CN111205704A - Weather-resistant long-life waterproof anticorrosion flame-retardant integrated coating and preparation method thereof - Google Patents
Weather-resistant long-life waterproof anticorrosion flame-retardant integrated coating and preparation method thereof Download PDFInfo
- Publication number
- CN111205704A CN111205704A CN201910366180.8A CN201910366180A CN111205704A CN 111205704 A CN111205704 A CN 111205704A CN 201910366180 A CN201910366180 A CN 201910366180A CN 111205704 A CN111205704 A CN 111205704A
- Authority
- CN
- China
- Prior art keywords
- weight
- flame
- weather
- retardant
- resistant long
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 76
- 239000003063 flame retardant Substances 0.000 title claims abstract description 76
- 238000000576 coating method Methods 0.000 title claims abstract description 57
- 239000011248 coating agent Substances 0.000 title claims abstract description 56
- 238000002360 preparation method Methods 0.000 title description 11
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 42
- 229920005989 resin Polymers 0.000 claims abstract description 42
- 239000011347 resin Substances 0.000 claims abstract description 42
- 229920001971 elastomer Polymers 0.000 claims abstract description 37
- 239000000806 elastomer Substances 0.000 claims abstract description 34
- 239000000080 wetting agent Substances 0.000 claims abstract description 31
- 239000003607 modifier Substances 0.000 claims abstract description 27
- 230000002745 absorbent Effects 0.000 claims abstract description 22
- 239000002250 absorbent Substances 0.000 claims abstract description 22
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 22
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 22
- 239000010881 fly ash Substances 0.000 claims abstract description 21
- 239000011787 zinc oxide Substances 0.000 claims abstract description 21
- 239000004519 grease Substances 0.000 claims abstract description 17
- 239000003921 oil Substances 0.000 claims description 24
- 235000019198 oils Nutrition 0.000 claims description 24
- 238000003756 stirring Methods 0.000 claims description 21
- 239000002245 particle Substances 0.000 claims description 14
- 238000010008 shearing Methods 0.000 claims description 14
- 239000000463 material Substances 0.000 claims description 12
- 239000003208 petroleum Substances 0.000 claims description 12
- -1 alkyl phenolic resin Chemical compound 0.000 claims description 8
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 7
- 239000000084 colloidal system Substances 0.000 claims description 7
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 claims description 7
- 229960001545 hydrotalcite Drugs 0.000 claims description 7
- 229910001701 hydrotalcite Inorganic materials 0.000 claims description 7
- 229920001568 phenolic resin Polymers 0.000 claims description 7
- 239000005011 phenolic resin Substances 0.000 claims description 7
- 229920001195 polyisoprene Polymers 0.000 claims description 7
- 238000004513 sizing Methods 0.000 claims description 7
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 7
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 6
- 239000004114 Ammonium polyphosphate Substances 0.000 claims description 6
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 6
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 6
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims description 6
- 229920001276 ammonium polyphosphate Polymers 0.000 claims description 6
- 239000010775 animal oil Substances 0.000 claims description 6
- 229920005557 bromobutyl Polymers 0.000 claims description 6
- 229920005549 butyl rubber Polymers 0.000 claims description 6
- 229920005556 chlorobutyl Polymers 0.000 claims description 6
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 6
- 239000000347 magnesium hydroxide Substances 0.000 claims description 6
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 6
- 229920000137 polyphosphoric acid Polymers 0.000 claims description 6
- 150000003505 terpenes Chemical class 0.000 claims description 6
- 235000007586 terpenes Nutrition 0.000 claims description 6
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 6
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 6
- 239000008158 vegetable oil Substances 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 2
- 239000002131 composite material Substances 0.000 claims 1
- 239000002585 base Substances 0.000 abstract description 6
- 150000003839 salts Chemical class 0.000 abstract description 6
- 238000005260 corrosion Methods 0.000 abstract description 5
- 230000007797 corrosion Effects 0.000 abstract description 5
- 239000002253 acid Substances 0.000 abstract description 4
- 230000032683 aging Effects 0.000 abstract description 4
- 239000003513 alkali Substances 0.000 abstract description 4
- 238000010276 construction Methods 0.000 abstract description 4
- 239000000853 adhesive Substances 0.000 abstract description 3
- 230000001070 adhesive effect Effects 0.000 abstract description 3
- 238000005265 energy consumption Methods 0.000 abstract description 3
- 239000002699 waste material Substances 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 8
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 5
- 239000006087 Silane Coupling Agent Substances 0.000 description 5
- 239000007769 metal material Substances 0.000 description 5
- HFQQZARZPUDIFP-UHFFFAOYSA-M sodium;2-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HFQQZARZPUDIFP-UHFFFAOYSA-M 0.000 description 5
- 239000008157 edible vegetable oil Substances 0.000 description 4
- 239000003973 paint Substances 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- 239000005060 rubber Substances 0.000 description 3
- 239000010426 asphalt Substances 0.000 description 2
- 230000004224 protection Effects 0.000 description 2
- VFWCMGCRMGJXDK-UHFFFAOYSA-N 1-chlorobutane Chemical compound CCCCCl VFWCMGCRMGJXDK-UHFFFAOYSA-N 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D123/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C09D123/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C09D123/22—Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefines
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D109/00—Coating compositions based on homopolymers or copolymers of conjugated diene hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D109/00—Coating compositions based on homopolymers or copolymers of conjugated diene hydrocarbons
- C09D109/06—Copolymers with styrene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/26—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers modified by chemical after-treatment
- C09D123/28—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
- C09D123/283—Halogenated homo- or copolymers of iso-olefines
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D191/00—Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/2224—Magnesium hydroxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/322—Ammonium phosphate
- C08K2003/323—Ammonium polyphosphate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention belongs to the technical field of waterproof anticorrosive coatings, and particularly relates to a weather-resistant long-life waterproof anticorrosive flame-retardant integrated coating which comprises 20-50 wt% of regenerated dehydrated biological grease, 5-20 wt% of fly ash, 10-40 wt% of an elastomer, 5-28 wt% of tackifying resin, 2-8 wt% of a wetting agent, 0.5-5 wt% of a modifier, 3-10 wt% of a flame retardant, 0.5-2 wt% of an ultraviolet absorbent, 0.5-2 wt% of an antioxidant and 2-10 wt% of zinc oxide. The weather-resistant long-life waterproof anticorrosion flame-retardant integrated coating disclosed by the invention is resistant to ultraviolet, aging, acid, alkali and salt corrosion, flame-retardant, strong in base layer adhesive force, good in low-temperature cohesiveness, good in creep self-healing property, low in construction energy consumption, safe and environment-friendly.
Description
Technical Field
The invention relates to a weather-resistant long-life waterproof anticorrosion flame-retardant integrated coating and a preparation method thereof. Belongs to the technical field of waterproof anticorrosive paint.
Background
At present, the service life of the waterproof and anticorrosive material generally does not meet the use requirement, and particularly, under the condition of exposure, the waterproof and anticorrosive material can be rapidly aged to influence the service life. In addition, most of waterproof and anticorrosive materials do not have self-healing property and flame retardance, have low bonding strength, and are easy to fall off from the surface of a base layer particularly in a cold environment. Therefore, the improvement committee proposed a long-life waterproof, anticorrosive and flame-retardant integrated material for bridge tunnels, underground pipe galleries, island reef facilities, marine facilities and the like in terms of "the directory of industrial structure adjustment guidance" (the title was obtained in 2019).
In summary, in order to solve the problems in the prior art, it is urgently needed to invent a weather-resistant long-life waterproof, anticorrosion and flame-retardant integrated coating which is resistant to ultraviolet light, aging, acid, alkali and salt corrosion, flame retardant, strong in base layer adhesion, good in low-temperature cohesiveness, good in creep self-healing property, low in construction energy consumption, safe and environment-friendly, and a preparation method thereof.
Disclosure of Invention
The weather-resistant long-life waterproof, anticorrosive and flame-retardant integrated coating and the preparation method thereof have the effects of ultraviolet resistance, aging resistance, acid-base salt corrosion resistance, flame retardance, strong base layer adhesive force, good low-temperature cohesiveness, good creep self-healing property, low construction energy consumption, safety and environmental protection, and solve the problems that the existing waterproof and anticorrosive material does not have self-healing property and flame retardance and is low in bonding strength.
In order to solve the technical problems, the technical scheme of the invention is as follows:
a weather-resistant long-life waterproof anticorrosion flame-retardant integrated coating comprises, by weight, 20-50% of regenerated dehydrated biological grease, 5-20% of fly ash, 10-40% of an elastomer, 5-28% of tackifying resin, 2-8% of a wetting agent, 0.5-5% of a modifier, 3-10% of a flame retardant, 0.5-2% of an ultraviolet absorbent, 0.5-2% of an antioxidant and 2-10% of zinc oxide.
In a preferred scheme, the weather-resistant long-life waterproof anticorrosion flame-retardant integrated coating comprises 26.5 wt% of regenerated dehydrated biological grease, 5 wt% of fly ash, 40 wt% of elastomer, 5 wt% of tackifying resin, 8 wt% of wetting agent, 1 wt% of modifier, 10 wt% of flame retardant, 0.5 wt% of ultraviolet absorbent, 1 wt% of antioxidant and 3 wt% of zinc oxide.
In a preferred scheme, the weather-resistant long-life waterproof anticorrosion flame-retardant integrated coating comprises, by weight, 20% of regenerated dehydrated biological grease, 20% of fly ash, 22% of elastomer, 28% of tackifying resin, 2% of wetting agent, 0.5% of modifier, 4% of flame retardant, 1% of ultraviolet absorbent, 0.5% of antioxidant and 2% of zinc oxide.
In a preferred scheme, the weather-resistant long-life waterproof anticorrosion flame-retardant integrated coating comprises, by weight, 50% of regenerated dehydrated biological grease, 8% of fly ash, 10% of elastomer, 7% of tackifying resin, 3% of wetting agent, 5% of modifier, 3% of flame retardant, 2% of ultraviolet absorbent, 2% of antioxidant and 10% of zinc oxide.
The regenerated dehydrated biological grease is one or the combination of two of regenerated vegetable oil and regenerated animal oil.
The tackifying resin is one or more of alkyl phenolic resin, C5 petroleum resin, C9 petroleum resin, rosin, terpene and EVA with high VA content.
The elastomer is one or more of butyl rubber, brominated butyl rubber, chlorinated butyl rubber, styrene-butadiene rubber and polyisoprene elastomer.
The modifier is one or the combination of two of ethylene oxide wax and polyphosphoric acid.
The flame retardant is one or a combination of more of hydrotalcite, ammonium polyphosphate, magnesium hydroxide and aluminum hydroxide.
The wetting agent is one or a combination of more of SDBS, CTAB and silane coupling agent, and the bonding strength between the hydrophilic interface and the hydrophilic interface can be improved by adding the wetting agent. The ultraviolet absorbent is one or a combination of more of UV-531, UV-O, UV-9 and a light stabilizer 744. The antioxidant is one or a combination of 1010, 168, 1076, CA, 330 and MEB.
A preparation method of a weather-resistant long-life waterproof, anticorrosive and flame-retardant integrated coating comprises the steps of adding an elastomer, tackifying resin, fly ash, an ultraviolet absorbent, an antioxidant and zinc oxide into a shearing kettle in proportion, shearing and stirring until no particles exist, adding a flame retardant, a modifier and a wetting agent, continuously stirring until a sizing material is uniform and no particles exist, adding regenerated dehydrated biological oil, stirring for 1 hour, and passing through a colloid mill to obtain the weather-resistant long-life waterproof, anticorrosive and flame-retardant integrated coating.
The invention has the following characteristics and beneficial effects:
the weather-resistant long-life waterproof anticorrosion flame-retardant integrated coating has the advantages that the service life of exposed parts can be more than 20 years, the service life of concealed works can be as long as that of buildings, the peel strength of the coating with a metal material at 180 ℃ can be more than 6.0N/mm, the bonding strength of the coating with concrete can be more than 5.0N/mm, and the flexibility at low temperature can be more than-35 ℃.
Compared with the prior art, the invention also has the following advantages: 1. the exposed service life is longer, and the service life of the concealed project can reach the same service life of the building; 2. the creep property is durable, and the newly generated and original gaps and holes of the base layer can be sealed; 3. the application environment range is wide, the flexibility at low temperature is-35 ℃, the heat resistance is 90 ℃, the normal use can be realized, the construction temperature is not required, the bonding strength is high, and the adhesive force is strong; 4. the flame retardant property can reach B1 grade; 5. has strong acid, alkali and salt corrosion resistance.
Detailed Description
The following further describes the embodiments of the present invention. It should be noted that the description of the embodiments is provided to help understanding of the present invention, but the present invention is not limited thereto. In addition, the technical features involved in the embodiments of the present invention described below may be combined with each other as long as they do not conflict with each other.
Example 1:
a weather-resistant long-life waterproof anticorrosion flame-retardant integrated coating comprises, by weight, 20-50% of regenerated dehydrated biological grease, 5-20% of fly ash, 10-40% of an elastomer, 5-28% of tackifying resin, 2-8% of a wetting agent, 0.5-5% of a modifier, 3-10% of a flame retardant, 0.5-2% of an ultraviolet absorbent, 0.5-2% of an antioxidant and 2-10% of zinc oxide.
The regenerated dehydrated biological oil is one or the combination of two of regenerated vegetable oil and regenerated animal oil, is derived from waste edible oil and comprises plant source waste oil and fat, animal source waste oil and fat and mixed oil and fat. The tackifying resin is one or more of alkyl phenolic resin, C5 petroleum resin, C9 petroleum resin, rosin, terpene and EVA with high VA content. The high VA content EVA means that the VA content reaches 28-50%, the higher the VA content is, the stronger the resin polarity is, the better the low temperature resistance is, and the stronger the substrate surface binding force is.
The elastomer is one or more of butyl rubber, brominated butyl rubber, chlorinated butyl rubber, styrene-butadiene rubber and polyisoprene elastomer. The modifier is one or the combination of two of ethylene oxide wax and polyphosphoric acid. The flame retardant is one or a combination of more of hydrotalcite, ammonium polyphosphate, magnesium hydroxide and aluminum hydroxide. The wetting agent is one or a combination of more of SDBS, CTAB and silane coupling agent, and the bonding strength between the hydrophilic interface and the hydrophilic interface can be improved by adding the wetting agent.
A preparation method of a weather-resistant long-life waterproof, anticorrosive and flame-retardant integrated coating comprises the steps of adding an elastomer, tackifying resin, fly ash, an ultraviolet absorbent, an antioxidant and zinc oxide into a shearing kettle in proportion, shearing and stirring until no particles exist, adding a flame retardant, a modifier and a wetting agent, continuously stirring until a sizing material is uniform and no particles exist, adding regenerated dehydrated biological oil, stirring for 1 hour, and passing through a colloid mill to obtain the weather-resistant long-life waterproof, anticorrosive and flame-retardant integrated coating. The weather-resistant long-life waterproof anticorrosion flame-retardant integrated coating has the exposed service life of more than 20 years, the service life of a concealed project can be the same as that of a building, the peeling strength of the coating with a metal material at 180 ℃ can be more than 6.0N/mm, the bonding strength of the coating with concrete can be more than 5.0N/mm, and the flexibility at low temperature can be more than-35 ℃.
Example 2:
the weather-resistant long-life waterproof anticorrosion flame-retardant integrated coating comprises 26.5 wt% of regenerated dehydrated biological grease, 5 wt% of fly ash, 40 wt% of elastomer, 5 wt% of tackifying resin, 8 wt% of wetting agent, 1 wt% of modifier, 10 wt% of flame retardant, 0.5 wt% of ultraviolet absorbent, 1 wt% of antioxidant and 3 wt% of zinc oxide.
The regenerated dehydrated biological oil is one or the combination of two of regenerated vegetable oil and regenerated animal oil, is derived from waste edible oil and comprises plant source waste oil and fat, animal source waste oil and fat and mixed oil and fat. The tackifying resin is one or more of alkyl phenolic resin, C5 petroleum resin, C9 petroleum resin, rosin, terpene and EVA with high VA content. The high VA content EVA means that the VA content reaches 28-50%, the higher the VA content is, the stronger the resin polarity is, the better the low temperature resistance is, and the higher the substrate surface binding force is.
The elastomer is one or more of butyl rubber, brominated butyl rubber, chlorinated butyl rubber, styrene-butadiene rubber and polyisoprene elastomer. The modifier is one or the combination of two of ethylene oxide wax and polyphosphoric acid. The flame retardant is one or a combination of more of hydrotalcite, ammonium polyphosphate, magnesium hydroxide and aluminum hydroxide. The wetting agent is one or a combination of more of SDBS, CTAB and silane coupling agent, and the bonding strength between the hydrophilic interface and the hydrophilic interface can be improved by adding the wetting agent.
A preparation method of a weather-resistant long-life waterproof, anticorrosive and flame-retardant integrated coating comprises the steps of adding an elastomer, tackifying resin, fly ash, an ultraviolet absorbent, an antioxidant and zinc oxide into a shearing kettle in proportion, shearing and stirring until no particles exist, adding a flame retardant, a modifier and a wetting agent, continuously stirring until a sizing material is uniform and no particles exist, adding regenerated dehydrated biological oil, stirring for 1 hour, and passing through a colloid mill to obtain the weather-resistant long-life waterproof, anticorrosive and flame-retardant integrated coating. The weather-resistant long-life waterproof anticorrosion flame-retardant integrated coating has the exposed service life of more than 20 years, the service life of a concealed project can be the same as that of a building, the peeling strength of the coating with a metal material at 180 ℃ can be more than 6.0N/mm, the bonding strength of the coating with concrete can be more than 5.0N/mm, and the flexibility at low temperature can be more than-35 ℃.
Example 3:
the weather-resistant long-life waterproof anticorrosion flame-retardant integrated coating comprises, by weight, 20% of regenerated dehydrated biological grease, 20% of fly ash, 22% of elastomer, 28% of tackifying resin, 2% of wetting agent, 0.5% of modifier, 4% of flame retardant, 1% of ultraviolet absorbent, 0.5% of antioxidant and 2% of zinc oxide.
The regenerated dehydrated biological oil is one or the combination of two of regenerated vegetable oil and regenerated animal oil, is derived from waste edible oil and comprises plant source waste oil and fat, animal source waste oil and fat and mixed oil and fat. The tackifying resin is one or more of alkyl phenolic resin, C5 petroleum resin, C9 petroleum resin, rosin, terpene and EVA with high VA content. The high VA content EVA means that the VA content reaches 28-50%, the higher the VA content is, the stronger the resin polarity is, the better the low temperature resistance is, and the higher the substrate surface binding force is.
The elastomer is one or more of butyl rubber, brominated butyl rubber, chlorinated butyl rubber, styrene-butadiene rubber and polyisoprene elastomer. The modifier is one or the combination of two of ethylene oxide wax and polyphosphoric acid. The flame retardant is one or a combination of more of hydrotalcite, ammonium polyphosphate, magnesium hydroxide and aluminum hydroxide. The wetting agent is one or a combination of more of SDBS, CTAB and silane coupling agent, and the bonding strength between the hydrophilic interface and the hydrophilic interface can be improved by adding the wetting agent.
A preparation method of a weather-resistant long-life waterproof, anticorrosive and flame-retardant integrated coating comprises the steps of adding an elastomer, tackifying resin, fly ash, an ultraviolet absorbent, an antioxidant and zinc oxide into a shearing kettle in proportion, shearing and stirring until no particles exist, adding a flame retardant, a modifier and a wetting agent, continuously stirring until a sizing material is uniform and no particles exist, adding regenerated dehydrated biological oil, stirring for 1 hour, and passing through a colloid mill to obtain the weather-resistant long-life waterproof, anticorrosive and flame-retardant integrated coating. The weather-resistant long-life waterproof anticorrosion flame-retardant integrated coating has the exposed service life of more than 20 years, the service life of a concealed project can be the same as that of a building, the peeling strength of the coating with a metal material at 180 ℃ can be more than 6.0N/mm, the bonding strength of the coating with concrete can be more than 5.0N/mm, and the flexibility at low temperature can be more than-35 ℃.
Example 4:
the weather-resistant long-life waterproof anticorrosion flame-retardant integrated coating comprises, by weight, 50% of regenerated dehydrated biological grease, 8% of fly ash, 10% of elastomer, 7% of tackifying resin, 3% of wetting agent, 5% of modifier, 3% of flame retardant, 2% of ultraviolet absorbent, 2% of antioxidant and 10% of zinc oxide.
The regenerated dehydrated biological oil is one or the combination of two of regenerated vegetable oil and regenerated animal oil, is derived from waste edible oil and comprises plant source waste oil and fat, animal source waste oil and fat and mixed oil and fat. The tackifying resin is one or more of alkyl phenolic resin, C5 petroleum resin, C9 petroleum resin, rosin, terpene and EVA with high VA content. The high VA content EVA means that the VA content reaches 28-50%, the higher the VA content is, the stronger the resin polarity is, the better the low temperature resistance is, and the higher the substrate surface binding force is.
The elastomer is one or more of butyl rubber, brominated butyl rubber, chlorinated butyl rubber, styrene-butadiene rubber and polyisoprene elastomer. The modifier is one or the combination of two of ethylene oxide wax and polyphosphoric acid. The flame retardant is one or a combination of more of hydrotalcite, ammonium polyphosphate, magnesium hydroxide and aluminum hydroxide. The wetting agent is one or a combination of more of SDBS, CTAB and silane coupling agent, and the bonding strength between the hydrophilic interface and the hydrophilic interface can be improved by adding the wetting agent.
A preparation method of a weather-resistant long-life waterproof, anticorrosive and flame-retardant integrated coating comprises the steps of adding an elastomer, tackifying resin, fly ash, an ultraviolet absorbent, an antioxidant and zinc oxide into a shearing kettle in proportion, shearing and stirring until no particles exist, adding a flame retardant, a modifier and a wetting agent, continuously stirring until a sizing material is uniform and no particles exist, adding regenerated dehydrated biological oil, stirring for 1 hour, and passing through a colloid mill to obtain the weather-resistant long-life waterproof, anticorrosive and flame-retardant integrated coating. The weather-resistant long-life waterproof anticorrosion flame-retardant integrated coating has the exposed service life of more than 20 years, the service life of a concealed project can be the same as that of a building, the peeling strength of the coating with a metal material at 180 ℃ can be more than 6.0N/mm, the bonding strength of the coating with concrete can be more than 5.0N/mm, and the flexibility at low temperature can be more than-35 ℃.
Example 5:
the weather-resistant long-life waterproof anticorrosion flame-retardant integrated coating comprises, by weight, 30% of regenerated dehydrated biological oil, 10% of fly ash, 6% of a styrene-butadiene rubber elastomer, 10% of a polyisoprene elastomer, 10% of butyl chloride rubber, 16% of an alkyl phenolic resin, 2% of a wetting agent, 1% of an ethylene oxide wax modifier, 6% of a hydrotalcite flame retardant, 0.5% of an ultraviolet absorbent, 0.5% of a 1010 antioxidant and 8% of zinc oxide.
The preparation process comprises the following steps: adding an elastomer, tackifying resin, fly ash, an ultraviolet absorbent, an antioxidant and zinc oxide into a shearing kettle, shearing and stirring until no particles exist, adding a flame retardant, a modifier and a wetting agent, continuously stirring until a sizing material is uniform and no particles exist, adding regenerated dehydrated biological oil, stirring for 1 hour, and passing through a colloid mill to obtain the weather-resistant long-life waterproof, anticorrosive and flame-retardant integrated coating.
Experimental data and procedures:
the experimental analysis is carried out on the waterproof anticorrosive paint in the above examples 2-5 and the existing market.
Comparative example 1: non-cured rubber asphalt waterproof paint related to JC/T2428-2017
Comparative example 2: spray coating rubber asphalt related to Q/CR517.2-2016
Comparative example 3: polyurethane waterproof coating related in GB/T19250-2013
Comparative example 4: permeable epoxy resin waterproof and anticorrosive paint involved in DB 44/T1607-
| Example 2 | Example 3 | Example 4 | Example 5 | Comparative example 1 | Comparative example 2 | Comparative example 3 | Comparative example 4 | |
| Solids content/% | 99.7 | 99.2 | 98.4 | 99.5 | 98 | 55 | 85 | 60 |
| Low temperature flexibility/. degree.C | -40 | -39 | -37 | -38 | -20 | -30 | -35 | - |
| High temperature resistance/deg.C | 105 | 97 | 110 | 100 | 65 | 140 | - | - |
| Strength of bonding with concrete | 2.6MPa | 2.5MPa | 2.7MPa | 2.5MPa | - | 0.6 | 1.0 | 3.5 |
| Peel strength from aluminum plate | 6.5N/mm | 6N/mm | 6.1N/mm | 6N/mm | - | - | - | - |
| Aging resistance/h | 5400 | 4925 | 5028 | 5000 | 168 | - | 1000 | - |
| Acid, alkali, salt and salt corrosion resistance/d | 100 | 100 | 100 | 100 | 7 | 7 | 7 | 7 |
| Self-healing property | Is provided with | Is provided with | Is provided with | Is provided with | Is provided with | Is provided with | Is free of | Is free of |
| Flame retardant properties | B1 | B1 | B1 | B1 | Is free of | B1 | B2 | - |
As can be seen from the table above, the weather-resistant long-life waterproof anticorrosion flame-retardant integrated coating of the embodiment completely exceeds the common waterproof anticorrosion coating in the market in the aspect of performance balance.
The embodiments of the present invention have been described in detail, but the present invention is not limited to the described embodiments. It will be apparent to those skilled in the art that various changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, and the scope of protection is still within the scope of the invention.
Claims (10)
1. The weather-resistant long-life waterproof anticorrosion flame-retardant integrated coating is characterized in that: comprises 20-50% of regenerated dehydrated biological grease by weight, 5-20% of fly ash by weight, 10-40% of elastomer by weight, 5-28% of tackifying resin by weight, 2-8% of wetting agent by weight, 0.5-5% of modifier by weight, 3-10% of flame retardant by weight, 0.5-2% of ultraviolet absorbent by weight, 0.5-2% of antioxidant by weight and 2-10% of zinc oxide by weight.
2. The weather-resistant long-life waterproof anticorrosion flame-retardant integrated coating as claimed in claim 1, wherein: the environment-friendly biological grease comprises 26.5% by weight of regenerated dehydrated biological grease, 5% by weight of fly ash, 40% by weight of elastomer, 5% by weight of tackifying resin, 8% by weight of wetting agent, 1% by weight of modifier, 10% by weight of flame retardant, 0.5% by weight of ultraviolet absorbent, 1% by weight of antioxidant and 3% by weight of zinc oxide.
3. The weather-resistant long-life waterproof anticorrosion flame-retardant integrated coating as claimed in claim 1, wherein: the environment-friendly composite material comprises 20 weight percent of regenerated dehydrated biological grease, 20 weight percent of fly ash, 22 weight percent of elastomer, 28 weight percent of tackifying resin, 2 weight percent of wetting agent, 0.5 weight percent of modifier, 4 weight percent of flame retardant, 1 weight percent of ultraviolet absorbent, 0.5 weight percent of antioxidant and 2 weight percent of zinc oxide.
4. The weather-resistant long-life waterproof anticorrosion flame-retardant integrated coating as claimed in claim 1, wherein: the environment-friendly biological grease comprises 50% of regenerated dehydrated biological grease by weight, 8% of fly ash by weight, 10% of elastomer by weight, 7% of tackifying resin by weight, 3% of wetting agent by weight, 5% of modifier by weight, 3% of flame retardant by weight, 2% of ultraviolet absorbent by weight, 2% of antioxidant by weight and 10% of zinc oxide by weight.
5. The weather-resistant long-life waterproof anticorrosion flame-retardant integrated coating as claimed in claim 1, 2, 3 or 4, wherein: the regenerated dehydrated biological grease is one or the combination of two of regenerated vegetable oil and regenerated animal oil.
6. The weather-resistant long-life waterproof anticorrosion flame-retardant integrated coating as claimed in claim 1, 2, 3 or 4, wherein: the tackifying resin is one or more of alkyl phenolic resin, C5 petroleum resin, C9 petroleum resin, rosin, terpene and EVA with high VA content.
7. The weather-resistant long-life waterproof anticorrosion flame-retardant integrated coating as claimed in claim 1, 2, 3 or 4, wherein: the elastomer is one or more of butyl rubber, brominated butyl rubber, chlorinated butyl rubber, styrene-butadiene rubber and polyisoprene elastomer.
8. The weather-resistant long-life waterproof anticorrosion flame-retardant integrated coating as claimed in claim 1, 2, 3 or 4, wherein: the modifier is one or the combination of two of ethylene oxide wax and polyphosphoric acid.
9. The weather-resistant long-life waterproof anticorrosion flame-retardant integrated coating as claimed in claim 1, 2, 3 or 4, wherein: the flame retardant is one or a combination of more of hydrotalcite, ammonium polyphosphate, magnesium hydroxide and aluminum hydroxide.
10. A method for preparing the weather-resistant long-life waterproof anticorrosion flame-retardant integrated coating based on any one of claims 1 to 9, which is characterized in that: adding the elastomer, tackifying resin, fly ash, ultraviolet absorbent, antioxidant and zinc oxide into a shearing kettle in proportion, shearing and stirring until no particles exist, adding the flame retardant, modifier and wetting agent, continuously stirring until the sizing material is uniform and no particles exist, adding the regenerated dehydrated biological oil, stirring for 1 hour, and passing through a colloid mill to obtain the weather-resistant long-life waterproof, anticorrosive and flame-retardant integrated coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910366180.8A CN111205704A (en) | 2019-05-03 | 2019-05-03 | Weather-resistant long-life waterproof anticorrosion flame-retardant integrated coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910366180.8A CN111205704A (en) | 2019-05-03 | 2019-05-03 | Weather-resistant long-life waterproof anticorrosion flame-retardant integrated coating and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN111205704A true CN111205704A (en) | 2020-05-29 |
Family
ID=70783265
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910366180.8A Withdrawn CN111205704A (en) | 2019-05-03 | 2019-05-03 | Weather-resistant long-life waterproof anticorrosion flame-retardant integrated coating and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111205704A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115974457A (en) * | 2022-12-27 | 2023-04-18 | 重庆鑫科新型建筑材料有限责任公司 | High-strength asphalt concrete and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999020701A1 (en) * | 1997-10-21 | 1999-04-29 | The Dow Chemical Company | Thermoplastic marking compositions |
| CN1863832A (en) * | 2003-10-03 | 2006-11-15 | 谢尼克特得国际有限公司 | Novolacquer alykylphenol resins, methods for the production thereof and use thereof of as tackifying and/or reinforcing resins for rubbers |
| CN103666261A (en) * | 2013-12-23 | 2014-03-26 | 李崇 | High-solid-content solvent type non-curing rubber asphalt waterproof paint and preparation method thereof |
| CN106281008A (en) * | 2016-08-22 | 2017-01-04 | 重庆中防德邦防水技术有限公司 | A kind of creepage type high molecular water-proof paint and preparation method |
-
2019
- 2019-05-03 CN CN201910366180.8A patent/CN111205704A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999020701A1 (en) * | 1997-10-21 | 1999-04-29 | The Dow Chemical Company | Thermoplastic marking compositions |
| CN1863832A (en) * | 2003-10-03 | 2006-11-15 | 谢尼克特得国际有限公司 | Novolacquer alykylphenol resins, methods for the production thereof and use thereof of as tackifying and/or reinforcing resins for rubbers |
| CN103666261A (en) * | 2013-12-23 | 2014-03-26 | 李崇 | High-solid-content solvent type non-curing rubber asphalt waterproof paint and preparation method thereof |
| CN106281008A (en) * | 2016-08-22 | 2017-01-04 | 重庆中防德邦防水技术有限公司 | A kind of creepage type high molecular water-proof paint and preparation method |
Non-Patent Citations (3)
| Title |
|---|
| 中华人民共和国公安部消防局编: "《中国消防手册 第12卷 消防装备·消防产品》", 31 December 2007, 上海科学技术出版社 * |
| 习应祥等: "《建筑材料》", 28 February 1997, 湖南大学出版社 * |
| 周祥兴: "《合成树脂新资料手册》", 31 May 2002, 中国物资出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115974457A (en) * | 2022-12-27 | 2023-04-18 | 重庆鑫科新型建筑材料有限责任公司 | High-strength asphalt concrete and preparation method thereof |
| CN115974457B (en) * | 2022-12-27 | 2024-02-20 | 重庆鑫科新型建筑材料有限责任公司 | High-strength asphalt concrete and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP2398863B1 (en) | Fusion bonded epoxy coating compositions that include magnesium oxide | |
| KR101079778B1 (en) | Aqueous rust-resisting paint composition | |
| CN102746766B (en) | Water-borne anticorrosion paint and method for preparing same | |
| WO2015096562A1 (en) | Aqueous expandable nano fireproof coating for cables and preparation method therefor | |
| CN110643283A (en) | Water-based non-cured rubber asphalt waterproof coating and production process thereof | |
| CN102071005B (en) | High-temperature acidification corrosion inhibitor and preparation method thereof | |
| CN105176247A (en) | Water-resistant fireproof coating | |
| CN110791170A (en) | Water-based bonding primer and preparation method thereof | |
| CN104341924A (en) | Water-based antirust and rust removing asphalt ship bottom coating and preparation method for same | |
| CN111454663B (en) | Non-cured rubber asphalt waterproof coating and preparation method thereof | |
| CN111205704A (en) | Weather-resistant long-life waterproof anticorrosion flame-retardant integrated coating and preparation method thereof | |
| CN109161294A (en) | A kind of fastener lubrication corrosion-resistant abrasion coating and its preparation method and application | |
| CN105925177B (en) | A kind of aqueous organic inorganic hybridization high-temperature resistant coating and preparation method thereof | |
| CN108250963B (en) | Acid-resistant non-cured waterproof coating and production process thereof | |
| CN111548696B (en) | Fireproof coating for steel structure surface and application thereof | |
| CN103468138A (en) | Waterproof coating for bridge floors, roofs and culverts | |
| CN103468143A (en) | Polymer asphalt waterproof coating | |
| CN110643210A (en) | High-performance anti-corrosion coating for metal surface treatment | |
| SE1630169A1 (en) | Inhibited aqueous deicing composition | |
| CN114854264A (en) | Compression-resistant waterproof environment-friendly coating | |
| CN114163929A (en) | Liquid rubber and preparation method and application thereof | |
| CN102372985A (en) | Temperature-insulating and antirust coating | |
| CN106367758A (en) | Hard film type nanometer corrosion inhibitor | |
| CN106675313A (en) | Water-based anticorrosive coating and preparation method thereof | |
| CN103602289A (en) | Pipeline joint watertightness anticorrosion hot melt adhesive |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20200529 |