CN111149044B

CN111149044B - Spectacle lens and spectacles

Info

Publication number: CN111149044B
Application number: CN201880062817.8A
Authority: CN
Inventors: 小乡洋一; 盐谷俊介
Original assignee: Jingzi Holding Co; Hoya Lens Thailand Ltd
Current assignee: Jingzi Holding Co; Hoya Lens Thailand Ltd
Priority date: 2017-09-29
Filing date: 2018-09-28
Publication date: 2022-03-08
Anticipated expiration: 2038-09-28
Also published as: KR102362349B1; US20200264341A1; KR20200042528A; JP2019066651A; EP3690521B1; EP3690521A1; CN111149044A; EP3690521B8; WO2019065991A1; US11513258B2; JP6873880B2; EP3690521A4

Abstract

The present invention provides a spectacle lens comprising a lens base material containing a blue light absorbing compound and a multilayer film comprising a chromium layer having a film thickness of 1.0 to 10.0nm, wherein the blue light blocking ratio is 21.0% or more, the dominant wavelength measured on the object side surface of the spectacle lens is in the range of 500.0 to 550.0nm, and the dominant wavelength measured on the eyeball side surface of the spectacle lens is in the range of 500.0 to 550.0 nm.

Description

Spectacle lens and spectacles

Technical Field

The present invention relates to an eyeglass lens and eyeglasses having the eyeglass lens.

Background

In recent years, display screens of digital devices have been replaced with liquid crystals from picture tubes, and recently, LED liquid crystals have become widespread. Therefore, in order to effectively reduce eye fatigue and eye pain caused when the digital device is used for a long time, measures for reducing the burden of blue light on the eyes should be taken. In general, light in a wavelength range of 400 to 500nm or light in the vicinity of the wavelength range is referred to as blue light.

Regarding the above points, for example, patent document 1 proposes an optical article having a multilayer film on a surface of a plastic substrate, the multilayer film having a property of reflecting light having a wavelength of 400 to 450 nm.

Prior Art

Patent document

Patent document 1: japanese patent laid-open publication No. 2013-8052.

Disclosure of Invention

Problems to be solved by the invention

As a technical means for reducing the burden of blue light on the eyes, there is a means in which a multilayer film having a property of reflecting blue light is provided on the surface of a lens base material in a spectacle lens as described in patent document 1.

On the other hand, the appearance of the eyeglass lens is also desired to be good. However, if a multilayer film having a property of strongly reflecting blue light is provided on the surface of the lens base material, the amount of blue light incident on the eyes of the wearer via the spectacle lens can be reduced, but the appearance of the spectacle lens tends to be greatly different from that of a general spectacle lens. In detail, in the spectacle lens in which a multilayer film having a property of strongly reflecting blue light is provided on the surface of the lens base material, the appearance is blue because blue light is strongly reflected on the surface on the side having the multilayer film.

Accordingly, an object of one embodiment of the present invention is to provide a spectacle lens which can reduce the burden on the eyes with blue light and has a good appearance.

Means for solving the problems

One embodiment of the present invention relates to an eyeglass lens comprising:

a lens substrate comprising a blue light absorbing compound; and

a multilayer film comprising a chromium layer having a film thickness of 1.0 to 10.0nm,

the blue light blocking rate is more than 21.0 percent,

the dominant wavelength measured on the object side surface of the spectacle lens is in the range of 500.0 to 550.0nm,

the dominant wavelength measured on the eyeball-side surface of the spectacle lens is in the range of 500.0 to 550.0 nm.

The above-mentioned spectacle lens is a spectacle lens comprising a blue light absorbing compound in a lens base material, and the blue light blocking ratio of the spectacle lens is 21.0% or more. In this way, since blue light can be blocked at a high blue light blocking ratio, the spectacle lens can reduce the amount of blue light incident on the eyes of the wearer of the spectacles having the spectacle lens, and can reduce the burden on the eyes of the wearer due to blue light.

The spectacle lens further comprises a multilayer film including a chromium layer having a film thickness of 1.0 to 10.0 nm. Chromium (Cr) has a property of absorbing light in a wide wavelength region in a visible region such as green light and red light in addition to light in a wavelength region of blue light. In contrast to a conventional spectacle lens, which has an appearance different from that of a conventional spectacle lens if blue light is selectively reflected strongly by a multilayer film, a spectacle lens having an appearance similar to that of a conventional spectacle lens can be realized by including a chromium layer as one layer of the multilayer film. Specifically, the main wavelength of the spectacle lens measured on the object side surface and the eyeball side surface is in the range of 500.0 to 550.0nm, which is a wavelength region of green light. In general eyeglass lenses that are widely used at present, since the same dominant wavelength is often displayed on both surfaces of the eyeglass lenses, the eyeglass lenses can have the same appearance as that of the general eyeglass lenses.

Further, since chromium is a metal, if the chromium layer is thick, the transmittance (for example, visual transmittance) of the spectacle lens may be significantly reduced, but if the chromium layer is thick at 1.0 to 10.0nm, the transmittance of the spectacle lens can be prevented from being significantly reduced.

Another aspect of the present invention relates to eyeglasses having the above-described eyeglass lenses.

Effects of the invention

According to one embodiment of the present invention, it is possible to provide an eyeglass lens that can reduce the burden on the eyes with blue light and can present the same appearance as a normal eyeglass lens, and eyeglasses having the eyeglass lens.

Detailed Description

[ spectacle lenses ]

The spectacle lens according to one embodiment of the present invention comprises a lens base material containing a blue light absorbing compound and a multilayer film containing a chromium layer having a film thickness of 1.0 to 10.0 nm; the blue light blocking rate is more than 21.0%; the dominant wavelength measured on the object side surface of the spectacle lens is in the range of 500.0-550.0 nm; and the dominant wavelength measured on the eyeball-side surface of the spectacle lens is in the range of 500.0 to 550.0 nm.

The present invention and the definition and/or measurement method of the terms in the present specification are explained below.

The "object side surface" means a surface located on the object side when the wearer wears glasses with spectacle lenses, and the "eyeball side surface" means a surface opposite thereto, i.e., a surface located on the eyeball side when the wearer wears glasses with spectacle lenses. In one embodiment, the object-side surface is a convex surface, and the eyeball-side surface is a concave surface. However, the present invention is not limited to this embodiment.

The "blue light absorbing compound" refers to a compound having absorption in a wavelength region of 400 to 500 nm.

The "blue light blocking ratio" is obtained by the following formula 1 in accordance with the standards of the japan medical optical equipment industry association.

(formula 1)

Blue light blocking ratio C_b＝1-τ_b

In the formula 1,. tau_bIs a weighted transmittance of blue light harmful to the eye, which is defined in the standards of the japan medical optical instrument industry association, and is calculated by the following formula 2. In equation 2, WB (λ) is a weighting function, and WB (λ) is calculated by the following equation 3.τ (λ) is the transmission at wavelength λ nm as measured by a spectrophotometer. Therefore, the blue light blocking ratio C_bIn (3), the blocking ratio based on the absorbed blue light and the blocking ratio based on the reflected blue light are summed.

[ number 1]

(formula 2)

[ number 2]

(formula 3)

WB(λ)＝E_sλ(λ)·B(λ)

In formula 3, E_sλ(λ) is the spectral irradiance of sunlight, and B (λ) is the blue light hazard function. E_sλ(λ), B (λ) and WB (λ) are described in JIS T7333, appendix C. In use of E_sλWhen the values are calculated as (λ), B (λ) and WB (λ), the measurement by the spectrophotometer is performed at a measurement wavelength interval (pitch) of 1 to 5nm at least in the wavelength range from 380nm to 500 nm.

The "dominant wavelength" is an index obtained by converting the wavelength of light perceived by the human eye into a numerical value, and is measured according to JIS Z8701.

The "visual reflectance" described later is measured in accordance with JIS T7334: 2011, and the "visual transmittance" is measured in accordance with JIS T7333: 2005.

The average reflectance in a wavelength region of 400 to 500nm measured on the object-side surface of the spectacle lens described later is an average reflectance with respect to light directly incident from the object-side surface (i.e., an incident angle of 0 °), and is also an arithmetic average of reflectances measured in a wavelength region of 400 to 500nm from the object side of the spectacle lens using a spectrophotometer. The average reflectance in a wavelength region of 400 to 500nm measured on the eyeball-side surface of the spectacle lens described later is the average reflectance with respect to light directly incident from the eyeball-side surface, and is also the arithmetic average of the reflectances measured from the eyeball side of the spectacle lens in the wavelength region of 400 to 500nm using a spectrophotometer. In the measurement, the measurement wavelength interval (pitch) can be arbitrarily set. For example, the thickness can be set in the range of 1 to 5 nm. Hereinafter, the average reflectance in the wavelength region of 400 to 500nm is also referred to as "blue light reflectance".

In the present invention and the present specification, "film thickness" is a physical film thickness. The film thickness can be determined by a known film thickness measuring method. For example, the film thickness can be obtained by converting the optical film thickness measured by an optical film thickness measuring instrument into a physical film thickness.

Hereinafter, the above-described eyeglass lens will be described in more detail.

< blue light blocking ratio >

The blue light blocking ratio of the spectacle lens is 21.0% or more. According to the spectacle lens having the blue light blocking rate of 21.0% or more, the wearer can reduce the amount of blue light incident on the eyes of the wearer and reduce the burden on the eyes of the wearer due to the blue light by wearing the spectacles having the spectacle lens. The blue light blocking ratio is preferably 21.5% or more, more preferably 22.0% or more, further preferably 22.5% or more, further preferably 23.0% or more, further preferably 23.5% or more, and further preferably 24.0% or more. The blue light blocking ratio may be 50.0% or less, 40.0% or less, or 30.0% or less, for example. However, from the viewpoint of reducing the amount of blue light incident on the eyes of the wearer, the higher the blue light blocking ratio, the more preferable, and therefore, the upper limit of the above example may be exceeded.

< dominant wavelength >

The main wavelength of the spectacle lens measured on the object side surface and the eyeball side surface is in the range of 500.0-550.0 nm. Since 500.0 to 550.0nm is a wavelength region of green light, a spectacle lens having a dominant wavelength in a wavelength region of 500.0 to 550.0nm on both surfaces can exhibit a green interference color when viewed from the surface side of any side. A general eyeglass lens has an antireflection film, but the general antireflection film is designed to exhibit a green interference color which is less likely to cause discomfort to human eyes. Therefore, the spectacle lens having a wavelength in the range of 500.0 to 550.0nm measured on each of both surfaces can exhibit the same appearance as that of a normal spectacle lens. The dominant wavelength measured on each surface of the spectacle lens may be in the range of 500.0 to 550.0 nm. In one embodiment, the dominant wavelength measured on each surface of the spectacle lens may be 510.0nm or more, for example. In one embodiment, the dominant wavelength measured on each surface of the spectacle lens may be, for example, 540.0nm or less.

The spectacle lens has a blue light blocking rate of 21.0% or more and a dominant wavelength measured at each of both surfaces in the range of 500.0 to 550.0nm, and is advantageous in that a lens base material includes a blue light absorbing compound and the spectacle lens has a multilayer film including a chromium layer as one layer of the multilayer film. The details of the lens base material and the multilayer film will be described later.

< lens substrate >

The lens base material included in the spectacle lens is not particularly limited as long as it contains a blue light absorbing compound. The lens substrate may be a plastic lens substrate or a glass lens substrate. The glass lens substrate may be, for example, a lens substrate made of inorganic glass. As the lens base material, a plastic lens base material is preferable from the viewpoint of light weight, being not easily broken, and easily introducing the blue light absorbing compound. Examples of the plastic lens base material include: a curable composition containing a (thio) epoxy compound having 1 or more disulfide bonds in the molecule is cured to obtain a cured product (generally referred to as a transparent resin) which is obtained by curing a curable composition containing a (thio) epoxy compound having 1 or more disulfide bonds in the molecule. The curable composition may also be referred to as a polymerizable composition. Further, as the lens base material, an undyed base material (colorless lens) or a dyed base material (dyed lens) may be used. The refractive index of the lens base material may be, for example, about 1.60 to 1.75. However, the refractive index of the lens base is not limited to the above range, and may be within the above range or may be deviated upward and downward from the above range. In the present invention and the present specification, the refractive index refers to a refractive index for light having a wavelength of 500 nm. The lens base material may be a lens having a refractive function (so-called dioptric lens) or a lens having no refractive function (so-called non-dioptric lens).

The spectacle lens may be any of various lenses such as a single focus lens, a multi-focus lens, and a progressive power lens. The kind of the lens is determined by the surface shape of both surfaces of the lens base material. In addition, the lens substrate surface may be any of a convex surface, a concave surface, and a flat surface. In a typical lens substrate and spectacle lens, the object-side surface is convex and the eyeball-side surface is concave. However, the present invention is not limited thereto.

(blue light absorbing Compound)

The above lens substrate contains a blue light absorbing compound. This is one of the reasons why the above-mentioned eyeglass lens can be provided with a blue light blocking ratio of 21.0% or more. Examples of blue light absorbing compounds include: various compounds having absorption in the wavelength region of blue light, such as benzotriazole compounds, benzophenone compounds, triazine compounds, and indole compounds, and the preferred blue light absorbing compounds include benzotriazole compounds and indole compounds, and the more preferred blue light absorbing compounds include benzotriazole compounds. The benzotriazole compound is preferably a benzotriazole compound represented by the following formula (1).

[ chemical formula 1]

In chemical formula (1), X represents a group that imparts a resonance effect. The substitution position of X is preferably the 5-position of the triazole ring.

Examples of X include a chlorine atom, a bromine atom, a fluorine atom, an iodine atom, a sulfo group, a carboxyl group, a nitrile group, an alkoxy group, a hydroxyl group, and an amino group, and among these, a chlorine atom, a bromine atom, and a fluorine atom are preferable, and a chlorine atom is more preferable.

In the formula (1), R₂Represents an alkyl group having 1 to 12 carbon atoms or an alkoxy group having 1 to 12 carbon atoms, and each of the alkyl group and the alkoxy group preferably has 1 to 8 carbon atoms, more preferably 2 to 8 carbon atoms, and further preferably 4 to 8 carbon atoms.

The alkyl and alkoxy groups may be branched or straight chain. Among the alkyl groups and alkoxy groups, the alkyl group is preferred.

Examples of the alkyl group include a methyl group, an ethyl group, an n-propyl group, an isopropyl group, an n-butyl group, a sec-butyl group, a tert-butyl group, a pentyl group, a hexyl group, a heptyl group, an n-octyl group, a 1,1,3, 3-tetramethylbutyl group, a nonyl group, a decyl group, an undecyl group, and a dodecyl group, and among these, at least 1 selected from the group consisting of an n-propyl group, an isopropyl group, an n-butyl group, a sec-butyl group, a tert-butyl group, and a 1,1,3, 3-tetramethylbutyl group is preferable, and an n-butyl group, a sec-butyl group, a tert-butyl group, and a 1,1,3, 3-tetramethylbutyl group are more preferable, and a tert-butyl group is further preferable.

Examples of alkoxy groups include methoxy, ethoxy, propoxy, butoxy, pentyloxy, hexyloxy, heptyloxy, octyloxy, nonyloxy, decyloxy, undecyloxy, dodecyloxy, of which butoxy or ethoxy is preferred.

In the formula (1), R₂The substitution position of (b) is preferably the 3-, 4-or 5-position based on the substitution position of the benzotriazolyl group.

In the formula (1), R₁Represents an alkyl group having 1 to 3 carbon atoms or an alkoxy group having 1 to 3 carbon atoms, and specific examples thereof include those for R₂Suitable groups of carbon atoms are listed in the above examples. Of these, methyl or ethyl is preferred.

In the chemical formula (1), m represents an integer of 0 or 1.

In the formula (1), R₂The substitution position of (b) is preferably the 5-position based on the substitution position of the benzotriazolyl group.

n represents R₃The valence number of (A) is 1 or 2.

In the formula (1), R₃Represents a hydrogen atom or a C1-8 valent hydrocarbon group. When n is 1, R₃Represents a hydrogen atom, and when n is 2, it represents a 2-valent hydrocarbon group having 1 to 8 carbon atoms.

As R₃Examples of the hydrocarbon group include an aliphatic hydrocarbon group and an aromatic hydrocarbon group. R₃The number of carbon atoms of the hydrocarbon group is 1 to 8, preferably 1 to 3.

As R₃Examples of the 2-valent hydrocarbon group include a methylene group, an ethylene group, a propylene group, a phenylene group, a tolylene group, and the like, and among them, a methylene group is preferable.

In the formula (1), R₃The substitution position of (b) is preferably the 3-position based on the substitution position of the benzotriazolyl group.

R₃Preferably a hydrogen atom, in which case n is 1.

The benzotriazole compound is preferably a benzotriazole compound represented by the following chemical formula (1-1).

[ chemical formula 2]

In the formula (1-1), R₁、R₂And m are the same as described above, and examples and preferred embodiments thereof are also the same as described above.

Specific examples of the benzotriazole compound represented by formula (1) include methylenebis [3- (5-chloro-2-benzotriazolyl) -5- (1,1,3, 3-tetramethylbutyl) -2-phenol ], methylenebis [3- (5-chloro-2-benzotriazolyl) -5-tert-butyl-2-phenol ], methylenebis [3- (5-chloro-2-benzotriazolyl) -5-ethoxy-2-phenol ], (methyl-ethyl-2-phenyl), Specific examples of the phenylenebis [3- (5-chloro-2-benzotriazolyl) -5- (1,1,3, 3-tetramethylbutyl) -2-phenol ] and the benzotriazole compound represented by the following formula (1-1).

Specific examples of the benzotriazole compound represented by the formula (1-1) include 2- (3-tert-butyl-2-hydroxy-5-methylphenyl) -5-chloro-2H-benzotriazole, 2- (3-tert-butyl-2-hydroxy-5-ethylphenyl) -5-chloro-2H-benzotriazole, 5-chloro-2- (3, 5-dimethyl-2-hydroxyphenyl) -2H-benzotriazole, 5-chloro-2- (3, 5-diethyl-2-hydroxyphenyl) -2H-benzotriazole, 5-chloro-2- (2-hydroxy-4-methoxyphenyl) -2H-benzotriazole, 2-trifluoromethyl-substituted phenyl group, 5-trifluoromethyl-2-hydroxy-5-methylphenyl) -2H-benzotriazole, and mixtures thereof, 5-chloro-2- (4-ethoxy-2-hydroxyphenyl) -2H-benzotriazole, 2- (4-butoxy-2-hydroxyphenyl) -5-chloro-2H-benzotriazole, and 5-chloro-2- (2-hydroxy-4-octyloxyphenyl) -2H-benzotriazole.

Of the above, 2- (3-tert-butyl-2-hydroxy-5-methylphenyl) -5-chloro-2H-benzotriazole, 2- (3-tert-butyl-2-hydroxy-5-ethylphenyl) -5-chloro-2H-benzotriazole, 5-chloro-2- (4-ethoxy-2-hydroxyphenyl) -2H-benzotriazole and 2- (4-butoxy-2-hydroxyphenyl) -5-chloro-2H-benzotriazole are preferable.

The lens base material may contain, for example, 0.05 to 3.00 parts by mass, preferably 0.05 to 2.50 parts by mass, more preferably 0.10 to 2.00 parts by mass, and still more preferably 0.30 to 2.00 parts by mass of the blue light absorbing compound per 100 parts by mass of the resin (or the polymerizable compound for obtaining the resin) constituting the lens base material. However, the content is not limited to the above range as long as the blue light blocking ratio of the spectacle lens can be set to 21.0% or more. As a method for producing a lens base material containing a blue light absorbing compound, a known method can be used. For example, in a method for obtaining a lens base material by curing a curable composition to form a molded article in the shape of a lens, a blue light absorbing compound is added to the curable composition to obtain a lens base material containing the blue light absorbing compound. Alternatively, the blue light-absorbing pigment can be introduced into the lens base material by various wet or dry methods generally used as a method for dyeing the lens base material. For example, an immersion method (immersion method) is an example of a wet method, and a sublimation dyeing method is an example of a dry method.

In addition, the lens base material may contain various additives that are generally contained in the lens base material of the spectacle lens. For example, when a curable composition containing a polymerizable compound and a blue light absorbing compound is cured to form a lens base material, one or more additives such as a polymerization catalyst described in, for example, japanese patent application laid-open nos. 7-063902, 7-104101, 9-208621, 9-255781, an internal mold release agent, an antioxidant, a fluorescent whitening agent, and a bluing agent described in japanese patent application laid-open nos. 1-163012 and 3-281312 may be added to the curable composition. The type and amount of these additives and the method of molding a lens base material using the curable composition can be applied by known techniques.

< multilayer film >

The spectacle lens has a multilayer film including a chromium layer having a film thickness of 1.0 to 10.0 nm. Hereinafter, a multilayer film including a chromium layer having a film thickness of 1.0 to 10.0nm is also referred to as "a multilayer film including a chromium layer", and other multilayer films are also referred to as "other multilayer films".

The multilayer film comprising a chromium layer may be located on the object side surface of the spectacle lens, on the eyeball side surface or on both surfaces. In addition, in one mode, a multilayer film including a chromium layer may be located on one surface of an eyeball-side surface and an object-side surface of the spectacle lens, and the other multilayer film may be located on the other surface. In another mode, a multilayer film including a chromium layer may be provided on one of an eyeball-side surface and an object-side surface of an eyeglass lens, and neither a multilayer film including a chromium layer nor other multilayer films may be provided on the other surface. In one embodiment, the multilayer film including a chromium layer may be located at least on the object side surface of the spectacle lens, or may be located only on the object side surface. The multilayer film including a chromium layer and other multilayer films may be directly on the surface of the lens base material, or may be indirectly on the surface of the lens base material with one or more other layers interposed therebetween. Examples of the layer that can be formed between the lens base material and the multilayer film include a polarizing layer, a light-adjusting layer, and a hard coat layer. By providing the hard coat layer, the durability (strength) of the eyeglass lens can be improved. The hard coat layer may be a cured layer obtained by curing the curable composition, for example. For details of the hard coat layer, for example, refer to paragraphs 0025 to 0028 and 0030 of japanese patent application laid-open No. 2012-128135. Further, an undercoat layer for improving adhesion may be formed between the lens base material and the multilayer film. For details of the undercoat layer, for example, see paragraphs 0029 to 0030 of Japanese patent application laid-open No. 2012-128135.

(multilayer film comprising chromium layer)

In the present invention and the present specification, the "chromium layer" refers to a film formed by depositing chromium (Cr) by an arbitrary film forming method, and is a film made of chromium (a simple substance of chromium element, that is, metallic chromium) if impurities inevitably mixed during film formation and known additives arbitrarily used for assisting film formation are removed. For example, the chromium layer may be a film in which chromium accounts for 90 to 100 mass% of the film, or a film in which chromium accounts for 95 to 100 mass% of the film. As the film formation method, a known film formation method can be used. From the viewpoint of ease of film formation, the film formation is preferably performed by vapor deposition. That is, the chromium layer is preferably a chromium deposited film. The vapor deposition film is a film formed by vapor deposition. The "vapor deposition" in the present invention and the present specification includes a dry method such as a vacuum vapor deposition method, an ion plating method, a sputtering method, and the like. In the vacuum vapor deposition method, an ion beam assist method in which an ion beam is simultaneously irradiated during vapor deposition may be used. The same applies to the formation of the high refractive index layer and the low refractive index layer described below.

The film thickness of the chromium layer contained in the multilayer film containing the chromium layer is 1.0 to 10.0 nm. Hereinafter, the chromium layer having a film thickness of 1.0 to 10.0nm is also referred to as "chromium layer". From the viewpoint of the transmittance (for example, visual transmittance) of the spectacle lens, the thickness of the chromium layer is preferably 9.0nm or less, more preferably 8.0nm or less, further preferably 7.0nm or less, further preferably 6.0nm or less, further preferably 5.0nm or less, further preferably 4.0nm or less, and further preferably 3.0nm or less. The thickness of the chromium layer is preferably 1.0nm or more, and more preferably 1.1nm or more, from the viewpoint of absorption efficiency of the chromium layer with respect to light having various wavelengths such as blue light. The multilayer film including a chromium layer preferably includes only one chromium layer having a film thickness of 1.0 to 10.0nm, but in one embodiment, the chromium layer is divided into two or more layers, and another layer may be present between the divided layers. In this case, the total film thickness of the chromium layers divided into two or more layers is 1.0 to 10.0 nm.

The multilayer film containing a chromium layer is preferably a multilayer film containing a chromium layer in a multilayer film in which a high refractive index layer and a low refractive index layer are alternately laminated. In the present invention and the present specification, "high" and "low" referring to "high refractive index" and "low refractive index" are relative expressions. That is, the high refractive index layer refers to a layer having a higher refractive index than the low refractive index layer included in the same multilayer film. In other words, a low refractive index layer refers to a layer having a lower refractive index than a high refractive index layer included in the same multilayer film. The refractive index of the high refractive index material constituting the high refractive index layer may be, for example, 1.60 or more (for example, in the range of 1.60 to 2.40), and the refractive index of the low refractive index material constituting the low refractive index layer may be, for example, 1.59 or less (for example, in the range of 1.37 to 1.59). However, as described above, since the expressions "high" and "low" relating to the high refractive index and the low refractive index are relative expressions, the refractive indices of the high refractive index material and the low refractive index material are not limited to the above ranges.

As the high refractive index material and the low refractive index material, an inorganic material, an organic material, or an organic-inorganic composite material can be used, and an inorganic material is preferable from the viewpoint of film forming property and the like. That is, the multilayer film containing a chromium layer is preferably an inorganic multilayer film. Specifically, the high refractive index material for forming the high refractive index layer may be formed of zirconium oxide (e.g., ZrO)₂) Tantalum oxide (Ta)₂O₅) Titanium oxide (e.g., TiO)₂) Aluminum oxide (Al)₂O₃) Yttrium oxide (e.g. Y)₂O₃) Hafnium oxide (e.g., HfO)₂) And niobium oxides (e.g., Nb)₂O₅) One or a mixture of two or more oxides selected from the group consisting of oxides. On the other hand, as a low refractive index material for forming the low refractive index layer, there may be mentioned a material selected from silicon oxides (e.g., SiO)₂) Magnesium fluoride (e.g., MgF)₂) And barium fluoride (e.g. BaF)₂) One kind of oxide or fluoride or a mixture of two or more kinds thereof selected from the group consisting of. In the above examples, the oxide and the fluoride are expressed by stoichiometric compositions for convenience, but a material in which oxygen or fluorine is absent or excess from the stoichiometric composition may be used as the high refractive index material or the low refractive index material.

Preferably, the high refractive index layer is a film containing a high refractive index material as a main component, and the low refractive index layer is a film containing a low refractive index material as a main component. The main component is a component that occupies the largest proportion in the film, and is usually about 50 to 100 mass%, more preferably about 90 to 100 mass%, based on the mass of the film. Such a film (e.g., a vapor deposition film) can be formed by forming a film using a film forming material (e.g., a vapor deposition source) containing the high refractive index material or the low refractive index material as a main component. The same applies to the main component relating to the film-forming material. The film and the film-forming material may contain impurities inevitably mixed therein, and may contain other components, for example, other inorganic substances and known additive components which function to assist film formation, within a range where the functions of the main component are not impaired. The film formation can be performed by a known film formation method, and is preferably performed by vapor deposition from the viewpoint of ease of film formation.

The film thickness of the high refractive index layer and the film thickness of the low refractive index layer may be determined depending on the layer structure. Specifically, the combination of layers included in the multilayer film and the film thickness of each layer may be determined by optical simulation using a known method based on the refractive index of a film forming material for forming the high refractive index layer and the low refractive index layer and desired reflection characteristics and transmission characteristics to be imparted to the spectacle lens by providing the multilayer film.

Examples of the layer structure of the multilayer film containing a chromium layer include a structure in which the layers are laminated in the following order from the lens base material side to the lens outermost surface side:

a structure in which a first layer (high refractive index layer)/a second layer (chromium layer)/a third layer (low refractive index layer)/a fourth layer (high refractive index layer)/a fifth layer (low refractive index layer) are laminated in this order;

the optical film has a structure of a first layer (low refractive index layer)/a second layer (high refractive index layer)/a third layer (low refractive index layer)/a fourth layer (high refractive index layer)/a fifth layer (chromium layer)/a sixth layer (low refractive index layer)/a seventh layer (high refractive index layer)/an eighth layer (low refractive index layer).

In addition, in the above-described example of the layer structure, the expression "/" is used in the meaning of: the case where the layer described on the left side of "/" is adjacent to the layer described on the right side thereof, and the case where a conductive oxide layer described later exists between the layer described on the left side of "/" and the layer described on the right side thereof are included.

As a preferable example of the combination of the low refractive index layer and the high refractive index layer included in the multilayer film including the chromium layer, a combination of a film (low refractive index layer) mainly composed of silicon oxide and a film (high refractive index layer) mainly composed of zirconium oxide can be cited.

The multilayer film including a chromium layer may include one or more layers containing a conductive oxide as a main component (conductive oxide layer), preferably a vapor deposited film of a conductive oxide formed by vapor deposition using a vapor deposition source containing a conductive oxide as a main component, at any position of the multilayer film, in addition to the chromium layer, the high refractive index layer, and the low refractive index layer described above. This is the same for other multilayer films. The main components described in relation to the conductive oxide layer are also the same as described above.

The conductive oxide layer is preferably a tin-doped indium oxide (ITO) layer having a thickness of 10.0nm or less, a tin oxide layer having a thickness of 10.0nm or less, and a titanium oxide layer having a thickness of 10.0nm or less, from the viewpoint of transparency of the spectacle lens. The tin-doped indium oxide (ITO) layer refers to a layer containing ITO as a main component. The same applies to the tin oxide layer and the titanium oxide layer. The multilayer film containing a chromium layer and other multilayer films contain a conductive oxide layer, and thus can prevent the charging of the spectacle lens and the adhesion of dust and dirt. In the present invention and the present specification, the "high refractive index layer" and the "low refractive index layer" included in the multilayer film containing a chromium layer and other multilayer films do not take into consideration the tin-doped indium oxide (ITO) layer having a film thickness of 10.0nm or less, the tin oxide layer having a film thickness of 10.0nm or less, and the titanium oxide layer having a film thickness of 10.0nm or less. That is, even in the case where one or more of these layers are included in a multilayer film containing a chromium layer or other multilayer films, these layers are not regarded as "high refractive index layer" or "low refractive index layer". The thickness of the conductive oxide layer may be, for example, 0.1nm or more, and is 10.0nm or less.

(other multilayer films)

When the above-mentioned spectacle lens has a multilayer film containing a chromium layer on one of the object side surface and the eyeball side surface and another multilayer film on the other surface, it is preferable to form a multilayer film which is generally provided as an antireflection film on the spectacle lens as the other multilayer film. The anti-reflective film may be a multilayer film exhibiting an anti-reflective effect on visible light (light having a wavelength of 380 to 780 nm). The structure of such multilayer films is well known. Still other multilayer films may be, for example, inorganic multilayer films. The other multilayer film may be, for example, a multilayer film in which 3 to 10 layers in total are alternately stacked with a high refractive index layer and a low refractive index layer. The details of the high refractive index layer and the low refractive index layer are as described above. As a preferable example of the combination of the low refractive index layer and the high refractive index layer included in the other multilayer film, a combination of a film containing silicon oxide as a main component (low refractive index layer) and a film containing zirconium oxide as a main component (high refractive index layer) can be cited.

In addition, a functional film may be further formed on the multilayer film containing the chromium layer and/or other multilayer films. Examples of such functional films include various functional films such as hydrophobic or hydrophilic antifouling films and antifogging films. For these functional films, any known technique can be applied.

< reflection characteristics and Transmission characteristics of spectacle lens >

(blue light reflectance)

As described above, if a multilayer film having a property of strongly reflecting blue light is provided on the surface of the lens base material, the appearance of the surface of the eyeglass lens having one side of the multilayer film appears blue. In contrast, in the above-mentioned spectacle lens, the blue light-absorbing compound and the multilayer film having the chromium-containing layer described above are contained in the lens base material, and thus the blue light-blocking ratio of 21.0% or more can be achieved without increasing the blue light reflectance on the surface of the spectacle lens. In the above-described spectacle lens, at least one (preferably both) of the blue light reflectance measured on the object-side surface and the blue light reflectance measured on the eyeball-side surface of the spectacle lens is preferably 2.00% or less, more preferably less than 2.00%, further preferably 1.50% or less, and still further preferably 1.00% or less. The blue light reflectance may be set to, for example, 0.10% or more, but may be lower than this.

(visual reflectance)

From the viewpoint of improving the appearance quality of the spectacle lens, it is preferable that the visual reflectance measured on the object-side surface of the spectacle lens is low. In addition, from the viewpoint of improving the wearing feeling of the spectacle lens, it is preferable that the visual reflectance measured on the eyeball-side surface of the spectacle lens is low. From the viewpoint of improving the appearance quality, the visual reflectance measured on the object-side surface of the spectacle lens is preferably 1.80% or less, more preferably 1.50% or less, and still more preferably 1.30% or less. On the other hand, from the viewpoint of improving wearing comfort, the visual reflectance measured on the eyeball-side surface of the spectacle lens is preferably 1.80% or less, more preferably 1.50% or less, and still more preferably 1.30% or less.

The visual reflectance measured on the object-side surface and the visual reflectance measured on the eyeball-side surface of the spectacle lens may be, for example, 0.10% or more, 0.20% or more, 0.30% or more, 0.40% or more, or 0.50% or more, respectively, but the lower limit is an example and is not limited thereto. The above-described visual reflectance can be achieved by film design of a chromium-containing layer multilayer film or other multilayer films provided on the object-side surface and/or the eyeball-side surface of the lens base material. The film design can be performed by optical simulation by a known method.

(visual transmittance)

In one embodiment, the above-described spectacle lens can be a spectacle lens excellent in transparency having a high visual transmittance. The visual transmittance of the spectacle lens is preferably 80.0% or more, more preferably 85.0% or more. The visual transmittance of the spectacle lens may be, for example, 95.0% or less, or 90.0% or less. By forming the chromium layer included in the multilayer film containing a chromium layer as a thin film (specifically, a film thickness of 1.0 to 10.0nm), the blue light blocking ratio and dominant wavelength described above can be realized without significantly reducing the visual transmittance.

[ spectacles ]

Another aspect of the present invention relates to eyeglasses having the eyeglass lens according to the above-described aspect of the present invention. The details of the spectacle lenses included in the spectacles are as described above. The eyeglass lens can reduce the burden on the eyes of the eyeglass wearer due to blue light by having the eyeglass lens. In addition, since the dominant wavelength measured on both surfaces of the spectacle lens of the above spectacles is in the range of 500 to 550nm, the interference color of green can be expressed similarly to a general spectacle lens. The configuration of the eyeglasses such as the frame is not particularly limited, and known techniques can be applied.

Examples

The present invention is further illustrated by the following examples. However, the present invention is not limited to the embodiment shown in the examples.

[ example 1]

(1) Production of lens base Material comprising blue light-absorbing Compound (lens base Material A)

After 100.00 parts by mass of bis (. beta. -thienylcyclopropane) sulfide and 0.40 parts by mass of 2- (3-tert-butyl-2-hydroxy-5-methylphenyl) -5-chloro-2H-benzotriazole as a blue light absorbing compound were stirred and mixed, 0.05 parts by mass of tetra-n-butylphosphine bromide as a catalyst was added thereto, and the mixture was stirred and mixed under reduced pressure of 10mmHg for 3 minutes, a monomer composition for a lens (curable composition) was prepared. Then, the monomer composition for a lens was injected into a lens-molding mold (set to 0.00D and a thickness of 2.0mm) composed of a glass mold and a resin spacer prepared in advance, and polymerized in an electric furnace at an in-furnace temperature of 20 ℃ to 100 ℃ for 20 hours. After completion of the polymerization, the spacer and the mold were removed, and then heat-treated at 110 ℃ for 1 hour to obtain a plastic lens (lens base material a). The object-side surface and the eyeball-side surface of the obtained lens base material a were convex and concave, respectively, and the refractive index was 1.60.

(2) Film formation of multilayer film

After both surfaces of the lens base material a were optically processed (polished) to optical surfaces, hard coat layers (cured layers obtained by curing the curable composition) having a film thickness of 3000nm were formed on both surfaces, respectively.

A multilayer deposited film having a structure shown in Table 1 (tables 1-1 and 1-2) was formed on the hard coat layer surface on the object side and the hard coat layer surface on the eyeball side by ion-assisted deposition using oxygen and nitrogen as assist gases, respectively.

In this way, the spectacle lens of example 1 having a multilayer film containing a chromium layer on the object side and another multilayer film (containing no chromium layer) on the eyeball side was obtained.

In this example, the multilayer vapor deposited film was formed such that the outermost layer on the front surface side of the spectacle lens was a layer described in the bottom column of table 1, by laminating 1 layer and 2 layers in this order from the lens base material side (hard coat layer side) to the front surface side of the spectacle lens. In this example, a film was formed using a deposition source (film forming material) made of an oxide or chromium shown in table 1, except for impurities that may be inevitably mixed. The refractive index of each oxide and the film thickness of each layer are shown in table 1. These cases are also the same in the examples and comparative examples described later.

[ example 2]

A multilayer vapor-deposited film having a structure shown in Table 2 (tables 2-1 and 2-2) was formed on the hard coat layer surface on the object side and the hard coat layer surface on the eyeball side by ion-assisted vapor deposition using oxygen and nitrogen as auxiliary gases, respectively.

Thus, the spectacle lens of example 2 having a multilayer film containing a chromium layer on the object side and another multilayer film (not containing a chromium layer) on the eyeball side was obtained.

Comparative example 1

On the hard coat layer surface on the object side and the hard coat layer surface on the eyeball side, a multilayer vapor deposited film having a structure shown in table 3 was formed by ion-assisted vapor deposition using oxygen gas and nitrogen gas as auxiliary gases, respectively.

Thus, the spectacle lens of comparative example 1 having other multilayer films (not containing chromium layers) on the object side and the eyeball side was obtained.

Comparative example 2

A multilayer deposited film having a structure shown in table 4 was formed by ion-assisted evaporation using oxygen and nitrogen as assist gases on the hard coat layer surface on the object side and on the hard coat layer surface on the eyeball side, respectively.

Thus, the spectacle lens of comparative example 2 having other multilayer films (not containing chromium layers) on the object side and the eyeball side was obtained.

The film thicknesses shown in tables 1 to 4 are values (unit: nm) obtained by converting the optical film thickness measured by the optical film thickness measuring instrument into a physical film thickness. The thickness of each layer is controlled by the film formation time.

[ tables 1-1]

[ tables 1-2]

[ Table 2-1]

[ tables 2-2]

[ Table 3]

[ Table 4]

[ evaluation method ]

<1. blue light blocking ratio and visual transmittance of spectacle lens >

The direct incidence transmission spectral characteristics of each of the spectacle lenses of examples and comparative examples were measured at a pitch of 1nm from a wavelength of 380nm to 780nm by using a spectrophotometer U4100 manufactured by hitachi, so that light was incident from the object-side surface side (convex side) of the spectacle lens to the optical center of the object-side surface.

Using the measurement results, the blue light blocking ratio and the visual transmittance were obtained by the methods described above.

<2. reflectance of blue light and reflectance of visual light measured on object-side surface and eyeball-side surface of spectacle lens >

The direct incidence reflection spectral characteristics of the optical center of the object side surface (convex side) were measured from the object side of each of the spectacle lenses of examples and comparative examples.

Using the measurement results, the blue reflectance and the visual reflectance of the object side surface in the wavelength region of 400 to 500nm were obtained by the methods described above.

Further, the direct incidence reflection spectral characteristics of the optical center of the eyeball-side surface (concave surface side) were measured from the eyeball side of each of the spectacle lenses of the examples and comparative examples.

Using the measurement results, the blue light reflectance and the visual reflectance of the eyeball surface in the wavelength region of 400 to 500nm were obtained by the methods described above.

The above measurement was carried out using a lens reflectance measuring instrument USPM-RU manufactured by Olympus corporation (measurement pitch: 1 nm).

<3. dominant wavelength >

Using the measurement results of the direct incidence reflection spectroscopic characteristics obtained with respect to the object side surface of the eyeglass lens in the above 2, the dominant wavelength measured on the object side surface of the eyeglass lens was obtained according to JIS Z8701.

Further, using the measurement results of the direct incidence reflection spectrum characteristics obtained for the eyeball surface of the spectacle lens in the above 2, the dominant wavelength measured for the eyeball surface of the spectacle lens was obtained according to JIS Z8701.

<4. interference color >

The observer visually observes each of the spectacle lenses of the examples and comparative examples from the object side (convex side) of the spectacle lens to confirm the interference color.

The above results are shown in Table 5.

[ Table 5]

Finally, the above-described modes are summarized.

According to one aspect, there is provided an eyeglass lens comprising a lens base material containing a blue light absorbing compound and a multilayer film comprising a chromium layer having a film thickness of 1.0 to 10.0nm, wherein the blue light blocking rate is 21.0% or more; the dominant wavelength measured at the object side surface of the spectacle lens is in the range of 500.0 to 550.0nm, and the dominant wavelength measured at the eyeball side surface of the spectacle lens is in the range of 500.0 to 550.0 nm.

The spectacle lens can reduce the burden on eyes by blue light and can present the same appearance as that of a general spectacle lens.

In one mode, for the above-mentioned spectacle lens, a multilayer film is located on the object side surface and the eyeball side surface of the lens base material, and a multilayer film containing the above-mentioned chromium layer is a multilayer film located on the object side surface of the lens base material.

According to one aspect, there is provided eyewear having the above eyewear lenses.

Two or more of the various embodiments described in the present specification may be combined in any combination.

The disclosed embodiments should be considered in all respects as illustrative and not restrictive. The scope of the present invention is indicated by the claims rather than the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are intended to be embraced therein.

Industrial applicability

The present invention is useful in the field of spectacle lenses and the manufacture of spectacles.

Claims

1. An eyeglass lens, comprising:

a lens substrate comprising a blue light absorbing compound; and

the blue light blocking rate is more than 21.0 percent,

the dominant wavelength measured on the eyeball-side surface of the spectacle lens is in the range of 500.0 to 550.0nm,

the dominant wavelength is an index obtained by converting the wavelength of the color of light perceived by the human eye into a numerical value, and is obtained according to JIS Z8701 using the measurement result of the direct incidence reflection spectral characteristics obtained on the object-side surface or the eyeball-side surface of the spectacle lens,

the visual reflectance measured on the object-side surface of the spectacle lens is 1.80% or less.

2. The eyeglass lens of claim 1, wherein,

a multilayer film on the object-side surface and on the eyeball-side surface of the lens base material,

the multilayer film comprising the chromium layer is a multilayer film on the object side surface of the lens substrate.

3. The eyeglass lens of claim 1, wherein,

the blue light blocking rate is more than 22.0%.

4. The eyeglass lens of claim 1, wherein,

the blue light blocking rate is more than 23.0%.

5. The eyeglass lens of claim 1, wherein,

the blue light blocking rate is more than 24.0%.

6. The eyeglass lens of claim 1, wherein,

the blue light blocking ratio is 50.0% or less.

7. The eyeglass lens of claim 1, wherein,

the blue light blocking ratio is 40.0% or less.

8. The eyeglass lens of claim 1, wherein,

the blue light blocking ratio is 30.0% or less.

9. The eyeglass lens of claim 1, wherein,

the lens substrate is a plastic lens substrate or a glass lens substrate.

10. The eyeglass lens of claim 9, wherein,

the glass lens substrate is a lens substrate made of inorganic glass.

11. The eyeglass lens of claim 1, wherein,

the lens base material contains 0.05-3.00 parts by mass of a blue light absorbing compound per 100 parts by mass of a resin constituting the lens base material.

12. The eyeglass lens of claim 1, wherein,

the lens base material contains 0.10 to 2.00 parts by mass of a blue light absorbing compound per 100 parts by mass of a resin constituting the lens base material.

13. The eyeglass lens of claim 1, wherein,

the lens base material contains 0.30 to 2.00 parts by mass of a blue light absorbing compound per 100 parts by mass of a resin constituting the lens base material.

14. The eyeglass lens of claim 1, wherein,

the thickness of the chromium layer is 9.0nm or less.

15. The eyeglass lens of claim 1, wherein,

the thickness of the chromium layer is 8.0nm or less.

16. The eyeglass lens of claim 1, wherein,

the thickness of the chromium layer is 7.0nm or less.

17. The eyeglass lens of claim 1, wherein,

the thickness of the chromium layer is 6.0nm or less.

18. The eyeglass lens of claim 1, wherein,

the thickness of the chromium layer is 5.0nm or less.

19. The eyeglass lens of claim 1, wherein,

the thickness of the chromium layer is 4.0nm or less.

20. The eyeglass lens of claim 1, wherein,

the thickness of the chromium layer is 3.0nm or less.

21. The eyeglass lens of claim 1, wherein,

in the spectacle lens, at least one of a blue light reflectance measured on an object side surface and a blue light reflectance measured on an eyeball side surface of the spectacle lens is 2.00% or less.

22. The eyeglass lens of claim 1, wherein,

in the eyeglass lens, at least one of a blue light reflectance measured on an object side surface and a blue light reflectance measured on an eyeball side surface of the eyeglass lens is 1.50% or less.

23. The eyeglass lens of claim 1, wherein,

in the spectacle lens, at least one of a blue light reflectance measured on an object side surface and a blue light reflectance measured on an eyeball side surface of the spectacle lens is 1.00% or less.

24. The eyeglass lens of claim 1, wherein,

in the spectacle lens, at least one of a blue light reflectance measured on an object side surface and a blue light reflectance measured on an eyeball side surface of the spectacle lens is 0.10% or more.

25. The eyeglass lens of claim 1, wherein,

the visual reflectance measured on the object-side surface of the spectacle lens is 1.50% or less.

26. The eyeglass lens of claim 1, wherein,

the visual reflectance measured on the object-side surface of the spectacle lens is 1.30% or less.

27. The eyeglass lens of claim 1, wherein,

the visual reflectance measured on the eyeball-side surface of the spectacle lens is 1.80% or less.

28. The eyeglass lens of claim 1, wherein,

the visual reflectance measured on the eyeball-side surface of the spectacle lens is 1.50% or less.

29. The eyeglass lens of claim 1, wherein,

the visual reflectance measured on the eyeball-side surface of the spectacle lens is 1.30% or less.

30. The eyeglass lens of claim 1, wherein,

the visual reflectance measured on the object-side surface and the visual reflectance measured on the eyeball-side surface of the spectacle lens are each 0.10% or more.

31. The eyeglass lens of claim 1, wherein,

the visual reflectance measured on the object-side surface and the visual reflectance measured on the eyeball-side surface of the spectacle lens are each 0.20% or more.

32. The eyeglass lens of claim 1, wherein,

the visual reflectance measured on the object-side surface and the visual reflectance measured on the eyeball-side surface of the spectacle lens are each 0.30% or more.

33. The eyeglass lens of claim 1, wherein,

the visual reflectance measured on the object-side surface and the visual reflectance measured on the eyeball-side surface of the spectacle lens are each 0.40% or more.

34. The eyeglass lens of claim 1, wherein,

the visual reflectance measured on the object-side surface and the visual reflectance measured on the eyeball-side surface of the spectacle lens are each 0.50% or more.

35. The eyeglass lens of claim 1, wherein,

the visual transmittance of the spectacle lens is more than 80.0%.

36. The eyeglass lens of claim 1, wherein,

the visual transmittance of the spectacle lens is more than 85.0%.

37. The eyeglass lens of claim 1, wherein,

the spectacle lens has a visual transmittance of 95.0% or less.

38. The eyeglass lens of claim 1, wherein,

the spectacle lens has a visual transmittance of 90.0% or less.

39. The eyeglass lens of claim 1, wherein,

the main wavelength measured on the object side surface and the eyeball side surface of the spectacle lens is 510.0nm or more.

40. The eyeglass lens of claim 1, wherein,

the main wavelength measured on the object side surface and eyeball side surface of the spectacle lens is 540.0nm or more.

41. An eyeglass having an eyeglass lens as claimed in any of claims 1 to 40.