CN111206745A - Rubber-plastic flexible mute floor material and preparation method thereof - Google Patents

Rubber-plastic flexible mute floor material and preparation method thereof Download PDF

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CN111206745A
CN111206745A CN202010187068.0A CN202010187068A CN111206745A CN 111206745 A CN111206745 A CN 111206745A CN 202010187068 A CN202010187068 A CN 202010187068A CN 111206745 A CN111206745 A CN 111206745A
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layer
rubber
powder
floor material
plastic flexible
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陈本源
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DONGGUAN MEIJER PLASTIC PRODUCTS Co Ltd
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DONGGUAN MEIJER PLASTIC PRODUCTS CO Ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00Flooring
    • E04F15/02Flooring or floor layers composed of a number of similar elements
    • E04F15/10Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials
    • E04F15/107Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials composed of several layers, e.g. sandwich panels
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00Flooring
    • E04F15/18Separately-laid insulating layers; Other additional insulating measures; Floating floors
    • E04F15/20Separately-laid insulating layers; Other additional insulating measures; Floating floors for sound insulation
    • E04F15/206Layered panels for sound insulation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2265Oxides; Hydroxides of metals of iron
    • C08K2003/2272Ferric oxide (Fe2O3)
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/30Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3045Sulfates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F2290/00Specially adapted covering, lining or flooring elements not otherwise provided for
    • E04F2290/04Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire
    • E04F2290/041Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire against noise

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  • Chemical Kinetics & Catalysis (AREA)
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  • Polymers & Plastics (AREA)
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Abstract

The invention relates to the technical field of paving materials, in particular to a rubber and plastic flexible mute floor material and a preparation method thereof, wherein the paving material comprises an underfill layer, a printing finish coat and a protective layer which are sequentially compounded from bottom to top, the underfill layer at least comprises a structural stabilizing layer, and the structural stabilizing layer comprises the following components in percentage by weight: 65-75% of inorganic filler, 15-20% of rubber modified polyvinyl chloride, 5-10% of plasticizer and 1-5% of functional auxiliary agent. The invention simplifies the structure and the manufacturing process, improves the production efficiency, reduces the production cost, is convenient for use of the produced product, is suitable for being laid in various indoor places, and can greatly reduce the technical difficulty of construction and installation and supporting measures by modifying the rubber and integrating the required functions into the product layer material.

Description

Rubber-plastic flexible mute floor material and preparation method thereof
Technical Field
The invention relates to the technical field of paving materials, in particular to a rubber and plastic flexible mute floor material and a preparation method thereof.
Background
Polyvinyl chloride is a cheap and well-processed general-purpose plastic, related products are commonly found in daily life, but the polyvinyl chloride has essential defects as plastic, such as low temperature brittleness, poor elasticity, poor impact resistance and easy permanent deformation, so that the properties of the polyvinyl chloride can be improved by other materials in reality, such as various plastics, rubber and additives. The polyvinyl chloride is modified by the rubber, so that the tendency of migration and precipitation of the plasticizer can be reduced, the calendering and extrusion process performance of the product can be improved, the flexibility, elasticity, wear resistance and pressure deformability of the product can be improved, and the dimensional stability and the stiffness of the extruded product can be facilitated. The rubber modification can also improve the oil resistance, the ageing resistance and the low temperature property, increase the stability of the product to ultraviolet radiation, further prolong the service life of the product and keep the advantages of the original PVC product, such as chemical resistance, heat resistance, flame retardance and insulativity.
The stone-plastic floor tile is a new type floor decoration material combining high-quality simulation printing and high-tech material compounding, the printing facing is protected by a high-molecular wear-resistant layer, the stone-plastic base material determining the key of whole thickness and performance is arranged below the printing facing layer, and various layer materials are processed and combined into a product which is beautiful, simulated, economical and durable through multiple procedures.
The traditional heterogeneous polyvinyl chloride floor tile can be further divided into a flexible soft board (such as LVT) and a non-flexible hard board (such as WPC and SPC), the main plastic is polyvinyl chloride, the hardness degree is usually controlled by a plasticizer, the higher the content of the plasticizer is, the softer the whole substrate is, but the toughness is poor, the accompanying disadvantages are that the size stability and the residual concavity performance are reduced, even other problems are caused by migration and precipitation of the plasticizer, although the size stability and the residual concavity performance of the hard board without the plasticizer are good, the requirement on the ground level is high due to insufficient laminating property, and if the floor is uneven, the floor tile cannot be installed or can generate sound when being trampled due to gaps.
Mineral powder filler in stone-plastic base material is mainly characterized by that it is cheap, stable and safe, and can be filled in a large volume to obtain required base material thickness, and the polyvinyl chloride plastic is mainly used for binding mineral powder to give soft property and can be easily processed into the required form, and the two portions of stone and plastic are mixed and combined by means of universal machine or extruder, and rolled into the sheet material with required thickness by means of roller, and is similar to a homogeneous flexible deformable ' soft stone ' structure, and the heterogeneous polyvinyl chloride floor tile is called ' heterogeneous ', and is actually a floor tile formed by combining several layers of different components of layer material, so that it is different from integral ' homogeneous transparent floor tile.
Paving floor materials, such as glue ground installation, floating installation, lock catch installation and the like, but the installation methods have great limitations, for example, the glue ground installation has high requirements on the quality of glue and is inconvenient to disassemble; in order to avoid directly sticking to the ground, the floating installation needs to additionally lay a bedding material firstly, and then sticks the ground material on the bedding material by glue, thereby increasing the construction cost; the lock catch installation has higher requirements on the shape of the product, and is not favorable for the beautiful design.
Disclosure of Invention
In order to overcome the defects and shortcomings in the prior art, the invention aims to provide the rubber-plastic flexible mute floor material and the preparation method thereof, the structure and the manufacturing process of the rubber-plastic flexible mute floor material are simplified, the rubber-plastic flexible mute floor material has the functions of flexibility, mute and low shrinkage, is convenient to assemble and disassemble and can be repeatedly used, can be completely recycled and reproduced in the future, and the burden on the environment is reduced.
The purpose of the invention is realized by the following technical scheme:
the utility model provides a flexible silence ground material of rubber and plastic, includes from bottom to top complex underfill layer, printing finish coat and protective layer in proper order, the underfill layer includes the stable in structure layer at least, the stable in structure layer includes following weight percent's constitution: 65-75% of inorganic filler, 15-20% of rubber modified polyvinyl chloride, 5-10% of plasticizer and 1-5% of functional auxiliary agent.
Wherein the inorganic filler is at least one of calcium carbonate powder, talcum powder, mica powder, barite powder, dolomite powder, vermiculite powder, kaolin, pottery clay, glass powder, chopped glass fiber, ceramic powder and alumina powder.
Wherein the particle size of the inorganic filler is 200-600 meshes.
The rubber modified polyvinyl chloride is characterized in that the weight ratio of rubber is more than 15%, and the rubber is at least one of chlorinated polyethylene, chloroprene rubber, nitrile rubber, ethylene propylene diene monomer rubber, polyurethane elastomer, acrylate copolymer and methyl methacrylate-butadiene-styrene terpolymer.
The bottom filling layer further comprises a mute vibration damping layer compounded on the upper surface of the structural stabilizing layer, and the mute vibration damping layer comprises the following components in percentage by weight: 45-75% of damping filler, 15-40% of rubber modified polyvinyl chloride, 5-10% of plasticizer and 1-5% of functional auxiliary agent, wherein the damping filler is at least one of hollow floating beads, barite powder and iron oxide powder.
The lower surface of the structure stabilizing layer is compounded with a bottom anti-slip layer, and the bottom anti-slip layer is provided with embossing formed by hot pressing.
Wherein, the printing decorative surface layer is a polyvinyl chloride layer with printing ink patterns printed on the surface.
The protective layer comprises a transparent wear-resistant layer and a scratch-resistant coating compounded on the upper surface of the transparent wear-resistant layer.
Wherein, the transparent wear-resisting layer is a transparent polyvinyl chloride wear-resisting layer.
The scratch-resistant coating is a high-molecular acrylate polymer layer formed by ultraviolet-initiated polymerization of acrylate monomers.
The rubber-plastic flexible mute floor material comprises the following steps: the bottom filling layer is combined with the printing decoration surface layer in a hot pressing mode, and the protective layer is compounded on the printing decoration surface layer in a hot pressing or coating mode.
Specifically, the preparation method of the present invention may comprise the following steps:
sequentially laying the shading anti-slip layer, the structural stable layer, the mute vibration damping layer, the printing decoration surface layer and the transparent wear-resistant layer, arranging matched embossed plates from top to bottom, putting the embossed plates into a hot press for hot pressing and laminating, wherein the heating temperature is 130-2For 23-25 minutes; the second stage pressure is 80-90kgf/cm2For 1-5 minutes; third stage pressure 120-2And the time is 15-20 minutes, the large semi-finished product is laminated by hot pressing, then the surface is coated with scratch-resistant coating, the ultraviolet light is firstly cured, then the stress is released by hot water tempering, and the product is cut and formed according to the required size after being placed in a constant temperature room for two days to obtain the final product.
The method can also comprise the following steps:
with shading limited slip layer, silence damping layer, printing finish coat, transparent wearing layer rolling respectively, hang the feeding axle of extruding the rigging machine in order, extrude the formula material feeding extruder on stable in structure layer, utilize material temperature waste heat with each layer material direct at online hot pressing laminating one-tenth an organic whole, wherein the required thickness of this layer of calendering wheel control, follow-up knurling wheel and shading wheel are giving surface and bottom surface line with 150 additionally-colored 175 ℃ pressure ply material simultaneously, recooling cooling, cut and receive the material. Hot pressing to form a large semi-finished product, coating a scratch-resistant coating on the surface, ultraviolet curing, hot water tempering to release stress, placing in a constant temperature room for two days, and cutting according to the required size to form the final product.
The invention has the beneficial effects that:
1. the glue-free installation is a simple and quick mode when the floor is used in places with limited space or time, but the floor is limited by the limitation of polyvinyl chloride floor materials, the development limitation is large, heavy polyvinyl chloride floor materials are often not well attached or not good in flexibility, noise is easy to generate due to the fact that the floor is easy to shake on the partially uneven ground, and the requirement of silence is not met; while a ground material with good flexibility has good conformability, the ground material also has low surface hardness, light weight, easy depression, and poor treading feeling and positioning performance. According to the invention, through rubber modification and integration of required functions into the product layer material, the structure and the manufacturing process are simplified, the production efficiency is improved, the production cost is reduced, the produced product is convenient to use, the product is suitable for being laid in various indoor places, and the technical difficulty and the supporting measures of construction and installation can be greatly reduced; the high filling amount can endow the structure stabilizing layer with the characteristics of high specific gravity and high hardness, so that the structure stabilizing layer has better positioning performance, the rubber modification can endow the structure stabilizing layer with better flexibility, the Shore D hardness of the common plastic floor tile is more than 50-70, and the product is about 38-45, so that the falling pedestrian can be provided with a safer buffer protection effect.
2. The invention uses rubber modification to increase flexibility, can reduce the dosage of plasticizer, improve the disadvantages of precipitation and physical property reduction caused by plasticizer softening, and the general physical property performance is measured by ISO 23999 or GB/T4085 method, wherein the heating size change rate measured by GB/T4085 method is less than 0.10% (standard is less than or equal to 0.25%), even transverse is less than 0.05%, in response to cold shrinkage in cold regions, a glass fiber layer can be added between bottom filling layers to reduce the gap width caused by shrinkage, the surface residual concavity is 0.08mm (standard is less than or equal to 0.10mm) measured by ISO 24343-1, and the surface residual concavity is 0.16mm measured by GB/T4085 (standard is 0.15< IR is less than or equal to 0.40 mm).
3. The invention integrates the mute and anti-slip functions into the integral structure layer material, avoids the method of sticking other heterogeneous foaming mute pads or anti-slip pads on the bottom surface of the ground material generally, improves the production efficiency, and the manufactured product has the characteristics of flexibility, mute, vibration reduction, wear resistance, scratch resistance, beauty, sticking, anti-slip, low shrinkage, quick assembly and disassembly, reusability and complete recovery and reproduction;
4. the invention introduces the high specific gravity and low specific gravity filler into the mute vibration damping layer, and improves the impact sound insulation effect. Taking the base material with 75% volume filling amount as an example, the specific gravity of calcium carbonate filler is 2.1, the specific gravity of hollow floating bead filler is 1.0, the specific gravity of barite filler is 3.2, the specific gravity of iron oxide filler is 3.5, and the four have obvious differences. Taking a product with the total thickness of 8.078mm as an example, the thickness of the silencing and damping layer is 2.0mm, if the bottom material is completely filled with calcium carbonate, the impact sound insulation improvement delta IIC of the finished product is 12dB by the method of ASTM E2179, if the bottom material is filled with hollow floating beads, the delta IIC can be increased to 16dB, and if the bottom material is filled with barite, the delta IIC is increased to 18 dB. Based on the above results, if a 2.0mm mute vibration damping layer is formed into two layers, one layer of the base material is filled with hollow floating beads, and the other layer of the base material is filled with barite, the Δ IIC can be increased to 19 dB.
Drawings
FIG. 1 is a schematic structural view of the product of example 1;
FIG. 2 is a schematic structural view of the product of example 2;
the reference signs are:
an underfill layer 10;
a shading anti-slip layer 11;
a structural stabilization layer 12;
a mute vibration damping layer 13;
a fiberglass layer 14;
printing a finishing layer 20;
a transparent wear layer 30;
a surface scratch resistant coating 40.
Detailed Description
For the understanding of those skilled in the art, the present invention will be further described with reference to the following examples and the accompanying fig. 1, and the description of the embodiments is not intended to limit the present invention.
Example 1
Referring to fig. 1, a detailed structure of a preferred embodiment 1 of the complete product of the present invention is shown, which comprises a bottom-grain anti-slip layer 11, a structural stabilizing layer 12, a mute vibration-damping layer 13, a printing decoration layer 20, a transparent wear-resistant layer 30 and a surface scratch-resistant coating 40 in sequence from bottom to top.
The structural stabilizing layer 12 comprises the following components in percentage by weight: 70% of inorganic filler, 17.5% of rubber modified polyvinyl chloride, 7.5% of plasticizer and 5% of functional auxiliary agent.
The inorganic filler is calcium carbonate.
Wherein, in the rubber modified polyvinyl chloride, the weight ratio of rubber is 25%, and the rubber is nitrile rubber.
The mute vibration attenuation layer 13 comprises the following components in percentage by weight: 45% of damping filler, 34% of rubber modified polyvinyl chloride, 18% of plasticizer and 3% of functional auxiliary agent. Wherein the damping filler is hollow floating beads.
The thickness of each layer of the product with the total thickness of 5.0mm is sequentially the shading anti-slip layer 11: 0.8mm, structural stability layer 12: 2.8mm, mute vibration damping layer 13: 0.8mm, print finish 20: 0.07mm, transparent wear layer 30: 0.55mm and surface scratch-resistant coating 40: 0.008 mm.
Example 2
This example differs from example 1 in that:
referring to fig. 2, a specific structure of a preferred embodiment 2 of the complete product of the present invention is shown, which sequentially comprises a bottom-grain anti-slip layer 11, a glass fiber layer 14, a structural stabilizing layer 12, a glass fiber layer 14, a silent vibration damping layer 13, a printing decoration layer 20, a transparent wear-resistant layer 30 and a surface scratch-resistant coating 40 from bottom to top.
In the rubber modified polyvinyl chloride, the weight ratio of rubber is 25%. Wherein the rubber is nitrile rubber.
The mute vibration damping layer 13 is formed by adjusting the actual weight percentage according to the specific gravity of individual fillers according to the principle of 75% volume filling amount: 45% of damping filler, 34% of rubber modified polyvinyl chloride, 18% of plasticizer and 3% of functional auxiliary agent. Wherein the damping filler is hollow floating beads.
The thickness of each layer of the product with the total thickness of 8.0mm is sequentially the shading anti-slip layer 11: 1.0mm, glass fiber layer 14: 0.25mm, structural stabilizing layer 12: 3.5mm, glass fiber layer 14: 0.25mm, mute vibration-damping layer 13: 2.0mm, print finish 20: 0.07mm, transparent wear layer 30: 1.0mm and surface scratch-resistant coating 40: 0.008 mm. The glass fiber layer is introduced, so that short-term cold and heat expansion and long-term longitudinal shrinkage are reduced.
The product has the heating size change rate of 0.08% (standard is less than or equal to 0.25%) and the transverse direction of 0.04% according to the GB/T4085 method, the surface residual concavity is 0.08mm (standard is less than or equal to 0.10mm) according to ISO 24343-1, the impact sound insulation improvement delta IIC is 16dB according to GB/T4085 (standard is 0.15< IR is less than or equal to 0.40 mm).
Example 3
This example differs from example 2 in that:
the mute vibration damping layer 13 is formed by adjusting the actual weight percentage according to the specific gravity of individual fillers according to the principle of 75% volume filling amount: 80% of damping filler, 12% of rubber modified polyvinyl chloride, 5% of plasticizer and 3% of functional auxiliary agent, wherein the damping filler is barite. The impact sound insulation improvement quantity delta IIC of the product is 18 dB.
Example 4
This example differs from example 2 in that:
the mute vibration damping layer 13 is formed by superposing two 1.0mm single layers, wherein one layer comprises the following components in percentage by weight: 45% of damping filler, 34% of rubber modified polyvinyl chloride, 18% of plasticizer and 3% of functional additive, wherein the damping filler is hollow floating beads, and the other layer comprises the following components in percentage by weight: 80% of damping filler, 12% of rubber modified polyvinyl chloride, 5% of plasticizer and 3% of functional auxiliary agent, wherein the damping filler is barite. The impact sound insulation improvement quantity delta IIC of the product is 19 dB.
Example 5
This example differs from example 2 in that:
wherein, the inorganic filler in the structure stabilizing layer 12 is calcium carbonate and chopped glass fiber which are mixed according to the weight ratio of 9: 1.
In the rubber modified polyvinyl chloride, the weight ratio of rubber is 25%. The rubber is prepared from chlorinated polyethylene and chloroprene rubber according to the weight ratio of 1: 1.
The mute vibration damping layer 13 is formed by adjusting the actual weight percentage according to the specific gravity of individual fillers according to the principle of 75% volume filling amount: 85% of damping filler, 9% of rubber modified polyvinyl chloride, 4% of plasticizer and 2% of functional auxiliary agent. Wherein the damping filler is iron oxide. The impact sound insulation improvement quantity delta IIC of the product is 19 dB.
Example 6
This example differs from example 2 in that:
the structural stabilizing layer 12 comprises the following components in percentage by weight: 75% of inorganic filler, 15% of rubber modified polyvinyl chloride, 9% of plasticizer and 1% of functional auxiliary agent. Wherein the inorganic filler is a mixture of glass powder, ceramic powder and alumina powder.
In the rubber modified polyvinyl chloride, the weight ratio of rubber is 25%. Wherein the rubber is a mixture of a polyurethane elastomer, an acrylate copolymer and a methyl methacrylate-butadiene-styrene terpolymer.
The mute vibration attenuation layer 13 comprises the following components in percentage by weight: 65% of damping filler, 18% of rubber modified polyvinyl chloride, 15% of plasticizer and 2% of functional additive, wherein the damping filler is a mixture of hollow floating beads and barite powder.
Example 7
This example differs from example 2 in that:
the inorganic filler in the structure stabilizing layer 12 is composed of calcium carbonate, talcum powder and mica powder barite according to the weight ratio of 8:1: 1.
Example 8
This example differs from example 2 in that:
the inorganic filler in the structure stabilizing layer 12 is composed of calcium carbonate, barite powder and dolomite powder barite according to the weight ratio of 8:1: 1.
Example 9
This example differs from example 2 in that:
the inorganic filler in the structure stabilizing layer 12 is composed of calcium carbonate, vermiculite powder and kaolin barite according to the weight ratio of 8:1: 1.
The above-described embodiments are preferred implementations of the present invention, and the present invention may be implemented in other ways without departing from the spirit of the present invention.

Claims (10)

1. A rubber and plastic flexible mute floor material is characterized in that: including from bottom to top in proper order compound underfill, printing finish coat and protective layer, the underfill includes the stable in structure layer at least, the stable in structure layer includes the following weight percent's of constitution: 65-75% of inorganic filler, 15-20% of rubber modified polyvinyl chloride, 5-10% of plasticizer and 1-5% of functional auxiliary agent.
2. The rubber-plastic flexible mute floor material as claimed in claim 1, wherein: the inorganic filler is at least one of calcium carbonate powder, talcum powder, mica powder, barite powder, dolomite powder, vermiculite powder, kaolin, pottery clay, glass powder, chopped glass fiber, ceramic powder and alumina powder.
3. The rubber-plastic flexible mute floor material as claimed in claim 1, wherein: in the rubber modified polyvinyl chloride, the weight ratio of rubber is more than 15%, and the rubber is at least one of chlorinated polyethylene, chloroprene rubber, nitrile rubber, ethylene propylene diene monomer, polyurethane elastomer, acrylate copolymer and methyl methacrylate-butadiene-styrene terpolymer.
4. The rubber-plastic flexible mute floor material as claimed in claim 1, wherein: the bottom filling layer also comprises a mute vibration damping layer compounded on the upper surface of the structural stabilizing layer, and the mute vibration damping layer comprises the following components in percentage by weight: 45-80% of damping filler, 10-40% of rubber modified polyvinyl chloride, 5-20% of plasticizer and 1-5% of functional auxiliary agent, wherein the damping filler is at least one of hollow floating beads, barite powder and iron oxide powder.
5. The rubber-plastic flexible mute floor material as claimed in claim 1, wherein: the lower surface of the structure stabilizing layer is compounded with a bottom anti-slip layer, and the bottom anti-slip layer is provided with embossing formed by hot pressing.
6. The rubber-plastic flexible mute floor material as claimed in claim 1, wherein: the printing decorative surface layer is a polyvinyl chloride layer with printing ink patterns printed on the surface.
7. The rubber-plastic flexible mute floor material as claimed in claim 1, wherein: the protective layer comprises a transparent wear-resistant layer and a scratch-resistant coating compounded on the upper surface of the transparent wear-resistant layer.
8. The rubber-plastic flexible mute floor material as claimed in claim 7, wherein: the transparent wear-resistant layer is a transparent polyvinyl chloride wear-resistant layer.
9. The rubber-plastic flexible mute floor material as claimed in claim 7, wherein: the scratch-resistant coating is a high-molecular acrylate polymer layer formed by ultraviolet-initiated polymerization of acrylate monomers.
10. The preparation method of the rubber-plastic flexible mute floor material as claimed in any one of claims 1-9, wherein the method comprises the following steps: the method comprises the following steps: and combining the bottom filling layer with the printing finish coat in a hot pressing mode, and compounding the protective layer on the printing finish coat in a hot pressing or coating mode.
CN202010187068.0A 2020-03-17 2020-03-17 Rubber-plastic flexible mute floor material and preparation method thereof Pending CN111206745A (en)

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