CN111073476A - Wear-resistant gel coat and preparation method and application thereof - Google Patents

Wear-resistant gel coat and preparation method and application thereof Download PDF

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CN111073476A
CN111073476A CN201911385026.1A CN201911385026A CN111073476A CN 111073476 A CN111073476 A CN 111073476A CN 201911385026 A CN201911385026 A CN 201911385026A CN 111073476 A CN111073476 A CN 111073476A
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wear
gel coat
resistant
graphite
resistant gel
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曹峰铖
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Shenzhen Panshi Foundation Management Center LP
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/06Unsaturated polyesters having carbon-to-carbon unsaturation
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2300/00Characterised by the use of unspecified polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2467/00Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2467/06Unsaturated polyesters
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    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
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    • C08K2201/003Additives being defined by their diameter
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    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
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  • Wood Science & Technology (AREA)
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  • Lubricants (AREA)
  • Chutes (AREA)

Abstract

The invention discloses a wear-resistant gel coat and a preparation method and application thereof. The wear-resistant gel coat comprises the following substances in parts by weight: 2-4 parts of wear-resistant agent, 4.5-9 parts of lubricant and 66.7-133.3 parts of m-phenyl neopentyl glycol type gel coat; the wear-resisting agent is molybdenum disulfide, and the lubricant comprises graphite and PTFE micro powder in a mass ratio of 1 (1-4). The preparation method comprises the following steps: and (3) adding the m-phenyl neopentyl glycol type gel coat into a grinding machine, sequentially adding PTFE micro powder, graphite and molybdenum disulfide, uniformly grinding and dispersing, and mechanically stirring at a high speed for 1-1.5h to obtain the wear-resistant gel coat. The wear-resistant gel coat has the advantages that the wear-resistant gel coat is coated on the sorting chute, the friction coefficient of the chute can be reduced, the gliding smoothness of an object is improved, the wear resistance of the surface of the chute is improved, and the service life of a working surface is prolonged.

Description

Wear-resistant gel coat and preparation method and application thereof
Technical Field
The invention relates to the technical field of logistics chutes, in particular to a wear-resistant gel coat and a preparation method and application thereof.
Background
Along with the development of the logistics equipment technology, the intellectualization and informatization of the logistics equipment become mainstream trends, and from the development condition of the logistics technology, the development of the logistics equipment is mainly applied to the technologies of the links of conveying, storing, selecting, sorting, distributing and the like, and is used as an important matching measure-sliding chute in the logistics sorting link, and along with the appearance of a new material sorting sliding chute, the effect in the logistics equipment is gradually highlighted.
According to the sorting direction, the sliding chutes are divided into a one-way sorting sliding chute, a one-to-two sliding chute and a high-fall spiral sliding chute, and the sliding chutes are divided into a cement sliding chute, a steel wire sliding chute, a stainless steel sliding chute, a carbon steel sliding chute and a glass fiber reinforced plastic sliding chute according to the material, and the carbon steel sliding chute and the glass fiber reinforced plastic sliding chute are widely applied at present.
Among the prior art, chinese utility model patent document with application number CN201822090311.8 discloses a novel glass steel sheet and letter sorting spout, and letter sorting spout is by glass steel sheet integrated press forming, and glass steel sheet is including outer protective layer, glass steel basic unit, back up coat and the gel coat layer that the stromatolite set up in proper order, glass steel basic unit includes the glass steel mesh that a plurality of stromatolites set up, and it has the resin to fill between intermediate layer and the mesh between the adjacent glass steel mesh.
The gel coat layer on the existing sorting chute has large friction coefficient, the object is easy to block and even block when sliding downwards, and the object and the gel coat layer rub each other when sliding downwards, so that the surface of the gel coat layer is easy to wear, the service life is short, the smoothness of the chute is improved, and the wear resistance of the chute is also enhanced.
Disclosure of Invention
In view of the defects in the prior art, a first object of the present invention is to provide a wear-resistant gel coat, which has the advantages of reducing the friction coefficient of the chute, improving the smoothness of the object sliding, increasing the wear resistance of the chute surface, and prolonging the service life of the working surface when being coated on the sorting chute.
The second purpose of the invention is to provide a preparation method of the wear-resistant gel coat, which has the advantages of simple and convenient preparation and easy operation.
The third purpose of the invention is to provide application of the wear-resistant gel coat, which has the advantages that the prepared sorting chute is light in weight, easy to form, capable of achieving the static weighing standard and reducing the damage rate of goods.
In order to achieve the first object, the invention provides the following technical scheme: the wear-resistant gel coat comprises the following substances in parts by weight: 2-4 parts of wear-resistant agent, 4.5-9 parts of lubricant and 66.7-133.3 parts of m-phenyl neopentyl glycol type gel coat;
the wear-resisting agent is molybdenum disulfide, and the lubricant comprises graphite and PTFE micro powder in a mass ratio of 1 (1-4).
By adopting the technical scheme, because the m-phenyl neopentyl glycol gel coat is adopted as the main base material of the wear-resistant gel coat, the wear-resistant gel coat has higher mechanical strength, thermal stability and chemical corrosion resistance at high temperature, has good weather resistance, can play a better protection role by being attached to the surface of the glass steel plate, has excellent mechanical property, can ensure that the surface of the wear-resistant gel coat attached to the glass steel plate does not generate cracks or fissures when the glass steel plate is bent and formed, thereby enhancing the wear resistance and prolonging the service life of the wear-resistant gel coat.
Graphite and PTFE micropowder are used as a lubricant, the graphite has a layered crystal structure, so that the graphite has good lubricity and has good wear resistance under high-speed sliding; the PTFE micro powder has low friction coefficient and excellent self-lubricating property, but the hardness of the PTFE micro powder is insufficient, so that the wear resistance of the sorting chute is poor when the PTFE micro powder is singly added, the PTFE micro powder is mixed with graphite and molybdenum disulfide for use, the compression strength of the graphite and the molybdenum disulfide is high, and the hardness and the wear resistance of the chute can be enhanced; the graphite has good film forming property, as the mass ratio of the graphite to the PTFE micro powder is 1 (1-4), the content of the PTFE micro powder is high, part of the PTFE micro powder can be adsorbed in the pores of the graphite, and the anti-friction effect of sliding of the laminas is lost due to the fact that the PTFE micro powder is filled between the adsorbed graphite laminas, but the adsorption capacity of the graphite is not reduced, the graphite laminas can be adsorbed to form a film on the friction surface, and the solid film is reinforced by the residual PTFE micro powder, so that the graphite has good lubricating effect and high wear resistance, and can prevent objects from being blocked when sliding in a.
Molybdenum disulfide has extremely low coefficient of friction, higher yield strength and fabulous wear resistance, and its lubrication effect is good, can reduce coefficient of friction, reduces the wear rate, and molybdenum disulfide covers the gel coat layer surface, can prevent it by oxidation, and its adhesion is strong simultaneously, can increase the adhesion of gel coat resin and glass steel board to prevent that the article that constantly passes through from causing wearing and tearing to the surface of gel coat layer, thereby increase the life of spout.
Further, the components in parts by weight are as follows: 2.49-3.48 parts of wear-resistant agent, 5.5.6-7.7 parts of lubricant and 83-116 parts of m-phenyl neopentyl glycol type gel coat;
the lubricant comprises graphite and PTFE micro powder with the mass ratio of 1 (1.5-3).
By adopting the technical scheme, the dosage of various components in the wear-resistant gel coat is more accurate, so that the sliding chute formed by coating the prepared wear-resistant gel coat on the glass fiber reinforced plastic has better smoothness and wear resistance.
Further, the graphite is expanded graphite, and the average particle size of the expanded graphite is 10-40 μm.
By adopting the technical scheme, the expanded graphite has a loose and porous structure, has strong adsorption force, is porous and bent, and has a large aperture, but has good flexibility, rebound resilience and plasticity, part of PTFE micropowder can be adsorbed into large pores and the surface of graphite, the strength and hardness of the graphite with the PTFE micropowder adsorbed in the surface and the pores are improved, the hardness of the chute can be obviously enhanced, the expanded graphite has good film forming property, a solid film can be formed on the surface of a glass steel plate, and the solid film is high in hardness, good in wear resistance and good in smoothness due to the filling of the PTFE micropowder.
Further, the particle size of the PTFE micropowder is 0.1-10 nm.
By adopting the technical scheme, the particle size of the PTFE micropowder is nanoscale, so that part of the PTFE micropowder is filled into the pores of the expanded graphite, the hardness of the expanded graphite is enhanced, and the expanded graphite after film forming has high hardness, high strength, good wear resistance and good smoothness.
Further, the average particle size of the molybdenum disulfide is 280-300 nm.
By adopting the technical scheme, the smaller the particle size is, the better the dispersion performance is, the more stable the dispersion and the spreading film formation in the m-phenyl neopentyl glycol gel coat are, and the smaller the particle size is, the better the lubricating effect is and the higher the wear resistance is.
Further, the solid content of the m-phenyl neopentyl glycol type gel coat is 60-64%, and the acid value is 8-12 mg/KOH.
In order to achieve the second object, the invention provides the following technical scheme: the preparation method of the wear-resistant gel coat comprises the following steps: and (3) adding the m-phenyl neopentyl glycol type gel coat into a grinding machine, sequentially adding PTFE micro powder, graphite and molybdenum disulfide, uniformly grinding and dispersing, and mechanically stirring at a high speed for 1-1.5h to obtain the wear-resistant gel coat.
By adopting the technical scheme, high-speed dispersion is adopted, the PTFE micro powder, the graphite and the molybdenum disulfide are sequentially added, the PTFE micro powder with good dispersibility can be uniformly dispersed in the gel coat resin, and the dispersibility of the PTFE micro powder and the graphite in the gel coat resin can be improved when the graphite and the molybdenum disulfide are added.
In order to achieve the third object, the invention provides the following technical solutions: an application of wear-resistant gel coat in the field of logistics.
Further, the glass fiber reinforced plastic express sorting device comprises a chute for express sorting, wherein the chute comprises a glass fiber reinforced plastic substrate and a wear-resistant gel coat coated on the glass fiber reinforced plastic substrate.
By adopting the technical scheme, the glass fiber reinforced plastic base body is light in weight, easy to form, capable of reaching the static weighing standard, capable of reducing the collision force when some fragile objects collide with the sliding chute, reducing the damage rate of goods and solving the problem that cambered surface forming is difficult to complete in a sheet metal process, the glass fiber reinforced plastic base body is fiber reinforced plastics formed by glass fiber reinforced unsaturated resin, epoxy resin and phenolic resin base bodies, the main base material in the wear-resistant gel coat is m-phenyl neopentyl glycol type gel coat, the m-phenyl neopentyl glycol type gel coat and various resins in glass fiber reinforced plastics belong to high polymer materials, the bonding force between molecules of the m-phenyl neopentyl glycol type gel coat is large, the bonding force with the glass fiber reinforced plastic base body is strong in the coating process, and when an object slides on the wear-resistant gel coat, the bonding force between the molecules of the gel coat and the glass fiber reinforced plastic base body is large, the object is not easy to wear the gel coat in the gliding process, the surface smoothness of the gel coat is good, the object can rapidly glide, and the phenomenon of blocking is not easy to occur.
In conclusion, the invention has the following beneficial effects:
firstly, as the graphite and PTFE micro powder are used as the lubricant, the molybdenum disulfide is used as the wear-resisting agent, the graphite and PTFE micro powder are nano-scale, are easy to disperse and difficult to agglomerate, have good lubricity, and can reduce the friction coefficient of the sliding chute, so that the object can slide down smoothly; the graphite has film forming property, the molybdenum disulfide has adsorption force, the adhesion force of the gel coat layer and the glass steel plate is enhanced under the action of the molybdenum disulfide, the graphite and the molybdenum disulfide which are adsorbed with the PTFE micro powder can improve the hardness, smoothness and wear resistance of the gel coat layer, the cost of the graphite is low, the price is low, the source is wide, and the cost can be effectively reduced.
Secondly, the expanded graphite and the nano-scale PTFE micropowder are preferably adopted in the invention, because the expanded graphite has a loose and porous structure, part of the PTFE micropowder can be adsorbed in the pores and on the surface of the graphite, and under the action of the film-forming property of the graphite, the graphite adsorbed with the PTFE micropowder is adsorbed on the surface of the glass fiber reinforced plastic to form a solid film, so that the adhesion force of the gel coat resin and the surface of the glass fiber reinforced plastic is increased, and the hardness, the wear resistance and the smoothness of the gel coat resin after being cured are improved.
And after the m-phenyl neopentyl glycol type gel coat is cured, the molecular bonding force of the m-phenyl neopentyl glycol type gel coat is large, the adhesion force with a glass steel matrix is strong, and the wear-resistant gel coat is not easily abraded when an object slides down.
Detailed Description
The present invention will be described in further detail with reference to examples.
Examples
Example 1: the raw material composition of the wear-resistant gel coat is shown in Table 1, wherein the wear-resistant agent is molybdenum disulfide with the average particle size of 280nm, and the lubricant comprises graphite and PTFE micro powder in a mass ratio of 1:1.5, wherein the weight of the graphite is 1.8kg, the weight of the PTFE micro powder is 2.7kg, the graphite is expanded graphite, the average particle size is 10 mu m, the particle size of the PTFE micro powder is 0.1nm, the solid content of the m-phenyl neopentyl glycol type gel coat is 60%, and the acid value is 8 mg/KOH.
The preparation method of the wear-resistant gel coat comprises the following steps: 66.7kg of m-phenyl neopentyl glycol type gel coat is added into a grinding machine, 2.7kg of PTFE micro powder, 1.8kg of graphite and 2kg of molybdenum disulfide are sequentially added, grinding and dispersing are carried out uniformly, and then high-speed mechanical stirring is carried out for 1h to prepare the wear-resistant gel coat, wherein the high-speed stirring speed is 5000 r/min.
The wear-resistant gel coat is applied to the field of logistics and comprises a sliding chute for express sorting, wherein the sliding chute comprises a glass steel matrix and a wear-resistant gel coat coated on the glass steel matrix, and the thickness of the wear-resistant gel coat is 0.3 mm.
TABLE 1 raw material ratios of abrasion resistant gel coats in examples 1-5
Figure BDA0002343349910000041
Example 2: the raw material composition of the wear-resistant gel coat is shown in Table 1, wherein the wear-resistant agent is molybdenum disulfide with the average particle size of 290nm, and the lubricant comprises graphite and PTFE micro powder in a mass ratio of 1:1, wherein the weight of the graphite is 2.78kg, the weight of the PTFE micro powder is 2.78kg, the graphite is expanded graphite, the average particle size is 25 mu m, the particle size of the PTFE micro powder is 5nm, the solid content of the m-phenyl neopentyl glycol type gel coat is 62%, and the acid value is 10 mg/KOH.
The preparation method of the wear-resistant gel coat comprises the following steps: 83kg of m-phenyl neopentyl glycol type gel coat is added into a grinding machine, 2.78kg of PTFE micro powder, 2.78kg of graphite and 2.49kg of molybdenum disulfide are sequentially added, grinding and dispersing are carried out uniformly, and then high-speed mechanical stirring is carried out for 1.3h, so that the wear-resistant gel coat is prepared, wherein the high-speed stirring speed is 4000 r/min.
The wear-resistant gel coat is applied to the field of logistics and comprises a sliding chute for express sorting, wherein the sliding chute comprises a glass steel matrix and a wear-resistant gel coat coated on the glass steel matrix, and the thickness of the wear-resistant gel coat is 0.4 mm.
Example 3: the raw material composition of the wear-resistant gel coat is shown in Table 1, wherein the wear-resistant agent is molybdenum disulfide with the average particle size of 300nm, and the lubricant comprises graphite and PTFE micro powder in a mass ratio of 1:2, wherein the weight of the graphite is 2.23kg, the weight of the PTFE micro powder is 4.47kg, the graphite is expanded graphite, the average particle size is 40 mu m, the particle size of the PTFE micro powder is 10nm, the solid content of the m-phenyl neopentyl glycol type gel coat is 64%, and the acid value is 12 mg/KOH.
The preparation method of the wear-resistant gel coat comprises the following steps: 100kg of m-phenyl neopentyl glycol type gel coat is added into a grinding machine, 4.47kg of PTFE micro powder, 2.23kg of graphite and 3kg of molybdenum disulfide are sequentially added, grinding and dispersing are uniform, high-speed mechanical stirring is carried out for 1.5h, and the wear-resistant gel coat is prepared, wherein the high-speed stirring speed is 5000 r/min.
The wear-resistant gel coat is applied to the field of logistics and comprises a sliding chute for express sorting, wherein the sliding chute comprises a glass steel matrix and a wear-resistant gel coat coated on the glass steel matrix, and the thickness of the wear-resistant gel coat is 0.6 mm.
Example 4: an abrasion resistant gel coat differing from example 1 in that the lubricant comprised graphite and PTFE micropowder in a mass ratio of 1:3, wherein 1.925kg of graphite and 5.775kg of PTFE micropowder.
Example 5: an abrasion resistant gel coat differs from example 1 in that the lubricant comprises graphite and PTFE micropowder in a mass ratio of 1:4, wherein 1.8kg of graphite and 7.2kg of PTFE micropowder.
Comparative example
Comparative example 1: a wear resistant gel coat differing from example 1 in that the lubricant does not contain graphite.
Comparative example 2: an abrasion resistant gel coat differing from example 1 in that the lubricant does not contain PTFE micropowder.
Comparative example 3: an abrasion-resistant gel coat differs from example 1 in that the mass ratio of graphite to PTFE fine powder in the lubricant is 1: 0.5.
Comparative example 4: an abrasion-resistant gel coat is different from that of example 1 in that the mass ratio of graphite to PTFE fine powder in the lubricant is 1: 4.5.
Comparative example 5: an abrasion resistant gel coat differing from example 1 in the amount of molybdenum disulfide used of 1kg and 66.7kg of m-phenyl neopentyl glycol type gel coat.
Comparative example 6: an abrasion resistant gel coat differing from example 1 in the amount of 5kg of molybdenum disulfide and 66.7kg of m-phenyl neopentyl glycol type gel coat.
Comparative example 7: a wear-resistant gel coat is different from the wear-resistant gel coat in example 1 in that the wear-resistant gel coat is prepared by stirring and dispersing 3kg of molybdenum disulfide micro powder and 100kg of m-phenyl neopentyl glycol type gel coat at a high speed.
Comparative example 8: an abrasion-resistant gel coat differing from example 1 in that it was prepared by dispersing 3kg of fine silica powder and 100kg of a m-phenyl neopentyl glycol type gel coat with high-speed stirring.
Performance test
Abrasion-resistant gel coats were prepared and coated on glass fiber reinforced plastic to prepare chute chutes for sorting according to the methods of examples 1 to 5 and comparative examples 1 to 6, and the properties of the abrasion-resistant gel coat on the chutes were measured and the measurement results are recorded in table 2:
1. roughness: detecting according to GB/T15056-2017 casting surface roughness evaluation method;
2. coefficient of dynamic friction and coefficient of static friction: the coating friction coefficient tester FPT-F1 is used for detection according to 10006-;
3. wear resistance: applying a downward force of 15.0 +/-0.2N to the gel coating layer on the sliding chute, repeatedly circulating, washing the surface of the ground sliding chute by using clear water, detecting the damage condition of the coating layer, and taking the circulation times when the glass fiber reinforced plastics begin to be exposed as a wear-resistant result;
4. hardness: testing according to GB/T6739-1996 pencil determination method for hardness of paint film;
5. adhesion force: detecting according to GB9286-98 Baige test standard;
6. wear rate (volumetric wear): detecting at a rotating speed of 60r/min and a load of 5.2N according to GB/T12444-2006 trial ring-test block of a metal material abrasion test method;
7. impact strength: testing according to GB/T1732-1993 'paint film impact resistance testing method';
8. bending strength: testing according to DIN53452, test for Plastic test for bending;
9. service life: dropping a weight of 5kg onto the sliding groove from a position 1 m above the sliding groove, repeatedly dropping for testing, and recording the dropping frequency of the weight when the surface of the sliding groove has micro cracks or depressions.
TABLE 2 examination results of abrasion resistant gel coats prepared in examples 1 to 5 and comparative examples 1 to 6
Figure BDA0002343349910000061
Figure BDA0002343349910000071
As can be seen from the data in table 2, the sliding chute prepared according to the embodiment 1-5 has smooth surface, small roughness, smooth and easy passage of goods, good silencing effect, small friction coefficient, good wear resistance, strong adhesive force between the gel coat resin and the glass fiber reinforced plastic, and large bending strength, and is not easy to crack when the glass fiber reinforced plastic is bent, small wear rate when objects circulate, longer service life of the working surface, low maintenance frequency of the sliding chute, high impact strength, and uneasy deformation of the objects under high-frequency impact collision.
Comparative example 1 because no graphite is added to the lubricant, the sliding chute made of the glass fiber reinforced plastic coated with the gel coat resin prepared in comparative example 1 has increased roughness and increased friction coefficient, and the adhesive force between the gel coat resin and the glass fiber reinforced plastic is reduced, so that the wear rate is increased and the wear resistance is poor, which indicates that the friction coefficient of the sliding chute can be reduced by adding the graphite, the smoothness of the sliding chute is increased, the adhesive force between the gel coat resin and the glass fiber reinforced plastic is improved, the wear rate of the sliding chute is reduced, and the wear resistance of the sliding chute is enhanced.
In the comparative example 2, because the PTFE micro powder is not added into the lubricant, the roughness of the sliding chute prepared in the comparative example 2 is increased, the friction coefficient is increased, the adhesive force of the gel coat resin is reduced, the wear rate of the sliding chute is increased, and the wear resistance is poor, which shows that the addition of the PTFE micro powder can increase the smoothness of the surface of the sliding chute, reduce the wear amount of the sliding chute, increase the adhesive force between the gel coat resin and the glass fiber reinforced plastic, and increase the wear resistance of the sliding chute.
Comparative example 3 since the mass ratio of graphite to PTFE fine powder in the lubricant was only 1:0.5, the surface roughness of the chute prepared in preparation example 3 was significantly increased, the smoothness was decreased, the wear rate was increased, the adhesion was decreased, and the wear resistance was deteriorated as compared with examples 1 to 5, which indicates that the smoothness and wear resistance of the chute could be significantly enhanced by using graphite and PTFE fine powder having a mass ratio of 1 (1-4) as the lubricant.
Comparative example 4 since the mass ratio of graphite to PTFE micropowder in the lubricant was 1:4.5, the run channel surface had a relatively low roughness, a low coefficient of dynamic friction and a low coefficient of static friction, a good smoothness, but a poor abrasion resistance, and the glass fiber reinforced plastic substrate was exposed only by grinding 55800 times, it was shown that excessive addition of PTFE micropowder reduced run channel friction, but reduced run channel abrasion resistance, and reduced its service life.
In comparative example 5, the usage amount of molybdenum disulfide in the lubricant is 1kg, so that the usage amount is small, the sliding chute prepared in comparative example 5 is large in roughness, poor in smoothness and wear resistance, large in wear rate and short in service life, and therefore, the fact that the roughness and smoothness of the sliding chute are affected by reducing the usage amount of molybdenum disulfide is shown, and the wear resistance and service life of the sliding chute are reduced.
Comparative example 6 since the amount of molybdenum disulfide used in the lubricant was 5kg and the amount used was large, the run channel prepared in comparative example 6 had a small roughness and good smoothness, but had a large wear rate and poor wear resistance, and the adhesion was only 3B, indicating that increasing the amount of molybdenum disulfide used reduced the coefficient of friction of the run channel and increased the smoothness, but had a reduced wear resistance, an increased wear rate, and a reduced adhesion to the glass fiber reinforced plastic substrate.
Comparative example 7 because the wear-resistant gel coat only contains 3kg of molybdenum disulfide and 100kg of m-phenyl neopentyl glycol type gel coat, and graphite powder and PTFE micropowder are not added, the friction coefficient of the chute prepared by the comparative example 7 is reduced, the smoothness is good, but the wear rate of the chute is high, and the wear resistance is poor, which shows that the friction coefficient can be reduced and the smoothness can be improved by only adding molybdenum disulfide, but the wear resistance of the chute can not be improved.
Comparative example 8 since the wear-resistant gel coat was made of 3kg of silica, which can fill the pores in the gel coat resin and increase the hardness of the run, and 100kg of the m-phenyl neopentyl glycol type gel coat, the run made of comparative example 8, which is large in both roughness and wear rate, shows that the use of silica as a wear-resistant component has less influence on the smoothness and wear resistance of the run.
The present embodiment is only for explaining the present invention, and it is not limited to the present invention, and those skilled in the art can make modifications of the present embodiment without inventive contribution as needed after reading the present specification, but all of them are protected by patent law within the scope of the claims of the present invention.

Claims (9)

1. The wear-resistant gel coat is characterized by comprising the following substances in parts by weight: 2-4 parts of wear-resistant agent, 4.5-9 parts of lubricant and 66.7-133.3 parts of m-phenyl neopentyl glycol type gel coat;
the wear-resisting agent is molybdenum disulfide, and the lubricant comprises graphite and PTFE micro powder in a mass ratio of 1 (1-4).
2. The wear-resistant gel coat as claimed in claim 1, wherein the components are, by weight: 2.49-3.48 parts of wear-resistant agent, 5.5.6-7.7 parts of lubricant and 83-116 parts of m-phenyl neopentyl glycol type gel coat;
the lubricant comprises graphite and PTFE micro powder with the mass ratio of 1 (1.5-3).
3. The wear resistant gel coat according to any one of claims 1-2, wherein the graphite is expanded graphite having an average particle size of 10-40 μm.
4. The abrasion resistant gel coat according to claim 3, wherein the particle size of the PTFE micropowder is 0.1 to 10 nm.
5. The wear resistant gel coat as claimed in any one of claims 1-2, wherein the molybdenum disulfide has an average particle size of 280-300 nm.
6. Wear resistant gel-coat according to any of claims 1-2, wherein the m-phenyl neopentyl glycol type gel-coat has a solids content of 60-64% and an acid number of 8-12 mg/KOH.
7. A method for preparing a wear resistant gel coat according to any one of claims 1 to 6, comprising the steps of: and (3) adding the m-phenyl neopentyl glycol type gel coat into a grinding machine, sequentially adding PTFE micro powder, graphite and molybdenum disulfide, uniformly grinding and dispersing, and mechanically stirring at a high speed for 1-1.5h to obtain the wear-resistant gel coat.
8. Use of a wear resistant gel coat according to any one of claims 1 to 7 in the field of logistics.
9. Use of a wear-resistant gel coat according to claim 8, comprising a chute for express sorting, the chute comprising a glass fibre reinforced plastic substrate and a wear-resistant gel coat applied to the glass fibre reinforced plastic substrate.
CN201911385026.1A 2019-12-28 2019-12-28 Wear-resistant gel coat and preparation method and application thereof Pending CN111073476A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102717517A (en) * 2012-07-06 2012-10-10 长沙晨东工贸有限公司 Manufacturing process of glass fiber reinforced plastic
CN110003698A (en) * 2019-04-15 2019-07-12 哈尔滨哈玻拓普复合材料有限公司 A kind of preparation method and applications of the hydrophobic gel coating resin of antenna house high durable
CN110016277A (en) * 2019-05-07 2019-07-16 河南科技大学 It is used to prepare the composition, self-lubricating abrasion-resistant coating, self-lubricating wear-resistant coating, self-lubricating abrasion-proof material of self-lubricating abrasion-proof material

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102717517A (en) * 2012-07-06 2012-10-10 长沙晨东工贸有限公司 Manufacturing process of glass fiber reinforced plastic
CN110003698A (en) * 2019-04-15 2019-07-12 哈尔滨哈玻拓普复合材料有限公司 A kind of preparation method and applications of the hydrophobic gel coating resin of antenna house high durable
CN110016277A (en) * 2019-05-07 2019-07-16 河南科技大学 It is used to prepare the composition, self-lubricating abrasion-resistant coating, self-lubricating wear-resistant coating, self-lubricating abrasion-proof material of self-lubricating abrasion-proof material

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Application publication date: 20200428