CN112746719A - Multilayer co-extrusion stone-plastic floor and manufacturing method thereof - Google Patents

Multilayer co-extrusion stone-plastic floor and manufacturing method thereof Download PDF

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Publication number
CN112746719A
CN112746719A CN202011641442.6A CN202011641442A CN112746719A CN 112746719 A CN112746719 A CN 112746719A CN 202011641442 A CN202011641442 A CN 202011641442A CN 112746719 A CN112746719 A CN 112746719A
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China
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stone
layer
parts
weight
plastic
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CN202011641442.6A
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Chinese (zh)
Inventor
宋剑刚
王劲松
符家进
晏鹏
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Zhejiang Yongyu Household Co Ltd
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Zhejiang Yongyu Household Co Ltd
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Priority to CN202011641442.6A priority Critical patent/CN112746719A/en
Publication of CN112746719A publication Critical patent/CN112746719A/en
Priority to EP21893118.6A priority patent/EP4050179A4/en
Priority to PCT/CN2021/143142 priority patent/WO2022143913A1/en
Priority to US17/664,420 priority patent/US20220275653A1/en
Priority to US18/361,846 priority patent/US20230383546A1/en
Pending legal-status Critical Current

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    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00—Flooring
    • E04F15/02—Flooring or floor layers composed of a number of similar elements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00—Flooring
    • E04F15/02—Flooring or floor layers composed of a number of similar elements
    • E04F15/10—Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials
    • E04F15/107—Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials composed of several layers, e.g. sandwich panels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
    • B32B2264/10—Inorganic particles
    • B32B2264/102—Oxide or hydroxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
    • B32B2264/10—Inorganic particles
    • B32B2264/104—Oxysalt, e.g. carbonate, sulfate, phosphate or nitrate particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/554—Wear resistance
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/732—Dimensional properties
    • B32B2307/734—Dimensional stability
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2471/00—Floor coverings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives

Abstract

The embodiment of the application disclosesMultilayer coextruding stone plastic floor. The multilayer co-extrusion stone-plastic floor comprises: at least one layer is moulded to coextruding stone, layer from the top down includes at least to coextruding stone: the stone-plastic composite material comprises a first stable layer, a stone-plastic rigid layer and a second stable layer; the dimensional change rates of the first stabilizing layer and the second stabilizing layer are both 0-0.12% at-15-80 ℃; at least one of the first stabilizing layer, the stone-plastic rigid layer and the second stabilizing layer comprises ACR/nano SiO2Composite particles. The stable floor is characterized in that a stable layer is added on the upper part and the lower part of a stone plastic rigid layer of the floor, and ACR/nano SiO is added into floor materials2The composite particles can improve the thermal stability of the floor material and reduce the thermal deformation of the floor material while ensuring the strength of the floor.

Description

Multilayer co-extrusion stone-plastic floor and manufacturing method thereof
Technical Field
The specification relates to the technical field of floor manufacturing, in particular to a multilayer co-extrusion stone-plastic floor and a manufacturing method thereof.
Background
The stone plastic floor (SPC) is a PVC floor with a multilayer structure, has the advantages of mildew resistance, moisture resistance, fire resistance, wear resistance, simple installation, long service life and the like, and is widely used for indoor floor decoration. The substrate layer of the common multilayer stone-plastic floor is formed by extrusion molding through a thermal fusion process by using natural stone powder (calcium carbonate powder) and high polymer resin (polyvinyl chloride) as main raw materials. To reduce costs, large amounts of inorganic fillers are often added. However, the PVC material has poor thermal stability, the brittleness of the material is increased by adding the inorganic filler, and the chlorinated polyvinyl Chloride (CPE) auxiliary agent is added into the floor, so that the Vicat softening point of the floor is reduced due to toughening of the CPE, the phenomena of warping deformation, arching and lock catch falling and breaking are more likely to occur, and the service life is shortened.
Therefore, it is necessary to provide a stone floor having good thermal stability and less thermal deformation.
Disclosure of Invention
One of the embodiments of this specification provides a floor is moulded to multilayer coextrusion stone, floor is moulded to multilayer coextrusion stone includes that layer is moulded to at least one coextrusion stone, layer from the top down includes at least to coextrusion stone: the stone-plastic composite material comprises a first stable layer, a stone-plastic rigid layer and a second stable layer; the first and second stabilizing layers have a dimensional change rate of-15 ℃ to 80 ℃All are 0-0.12%; at least one of the first stabilizing layer, the stone-plastic rigid layer and the second stabilizing layer comprises ACR/nano SiO2Composite particles.
In another aspect of the present description, there is provided a method of manufacturing a multilayer co-extruded stone floor, the method including: mixing materials of at least one layer of the first stabilizing layer and the second stabilizing layer to obtain a first mixed material, and stirring the first mixed material to obtain a first ingredient, wherein the first mixed material contains ACR/nano SiO2Composite particles; mixing the materials of the stone-plastic rigid layer to obtain a second mixed material, and stirring the second mixed material to obtain a second ingredient, wherein the second mixed material contains ACR/nano SiO2Composite particles; will first compounding with the layer is moulded to the second compounding through extruder extrusion crowded stone altogether, crowded stone altogether moulds the layer and includes three layer construction, and from the top down does in proper order first stable layer the rigid layer is moulded to stone with the second stable layer.
Drawings
The present description will be further explained by way of exemplary embodiments, which will be described in detail by way of the accompanying drawings. These embodiments are not intended to be limiting, and in these embodiments like numerals are used to indicate like structures, wherein:
FIG. 1 is a cross-sectional view of a coextruded stone layer according to some embodiments herein;
FIG. 2 is a cross-sectional view of a multi-layer co-extruded stone floor according to some embodiments herein;
FIG. 3 is a flow chart of a method of manufacturing a multi-layer co-extruded stone floor according to some embodiments of the present disclosure.
Detailed Description
In order to more clearly illustrate the technical solutions of the embodiments of the present disclosure, the drawings used in the description of the embodiments will be briefly described below. It is obvious that the drawings in the following description are only examples or embodiments of the present description, and that for a person skilled in the art, the present description can also be applied to other similar scenarios on the basis of these drawings without inventive effort. Unless otherwise apparent from the context, or otherwise indicated, like reference numbers in the figures refer to the same structure or operation.
As used in this specification and the appended claims, the terms "a," "an," "the," and/or "the" are not intended to be inclusive in the singular, but rather are intended to be inclusive in the plural, unless the context clearly dictates otherwise. In general, the terms "comprises" and "comprising" merely indicate that steps and elements are included which are explicitly identified, that the steps and elements do not form an exclusive list, and that a method or apparatus may include other steps or elements.
Flow charts are used in this description to illustrate operations performed by a system according to embodiments of the present description. It should be understood that the preceding or following operations are not necessarily performed in the exact order in which they are performed. Rather, the various steps may be processed in reverse order or simultaneously. Meanwhile, other operations may be added to the processes, or a certain step or several steps of operations may be removed from the processes.
FIG. 1 is a cross-sectional view of a coextruded stone layer according to some embodiments herein.
The co-extruded stone-plastic floor may be a floor of a multilayer structure. In some embodiments, a coextruded stone floor may comprise at least one or more coextruded stone layers. The co-extrusion stone-plastic layer is a structure for providing support for the co-extrusion stone-plastic floor, for example, the co-extrusion stone-plastic layer can provide main strength or hardness and the like for the co-extrusion stone-plastic floor.
In some embodiments, the coextruded stone layer of the coextruded stone floor may be a multilayer structure. The coextruded stone layer may include: a stabilizing layer and a stone-plastic rigid layer. A stabilizing layer may refer to a structural layer that stabilizes other layers in the floor when the other layers are deformed. The stone-plastic rigid layer may be a structural layer that provides strength and support to the floor.
In some embodiments, the number of stabilizing layers and/or rigid stone-plastic layers in the co-extruded stone-plastic layer may be one or more, and the composition of the stabilizing layer or rigid stone-plastic layer of each layer may be the same or different.
In some embodiments, the sequence between different layers in the co-extruded stone-plastic layer can be that the stone-plastic rigid layer is positioned between the stabilizing layers, and the stone-plastic rigid layer is positioned on the stabilizing layers. In some embodiments, adjacent layers may be connected in a variety of ways. For example, the bonding agent is a substance for bonding objects to each other, and the bonding agent may be a PLA resin, a phenol resin, or the like. For example, the bonding is performed by thermal compression bonding. It will be appreciated that the manner of connection between different adjacent layers may be the same or different.
In some embodiments, the co-extruded stone-plastic layer may include two stable layers and a stone-plastic rigid layer, and as shown in fig. 1, the co-extruded stone-plastic layer 100 may include, in order from top to bottom: a first stabilizing layer 101, a stone-plastic rigid layer 102 and a second stabilizing layer 103.
The first stabilizing layer may refer to a structural layer used to stabilize other layers in the co-extruded stone-plastic flooring. For example, the first stabilizing layer may be a structural layer that provides a downward pulling force when other layers (e.g., UV coating, wear layer, etc.) above the first stabilizing layer expand with heat and contract with cold in a co-extruded stone floor (e.g., the co-extruded stone floor 200). See below for more details on the other layers.
In some embodiments, the first stabilizing layer may cause the layer to deform little or no under external forces from other layers (e.g., layers above the first stabilizing layer). For example, under an external force of 2000psi (Pounds square inch), the deformation is less than 0.13 mm. Wherein, 1psi is 0.006895 MPa. For example, the first stabilizing layer may be a rigid material layer, i.e. a material which prevents the layer from deforming under the action of external force, thereby ensuring the compressive strength of the stone-plastic floor and preventing brittle fracture.
In some embodiments, the first stabilizing layer has a dimensional change of 0-0.12% at-15 ℃ to 80 ℃.
In some embodiments, the composition of the first stabilizing layer may include ACR/nano SiO2Composite particles.
ACR/nano SiO2The composite particles are based on ACR (acrylate copolymer) and nano SiO2And (4) compounding the generated chemical substances. In some embodiments, ACR/nano SiO2CompoundingThe particles may be nanoparticles. For example, the composite particles may have a particle size in the range of 20-80 nm. It will be appreciated that the particle size of the composite particles may be based on the nano-SiO that forms the composite particles2And (4) determining.
In some embodiments, ACR/nano SiO2Composite particles can be produced by a variety of compounding means. For example, ACR and nano SiO2 can be physically or mechanically mixed to obtain ACR/nano SiO2Composite particles. For another example, ACR and nano SiO2 can be chemically mixed to obtain ACR/nano SiO2Composite particles.
In some embodiments, the nano-SiO is surface modified by a modifier2The particles are dispersed in an acrylate monomer, and allyl is introduced to carry out polymerization reaction with the monomer to obtain a graft polymer chain, so as to form the ACR/nano SiO2 composite particles. For example, a composite particle prepared by modifying a miniemulsion polymer of acrylic monomers of nano SiO2 with a methacrylic acid-3-trimethoxy silane (MPS) coupling agent.
In some embodiments, the second stabilizing layer may refer to a structural layer used to stabilize other layers in the coextruded stone floor. For example, the second stable layer may be a structural layer that provides a downward pulling force when the other layers (e.g., the first stable layer, the stone-plastic rigid layer, the UV coating, the wear layer, etc.) above the second stable layer expand with heat and contract with cold in the co-extruded stone-plastic floor.
In some embodiments, the second stabilizing layer may cause the layer to deform little or no under external forces from other layers (e.g., layers above the second stabilizing layer). For example, under an external force of 2000psi (Pounds square inch), the deformation is less than 0.13 mm. Wherein, 1psi is 0.006895 MPa. Similar to the first stabilizing layer, the second stabilizing layer may be a layer of rigid material.
In some embodiments, the second stabilizing layer has a dimensional change of 0-0.12% at-15 ℃ to 80 ℃.
In some embodiments, the composition of the second stabilizing layer may include ACR/nano SiO2Composite particles. About ACR/nano SiO2The composite particles can be seen from the foregoing and are not described in detail.
The stone-plastic rigid layer refers to a structural layer for providing strength and supporting force to the co-extrusion stone-plastic floor.
In some embodiments, the composition of the stone-plastic rigid layer may include ACR/nano SiO2Composite particles.
In some embodiments, the composition of the stone-plastic rigid layer, the first stabilizing layer and the second stabilizing layer may also include other compositions, see in particular below.
The layer is moulded to crowded stone altogether on with the floor sets up to three layer construction, can the effective control multilayer crowded stone altogether mould floor overall stability, and the effective control multilayer crowded stone altogether moulds the warpage tile form that other layer shranks in floor brought. Meanwhile, the strength of the multilayer co-extrusion stone-plastic floor is ensured by the arrangement of the stone-plastic rigid layer in the co-extrusion stone-plastic layer, and the heat resistance and the creep resistance of the multilayer co-extrusion stone-plastic floor are improved.
Also, by adding ACR/nano SiO in the floor (e.g. a stabilizing layer or a stone-plastic rigid layer)2The composite particle component can obviously improve the performance of the floor. ACR/nano SiO2The composite particles are nanoparticles, and the nanoparticles have size effect, local field effect, quantum effect and the like, so that the nanoparticles can show excellent performances which are not possessed by conventional materials, including improvement of the strength of the floor and improvement of the heat deformation resistance of the floor by improving the Vicat softening point of the floor.
As mentioned above, the co-extruded stone-plastic flooring may comprise other layers in addition to the co-extruded stone-plastic layer. In some embodiments, the multilayer coextruded stone floor may further comprise at least one of the following structural layers: UV coating, wearing layer, various rete. Please refer to fig. 2 and the description thereof for more contents of the UV coating, the wear layer, and the color film layer.
In some embodiments, ACR/nano SiO2The ACR grafting rate on the surface of the composite particle can be 70-110%.
The ACR grafting ratio refers to the efficiency of bonding other functional groups to the compound formula of the acrylate-based copolymer through chemical bonds. Other functional groups are atoms or groups of atoms which determine the chemical nature of the organic compound, apart from the compound itself. For example, the other functional group may be a methyl group, an epoxy group, or the like.
ACR/nano SiO2The grafting rates of the composite particles are different, and the performance detection results of the multilayer co-extrusion stone-plastic floor board are affected differently. Specifically, the specific influence on the performance test result can be embodied by the following set of experiments.
In this group of experiments, the first stable layer and the second stable layer in the multilayer co-extrusion stone-plastic floor are set as follows: the composite material comprises 100 parts by weight of polyvinyl chloride, 270 parts by weight of inorganic filler, 1.5 parts by weight of polyethylene wax, 10 parts by weight of stabilizer, 1.4 parts by weight of stearic acid, 0.6 part by weight of oxidized polyethylene wax, 15 parts by weight of ACR/nano SiO2 composite particles with different grafting ratios and 0.5 part by weight of carbon black; the stone-plastic rigid layer in the multilayer co-extrusion stone-plastic floor is set as follows: 100 parts by weight of polyvinyl chloride, 360 parts by weight of inorganic filler, 1.2 parts by weight of polyethylene wax, 5 parts by weight of stabilizer, 1.0 part by weight of stearic acid, 10 parts by weight of ACR/nano SiO2 composite particles with different grafting rates and 10 parts by weight of glass beads.
The test results included the impact strength of the multilayer coextruded stone-plastic flooring. The impact strength is the energy absorbed per unit cross-sectional area when the test specimen is broken or fractured by an impact load. Impact load refers to a load that acts on an object at a great speed in a short time.
The test results were as follows:
(1) when ACR/nano SiO2When the grafting rate of the composite particles is 0 percent, the impact strength of the multilayer co-extrusion stone-plastic floor is 1.8KJ/m2；
(2) When ACR/nano SiO2When the grafting rate of the composite particles is 70 percent, the impact strength of the multilayer co-extrusion stone-plastic floor is 10.5KJ/m2；
(3) When ACR/nano SiO2When the grafting rate of the composite particles is 85 percent, the impact strength of the multilayer co-extrusion stone-plastic floor is 10.8KJ/m2；
(4) When ACR/nano SiO2When the grafting rate of the composite particles is 100 percent, the impact strength of the multilayer co-extrusion stone-plastic floor is 11.3KJ/m2；
(5) When ACR/nano SiO2When the grafting rate of the composite particles is 110 percent, the impact strength of the multilayer co-extrusion stone-plastic floor is 10.8KJ/m2；
The experimental data show that the ACR/nano SiO are under the condition of the same components2When the grafting rate of the composite particles is 70%, 85%, 100% and 110%, the material has impact resistance, and the performance is obviously superior to ACR/nano SiO2The graft ratio of the composite particles was 0%. The grafting rate of 0% can be understood as nano SiO2When the particles are mixed with ACR, ACR is not mixed with SiO2By chemical bonding, ACR is not modified. The higher the impact resistance, the better the impact resistance and the better the toughening effect. It can be understood that ACR/nano SiO with the surface ACR grafting rate of 70-110 percent is adopted2The composite particles have better toughening effect. At the same time, ACR/nano SiO2The composite particles can be dispersed into fine particles suspended in the polyvinyl chloride PVC, thereby increasing the toughening effect of the polyvinyl chloride PVC, and the toughening effect of the polyvinyl chloride PVC with the composite particles is obviously better than that of the nano SiO2Particles and unmodified ACR copolymer. These experimental data may be used as a basis for a related embodiment.
In some embodiments, ACR/nano SiO2The ACR grafting ratio on the surface of the composite particle may be 70%. Adopting ACR/nano SiO with the surface ACR grafting rate of 70 percent2The composite particles and the stone plastic floor have better toughening effect.
In some embodiments, ACR/nano SiO2The ACR grafting ratio on the surface of the composite particle may be 85%. Adopting ACR/nano SiO with surface ACR grafting rate of 85%2The composite particles and the stone plastic floor have better toughening effect, and simultaneously the impact resistance effect, the impact strength, the static bending strength, the elongation at break displacement and the warping degree of the stone plastic floor reach the optimal value of the comprehensive performance of product design.
In some embodiments, ACR/nano SiO2The ACR grafting ratio on the surface of the composite particle may be 100%. Adopting ACR/nano SiO with 100 percent of surface ACR grafting rate2The composite particle and the stone plastic floor have the best toughening effect.
In some casesIn the examples, ACR/nano SiO2The ACR grafting ratio on the surface of the composite particle may be 110%. Adopting ACR/nano SiO with the surface ACR grafting rate of 110%2The composite particles and the stone plastic floor also have better toughening effect.
As previously mentioned, the stabilizing layer and the stone-plastic rigid layer may be composed of multiple components, and may contain polyvinyl chloride in addition to the aforementioned ACR/nano SiO2 composite particles. In some embodiments, the stone-plastic rigid layer may comprise polyvinyl chloride. At least one of the first and second stabilizing layers may comprise polyvinyl chloride.
In some embodiments, the polyvinyl chloride mass content in the rigid stone-plastic layer can be 18-21%. In some embodiments, at least one of the first and second stabilizing layers may have a polyvinyl chloride content of 25 to 30% by mass. In some embodiments, ACR/nano SiO2The dosage of the composite particles is 10-15% of the mass content of the polyvinyl chloride in the corresponding layer. For example, ACR/nano SiO in a rigid layer of stone2The composite particles account for 10-15% of the mass content of the polyvinyl chloride in the stone-plastic rigid layer.
In some embodiments, the polyvinyl chloride mass content of the rigid layer of stone may be 18%. At least one of the first and second stabilizing layers may have a polyvinyl chloride content of 25% by mass. In some embodiments, the ACR/nano SiO2 composite particles may be used in an amount of 10% by mass of the polyvinyl chloride content in the corresponding layer.
In some embodiments, the polyvinyl chloride mass content of the rigid layer of stone may be 19.5%. At least one of the first and second stabilizing layers may have a polyvinyl chloride content of 27% by mass. In some embodiments, ACR/nano SiO2The amount of the composite particles may be 12.5% by mass of the polyvinyl chloride in the corresponding layer.
In some embodiments, the polyvinyl chloride mass content of the rigid layer of stone may be 20%. At least one of the first and second stabilizing layers may have a polyvinyl chloride content of 28% by mass. In some embodiments, ACR/nano SiO2The amount of the composite particles may be 13% by mass of the polyvinyl chloride in the corresponding layer.
In some embodiments, the polyvinyl chloride mass content of the rigid layer of stone may be 21%. At least one of the first and second stabilizing layers may have a polyvinyl chloride content of 30% by mass. In some embodiments, ACR/nano SiO2The amount of composite particles may be 15% of the mass content of polyvinyl chloride in the respective layer.
In some embodiments, the stone-plastic rigid layer may include, based on 526.8 parts by weight of the stone-plastic rigid layer: 10-15 parts by weight of ACR/nano SiO2Composite particles. For example, ACR/nano SiO based on 526.8 parts by weight of the stone-plastic rigid layer2The composite particle content may be 12.5 parts by weight.
ACR/nano SiO2The composite particles have different component contents, and have different influences on the performance detection result of the multilayer co-extrusion stone-plastic floor. Specifically, the specific influence on the performance test result can be embodied by the following set of experiments.
In this group of experiment, all set up first stable layer, the second stable layer component of multilayer coextrusion stone plastic floor into: 100 parts by weight of polyvinyl chloride, 270 parts by weight of inorganic filler, 1.5 parts by weight of polyethylene wax, 10 parts by weight of stabilizer, 1.4 parts by weight of stearic acid, 0.6 part by weight of oxidized polyethylene wax, 15 parts by weight of ACR/nano SiO2 composite particles, and 0.5 part by weight of carbon black; the stone-plastic rigid layer of the multilayer co-extrusion stone-plastic floor is set as follows: 100 parts by weight of polyvinyl chloride, 360 parts by weight of inorganic filler, 1.2 parts by weight of polyethylene wax, 5 parts by weight of stabilizer, 1.0 part by weight of stearic acid, 10 parts by weight of glass beads, ACR/nano SiO2The composite particle content was used as a variable.
The test results include: impact strength, static bending strength, thermal deformation vicat, and thermal warpage. Wherein, the impact strength is the energy absorbed by the unit cross-sectional area when the test piece is broken or fractured under the action of the impact load. The static bending strength is the pressure strength that the test piece is subjected to when being bent to break under stress. The heat-deformable Vicat is prepared by placing a sample in a liquid heat-transfer medium, and heating at a constant load and constant speed by 1mm2The pressing pin of (1) is pressed into the mold at a depth of 1 mm. The degree of warping by heating refers to the objectWhen the surface was restored to 23. + -. 2 ℃ after heating at 80 ℃ for 6 hours, the surface of the object was distorted.
The test results were as follows:
(1) stone-plastic rigid layer ACR/nano SiO2When the content of the composite particles is 0 part, the impact strength is 2.0KJ/m2(ii) a The static bending strength is 20 MPa; the thermal deformation Vicat is 45 ℃; the heating warpage is 1.5 mm;
(2) stone-plastic rigid layer ACR/nano SiO2When the content of the composite particles is 10 parts, the impact strength is 13.0KJ/m2(ii) a The static bending strength is 32 MPa; the thermal deformation Vicat is 65 ℃; the heating warpage is 0.3 mm;
(3) stone-plastic rigid layer ACR/nano SiO2When the content of the composite particles is 12.5 parts, the impact strength is 13.2KJ/m2(ii) a The static bending strength is 32 MPa; the thermal deformation Vicat is 65 ℃; the heating warpage is 0.28 mm;
(4) stone-plastic rigid layer ACR/nano SiO2When the content of the composite particles is 15 parts, the impact strength is 13.5KJ/m2(ii) a The static bending strength is 32 MPa; the thermal deformation Vicat is 65 ℃; the heating warpage is 0.3 mm;
(5) stone-plastic rigid layer ACR/nano SiO2When the content of the composite particles is 20 parts, the impact strength is 12.5KJ/m2(ii) a The static bending strength is 30 MPa; the thermal deformation Vicat is 65 ℃; the warpage by heating was 0.70 mm.
Experimental data show that under the condition of the same other components, the stone-plastic rigid layer ACR/nano SiO2When the content of the composite particles is 10 parts, 12.5 parts and 15 parts, the stone plastic floor has good impact resistance and thermal stability, and the performance is obviously superior to ACR/nano SiO2When the content of the composite particles is 0 part. It can be understood that when the stone plastic rigid layer adopts 10-15 parts by weight of ACR/nano SiO2The composite particle and the stone plastic floor have better shock resistance and good thermal stability. These experimental data may be used as a basis for a related embodiment.
In some embodiments, ACR/nano SiO2The composite particles may be present in the rigid layer of the stone-plastic in an amount of 10 parts by weight. When the plastic rigid layer contains 10 parts by weight of ACR/nano SiO2The composite particle and stone plastic floor has better shock resistance and heat resistanceAnd (4) stability.
In some embodiments, ACR/nano SiO2The composite particles may be present in the rigid layer of the stone-plastic in an amount of 12.5 parts by weight. When the plastic rigid layer contains 12.5 weight parts of ACR/nano SiO2The composite particle and the stone plastic floor have better shock resistance and thermal stability.
In some embodiments, ACR/nano SiO2The composite particles may be present in the rigid layer of the stone-plastic in an amount of 13 parts by weight. When the plastic rigid layer contains 13 parts by weight of ACR/nano SiO2The composite particle and the stone plastic floor have the best impact resistance and thermal stability.
In some embodiments, ACR/nano SiO2The composite particles may be present in the rigid layer of the stone-plastic in an amount of 15 parts by weight. When the plastic rigid layer contains 15 weight parts of ACR/nano SiO2The composite particle and the stone plastic floor have better shock resistance and thermal stability.
In some embodiments, the stone rigid layer may further comprise glass beads. Glass beads are understood to be hollow glass spheres of a small size. The density of the glass beads may be 0.50 to 0.70g/cm3The particle size may be between 45 and 55 μm.
In some embodiments, the glass microspheres may be modified hollow glass microspheres. The modified hollow glass bead refers to a hollow glass bead with changed performance. The change in performance may include: the surface has varying oleophilic properties, different states (e.g., dispersibility or flowability in the molten state, etc.). In some embodiments, the glass microspheres may be present in an amount of 10-15% by mass of the polyvinyl chloride in the rigid layer of stone. For example, the glass microspheres may be present in an amount of 10% by mass of the polyvinyl chloride in the rigid layer of stone. For another example, the glass microspheres may be present in an amount of 12.5% by mass of the polyvinyl chloride in the rigid layer of stone. For another example, the glass microspheres may be present in an amount of 14% by mass of the polyvinyl chloride in the rigid layer of stone. For another example, the glass microspheres may be present in an amount of 15% by mass of the polyvinyl chloride in the rigid layer of stone.
The glass beads are added into the polyvinyl chloride which is the component of the stone-plastic rigid layer, so that the material processing flowability can be improved, the strength, the creep resistance and the heat resistance stability of the rigid stone-plastic layer of the floor can be effectively improved, and the floor is not easy to deform in the use process.
In some embodiments, the composition of the stone rigid layer comprises 10-15 parts by weight of glass microspheres based on 526.8 parts by weight of the stone rigid layer. For example, the glass bead content may be 12.5 parts by weight based on 526.8 parts by weight of the stone rigid layer.
The glass beads have different component contents, and have different influences on the performance detection result of the multilayer co-extrusion stone-plastic floor. Specifically, the specific influence on the performance test result can be embodied by the following set of experiments.
In this group of experiments, set up first stabilizer layer, the second stabilizer layer on multilayer crowded stone altogether and mould floor into: 100 parts by weight of polyvinyl chloride, 270 parts by weight of inorganic filler, 1.5 parts by weight of polyethylene wax, 10 parts by weight of stabilizer, 1.4 parts by weight of stearic acid, 0.6 part by weight of oxidized polyethylene wax, 15 parts by weight of ACR/nano SiO2 composite particles, and 0.5 part by weight of carbon black; the stone-plastic rigid layer of the multilayer co-extrusion stone-plastic floor is set as follows: 100 parts by weight of polyvinyl chloride, 360 parts by weight of inorganic filler, 1.2 parts by weight of polyethylene wax, 5 parts by weight of stabilizer, 1.0 part by weight of stearic acid, 10 parts by weight of ACR/nano SiO2The content of the composite particles and the content of the glass beads are used as variables.
The test results include: static bending strength, elongation at break displacement, heating warpage, heating dimensional change rate, and thermal deformation vicat. The breaking elongation displacement refers to the displacement that an object passes through when the object is broken by pressure. The heating dimension change rate is how much the dimension of the object changes when the object is restored to 23 ± 2 ℃ after being heated at 80 ℃ for 6 hours.
The test results were as follows:
(1) when the content of the glass beads in the stone-plastic rigid layer is 0 part, the static bending strength is 20 MPa; elongation displacement at break of 14 mm; the heating warpage is 1.2 mm; the heating size change rate is 0.190%; the thermal deformation Vicat is 45 ℃;
(2) when the content of the glass beads in the stone-plastic rigid layer is 10 parts, the static bending strength is 32 MPa; elongation displacement at break of 12 mm; the heating warpage is 0.25 mm; the heating size change rate is 0.050%; the thermal deformation Vicat is 65 ℃;
(3) when the content of the glass beads in the stone-plastic rigid layer is 12.5 parts, the static bending strength is 32.5 MPa; elongation displacement at break of 11 mm; the heating warpage is 0.35 mm; the heating dimensional change rate is 0.060%; the thermal deformation Vicat is 65 ℃;
(4) when the content of the glass beads in the stone-plastic rigid layer is 15 parts, the static bending strength is 34 MPa; elongation displacement at break of 10 mm; the heating warpage is 0.35 mm; the heating size change rate was 0.055%; the thermal deformation Vicat is 65 ℃;
(5) when the content of the glass beads in the stone-plastic rigid layer is 20 parts, the static bending strength is 36 MPa; elongation displacement at break of 4 mm; the heating warpage is 0.80 mm; the heating size change rate is 0.220%; the heat distortion vicat was 55 ℃.
Experimental data show that under the condition that other components are the same, when the content of the glass beads in the stone-plastic rigid layer is 10 parts, 12.5 parts and 15 parts, the stone-plastic floor is good in impact resistance and thermal stability, and the performance is obviously superior to that when the content of the glass beads is 0 part. As can be understood, the components of the stone-plastic rigid layer adopt 10-15 parts by weight of glass beads, and the stone-plastic floor has good impact resistance and thermal stability. These experimental data may be used as a basis for a related embodiment.
In some embodiments, the glass microspheres may be present in the rigid layer of stone in an amount of 10 parts by weight. When the stone-plastic rigid layer contains 10 parts by weight of glass beads, the stone-plastic floor has better impact resistance and thermal stability.
In some embodiments, the glass microspheres may be present in the rigid layer of stone in an amount of 12.5 parts by weight. When the rigid layer of the stone plastic contains 12.5 weight parts of glass beads, the stone plastic floor has better impact resistance and thermal stability.
In some embodiments, the glass microspheres may be present in the rigid layer of stone in an amount of 14 parts by weight. When the stone-plastic rigid layer contains 14 parts by weight of glass beads, the stone-plastic floor has better impact resistance and thermal stability.
In some embodiments, the glass microspheres may be present in the rigid layer of stone in an amount of 15 parts by weight. When the stone-plastic rigid layer contains 15 parts by weight of glass beads, the stone-plastic floor has better impact resistance and thermal stability.
In some embodiments, other components may also be included in the stabilizing layer and the stone-plastic rigid layer. For example, the ingredients of the rigid layer of stone-plastic may comprise, in addition to polyvinyl chloride, inorganic fillers, polyethylene waxes, stabilizers, stearic acid or other additives, etc., such as colorants, plasticizers, etc. For another example, the stabilizing layer (the first stabilizing layer and/or the second stabilizing layer) may contain an inorganic filler, polyethylene wax, a stabilizer, stearic acid, oxidized polyethylene wax, carbon black, or other additives, in addition to polyvinyl chloride.
In some embodiments, the proportion of the other components of the stabilizing layer and the stone-plastic rigid layer can be selected according to different conditions. For example, based on 353.5 parts by weight of the stabilizer layer the first stabilizer layer and/or the second stabilizer layer, the composition of the stabilizer layer may include 100 parts by weight of polyvinyl chloride, 12.5 parts by weight of ACR/nano SiO2 composite particles, and at least one of the following: 240 parts by weight of inorganic filler, 1.2 parts by weight of polyethylene wax, 8 parts by weight of stabilizer, 1.1 parts by weight of stearic acid, 0.4 parts by weight of oxidized polyethylene wax, 0.3 parts by weight of carbon black. For another example, the composition of the rigid layer further comprises 100 parts by weight of polyvinyl chloride and at least one of the following based on 526.8 parts by weight of the rigid layer: 392.5 parts by weight of inorganic filler, 1.5 parts by weight of polyethylene wax, 6.5 parts by weight of stabilizer, 1.3 parts by weight of stearic acid.
The stabilizer is an agent for keeping the structure of the polymer compound stable. For example, the stabilizer may be calcium stearate, dibasic lead salt, or the like.
Inorganic fillers are understood to mean added inorganic fillers. The inorganic filler may include silicate-based inorganic fillers, carbonate-based inorganic fillers, and sulfate-based inorganic fillers. For example, the silicate-based inorganic filler may be china clay, mica powder, talc powder, feldspar powder, or the like. The carbonate inorganic filler can be heavy calcium carbonate, light calcium carbonate, superfine calcium carbonate and the like. The sulfate inorganic filler can be barium sulfate, lithopone and the like.
The first stable layer has different component contents, and has different influences on the performance detection result of the multilayer co-extrusion stone-plastic floor. Specifically, the specific influence on the performance test result can be embodied by the following set of experiments.
The thickness of the wear-resistant layer is 0.3mm in the following tests, the thickness of the co-extrusion stone plastic layer is 3.7mm, wherein the first stable layer is 0.95mm, the rigid layer is 1.8mm, the second stable layer is 0.95mm, and the stone plastic rigid layer of the multi-layer co-extrusion stone plastic floor comprises the following components: 100 parts by weight of polyvinyl chloride, 360 parts by weight of inorganic filler, 1.2 parts by weight of polyethylene wax, 5 parts by weight of stabilizer, 1.0 part by weight of stearic acid, 10 parts by weight of ACR/nano SiO2Composite particles, 10 parts by weight of glass beads. The first stabilizer layer composition is set differently.
The test results include: normal temperature warping, heating dimensional change rate, and low temperature dimensional change rate. The normal temperature warpage is the degree of distortion of the surface of an object at 25 ℃. The low-temperature dimensional change rate refers to the degree of dimensional change of an object when the object is cooled to-18 ℃ for 6 hours and then returns to 23 +/-2 ℃.
The test results were as follows:
(1) the stabilizing layer comprises the following components: 100 parts by weight of polyvinyl chloride, 270 parts by weight of inorganic filler, 1.5 parts by weight of polyethylene wax, 10 parts by weight of stabilizer, 1.4 parts by weight of stearic acid, 0.6 part by weight of oxidized polyethylene wax, 15 parts by weight of ACR/nano SiO2When the composite particles and 0.5 part by weight of carbon black are used, the normal-temperature warpage is 0.20mm, the heating warpage is 0.25mm, the heating dimensional change rate is 0.05%, and the low-temperature dimensional change rate is 0.06%;
(2) the stabilizing layer comprises the following components: 100 parts by weight of polyvinyl chloride, 240 parts by weight of inorganic filler, 1.2 parts by weight of polyethylene wax, 7.5 parts by weight of stabilizer, 1.1 parts by weight of stearic acid, 0.4 parts by weight of oxidized polyethylene wax, 12.5 parts by weight of ACR/nano SiO2When the composite particles and 12.5 parts by weight of carbon black are used, the normal-temperature warpage is 0.30mm, the heating warpage is 0.50mm, the heating dimensional change rate is 0.08%, and the low-temperature dimensional change rate is 0.09%;
(3) the stabilizing layer comprises the following components: 100 parts by weight of polyvinyl chloride, 210 parts by weight of inorganic filler, 0.9 part by weight of polyethylene wax, 6 parts by weight of stabilizer, 0.8 part by weight of stearic acid, 0.2 part by weight of oxidized polyethylene wax, 10 parts by weight of ACR/nano SiO2When the composite particles and 0.5 part by weight of carbon black are used, the normal-temperature warping is 0.35mm, the heating warping is 0.60mm, the heating dimensional change rate is 0.075%, and the low-temperature dimensional change rate is 0.10%;
(4) the stabilizing layer comprises the following components: 100 parts by weight of polyvinyl chloride, 180 parts by weight of inorganic filler, 0.9 part by weight of polyethylene wax, 6 parts by weight of stabilizer, 0.8 part by weight of stearic acid, 0.2 part by weight of oxidized polyethylene wax, 10 parts by weight of ACR/nano SiO2When the composite particles and 0.5 part by weight of carbon black are used, the normal-temperature warpage is 0.75mm, the heating warpage is 0.90mm, the heating dimensional change rate is 0.18%, and the low-temperature dimensional change rate is 0.20%;
(5) the stabilizing layer comprises the following components: 100 parts by weight of polyvinyl chloride, 300 parts by weight of inorganic filler, 1.5 parts by weight of polyethylene wax, 10 parts by weight of stabilizer, 1.4 parts by weight of stearic acid, 0.6 part by weight of oxidized polyethylene wax, 15 parts by weight of ACR/nano SiO2When the composite particles and 0.5 part by weight of carbon black were used, the normal-temperature warpage was 0.65mm, the heating warpage was 1.50mm, the heating dimensional change rate was 0.13%, and the low-temperature dimensional change rate was 0.15%.
The experimental data show that, in the case of the same thickness of the layers and the same composition of the rigid layer of stone-plastic, 100 parts by weight of polyvinyl chloride, 270 parts by weight of inorganic filler, 1.5 parts by weight of polyethylene wax, 10 parts by weight of stabilizer, 1.4 parts by weight of stearic acid, 0.6 part by weight of oxidized polyethylene wax, 15 parts by weight of ACR/nano-SiO2The composite particles and 0.5 weight part of carbon black have better deformation resistance and thermal stability.
It is understood that the first stabilizer layer comprises the following components, based on 363.5 parts by weight of the first stabilizer layer: 100 parts of polyvinyl chloride, 210-270 parts of inorganic filler, 0.9-1.5 parts of polyethylene wax, 6-10 parts of stabilizer, 0.8-1.4 parts of stearic acid, 0.2-0.6 part of oxidized polyethylene wax, 10-15 parts of ACR/nano SiO2 composite particles and 0.1-0.5 part of carbon black, and the floor has better deformation resistance and thermal stability. These experimental data may be used as a basis for a related embodiment.
In some embodiments, the first stabilizing layer comprises the following components, based on 363.5 parts by weight of the first stabilizing layer: 100 parts of polyvinyl chloride, 210-270 parts of inorganic filler, 0.9-1.5 parts of polyethylene wax, 6-10 parts of stabilizer, 0.8-1.4 parts of stearic acid, 0.2-0.6 part of oxidized polyethylene wax, 10-15 parts of ACR/nano SiO2 composite particles and 0.1-0.5 part of carbon black.
In some embodiments, the first stabilizing layer may comprise the following components, based on 363.5 parts by weight of the first stabilizing layer: 100 parts by weight of polyvinyl chloride, 210 parts by weight of inorganic filler, 0.9 part by weight of polyethylene wax, 6 parts by weight of stabilizer, 0.8 part by weight of stearic acid, 0.2 part by weight of oxidized polyethylene wax, 10 parts by weight of ACR/nano SiO2 composite particles, and 0.1 part by weight of carbon black. The arrangement of the component proportion in the first stable layer has better deformation resistance and thermal stability.
In some embodiments, the first stabilizing layer may comprise the following components, based on 363.5 parts by weight of the first stabilizing layer: 100 parts by weight of polyvinyl chloride, 240 parts by weight of inorganic filler, 1.2 parts by weight of polyethylene wax, 8 parts by weight of stabilizer, 1.1 parts by weight of stearic acid, 0.4 part by weight of oxidized polyethylene wax, 12.5 parts by weight of ACR/nano SiO2Composite particles, 0.3 parts by weight of carbon black. The arrangement of the component proportion in the first stable layer has better deformation resistance and thermal stability.
In some embodiments, the first stabilizing layer may comprise the following components, based on 363.5 parts by weight of the first stabilizing layer: 100 parts by weight of polyvinyl chloride, 270 parts by weight of inorganic filler, 1.5 parts by weight of polyethylene wax, 10 parts by weight of stabilizer, 1.4 parts by weight of stearic acid, 0.6 part by weight of oxidized polyethylene wax, 15 parts by weight of ACR/nano SiO2Composite particles, 0.5 parts by weight of carbon black. The arrangement of the component proportion in the first stable layer has better deformation resistance and thermal stability.
In some embodiments, the thickness of the first stabilizing layer may range from 0.55mm to 1.15mm, the thickness of the stone-plastic rigid layer may range from 1.8mm to 2.2mm, and the thickness of the first stabilizing layer may range from 0.55mm to 1.15 mm.
In some embodiments, the ratio of the thickness of the stabilizing layer (first stabilizing layer or second stabilizing layer) to the thickness of the stone-plastic rigid layer can be 1: 1.8-2.2. In some embodiments, the first stabilizing layer, the second stabilizing layer, and the stone-plastic rigid layer may be the same or different in thickness between each other. For example, the thickness ratio of the first stabilizing layer, the stone-plastic rigid layer and the second stabilizing layer can be 1: 1.8-2.2: 1.
The thickness of the first stabilizing layer is different, and different influences can be caused on the performance detection result of the multilayer co-extrusion stone plastic floor. Specifically, the specific influence on the performance test result can be embodied by the following set of experiments.
In this set of experiments, the first and second stabilizer layer compositions were set as: 100 parts by weight of polyvinyl chloride, 270 parts by weight of inorganic filler, 1.5 parts by weight of polyethylene wax, 10 parts by weight of stabilizer, 1.4 parts by weight of stearic acid, 0.6 part by weight of oxidized polyethylene wax, 15 parts by weight of ACR/nano SiO2Composite particles, 0.5 parts by weight of carbon black; the stone-plastic rigid layer comprises the following components: 100 parts by weight of polyvinyl chloride, 360 parts by weight of inorganic filler, 1.2 parts by weight of polyethylene wax, 5 parts by weight of stabilizer, 1.0 part by weight of stearic acid, 10 parts by weight of ACR/nano SiO2Composite particles, 10 parts by weight of glass beads. The first stabilizing layers with different thicknesses are adopted in different experimental examples, and the performance of the floor in the aspects of normal-temperature warping, heating size change rate and low-temperature size change rate is tested.
The test results were as follows:
(1) the thickness of the wear-resistant layer is 0.3mm, the thickness of the co-extrusion stone plastic layer is 3.7mm, the thickness of the first stable layer is 0.95mm, the thickness of the rigid layer is 1.8mm, the thickness of the second stable layer is 0.95mm, and the test result is as follows: the normal temperature warping degree is 0.20 mm; the heating warping degree is 0.25 mm; the heating size change rate at 80 ℃ is 0.05 percent; the dimensional change rate at the low temperature of 18 ℃ below zero is 0.06 percent;
(2) the thickness of the wear-resistant layer is 0.3mm, the thickness of the co-extrusion base material is 3.7mm, the thickness of the first stable layer is 0.75mm, the thickness of the rigid layer is 2.0mm, the thickness of the second stable layer is 0.95mm, and the test result is as follows: the normal temperature warping degree is 0.70 mm; the heating warping degree is 0.70 mm; the heating size change rate at 80 ℃ is 0.12 percent; the dimensional change rate at the low temperature of 18 ℃ below zero is 0.20 percent;
(3) the thickness of the wear-resistant layer is 0.3mm, the thickness of the co-extrusion stone plastic layer is 3.7mm, the thickness of the first stable layer is 0.55mm, the thickness of the rigid layer is 2.2mm, the thickness of the second stable layer is 0.95mm, and the test result is as follows: the normal temperature warping degree is 0.85 mm; the heating warping degree is 0.70 mm; the heating size change rate at 80 ℃ is 0.25%; the dimensional change rate at the low temperature of 18 ℃ below zero is 0.22 percent;
(4) the thickness of the wear-resistant layer is 0.3mm, the thickness of the co-extrusion stone plastic layer is 3.7mm, the thickness of the first stable layer is 1.15mm, the thickness of the rigid layer is 1.8mm, the thickness of the second stable layer is 0.75mm, and the test result is as follows: the normal temperature warping degree is 1.0 mm; the heating warping degree is 1.2 mm; the heating size change rate at 80 ℃ is 0.30 percent; the dimensional change rate at a low temperature of-18 ℃ is 0.18 percent.
Experimental data show that under the conditions that the components of the stabilizing layer and the rigid layer are as above and the thickness of the second stabilizing layer is constant, the stone plastic floor has better heat resistance and stability when the thickness of the first stabilizing layer is 0.95mm, and is obviously superior to the cases that the thicknesses of the first stabilizing layer and the rigid layer are 0.75mm, 0.55mm and 1.15 mm. Such data may be used as a basis for a related embodiment.
In some embodiments, the thickness ratio of the first stabilizing layer to the stone-plastic rigid layer may be 1: 1.8. The stone plastic floor with the thickness has good heat resistance and stability.
In some embodiments, the thickness ratio of the first stabilizing layer to the stone-plastic rigid layer may be 1: 1.9. The stone plastic floor with the thickness has good heat resistance and stability.
In some embodiments, the thickness ratio of the first stabilizing layer to the stone-plastic rigid layer may be 1: 2.0. Through the arrangement of the thickness ratio, the plastic floor has better heat resistance and stability.
In some embodiments, the thickness ratio of the first stabilizing layer to the stone-plastic rigid layer may be 1: 2.2. The stone plastic floor with the thickness has good heat resistance and stability.
The thickness of the second stabilizing layer is different, and different influences can be caused on the performance detection result of the multilayer co-extrusion stone plastic floor. Specifically, the specific influence on the performance test result can be embodied by the following set of experiments.
In this set of experiments, the first and second stabilizer layer compositions were set as: 100 parts by weight of polyvinyl chloride, 270 parts by weight of inorganic filler, 1.5 parts by weight of polyethylene wax, 10 parts by weight of stabilizer, 1.4 parts by weight of stearic acid, 0.6 part by weight of oxidized polyethylene wax, 15 parts by weight of ACR/nano SiO2Composite particles, 0.5 parts by weight of carbon black; the stone-plastic rigid layer comprises the following components: 100 parts by weight of polyvinyl chloride, 360 parts by weight of inorganic filler, 1.2 parts by weight of polyethylene wax, 5 parts by weight of stabilizer, 1.0 part by weight of stearic acid, 10 parts by weight of ACR/nano SiO2Composite particles, 10 parts by weight of glass beads. And adopting second stabilizing layers with different thicknesses in different experimental examples to test the performances of the floor in the aspects of normal-temperature warping, heating size change rate and low-temperature size change rate.
The test results were as follows:
(1) the thickness of the wear-resistant layer is 0.3mm, the thickness of the co-extrusion stone plastic layer is 3.7mm, wherein the first stable layer is 0.95mm, the rigid layer is 1.8mm, the second stable layer is 0.95mm, and the test result is as follows: the normal temperature warping degree is 0.20 mm; the heating warping degree is 0.25 mm; the heating size change rate at 80 ℃ is 0.05 percent; the dimensional change rate at the low temperature of 18 ℃ below zero is 0.06 percent;
(2) the thickness of the wear-resistant layer is 0.3mm, the thickness of the co-extrusion stone plastic layer is 3.7mm, wherein the first stable layer is 0.95mm, the rigid layer is 2.0mm, the second stable layer is 0.75mm, and the test result is as follows: the normal temperature warping degree is 1.20 mm; the heating warping degree is 1.0 mm; the heating size change rate at 80 ℃ is 0.18 percent; the dimensional change rate at the low temperature of 18 ℃ below zero is 0.23 percent;
(3) the thickness of the wear-resistant layer is 0.3mm, the thickness of the co-extrusion stone plastic layer is 3.7mm, wherein the first stable layer is 0.95mm, the rigid layer is 2.2mm, the second stable layer is 0.55mm, and the test result is as follows: the normal temperature warping degree is 2.0 mm; the heating warping degree is 2.5 mm; the heating size change rate at 80 ℃ is 0.25%; the dimensional change rate at the low temperature of 18 ℃ below zero is 0.35 percent;
(4) the thickness of the wear-resistant layer is 0.3mm, the thickness of the co-extrusion stone plastic layer is 3.7mm, wherein the first stable layer is 0.75mm, the rigid layer is 1.8mm, the second stable layer is 1.15mm, and the test result is as follows: the normal temperature warping degree is 0.80 mm; the heating warping degree is 0.70 mm; the heating size change rate at 80 ℃ is 0.20 percent; the dimensional change rate at a low temperature of-18 ℃ is 0.25%.
Experimental data show that under the conditions that the components of the stabilizing layer and the rigid layer are as above and the thickness of the first stabilizing layer is constant, and the thickness of the second stabilizing layer is 0.95mm, the stone-plastic floor has better heat resistance and stability, and is obviously superior to the cases that the thicknesses of the stabilizing layer and the rigid layer are 0.75mm, 0.55mm and 1.15 mm. Such data may be used as a basis for a related embodiment.
In some embodiments, the thickness ratio of the second stabilizing layer to the stone-plastic rigid layer may be 1: 1.8. The stone plastic floor with the thickness has good heat resistance and stability.
In some embodiments, the thickness ratio of the second stabilizing layer to the stone-plastic rigid layer may be 1: 1.9. The stone plastic floor with the thickness has good heat resistance and stability.
In some embodiments, the thickness ratio of the second stabilizing layer to the stone-plastic rigid layer may be 1: 2.0. The stone plastic floor with the thickness has good heat resistance and stability.
In some embodiments, the thickness ratio of the second stabilizing layer to the stone-plastic rigid layer may be 1: 2.2. The stone plastic floor with the thickness has good heat resistance and stability.
In conclusion, the size change rate of the first stabilizing layer and the second stabilizing layer at-15-80 ℃ is 0-0.12% only when the thickness ratio of the first stabilizing layer to the stone-plastic rigid layer to the second stabilizing layer is 1: 1.8-2.2: 1, so that the stone-plastic floor has better heat resistance and stability. If the thickness ratio of the first stabilizing layer to the stone-plastic rigid layer to the second stabilizing layer is not 1: 1.8-2.2: 1, the dimensional change rate of the first stabilizing layer to the second stabilizing layer is more than 0-0.12% at-15-80 ℃, and the heat resistance and the stability of the stone-plastic floor are poor.
FIG. 2 is a cross-sectional view of a multi-layer co-extruded stone floor according to some embodiments of the present description.
In some embodiments, the multi-layer coextruded stone floor includes a coextruded stone layer 100, a UV coating 210, a wear layer 220, and a color film layer 230.
The UV coating 210 may be a polyurethane UV curable coating layer coated on the surface. In some embodiments, the UV coating has abrasion, stain, water and moisture resistant effects.
The wear layer 220 may be a structural layer that slows down mechanical wear.
In some embodiments, the thickness of the wear layer affects the thickness of the first and second stabilizing layers. Specifically, when the thickness of the wear-resistant layer is larger, the strength provided by the rigid structural layer is required to be larger, and the thicknesses of the first stabilizing layer and the second stabilizing layer are larger. For example, under the condition that the total thickness of the multilayer co-extrusion stone-plastic floor is constant, when the thickness of the wear-resistant layer is 0.3mm, the thickness ratio of the first stabilizing layer to the stone-plastic rigid layer to the second stabilizing layer can be 1:2.2: 1; when the thickness of the wear-resistant layer is 0.40mm, the thickness ratio of the first stabilizing layer to the stone-plastic rigid layer to the second stabilizing layer can be 1:2.0: 1.
The color film layer 230 may be a decorative layer structure layer in the floor structure, and may provide effects of color, pattern, etc.
In some embodiments, adjacent two of the UV coating, the abrasion resistant layer, and the color film layer may be connected by various means. For example by means of an adhesive. For example, the bonding is performed by thermal compression bonding. It will be appreciated that the manner of connection between different adjacent layers may be the same or different.
FIG. 3 is a flow chart of a method of manufacturing a multi-layer co-extruded stone floor according to some embodiments of the present disclosure.
Step 301, mixing the materials of at least one of the first stabilizing layer and the second stabilizing layer to obtain a first mixed material, and stirring the first mixed material to obtain a first ingredient.
For the definition of the first and second stabilizer layers, reference may be made to the description of fig. 1. The material of the first stabilizer layer is the raw material required for producing the first stabilizer layer. For the material of the first stable layer, see the description of fig. 1. The material of the second stabilizer layer is the raw material required for producing the second stabilizer layer. For the material of the second stable layer, see the description of fig. 1. The first mixed material refers to a substance obtained by mixing the components in the first stabilizing layer or the second stabilizing layer according to the proportion in fig. 1. The first ingredient is a substance obtained by processing the first mixed material. The processing treatment process can comprise one or more of stirring and heating operation, cooling operation and the like.
In some embodiments, the first blend may include ACR/nano SiO2 composite particles. For the definition of ACR/nano SiO2 composite particles, reference can be made to the description of fig. 1.
In some embodiments, the materials of at least one of the first stable layer and the second stable layer can be fed into a high-speed mixer through an automatic metering system, stirred and heated to 110-125 ℃, then fed into a low-speed mixer, cooled to 45-60 ℃, and then placed into a discharge tank to obtain the first ingredient.
The automatic metering system may be a digital system for quantitatively proportioning various materials.
The high-speed stirrer can be a stirrer with a self-friction heating or a built-in heating device, and the rotating speed of the stirrer is 860-1500 r/min.
The low-speed stirrer can be a stirrer with a built-in heat dissipation device and the rotating speed of 325r/min-650 r/min. The discharge tank may be a tank for collecting the stirred material.
And 302, mixing the materials of the stone-plastic rigid layer to obtain a second mixed material, and stirring the second mixed material to obtain a second ingredient.
For the definition of the rigid layer of stone, reference is made to the description of fig. 1. The material of the rigid layer of the stone plastic is raw material required for manufacturing the rigid layer of the stone plastic. For the material of the rigid stone layer, reference is made to the description of fig. 1. The second blend is the mixture of the ingredients of the rigid stone-plastic layer in the proportions shown in figure 1. The second ingredient is a substance obtained by processing the second mixed material. The processing procedure may include one or more of stirring and heating operation, cooling operation, etc.
In some embodiments, the second composition can include ACR/nano SiO2Composite particles. About ACR/nano SiO2The definition of the composite particles can be seen in the description of fig. 1.
In some embodiments, the material of the stone-plastic rigid layer can enter a high-speed mixer through an automatic metering system, the temperature is raised to 110-125 ℃ by stirring, the material is sent into a low-speed mixer to be cooled to 45-60 ℃, and then the cooled material is placed into a discharge tank to obtain a second ingredient.
In some embodiments, the material of the rigid stone-plastic layer can be fed into a high-speed mixer through an automatic metering system, and after the temperature is raised to 115 ℃ by stirring, the material is fed into a low-speed mixer to be cooled to 55 ℃, and then is placed into a discharge tank, so as to obtain a second ingredient.
For the definition of the automatic metering system, high speed mixer, low speed mixer, discharge tank, see the description of step 301.
And 303, extruding the first mixed material and the second mixed material through an extruder to form a co-extrusion stone plastic layer.
For the definition of the coextruded stone layer reference is made to the description of fig. 1. The extruder is a device for forming a plastic material in a viscous flow state after heating into a mold body having a cross section similar to the shape of a mold by passing the plastic material through an extrusion mold. The viscous flow state refers to the mechanical state of the amorphous high molecular polymer under the action of higher temperature and larger external force for a long time. In some embodiments, the extruder may include a non-co-extruder and a co-extruder. The non-co-extrusion extruder may include a main extruder and a die having a cross-sectional shaped passageway. The co-extrusion extruder can comprise a main extruder, an auxiliary extruder, a blanking device, a PLC control system, a distributor and a die with a channel with a certain cross section shape, wherein the blanking device is arranged on the main extruder, the main extruder is connected with the distributor through a confluence core channel, the auxiliary extruder is connected with the distributor through a confluence core channel, the distributor is connected with the die, and the PLC control system is used for controlling the running of the extruder and the matched equipment. The co-extrusion extruder adopted in the embodiments of the present description is an existing co-extrusion extruder on the market, and is not described herein again.
In some embodiments, the manufacturing method of extruding the co-extruded stone-plastic layer through the extruder may be: putting the first mixed material into a main extruder and an auxiliary extruder on a co-extrusion extruder, plasticizing and extruding the first mixed material to an upper flow passage and a lower flow passage of a distributor; then putting the second mixed material into another extruder, extruding the stone-plastic rigid layer to a middle runner of a distributor so as to form a multilayer structure in the distributor, and then entering a die; and finally, in a mould, carrying out extrusion molding to obtain the three-layer co-extrusion stone-plastic layer.
In some embodiments, the co-extruded stone-plastic layer is extruded to enter a calender roll set for calendering and thickness setting, then is attached to the color film and the wear-resistant layer, and the texture is rolled by an embossing roll for one-step forming, so that the stone-plastic floor is obtained. Calender roll stack refers to a device that applies pressure to a material with rolls to create a texture. For example, the set of calender rolls can include four rolls, five rolls, six rolls, or the like. Calendering to determine the thickness refers to determining the final thickness of the substrate after compacting and smoothing the surface of the extruded substrate. The embossing roller is a roller for embossing an uneven pattern on the surface of an object. The definition of the color film layer and the wear-resistant layer can be referred to the related description of fig. 2.
In some embodiments, the material of at least one of the first and second stabilizing layers may comprise 90 to 110 parts by weight of polyvinyl chloride, 10 to 15 parts by weight of ACR/nano SiO2 composite particles, and at least one of the following materials, based on 363.5 parts by weight of the first or second stabilizing layer: 210-270 parts by weight of inorganic filler, 0.9-1.5 parts by weight of polyethylene wax, 6-10 parts by weight of stabilizer, 0.8-1.4 parts by weight of stearic acid, 0.2-0.6 parts by weight of oxidized polyethylene wax and 0.1-0.5 parts by weight of carbon black.
In some embodiments, the material of the stone-plastic rigid layer may include 90-110 parts by weight of polyvinyl chloride, 10-15 parts by weight of ACR/nano SiO2 composite particles, and at least one of the following materials, based on 526.8 parts by weight of the stone-plastic rigid layer: 360-425 parts by weight of inorganic filler, 1.2-1.8 parts by weight of polyethylene wax, 5-8 parts by weight of stabilizer, 1.0-1.6 parts by weight of stearic acid and 10-15 parts by weight of glass beads.
Further details regarding the composition of the first stabilizer layer, the second stabilizer layer, and the stone-plastic rigid layer are described with reference to fig. 1.
In some embodiments, the ACR/nano SiO in the material is2The ACR grafting rate on the surface of the composite particle can be 70-110%. For the definition of the ACR grafting ratio, reference is made to the description of FIG. 1.
In some embodiments, the second blend further comprises polyvinyl chloride. The first blend also includes polyvinyl chloride. ACR/nano SiO2The dosage of the composite particles is 10-15% of the mass content of the polyvinyl chloride in the corresponding mixed material.
In some embodiments, ACR/nano SiO2The amount of the composite particles may be 12.5% of the mass content of polyvinyl chloride in the corresponding compound. About ACR/nano SiO2The amount of composite particles used is a more detailed description of the mass content of polyvinyl chloride in the corresponding mix, as can be seen from the description of fig. 1.
Having thus described the basic concept, it will be apparent to those skilled in the art that the foregoing detailed disclosure is to be regarded as illustrative only and not as limiting the present specification. Various modifications, improvements and adaptations to the present description may occur to those skilled in the art, although not explicitly described herein. Such modifications, improvements and adaptations are proposed in the present specification and thus fall within the spirit and scope of the exemplary embodiments of the present specification.
Also, the description uses specific words to describe embodiments of the description. Reference throughout this specification to "one embodiment," "an embodiment," and/or "some embodiments" means that a particular feature, structure, or characteristic described in connection with at least one embodiment of the specification is included. Therefore, it is emphasized and should be appreciated that two or more references to "an embodiment" or "one embodiment" or "an alternative embodiment" in various places throughout this specification are not necessarily all referring to the same embodiment. Furthermore, some features, structures, or characteristics of one or more embodiments of the specification may be combined as appropriate.
Additionally, the order in which the elements and sequences of the process are recited in the specification, the use of alphanumeric characters, or other designations, is not intended to limit the order in which the processes and methods of the specification occur, unless otherwise specified in the claims. While various presently contemplated embodiments of the invention have been discussed in the foregoing disclosure by way of example, it is to be understood that such detail is solely for that purpose and that the appended claims are not limited to the disclosed embodiments, but, on the contrary, are intended to cover all modifications and equivalent arrangements that are within the spirit and scope of the embodiments herein. For example, although the system components described above may be implemented by hardware devices, they may also be implemented by software-only solutions, such as installing the described system on an existing server or mobile device.
Similarly, it should be noted that in the preceding description of embodiments of the present specification, various features are sometimes grouped together in a single embodiment, figure, or description thereof for the purpose of streamlining the disclosure aiding in the understanding of one or more of the embodiments. This method of disclosure, however, is not intended to imply that more features than are expressly recited in a claim. Indeed, the embodiments may be characterized as having less than all of the features of a single embodiment disclosed above.
Numerals describing the number of components, attributes, etc. are used in some embodiments, it being understood that such numerals used in the description of the embodiments are modified in some instances by the use of the modifier "about", "approximately" or "substantially". Unless otherwise indicated, "about", "approximately" or "substantially" indicates that the number allows a variation of ± 20%. Accordingly, in some embodiments, the numerical parameters used in the specification and claims are approximations that may vary depending upon the desired properties of the individual embodiments. In some embodiments, the numerical parameter should take into account the specified significant digits and employ a general digit preserving approach. Notwithstanding that the numerical ranges and parameters setting forth the broad scope of the range are approximations, in the specific examples, such numerical values are set forth as precisely as possible within the scope of the application.
For each patent, patent application publication, and other material, such as articles, books, specifications, publications, documents, etc., cited in this specification, the entire contents of each are hereby incorporated by reference into this specification. Except where the application history document does not conform to or conflict with the contents of the present specification, it is to be understood that the application history document, as used herein in the present specification or appended claims, is intended to define the broadest scope of the present specification (whether presently or later in the specification) rather than the broadest scope of the present specification. It is to be understood that the descriptions, definitions and/or uses of terms in the accompanying materials of this specification shall control if they are inconsistent or contrary to the descriptions and/or uses of terms in this specification.
Finally, it should be understood that the embodiments described herein are merely illustrative of the principles of the embodiments of the present disclosure. Other variations are also possible within the scope of the present description. Thus, by way of example, and not limitation, alternative configurations of the embodiments of the specification can be considered consistent with the teachings of the specification. Accordingly, the embodiments of the present description are not limited to only those embodiments explicitly described and depicted herein.

Claims (17)

1. A multilayer co-extruded stone-plastic floor, comprising:
at least one layer is moulded to coextruding stone, layer from the top down includes at least to coextruding stone: the stone-plastic composite material comprises a first stable layer, a stone-plastic rigid layer and a second stable layer;
the dimensional change rates of the first stabilizing layer and the second stabilizing layer are both 0-0.12% at-15-80 ℃;
at least one of the first stabilizing layer, the stone-plastic rigid layer and the second stabilizing layer comprises ACR/nano SiO2Composite particles.
2. The multilayer co-extruded stone floor as claimed in claim 1, wherein the ACR/nano SiO2The grafting rate of ACR on the surface of the composite particle is 70-110%.
3. The multilayer co-extruded stone-plastic floor as claimed in claim 1, wherein the co-extruded stone-plastic layer comprises in order from top to bottom: the first stabilizing layer, the stone-plastic rigid layer and the second stabilizing layer are arranged in a thickness ratio of 1: 1.8-2.2: 1.
4. The multilayer co-extrusion stone-plastic floor as claimed in claim 3, wherein the stone-plastic rigid layer further comprises polyvinyl chloride, at least one of the first and second stabilizing layers further comprises polyvinyl chloride, and the ACR/nano SiO is2The using amount of the composite particles is 10-15% of the mass content of the polyvinyl chloride in the corresponding layer.
5. The multilayer co-extrusion stone-plastic floor as claimed in claim 4, wherein the polyvinyl chloride mass content in the stone-plastic rigid layer is 18-21%.
6. The multilayer co-extrusion stone-plastic floor as claimed in claim 4, wherein the polyvinyl chloride mass content in at least one of the first and second stabilizing layers is 25-30%.
7. The multilayer co-extruded stone floor as claimed in claim 4, wherein the composition of the stone rigid layer comprises 10-15 parts by weight of ACR/nano SiO2 composite particles based on 526.8 parts by weight of the stone rigid layer.
8. The multilayer co-extrusion stone-plastic floor as claimed in claim 7, wherein the stone-plastic rigid layer further comprises glass beads, and the amount of the glass beads is 10-15% of the mass content of polyvinyl chloride in the stone-plastic rigid layer.
9. The multilayer co-extruded stone floor as claimed in claim 8, wherein the composition of the stone rigid layer further comprises 10-15 parts by weight of glass beads based on 526.8 parts by weight of the stone rigid layer.
10. The multilayer co-extruded stone floor as claimed in claim 9, wherein the composition of the stone rigid layer further comprises 90-110 parts by weight of polyvinyl chloride and at least one of the following components based on 526.8 parts by weight of the stone rigid layer:
360-425 parts by weight of inorganic filler, 1.2-1.8 parts by weight of polyethylene wax, 5-8 parts by weight of stabilizer and 1.0-1.6 parts by weight of stearic acid.
11. The multi-layer co-extruded stone floor as claimed in claim 4, wherein the composition of the first and second stabilizing layers comprises 90-110 parts by weight of polyvinyl chloride, 10-15 parts by weight of ACR/nano SiO based on 363.5 parts by weight of the first or second stabilizing layer2Composite particles and at least one of the following components:
210-270 parts of inorganic filler, 0.9-1.5 parts of polyethylene wax, 6-10 parts of stabilizer, 0.8-1.4 parts of stearic acid, 0.2-0.6 part of oxidized polyethylene wax and 0.1-0.5 part of carbon black.
12. The multilayer co-extruded floor according to claim 1, further comprising at least one of the following structural layers: UV coating, wearing layer, various rete.
13. A method for manufacturing a multilayer co-extruded stone floor as claimed in any one of claims 1 to 12, characterized in that it comprises the following steps:
mixing materials of at least one layer of a first stabilizing layer and a second stabilizing layer to obtain a first mixed material, and stirring the first mixed material to obtain a first ingredient, wherein the first mixed material contains ACR/nano SiO2Composite particles;
mixing the materials of the stone-plastic rigid layer to obtain a second mixed material, and stirring the second mixed material to obtain a second ingredient, wherein the second mixed material contains ACR/nano SiO2Composite particles;
will first compounding with the layer is moulded to the second compounding through extruder extrusion crowded stone altogether, crowded stone altogether moulds the layer and includes three layer construction, and from the top down does in proper order first stable layer the rigid layer is moulded to stone with the second stable layer.
14. The method for manufacturing a multilayer co-extrusion stone-plastic floor as claimed in claim 13, wherein the material of the first or second stabilizing layer comprises 90-110 parts by weight of polyvinyl chloride, 10-15 parts by weight of ACR/nano SiO based on 363.5 parts by weight of the first or second stabilizing layer2Composite particles and at least one of the following materials: 210-270 parts by weight of inorganic filler, 0.9-1.5 parts by weight of polyethylene wax, 6-10 parts by weight of stabilizer, 0.8-1.4 parts by weight of stearic acid, 0.2-0.6 parts by weight of oxidized polyethylene wax and 0.1-0.5 parts by weight of carbon black.
15. The manufacturing method of the multilayer co-extrusion stone-plastic floor as claimed in claim 13, wherein the material of the stone-plastic rigid layer comprises 90-110 parts by weight of polyvinyl chloride, 10-15 parts by weight of ACR/nano SiO based on 526.8 parts by weight of the stone-plastic rigid layer2Composite particles and at least one of the following materials:
360-425 parts by weight of inorganic filler, 1.2-1.8 parts by weight of polyethylene wax, 5-8 parts by weight of stabilizer, 1.0-1.6 parts by weight of stearic acid and 10-15 parts by weight of glass beads.
16. The method of claim 13, wherein the ACR/nano SiO is used to manufacture a multi-layer co-extruded floor2The grafting rate of ACR on the surface of the composite particle is 70-110%.
17. The method of claim 16, wherein the second composition further comprises polyvinyl chloride, the first composition further comprises polyvinyl chloride, and the ACR/nano SiO is2The using amount of the composite particles is 10-15% of the mass content of the polyvinyl chloride in the corresponding mixed material.
CN202011641442.6A 2020-12-31 2020-12-31 Multilayer co-extrusion stone-plastic floor and manufacturing method thereof Pending CN112746719A (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
CN202011641442.6A CN112746719A (en) 2020-12-31 2020-12-31 Multilayer co-extrusion stone-plastic floor and manufacturing method thereof
EP21893118.6A EP4050179A4 (en) 2020-12-31 2021-12-30 Multi-layer co-extruded stone plastic floor and manufacturing method therefor
PCT/CN2021/143142 WO2022143913A1 (en) 2020-12-31 2021-12-30 Multi-layer co-extruded stone plastic floor and manufacturing method therefor
US17/664,420 US20220275653A1 (en) 2020-12-31 2022-05-22 Multi-layer co-extrusion stone plastic floors and manufacturing methods thereof
US18/361,846 US20230383546A1 (en) 2020-12-31 2023-07-29 Multi-layer co-extrusion stone plastic floors and manufacturing methods thereof

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022143913A1 (en) * 2020-12-31 2022-07-07 浙江永裕家居股份有限公司 Multi-layer co-extruded stone plastic floor and manufacturing method therefor
EP4282654A1 (en) * 2022-05-26 2023-11-29 Zhejiang Yongyu Home Furnishings Co., Ltd. Composite decorative boards and manufacturing methods thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022143913A1 (en) * 2020-12-31 2022-07-07 浙江永裕家居股份有限公司 Multi-layer co-extruded stone plastic floor and manufacturing method therefor
EP4282654A1 (en) * 2022-05-26 2023-11-29 Zhejiang Yongyu Home Furnishings Co., Ltd. Composite decorative boards and manufacturing methods thereof

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