CN111117786A - Anti-freezing type glass cleaning water for preventing glass from fogging and manufacturing method thereof - Google Patents
Anti-freezing type glass cleaning water for preventing glass from fogging and manufacturing method thereof Download PDFInfo
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- CN111117786A CN111117786A CN201911312546.XA CN201911312546A CN111117786A CN 111117786 A CN111117786 A CN 111117786A CN 201911312546 A CN201911312546 A CN 201911312546A CN 111117786 A CN111117786 A CN 111117786A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/162—Organic compounds containing Si
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
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Abstract
The invention relates to an anti-freezing type clean glass water for preventing glass from fogging and a preparation method thereof, wherein the glass water comprises the following raw materials in parts by weight: 0.1-0.8 part of surfactant, 30-50 parts of methanol, 5-15 parts of ethanol, 5-15 parts of ethylene glycol, 0.1-1 part of water-based silicone oil, 0.01-0.1 part of kason, 0.01-0.02 part of organic silicon, 0.1-0.5 part of ultraviolet absorbent, 0.02-0.05 part of quencher, 0.5-1 part of sodium acetate, 0.3-0.8 part of peppermint oil and 50-70 parts of deionized water. The invention has good antifreezing ability, and the methanol, the ethanol and the glycol can reduce the freezing point of liquid, so that the glass water has antifreezing ability, can quickly dissolve frost and can well remove oil stains on the surface of glass.
Description
Technical Field
The invention relates to the technical field of cleaning, in particular to anti-freezing glass cleaning water for preventing glass from fogging and a manufacturing method thereof.
Background
With the rapid development of social economy and the continuous improvement of living standard of people, automobiles become mass consumer goods and gradually enter common people, and the retention amount on the market is larger and larger. However, after the automobile runs for a long time, due to the influence of external environments such as wind, sunshine, rain and the like, a large amount of dust and dirt are often deposited on the automobile glass, if the automobile glass is not cleaned in time, the whole attractiveness of the automobile is affected, the visual field of a driver is interfered, and traffic accidents can be caused in serious cases. Therefore, how to keep the glass clean and bright in the using process of the automobile has become the focus of attention of drivers of each automobile.
With the rapid increase of automobile demand in China, the maintenance of automobiles becomes a new industry.
In winter in northern China, the temperature is lower and is generally about minus 25 ℃. Therefore, a thin layer of ice crystals is easily generated on the windshield of the automobile, which causes the problems of low visibility and the like, and brings certain difficulty to the safe driving of drivers. When the windshield of an automobile is stained with viscous liquid or stubborn stains, the existing glass water cannot be quickly cleaned, so that the environment-friendly glass water with good cleaning capability is urgently needed in the field.
Disclosure of Invention
The invention aims to solve the technical problem and provides anti-freezing glass cleaning water for preventing glass from fogging and a manufacturing method thereof.
In order to solve the technical problems, the invention adopts the following technical scheme:
an anti-freezing type glass cleaning water for preventing glass fogging comprises the following raw materials in parts by weight:
0.1-0.8 part of surfactant, 30-50 parts of methanol, 5-15 parts of ethanol, 5-15 parts of ethylene glycol, 0.1-1 part of water-based silicone oil, 0.01-0.1 part of kason, 0.01-0.02 part of organic silicon, 0.1-0.5 part of ultraviolet absorbent, 0.02-0.05 part of quencher, 0.5-1 part of sodium acetate, 0.3-0.8 part of peppermint oil and 50-70 parts of deionized water.
Further, the material comprises the following raw materials in parts by mass:
0.3-0.7 part of surfactant, 30-45 parts of methanol, 8-15 parts of ethanol, 8-15 parts of glycol, 0.1-0.7 part of water-based silicone oil, 0.03-0.1 part of cason, 0.01-0.018 part of organic silicon, 0.1-0.4 part of ultraviolet absorbent, 0.02-0.04 part of quencher, 0.6-0.9 part of sodium acetate, 0.5-0.8 part of peppermint oil and 55-70 parts of deionized water.
Further, the material comprises the following raw materials in parts by mass:
0.4-0.6 part of surfactant, 35-45 parts of methanol, 9-12 parts of ethanol, 9-12 parts of ethylene glycol, 0.4-0.6 part of water-based silicone oil, 0.06-0.1 part of cason, 0.01-0.015 part of organic silicon, 0.25-0.4 part of ultraviolet absorbent, 0.03-0.04 part of quencher, 0.6-0.7 part of sodium acetate, 0.6-0.7 part of peppermint oil and 55-65 parts of deionized water.
Further, the material comprises the following raw materials in parts by mass:
0.5 part of surfactant, 40 parts of methanol, 10 parts of ethanol, 10 parts of glycol, 0.5 part of water-based silicone oil, 0.1 part of cason, 0.01 part of organic silicon, 0.3 part of ultraviolet absorbent, 0.03 part of quencher, 0.7 part of sodium acetate, 0.6 part of peppermint oil and 60 parts of deionized water.
Further, the surfactant is one of 1227-dodecyl dimethyl benzyl ammonium chloride, fatty alcohol-polyoxyethylene ether sodium sulfate and alkyl glucoside.
Further, the ultraviolet absorbent is one of benzophenones or benzotriazoles.
Further, the quenching agent is one of 3, 5-di-tert-butyl-4-hydroxybenzylphosphonic acid monoethyl ester nickel, 2' thio-bis (4-tert-octylphenol) nickel or dibutyl dithiocarbamate nickel.
A method for manufacturing anti-freezing type glass cleaning water for preventing glass from fogging comprises the following steps:
step S1, weighing corresponding parts by weight of surfactant, methanol, ethanol, glycol, water-based silicone oil, kasong, organic silicon, ultraviolet absorbent, quencher, sodium acetate, peppermint oil and deionized water;
step S2, adding a surfactant, methanol, ethanol, glycol, water-based silicone oil, organic silicon, an ultraviolet absorbent, a quencher and peppermint oil into a container, uniformly mixing, heating to 55-60 ℃, and stirring to obtain a mixed solution a;
step S3, adding sodium acetate into deionized water, and stirring to obtain a mixed solution b;
and step S4, adding the mixed solution a and the kasong into the mixed solution b, heating to 50-70 ℃, stirring, and obtaining the anti-freezing type glass cleaning water for preventing glass from fogging after stirring.
Further, the stirring speed of the step S2 is 20-30r/min, and the stirring time is 10-20 min.
Further, the stirring speed of the step S3 is 15-25r/min, and the stirring time is 5-10 min; the stirring speed of the step S4 is 15-30r/min, and the stirring time is 5-10 min.
The invention has the beneficial effects that:
the invention has good antifreezing ability, and the methanol, the ethanol and the glycol can reduce the freezing point of liquid, so that the glass water has antifreezing ability, can quickly dissolve frost and can well remove oil stains on the surface of glass; the glycol and the water-based silicone oil can enhance the lubricity of the glass water, prevent the glass from being damaged and improve the transmittance of the glass; the peppermint oil can have the effects of repelling mosquitoes and insects, and prevents insects from staying on the vehicle glass to block sight; the ultraviolet absorbent and the quencher can form a film on the vehicle glass, can absorb ultraviolet rays in sunlight, and prevent people in the vehicle from irradiating the ultraviolet rays for a long time to damage the skin; the organosilicon can eliminate the foam fast, prevents that the foam from sheltering from driver's sight.
Detailed Description
The principles and features of this invention are described below in conjunction with embodiments, which are included to explain the invention and not to limit the scope of the invention.
Example 1
In this example, the surfactant was 1227-dodecyldimethylbenzylammonium chloride, the ultraviolet absorber was 2, 4-dihydroxybenzophenone, and the quencher was 3, 5-ditert-4-hydroxybenzylphosphonic acid monoethyl ester nickel.
An anti-freezing type glass cleaning water for preventing glass fogging comprises the following raw materials in parts by weight:
1227-dodecyl dimethyl benzyl ammonium chloride 0.4 parts, methanol 30 parts, ethanol 15 parts, ethylene glycol 15 parts, water-based silicone oil 0.5 parts, Kathon 0.05 parts, organic silicon 0.01 parts, 2, 4-dihydroxy benzophenone 0.2 parts, 3, 5-di-tert-butyl-4-hydroxy benzyl phosphonic acid monoethyl ester nickel 0.02 parts, sodium acetate 0.5 parts, peppermint oil 0.4 parts and deionized water 65 parts.
A method for manufacturing anti-freezing type glass cleaning water for preventing glass from fogging comprises the following steps:
step S1, weighing 1227-dodecyl dimethyl benzyl ammonium chloride, methanol, ethanol, ethylene glycol, water-based silicone oil, karson, organic silicon, 2, 4-dihydroxy benzophenone, 3, 5-di-tert-butyl-4-hydroxy benzyl phosphonic acid monoethyl ester nickel, sodium acetate, peppermint oil and deionized water in corresponding parts by weight;
step S2, adding 1227-dodecyl dimethyl benzyl ammonium chloride, methanol, ethanol, ethylene glycol, water-based silicone oil, organic silicon, 2, 4-dihydroxy benzophenone, 3, 5-di-tert-butyl-4-hydroxy benzyl phosphonic acid monoethyl ester nickel and peppermint oil into a container, uniformly mixing, heating to 55 ℃, stirring at the speed of 25r/min for 10min to obtain a mixed solution a;
step S3, adding sodium acetate into deionized water, and stirring at the stirring speed of 20r/min for 5min to obtain a mixed solution b;
and step S4, adding the mixed solution a and the kasong into the mixed solution b, heating to 60 ℃, stirring at the stirring speed of 20r/min for 5min, and obtaining the anti-freezing type glass cleaning water for preventing glass from fogging after stirring.
Example 2
In this embodiment, the surfactant is sodium fatty alcohol-polyoxyethylene ether sulfate, the ultraviolet absorber is 2- (2 '-hydroxy-5' -methylphenyl) benzotriazole, and the quencher is 3, 5-di-tert-butyl-4-hydroxybenzylphosphonic acid monoethyl ester nickel.
An anti-freezing type glass cleaning water for preventing glass fogging comprises the following raw materials in parts by weight:
0.6 part of sodium fatty alcohol-polyoxyethylene ether sulfate, 35 parts of methanol, 10 parts of ethanol, 10 parts of ethylene glycol, 0.7 part of water-based silicone oil, 0.06 part of kason, 0.015 part of organic silicon, 0.3 part of 2- (2 '-hydroxy-5' -methylphenyl) benzotriazole, 0.03 part of 3, 5-di-tert-butyl-4-hydroxybenzylphosphonic acid monoethyl ester nickel, 0.7 part of sodium acetate, 0.6 part of peppermint oil and 60 parts of deionized water.
A method for manufacturing anti-freezing type glass cleaning water for preventing glass from fogging comprises the following steps:
step S1, weighing corresponding parts by weight of sodium fatty alcohol polyoxyethylene ether sulfate, methanol, ethanol, ethylene glycol, water-based silicone oil, kasong, organic silicon, 2- (2 '-hydroxy-5' -methylphenyl) benzotriazole, 3, 5-di-tert-butyl-4-hydroxybenzylphosphonic acid monoethyl ester nickel, sodium acetate, peppermint oil and deionized water;
step S2, adding fatty alcohol-polyoxyethylene ether sodium sulfate, methanol, ethanol, ethylene glycol, water-based silicone oil, organic silicon, 2- (2 '-hydroxy-5' -methylphenyl) benzotriazole, 3, 5-di-tert-butyl-4-hydroxybenzylphosphonic acid monoethyl ester nickel and peppermint oil into a container, uniformly mixing, heating to 60 ℃, and stirring at the speed of 25r/min for 15min to obtain a mixed solution a;
step S3, adding sodium acetate into deionized water, and stirring at a stirring speed of 15r/min for 5min to obtain a mixed solution b;
and step S4, adding the mixed solution a and the kasong into the mixed solution b, heating to 50 ℃, stirring at the stirring speed of 20r/min for 10min, and obtaining the anti-freezing type glass cleaning water for preventing glass from fogging after stirring.
Example 3
In this example, the surfactant is an alkyl glucoside, the ultraviolet absorber is 2- (2 '-hydroxy-5' -methylphenyl) benzotriazole, and the quencher is nickel dibutyl dithiocarbamate.
An anti-freezing type glass cleaning water for preventing glass fogging comprises the following raw materials in parts by weight:
0.5 part of alkyl glucoside, 40 parts of methanol, 10 parts of ethanol, 10 parts of ethylene glycol, 0.5 part of water-based silicone oil, 0.1 part of kason, 0.01 part of organic silicon, 0.3 part of 2- (2 '-hydroxy-5' -methylphenyl) benzotriazole, 0.03 part of nickel dibutyl dithiocarbamate, 0.6 part of sodium acetate, 0.5 part of peppermint oil and 70 parts of deionized water.
A method for manufacturing anti-freezing type glass cleaning water for preventing glass from fogging comprises the following steps:
step S1, weighing corresponding parts by mass of alkyl glucoside, methanol, ethanol, ethylene glycol, water-based silicone oil, kasong, organic silicon, 2- (2 '-hydroxy-5' -methylphenyl) benzotriazole, nickel dibutyldithiocarbamate, sodium acetate, peppermint oil and deionized water;
step S2, adding alkyl glucoside, methanol, ethanol, ethylene glycol, water-based silicone oil, organic silicon, 2- (2 '-hydroxy-5' -methylphenyl) benzotriazole, nickel dibutyl dithiocarbamate and peppermint oil into a container, uniformly mixing, heating to 60 ℃, and stirring at a stirring speed of 20r/min for 20min to obtain a mixed solution a;
step S3, adding sodium acetate into deionized water, and stirring at the stirring speed of 20r/min for 10min to obtain a mixed solution b;
and step S4, adding the mixed solution a and the kasong into the mixed solution b, heating to 65 ℃, stirring at the stirring speed of 15r/min for 10min, and obtaining the anti-freezing type glass cleaning water for preventing glass from fogging after stirring.
The invention has good antifreezing ability, and the methanol, the ethanol and the glycol can reduce the freezing point of liquid, so that the glass water has antifreezing ability, can quickly dissolve frost and can well remove oil stains on the surface of glass; the glycol and the water-based silicone oil can enhance the lubricity of the glass water, prevent the glass from being damaged and improve the transmittance of the glass; the peppermint oil can have the effects of repelling mosquitoes and insects, and prevents insects from staying on the vehicle glass to block sight; the ultraviolet absorbent and the quencher can form a film on the vehicle glass, can absorb ultraviolet rays in sunlight, and prevent people in the vehicle from irradiating the ultraviolet rays for a long time to damage the skin; the organosilicon can eliminate the foam fast, prevents that the foam from sheltering from driver's sight.
The foregoing is illustrative of the best mode of the invention and details not described herein are within the common general knowledge of a person of ordinary skill in the art. The scope of the present invention is defined by the appended claims, and any equivalent modifications based on the technical teaching of the present invention are also within the scope of the present invention.
Claims (10)
1. The anti-freezing glass cleaning water for preventing glass fogging is characterized by comprising the following raw materials in parts by weight:
0.1-0.8 part of surfactant, 30-50 parts of methanol, 5-15 parts of ethanol, 5-15 parts of ethylene glycol, 0.1-1 part of water-based silicone oil, 0.01-0.1 part of kason, 0.01-0.02 part of organic silicon, 0.1-0.5 part of ultraviolet absorbent, 0.02-0.05 part of quencher, 0.5-1 part of sodium acetate, 0.3-0.8 part of peppermint oil and 50-70 parts of deionized water.
2. The anti-freezing type glass cleaning water for preventing glass fogging according to claim 1, characterized by comprising the following raw materials in parts by mass:
0.3-0.7 part of surfactant, 30-45 parts of methanol, 8-15 parts of ethanol, 8-15 parts of glycol, 0.1-0.7 part of water-based silicone oil, 0.03-0.1 part of cason, 0.01-0.018 part of organic silicon, 0.1-0.4 part of ultraviolet absorbent, 0.02-0.04 part of quencher, 0.6-0.9 part of sodium acetate, 0.5-0.8 part of peppermint oil and 55-70 parts of deionized water.
3. The anti-freezing type glass cleaning water for preventing glass fogging according to claim 1, characterized by comprising the following raw materials in parts by mass:
0.4-0.6 part of surfactant, 35-45 parts of methanol, 9-12 parts of ethanol, 9-12 parts of ethylene glycol, 0.4-0.6 part of water-based silicone oil, 0.06-0.1 part of cason, 0.01-0.015 part of organic silicon, 0.25-0.4 part of ultraviolet absorbent, 0.03-0.04 part of quencher, 0.6-0.7 part of sodium acetate, 0.6-0.7 part of peppermint oil and 55-65 parts of deionized water.
4. The anti-freezing type glass cleaning water for preventing glass fogging according to claim 1, characterized by comprising the following raw materials in parts by mass:
0.5 part of surfactant, 40 parts of methanol, 10 parts of ethanol, 10 parts of glycol, 0.5 part of water-based silicone oil, 0.1 part of cason, 0.01 part of organic silicon, 0.3 part of ultraviolet absorbent, 0.03 part of quencher, 0.7 part of sodium acetate, 0.6 part of peppermint oil and 60 parts of deionized water.
5. The anti-freezing glass cleaner for preventing glass fogging as claimed in claim 1, wherein the surfactant is one of 1227-dodecyldimethylbenzylammonium chloride, sodium fatty alcohol-polyoxyethylene ether sulfate and alkyl glucoside.
6. The antifreeze type glass cleaning water according to claim 1, wherein the ultraviolet absorber is one of benzophenones and benzotriazoles.
7. The anti-freeze cleaning glass water according to claim 1, wherein the quencher is one of 3, 5-di-tert-butyl-4-hydroxybenzylphosphonic acid monoethyl ester nickel, 2' thiobis (4-tert-octylphenol) nickel or dibutyl dithiocarbamate nickel.
8. A manufacturing method of anti-freezing type glass cleaning water for preventing glass fogging is characterized by comprising the following steps:
step S1, weighing corresponding parts by weight of surfactant, methanol, ethanol, glycol, water-based silicone oil, kasong, organic silicon, ultraviolet absorbent, quencher, sodium acetate, peppermint oil and deionized water;
step S2, adding a surfactant, methanol, ethanol, glycol, water-based silicone oil, organic silicon, an ultraviolet absorbent, a quencher and peppermint oil into a container, uniformly mixing, heating to 55-60 ℃, and stirring to obtain a mixed solution a;
step S3, adding sodium acetate into deionized water, and stirring to obtain a mixed solution b;
and step S4, adding the mixed solution a and the kasong into the mixed solution b, heating to 50-70 ℃, stirring, and obtaining the anti-freezing type glass cleaning water for preventing glass from fogging after stirring.
9. The method for producing an antifreeze type clean glass water for preventing fogging of glass according to claim 8, wherein the stirring speed in step S2 is 20 to 30r/min, and the stirring time is 10 to 20 min.
10. The method for producing an antifreeze type clean glass water for preventing fogging of glass according to claim 8, wherein the stirring speed of step S3 is 15 to 25r/min, and the stirring time is 5 to 10 min; the stirring speed of the step S4 is 15-30r/min, and the stirring time is 5-10 min.
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| CN113088408A (en) * | 2021-04-07 | 2021-07-09 | 四川兴望源商贸有限公司 | Automobile glass water for cleaning and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113088408A (en) * | 2021-04-07 | 2021-07-09 | 四川兴望源商贸有限公司 | Automobile glass water for cleaning and preparation method thereof |
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