CN111073414A - Fire-retardant coating - Google Patents
Fire-retardant coating Download PDFInfo
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- CN111073414A CN111073414A CN201911276946.XA CN201911276946A CN111073414A CN 111073414 A CN111073414 A CN 111073414A CN 201911276946 A CN201911276946 A CN 201911276946A CN 111073414 A CN111073414 A CN 111073414A
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- coating
- fireproof coating
- fireproof
- fire retardant
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
- C09D5/185—Intumescent paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/322—Ammonium phosphate
- C08K2003/323—Ammonium polyphosphate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Fireproofing Substances (AREA)
Abstract
The invention provides a fireproof coating, which comprises, by weight, 13-30% of a base material, 63-82% of a flame retardant and 5-10% of an auxiliary agent, wherein the auxiliary agent at least comprises an anti-aging agent and a crosslinking agent. In the fireproof coating, the content of a base material is controlled to be 13-30%, so that the fireproof coating has good rheological property, the coating can be conveniently sprayed on the surface of a cable to form a uniform fireproof coating, the content of a flame retardant is controlled to be 63-82%, the cable sprayed with the fireproof coating has good fireproof performance, the content of an anti-aging agent and a crosslinking agent is controlled to be 5-10%, the anti-ultraviolet, anti-yellowing and anti-oxidation performance of the fireproof coating is improved through the anti-aging agent, the plasticizing and reinforcing effects are realized through the crosslinking agent, and the fireproof coating is prevented from cracking after a dry film is formed, so that the weather resistance of the fireproof coating is improved, and the application range of the fireproof coating is further improved.
Description
Technical Field
The application relates to the technical field of fireproof coatings, in particular to a fireproof coating.
Background
At present, telecommunication cables are high in application rate in the power industry, but most cables are not coated with fireproof coatings for protection. With the frequent occurrence of fire accidents, people continuously deepen the understanding of the fire hazard of the cable, and the requirement on the fireproof performance of the cable is higher and higher.
However, many cables on the market still do not meet good fireproof requirements at present, mainly because the fireproof coating for cable surface is easy to crack after being dried, the weather resistance is poor, the application range is narrow, and in addition, the fireproof coating with thin properties is easy to be uneven when being sprayed on the cable surface, so that the fireproof performance of the cable does not meet good fireproof requirements. At present, two kinds of fireproof coatings exist in the market, one kind of fireproof coating is a solvent type fireproof coating, and the pollution is serious and harmful to human bodies; the other is water-based paint, which has extremely low solid content and poor weather resistance, is easy to fall off in a humid environment and is easy to crack in a dry environment.
The above information disclosed in this background section is only for enhancement of understanding of the background of the technology described herein and, therefore, certain information may be included in the background that does not form the prior art that is already known in this country to a person of ordinary skill in the art.
Disclosure of Invention
The main object of the application is to provide a fire retardant coating to solve the problem of poor weather resistance of fire retardant coatings in the prior art.
In order to achieve the above object, according to one aspect of the present application, there is provided a fire retardant coating, comprising, by weight, 13% to 30% of a base material, 63% to 82% of a flame retardant, and 5% to 10% of an auxiliary agent, the auxiliary agent including at least an anti-aging agent and a crosslinking agent.
Further, the flame retardant comprises ammonium polyphosphate, and the ammonium polyphosphate accounts for 40-50% of the fireproof coating in percentage by weight.
Further, the flame retardant also comprises pentaerythritol, and the pentaerythritol accounts for 12-20% of the fireproof coating according to weight percentage.
Further, the flame retardant also comprises aluminum hydroxide, and the aluminum hydroxide accounts for 11-12% of the fireproof coating in percentage by weight.
Further, the base material is selected from at least one of epoxy resin emulsion, acrylic emulsion and styrene-acrylic emulsion.
Further, the auxiliary agent also comprises a catalyst and a foam stabilizer.
Further, the antioxidant is at least one selected from 6-ethoxy-2, 2, 4-trimethyl-1, 2-dihydroquinoline, N-phenyl- α -aniline, N-phenyl- β -naphthylamine, N-phenyl-N '-isopropyl-p-phenylenediamine and N-N' -diphenyl-p-phenylenediamine.
Further, the crosslinking agent is selected from at least one of dicumyl peroxide, benzoyl peroxide, di-tert-butyl peroxide, dicumyl peroxide, diethylenetriamine and 2, 5-dimethyl-2, 5-di-tert-butyl hexane peroxide.
Further, the catalyst is selected from at least one of bis-methyl amino ethyl ether, pentamethyl diethylene triamine, dimethyl cyclohexane, dibutyl tin dilaurate and organic bismuth.
Further, the foam stabilizer is polyether siloxane.
By applying the technical scheme of the application, in the fireproof coating, the content of the base material is controlled to be 13% -30%, so that the fireproof coating has better rheological property, the coating can be conveniently sprayed on the surface of a cable to form an even fireproof coating, the content of the flame retardant is controlled to be 63% -82%, the cable sprayed with the fireproof coating has better fireproof property, the content of the anti-aging agent and the cross-linking agent is controlled to be 5% -10%, the ultraviolet resistance, yellowing resistance and oxidation resistance of the fireproof coating are improved through the anti-aging agent, the plasticizing and reinforcing effects are realized through the cross-linking agent, cracking of the fireproof coating after a dry film is avoided, the weather resistance of the fireproof coating is improved, the fireproof coating can be suitable for outdoor severe environment, and the application range of the fireproof coating is further improved.
Detailed Description
It should be noted that the embodiments and features of the embodiments in the present application may be combined with each other without conflict. The present application will be described in detail with reference to examples.
In order to make the technical solutions of the present application better understood by those skilled in the art, the technical solutions in the embodiments of the present application will be clearly and completely described below in conjunction with the embodiments of the present application, and it is obvious that the described embodiments are only some embodiments of the present application, but not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present application.
It is noted that the terms first, second and the like in the description and in the claims of the present application are used for distinguishing between similar elements and not necessarily for describing a particular sequential or chronological order. It should be understood that the data so used may be interchanged under appropriate circumstances such that embodiments of the application described herein may be used. Furthermore, the terms "comprises," "comprising," and "having," and any variations thereof, are intended to cover a non-exclusive inclusion, such that a process, method, system, article, or apparatus that comprises a list of steps or elements is not necessarily limited to those steps or elements expressly listed, but may include other steps or elements not expressly listed or inherent to such process, method, article, or apparatus.
It will be understood that when an element such as a layer, film, region, or substrate is referred to as being "on" another element, it can be directly on the other element or intervening elements may also be present. Also, in the specification and claims, when an element is described as being "connected" to another element, the element may be "directly connected" to the other element or "connected" to the other element through a third element.
As described in the background of the invention, the weather resistance of the fire retardant coating in the prior art is poor, and in order to solve the above technical problems, the present application proposes a fire retardant coating.
In a typical embodiment of the present application, there is provided a fire retardant coating, which comprises, by weight, 13% to 30% of a base material, 63% to 82% of a flame retardant, and 5% to 10% of an auxiliary agent, wherein the auxiliary agent comprises at least an anti-aging agent and a crosslinking agent.
In the fireproof coating, the content of the base material is controlled to be 13-30%, so that the fireproof coating has better rheological property, the coating can be conveniently sprayed on the surface of a cable to form a uniform fireproof coating, the content of the flame retardant is controlled to be 63-82%, the cable sprayed with the fireproof coating has better fireproof property, the content of the anti-aging agent and the crosslinking agent is controlled to be 5-10%, the anti-ultraviolet, anti-yellowing and anti-oxidation properties of the fireproof coating are improved through the anti-aging agent, the plasticizing and reinforcing effects are realized through the crosslinking agent, and the fireproof coating is prevented from cracking after a dry film is formed, so that the weather resistance of the fireproof coating is improved, the fireproof coating can be suitable for outdoor severe environment, and the application range of the fireproof coating is further improved.
In an embodiment of the present application, the flame retardant includes ammonium polyphosphate, and the ammonium polyphosphate accounts for 40% to 50% of the fire retardant coating by weight. In the fireproof coating, the content of ammonium polyphosphate in the flame retardant is controlled to be between 40% and 50%, so that a phosphoric acid layer is generated in the decomposition process of the flame retardant under the action of high temperature, a non-volatile protective layer is formed to cover a combustion surface, oxygen supply is isolated to promote combustion termination, and a cable sprayed with the fireproof coating has good fireproof performance.
In an embodiment of the present application, the flame retardant further includes pentaerythritol, and the pentaerythritol accounts for 12% to 20% of the fire retardant coating in terms of weight percentage. In the fireproof coating, the content of pentaerythritol in the flame retardant is controlled to be 12-20%, so that the fireproof coating expands when heated in fire to form a carbonaceous foam layer with a certain thickness, good strength, excellent adhesive force and heat insulation capability, and a cable sprayed with the fireproof coating has good fireproof performance.
In an embodiment of the present application, the flame retardant further includes aluminum hydroxide, and the aluminum hydroxide accounts for 11% to 12% of the fireproof coating by weight. In the fireproof coating, the content of aluminum hydroxide in the flame retardant is controlled to be 11-12%, so that heat released by combustion is absorbed when meeting fire, the surface temperature of combustible materials is reduced, and the spread of combustion is prevented.
It should be noted that in the above fire-retardant coating, ammonium polyphosphate accounts for 40% -50% of the fire-retardant coating, pentaerythritol accounts for 12% -20% of the fire-retardant coating, and aluminum hydroxide accounts for 11% -12% of the above fire-retardant coating, so that the cable sprayed with the fire-retardant coating has good fire-retardant performance, can inhibit the spread of fire, can keep the smooth circuit of the cable in the fire scene, and can allow the data to have enough time to be transferred to a safe place in the fire scene.
In one embodiment of the present application, the substrate is at least one selected from the group consisting of an epoxy resin emulsion, an acrylic emulsion, and a styrene-acrylic emulsion. Specifically, the emulsion is selected as a base material, so that the bonding property and the curing property of the fireproof coating can be improved, and the water resistance and the adhesive force strength of a coating formed by the fireproof coating are improved. Of course, the substrate is not limited thereto, and those skilled in the art can select other suitable substrates according to the actual situation.
In one embodiment of the present application, the auxiliary further comprises a catalyst and a foam stabilizer. The catalyst can play a role in catalyzing the chemical reaction of polyether and a curing agent in the synthesis process of a polyurethane product, so that the fireproof coating can be quickly cured, the phenomenon of coating sagging is avoided, the foam stabilizer can control the uniformity and the opening rate of foam pores of a polyurethane foaming material, and the generated polyurethane foam and a carbon layer generated by the oxidative decomposition of pentaerythritol form a carbonaceous foam layer together.
In one embodiment of the present application, the anti-aging agent is at least one selected from 6-ethoxy-2, 2, 4-trimethyl-1, 2-dihydroquinoline, N-phenyl- α -aniline, N-phenyl- β -naphthylamine, N-phenyl-N '-isopropyl-p-phenylenediamine, and N-N' -diphenyl-p-phenylenediamine.
In one embodiment of the present application, the crosslinking agent is at least one selected from the group consisting of dicumyl peroxide, benzoyl peroxide, di-t-butyl peroxide, dicumyl peroxide, diethylenetriamine, and 2, 5-dimethyl-2, 5-di-t-butylperoxyhexane. Specifically, the selection of the above crosslinking agents can improve the plasticizing and reinforcing effects, and certainly, the crosslinking agents are not limited thereto, and those skilled in the art can select other suitable crosslinking agents according to the actual situation.
In one embodiment of the present application, the catalyst is at least one selected from the group consisting of bis-methylaminoethyl ether, pentamethyldiethylenetriamine, dimethylcyclohexane, dibutyltin dilaurate, and organobismuth. Specifically, the catalysts are selected to improve the catalytic effect of the chemical reaction of the polyether and the curing agent in the synthesis process of the polyurethane product, so as to further shorten the curing time.
In one embodiment of the present application, the foam stabilizer is polyether siloxane. Specifically, polyether siloxane is selected as the foam stabilizer to control the uniformity and the opening rate of the foam pores of the polyurethane foam material, so that the fire-retardant coating generates a carbonaceous foam layer with good heat insulation capability when encountering fire.
In order to make the technical solutions of the present application more clearly understood by those skilled in the art, the technical solutions of the present application will be described below with reference to specific embodiments.
Examples
The fire retardant coating of the embodiment comprises 20% of acrylic emulsion, 72% of flame retardant and 8% of auxiliary agent, wherein in the components of the flame retardant, ammonium polyphosphate accounts for 44% of the fire retardant coating, pentaerythritol accounts for 16% of the fire retardant coating, and aluminum hydroxide accounts for 12% of the fire retardant coating.
The fireproof coating of the above embodiment is applied to a tunnel cable and subjected to a performance test, and the test results are shown in table 1.
TABLE 1
As can be seen from Table 1, the fireproof coating of the embodiment has good ultraviolet resistance, oil resistance, salt water resistance, humidity resistance and freeze-thaw cycle resistance, the weather resistance of the fireproof coating is greatly improved, the service life of the fireproof coating is prolonged, the flame retardance of the fireproof coating reaches 1.5, the cable sprayed with the fireproof coating has good fireproof performance, the curing time is short, the coating sagging phenomenon can be effectively prevented, in addition, the content of harmful substances in the fireproof coating is as low as 0.01g/kg, the generation of harmful gases in case of fire can be greatly reduced, and the environmental pollution is reduced.
From the above description, it can be seen that the above-described embodiments of the present application achieve the following technical effects:
in the fireproof coating, the content of the base material is controlled between 13% and 30%, so that the fireproof coating has better rheological property, the coating can be conveniently sprayed on the surface of a cable to form an even fireproof coating, the content of the flame retardant is controlled between 63% and 82%, the cable sprayed with the fireproof coating has better fireproof property, the content of the anti-aging agent and the crosslinking agent is controlled between 5% and 10%, the anti-ultraviolet, anti-yellowing and anti-oxidation properties of the fireproof coating are improved through the anti-aging agent, the plasticizing and reinforcing effects are realized through the crosslinking agent, cracking after a dry film of the fireproof coating is avoided, the weather resistance of the fireproof coating is improved, the fireproof coating can be suitable for outdoor severe environment, and the application range of the fireproof coating is further improved.
The above description is only a preferred embodiment of the present application and is not intended to limit the present application, and various modifications and changes may be made by those skilled in the art. Any modification, equivalent replacement, improvement and the like made within the spirit and principle of the present application shall be included in the protection scope of the present application.
Claims (10)
1. The fireproof coating is characterized by comprising, by weight, 13-30% of a base material, 63-82% of a flame retardant and 5-10% of an auxiliary agent, wherein the auxiliary agent at least comprises an anti-aging agent and a crosslinking agent.
2. The fireproof coating according to claim 1, wherein the flame retardant comprises ammonium polyphosphate, and the ammonium polyphosphate accounts for 40-50% of the fireproof coating in percentage by weight.
3. The fireproof coating of claim 2, wherein the flame retardant further comprises pentaerythritol, and the pentaerythritol comprises 12% to 20% of the fireproof coating by weight.
4. The fire retardant coating of claim 1, wherein the flame retardant further comprises aluminum hydroxide, and the aluminum hydroxide accounts for 11-12% of the fire retardant coating by weight.
5. The fire retardant coating of any one of claims 1 to 4 wherein said substrate is selected from at least one of epoxy resin emulsion, acrylic emulsion and styrene-acrylic emulsion.
6. The fireproofing coating according to any one of claims 1 to 4, wherein the auxiliary further comprises a catalyst and a foam stabilizer.
7. The fire retardant coating of any one of claims 1 to 4, wherein said antioxidant is selected from at least one of 6-ethoxy-2, 2, 4-trimethyl-1, 2-dihydroquinoline, N-phenyl- α -aniline, N-phenyl- β -naphthylamine, N-phenyl-N '-isopropyl-p-phenylenediamine and N-N' -diphenyl-p-phenylenediamine.
8. The fire retardant coating according to any one of claims 1 to 4 wherein said cross-linking agent is selected from at least one of dicumyl peroxide, benzoyl peroxide, di-t-butyl peroxide, dicumyl peroxide, diethylenetriamine and 2, 5-dimethyl-2, 5-di-t-butyl hexane peroxide.
9. The fire retardant coating of claim 6, wherein said catalyst is selected from at least one of bis-methyl aminoethyl ether, pentamethyldiethylenetriamine, dimethylcyclohexane, dibutyltin dilaurate, and organobismuth.
10. The fire retardant coating of claim 6 wherein said foam stabilizer is a polyether siloxane.
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CN201911276946.XA CN111073414A (en) | 2019-12-12 | 2019-12-12 | Fire-retardant coating |
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CN201911276946.XA CN111073414A (en) | 2019-12-12 | 2019-12-12 | Fire-retardant coating |
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Citations (4)
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CA1109607A (en) * | 1978-12-06 | 1981-09-29 | Gil M. Dias | Semi-durable, water repellent, fire resistant intumescent composition |
CN101077953A (en) * | 2007-07-05 | 2007-11-28 | 湖南大学 | Water super-thin steel structure fire-proof paint and preparation method thereof |
CN102093789A (en) * | 2011-01-14 | 2011-06-15 | 沈阳建筑大学 | Modified nano aluminium hydroxide water expansion type overcoating fire retardant paint and preparation method thereof |
CN108795205A (en) * | 2018-06-27 | 2018-11-13 | 广东黑卫防火技术有限公司 | Weather-proof intumescent cable fireproof coating and preparation method thereof |
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2019
- 2019-12-12 CN CN201911276946.XA patent/CN111073414A/en active Pending
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CA1109607A (en) * | 1978-12-06 | 1981-09-29 | Gil M. Dias | Semi-durable, water repellent, fire resistant intumescent composition |
CN101077953A (en) * | 2007-07-05 | 2007-11-28 | 湖南大学 | Water super-thin steel structure fire-proof paint and preparation method thereof |
CN102093789A (en) * | 2011-01-14 | 2011-06-15 | 沈阳建筑大学 | Modified nano aluminium hydroxide water expansion type overcoating fire retardant paint and preparation method thereof |
CN108795205A (en) * | 2018-06-27 | 2018-11-13 | 广东黑卫防火技术有限公司 | Weather-proof intumescent cable fireproof coating and preparation method thereof |
Non-Patent Citations (6)
Title |
---|
YING DONG ET AL: "Influences of silicone emulsion on fire protection of waterborne intumescent fire-resistive coating", 《JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH 》 * |
于静等: "环保超薄型钢结构防火涂料", 《中国涂料》 * |
刘国杰: "《现代涂料与涂装技术》", 31 May 2002 * |
化工部合成材料研究院等: "《聚合物防老化实用手册》", 30 June 1999 * |
周大纲: "《土工合成材料制造技术及性能(第二版)》", 30 April 2019 * |
张学敏: "《涂料与涂装技术》", 31 January 2006 * |
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