CN111138627B - Graphene oxide/carbon nanotube high-strength polyurethane insulation board and preparation method thereof - Google Patents
Graphene oxide/carbon nanotube high-strength polyurethane insulation board and preparation method thereof Download PDFInfo
- Publication number
- CN111138627B CN111138627B CN202010020818.5A CN202010020818A CN111138627B CN 111138627 B CN111138627 B CN 111138627B CN 202010020818 A CN202010020818 A CN 202010020818A CN 111138627 B CN111138627 B CN 111138627B
- Authority
- CN
- China
- Prior art keywords
- graphene oxide
- isophorone diisocyanate
- carbon nanotube
- graphene
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
- C08G18/751—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
- C08G18/752—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
- C08G18/753—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
- C08G18/755—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4829—Polyethers containing at least three hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
- C08J9/146—Halogen containing compounds containing carbon, halogen and hydrogen only only fluorine as halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
- C08K3/041—Carbon nanotubes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
- C08K3/042—Graphene or derivatives, e.g. graphene oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2101/00—Manufacture of cellular products
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
- C08J2203/142—Halogenated saturated hydrocarbons, e.g. H3C-CF3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/16—Unsaturated hydrocarbons
- C08J2203/162—Halogenated unsaturated hydrocarbons, e.g. H2C=CF2
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Nanotechnology (AREA)
- Polyurethanes Or Polyureas (AREA)
- Carbon And Carbon Compounds (AREA)
Abstract
Description
Claims (9)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202010020818.5A CN111138627B (en) | 2020-01-09 | 2020-01-09 | Graphene oxide/carbon nanotube high-strength polyurethane insulation board and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202010020818.5A CN111138627B (en) | 2020-01-09 | 2020-01-09 | Graphene oxide/carbon nanotube high-strength polyurethane insulation board and preparation method thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CN111138627A CN111138627A (en) | 2020-05-12 |
CN111138627B true CN111138627B (en) | 2022-04-22 |
Family
ID=70524113
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202010020818.5A Active CN111138627B (en) | 2020-01-09 | 2020-01-09 | Graphene oxide/carbon nanotube high-strength polyurethane insulation board and preparation method thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN111138627B (en) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112980415B (en) * | 2021-02-19 | 2021-11-16 | 中国石油大学(华东) | Multi-grafting-site nano carbon material and active nano carbon material, preparation methods thereof and oil displacement system for ultra-low permeability reservoir |
CN113817242B (en) * | 2021-09-24 | 2023-06-13 | 五邑大学 | Conductive flexible material and preparation method and application thereof |
CN114395160B (en) * | 2022-02-15 | 2023-01-20 | 泗阳蓝天新材料科技股份有限公司 | Graphene modified polyurethane composite material and preparation method thereof |
CN116253859A (en) * | 2023-03-15 | 2023-06-13 | 无锡墨诺半导体科技有限公司 | Preparation method of graphene modified polyurethane electromagnetic shielding material |
CN116462825A (en) * | 2023-03-29 | 2023-07-21 | 佛山市惠安家居用品有限公司 | Smoke-inhibiting flame-retardant polyurethane soft foam and preparation method thereof |
CN116517129A (en) * | 2023-05-11 | 2023-08-01 | 唐宽 | Modified polyurethane foam heat insulation board and preparation method thereof |
CN117584268B (en) * | 2024-01-19 | 2024-03-19 | 山东金锐住宅工业科技有限公司 | Steel wire mesh frame insulation board containing modified polyurethane and preparation method thereof |
Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103408718A (en) * | 2013-08-05 | 2013-11-27 | 江苏大学 | Preparation method and application of graphene oxide-polyurethane foam material |
KR20140094861A (en) * | 2013-01-23 | 2014-07-31 | 전자부품연구원 | Method of graphene-cnt complex structure for water treatment and membrane using the same |
CN104844781A (en) * | 2015-05-29 | 2015-08-19 | 杨秀莲 | Graphene chemically-modified hard polyurethane foam |
CN106629668A (en) * | 2016-12-27 | 2017-05-10 | 江汉大学 | Preparation method of three-dimensional-structure graphene/carbon nanotube hybrid carbon material |
CN106632958A (en) * | 2016-09-29 | 2017-05-10 | 四川大学 | Method for preparing a flame-retardant water-based polyurethane based on reactive graphene flame retardant |
CN107681159A (en) * | 2017-08-17 | 2018-02-09 | 清华大学 | A kind of metal foil collector of battery |
CN107722232A (en) * | 2017-11-06 | 2018-02-23 | 东北林业大学 | A kind of preparation method of graphene oxide/sodium lignin sulfonate modified polyurethane rigid foam material |
CN108069420A (en) * | 2017-11-24 | 2018-05-25 | 江苏先丰纳米材料科技有限公司 | A kind of preparation method of graphene/graphene oxide-carbon nano tube compound material |
JP2018127567A (en) * | 2017-02-10 | 2018-08-16 | 株式会社イノアックコーポレーション | Flexible polyurethane foam and manufacturing method therefor |
US10259923B1 (en) * | 2016-03-03 | 2019-04-16 | Phillips Intellectual Properties, Llc | Electrically-conductive compositions and methods of using them with pipelines |
CN110240690A (en) * | 2019-05-23 | 2019-09-17 | 江苏江山红化纤有限责任公司 | Graphene modified polyurethane foam and preparation method thereof |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101400686B1 (en) * | 2009-09-24 | 2014-05-29 | 한국과학기술원 | 3-Dimensional Nano Structures Composed of Nano Materials Grown on Mechanically Compliant Graphene Films and Method for Preparing the Same |
CN103910349B (en) * | 2014-03-13 | 2015-11-11 | 吉林大学 | A kind of method preparing the directed bamboo-like carbon nano tubes/Graphene complex metal oxides of nitrating |
CA3001424A1 (en) * | 2015-10-27 | 2017-05-04 | Jinan Shengquan Group Share Holding Co., Ltd. | Composite polyurethane foam containing graphene, and preparation method and use |
EP3538611B1 (en) * | 2016-11-09 | 2023-08-02 | Basf Se | Polyurethane comprising graphene nano structure |
CN107022056B (en) * | 2017-05-12 | 2019-07-16 | 湖北大学 | A kind of redox graphene/polyurethane nano composite foam and its preparation method and application |
CN109573982A (en) * | 2017-09-28 | 2019-04-05 | 江苏津谊新能源科技有限公司 | A kind of three-dimensional structure carbon material |
-
2020
- 2020-01-09 CN CN202010020818.5A patent/CN111138627B/en active Active
Patent Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20140094861A (en) * | 2013-01-23 | 2014-07-31 | 전자부품연구원 | Method of graphene-cnt complex structure for water treatment and membrane using the same |
CN103408718A (en) * | 2013-08-05 | 2013-11-27 | 江苏大学 | Preparation method and application of graphene oxide-polyurethane foam material |
CN104844781A (en) * | 2015-05-29 | 2015-08-19 | 杨秀莲 | Graphene chemically-modified hard polyurethane foam |
US10259923B1 (en) * | 2016-03-03 | 2019-04-16 | Phillips Intellectual Properties, Llc | Electrically-conductive compositions and methods of using them with pipelines |
CN106632958A (en) * | 2016-09-29 | 2017-05-10 | 四川大学 | Method for preparing a flame-retardant water-based polyurethane based on reactive graphene flame retardant |
CN106629668A (en) * | 2016-12-27 | 2017-05-10 | 江汉大学 | Preparation method of three-dimensional-structure graphene/carbon nanotube hybrid carbon material |
JP2018127567A (en) * | 2017-02-10 | 2018-08-16 | 株式会社イノアックコーポレーション | Flexible polyurethane foam and manufacturing method therefor |
CN107681159A (en) * | 2017-08-17 | 2018-02-09 | 清华大学 | A kind of metal foil collector of battery |
CN107722232A (en) * | 2017-11-06 | 2018-02-23 | 东北林业大学 | A kind of preparation method of graphene oxide/sodium lignin sulfonate modified polyurethane rigid foam material |
CN108069420A (en) * | 2017-11-24 | 2018-05-25 | 江苏先丰纳米材料科技有限公司 | A kind of preparation method of graphene/graphene oxide-carbon nano tube compound material |
CN110240690A (en) * | 2019-05-23 | 2019-09-17 | 江苏江山红化纤有限责任公司 | Graphene modified polyurethane foam and preparation method thereof |
Non-Patent Citations (2)
Title |
---|
功能化氧化石墨烯/聚氨酯泡沫材料的制备及性能研究;谢毓;《中国优秀硕士学位论文全文数据库 工程科技Ⅰ辑》;20180515(第5期);B016-157 * |
石墨及其衍生物对异氰酸酯基聚酰亚胺泡沬阻燃性影响;张超;《中国优秀硕士学位论文全文数据库 工程科技Ⅰ辑》;20180315(第3期);B016-170 * |
Also Published As
Publication number | Publication date |
---|---|
CN111138627A (en) | 2020-05-12 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN111138627B (en) | Graphene oxide/carbon nanotube high-strength polyurethane insulation board and preparation method thereof | |
Ge et al. | High-strength and morphology-controlled aerogel based on carboxymethyl cellulose and graphene oxide | |
Bandarian et al. | Thermal, mechanical and acoustic damping properties of flexible open‐cell polyurethane/multi‐walled carbon nanotube foams: effect of surface functionality of nanotubes | |
Kim et al. | Synthesis of nanoparticle-enhanced polyurethane foams and evaluation of mechanical characteristics | |
Verdejo et al. | Physical properties of silicone foams filled with carbon nanotubes and functionalized graphene sheets | |
Lyu et al. | Enhanced interfacial and mechanical properties of carbon fiber/PEEK composites by hydroxylated PEEK and carbon nanotubes | |
Xu et al. | Novel preparation and mechanical properties of rigid polyurethane foam/organoclay nanocomposites | |
CN111138150A (en) | Preparation method of graphene oxide/carbon nanotube high-strength building concrete | |
Bernardo et al. | Highly anisotropic crosslinked HDPE foams with a controlled anisotropy ratio: Production and characterization of the cellular structure and mechanical properties | |
Strauss et al. | Supercritical CO2 processed polystyrene nanocomposite foams | |
Li et al. | Preparation and characterization of novel cellular/nonporous foam structures derived from tannin furanic resin | |
Guo et al. | Preparation, characterization of highly dispersed reduced graphene oxide/epoxy resin and its application in alkali-activated slag composites | |
Ji et al. | Fabrication and properties of novel porous CuAlMn shape memory alloys and polymer/CuAlMn composites | |
Li et al. | Fabrication and properties of antimicrobial flexible nanocomposite polyurethane foams with in situ generated copper nanoparticles | |
Jia et al. | Ultra-light poly (lactic acid)/SiO2 aerogel composite foam: A fully biodegradable and full life-cycle sustainable insulation material | |
Wang et al. | Morphologies and properties of epoxy/multi-walled carbon nanotube nanocomposite foams prepared through the free-foaming and limited-foaming process | |
Liu et al. | Enhanced thermal shrinkage behavior of phenolic-derived carbon aerogel-reinforced by HNTs with superior compressive strength performance | |
Tran et al. | Influence of cellulose nanocrystal on the cryogenic mechanical behavior and thermal conductivity of polyurethane composite | |
Antunes et al. | Esparto wool as reinforcement in hybrid polyurethane composite foams | |
Wu et al. | Preparation and properties of thermoplastic polyurethane foams with bimodal structure based on TPU/PDMS blends | |
CN112358648A (en) | High-strength low-thermal-conductivity polyimide foam composite material and preparation method thereof | |
Qi et al. | Mechanically robust and thermally insulating polyarylene ether nitrile with a bone-like structure | |
CN114854083A (en) | Ultra-light and hydrophobic polyimide aerogel and preparation method and application thereof | |
Zhang et al. | Reinforcement of recycled paint slag hybrid-filled lightweight calcium sulphate whisker/PVC foam composites | |
US20080281011A1 (en) | High temperature resistant, structural polymer foam |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
TA01 | Transfer of patent application right | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20210421 Address after: Room 2223, 22 / F, building 12, wanchuang center, 433 Xuanwuhu Road, Urumqi Economic and Technological Development Zone, 830000 Xinjiang Uygur Autonomous Region Applicant after: Xinjiang yiyuanda Photoelectric Technology Co.,Ltd. Address before: 830000 room 2902, No. 387, Guangming Road, Tianshan District, Urumqi, Xinjiang Uygur Autonomous Region Applicant before: Xinjiang Hongyu Zhixiang Engineering Consulting Co.,Ltd. |
|
GR01 | Patent grant | ||
GR01 | Patent grant | ||
CP01 | Change in the name or title of a patent holder | ||
CP01 | Change in the name or title of a patent holder |
Address after: Room 2223, 22 / F, building 12, wanchuang center, 433 Xuanwuhu Road, Urumqi Economic and Technological Development Zone, 830000 Xinjiang Uygur Autonomous Region Patentee after: Xinjiang Aodi Construction Engineering Co.,Ltd. Address before: Room 2223, 22 / F, building 12, wanchuang center, 433 Xuanwuhu Road, Urumqi Economic and Technological Development Zone, 830000 Xinjiang Uygur Autonomous Region Patentee before: Xinjiang yiyuanda Photoelectric Technology Co.,Ltd. |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20230420 Address after: 830000 Room 2902, No. 387 Guangming Road, Tianshan District, Urumqi, Xinjiang Uygur Autonomous Region Patentee after: Xinjiang Hongyu Zhixiang Engineering Consulting Co.,Ltd. Address before: Room 2223, 22 / F, building 12, wanchuang center, 433 Xuanwuhu Road, Urumqi Economic and Technological Development Zone, 830000 Xinjiang Uygur Autonomous Region Patentee before: Xinjiang Aodi Construction Engineering Co.,Ltd. |