and oxygen production device with built-in ultrasonic waves, which comprises a shell, a diaphragm, an anode plate, a cathode plate, a hydrogen outlet and an oxygen outlet, wherein ultrasonic transducer modules are respectively wrapped around the anode plate and the cathode plate in the shell, and empty gaps are respectively formed between the inner side of each ultrasonic transducer module and the surface of the anode plate and between the inner side of each ultrasonic transducer module and the surface of the cathode plate; the ultrasonic transducer module is composed of a sealed and wrapped shell and a plurality of ultrasonic transducers arranged in the sealed and wrapped shell. When the ultrasonic transducer module works, the ultrasonic cavitation effect is continuously generated on the electrolyte to wash the surfaces of the anode plate and the cathode plate, so that the anode plate and the cathode plate are not shielded and eroded by any impurity, the new conductivity is always kept for a long time, the service lives of the anode plate and the cathode plate are greatly prolonged, and the electrolysis quality and the quality of preparing hydrogen and oxygen are effectively ensured.
Description
Technical Field
The invention relates to the technical field of hydrogen and oxygen production devices, in particular to an electrolytic hydrogen and oxygen production device.
Background
The electrolytic hydrogen and oxygen producing device is one of the important means for obtaining hydrogen and oxygen at present, the electrolyte added into an electrolytic tank or an electrolytic chamber of the electrolytic hydrogen and oxygen producing device is decomposed into hydrogen and oxygen under the action of direct current, and the hydrogen and the oxygen are respectively treated by a storage device and then are respectively and correspondingly filled into a hydrogen storage tank and an oxygen storage tank for storage. However, in the process of producing hydrogen and oxygen by electrolysis, the anode plate and the cathode plate in the electrolytic cell are soaked in the electrolyte for a long time and participate in chemical reaction, and impurities are generated in the process of adhering the upper layer of chemical reaction on the surfaces of the anode plate and the cathode plate, so that the conductivity of the anode plate and the cathode plate is continuously reduced along with the continuous thickening of the layer of impurities, and the electrolysis quality and the hydrogen and oxygen production quantity are influenced. Therefore, the applicant believes that in order to overcome this disadvantage and to extend the service life of the anode and cathode plates, it is necessary to improve the structural scheme of the electrolytic oxyhydrogen production device so that it can better serve the production needs of people.
Disclosure of Invention
The invention aims to solve the problems and the defects and provides an electrolytic hydrogen and oxygen production device with built-in ultrasonic waves, wherein a set of ultrasonic transducer modules are respectively wrapped on the outer side surfaces of an anode plate and a cathode plate in a surrounding manner, and the wrapping structure design of the ultrasonic transducer modules does not shield or obstruct the anode plate, the cathode plate and the electrolyte from fully contacting and does not influence the electric contact reaction among the anode plate, the cathode plate and the electrolyte; when the ultrasonic transducer module works, the ultrasonic cavitation effect is continuously generated on the electrolyte to wash the surfaces of the anode plate and the cathode plate, so that the anode plate and the cathode plate are not shielded and eroded by any impurity, and the new conductivity is always kept for a long time, the service lives of the anode plate and the cathode plate are greatly prolonged, and the electrolysis quality and the quality of preparing hydrogen and oxygen are effectively ensured; and under the ultrasonic high-frequency vibration of the ultrasonic transducer module, the electric conduction effect of the electrolyte, the anode plate and the cathode plate is greatly accelerated, the speed of chemical reaction is increased, and the efficiency of preparing hydrogen and oxygen by electrolysis is improved.
The technical scheme of the invention is realized as follows: an electrolytic hydrogen and oxygen production device with built-in ultrasonic waves comprises a shell, a diaphragm, an anode plate, a cathode plate, a hydrogen outlet and an oxygen outlet, wherein the diaphragm, the anode plate and the cathode plate are respectively arranged in an inner cavity of the shell, and the hydrogen outlet and the oxygen outlet are respectively arranged on the shell; the ultrasonic transducer module is composed of a sealed coating shell and a plurality of ultrasonic transducers arranged in the sealed coating shell, each ultrasonic transducer is connected with an electric wire, the electric wire penetrates out of one end of the ultrasonic transducer module to form an electric connecting end, and the electric connecting end penetrates out of the top surface of the shell.
Further, the structure of the specific embodiment of the ultrasonic transducer module has various realizable forms: for example, the sealed enclosure may be a sheet enclosure formed by bending a metal sheet and then processing the metal sheet by a welding process, and the ultrasonic transducers are uniformly arranged in the sheet enclosure, so as to construct a sheet ultrasonic transducer module; and a through hole transversely penetrating through the sheet-shaped coating shell is also formed in the position of a gap formed between the ultrasonic transducer and the sheet-shaped coating shell. Or the sealed coating shell is a strip-shaped coating shell formed by bending and molding a strip-shaped metal sheet and then processing the strip-shaped metal sheet by adopting a welding process, and the ultrasonic transducers are arranged in the strip-shaped coating shell along the length direction of the strip-shaped coating shell so as to construct a strip-shaped ultrasonic transducer module; the strip-shaped ultrasonic transducer modules are respectively wrapped on the anode plate and the cathode plate in the shell, and transverse gap seams are formed between the strip-shaped ultrasonic transducer modules and the strip-shaped ultrasonic transducer modules. The sealed cladding shell is a square flat tube with a rectangular cross section, two ends of the square flat tube are provided with sealed end covers, each ultrasonic transducer is fixedly connected through a metal strip to form an ultrasonic transducer strip, the ultrasonic transducer strip is sleeved in the square flat tube in a penetrating manner, and two ends of the ultrasonic transducer strip are respectively provided with a bolt rod with a hollow structure and a nut screwed on the bolt rod; the bolt rod penetrates through a through hole formed in the sealing end cover, and the bolt rod is screwed tightly through a nut to fix the ultrasonic transducer strip in the square flat tube; and the ultrasonic transducers are connected with electric wires and then penetrate out of the bolt rods of the hollow structures to form the electric connection ends of the ultrasonic transducer modules.
The invention has the beneficial effects that: the invention adopts the structure that the outer side surfaces of the anode plate and the cathode plate are respectively wrapped with a set of ultrasonic transducer modules in a surrounding way, and the wrapping structure design of the ultrasonic transducer modules is designed to not shield or obstruct the anode plate, the cathode plate and the electrolyte from fully contacting, and not to influence the electric contact reaction between the anode plate, the cathode plate and the electrolyte. When the ultrasonic transducer module works, the ultrasonic cavitation effect is continuously generated on the electrolyte to wash the surfaces of the anode plate and the cathode plate, so that the anode plate and the cathode plate are not shielded and eroded by any impurity, and the new conductivity is always kept for a long time, the service lives of the anode plate and the cathode plate are greatly prolonged, and the electrolysis quality and the quality of preparing hydrogen and oxygen are effectively ensured; and under the ultrasonic high-frequency vibration of the ultrasonic transducer module, the electric conduction effect of the electrolyte, the anode plate and the cathode plate is greatly accelerated, the speed of chemical reaction is increased, and the efficiency of preparing hydrogen and oxygen by electrolysis is improved. Meanwhile, under the action of the ultrasonic cavitation effect of the ultrasonic transducer module, the side wall of the electrolytic cell or the electrolytic chamber in the shell is also cleaned completely without any impurity adhesion, so that the volume of the electrolytic cell or the electrolytic chamber is greatly ensured not to be occupied by impurities, and the quality of hydrogen and oxygen production is ensured for a long time. The scheme structure of the invention has simple structural design and easy realization, does not need to greatly change the principle structure of the electrolytic hydrogen and oxygen production device, and can be widely popularized and applied to electrolytic hydrogen and oxygen production devices with various specifications and models.
Drawings
Fig. 1 is a schematic top view of the present invention.
Fig. 2 is a schematic cross-sectional view taken along the direction a-a in fig. 1 according to the present invention.
Fig. 3 is a schematic cross-sectional structural diagram of an ultrasonic transducer module according to an embodiment of the present invention.
Fig. 4 is a schematic cross-sectional view of an ultrasonic transducer module according to an embodiment of the present invention.
Fig. 5 is a schematic side view of an ultrasonic transducer module according to a second embodiment of the present invention in an unfolded state.
Fig. 6 is a schematic cross-sectional view of the embodiment of fig. 5 bent into a U-shape according to the present invention.
Detailed Description
As shown in figures 1 and 2, the electrolysis oxyhydrogen making device with built-in ultrasonic waves comprises a shell 1, a diaphragm 2, an anode plate 3 and a cathode plate 4 which are respectively arranged in the inner cavity of the shell 1, and a hydrogen outlet 5 and an oxygen outlet 6 which are respectively arranged on the shell 1, in order to realize the proposed purpose of the invention, the shell 1 is respectively wrapped with ultrasonic transducer modules 7 at the peripheries of the anode plate 5 and the cathode plate 6, a gap 8 is formed between the inner side of the ultrasonic transducer module 7 and the surface of the anode plate 5 and between the inner side of the ultrasonic transducer module 7 and the surface of the cathode plate 6, so that the coating of the ultrasonic transducer module 7 does not form shielding or obstruction to the full contact of the anode plate 3 and the cathode plate 4 with the electrolyte, and does not influence the contact reaction between the anode plate 3 and the electrolyte and between the cathode plate 4 and the electrolyte.
As shown in fig. 3, the ultrasonic transducer module 7 is composed of a sealed and covered housing 71 and a plurality of ultrasonic transducers 72 arranged in the sealed and covered housing 71, each ultrasonic transducer 72 is connected with an electric wire 75, the electric wire 75 penetrates out from one end of the ultrasonic transducer module 7 to form an electric connection end 73, and the electric connection end 73 is arranged to penetrate out of the top surface of the housing 1. The seal-clad housing 71 is typically formed from a corrosion resistant material, such as type 304 or type 316 stainless steel. The ultrasonic transducer 72 is a patch-type ultrasonic transducer or a button cell-shaped ultrasonic transducer. Each ultrasonic transducer 72 is implemented to operate in conjunction with an ultrasonic generator or ultrasonic generating circuit.
In order to make the solution of the present invention, when implemented, able to provide a plurality of different configurations of the ultrasonic transducer module 7 to meet the requirements of different applications of the electrolytic hydrogen and oxygen production device, the ultrasonic transducer module 7 may be such that: as shown in fig. 5, the sealed and covered housing 71 is a sheet-shaped covered housing formed by bending a metal sheet and then processing the metal sheet by a welding process, and the ultrasonic transducers 72 are uniformly arranged in the sheet-shaped covered housing, so as to construct a sheet-shaped ultrasonic transducer module; a through hole 74 transversely penetrating the sheet-like cover is also provided at a position of a gap formed between the ultrasonic transducer 72 and the ultrasonic transducer 72. When in use, the ultrasonic transducer module of the scheme is bent into the shape shown in fig. 6 and then installed in the shell 1 like the scheme shown in fig. 2.
Alternatively, the ultrasonic transducer module 7 may be such that: the sealed cladding shell 71 is a strip cladding shell formed by bending and molding a strip metal sheet and then processing the metal sheet by adopting a welding process, and each ultrasonic transducer 42 is arranged in the strip cladding shell along the length direction of the strip cladding shell so as to construct a strip ultrasonic transducer module; a plurality of strip-shaped ultrasonic transducer modules are respectively wrapped on the anode plate 5 and the cathode plate 6 in the shell 1, and a transverse gap is formed between each strip-shaped ultrasonic transducer module and each strip-shaped ultrasonic transducer module, so that the electrolyte can be conveniently communicated without being shielded.
Still alternatively, the ultrasonic transducer module 7 may be: as shown in fig. 3 and 4, the hermetically-sealed housing 71 is a square flat tube with a rectangular cross section, two ends of the square flat tube are further provided with a hermetically-sealed end cap 76, each ultrasonic transducer 72 is fixedly connected by a metal strip to form an ultrasonic transducer strip 77, the ultrasonic transducer strip 77 is inserted into the square flat tube, and two ends of the ultrasonic transducer strip 77 are further provided with a hollow bolt rod 78 and a nut 79 screwed on the bolt rod 78. The bolt rod 78 passes through a through hole formed in the end cap 76, and is screwed on the bolt rod 78 through a nut 79 to fix the ultrasonic transducer strip 77 in the square flat tube. After the ultrasonic transducers 72 are connected with the electric wires 75, the electric wires are penetrated out from the bolt rods 78 of the hollow structure to form the electric connection ends 73 of the ultrasonic transducer module 7. Similarly, when the ultrasonic transducer module 7 with the structure is arranged and applied, a gap is reserved between the ultrasonic transducer module 7 and the ultrasonic transducer module 7, so that the electrolyte can be conveniently communicated without shielding.
In order to further improve the corrosion resistance of the seal-coating housing 71 itself, as shown in the upper right corner of fig. 3, the outer surface of the seal-coating housing 71 is covered with a protective layer 70 made of a corrosion-resistant material.
In order to add electrolyte to the electrolysis chamber of the housing 1, as shown in fig. 2, the housing 1 is further provided with a filling opening 10 with a cap 101.
In order to facilitate people to clean the residues in the housing 1 regularly, which are shaken off by the ultrasonic transducer, as shown in fig. 1 and 2, the housing 1 is further provided with a liquid pumping pump mechanism 9, the liquid pumping pump mechanism 9 is composed of a liquid pumping pump 91, an electromagnetic switch valve 92 and a pipeline 93, one end of the pipeline 93 extends into the bottom of the inner cavity of the housing 1, the other end of the pipeline 93 is connected with the liquid pumping pump 91, and the electromagnetic switch valve 92 is connected in series between the pipeline 93 and the liquid pumping pump 91. Like this, make people can utilize pipeline 93 and drawing liquid pump 91 to go on draining residue, waste liquid through opening electromagnetic switch valve 92, greatly promoted convenience and the high efficiency of maintaining.
Claims (7)
1. The utility model provides a built-in ultrasonic electrolytic hydrogen oxygen production device, includes casing (1), and sets up diaphragm (2), anode plate (3), negative plate board (4) in casing (1) inner chamber respectively to and set up hydrogen export (5) and oxygen export (6) on casing (1) respectively, its characterized in that: the shell (1) is positioned on the periphery of the anode plate (5) and the periphery of the cathode plate (6) and is respectively wrapped with an ultrasonic transducer module (7), and empty gaps (8) are respectively formed between the inner side of the ultrasonic transducer module (7) and the surface of the anode plate (5) and between the inner side of the ultrasonic transducer module (7) and the surface of the cathode plate (6);
the ultrasonic transducer module (7) is composed of a sealed coating shell (71) and a plurality of ultrasonic transducers (72) arranged in the sealed coating shell (71), each ultrasonic transducer (72) is connected with an electric wire, the electric wires penetrate out of one end of the ultrasonic transducer module (7) to form an electric connecting end (73), and the electric connecting ends (73) are arranged on the top surface of the shell (1) in a penetrating mode.
2. The electrolytic oxyhydrogen generation device with built-in ultrasonic waves according to claim 1, wherein: the sealed coating shell (71) is a sheet coating shell which is formed by bending and molding a metal sheet and then processing the metal sheet by adopting a welding process, and all the ultrasonic transducers (72) are uniformly arranged in the sheet coating shell so as to construct a sheet ultrasonic transducer module; and a through hole (74) transversely penetrating through the sheet-shaped cladding shell is also arranged at the position of a gap formed between the ultrasonic transducer (72) and the ultrasonic transducer (72) on the sheet-shaped cladding shell.
3. The electrolytic oxyhydrogen generation device with built-in ultrasonic waves according to claim 1, wherein: the sealed coating shell (71) is a strip-shaped coating shell formed by bending and molding a strip-shaped metal sheet and then processing the metal sheet by adopting a welding process, and each ultrasonic transducer (42) is arranged in the strip-shaped coating shell along the length direction of the strip-shaped coating shell so as to construct a strip-shaped ultrasonic transducer module; the shell (1) is positioned on the anode plate (5) and the cathode plate (6) and respectively wrapped with a plurality of strip-shaped ultrasonic transducer modules, and transverse clearance gaps are formed between the strip-shaped ultrasonic transducer modules and the strip-shaped ultrasonic transducer modules.
4. The electrolytic oxyhydrogen generation device with built-in ultrasonic waves according to claim 1, wherein: the sealing and coating shell (71) is a square flat pipe with a rectangular cross section, sealing end covers (76) are further arranged at two ends of the square flat pipe, each ultrasonic transducer (72) is fixedly connected through a metal strip to form an ultrasonic transducer strip (77), the ultrasonic transducer strip (77) penetrates through the square flat pipe, and a bolt rod (78) with a hollow structure and a nut (79) screwed on the bolt rod (78) are further respectively arranged at two ends of the ultrasonic transducer strip (77);
the bolt rod (78) penetrates through a through hole formed in the sealing end cover (76), and the bolt rod (78) is screwed tightly through a nut (79) to fix the ultrasonic transducer strip (77) in the square flat tube;
and after being connected with electric wires, each ultrasonic transducer (72) penetrates out of a bolt rod (78) with a hollow structure to form an electric connection end (73) of the ultrasonic transducer module (7).
5. The electrolytic oxyhydrogen generation device with built-in ultrasonic waves according to claim 1, 2, 3 or 4, characterized in that: the outer surface of the sealed and coated shell (71) is also covered with a protective layer (70) which is made of corrosion-resistant materials.
6. The electrolytic oxyhydrogen generation device with built-in ultrasonic waves according to claim 1, wherein: the shell (1) is also provided with a filling opening (10) with a cap (101).
7. The electrolytic oxyhydrogen generation device with built-in ultrasonic waves according to claim 1, wherein: the liquid pumping device is characterized in that a liquid pumping pump mechanism (9) is further arranged on the shell (1), the liquid pumping pump mechanism (9) is composed of a liquid pumping pump (91), an electromagnetic switch valve (92) and a pipeline (93), one end of the pipeline (93) extends into the inner cavity bottom of the shell (1), the other end of the pipeline (93) is connected with the liquid pumping pump (91), and the electromagnetic switch valve (92) is connected between the pipeline (93) and the liquid pumping pump (91) in series.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201811505416.3A CN111286747A (en) | 2018-12-10 | 2018-12-10 | Built-in ultrasonic electrolysis system oxyhydrogen device |
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| CN201811505416.3A CN111286747A (en) | 2018-12-10 | 2018-12-10 | Built-in ultrasonic electrolysis system oxyhydrogen device |
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| CN111286747A true CN111286747A (en) | 2020-06-16 |
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| CN111840724A (en) * | 2020-08-05 | 2020-10-30 | 山东维尔命生物科技有限公司 | Hydrogen-oxygen breathing machine |
| CN111910237A (en) * | 2020-06-17 | 2020-11-10 | 吴征威 | Plasma bionic material micro-arc oxidation method and device |
| CN113526468A (en) * | 2021-08-10 | 2021-10-22 | 江苏苏沪智能科技有限责任公司 | Portable oxygenerator that noise is little |
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