CN111267421A - Waterproof and fireproof glass fiber composite board and manufacturing method thereof - Google Patents
Waterproof and fireproof glass fiber composite board and manufacturing method thereof Download PDFInfo
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- CN111267421A CN111267421A CN202010169443.9A CN202010169443A CN111267421A CN 111267421 A CN111267421 A CN 111267421A CN 202010169443 A CN202010169443 A CN 202010169443A CN 111267421 A CN111267421 A CN 111267421A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/14—Layered products comprising a layer of metal next to a fibrous or filamentary layer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/02—Coating on the layer surface on fibrous or filamentary layer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/20—Inorganic coating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/101—Glass fibres
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
- B32B2307/3065—Flame resistant or retardant, fire resistant or retardant
Abstract
The invention discloses a waterproof and fireproof glass fiber composite board and a manufacturing method thereof, wherein the waterproof and fireproof glass fiber composite board comprises a board body, wherein the board body is of a multilayer structure and is sequentially divided into a first waterproof layer, a first flame-retardant layer, a first heat-insulating layer, a first glass fiber layer, a second heat-insulating layer, a second flame-retardant layer and a second waterproof layer from top to bottom.
Description
Technical Field
The invention relates to the technical field of fireproof plates, in particular to a waterproof and fireproof glass fiber composite plate and a manufacturing method thereof.
Background
The anti-doublet board is a high-temperature and high-pressure post-forming board formed by combining kraft paper impregnated with phenolic resin and melamine decorative paper impregnated on the surface, has the advantages of scratch resistance, wear resistance, radiation resistance, high temperature resistance, impact resistance, easiness in cleaning and the like on the surface, and is widely applied to wall surface dry hanging, toilet partition, home and office desktops, laboratory table tops and the like. However, the main components of the flame-retardant coating are resin and kraft paper, so that the flame-retardant coating is poor in flame retardance and cannot be well adapted to places requiring high fire-retardant rating.
Disclosure of Invention
The invention aims to provide a waterproof and fireproof glass fiber composite board and a manufacturing method thereof, and aims to solve the problems in the background technology.
In order to achieve the purpose, the invention provides the following technical scheme:
the utility model provides a fine composite sheet of waterproof fire prevention glass, the package rubbing board body, the plate body is multilayer structure, down divide into first waterproof layer, first fire-retardant layer, first heat preservation, first glass fiber layer, second heat preservation, the fire-retardant layer of second and second waterproof layer from last.
Preferably, a reinforcing layer is arranged between the first glass fiber layer and the second glass fiber layer, and the reinforcing layer is a metal foil layer.
Preferably, the first heat-insulating layer and the second heat-insulating layer are aerogel felt layers.
Preferably, the first waterproof layer and the second waterproof layer are waterproof coatings, and the used waterproof agent comprises the following components in parts by weight: 5-10 parts of copper sulfate, 1-5 parts of silane, 1-3 parts of aluminum potassium sulfate dodecahydrate, 1-5 parts of sodium silicate, 1-5 parts of ferrous sulfate and 20-40 parts of water.
Preferably, the first flame-retardant layer and the second flame-retardant layer are flame-retardant coatings, and the used flame retardant comprises the following components in parts by weight: 1-5 parts of zinc borate, 1-5 parts of aluminum hydroxide, 1-5 parts of ammonium polyphosphate, 5-7 parts of ammonium chloride, 1-3 parts of polyisoprene and 10-15 parts of water.
A manufacturing method of a waterproof and fireproof glass fiber composite board comprises the following steps:
s1, dipping the prefabricated glass fiber board in a treating agent, taking out after a period of time, coating a binding agent on the surface of one end of the glass fiber board, stacking the glass fiber board, the metal foil and the other glass fiber board in sequence from top to bottom, putting the glass fiber board, the metal foil and the other glass fiber board into a laminating machine, and performing hot pressing to obtain a core board;
s2, coating an adhesive on one end surface of the core board, stacking an aerogel felt layer on the upper part, putting the core board into a laminating machine for lamination, and performing the same treatment on the other end surface of the core board to obtain a semi-finished board;
s3, uniformly spraying flame retardants on the surfaces of the two ends of the semi-finished plate to form a flame-retardant film on the surface of the semi-finished plate;
s4, coating a waterproof layer on the surface of the semi-finished plate by using a spin coating method;
and S5, compacting the plate by using a roller press, and naturally drying and cooling to obtain a finished product.
Preferably, the treating agent in the step S1 includes the following components in parts by weight: 5-10 parts of gypsum powder, 5-10 parts of calcium carbonate, 1-5 parts of titanium dioxide, 10-15 parts of polyether glycol and 10-20 parts of water.
Preferably, the hot pressing temperature in the step S1 is 80-120 ℃, the pressure is 0.01-0.05MPa, and the time is 5-15 min.
Compared with the prior art, the invention has the beneficial effects that: according to the invention, the raw materials of the board are improved, the glass fiber is used for replacing the traditional kraft paper, the flame retardance is greatly enhanced, and the board has good heat insulation and heat preservation performance and mechanical strength and good waterproof and fireproof effects by adding the heat preservation layer and the reinforcing layer.
Drawings
Fig. 1 is a schematic structural view of a waterproof and fireproof glass fiber composite board and a manufacturing method thereof.
In the figure: 1-a first waterproof layer, 2-a first flame-retardant layer, 3-a first heat-insulating layer, 4-a first glass fiber layer, 5-a reinforcing layer, 6-a second glass fiber layer, 7-a second heat-insulating layer, 8-a second flame-retardant layer and 9-a second waterproof layer.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example one
Referring to fig. 1, the present invention provides a technical solution: the utility model provides a fine composite sheet of waterproof fire prevention glass, the package rubbing board body, the plate body is multilayer structure, down divide into first waterproof layer 1, first fire-retardant layer 2, first heat preservation 3, first glass fiber layer 4, second glass fiber layer 6, second heat preservation 7, the fire-retardant layer 8 of second and second waterproof layer 9 from last in proper order.
A reinforcing layer 5 is arranged between the first glass fiber layer 4 and the second glass fiber layer 6, and the reinforcing layer 5 is a metal foil layer.
The first heat-insulating layer 3 and the second heat-insulating layer 7 are aerogel felt layers.
The first waterproof layer 1 and the second waterproof layer 9 are waterproof coatings, and the used waterproof agent comprises the following components in parts by weight: 5 parts of copper sulfate, 1 part of silane, 1 part of aluminum potassium sulfate dodecahydrate, 1 part of sodium silicate, 1 part of ferrous sulfate and 20 parts of water.
The first flame-retardant layer 2 and the second flame-retardant layer 8 are flame-retardant coatings, and the used flame retardant comprises the following components in parts by weight: 1 part of zinc borate, 1 part of aluminum hydroxide, 1 part of ammonium polyphosphate, 5 parts of ammonium chloride, 1 part of polyisoprene and 10 parts of water.
A manufacturing method of a waterproof and fireproof glass fiber composite board comprises the following steps:
s1, dipping the prefabricated glass fiber board in a treating agent, taking out after a period of time, coating a binding agent on the surface of one end of the glass fiber board, stacking the glass fiber board, the metal foil and the other glass fiber board in sequence from top to bottom, putting the glass fiber board, the metal foil and the other glass fiber board into a laminating machine, and performing hot pressing to obtain a core board;
s2, coating an adhesive on one end surface of the core board, stacking an aerogel felt layer on the upper part, putting the core board into a laminating machine for lamination, and performing the same treatment on the other end surface of the core board to obtain a semi-finished board;
s3, uniformly spraying flame retardants on the surfaces of the two ends of the semi-finished plate to form a flame-retardant film on the surface of the semi-finished plate;
s4, coating a waterproof layer on the surface of the semi-finished plate by using a spin coating method;
and S5, compacting the plate by using a roller press, and naturally drying and cooling to obtain a finished product.
The treating agent in the step S1 comprises the following components in parts by weight: 5 parts of gypsum powder, 5 parts of calcium carbonate, 1 part of titanium dioxide, 10 parts of polyether glycol and 10 parts of water.
The hot pressing temperature in the step S1 is 80 ℃, the pressure is 0.01MPa, and the time is 5 min.
Example two
The difference from the first embodiment is that: the first waterproof layer 1 and the second waterproof layer 9 are waterproof coatings, and the used waterproof agent comprises the following components in parts by weight: 7 parts of copper sulfate, 3 parts of silane, 2 parts of aluminum potassium sulfate dodecahydrate, 3 parts of sodium silicate, 3 parts of ferrous sulfate and 30 parts of water.
The first flame-retardant layer 2 and the second flame-retardant layer 8 are flame-retardant coatings, and the used flame retardant comprises the following components in parts by weight: 3 parts of zinc borate, 3 parts of aluminum hydroxide, 3 parts of ammonium polyphosphate, 6 parts of ammonium chloride, 2 parts of polyisoprene and 13 parts of water.
A manufacturing method of a waterproof and fireproof glass fiber composite board comprises the following steps:
s1, dipping the prefabricated glass fiber board in a treating agent, taking out after a period of time, coating a binding agent on the surface of one end of the glass fiber board, stacking the glass fiber board, the metal foil and the other glass fiber board in sequence from top to bottom, putting the glass fiber board, the metal foil and the other glass fiber board into a laminating machine, and performing hot pressing to obtain a core board;
s2, coating an adhesive on one end surface of the core board, stacking an aerogel felt layer on the upper part, putting the core board into a laminating machine for lamination, and performing the same treatment on the other end surface of the core board to obtain a semi-finished board;
s3, uniformly spraying flame retardants on the surfaces of the two ends of the semi-finished plate to form a flame-retardant film on the surface of the semi-finished plate;
s4, coating a waterproof layer on the surface of the semi-finished plate by using a spin coating method;
and S5, compacting the plate by using a roller press, and naturally drying and cooling to obtain a finished product.
The treating agent in the step S1 comprises the following components in parts by weight: 7 parts of gypsum powder, 7 parts of calcium carbonate, 3 parts of titanium dioxide, 13 parts of polyether glycol and 15 parts of water.
The hot pressing temperature in the step S1 is 100 ℃, the pressure is 0.03MPa, and the time is 10 min.
EXAMPLE III
The difference from the first embodiment is that: the first waterproof layer 1 and the second waterproof layer 9 are waterproof coatings, and the used waterproof agent comprises the following components in parts by weight: 10 parts of copper sulfate, 5 parts of silane, 3 parts of aluminum potassium sulfate dodecahydrate, 5 parts of sodium silicate, 5 parts of ferrous sulfate and 40 parts of water.
The first flame-retardant layer 2 and the second flame-retardant layer 8 are flame-retardant coatings, and the used flame retardant comprises the following components in parts by weight: 5 parts of zinc borate, 5 parts of aluminum hydroxide, 5 parts of ammonium polyphosphate, 7 parts of ammonium chloride, 3 parts of polyisoprene and 15 parts of water.
A manufacturing method of a waterproof and fireproof glass fiber composite board comprises the following steps:
s1, dipping the prefabricated glass fiber board in a treating agent, taking out after a period of time, coating a binding agent on the surface of one end of the glass fiber board, stacking the glass fiber board, the metal foil and the other glass fiber board in sequence from top to bottom, putting the glass fiber board, the metal foil and the other glass fiber board into a laminating machine, and performing hot pressing to obtain a core board;
s2, coating an adhesive on one end surface of the core board, stacking an aerogel felt layer on the upper part, putting the core board into a laminating machine for lamination, and performing the same treatment on the other end surface of the core board to obtain a semi-finished board;
s3, uniformly spraying flame retardants on the surfaces of the two ends of the semi-finished plate to form a flame-retardant film on the surface of the semi-finished plate;
s4, coating a waterproof layer on the surface of the semi-finished plate by using a spin coating method;
and S5, compacting the plate by using a roller press, and naturally drying and cooling to obtain a finished product.
The treating agent in the step S1 comprises the following components in parts by weight: 10 parts of gypsum powder, 10 parts of calcium carbonate, 5 parts of titanium dioxide, 15 parts of polyether glycol and 20 parts of water.
The hot pressing temperature in the step S1 is 120 ℃, the pressure is 0.05MPa, and the time is 15 min.
Test example
The fire resistance of the composite boards of the first to third examples was tested according to the temperature rise curve of GB/T9978.1-2008, and some commercially available fire proof boards were selected for comparison, with the following results:
| duration of fire resistance (min) | |
| Example one | 155 |
| Example two | 156 |
| EXAMPLE III | 160 |
| Comparison group | 106 |
Therefore, the composite board provided by the invention has obvious improvement on flame retardance compared with the traditional board.
It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodiments, and that the present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein. Any reference sign in a claim should not be construed as limiting the claim concerned.
Furthermore, it should be understood that although the present description refers to embodiments, not every embodiment may contain only a single embodiment, and such description is for clarity only, and those skilled in the art should integrate the description, and the embodiments may be combined as appropriate to form other embodiments understood by those skilled in the art.
Claims (8)
1. The utility model provides a waterproof fire prevention glass fiber composite sheet, includes the plate body, its characterized in that: the plate body is of a multilayer structure and is sequentially divided into a first waterproof layer (1), a first flame-retardant layer (2), a first heat-preservation layer (3), a first glass fiber layer (4), a second glass fiber layer (6), a second heat-preservation layer (7), a second flame-retardant layer (8) and a second waterproof layer (9) from top to bottom.
2. The waterproof and fireproof glass fiber composite board according to claim 1, wherein: a reinforcing layer (5) is arranged between the first glass fiber layer (4) and the second glass fiber layer (6), and the reinforcing layer (5) is a metal foil layer.
3. The waterproof and fireproof glass fiber composite board according to claim 1, wherein: the first heat-insulating layer (3) and the second heat-insulating layer (7) are aerogel felt layers.
4. The waterproof and fireproof glass fiber composite board according to claim 1, wherein: the waterproof coating comprises a first waterproof layer (1) and a second waterproof layer (9), wherein the first waterproof layer and the second waterproof layer are waterproof coatings, and the waterproof agent comprises the following components in parts by weight: 5-10 parts of copper sulfate, 1-5 parts of silane, 1-3 parts of aluminum potassium sulfate dodecahydrate, 1-5 parts of sodium silicate, 1-5 parts of ferrous sulfate and 20-40 parts of water.
5. The waterproof and fireproof glass fiber composite board according to claim 1, wherein: the first flame-retardant layer (2) and the second flame-retardant layer (8) are flame-retardant coatings, and the used flame retardant comprises the following components in parts by weight: 1-5 parts of zinc borate, 1-5 parts of aluminum hydroxide, 1-5 parts of ammonium polyphosphate, 5-7 parts of ammonium chloride, 1-3 parts of polyisoprene and 10-15 parts of water.
6. The manufacturing method of the waterproof and fireproof glass fiber composite board is characterized by comprising the following steps of: the method comprises the following steps:
s1, dipping the prefabricated glass fiber board in a treating agent, taking out after a period of time, coating a binding agent on the surface of one end of the glass fiber board, stacking the glass fiber board, the metal foil and the other glass fiber board in sequence from top to bottom, putting the glass fiber board, the metal foil and the other glass fiber board into a laminating machine, and performing hot pressing to obtain a core board;
s2, coating an adhesive on one end surface of the core board, stacking an aerogel felt layer on the upper part, putting the core board into a laminating machine for lamination, and performing the same treatment on the other end surface of the core board to obtain a semi-finished board;
s3, uniformly spraying flame retardants on the surfaces of the two ends of the semi-finished plate to form a flame-retardant film on the surface of the semi-finished plate;
s4, coating a waterproof layer on the surface of the semi-finished plate by using a spin coating method;
and S5, compacting the plate by using a roller press, and naturally drying and cooling to obtain a finished product.
7. The method for manufacturing the waterproof and fireproof glass fiber composite board according to claim 6, wherein the method comprises the following steps: the treating agent in the step S1 comprises the following components in parts by weight: 5-10 parts of gypsum powder, 5-10 parts of calcium carbonate, 1-5 parts of titanium dioxide, 10-15 parts of polyether glycol and 10-20 parts of water.
8. The method for manufacturing the waterproof and fireproof glass fiber composite board according to claim 6, wherein the method comprises the following steps: the hot pressing temperature in the step S1 is 80-120 ℃, the pressure is 0.01-0.05MPa, and the time is 5-15 min.
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| CN202010169443.9A CN111267421A (en) | 2020-03-12 | 2020-03-12 | Waterproof and fireproof glass fiber composite board and manufacturing method thereof |
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| CN202010169443.9A CN111267421A (en) | 2020-03-12 | 2020-03-12 | Waterproof and fireproof glass fiber composite board and manufacturing method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112339041A (en) * | 2020-11-03 | 2021-02-09 | 南京国豪装饰安装工程股份有限公司 | Preparation method of restructuring functional type technical wood, technical wood and partition board |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112339041A (en) * | 2020-11-03 | 2021-02-09 | 南京国豪装饰安装工程股份有限公司 | Preparation method of restructuring functional type technical wood, technical wood and partition board |
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Application publication date: 20200612 |