CN111285519A - System and process for treating sewage by utilizing photocatalytic nano material - Google Patents

System and process for treating sewage by utilizing photocatalytic nano material Download PDF

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Publication number
CN111285519A
CN111285519A CN202010241988.6A CN202010241988A CN111285519A CN 111285519 A CN111285519 A CN 111285519A CN 202010241988 A CN202010241988 A CN 202010241988A CN 111285519 A CN111285519 A CN 111285519A
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China
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chamber
light
sewage
water
treatment
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Pending
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CN202010241988.6A
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Chinese (zh)
Inventor
司崇殿
宋文路
于福海
张功国
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Jining University
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Jining University
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Priority to CN202010241988.6A priority Critical patent/CN111285519A/en
Publication of CN111285519A publication Critical patent/CN111285519A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/283Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/30Treatment of water, waste water, or sewage by irradiation
    • C02F1/32Treatment of water, waste water, or sewage by irradiation with ultraviolet light
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/66Treatment of water, waste water, or sewage by neutralisation; pH adjustment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/725Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/04Disinfection
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00Use of specific compounds during water treatment
    • C02F2305/02Specific form of oxidant
    • C02F2305/023Reactive oxygen species, singlet oxygen, OH radical

Abstract

The invention discloses a system for treating sewage by utilizing a photocatalytic nano material, which comprises a primary filter chamber, a secondary filter chamber, a gas recovery chamber and a light treatment chamber; the light processing chamber is respectively communicated with the primary filter chamber, the secondary filter chamber and the gas recovery chamber. The process comprises the following steps: sewage enters the light treatment chamber through the primary filter chamber; the light treatment chamber kills bacteria and algae in water; then discharged through the secondary filtering chamber; the gas recovery chamber recovers carbon dioxide. The invention utilizes the photocatalysis function of the nano titanium dioxide to carry out sterilization and algae removal treatment on the sewage, and is a safe and effective water treatment method; the illumination source of the nano titanium dioxide is natural light, and the nano titanium dioxide can replace an electric lamp to reduce the electric energy consumed by the electric lamp; the invention increases the contact area of light and nano titanium dioxide by utilizing the diffusion effect of the concave lens on the light, increases the light entering amount by utilizing the plane mirror inclined on the light collecting device, and increases the photon amount participating in photocatalysis, thereby obviously improving the photocatalysis effect.

Description

System and process for treating sewage by utilizing photocatalytic nano material
Technical Field
The invention relates to a system and a process for treating sewage, in particular to a system and a process for treating sewage by utilizing a photocatalytic nano material.
Background
The sewage is purified to reach the water quality requirement of being discharged into a certain water body or being reused. Sewage treatment is widely applied to various fields such as buildings, agriculture, traffic, energy, petrifaction, environmental protection, urban landscape, medical treatment, catering and the like, and is increasingly used in daily life of common people. The domestic sewage mainly contains organic matters such as carbohydrate, protein, amino acid, fat and the like, is suitable for the growth of bacteria, becomes a place for the survival and propagation of bacteria, algae and viruses, causes sewage malodor and seriously affects the living environment of surrounding residents.
The prior art methods for treating sewage mainly include filtration and sterilization. The filtration can remove insoluble solid particles in the sewage, but the small microorganisms such as bacteria, algae and the like are difficult to eliminate by the filtration. The commonly used method for killing bacteria and algae is to spray chlorine-containing disinfectant into sewage, which has good effect of killing microorganisms but has certain harm to human bodies and environment.
Disclosure of Invention
In order to solve the defects of the technology, the invention provides a system and a process for treating sewage by utilizing a photocatalytic nano material.
In order to solve the technical problems, the invention adopts the technical scheme that: a system for treating sewage by utilizing a photocatalysis nano material comprises a primary filter chamber, a secondary filter chamber, a gas recovery chamber and a light treatment chamber; the light processing chamber is respectively communicated with the primary filter chamber, the secondary filter chamber and the gas recovery chamber;
the interior of the light treatment chamber comprises a light inlet area and a water treatment area; the light inlet area is positioned above the water treatment area; the light inlet area comprises a concave lens fixed at the top end of the light treatment chamber, and a virtual focus of the concave lens is positioned in the water treatment area;
the water treatment area comprises a purification layer, and an inlet, a water outlet and an air outlet which are arranged on the wall of the chamber; the water outlet is positioned above the inlet;
the first-stage filter chamber is positioned at the inlet of the light treatment chamber, and a sewage inlet is formed in the first-stage filter chamber; the secondary filter chamber is positioned at the water outlet of the light treatment chamber and is provided with a filtered water outlet; the upper part of the light processing chamber is also provided with a gas outlet which is communicated with the gas recovery chamber through an exhaust pipe;
one or more purification layers; the purifying layer is filled with photocatalytic nano-material titanium dioxide; a plane mirror is arranged in the water treatment area; the plane mirror is tightly attached to the inner wall of the light treatment chamber.
Furthermore, the upper end of the light processing chamber is fixedly connected with a light collecting device for collecting light rays through a flange.
Further, the light collecting device is arranged on the flange through the connecting neck; the light collecting device is in a horn shape which is communicated up and down, and the diameter of an opening at the upper end of the light collecting device is larger than that of an opening at the lower end of the light collecting device; the inner wall of the light collecting device is fixedly provided with a plane mirror.
Furthermore, the concave lens is embedded in the light treatment chamber through a fixing sleeve, and a clamping groove is correspondingly formed in the inner wall of the light treatment chamber; the fixing sleeve is slidably clamped in the clamping groove.
Furthermore, a plane mirror or a stirring device is fixedly arranged on the bottom surface of the light treatment chamber.
Furthermore, an ultraviolet lamp or a fluorescent lamp is fixedly arranged on the bottom surface of the light processing chamber.
Further, a plurality of filter layers are arranged inside the primary filter chamber and the secondary filter chamber, and the filter layers include, but are not limited to, a quartz sand filter layer and an activated carbon filter layer.
Further, a ph meter and an acid-base adjusting device are arranged inside the secondary filtering chamber.
Further, an alkaline liquid is arranged in the gas recovery chamber; an air extractor is arranged in the exhaust pipe.
A process for treating sewage by utilizing a photocatalytic nano material comprises the following steps:
a. sewage is discharged into a first-stage filter chamber through a sewage inlet by a water pump, and non-dissolved substances and colored dissolved substances in the sewage are filtered and adsorbed in the first-stage filter chamber; then enters the light processing chamber through the inlet;
b. the concave lens of the light treatment chamber disperses and refracts visible light rays in the external environment into the water treatment area, so that the contact area between a purification layer filled with photocatalytic nano material titanium dioxide and light in the water treatment area is increased, and the nano titanium dioxide is catalyzed to generate a large amount of reactive active oxygen to kill bacteria and algae in water;
c. b, the water treated in the step b enters the secondary filter chamber from the water outlet to be subjected to adsorption treatment and acid-base regulation treatment, and is discharged from a filtered water outlet;
d. organic pollutants in the sewage are decomposed into carbon dioxide and water by the photocatalytic nano material, and the undissolved carbon dioxide enters the gas recovery chamber through the exhaust pipe to be recovered and decomposed.
The nanometer titanium dioxide photocatalysis effect of the invention generates reactive oxygen through light, and superoxide and hydroxyl free radical are generated under the irradiation of ultraviolet ray to destroy bacteria and algae cells, thereby realizing the function of killing bacteria and algae.
The concave lens is also called as a negative ball lens, and the middle of the lens is thin, and the edge of the lens is thick and is concave, so the lens is also called as a concave lens. The concave lens has a light diverging effect. A beam of light parallel to the main optical axis is diffused through the concave lens and can irradiate more places in the water treatment area, so that the irradiation surface of the light becomes wider and wider, the contact area of the nano titanium dioxide and the light is increased, and the photocatalytic effect is enhanced.
The invention has the following beneficial effects: the invention utilizes the photocatalysis function of the nano titanium dioxide to carry out sterilization and algae removal treatment on the sewage, and is a safe and effective water treatment method; in addition, the invention designs that the illumination source of the nano titanium dioxide is natural light, and the nano titanium dioxide can replace an electric lamp to reduce the electric energy consumed by the electric lamp; meanwhile, in order to enhance the photocatalytic effect, the contact area between the light and the nano titanium dioxide is increased by utilizing the diffusion effect of the concave lens on the light, the light collecting device is arranged, the entering amount of the light is increased by utilizing the plane mirror inclined on the light collecting device, and the quantity of photons participating in photocatalysis is increased, so that the photocatalytic effect can be obviously improved compared with the prior art.
Drawings
Fig. 1 is a schematic view of the overall structure of the present invention.
Fig. 2 is a schematic overall structure diagram of a fourth embodiment of the present invention.
In the figure: 1. a first-stage filter chamber; 2. a secondary filter chamber; 3. a gas recovery chamber; 4. a light processing chamber; 5. a concave lens; 6. a purification layer; 7. a sewage inlet; 8. a filtered water outlet; 9. an exhaust pipe; 10. a plane mirror; 11. a flange; 12. a light collecting device; 13. and (4) fixing sleeves.
Detailed Description
The present invention will be described in further detail with reference to the accompanying drawings and specific embodiments.
The first embodiment,
FIG. 1 shows a system for treating sewage by using photocatalytic nanomaterial, which comprises a primary filtering chamber 1, a secondary filtering chamber 2, a gas recovery chamber 3 and a light treatment chamber 4; the light processing chamber is respectively communicated with the primary filter chamber, the secondary filter chamber and the gas recovery chamber; and a plurality of filter layers are arranged inside the primary filter chamber and the secondary filter chamber, and the filter layers comprise but are not limited to a quartz sand filter layer and an activated carbon filter layer. The quartz sand filter layer can remove insoluble solid particles in sewage, and the activated carbon filter layer further removes floating colored particles in water, so that the water is clear.
The interior of the light treatment chamber comprises a light inlet area and a water treatment area; the light inlet area is positioned above the water treatment area; the light inlet area comprises a concave lens 5 fixed at the top end of the light treatment chamber, and one virtual focus of the concave lens is positioned in the water treatment area; the concave lens is capable of receiving visible light over a sufficiently large range and refracting into the water treatment zone.
The concave lens is embedded in the light treatment chamber through a fixing sleeve 13, and a clamping groove is correspondingly formed in the inner wall of the light treatment chamber; the fixing sleeve is slidably clamped in the clamping groove. The fixed cover and the clamping groove are matched to form a detachable structure, so that the concave lens with different focuses and transmissivity can be replaced according to actual effects, and the concave lens can be detached to fill or replace the purification layer.
The water treatment area comprises a purification layer 6, and an inlet, a water outlet and an air outlet which are arranged on the wall of the chamber; the water outlet is positioned above the inlet, and a water pump can be arranged at the water outlet to promote water flow to pass through the purification layer.
The first-stage filter chamber is positioned at the inlet of the light treatment chamber, and a sewage inlet 7 is formed in the first-stage filter chamber; the secondary filter chamber is positioned at the water outlet of the light treatment chamber, and is provided with a filtered water outlet 8.
The upper part of the light processing chamber is also provided with a gas outlet which is communicated with the gas recovery chamber through a gas exhaust pipe 9. The gas recovery chamber is provided with an alkaline liquid such as sodium hydroxide; an air extractor is arranged in the exhaust pipe, and undissolved carbon dioxide generated by photocatalysis is pumped into the gas recovery chamber through the air extractor. Alkaline liquid such as sodium hydroxide in the gas recovery chamber can react with carbon dioxide to absorb the carbon dioxide.
For the purpose of reducing the pH value of the purified water caused by the generation, i.e. dissolution, of carbon dioxide in the water, a pH meter and an acid-base adjusting device are arranged inside the secondary filtering chamber. To control the pH of the filtered purified water.
One or more purification layers; the purifying layer is filled with photocatalytic nano-material titanium dioxide; a plane mirror 10 is arranged in the water treatment area; the plane mirror is tightly attached to the inner wall of the light treatment chamber.
The plane mirror is fixedly arranged on the bottom surface of the light treatment chamber, so that light can be reflected between the side wall plane mirror and the bottom surface plane mirror, the probability that the lower purification layer is exposed to light is increased, the catalysis effect of the photocatalytic nano material is enhanced, and the sterilization and purification effects are enhanced.
The process for treating sewage by using the photocatalytic nano material comprises the following steps:
a. sewage is discharged into a first-stage filter chamber through a sewage inlet by a water pump, and non-dissolved substances and colored dissolved substances in the sewage are filtered and adsorbed in the first-stage filter chamber; then enters the light processing chamber through the inlet;
b. the concave lens of the light treatment chamber disperses and refracts visible light rays in the external environment into the water treatment area, so that the contact area between a purification layer filled with photocatalytic nano material titanium dioxide and light in the water treatment area is increased, and the nano titanium dioxide is catalyzed to generate a large amount of reactive active oxygen to kill bacteria and algae in water;
c. b, the water treated in the step b enters the secondary filter chamber from the water outlet to be subjected to adsorption treatment and acid-base regulation treatment, and is discharged from a filtered water outlet;
d. organic pollutants in the sewage are decomposed into carbon dioxide and water by the photocatalytic nano material, and the undissolved carbon dioxide enters the gas recovery chamber through the exhaust pipe to be recovered and decomposed.
Example II,
The difference from the first embodiment is that: the bottom surface of the light processing chamber is fixedly provided with a stirring device; sodium peroxide is provided in the gas recovery chamber. In this embodiment, the stirring means can promote the flow of water in the water treatment zone, thereby increasing the contact area between the water and the purification layer, and thus enhancing the sterilization effect.
The gas recovery chamber is provided with hydrogen peroxide and replaces the pumping device. The sodium peroxide reacts with the carbon dioxide to produce oxygen, which balances the negative pressure caused by the absence of carbon dioxide in the light treatment chamber.
Example III,
The difference from the first embodiment is that: the bottom surface of the light processing chamber is fixedly provided with an ultraviolet lamp or a fluorescent lamp. The light processing chamber of the invention replaces an ultraviolet lamp in the prior art, but the invention has the defect that the light processing chamber can not be used and can only be stopped at night without light, so the light processing chamber is arranged to make up for the use in night scenes. Compared with the prior art that the ultraviolet lamp is used for irradiating for 24 hours continuously, the ultraviolet lamp can be used continuously in the day and at night, and a large amount of power can be saved.
Example four,
The difference from the first embodiment is that: the upper end of the light processing chamber is fixedly connected with a light collecting device 12 for collecting light rays through a flange 11. As shown in fig. 2, the light collecting means is mounted on the flange by means of a connecting neck; the light collecting device is in a horn shape which is communicated up and down, and the diameter of an opening at the upper end of the light collecting device is larger than that of an opening at the lower end of the light collecting device; the inner wall of the light collecting device is fixedly provided with a plane mirror.
When no light collecting device is installed, only the light rays vertical to the upper part of the light processing chamber can irradiate into the light processing chamber, the entering amount of the light rays is limited, and the catalytic effect of the photocatalytic nano material is limited, so that the actual water purifying effect is influenced. Thus, light collection means are added to the top of the light processing chamber. The light collecting device horn-shaped structure and the plane mirror installed on the inner wall can transmit more light rays to the light treatment chamber in a reflection mode, so that the quantity of photons entering the light treatment chamber is increased, and the photons with enough quantity can contact the nano titanium dioxide to perform catalytic reaction, thereby enhancing the water purification effect.
The above embodiments are not intended to limit the present invention, and the present invention is not limited to the above examples, and those skilled in the art may make variations, modifications, additions or substitutions within the technical scope of the present invention.

Claims (10)

1. A system for treating sewage by utilizing photocatalysis nano materials is characterized in that: the system comprises a primary filter chamber (1), a secondary filter chamber (2), a gas recovery chamber (3) and a light treatment chamber (4); the light processing chamber is respectively communicated with the primary filter chamber, the secondary filter chamber and the gas recovery chamber;
the interior of the light treatment chamber comprises a light inlet area and a water treatment area; the light inlet area is positioned above the water treatment area; the light inlet area comprises a concave lens (5) fixed at the top end of the light treatment chamber, and one virtual focus of the concave lens is positioned in the water treatment area;
the water treatment area comprises a purification layer (6) and an inlet, a water outlet and an air outlet which are arranged on the wall of the chamber; the water outlet is positioned above the inlet;
the primary filter chamber is positioned at the inlet of the light treatment chamber, and a sewage inlet (7) is formed in the primary filter chamber; the secondary filter chamber is positioned at the water outlet of the light treatment chamber and is provided with a filtered water outlet (8); the upper part of the light processing chamber is also provided with a gas outlet which is communicated with the gas recovery chamber through a gas exhaust pipe (9);
the purification layer is one or more; the purifying layer is filled with photocatalytic nano-material titanium dioxide; a plane mirror (10) is arranged in the water treatment area; the plane mirror is tightly attached to the inner wall of the light treatment chamber.
2. The system for treating sewage using photocatalytic nanomaterial according to claim 1, wherein: the upper end of the light processing chamber is fixedly connected with a light collecting device (12) for collecting light rays through a flange (11).
3. The system for treating sewage using photocatalytic nanomaterial according to claim 2, wherein: the light collecting device is arranged on the flange through the connecting neck; the light collecting device is in a horn shape which is communicated up and down, and the diameter of an opening at the upper end of the light collecting device is larger than that of an opening at the lower end of the light collecting device; the inner wall of the light collecting device is fixedly provided with a plane mirror.
4. The system for treating sewage using photocatalytic nanomaterial according to claim 1, wherein: the concave lens is embedded in the light treatment chamber through a fixing sleeve (13), and a clamping groove is correspondingly formed in the inner wall of the light treatment chamber; the fixing sleeve is slidably clamped in the clamping groove.
5. The system for treating sewage using photocatalytic nanomaterial according to claim 1, wherein: and a plane mirror or a stirring device is fixedly arranged on the bottom surface of the light treatment chamber.
6. The system for treating sewage using photocatalytic nanomaterial according to claim 1, wherein: and an ultraviolet lamp or a fluorescent lamp is fixedly arranged on the bottom surface of the light processing chamber.
7. The system for treating sewage using photocatalytic nanomaterial according to claim 1, wherein: and a plurality of filter layers are arranged in the first-stage filter chamber and the second-stage filter chamber, and the filter layers include but are not limited to a quartz sand filter layer and an activated carbon filter layer.
8. The system for treating sewage using photocatalytic nanomaterial according to claim 7, wherein: and a ph meter and an acid-base adjusting device are also arranged in the secondary filtering chamber.
9. The system for treating sewage using photocatalytic nanomaterial according to claim 8, wherein: alkaline liquid is arranged in the gas recovery chamber; an air extractor is arranged in the exhaust pipe.
10. A process for treating sewage by using the photocatalytic nanomaterial as set forth in claim 1, wherein: the process comprises the following steps:
a. sewage is discharged into a first-stage filter chamber through a sewage inlet by a water pump, and non-dissolved substances and colored dissolved substances in the sewage are filtered and adsorbed in the first-stage filter chamber; then enters the light processing chamber through the inlet;
b. the concave lens of the light treatment chamber disperses and refracts visible light rays in the external environment into the water treatment area, so that the contact area between a purification layer filled with photocatalytic nano material titanium dioxide and light in the water treatment area is increased, and the nano titanium dioxide is catalyzed to generate a large amount of reactive active oxygen to kill bacteria and algae in water;
c. b, the water treated in the step b enters the secondary filter chamber from the water outlet to be subjected to adsorption treatment and acid-base regulation treatment, and is discharged from a filtered water outlet;
d. organic pollutants in the sewage are decomposed into carbon dioxide and water by the photocatalytic nano material, and the undissolved carbon dioxide enters the gas recovery chamber through the exhaust pipe to be recovered and decomposed.
CN202010241988.6A 2020-03-31 2020-03-31 System and process for treating sewage by utilizing photocatalytic nano material Pending CN111285519A (en)

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CN112176942A (en) * 2020-10-29 2021-01-05 南京信息职业技术学院 Corridor structure with river course purification performance
CN114671576A (en) * 2022-05-05 2022-06-28 哈尔滨工业大学 Organic sewage treatment device

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Publication number Priority date Publication date Assignee Title
CN112176942A (en) * 2020-10-29 2021-01-05 南京信息职业技术学院 Corridor structure with river course purification performance
CN114671576A (en) * 2022-05-05 2022-06-28 哈尔滨工业大学 Organic sewage treatment device

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