CN111072090A - Desulfurization wastewater evaporation tower capable of maintaining constant flow field and method - Google Patents

Desulfurization wastewater evaporation tower capable of maintaining constant flow field and method Download PDF

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Publication number
CN111072090A
CN111072090A CN201911364183.4A CN201911364183A CN111072090A CN 111072090 A CN111072090 A CN 111072090A CN 201911364183 A CN201911364183 A CN 201911364183A CN 111072090 A CN111072090 A CN 111072090A
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China
Prior art keywords
flue gas
evaporation tower
waste water
desulfurization waste
flue
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CN201911364183.4A
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Inventor
陈彪
童小忠
祁志福
刘春红
王洁
张光学
陈雨帆
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Zhejiang Energy Group Research Institute Co Ltd
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Zhejiang Energy Group Research Institute Co Ltd
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Priority to CN201911364183.4A priority Critical patent/CN111072090A/en
Publication of CN111072090A publication Critical patent/CN111072090A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • C02F1/16Treatment of water, waste water, or sewage by heating by distillation or evaporation using waste heat from other processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/18Nature of the water, waste water, sewage or sludge to be treated from the purification of gaseous effluents

Abstract

The invention relates to a desulfurization wastewater evaporation tower capable of keeping a constant flow field and a method, comprising the following steps: the evaporation tower body and the recycling flue gas pipe; and the recycling flue gas pipe is respectively connected with the outlet flue of the evaporation tower and the inlet flue of the evaporation tower, and a recycling flue gas regulating valve and a variable-frequency high-temperature fan are arranged on the recycling flue gas pipe. The invention has the beneficial effects that: the invention is provided with the recirculation flue gas pipe, and leads part of the flue gas at the outlet of the evaporation tower back to the volute type air chamber again, so that the total amount of the flue gas entering the evaporation tower is maintained, and the flow field in the tower can be kept constant under the condition of any flow of the desulfurization waste water, thereby avoiding the problems of wall sticking of liquid drops or poor evaporation and the like caused by the change of the flow of the desulfurization waste water; the invention is provided with the recycled flue gas regulating valve, the air quantity testing device, the hot flue gas regulating valve and the temperature measuring device, and the flue gas quantity at the inlet and the outlet of the evaporation tower and the recycled flue gas quantity can be quantitatively controlled, so that the system can accurately control the operation parameters and reduce the energy consumption.

Description

Desulfurization wastewater evaporation tower capable of maintaining constant flow field and method
Technical Field
The invention relates to the technical field of desulfurization wastewater treatment, in particular to a desulfurization wastewater evaporation tower and a method capable of keeping a constant flow field.
Background
The thermal power generating set of China generally adopts the flue gas desulfurization technology of limestone-gypsum method to remove the sulfur dioxide pollution in the flue gas, however, when the system is in operation, various salinity, chloride ions, particulate matters and heavy metals can be continuously enriched in the desulfurization slurry, so that the water quality is deteriorated, and the desulfurization waste water needs to be discharged regularly. In addition, boiler circulating water, sewage, cooling water and chemical plant drainage in the power plant are usually gathered into the desulfurizing tower for centralized treatment, so that the desulfurization wastewater becomes the terminal point of the cascade utilization of the wastewater in the whole plant.
The traditional desulfurization wastewater treatment means is a 'triple-box' process, which comprises the steps of neutralization, precipitation, flocculation and the like, but can not remove chloride ions in water. The bypass flue evaporation treatment technology is characterized in that after a part of boiler economizers are led out, medium-temperature flue gas is used as a heat source, desulfurization waste water is evaporated in special equipment such as a rotary spray evaporation tower, the waste water is evaporated and gasified, and pollutants in the waste water are changed into solid fine particles and enter the flue gas. The smoke at the outlet of the rotary spray evaporation tower returns to the dust remover of the boiler again and is captured by the dust remover together with the fly ash. The method has the advantages of low investment cost, simple and reliable system, low requirement on initial water quality, low energy consumption and the like, and becomes a power plant desulfurization wastewater treatment technology with great development potential.
In the spray evaporation tower, a desulfurization waste water atomization device is generally arranged at the top, and is dried by hot flue gas. In order to avoid that the atomized desulfurization waste water is not sprayed to the inner wall surface and to ensure that liquid drops have proper residence time, a flow field in the spray drying tower needs to be carefully designed, and particularly, the rotational flow strength and the axial speed are reasonable and stable.
However, the output of the desulfurization waste water of the power plant is greatly changed due to the frequent fluctuation of the load of the boiler, so the treatment capacity of the desulfurization waste water evaporation tower is also not changed. Taking a typical 1000MW coal-fired unit in China as an example, when the limestone-gypsum method flue gas desulfurization technology is adopted for desulfurization, the wastewater yield is sometimes 3-5t/h, and sometimes 15-20 t/h. In actual operation, in order to avoid the reduction of the thermal efficiency of the boiler system caused by the extraction of too much hot flue gas, the temperature of the flue gas at the outlet of the desulfurization waste water evaporation tower is always controlled to be a constant value, such as about 150 ℃. Therefore, when the desulfurization waste water evaporation tower works under high load, the inlet hot flue gas flow is large; when the low-load work is carried out, the flow of hot flue gas is small. The flue gas flow of the desulfurization waste water evaporation tower can greatly influence the flow field in the tower, when the flow is large, the rotational flow strength and the axial speed are high, and vice versa. In this case, the large change of the flow field in the column is very disadvantageous in ensuring the normal evaporation of the desulfurization waste water and maintaining a reasonable droplet trajectory.
In view of the above, it is desirable to design a desulfurization waste water evaporation tower and a method capable of maintaining a constant flow field.
Disclosure of Invention
The invention aims to overcome the defects in the prior art and provides a desulfurization wastewater evaporation tower capable of keeping a constant flow field and a method for ensuring the evaporation of desulfurization wastewater by adopting the device.
The desulfurization waste water evaporation tower capable of keeping a constant flow field comprises an evaporation tower body and a recirculating flue gas pipe; the recycling flue gas pipe is respectively connected with the outlet flue of the evaporation tower and the inlet flue of the evaporation tower, and a recycling flue gas regulating valve and a variable-frequency high-temperature fan are arranged on the recycling flue gas pipe; a volute type air chamber and a desulfurization wastewater atomizer are arranged at the upper part of the evaporation tower body, and an annular flue gas flow channel is arranged at the lower part of the volute type air chamber; the inlet flue of the evaporation tower is connected with the inlet of the volute type air chamber; an air quantity testing device and a hot flue gas regulating valve are installed on an inlet flue of the evaporation tower, and a temperature measuring device is installed on an outlet flue of the evaporation tower.
Preferably, the method comprises the following steps: the ratio of the diameter to the height of the evaporation tower body is 0.5-0.9.
Preferably, the method comprises the following steps: the atomization angle of the desulfurization waste water atomizer is 60-120 degrees, and the atomization particle size is 50-200 mu m.
Preferably, the method comprises the following steps: the desulfurization waste water atomizer is connected with a desulfurization waste water pipeline.
The wastewater treatment method of the desulfurization wastewater evaporation tower capable of keeping a constant flow field comprises the following steps:
1) introducing desulfurization waste water into a desulfurization waste water atomizer, atomizing into liquid mist, introducing hot flue gas from a volute type air chamber, allowing the hot flue gas to enter an evaporation tower body after passing through an annular flue gas flow channel, evaporating the atomized desulfurization waste water, converting pollutants in the desulfurization waste water into a solid phase, allowing the solid phase to enter the flue gas, and allowing the solid phase to leave the evaporation tower;
2) a recirculating flue gas pipe connecting the outlet flue of the evaporation tower and the inlet flue of the evaporation tower leads a part of the outlet flue gas of the evaporation tower back to the volute type air chamber again;
3) adjusting the opening of a recirculated flue gas adjusting valve and the output of a variable-frequency high-temperature fan through an air quantity testing device of an inlet flue of the evaporation tower; adjusting a hot flue gas adjusting valve through a temperature measuring device of an outlet flue of the evaporation tower; so that the smoke quantity entering the evaporation tower is always kept constant.
Preferably, the method comprises the following steps: in the step 1), the flow velocity of the flue gas in the volute type air chamber is 3-8m/s, and the flow velocity of the flue gas in the flue gas flow channel is 20-35 m/s.
The invention has the beneficial effects that:
1. the invention is provided with the recirculation flue gas pipe, and leads part of the flue gas at the outlet of the evaporation tower back to the volute type air chamber again, so that the total amount of the flue gas entering the evaporation tower is maintained, and the flow field in the tower can be kept constant under the condition of any flow of the desulfurization waste water, thereby avoiding the problems of liquid drops sticking to the wall or poor evaporation and the like caused by the change of the flow of the desulfurization waste water.
2. The invention is provided with the recycled flue gas regulating valve, the air quantity testing device, the hot flue gas regulating valve and the temperature measuring device, and the flue gas quantity at the inlet and the outlet of the evaporation tower and the recycled flue gas quantity can be quantitatively controlled, so that the system can accurately control the operation parameters and reduce the energy consumption.
Drawings
FIG. 1 is a schematic structural view of a desulfurization waste water evaporation tower capable of maintaining a constant flow field according to the present invention;
fig. 2 is a graph showing the results of the computational fluid dynamics simulation.
Description of reference numerals: 1-a desulphurisation waste water pipeline; 2-volute type air chamber; 3-an evaporation tower body; 4-a flue gas flow channel; 5-a desulfurized wastewater atomizer; 6-volute type air chamber inlet; 7-an evaporation tower outlet flue; 8-a recirculating flue gas duct; 9-recirculated flue gas regulating valve; 10-variable frequency high temperature fan; 11-an evaporation tower inlet flue; 12-an air volume testing device; 13-hot flue gas regulating valve; 14-temperature measuring device.
Detailed Description
The present invention will be further described with reference to the following examples. The following examples are set forth merely to aid in the understanding of the invention. It should be noted that, for those skilled in the art, it is possible to make various improvements and modifications to the present invention without departing from the principle of the present invention, and those improvements and modifications also fall within the scope of the claims of the present invention.
The desulfurization waste water evaporation tower capable of keeping a constant flow field leads part of the flue gas at the outlet of the evaporation tower back to the volute type air chamber through the recirculation flue gas pipe, so that the flow field in the evaporation tower is kept constant.
As shown in fig. 1, the desulfurization waste water evaporation tower capable of maintaining a constant flow field comprises an evaporation tower body 3 and a recirculation flue gas pipe 8, wherein the recirculation flue gas pipe 8 is respectively connected with an evaporation tower outlet flue 7 and an evaporation tower inlet flue 11, and the recirculation flue gas pipe 8 is provided with a recirculation flue gas regulating valve 9 and a variable-frequency high-temperature fan 10; a volute type air chamber 2 and a desulfurization waste water atomizer 5 are arranged at the upper part of the evaporation tower body 3, and an annular flue gas flow channel 4 is arranged at the lower part of the volute type air chamber 2; an inlet flue 11 of the evaporation tower is connected with a volute type air chamber inlet 6; an air quantity testing device 12 and a hot flue gas regulating valve 13 are arranged on an inlet flue 11 of the evaporation tower, and a temperature measuring device 14 is arranged on an outlet flue 7 of the evaporation tower.
The ratio of the diameter to the height of the evaporation tower body 3 is 0.5-0.9.
The flue gas flow velocity in the volute type air chamber 2 is designed according to 3-8 m/s.
The flue gas flow velocity in the flue gas flow channel 4 is designed according to 20-35 m/s.
The atomization angle of the desulfurization waste water atomizer 5 is 60-120 degrees, and the atomization particle size is 50-200 μm.
The desulfurization waste water atomizer 5 is connected with the desulfurization waste water pipeline 1.
The wastewater treatment method of the desulfurization wastewater evaporation tower capable of keeping a constant flow field comprises the following steps: the desulfurization waste water is introduced into a desulfurization waste water atomizer 5 and atomized into liquid mist with extremely small particle size, hot flue gas is introduced from a volute type air chamber 2, enters an evaporation tower body 3 after passing through an annular flue gas flow channel 4, the atomized desulfurization waste water is evaporated, and pollutants in the desulfurization waste water are converted into solid phase to enter the flue gas and leave the evaporation tower. In order to keep the flow field in the evaporation tower constant under the condition of any flow of the desulfurization waste water, a recirculating flue gas pipe 8 is arranged to connect an outlet flue 7 of the evaporation tower and an inlet flue 11 of the evaporation tower, and a part of the outlet flue gas of the evaporation tower is led back to the volute type air chamber 2 again. The opening degree of a recirculated flue gas regulating valve 9 and the output force of a variable-frequency high-temperature fan 10 are regulated through an air quantity testing device 12 of an inlet flue 11 of the evaporation tower; the hot flue gas regulating valve 13 is regulated by a temperature measuring device 14 of the evaporation tower outlet flue 7. When the evaporation tower operates, the amount of flue gas entering the evaporation tower is always kept constant, and the flow field in the tower is kept constant, so that the problems of wall sticking of liquid drops or poor evaporation and the like caused by the change of the flow of the desulfurization waste water are solved.
Fig. 2 is a diagram of a computational fluid dynamics simulation result, and a simulation object is a desulfurization wastewater evaporation tower corresponding to a 1000MW boiler unit, wherein: (b) when the flow of the desulfurization waste water is operated according to a design value, the liquid drop track is appropriate, the liquid drop is not sprayed to the wall surface, and the distribution is reasonable; (a) when the flow of the desulfurization waste water is reduced to 50% of a design value, if the flue gas amount is correspondingly reduced to 50% of the original amount, the flow velocity of the flue gas is reduced, liquid drops are transversely spread too much, and the risk of wall sticking exists; (c) when the flow of the desulfurization waste water is increased to 150% of a design value, the flue gas volume is large, liquid drops are concentrated in the middle of the evaporation tower, the effective volume of the evaporation tower cannot be fully utilized, and the method is not reasonable.

Claims (6)

1. The utility model provides a desulfurization waste water evaporation tower that can keep invariable flow field which characterized in that: comprises an evaporation tower body (3) and a recirculation flue gas pipe (8); a recirculating flue gas pipe (8) is respectively connected with an outlet flue (7) of the evaporation tower and an inlet flue (11) of the evaporation tower, and a recirculating flue gas regulating valve (9) and a variable-frequency high-temperature fan (10) are arranged on the recirculating flue gas pipe (8); a volute type air chamber (2) and a desulfurization wastewater atomizer (5) are arranged at the upper part of the evaporation tower body (3), and an annular flue gas flow channel (4) is arranged at the lower part of the volute type air chamber (2); an inlet flue (11) of the evaporation tower is connected with an inlet (6) of the volute type air chamber; an air volume testing device (12) and a hot flue gas regulating valve (13) are arranged on an inlet flue (11) of the evaporation tower, and a temperature measuring device (14) is arranged on an outlet flue (7) of the evaporation tower.
2. The desulfurization waste water evaporation tower capable of maintaining a constant flow field according to claim 1, wherein: the ratio of the diameter to the height of the evaporation tower body (3) is 0.5-0.9.
3. The desulfurization waste water evaporation tower capable of maintaining a constant flow field according to claim 1, wherein: the atomization angle of the desulfurization waste water atomizer (5) is 60-120 degrees, and the atomization particle size is 50-200 mu m.
4. The desulfurization waste water evaporation tower capable of maintaining a constant flow field according to claim 1, wherein: the desulfurization waste water atomizer (5) is connected with the desulfurization waste water pipeline (1).
5. A wastewater treatment method of a desulfurization wastewater evaporation tower capable of maintaining a constant flow field according to claim 1, comprising the steps of:
1) introducing desulfurization waste water into a desulfurization waste water atomizer (5) to be atomized into liquid mist, introducing hot flue gas from a volute type air chamber (2), passing through an annular flue gas flow channel (4), then entering an evaporation tower body (3), evaporating the atomized desulfurization waste water, converting pollutants in the desulfurization waste water into a solid phase, entering the flue gas, and leaving the evaporation tower;
2) a recirculation flue gas pipe (8) connecting the evaporation tower outlet flue (7) and the evaporation tower inlet flue (11) leads a part of the evaporation tower outlet flue gas back to the volute type air chamber (2);
3) the opening degree of a recirculated flue gas adjusting valve (9) and the output of a variable-frequency high-temperature fan (10) are adjusted through an air quantity testing device (12) of an inlet flue (11) of the evaporation tower; a hot flue gas regulating valve (13) is regulated through a temperature measuring device (14) of an evaporation tower outlet flue (7); so that the smoke quantity entering the evaporation tower is always kept constant.
6. The wastewater treatment method of a desulfurization wastewater evaporation tower capable of maintaining a constant flow field according to claim 5, wherein: in the step 1), the flow velocity of the flue gas in the volute type air chamber (2) is 3-8m/s, and the flow velocity of the flue gas in the flue gas flow channel (4) is 20-35 m/s.
CN201911364183.4A 2019-12-26 2019-12-26 Desulfurization wastewater evaporation tower capable of maintaining constant flow field and method Pending CN111072090A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113443674A (en) * 2021-07-07 2021-09-28 南方电网电力科技股份有限公司 Spray drying tower
CN114560519A (en) * 2022-03-02 2022-05-31 北京节度科技有限公司 Coal fired power plant flue gas desulfurization waste water evaporation tower

Citations (2)

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Publication number Priority date Publication date Assignee Title
CN101703884A (en) * 2009-12-18 2010-05-12 哈尔滨工业大学 Wet desulfurization tower based flue gas desulphurization method capable of enhancing adaptability to low load
CN211770395U (en) * 2019-12-26 2020-10-27 浙江浙能技术研究院有限公司 Desulfurization waste water evaporation tower capable of keeping constant flow field

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101703884A (en) * 2009-12-18 2010-05-12 哈尔滨工业大学 Wet desulfurization tower based flue gas desulphurization method capable of enhancing adaptability to low load
CN211770395U (en) * 2019-12-26 2020-10-27 浙江浙能技术研究院有限公司 Desulfurization waste water evaporation tower capable of keeping constant flow field

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王晓焙等: "330 MW机组脱硫废水旁路烟道喷雾干燥技术数值模拟与应用示范", 热力发电, 30 June 2019 (2019-06-30), pages 97 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113443674A (en) * 2021-07-07 2021-09-28 南方电网电力科技股份有限公司 Spray drying tower
CN114560519A (en) * 2022-03-02 2022-05-31 北京节度科技有限公司 Coal fired power plant flue gas desulfurization waste water evaporation tower
CN114560519B (en) * 2022-03-02 2022-11-29 北京节度科技有限公司 Coal fired power plant flue gas desulfurization waste water evaporation tower

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