CN112094585A - Ultrathin steel structure fireproof coating and preparation method thereof - Google Patents

Ultrathin steel structure fireproof coating and preparation method thereof Download PDF

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CN112094585A
CN112094585A CN202010992853.3A CN202010992853A CN112094585A CN 112094585 A CN112094585 A CN 112094585A CN 202010992853 A CN202010992853 A CN 202010992853A CN 112094585 A CN112094585 A CN 112094585A
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coating
resin
steel structure
fireproof coating
proportion
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魏超
顾剑东
王志强
李斌
周敏
施颖波
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CHC NORTH PAINT & COATINGS INDUSTRY RESEARCH AND DESIGN INSTITUTE
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CHC NORTH PAINT & COATINGS INDUSTRY RESEARCH AND DESIGN INSTITUTE
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18—Fireproof paints including high temperature resistant paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2217—Oxides; Hydroxides of metals of magnesium
    • C08K2003/2224—Magnesium hydroxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2227—Oxides; Hydroxides of metals of aluminium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/38—Boron-containing compounds
    • C08K2003/387—Borates

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  • Inorganic Chemistry (AREA)
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Abstract

An ultra-thin steel structure fireproof coating and a preparation method thereof, the ultra-thin steel structure fireproof coating comprises: 10-50% of organic-inorganic hybrid resin; 10-70% of heat insulation filler; 5-15% of flame-retardant filler; 2-10% of an auxiliary agent; 5-40% of a solvent; 5-30% of a curing agent; the organic-inorganic hybrid resin includes: 15-30% of siloxane monomer; 25-60% of sol; 20-40% of modified hydroxyl resin; 0.01-3% of a first catalyst; 10-40% of a solvent; the balance of water. The ultra-thin steel structure fireproof coating provided by the invention has low coating heat conductivity, and the fire resistance limit of the coating reaches more than 2h under the condition that the thickness of the coating is less than 3 mm; when the thickness is less than 2mm, the fire resistance limit can still reach more than 2h, and the fireproof performance is good.

Description

Ultrathin steel structure fireproof coating and preparation method thereof
Technical Field
The invention belongs to the technical field of coatings, and particularly relates to an ultrathin steel structure fireproof coating and a preparation method thereof.
Background
With the high-speed development of economy, the development of various industries is rapidly advanced, various new materials are continuously emerged in the civil building industry, high-rise and super high-rise buildings are pulled out, and the steel structure has the characteristics of small density, high strength, easiness in installation and good shock resistance, so that the steel structure is widely applied to the building industry, but the steel structure has poor fire resistance, the temperature is rapidly increased when a fire disaster occurs, and when the temperature exceeds the critical temperature of 500 ℃, the structure is damaged, the bearing capacity is lost, the deformation or the fracture occurs, the building is collapsed, and the serious personal injury and the economic loss are caused. Therefore, the flame-retardant and fireproof coating is produced at the same time, and is widely applied to the fields of engineering construction, ancient buildings, cultural relics, ships, tunnels, transportation, war industry, chemical industry, petroleum and the like.
The currently adopted fire-retardant coatings are divided into intumescent and non-intumescent fire-retardant coatings according to different fire-retardant principles; according to the thickness of the coating, the coating is divided into an ultra-thin type (the thickness is less than 3mm), a thin type (3-7mm) and a thick type (7-45 mm). The mainstream fireproof coating in the market at present is a thick fireproof coating, the fire resistance limit of the thick fireproof coating can reach 3 hours, but the coating has poor decoration, high density and poor coating adhesion, and the coating thickness causes certain burden on a steel structure. The coating is thin and ultrathin, has good coating effect and good adhesive force, but has poor weather resistance, the fire resistance limit is only 1-2h, and the use is limited to a certain extent. Therefore, the development of the ultra-thin fireproof coating with long fire resistance limit has good application value.
Disclosure of Invention
The invention aims to provide an ultrathin steel structure fireproof coating and a preparation method thereof, and solves at least one of the problems of high thickness, low fire resistance limit, poor adhesion, low thermal conductivity, poor weather resistance and the like of the conventional fireproof coating.
The organic-inorganic hybrid resin is prepared by adopting a sol-gel method, is used as a main resin, does not need to be added with any flame retardant, has good ablation resistance, can not be pulverized after being ablated for a certain time at high temperature, can keep a resin prototype, and has small volume shrinkage; the fireproof coating is prepared by matching with heat insulation filler and foaming substances, and the fire resistance limit of the coating reaches more than 2 hours under the condition that the thickness of the coating is less than 3 mm; when the thickness is less than 2mm, the fire resistance limit can still reach more than 2h, and the fireproof performance is good; the bonding strength of the coating after film formation is not lower than 7MPa, and the tensile strength is not lower than 5 MPa; the coating has low heat conductivity and good weather resistance, and the coating can be used as an anticorrosive heat-insulating coating under the non-fire condition.
In order to achieve the purpose, the invention provides the following technical scheme:
the invention provides an ultrathin steel structure fireproof coating, which comprises the following components in percentage by mass:
Figure BDA0002691336550000021
in one example of the invention, the flame retardant filler may be selected from, but is not limited to: one or a combination of more than two of pentaerythritol, dipentaerythritol, melamine, zinc borate, magnesium hydroxide and aluminum hydroxide in any proportion.
In an example of the invention, the insulating filler may be selected from, but not limited to: one of titanium dioxide, hollow glass beads, fumed silica and carbon fiber and the combination of more than two of the titanium dioxide, the hollow glass beads, the fumed silica and the carbon fiber in any proportion.
In an example of the present invention, the auxiliary agent is used to improve the wet dispersibility of the pigment and filler, and any commercially available auxiliary agent meeting the requirement may be suitable for the present invention, for example, the auxiliary agent may be selected from, but is not limited to: one or a combination of more than two of BYK110, BYK163, BYK180, BYK358N and BYK378 in any proportion. BYK110, BYK163, BYK180, BYK358N and BYK378 are all auxiliary products produced by Pico chemical company.
In one example of the present invention, the solvent may be selected from, but is not limited to: one or a combination of more than two of xylene, cyclohexanone, ethyl acetate, butyl acetate, propylene glycol methyl ether acetate, ethanol, isopropanol, butanol, butanone and acetone in any proportion.
In one example of the present invention, the curing agent may be selected from, but is not limited to: hexamethylene diisocyanate trimer, isophorone diisocyanate, hexamethylene diisocyanate (HDI monomer), hexamethylene diisocyanate trimer (HDI trimer), hexamethylene diisocyanate biuret (HDI biuret), diphenylmethane diisocyanate, and hydrogenated phenylmethane diisocyanate.
In an example of the present invention, the organic-inorganic hybrid resin includes the following components, by mass:
Figure BDA0002691336550000031
the balance of water.
In one example of the present invention, the siloxane monomer may be selected from, but is not limited to: methyl triethoxysilane, methyl trimethoxysilane, dimethyl diethoxy silane, dimethyl dimethoxy silane, isopropyl triethoxysilane, isopropyl trimethoxysilane, n-octyl triethoxysilane, n-octyl trimethoxysilane, and/or ethyl orthosilicate.
In one example of the present invention, the sol may be selected from, but is not limited to: one or a combination of more than two of silica sol, aluminum sol, zirconium sol and titanium sol in any proportion.
In one example of the present invention, the water is deionized water.
In one example of the present invention, the first catalyst may be selected from, but is not limited to: one or a combination of more than two of hydrochloric acid, acetic acid, butyric acid, caproic acid, phosphoric acid and sulfuric acid in any proportion.
In one example of the present invention, the solvent may be selected from, but is not limited to: one or the combination of more than two of ethanol, isopropanol, butanol, butanone, xylene, cyclohexanone, ethanol, ethyl acetate and butyl acetate in any proportion.
In an example of the invention, the modified hydroxyl resin comprises the following components in percentage by mass: 50-80% of hydroxyl resin; 18-45% of resin modifier; 0.1-5% of second catalyst.
In one example of the present invention, the hydroxyl resin may be selected from, but not limited to: one or a combination of more than two of polyester dihydric alcohol, polyether dihydric alcohol, polycarbonate dihydric alcohol, polycaprolactone dihydric alcohol and polycaprolactone trihydric alcohol in any proportion.
In one example of the present invention, the resin modifier may be selected from, but is not limited to: one of gamma-isocyanate trimethoxy silane and gamma-isocyanate triethoxy silane.
In one example of the present invention, the second catalyst may be selected from, but is not limited to: one or a combination of more than two of tetrabutyl titanate, diethylenetriamine, trimethyl amine bromide, N dimethyl cyclohexane and dibutyltin dilaurate in any proportion.
In an example of the present invention, a method for preparing the modified hydroxyl resin is provided, which includes the following steps: mixing the hydroxyl resin and the resin modifier according to the formula amount of the raw materials, reacting for 2-2.5h at the temperature of 40-50 ℃, adding the second catalyst, and reacting for 5-6h at the temperature of 50-60 ℃ to obtain the modified hydroxyl resin.
In one example of the present invention, there is provided a method for preparing the organic-inorganic hybrid resin, comprising the steps of: the sol, water and the first catalyst are mixed and stirred uniformly according to the formula amount of the raw materials, the siloxane monomer is dripped, the dripping speed of 2-3 drops per second is controlled, then the mixture is heated, kept warm and refluxed for 2-2.5 hours, then the temperature is reduced to be below 40 ℃, the modified hydroxyl resin and the solvent are added, then the temperature is raised to be enough to remove the added equal solvent amount, and then the temperature is reduced to be room temperature, so that the organic-inorganic hybrid resin is obtained.
The second aspect of the invention provides a preparation method of the ultrathin steel structure fireproof coating, which comprises the following steps:
according to the formula amount of the raw materials, the auxiliary agent and the flame-retardant filler are added into the organic-inorganic hybrid resin, uniformly mixed and ground, then the heat-insulating filler and the solvent are added, uniformly mixed, and then mixed with the curing agent, so that the ultrathin steel structure fireproof coating is obtained.
In one example of the invention, the heat insulating filler and the solvent are added and then stirred at a high speed under the condition of 800-1000r/min, so that the pigment and the resin are fully and uniformly mixed.
In one example of the invention, the auxiliary agent and the flame-retardant filler are added into the organic-inorganic hybrid resin, mixed uniformly and ground to the fineness of less than or equal to 80 μm.
Compared with the prior art, the technical effects of the invention comprise the following aspects:
the ultrathin steel structure fireproof coating prepared by the invention has good construction performance, low coating heat conductivity and good weather resistance, and the fire resistance limit of the coating reaches more than 2 hours under the condition that the thickness of the coating is less than 3 mm; when the thickness is less than 2mm, the fire resistance limit can still reach more than 2h, and the fireproof performance is good.
It is to be understood that both the foregoing general description and the following detailed description are exemplary and explanatory only and are not restrictive of the invention, as claimed.
Detailed Description
The present invention will be further described with reference to the following examples.
Embodiments of the present invention will be described in detail below with reference to examples, but it will be understood by those skilled in the art that the following examples are only illustrative of the present invention and should not be construed as limiting the scope of the present invention. The examples, in which specific conditions are not specified, were conducted under conventional conditions or conditions recommended by the manufacturer. The reagents or instruments used are not indicated by the manufacturer, and are all conventional products available commercially.
In order to overcome the defects of the prior art and meet the requirements of the prior market, the invention provides an ultrathin steel structure fireproof coating and a preparation method thereof.
According to a first aspect of the present invention, some embodiments of the present invention provide an ultrathin steel structure fireproof coating, which comprises the following components by mass: 10-50% of organic-inorganic hybrid resin; 10-70% of heat insulation filler; 5-15% of flame-retardant filler; 2-10% of an auxiliary agent; 5-40% of a solvent; 5 to 30 percent of curing agent.
The fireproof coating provided by the invention is used for self-made organic-inorganic hybrid resin, wherein silane monomer hydrolysate is an inorganic component, and the temperature resistance of the resin is provided; the modified hydroxyl resin is an organic component and provides better mechanical property for the resin, and the modified hydroxyl resin and the resin are chemically modified according to a certain proportion, so that the resin has good temperature resistance and good mechanical property, has good temperature resistance, can reach the fire resistance limit of the traditional thick fire-proof coating when being used for preparing the ultrathin fire-proof coating, even has a better fire resistance limit than the thick fire-proof coating, and has excellent construction performance compared with the coating.
In certain embodiments of the present invention, the flame retardant filler may be selected from, but is not limited to: one or a combination of more than two of pentaerythritol, dipentaerythritol, melamine, zinc borate, magnesium hydroxide and aluminum hydroxide in any proportion.
In some embodiments of the present invention, the insulating filler may be selected from, but is not limited to: one of titanium dioxide, hollow glass beads, fumed silica and carbon fiber and the combination of more than two of the titanium dioxide, the hollow glass beads, the fumed silica and the carbon fiber in any proportion.
In certain embodiments of the present invention, the adjuvant may be selected from, but is not limited to: one or a combination of more than two of BYK110, BYK163, BYK180, BYK358N and BYK378 in any proportion. BYK110, BYK163, BYK180, BYK358N and BYK378 are all auxiliary products produced by Pico chemical company.
In certain embodiments of the present invention, the solvent may be selected from, but is not limited to: one or a combination of more than two of xylene, cyclohexanone, ethyl acetate, butyl acetate, propylene glycol methyl ether acetate, ethanol, isopropanol, butanol, butanone and acetone in any proportion.
In certain embodiments of the present invention, the curing agent may be selected from, but is not limited to: hexamethylene diisocyanate trimer, isophorone diisocyanate, hexamethylene diisocyanate (HDI monomer), hexamethylene diisocyanate trimer (HDI trimer, for example, N-3390), hexamethylene diisocyanate biuret (HDI biuret, for example, N-75), diphenylmethane diisocyanate, hydrogenated phenylmethane diisocyanate, or a combination of two or more thereof in any ratio.
In some embodiments of the present invention, the amount of the heat insulating filler added in the fireproof coating is 10-70% of the total mass, i.e., the mass percentage content of the heat insulating filler is greater than or equal to 10% and less than or equal to 70%, and a typical but non-limiting content may be, for example, 10%, 15%, 18%, 20%, 23%, 25%, 27%, 30%, 35%, 40%, 44%, 48%, 50%, 55%, 59%, 62%, 65%, 68%, or 70%.
Further, in the fire-retardant coating, the amount of the insulating filler added is controlled in the range of 10 to 70%, and if the amount of the insulating filler added is higher than 70%, the results include, but are not limited to: the coating has poor application property, and the mechanical property of the coating is reduced; if the amount of insulating filler added is less than 10%, this results in a range including, but not limited to: the coating has high thermal conductivity and poor thermal insulation.
In some embodiments of the present invention, the amount of the flame retardant filler added in the fire retardant coating is 5-15% of the total mass, that is, the mass percentage of the flame retardant filler is greater than or equal to 5% and less than or equal to 15%, and a typical but non-limiting content may be, for example, 5%, 6%, 7%, 8%, 9%, 10%, 11%, 12%, 13%, 14%, or 15%.
Further, in the fire-retardant coating, the addition amount of the flame-retardant filler is controlled in the range of 5 to 15%, and if the addition amount of the flame-retardant filler is more than 15%, the effects include, but are not limited to: the workability and mechanical property of the coating are reduced; if the flame retardant filler is added in an amount less than 5%, this results in a flame retardant filler that includes, but is not limited to: the coating has short fire resistance limit and poor fire-proof effect.
In some embodiments of the present invention, the addition amount of the auxiliary agent in the fire-retardant coating is 2-10% of the total mass, that is, the mass percentage content of the flame-retardant filler is greater than or equal to 2% and less than or equal to 10%, and a typical but non-limiting content may be, for example, 2%, 2.5%, 3%, 3.5%, 4%, 5%, 6%, 7%, 8%, 9%, or 10%.
Furthermore, in the fireproof coating, the addition amount of the auxiliary agent is controlled within the range of 2-10%, and if the addition amount of the auxiliary agent is less than 2%, the wetting dispersibility of the pigment and filler in the coating is poor, so that the performance of the coating is influenced.
In some embodiments of the present invention, the amount of the solvent added in the fire-retardant coating is 5-40% of the total mass, that is, the mass percentage of the solvent is greater than or equal to 5% and less than or equal to 40%, and a typical but non-limiting content may be, for example, 5%, 10%, 15%, 20%, 25%, 30%, 35%, or 40%.
Further, in the fire retardant coating, the amount of the solvent added is controlled in the range of 5 to 40%, and if the amount of the solvent added is higher than 40%, it is caused to include but not limited to: the thickness of the coating is poor after curing, and the coating needs to be constructed for many times to meet the thickness requirement, so that the cost is increased; if the amount of solvent added is less than 5%, this results in a range including, but not limited to: the coating has poor application property, and further the performance of the coating is influenced.
In some embodiments of the present invention, the amount of the curing agent added in the fireproof coating is 5-30% of the total mass, that is, the content of the curing agent is greater than or equal to 5% and less than or equal to 30% by mass, and a typical but non-limiting content may be, for example, 5%, 10%, 15%, 20%, 25%, or 30%.
Further, in the fire retardant coating, the addition amount of the curing agent is controlled in the range of 5 to 30%, and if the addition amount of the curing agent is more than 30%, it results in the following including but not limited to: the coating is brittle and has poor mechanical properties; if the addition amount of the curing agent is less than 5%, this results in the following properties including, but not limited to: the coating is not cured completely, is soft and sticky, and influences the mechanical properties.
In some embodiments of the present invention, the amount of the organic-inorganic hybrid resin added in the fire retardant coating is 10-50% of the total mass, i.e., the mass percentage of the organic-inorganic hybrid resin is greater than or equal to 10% and less than or equal to 50%, and a typical but non-limiting content may be, for example, 10%, 12%, 15%, 20%, 25%, 28%, 30%, 32%, 35%, 40%, 45%, 48%, or 50%.
Further, in the fire retardant coating, the addition amount of the organic-inorganic hybrid resin is controlled in the range of 10 to 50%, and if the addition amount of the organic-inorganic hybrid resin is more than 50%, it results in the following including but not limited to: the coating has poor fire resistance limit and poor fire resistance; if the organic-inorganic hybrid resin is added in an amount of less than 10%, it results in the following, including but not limited to: the mechanical property of the coating is poor, and the workability is poor.
In certain embodiments of the present invention, the organic-inorganic hybrid resin comprises the following components in percentage by mass: 15-30% of siloxane monomer; 25-60% of sol; 20-40% of modified hydroxyl resin; 0.01-3% of a first catalyst; 10-40% of a solvent; the balance of water.
In certain embodiments of the present invention, the siloxane monomer may be selected from, but is not limited to: methyl triethoxysilane, methyl trimethoxysilane, dimethyl diethoxy silane, dimethyl dimethoxy silane, isopropyl triethoxysilane, isopropyl trimethoxysilane, n-octyl triethoxysilane, n-octyl trimethoxysilane, and/or ethyl orthosilicate.
In some embodiments of the present invention, the sol may be selected from, but is not limited to: one or a combination of more than two of silica sol, aluminum sol, zirconium sol and titanium sol in any proportion.
In certain embodiments of the present invention, the water is deionized water.
In certain embodiments of the present invention, the first catalyst may be selected from, but is not limited to: one or a combination of more than two of hydrochloric acid, acetic acid, butyric acid, caproic acid, phosphoric acid and sulfuric acid in any proportion.
In certain embodiments of the present invention, the solvent may be selected from, but is not limited to: one or the combination of more than two of ethanol, isopropanol, butanol, butanone, xylene, cyclohexanone, ethanol, ethyl acetate and butyl acetate in any proportion.
In some embodiments of the present invention, the modified hydroxyl resin comprises the following components by mass: 50-80% of hydroxyl resin; 18-45% of resin modifier; 0.1-5% of second catalyst.
In certain embodiments of the present invention, the hydroxyl resin may be selected from, but is not limited to: one or a combination of more than two of polyester dihydric alcohol, polyether dihydric alcohol, polycarbonate dihydric alcohol, polycaprolactone dihydric alcohol and polycaprolactone trihydric alcohol in any proportion.
In certain embodiments of the present invention, the resin modifier may be selected from, but is not limited to: one of gamma-isocyanate trimethoxy silane and gamma-isocyanate triethoxy silane.
In certain embodiments of the present invention, the second catalyst may be selected from, but is not limited to: tetrabutyl titanate, diethylenetriamine, trimethyl ammonium bromide, N dimethyl cyclohexane and dibutyltin dilaurate in any proportion.
In some embodiments of the present invention, the siloxane monomer accounts for 15 to 30% by mass of the total mass of the organic-inorganic hybrid resin, i.e., the siloxane monomer is present in an amount of 15% by mass or more and 30% by mass or less, and may be present in an amount of, for example, 15%, 17%, 18%, 20%, 23%, 25%, 28%, or 30% by mass, which is typical but not limiting.
Further, in the organic-inorganic hybrid resin, the added amount of the siloxane monomer is controlled in the range of 15 to 30%, and if the added amount of the siloxane monomer is more than 30%, it results in the following including but not limited to: the resin has high crosslinking density, and shows that the resin is brittle; if the siloxane monomer is added in an amount less than 15%, this results in a composition including, but not limited to: the crosslinking density is insufficient and the mechanical properties of the resin are poor.
In some embodiments of the present invention, the mass of the sol in the organic-inorganic hybrid resin accounts for 25-60% of the total mass, i.e., the mass percentage of the sol is greater than or equal to 25% and less than or equal to 60%, and a typical but non-limiting content may be, for example, 25%, 30%, 35%, 40%, 45%, 50%, 52%, 55%, or 60%.
Further, in the organic-inorganic hybrid resin, the amount of sol added is controlled in the range of 25 to 60%, and if the amount of sol added is higher than 60%, it results in the following including but not limited to: resins tend to be inorganic and have poor mechanical properties. If the sol addition level is below 25%, this results in a range including, but not limited to: the temperature resistance of the resin is poor, and the fire resistance of the coating is further influenced.
In some embodiments of the present invention, the mass of the modified hydroxyl resin in the organic-inorganic hybrid resin accounts for 20-40% of the total mass, i.e., the mass percentage content of the modified hydroxyl resin is greater than or equal to 20% and less than or equal to 40%, and a typical but non-limiting content may be, for example, 20%, 22%, 25%, 30%, 35%, or 40%.
Further, in the organic-inorganic hybrid resin, the addition amount of the modified hydroxyl resin is controlled in the range of 20 to 40%, and if the addition amount of the modified hydroxyl resin is more than 40%, it results in the following including but not limited to: the resin tends to be organized more and has poor temperature resistance; if the modified hydroxyl resin is added in an amount less than 20%, this results in the following, including but not limited to: the mechanical properties of the resin are poor.
In certain embodiments of the present invention, the mass of the first catalyst in the organic-inorganic hybrid resin is 0.01 to 3% of the total mass, i.e., the mass percentage content of the first catalyst is 0.01% or more and 3% or less, and typical but non-limiting contents may be, for example, 0.01%, 0.1%, 0.2%, 0.3%, 0.4%, 0.5%, 0.6%, 0.7%, 0.8%, 0.9%, 1%, 1.2%, 1.4%, 1.5%, 1.7%, 2.0%, 2.2%, 2.4%, 2.5%, 2.7%, or 3.0%.
In some embodiments of the present invention, the organic-inorganic hybrid resin contains 10 to 40% by mass of the solvent based on the total mass, i.e., the solvent is contained in an amount of 10% by mass or more and 40% by mass or less, and a typical but non-limiting amount may be, for example, 10%, 15%, 20%, 25%, 30%, 35%, or 40%.
Further, in the organic-inorganic hybrid resin, the amount of solvent added is controlled in the range of 10 to 40%, and if the amount of solvent added is higher than 40%, it results in the following including but not limited to: the solid content of the resin is low, so that the solid content of the later coating is low, and the thickness of the coating is influenced; if the amount of solvent added is less than 10%, this results in a range including, but not limited to: the resin is susceptible to coking during synthesis.
In some embodiments of the present invention, the modified hydroxyl resin comprises the following components by mass: 50-80% of hydroxyl resin; 18-45% of resin modifier; 0.1-5% of second catalyst.
In some embodiments of the present invention, the mass of the hydroxyl resin in the modified hydroxyl resin accounts for 50 to 80% of the total mass, i.e., the mass percentage content of the hydroxyl resin is greater than or equal to 50% and less than or equal to 80%, and a typical but non-limiting content may be, for example, 50%, 53%, 56%, 60%, 62%, 65%, 70%, 72%, 75%, 78%, or 80%.
Further, in the modified hydroxyl resin, the amount of the hydroxyl resin added is controlled in the range of 50 to 80%, and if the amount of the hydroxyl resin added is higher than 80%, this results in the following including but not limited to: the modification is incomplete, and the resin performance is poor; if the hydroxyl resin is added in an amount less than 50%, this results in a range including, but not limited to: the toughness of the resin is poor.
In some embodiments of the present invention, the mass of the resin modifier in the modified hydroxyl resin is 18 to 45% of the total mass, i.e., the mass percentage content of the resin modifier is greater than or equal to 18% and less than or equal to 45%, and a typical but non-limiting content may be, for example, 18%, 20%, 25%, 30%, 35%, 40%, 42%, or 45%.
Further, in the modified hydroxyl resin, the addition amount of the resin modifier is controlled in the range of 18 to 45%, and if the addition amount of the resin modifier is less than 18%, results in the following including but not limited to: the resin is not thoroughly modified, and the mechanical property is influenced; if the resin modifier addition is above 45%, this results in a range including, but not limited to: the residual modifier is more, and the mechanical property of the resin is further influenced.
In some embodiments of the present invention, the second catalyst is present in the modified hydroxyl resin in an amount of 0.1 to 5% by mass, i.e., the second catalyst is present in an amount of 0.1% by mass or more and 5% by mass or less, and a typical, but non-limiting, amount of the second catalyst may be, for example, 0.1%, 0.2%, 0.3%, 0.4%, 0.5%, 0.7%, 1.0%, 1.2%, 1.5%, 1.8%, 2.0%, 2.5%, 2.8%, 3%, 3.5%, 4.5%, 4.8%, or 5% by mass.
Further, in the modified hydroxyl resin, the adding amount of the second catalyst is controlled within the range of 0.1-5%, and if the adding amount of the second catalyst is higher than 5%, the waste of raw materials is caused; if the second catalyst addition is less than 0.1%, this results in an amount that includes, but is not limited to: the reaction is carried out for a long time, even the reaction is not complete, resulting in poor resin performance.
In order to facilitate an understanding of the invention, the invention will now be further described with reference to the following specific examples.
Example 1
Preparation of modified hydroxy resin: 80g of polycarbonate diol (T-5651) and 40g of gamma-isocyanate triethoxy silane are mixed and added into a reaction bottle, the mixture is subjected to heat preservation reaction at the temperature of 40-50 ℃ for 2h, and then 0.2g of tetrabutyl titanate is added and subjected to heat preservation reaction at the temperature of 50-60 ℃ for 5h to obtain the modified hydroxyl resin Y1.
Example 2
Preparation of modified hydroxy resin: 70g of polycaprolactone triol (CAPA-3050) and 40g of gamma-isocyanate triethoxy silane are mixed and added into a reaction bottle, the heat preservation reaction is carried out for 2h at the temperature of 40-50 ℃, then 0.2g of dibutyltin dilaurate is added, the heat preservation reaction is carried out for 5h at the temperature of 50-60 ℃, and the modified hydroxyl resin Y is obtained2。
Example 3
Preparation of organic-inorganic hybrid resin: mixing 60g of silica sol, 5g of water and 0.5g of hydrochloric acid, stirring uniformly, dropwise adding 20g of methyltriethoxysilane and 15g of tetraethoxysilane, controlling the dropwise adding speed (2-3 drops per second), dropwise adding for not less than 30min, carrying out heat preservation reflux reaction for 2h, cooling to below 40 ℃, adding 30gY1And 40g of butyl acetate, then heating to 78 +/-2 ℃, evaporating 40g of solvent, and then cooling to room temperature to obtain the organic-inorganic hybrid resin Z1。
Example 4
Preparation of organic-inorganic hybrid resin: mixing 55g of silica sol, 10g of water and 0.5g of hydrochloric acid, stirring uniformly, dropwise adding 20g of dimethyldiethoxysilane and 20g of tetraethoxysilane, controlling the dropwise adding speed (2-3 drops per second), finishing dropwise adding for not less than 30min, then carrying out heat preservation reflux reaction for 2h, then cooling to below 40 ℃, adding 28gY1And 30g of isopropanol, then heating to 78 +/-2 ℃, evaporating 30g of solvent, and then cooling to room temperature to obtain the organic-inorganic hybrid resin Z2。
Example 5
Preparation of organic-inorganic hybrid resin: mixing 65g of silica sol, 10g of water and 0.5g of hydrochloric acid, uniformly stirring, dropwise adding 35g of dimethyldiethoxysilane and 20g of tetraethoxysilane, controlling the dropwise adding speed (2-3 drops per second), finishing dropwise adding for not less than 30min, then carrying out heat preservation reflux reaction for 2h, then cooling to below 40 ℃, adding 13gY1、18gY2And 35g of ethyl acetate, and then the temperature is raised to 78 +/-2 DEG CEvaporating 35g of solvent, and cooling to room temperature to obtain the organic-inorganic hybrid resin Z3。
Example 6
Preparing a fireproof coating: taking resin Y180g, adding 5g of BYK163, 2g of BYK358N, 40g of pentaerythritol, 40g of zinc borate and 20g of magnesium hydroxide, uniformly mixing and grinding until the fineness is less than or equal to 80um, then adding 8.5g of fumed silica, 6.5g of hollow glass microspheres and 30g of butyl acetate, uniformly stirring at a high speed to prepare a component A of the fireproof coating, and then mixing the component A with 36g of curing agent N-75 (product brand:
Figure BDA0002691336550000131
n-75, manufacturer: bayer) to obtain the fire-retardant coating.
The fireproof coating prepared in the embodiment is coated on the surface of a steel plate substrate for coating performance test, the thickness of the coating is 1.8mm, and the coating test method comprises the following steps: adhesion force: GB/T9286-1998; thermal conductivity: ASTM 1530-19; salt spray resistance: GJB 150.11; and (3) testing the fireproof performance: and (3) placing the prepared coating sample wafer above an alcohol blast lamp for ablation by 100mm, and observing the time required for carbonization of the sample wafer, namely the fire resistance limit.
The test results were as follows: the adhesive force (pull-open method) is 7.3 MPa; the thermal conductivity of the coating is 0.18W/(m multiplied by K); the 1.8mm coating has salt spray resistance for 3000h and has no abnormality; fireproof performance of the coating: 1.8mm thickness, fire limit 138 min.
Example 7
Preparing a fireproof coating: taking resin Y180g, adding 5g of BYK110, 2g of BYK358N, 40g of pentaerythritol, 20g of zinc borate and 40g of magnesium hydroxide, uniformly mixing and grinding until the fineness is less than or equal to 80um, then adding 15g of fumed silica, 20g of xylene and 20g of butyl acetate, uniformly stirring at a high speed to prepare a first component of the fireproof coating, and then mixing the first component with 16g of curing agent N-75 (product brand:
Figure BDA0002691336550000132
n-75, manufacturer: bayer) to obtain the fire-retardant coating.
The fireproof coating prepared in the embodiment is coated on the surface of a steel plate substrate to carry out coating performance test, the thickness of the coating is 1.8mm, and the coating test method is the same as that of the embodiment 6.
And (3) testing results: the adhesive force (pull-open method) is 7.3 MPa; the thermal conductivity of the coating is 0.18W/(m multiplied by K); the 1.8mm coating has salt spray resistance for 3000h and has no abnormality; fireproof performance of the coating: 1.8mm thickness, refractory limit 140 min.
Example 8
Preparing a fireproof coating: taking resin Y280g, adding 5g of BYK110, 40g of pentaerythritol, 20g of zinc borate and 20g of magnesium hydroxide, uniformly mixing and grinding until the fineness is less than or equal to 80um, then adding 10g of fumed silica and 5g of hollow glass beads, uniformly stirring at a high speed to prepare a first component of the fireproof coating, and then mixing the first component with 14g of a curing agent N-75 (product brand:
Figure BDA0002691336550000141
n-75, manufacturer: bayer) to obtain the fire-retardant coating.
The fireproof coating prepared in the embodiment is coated on the surface of a steel plate substrate to carry out coating performance test, the thickness of the coating is 1.8mm, and the coating test method is the same as that of the embodiment 6.
And (3) testing results: the adhesive force (pull-open method) is 7.5 MPa; the thermal conductivity of the coating is 0.19W/(m multiplied by K); the 1.5mm coating has salt spray resistance for 3000h and has no abnormality; fireproof performance of the coating: 1.5mm thickness, refractory limit 140 min.
Example 9
Preparing a fireproof coating: taking resin Y280g, adding 5g of BYK110, 40g of dipentaerythritol, 20g of melamine and 20g of magnesium hydroxide, uniformly mixing and grinding until the fineness is less than or equal to 80um, then adding 15g of fumed silica, uniformly stirring at a high speed, and preparing a first component of the fireproof coating, and then mixing the first component with 11g of a curing agent N-3390 (product brand:
Figure BDA0002691336550000142
n-3390, manufacturer: bayer) to obtain the fire-retardant coating.
The fireproof coating prepared in the embodiment is coated on the surface of a steel plate substrate to carry out coating performance test, the thickness of the coating is 1.8mm, and the coating test method is the same as that of the embodiment 6.
And (3) testing results: and (3) testing the performance of the coating: the adhesive force (pull-open method) is 7.6 MPa; the thermal conductivity of the coating is 0.19W/(m multiplied by K); the 1.8mm coating has salt spray resistance for 3000h and has no abnormality; fireproof performance of the coating: 1.8mm thickness, refractory limit 142 min.
Example 10
Preparing a fireproof coating: taking resin Y380g, adding 5g of BYK110, 40g of pentaerythritol, 20g of zinc borate and 20g of aluminum hydroxide, uniformly mixing and grinding until the fineness is less than or equal to 80um, then adding 10g of fumed silica and 5g of carbon fiber, uniformly stirring at a high speed to prepare a component A of the fireproof coating, and then mixing the component A with 12g of a curing agent N-3390 (product brand:
Figure BDA0002691336550000151
n-3390, manufacturer: bayer) to obtain the fire-retardant coating.
The fireproof coating prepared in the embodiment is coated on the surface of a steel plate substrate to carry out coating performance test, the thickness of the coating is 1.8mm, and the coating test method is the same as that of the embodiment 6.
And (3) testing results: the adhesive force (pull-open method) is 7.5 MPa; the thermal conductivity of the coating is 0.18W/(m multiplied by K); the 1.8mm coating has salt spray resistance for 3000h and has no abnormality; fireproof performance of the coating: 1.8mm thickness, fire limit 146 min.
Example 11
Preparing a fireproof coating: taking resin Y380g, adding 5g of BYK110, 40g of pentaerythritol, 20g of zinc borate and 30g of magnesium hydroxide, uniformly mixing and grinding until the fineness is less than or equal to 80um, then adding 5g of fumed silica, 5g of carbon fiber and 5g of hollow glass microsphere, uniformly stirring at a high speed to prepare a first component of the fireproof coating, and then mixing the first component with 12g of curing agent N-3390 to obtain the fireproof coating.
The fireproof coating prepared in the embodiment is coated on the surface of a steel plate substrate to carry out coating performance test, the thickness of the coating is 1.8mm, and the coating test method is the same as that of the embodiment 6.
And (3) testing results: the adhesive force (pull-open method) is 8.1 MPa; the thermal conductivity of the coating is 0.15W/(m multiplied by K); the 1.8mm coating has salt spray resistance for 3000h and has no abnormality; fireproof performance of the coating: 1.8mm thickness, refractory limit 145 min.
Example 12
Preparing a fireproof coating: taking resin Y380g, adding 5g of BYK358N, 40g of dipentaerythritol, 20g of zinc borate and 30g of magnesium hydroxide, uniformly mixing and grinding until the fineness is less than or equal to 80um, then adding 10g of fumed silica and 10g of hollow glass beads, uniformly stirring at a high speed to prepare a first component of the fireproof coating, and then mixing the first component with 13g of curing agent N-3390.
The fireproof coating prepared in the embodiment is coated on the surface of a steel plate substrate to carry out coating performance test, the thickness of the coating is 1.8mm, and the coating test method is the same as that of the embodiment 6.
And (3) testing results: the adhesive force (pull-open method) is 7.6 MPa; the thermal conductivity of the coating is 0.13W/(m multiplied by K); the 1.8mm coating has salt spray resistance for 3000h and has no abnormality; fireproof performance of the coating: 1.8mm thick, refractory limit 150 min.
The invention is not limited to the embodiments of the invention described. The technical scheme and the implementation mode of the invention are explained by applying specific examples in the invention, and the description of the above examples is only used for helping to understand the core idea of the invention. It should be noted that, for those skilled in the art, it is possible to make various improvements and modifications to the present invention without departing from the principle of the present invention, and those improvements and modifications also fall within the scope of the claims of the present invention.

Claims (10)

1. The ultrathin steel structure fireproof coating is characterized by comprising the following components in percentage by mass:
Figure FDA0002691336540000011
2. the ultrathin steel structure fireproof paint as claimed in claim 1, wherein the flame retardant filler comprises one or a combination of more than two of pentaerythritol, dipentaerythritol, melamine, zinc borate, magnesium hydroxide and aluminum hydroxide in any proportion.
3. The ultrathin fireproof paint for steel structures as claimed in claim 1, wherein the curing agent comprises one or more of hexamethylene diisocyanate trimer, isophorone diisocyanate, hexamethylene diisocyanate trimer, hexamethylene diisocyanate biuret, diphenylmethane diisocyanate and hydrogenated phenylmethane diisocyanate in any proportion.
4. The ultrathin fireproof coating for steel structures as claimed in claim 1, wherein the organic-inorganic hybrid resin comprises the following components in percentage by mass:
Figure FDA0002691336540000012
5. the ultrathin steel structure fireproof paint as claimed in claim 4, wherein the siloxane monomer comprises one or a combination of more than two of methyl triethoxysilane, methyl trimethoxysilane, dimethyl diethoxy silane, dimethyl dimethoxy silane, isopropyl triethoxysilane, isopropyl trimethoxysilane, n-octyl triethoxysilane, n-octyl trimethoxysilane and ethyl orthosilicate in any proportion.
6. The ultrathin steel structure fireproof coating of claim 4, wherein the sol comprises one or a combination of more than two of silica sol, aluminum sol, zirconium sol and titanium sol in any proportion.
7. The ultrathin steel structure fireproof paint as claimed in claim 4, wherein the first catalyst comprises one or a combination of more than two of hydrochloric acid, acetic acid, butyric acid, caproic acid, phosphoric acid and sulfuric acid in any proportion.
8. The ultrathin fireproof coating for steel structures as claimed in claim 4, wherein the modified hydroxyl resin comprises the following components in percentage by mass: 50-80% of hydroxyl resin; 18-45% of resin modifier; 0.1-5% of a second catalyst; wherein the hydroxyl resin comprises one or a combination of more than two of polyester dihydric alcohol, polyether dihydric alcohol, polycarbonate dihydric alcohol, polycaprolactone dihydric alcohol and polycaprolactone trihydric alcohol in any proportion; the resin modifier comprises one of gamma-isocyanate trimethoxy silane and gamma-isocyanate triethoxy silane; the second catalyst comprises one or a combination of more than two of tetrabutyl titanate, diethylenetriamine, trimethyl ammonium bromide, N-dimethylcyclohexane and dibutyltin dilaurate in any proportion.
9. A preparation method of an organic-inorganic hybrid resin is characterized by comprising the following steps:
mixing sol, water and a first catalyst uniformly according to a raw material formula of any one of claims 4 to 8, dropwise adding the siloxane monomer, controlling the dropping speed of 2 to 3 drops per second, then heating, preserving heat, refluxing for 2 to 2.5 hours, then cooling to below 40 ℃, adding the modified hydroxyl resin and the solvent, then heating to a sufficient temperature to remove the added equivalent amount of the solvent, and then cooling to room temperature to obtain the organic-inorganic hybrid resin;
the preparation method of the modified hydroxyl resin comprises the following steps: the raw material formula of claim 8, wherein the hydroxyl resin and the resin modifier are mixed and react at 40-50 ℃ for 2-2.5h under heat preservation, then the second catalyst is added, and the modified hydroxyl resin is obtained after 5-6h under heat preservation at 50-60 ℃.
10. A preparation method of the ultrathin steel structure fireproof coating is characterized by comprising the following steps: the formulation of any one of claims 1 to 8, wherein the auxiliary agent and the flame-retardant filler are added into the organic-inorganic hybrid resin, mixed uniformly, ground, added with the heat-insulating filler and the solvent, mixed uniformly, and mixed with the curing agent to obtain the ultrathin steel structure fireproof coating.
CN202010992853.3A 2020-09-21 2020-09-21 Ultrathin steel structure fireproof coating and preparation method thereof Pending CN112094585A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112940611A (en) * 2021-01-27 2021-06-11 浙江大学杭州国际科创中心 High-performance expansion type sandwich structure ultrathin steel structure fireproof and anticorrosive composite coating and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1587299A (en) * 2004-07-29 2005-03-02 复旦大学 Process for preparing organic-inorganic hybridized resin and its coating material
CN1974695A (en) * 2006-11-23 2007-06-06 复旦大学 Super thin no-halogen less-smoke fire proof organic-inorganic composite paint and its prepn process
CN102344726A (en) * 2010-08-03 2012-02-08 无锡市全发化工有限公司 Fire resistant coating for composite steel structure and preparation method thereof
CN109651578A (en) * 2018-12-12 2019-04-19 中昊北方涂料工业研究设计院有限公司 A kind of fire-retardant organic and inorganic resin of resistance to ablation and its preparation

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1587299A (en) * 2004-07-29 2005-03-02 复旦大学 Process for preparing organic-inorganic hybridized resin and its coating material
CN1974695A (en) * 2006-11-23 2007-06-06 复旦大学 Super thin no-halogen less-smoke fire proof organic-inorganic composite paint and its prepn process
CN102344726A (en) * 2010-08-03 2012-02-08 无锡市全发化工有限公司 Fire resistant coating for composite steel structure and preparation method thereof
CN109651578A (en) * 2018-12-12 2019-04-19 中昊北方涂料工业研究设计院有限公司 A kind of fire-retardant organic and inorganic resin of resistance to ablation and its preparation

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112940611A (en) * 2021-01-27 2021-06-11 浙江大学杭州国际科创中心 High-performance expansion type sandwich structure ultrathin steel structure fireproof and anticorrosive composite coating and preparation method thereof

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Application publication date: 20201218