CN111110622B - Surfactant-free oil-in-water cosmetic composition for stabilizing silicon powder - Google Patents
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- CN111110622B CN111110622B CN201911045513.3A CN201911045513A CN111110622B CN 111110622 B CN111110622 B CN 111110622B CN 201911045513 A CN201911045513 A CN 201911045513A CN 111110622 B CN111110622 B CN 111110622B
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
- A61K8/062—Oil-in-water emulsions
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/895—Polysiloxanes containing silicon bound to unsaturated aliphatic groups, e.g. vinyl dimethicone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/98—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of animal origin
- A61K8/981—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of animal origin of mammals or bird
- A61K8/986—Milk; Derivatives thereof, e.g. butter
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
- A61K2800/33—Free of surfactant
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/52—Stabilizers
Abstract
The present invention relates to an oil-in-water type cosmetic composition for stabilizing a high content of silicon powder, and more particularly, to an oil-in-water type cosmetic composition for stabilizing a high content of silicon powder without including a surfactant by mixing a suitable amount of a high viscosity lubricant, a polyol, a carbomer, and an acrylic polymer.
Description
Technical Field
The present invention relates to an oil-in-water type cosmetic composition that stabilizes a high content of silicon powder, and more particularly, to an oil-in-water type cosmetic composition that stabilizes a high content of silicon powder while not including a surfactant by mixing a suitable amount of a high viscosity lubricant, a polyol, a carbomer, and an acrylic polymer.
Background
In a conventional general emulsion type having a liquid type of fluidity, particularly an oil-in-water emulsion type, it is difficult to contain components such as silicone elastomer powder and butter (butter) at a high content even if a surfactant is contained. This is because there are problems such as poor stability over time, for example, separation of dosage forms, or poor stability of dosage forms, for example, uneven surface of dosage forms due to deposition of silicon powder.
On the one hand, water-in-oil (W/O) formulations are excellent in water resistance and durability, and on the other hand, oil-in-water (O/W) formulations have characteristics of water supply ability, skin affinity, excellent stability, light use, etc. In addition, in the case of a formulation containing no surfactant, irritation due to the surfactant can be prevented, and thus, there is an advantage of excellent skin stability and moisture retention durability. However, the surfactant-free composition not only shows limited feeling of use with only moisture feeling, but also is not excellent in freezing stability and formulation stability, so that not only is it possible to develop not much surfactant-free cosmetics in skin care products, but also it is possible to contain only a small amount of silicon powder or butter, etc. in view of formulation stability.
Thus, there remains a need for an oil-in-water dosage form that has the advantages of oil-in-water compositions, while having improved feel in use of large quantities of silicon powder or butter stabilized without the presence of surfactant.
[ Prior art documents ]
[ patent document ]
1. International publication No. WO84/15580 (published on 21/7/1994)
2. Korean laid-open patent No. 2014-0026056 (published 3/5/2014)
Disclosure of Invention
Accordingly, the present inventors have found that mixing a high viscosity lubricant to increase the viscosity of an oil phase component and, at the same time, appropriately combining a polyol, a carbomer, and an acrylic polymer can stabilize a large amount of silicon powder or butter within a dosage form without using a surfactant, thereby completing the present invention.
Accordingly, an object of the present invention is to provide an oil-in-water type cosmetic composition which can stabilize a large amount of silicon powder or butter without using a surfactant.
In order to achieve the above object, the present invention provides an oil-in-water type cosmetic composition comprising, relative to the total weight of the composition: 11% by weight or less of a silicone elastomer powder; 1.5 to 4.5 weight percent of a high viscosity lubricant; 20 to 50 weight percent of a polyol; 0.1 to 0.3% by weight of carbomer and 0.05 to 0.2% by weight of acrylic polymer, and surfactant free.
The composition of the present invention contains silicon powder and butter at high contents, has excellent formulation stability, does not contain a surfactant, and therefore, has high skin safety, and can improve the limited feeling of use of a surfactant-free formulation because of containing silicon powder and butter at high contents.
Drawings
FIG. 1 is a photograph of the dosage forms of comparative example 1 and comparative example 6.
Fig. 2 is a photograph showing the fluidity of example 1.
Fig. 3 is a schematic diagram of the precipitation of excessive silicone elastomer powder in comparative example 5.
FIG. 4 is a schematic view showing that the silicone elastomer powder is partially precipitated in comparative example 1.
Detailed Description
The cosmetic composition according to the present invention provides an oil-in-water type cosmetic composition which contains a high content of silicone elastomer powder, contains a high viscosity lubricant, a polyol, a carbomer, and an acrylic polymer for the purpose of stabilizing the same in a dosage form, and does not contain a surfactant.
In the cosmetic composition according to the present invention, the content of the silicone elastomer powder may be 11% by weight or less, more preferably 10% by weight or less, relative to the total weight of the composition.
The type of silicone elastomer powder that can be used in the cosmetic composition according to the present invention is not particularly limited, and includes, for example, one or more selected from the group consisting of an ethylene polydimethylsiloxane/polymethylsilsesquioxane crosspolymer, polymethylsilsesquioxane, polysiloxane-11, and polysiloxane 13.
In addition, the cosmetic composition according to the present invention may further include butter (butter), wherein the butter may be contained in an amount of 2 to 10% by weight, relative to the total weight of the composition.
In the cosmetic composition according to the present invention, the type of Butter that can be used is not particularly limited, and includes, for example, one or more selected from the group consisting of Shea Butter (buttermomum Parkii (Shea) Butter), mango Seed Butter (Mangifera Indica Seed Butter), jojoba Seed Butter (Jojoba Seed Butter), mango Seed Butter (Mangifera Indica Kernel Butter), and Cocoa Seed Butter (Theobroma Cacao (coco) Seed Butter).
The cosmetic composition according to the invention comprises a high viscosity lubricant (oil), wherein the high viscosity lubricant may be present in an amount of 1.5 to 4.5% by weight, preferably 2 to 4% by weight, relative to the total weight of the composition. When the content is less than 1.5% by weight, the viscosity of the oily component cannot be sufficiently increased, and silicon elastomer powder is precipitated, so that it is difficult to secure the formulation stability, and when the content exceeds 4.5% by weight, the sticky feeling of use of the high-viscosity lubricant is mainly exhibited, and the characteristics of the oil-in-water composition providing a light feeling of use are deteriorated, so that it is not suitable for commercialization of the product.
In the cosmetic composition according to the present invention, the type of the high viscosity lubricant to be used is not particularly limited, but a lubricant having a viscosity of 10000 to 100000cps is preferably used, and for example, one or more selected from the group consisting of polyisobutylene, hydrogenated polyisobutylene, polybutene, hydrogenated ethylene/propylene/styrene copolymer, hydrogenated butene/ethylene/styrene copolymer, dimethiconol and cyclopentadimethylsiloxane is contained.
The cosmetic composition according to the present invention comprises a polyol, wherein the content of the polyol may be 20 to 50% by weight, more preferably 25 to 40% by weight, relative to the total weight of the composition. When the content is less than 20% by weight, the content of the polyhydric alcohol is insufficient to wet the silicon powder, and when the content exceeds 50% by weight, the feeling of stickiness is heavy and phase inversion is not easily generated, and the polyhydric alcohol excessively mainly gives a feeling of use with a heavy feeling, and therefore, is not suitable for an oil-in-water type cosmetic composition giving a feeling of light use.
In the cosmetic composition according to the present invention, the type of the polyol that can be used is not particularly limited, and includes at least one selected from the group consisting of glycerin, butylene glycol, propylene glycol, and dipropylene glycol.
In the cosmetic composition according to the present invention, the polyol is used in an amount of 2.5 to 6 times, preferably 3 to 4.5 times the weight of the silicon elastomer powder.
The cosmetic composition according to the present invention includes carbomer, wherein the content of carbomer may be 0.1 to 0.3% by weight. When the content is less than 0.1% by weight, the suspension ability of the composition is insufficient and the stability of the dosage form is poor, and when the content exceeds 0.3% by weight, the composition is manufactured into a cream-like dosage form without departing from the viscosity range of the composition to be manufactured in the present invention.
The cosmetic composition according to the present invention includes an acrylic polymer, wherein the content of the acrylic polymer may be 0.05 to 0.2% by weight. When the content is less than 0.05% by weight, the viscosity of the composition is insufficient and the stability of the dosage form is poor, and when the content exceeds 0.2% by weight, the composition is manufactured into a cream-like dosage form without departing from the viscosity range of the composition to be manufactured in the present invention.
In the cosmetic composition according to the present invention, the type of the acrylic polymer that can be used is not particularly limited, and includes at least one selected from the group consisting of acrylate/C10-30 alkanol acrylate crosspolymer, polyacrylate crosspolymer-6, and hydroxyethyl acrylate/sodium acryloyldimethyl taurate copolymer.
In the cosmetic composition according to the present invention, carbomer and acrylic polymer are mixed in the ratio described above using 1:1 to 3:1, preferably 2:1 on a weight basis to have appropriate viscosity, thereby manufacturing a dosage form having fluidity. When the compounding ratio is less than 1:1, the emulsion is gelled under freeze-thaw conditions and becomes a formulation having no fluidity, and when the compounding ratio exceeds 3:1, creaming of the emulsion particles occurs at high temperature, and an oil layer is formed in the upper layer.
The cosmetic composition according to the present invention has a high-viscosity formulation, and particularly, has a viscosity of 5000 to 20000cps. When the viscosity is less than 5000cps, it is not favorable for stabilization of the high content silicone elastomer powder or butter, and when the viscosity exceeds 20000cps, it becomes creamy and is not suitable for the present invention which intends to provide an emulsion type composition.
The cosmetic composition according to the present invention is characterized by not containing surfactants such as cationic surfactants (quaternary ammonium, amine salts, etc.), anionic surfactants (carboxylate, sulfonate, sulfate, phosphate salts, etc.), nonionic surfactants (PEG, saccharides, polyglycerol, behenic polysaccharide, etc.), amphoteric surfactants (lecithin, etc.), and the like.
If the cosmetic composition according to the present invention is an emulsion type composition having a viscosity of 20000cps or less, the formulation thereof is not particularly limited, and may be, for example, a makeup cosmetic composition or a skin care cosmetic composition. For example, it can be formulated into a face makeup cosmetic composition such as a makeup cream, a makeup base, a liquid foundation, a concealer, or the like; cosmetic compositions for makeup such as lip gloss, eyeliner, mascara, eyebrow pencil, and blush; functional makeup cosmetic compositions including sunscreens and the like; and skin care cosmetic compositions such as lotions, essences, etc., but not limited thereto.
The structure and effects of the present invention will be described in more detail below by way of test examples and production examples. However, the test examples and the production examples are provided only for the purpose of illustration to facilitate understanding of the present invention, and the scope and the range of the present invention are not limited by the following examples.
[ referential example 1 ]
The oil-in-water emulsions of examples 1 to 2 and comparative examples 1 to 9 were produced from the components shown in table 1 below by the following production methods.
[ TABLE 1 ]
< production method >
1) In the components of the oil phase portion and the water phase portion in table 1, glycerin and propylene glycol as polyols were emulsified with gelatin, so that the powder was sufficiently wetted with the polyols and the oil.
2) The remaining aqueous phase components were put into the 1) to carry out the emulsion of lipids.
[ test example 1 ] Observation of appearance of composition
The compositions of examples 1 to 2 and comparative examples 1 to 9 produced in reference example 1 were observed for appearance immediately after production.
The observation results are shown in table 2 below.
[ TABLE 2 ]
[ test example 2 ] evaluation of the stability of the dosage form of the composition
As shown in test example 1, the stability of the dosage forms of the compositions of the remaining examples 1 and 2 and comparative examples 2 and 4 was evaluated, except for comparative examples 1, 3, 5 to 9, which were separated or creamed immediately after the production.
Specifically, in a state where the composition was held in a test container, it was stored for 8 weeks under freezing conditions of a cavity at 45 ℃ and-15 ℃, and whether or not separation of the oil phase portion and the water phase portion of the composition occurred and the appearance of the composition was observed.
The observation results are shown in table 3 below and fig. 1 to 3.
[ TABLE 3 ]
As shown in table 3 and the figures, it was confirmed that examples 1 and 2, which are the compositions according to the present invention, exhibited excellent formulation stability, whereas comparative example 4, which is not the composition according to the present invention, could not secure freezing stability, and gelation occurred during low-temperature storage.
Claims (8)
1. An oil-in-water cosmetic composition characterized by comprising, relative to the total weight of the composition: more than 0% by weight and 11% by weight or less of a silicone elastomer powder; 1.5 to 4.5 weight percent of a high viscosity lubricant; 20 to 50 weight percent of a polyol; 0.1 to 0.3% by weight of carbomer and 0.05 to 0.2% by weight of acrylic polymer, and no surfactant, wherein the high viscosity lubricant is a lubricant having a viscosity of 10000 to 100000cps, and the mixing ratio of carbomer and acrylic polymer is 1:1 to 3:1 on a weight basis.
2. The oil-in-water cosmetic composition according to claim 1, characterized in that the composition further comprises butter.
3. The oil-in-water cosmetic composition according to claim 1, wherein the silicone elastomer powder is one or more selected from the group consisting of an ethylene polydimethylsiloxane/polymethylsiloxane silsesquioxane crosspolymer, polymethylsilsesquioxane, polysiloxane-11, and polysiloxane-13.
4. The oil-in-water type cosmetic composition according to claim 1, wherein the high viscosity lubricant is at least one selected from the group consisting of polyisobutylene, hydrogenated polyisobutylene, polybutene, hydrogenated ethylene/propylene/styrene copolymer, hydrogenated butene/ethylene/styrene copolymer, dimethiconol and cyclopentadimethylsiloxane.
5. The oil-in-water type cosmetic composition according to claim 1, wherein the polyhydric alcohol is contained in an amount of 2.5 to 6 times by weight of the silicone elastomer powder.
6. The oil-in-water type cosmetic composition according to claim 1, wherein the polyhydric alcohol is one or more selected from the group consisting of glycerin, butylene glycol, propylene glycol, and dipropylene glycol.
7. The oil-in-water type cosmetic composition according to claim 1, wherein the acrylic polymer is at least one selected from the group consisting of acrylate/C10-30 alkanol acrylate cross-linked polymer, polyacrylate cross-linked polymer-6, and hydroxyethyl acrylate/sodium acryloyldimethyl taurate copolymer.
8. The oil-in-water type cosmetic composition according to claim 1, wherein the viscosity of the composition is 5000 to 20000cps.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
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| KR10-2018-0132075 | 2018-10-31 | ||
| KR1020180132075A KR102575095B1 (en) | 2018-10-31 | 2018-10-31 | Oil-in-water type cosmetic composition containing stabilized silicone powder with no surfactant |
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| CN111110622A CN111110622A (en) | 2020-05-08 |
| CN111110622B true CN111110622B (en) | 2023-03-28 |
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| KR102428284B1 (en) * | 2020-05-29 | 2022-08-03 | 코스맥스 주식회사 | Cream composition for sebum adsorption containing no polysaccharide thickener |
| KR102625672B1 (en) * | 2021-12-28 | 2024-01-16 | (주)바이오제닉스 | Tinted cosmetic composition comprising a pigment and preparation method thereof |
| KR102517231B1 (en) * | 2022-10-26 | 2023-04-04 | 주식회사 한국화장품제조 | Makeup cosmetic composition with excellent adhesion and durability |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102010028313A1 (en) * | 2010-04-28 | 2011-11-03 | Henkel Ag & Co. Kgaa | Cosmetic composition for optical lamination of wrinkles |
| CN102238934A (en) * | 2008-12-03 | 2011-11-09 | 株式会社资生堂 | Oil-in-water cosmetic |
| KR20140026056A (en) * | 2012-08-24 | 2014-03-05 | 한국콜마주식회사 | Oil-in-water type of semi-transparent cosmetic composition for blocking ultraviolet |
| CN105451819A (en) * | 2012-12-21 | 2016-03-30 | 莱雅公司 | Composition comprising a superabsorbent polymer and an organopolysiloxane elastomer |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002092047A1 (en) * | 2001-05-10 | 2002-11-21 | The Procter & Gamble Company | Cosmetic composition comprising silicone elastomer |
| US20080046822A1 (en) | 2006-08-15 | 2008-02-21 | Frank Meyer | Apparatus and method for interactive user software interface design |
| KR20120096664A (en) * | 2011-02-23 | 2012-08-31 | 한국콜마 주식회사 | Water in silicone emulsion and oil-based cosmetic composition comprising the same |
| KR20160065658A (en) * | 2014-12-01 | 2016-06-09 | 코웨이 주식회사 | Emulsifier-Free Washable Cleansing Cosmetic Composition |
| KR102380272B1 (en) * | 2017-04-12 | 2022-03-29 | 주식회사 엘지생활건강 | An oil-in-water cosmetic composition comprising high-content butter |
| KR102453279B1 (en) * | 2017-09-15 | 2022-10-12 | 주식회사 엘지생활건강 | Oil-in-water emulsion composition comprising high content silicone elastomer |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102238934A (en) * | 2008-12-03 | 2011-11-09 | 株式会社资生堂 | Oil-in-water cosmetic |
| DE102010028313A1 (en) * | 2010-04-28 | 2011-11-03 | Henkel Ag & Co. Kgaa | Cosmetic composition for optical lamination of wrinkles |
| KR20140026056A (en) * | 2012-08-24 | 2014-03-05 | 한국콜마주식회사 | Oil-in-water type of semi-transparent cosmetic composition for blocking ultraviolet |
| CN105451819A (en) * | 2012-12-21 | 2016-03-30 | 莱雅公司 | Composition comprising a superabsorbent polymer and an organopolysiloxane elastomer |
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| KR102575095B1 (en) | 2023-09-06 |
| KR20200049151A (en) | 2020-05-08 |
| CN111110622A (en) | 2020-05-08 |
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