CN111043909B - A kind of Ti-Al intermetallic compound micro-laminated composite armor and preparation method thereof - Google Patents

A kind of Ti-Al intermetallic compound micro-laminated composite armor and preparation method thereof Download PDF

Info

Publication number
CN111043909B
CN111043909B CN201911088372.3A CN201911088372A CN111043909B CN 111043909 B CN111043909 B CN 111043909B CN 201911088372 A CN201911088372 A CN 201911088372A CN 111043909 B CN111043909 B CN 111043909B
Authority
CN
China
Prior art keywords
foil
laminated composite
armor
alti
intermetallic compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201911088372.3A
Other languages
Chinese (zh)
Other versions
CN111043909A (en
Inventor
原梅妮
马健
韩方洲
郑丽荣
张国庆
王凯
魏泽源
姚宇航
李立州
姚磊斌
辛乐
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
North University of China
Original Assignee
North University of China
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by North University of China filed Critical North University of China
Priority to CN201911088372.3A priority Critical patent/CN111043909B/en
Publication of CN111043909A publication Critical patent/CN111043909A/en
Application granted granted Critical
Publication of CN111043909B publication Critical patent/CN111043909B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F41WEAPONS
    • F41HARMOUR; ARMOURED TURRETS; ARMOURED OR ARMED VEHICLES; MEANS OF ATTACK OR DEFENCE, e.g. CAMOUFLAGE, IN GENERAL
    • F41H5/00Armour; Armour plates
    • F41H5/02Plate construction
    • F41H5/04Plate construction composed of more than one layer
    • F41H5/0442Layered armour containing metal

Landscapes

  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Laminated Bodies (AREA)
  • Pressure Welding/Diffusion-Bonding (AREA)

Abstract

本发明属装甲防护技术领域,为提高钛铝金属间化合物叠层复合装甲的抗侵彻性能,提供一种Ti‑Al金属间化合物微叠层复合装甲及其制备方法。由Ti‑AlTi和Ti‑Al3Ti‑Al叠层复合材料组成的Ti‑Al金属间化合物微叠层复合装甲,其中:Ti‑AlTi叠层复合材料作为装甲前板,Ti‑Al3Ti‑Al叠层复合材料作为装甲后板,装甲前板与装甲后板用扩散焊的方式连接;装甲前板与装甲后板的厚度比为3:1‑4:1。综合Ti‑AlTi叠层复合材料高硬度、高刚度以及良好的迎弹面抗破片侵彻能力和Ti‑Al3Ti‑Al叠层复合材料高韧性,高吸能性的优点,对破片冲击有着优异的缓冲抑制能力,具有优良的抗侵彻性能。

Figure 201911088372

The invention belongs to the technical field of armor protection, and provides a Ti-Al intermetallic compound micro-layered composite armor and a preparation method thereof in order to improve the penetration resistance of the titanium-aluminum intermetallic compound laminated composite armor. Ti-Al intermetallic compound micro-laminate composite armor composed of Ti-AlTi and Ti-Al 3 Ti-Al laminated composite materials, wherein: Ti-AlTi laminated composite material is used as armor front plate, Ti-Al 3 Ti-Al The Al laminated composite material is used as the armored rear plate, and the armored front plate and the armored rear plate are connected by diffusion welding; the thickness ratio of the armored front plate and the armored rear plate is 3:1‑4:1. Combining the advantages of high hardness, high stiffness and good resistance to fragment penetration of the Ti-AlTi laminated composite material and high toughness and high energy absorption of Ti-Al 3 Ti-Al laminated composite material, it has a good impact on fragmentation. Excellent buffer inhibition ability, with excellent anti-penetration performance.

Figure 201911088372

Description

Ti-Al intermetallic compound micro-laminated composite armor and preparation method thereof
Technical Field
The invention belongs to the technical field of armor protection, and particularly relates to a Ti-Al intermetallic compound micro-laminated composite armor and a preparation method thereof.
Background
With the rapid development of science and technology, the threat of personnel and equipment on the battlefield is larger and larger, the requirement on the performance of armor protection materials is higher and higher, and the armor materials are developing towards the directions of high hardness, high strength, high toughness and low density at present. Ti-Al3The Ti laminated composite material integrates the ductile metal Ti and the brittle intermetallic compound Al3The Ti has the advantages of excellent performances of low density, high modulus and high fracture toughness, and has great application prospect in the field of armor protection. It is worth noting that: due to Al3Greater difference in thermal expansion coefficient between Ti and Ti, Ti-Al3During the process of cooling the Ti laminated composite material from the preparation temperature to the room temperature, large thermal residual stress is inevitably generated. The residual stress can in turn lead to Ti-Al3A great number of tunnel cracks are generated inside the Ti laminated composite material, and the mechanical property of the Ti laminated composite material is further deteriorated. In addition, Ti-Al is affected by the Cokendall effect3Defects such as holes, peeling cracks and the like are easy to generate in the preparation process of the Ti laminated composite material. Preparation of Ti-Al by endothermic semi-solid reaction3The Ti-Al composite material can completely avoid Ti-Al3Tunnel crack, peeling crack, hole and other defects in the Ti laminated composite material. In addition, the Ti-AlTi laminated composite material is prepared by adopting high-temperature solid-liquid reaction, and the defects of cracks, cavities and the like can be avoided by applying larger pressure at the later stage of the reaction.
Carrying out Ti-Al3In ballistic penetration experiments of Ti-Al laminated composite armor, it was found that when the initial velocity of the body was near or above that of Ti-Al3When the ballistic performance of the Ti-Al laminated composite material is limited, the damage form of the back surface of the target plate is petal-shaped cracking, which shows that the target plate absorbs huge energy in the process of resisting penetration of the shot, as shown in figure 1. However, the diameter of the target plate front surface crater is the same as that of the shot and plastic deformation occurs, which indicates that Ti-Al3The hardness of the Ti-Al laminated composite material is lower than that of the shot.
In ballistic penetration experiments of Ti-AlTi laminated composite armor, ceramic cones appeared on the back of the target plate when the initial velocity of the projectile was near or above the ballistic limit of the Ti-AlTi laminated composite, as shown in fig. 2. The composite material is a brittle failure mode, which shows that the Ti-AlTi laminated composite material has higher hardness and better fragment penetration resistance on the bullet-facing surface, and plays a larger role in buffering and inhibiting the fragment impact kinetic energy.
Ti-Al3The Ti-Al laminated composite armor has lower hardness and rigidity and poor fragment penetration resistance on the bullet-facing surface, but petal-type cracking on the back surface of the target plate shows that the armor has the characteristic of high energy absorption. The Ti-AlTi laminated composite armor has high hardness and rigidity, good fragment penetration resistance of the bullet-facing surface and large buffer inhibition effect on fragment impact kinetic energy.
Disclosure of Invention
The invention provides a Ti-Al intermetallic compound micro-laminated composite armor and a preparation method thereof, aiming at improving the penetration resistance of the titanium-aluminum intermetallic compound laminated composite armor.
The invention is realized by adopting the following technical scheme: the Ti-Al intermetallic compound micro-laminated composite armor is prepared from Ti-AlTi and Ti-Al3Ti-Al intermetallic compound micro-laminated composite armor consisting of Ti-Al laminated composite material, wherein: Ti-AlTi laminated composite material as front plate of armour, Ti-Al3The Ti-Al laminated composite material is used as an armor rear plate, and the armor front plate and the armor rear plate are connected in a diffusion welding mode; the thickness ratio of the front plate to the rear plate is 3:1-4: 1.
The method for preparing the Ti-Al intermetallic compound micro-laminated composite armor comprises the steps of preparing Ti-AlTi and Ti-Al by a vacuum hot-pressing sintering method3Ti-Al two laminated composite materials, and then adding Ti-AlTi and Ti-Al3And welding the Ti-Al laminated composite materials together in a diffusion welding mode to obtain the Ti-Al intermetallic compound micro-laminated composite armor.
The specific preparation method of the Ti-AlTi laminated composite material comprises the following steps:
(1) acid-base cleaning TC4Al foil: mixing TC4Cutting the foil and the Al foil into the same size; cutting TC4Treating the foil in acid solution prepared from HF and water at a volume ratio of 1:20, treating the cut Al foil in 5% NaOH solution for 2min to remove surface oxygenA compound; washing the two reacted foils with clear water; ultrasonically cleaning the two foils for 5min by using alcohol, and finally drying the two foils for later use;
(2) laminating and sheathing: TC to be prepared4Foil, Al foil according to TC4-Al-TC4The lamination thickness is 7-10 mm, and the outermost layer is TC4Layer, using TC of 20 μm thickness for the laminated sample4Packaging the foil to obtain a packaging body;
(3) vacuum hot-pressing sintering: placing the obtained packaging body in a graphite mold, and carrying out vacuum hot-pressing sintering according to the following process to obtain the Ti-AlTi laminated composite material;
A. applying 3-5MPa pressure to the obtained packaging body, raising the sintering temperature to 580-610 ℃ at the speed of 20 ℃/min, and then preserving heat for 200 min, wherein the pressure during the heat preservation is 3-5 MPa;
B. unloading the loaded pressure, raising the sintering temperature to 1300 ℃ at the speed of 20 ℃/min, preserving the heat for 150 min at the temperature of 1100-;
C. reducing the sintering temperature to 610 ℃ at the rate of 10 ℃/min, and preserving the heat for 150 min at the temperature of 580-;
D. cooling along with the furnace, wherein the pressure is 2-3 MPa during cooling, and demolding to prepare the Ti-AlTi laminated composite material.
The Ti-Al3The specific preparation method of the Ti-Al laminated composite material comprises the following steps:
(1) acid-base cleaning TC4Al foil: mixing TC4Cutting the foil and the Al foil into the same size; cutting TC4Placing the foil into an acid solution prepared from HF and water at a volume ratio of 1:20 for treatment, and placing the cut Al foil into a 5% NaOH solution for treatment, wherein the reaction time of the two is 2min, so as to remove surface oxides of the Al foil; washing the two reacted foils with clear water; ultrasonically cleaning the two foils for 5min by using alcohol, and finally drying the two foils for later use;
(2) laminating and sheathing: TC to be prepared4Foil, Al foil according to TC4-Al-TC4In a sequence of layers, stacksThe thickness of the layer is 5-7 mm, and the outermost layer is ensured to be TC4Layer, using TC of 20 μm thickness for the laminated sample4Packaging the foil to obtain a package body;
(3) vacuum hot-pressing sintering: placing the obtained packaging body in a graphite mold, and carrying out vacuum hot-pressing sintering according to the following process to obtain the Ti-Al3Ti-Al laminated composite material:
a. applying 3-5MPa pressure to the obtained packaging body, raising the sintering temperature to 610 ℃ at the speed of 20 ℃/min, and preserving the temperature for 60-100min, wherein the pressure during the heat preservation is 3-5 MPa;
b. raising the sintering temperature to 640 ℃ at the speed of 5 ℃/min, and preserving the heat for 400min, wherein the pressure during the heat preservation is 2-3 Mpa;
c. reducing the sintering temperature to 570 ℃ at the speed of 5 ℃/min, and preserving the heat for 180min, wherein the pressure during the temperature reduction and preservation is 2-3 MPa;
d. cooling along with the furnace, the pressure is 2-3 MPa during cooling, and demoulding to prepare the Ti-Al3Ti-Al laminated composite material.
The specific preparation method of the Ti-Al intermetallic compound micro-laminated composite armor comprises the following steps:
(1) mixing the prepared Ti-AlTi and Ti-Al3Polishing the surface layer of the Ti-Al laminated composite material by using sand paper until fresh TC is exposed4Surface, standby;
(2) cutting the aluminum foil into the same size, and putting the cut Al foil into a 5% NaOH solution for treatment, wherein the reaction time is 2min, so as to remove the surface oxide of the aluminum foil; washing the reacted Al foil with clear water; ultrasonically cleaning the Al foil for 5min by using alcohol, and finally drying the Al foil for later use;
(3) placing the treated Al foil on the prepared Ti-AlTi and Ti-Al3The Ti-Al laminated composite material is internally provided with TC with the thickness of 20 mu m4The foil encapsulates the whole;
(4) placing the packaging body in a graphite mold, and performing diffusion welding connection in a vacuum hot-pressing sintering furnace according to the following process:
Figure DEST_PATH_IMAGE001
applying 4-6 MPa pressure to the obtained packaging body, raising the sintering temperature to 660 ℃ at the speed of 20 ℃/min, and then preserving heat for 20min, wherein the pressure during the heat preservation is 4-6 MPa;
Figure 118237DEST_PATH_IMAGE002
cooling along with the furnace, wherein the pressure is 1-2 MPa during cooling, and demolding to prepare the Ti-Al intermetallic compound micro-laminated composite armor.
The thickness of the Al foil is 0.1-0.2 mm; the thickness ratio of the Al foil to the TC4 foil is 1:3-2: 3. The TC4The foil, Al foil and aluminum foil 0.2mm thick were cut out to 100X 100 mm.
The invention adopts a new structure mode and consists of a front plate and a rear plate, wherein the front plate is made of Ti-AlTi laminated composite material with high hardness, and the rear plate is made of Ti-Al laminated composite material with high toughness3The front plate and the rear plate of the Ti-Al laminated composite material are connected by adopting a diffusion welding method. The composite armor has the advantages of fully utilizing the performance advantages of different materials and greatly improving the penetration resistance of the composite armor. The front plate of the composite armor is made of a low-density high-hardness Ti-AlTi laminated composite material, the anti-fragment penetration capability of the bullet-facing surface of the front plate is good, and the front plate plays a large role in buffering and inhibiting fragment impact kinetic energy; from low-density high-toughness Ti-Al3The Ti-Al laminated composite material is used as a back plate of the composite armor, so that the impact kinetic energy of fragments is fully absorbed, and the penetration resistance of the composite armor is improved. In addition, materials of all layers are metallurgically bonded, the interface bonding strength is high, and the integrity of the composite armor structure can be ensured when the composite armor is impacted by a projectile.
The front plate of the composite armor is a Ti-AlTi laminated composite material, and the rear plate is Ti-Al3The Ti-Al laminated composite material can effectively disperse the impact force of the projectile when the composite armor front plate is impacted by the projectile, resist the penetration of the projectile, effectively absorb the impact force transmitted by the front plate in the penetration process of the projectile by the rear plate, maintain the integrity of the composite armor structure and effectively improve the penetration resistance of the laminated composite armor.
Drawings
FIG. 1 shows Ti-Al3Ti-Al laminated composite materialThe trajectory of the target plate is penetrated, and the back of the target plate is failed;
FIG. 2 is a schematic diagram of ballistic penetration of a Ti-AlTi laminated composite target plate and target plate backside failure.
Detailed Description
In order to further clarify the technical solutions and effects of the present invention, the present invention is further described with reference to the following specific examples.
Example 1: the Ti-Al intermetallic compound micro-laminated composite armor is prepared from Ti-AlTi and Ti-Al3Ti-Al intermetallic compound micro-laminated composite armor consisting of Ti-Al laminated composite material, wherein: Ti-AlTi laminated composite material as front plate of armour, Ti-Al3The Ti-Al laminated composite material is used as an armor rear plate, and the armor front plate and the armor rear plate are connected in a diffusion welding mode; the thickness ratio of the front plate to the rear plate is 3: 1.
The specific preparation method of the Ti-AlTi laminated composite material comprises the following steps:
(1) acid-base cleaning TC4Al foil: mixing 0.15mm thick TC4Cutting foil and 0.1mm thick Al foil according to 100 × 100mm size; cutting TC4Placing the foil into an acid solution prepared from HF and water at a volume ratio of 1:20 for treatment, and placing the cut Al foil into a 5% NaOH solution for treatment, wherein the reaction time of the two is 2min, so as to remove surface oxides of the Al foil; washing the two reacted foils with clear water; ultrasonically cleaning the two foils with alcohol for 5min, and drying the two foils for use
(2) Laminating and sheathing: TC to be prepared4Foil, Al foil according to TC4-Al-TC4The laminated layer number is 65, and the outermost layer is ensured to be TC4Layer, using TC of 20 μm thickness for the laminated sample4And (7) packaging the foil.
(3) Vacuum hot-pressing sintering: placing the obtained packaging body in a graphite mold, and carrying out vacuum hot-pressing sintering according to the following process to obtain the Ti-AlTi laminated composite material:
A. applying 3.8 MPa pressure to the obtained packaging body, raising the sintering temperature to 600 ℃ at the speed of 20 ℃/min, and then preserving heat for 180min, wherein the pressure during the heat preservation is 3.8 MPa;
B. unloading the loaded pressure, increasing the sintering temperature to 1100 ℃ at the speed of 20 ℃/min, preserving the temperature for 120min, not applying the pressure in the early stage of heat preservation, and applying the pressure of 2Mpa in the later 30 min;
C. reducing the sintering temperature to 600 ℃ at the speed of 10 ℃/min, and preserving the temperature for 120min, wherein the pressure during the temperature reduction and preservation is 2 MPa;
D. cooling along with the furnace, wherein the pressure is 2MPa during cooling, and demolding to prepare the Ti-AlTi laminated composite material.
Ti-Al3The specific preparation method of the Ti-Al laminated composite material comprises the following steps:
(1) acid-base cleaning TC4Al foil: mixing 0.15mm thick TC4Cutting foil and 0.1mm thick Al foil according to 100 × 100mm size; cutting TC4Placing the foil into an acid solution prepared from HF and water at a volume ratio of 1:20 for treatment, and placing the cut Al foil into a 5% NaOH solution for treatment, wherein the reaction time of the two is 2min, so as to remove surface oxides of the Al foil; washing the two reacted foils with clear water; and ultrasonically cleaning the two foils for 5min by using alcohol, and finally drying the two foils for later use.
(2) Laminating and sheathing: TC to be prepared4Foil, Al foil according to TC4-Al-TC4The laminated layer number is 45, and the outermost layer is ensured to be TC4Layer, using TC of 20 μm thickness for the laminated sample4And (7) packaging the foil.
(3) Vacuum hot-pressing sintering: placing the obtained packaging body in a graphite mold, and carrying out vacuum hot-pressing sintering according to the following process to obtain the Ti-Al3Ti-Al laminated composite material:
A. applying 3.8 MPa pressure to the obtained packaging body, raising the sintering temperature to 600 ℃ at the speed of 20 ℃/min, and then preserving heat for 60 min, wherein the pressure during the heat preservation is 3.8 MPa;
B. raising the sintering temperature to 640 ℃ at the speed of 5 ℃/min, and preserving the heat for 400min, wherein the pressure is 3Mpa during the heat preservation period; reducing the sintering temperature to 570 ℃ at the speed of 5 ℃/min, and preserving the temperature for 120min, wherein the pressure during the temperature reduction and preservation is 2 MPa;
C. cooling along with the furnace, the pressure during cooling is 2MPa, and demoulding to prepare the Ti-Al3Ti-Al laminated composite material.
Diffusion welding Ti-AlTi and Ti-Al3Ti-Al laminated composite material:
(1) mixing the prepared Ti-AlTi and Ti-Al3Polishing the surface layer of the Ti-Al laminated composite material by using sand paper until the surface of fresh TC4 is exposed for later use;
(2) cutting 0.2mm thick aluminum foil according to 100 × 100mm size, and treating the cut Al foil in 5% NaOH solution for 2min to remove surface oxide; washing the reacted Al foil with clear water; ultrasonically cleaning the Al foil for 5min by using alcohol, and finally drying the Al foil for later use;
(3) placing the treated Al foil on the prepared Ti-AlTi and Ti-Al3The Ti-Al laminated composite material is internally provided with TC with the thickness of 20 mu m4The foil encapsulates the whole;
(4) placing the packaging body in a graphite mold, and performing diffusion welding connection in a vacuum hot-pressing sintering furnace according to the following process:
a. applying 6 MPa pressure to the obtained packaging body, raising the sintering temperature to 660 ℃ at the speed of 20 ℃/min, and then preserving heat for 20min, wherein the pressure during the heat preservation is 6 MPa;
b. cooling along with the furnace, wherein the pressure is 2MPa during cooling, and demoulding to prepare the intermetallic compound composite armor with the new structure.
Example 2: the first difference between the present embodiment and the specific embodiment is: TC (tungsten carbide)4The thickness of the foil was 0.3mm, the thickness of the Al foil was 0.2mm, and the other steps and parameters were the same as in the first embodiment.
Example 3: the first difference between the present embodiment and the specific embodiment is: the maximum temperature for preparing the Ti-AlTi laminated composite material is 1300 ℃, and other steps and parameters are the same as those of the first embodiment.
The Ti-Al intermetallic compound micro-laminated composite armor prepared by the invention has excellent penetration resistance. The composite target plate prepared in example 1 was subjected to a ballistic penetration test, a 9.5 mm tungsten alloy fragment shooting test was performed on the composite target plate using a 10mm bore smoothbore gun, and the fragment speed was controlled by the charge amount. The range is 6 m, normal incidence. The ballistic limit V50 of the Ti-Al intermetallic compound micro-laminated composite target plate is obtained by a plurality of tests.
TABLE 1 ballistic penetration test data for Ti-Al intermetallic compound micro-laminated composite target plate
Figure DEST_PATH_IMAGE003
In a penetration test, the initial impact speed of the tungsten alloy fragments is controlled by changing the loading amount. The validity tests are carried out for 5 times in total, and the initial impact speed ranges of the projectile bodies are obtained to be 501 m/s, 485 m/s, 529 m/s, 562m/s and 538 m/s. As can be seen from Table 1, the lowest initial velocity of the tungsten alloy fragments penetrating through the Ti-Al intermetallic compound micro-laminated target plate is 562m/s, and the highest initial velocity of the tungsten alloy fragments not penetrating through the Ti-Al intermetallic compound micro-laminated target plate is 538m/s, so that the ballistic limit of the tungsten alloy fragments penetrating through the Ti-Al intermetallic compound micro-laminated target plate is 538 m/s-562 m/s.
The average value of the data of the 4 th group and the 5 th group is about 550 m/s of the ballistic limit V50 of the Ti-Al intermetallic compound micro-laminated composite target plate. Under the same test conditions, the ballistic limit V50 of the Q235 steel sheet obtained was about 522 m/s. Therefore, the protective capability of the Ti-Al intermetallic compound micro-laminated composite armor is higher than that of Q235 steel, and the density of the Ti-Al intermetallic compound micro-laminated composite armor is far lower than that of the Q235 steel, so that the Ti-Al intermetallic compound micro-laminated composite armor has a huge application prospect.

Claims (4)

1.一种制备Ti-Al金属间化合物微叠层复合装甲的方法,其特征在于:所述Ti-Al金属间化合物微叠层复合装甲为由Ti-AlTi和Ti-Al3Ti-Al叠层复合材料组成的Ti-Al金属间化合物微叠层复合装甲,其中:Ti-AlTi叠层复合材料作为装甲前板,Ti-Al3Ti-Al叠层复合材料作为装甲后板,装甲前板与装甲后板用扩散焊的方式连接;装甲前板与装甲后板的厚度比为3:1-4:1;1. a method for preparing Ti-Al intermetallic compound micro-laminate composite armor, it is characterized in that: described Ti-Al intermetallic compound micro-laminate composite armor is composed of Ti-AlTi and Ti-Al 3 Ti-Al stack. Ti-Al intermetallic compound micro-laminate composite armor composed of layers of composite materials, in which: Ti-AlTi laminated composite material is used as armor front plate, Ti-Al 3 Ti-Al laminated composite material is used as armor rear plate, armor front plate It is connected with the armored rear plate by diffusion welding; the thickness ratio of the armored front plate and the armored rear plate is 3:1-4:1; 先用真空热压烧结法制备Ti-AlTi与Ti-Al3Ti-Al两种叠层复合材料,然后将Ti-AlTi和Ti-Al3Ti-Al两种叠层复合材料用扩散焊的方式焊接在一起,即为Ti-Al金属间化合物微叠层复合装甲;First, two kinds of laminated composite materials, Ti-AlTi and Ti-Al 3 Ti-Al, were prepared by vacuum hot pressing sintering method, and then two kinds of laminated composite materials, Ti-AlTi and Ti-Al 3 Ti-Al, were prepared by diffusion welding. Welded together, that is, Ti-Al intermetallic compound micro-laminated composite armor; 所述Ti-AlTi叠层复合材料的具体制备方法为:The specific preparation method of the Ti-AlTi laminated composite material is: (1)酸碱清洗TC4箔、Al箔:将TC4箔、Al箔裁剪成大小相同的尺寸;将所裁TC4箔放入HF与水按体积比为1:20配制的酸溶液中处理,将所裁Al箔放入5 %浓度的NaOH溶液中处理,二者反应时间均为2 min,以除去其表面氧化物;将反应后的两种箔材用清水冲洗;再用酒精对两种箔材超声波清洗5min,最后将两种材料烘干备用;(1) Acid-base cleaning of TC 4 foil and Al foil: Cut the TC 4 foil and Al foil into the same size; put the cut TC 4 foil into an acid solution prepared with HF and water in a volume ratio of 1:20 Treatment, put the cut Al foil into a 5% concentration NaOH solution for treatment, and the reaction time of both is 2 min to remove the surface oxide; rinse the two kinds of foils after the reaction with clean water; The two foils were ultrasonically cleaned for 5 minutes, and finally the two materials were dried for later use; (2)叠层包套:将准备好的TC4箔、Al箔按照TC4-Al-TC4的顺序叠层,叠层厚度为7-10mm,且最外层为TC4层,将叠层好的试样用20μm厚的TC4箔材封装获得封装体;(2) Lamination wrapping: Laminate the prepared TC 4 foil and Al foil in the order of TC 4 -Al-TC 4 , the thickness of the lamination is 7-10mm, and the outermost layer is TC 4 layer. The laminated samples were packaged with 20μm thick TC 4 foil to obtain a package; (3)真空热压烧结:将所得封装体置于石墨模具中,按照如下工艺真空热压烧结获得所述Ti-AlTi叠层复合材料;(3) Vacuum hot pressing sintering: the obtained package body is placed in a graphite mold, and the Ti-AlTi laminated composite material is obtained by vacuum hot pressing sintering according to the following process; A、对所得封装体施加3-5 MPa压力,以20℃/min速率升高烧结温度到580-610℃,而后保温150-200 min,保温期间压力为3-5MPa;A. Apply a pressure of 3-5 MPa to the obtained package, increase the sintering temperature to 580-610 ℃ at a rate of 20 ℃/min, and then keep it for 150-200 min, and the pressure during the heating is 3-5 MPa; B、卸载所加载的压力,以20℃/min的速率升高烧结温度到1100-1300 ℃,保温100-150min,保温前期不施加压力,后30 min施加2-3 Mpa压力;B. Unload the loaded pressure, increase the sintering temperature to 1100-1300 °C at a rate of 20 °C/min, keep the temperature for 100-150 minutes, do not apply pressure in the early stage of the insulation, and apply 2-3 Mpa pressure in the last 30 minutes; C、以10 ℃/min的速率降低烧结温度至580-610℃,保温120-150 min,降温及保温期间压力为2-3 MPa;C. Reduce the sintering temperature to 580-610°C at a rate of 10°C/min, hold for 120-150 min, and keep the pressure at 2-3 MPa during cooling and holding; D、随炉冷却,冷却期间压力为2-3 MPa,退模,即可制备出所述Ti-AlTi叠层复合材料。D. Cooling with the furnace, the pressure during cooling is 2-3 MPa, and the mold is removed, and the Ti-AlTi laminated composite material can be prepared. 2.根据权利要求1所述的一种制备Ti-Al金属间化合物微叠层复合装甲的方法,其特征在于:所述Ti-Al3Ti-Al叠层复合材料的具体制备方法为:2. a kind of method for preparing Ti-Al intermetallic compound micro-laminate composite armor according to claim 1, is characterized in that: the concrete preparation method of described Ti-Al 3 Ti-Al laminated composite material is: (1)酸碱清洗TC4箔、Al箔:将TC4箔、Al箔裁剪成大小相同的尺寸;将所裁TC4箔放入HF与水按体积比为1:20配制的酸溶液中处理、将所裁Al箔放入5%浓度的NaOH溶液中处理,二者反应时间均为2 min,以除去其表面氧化物;将反应后的两种箔材用清水冲洗;再用酒精对两种箔材超声波清洗5 min,最后将两种材料烘干备用;(1) Acid-base cleaning of TC 4 foil and Al foil: Cut the TC 4 foil and Al foil into the same size; put the cut TC 4 foil into an acid solution prepared with HF and water in a volume ratio of 1:20 Treatment, put the cut Al foil into a 5% concentration NaOH solution for treatment, and the reaction time of both is 2 min to remove the surface oxide; rinse the two foils after the reaction with clean water; The two foils were ultrasonically cleaned for 5 min, and finally the two materials were dried for later use; (2)叠层包套:将准备好的TC4箔、Al箔按照TC4-Al-TC4的顺序叠层,叠层厚度5-7 mm,且保证最外层为TC4层,将叠层好的试样用20μm厚的TC4箔材封装即得封装体;(2) Laminated wrapping: Laminate the prepared TC 4 foil and Al foil in the order of TC 4 -Al-TC 4 , with a thickness of 5-7 mm, and ensure that the outermost layer is a TC 4 layer. The laminated samples are packaged with 20μm thick TC 4 foil to obtain the package; (3)真空热压烧结:将所得封装体置于石墨模具中,按照如下工艺真空热压烧结获得所述Ti-Al3Ti-Al叠层复合材料:(3) Vacuum hot pressing sintering: The obtained package body is placed in a graphite mold, and the Ti-Al 3 Ti-Al laminated composite material is obtained by vacuum hot pressing sintering according to the following process: a、对所得封装体施加3-5MPa压力,以20℃/min速率升高烧结温度到600-610℃,保温60-100min,保温期间压力为3-5 MPa;a. Apply a pressure of 3-5MPa to the obtained package, increase the sintering temperature to 600-610°C at a rate of 20°C/min, hold the temperature for 60-100min, and keep the pressure at 3-5 MPa during the heat preservation; b、以5℃/min的速率升高烧结温度到640℃,保温300-400 min,保温期间压力为2-3Mpa;b. Raise the sintering temperature to 640°C at a rate of 5°C/min, hold for 300-400 min, and keep the pressure at 2-3Mpa during the holding period; c、以5℃/min的速率降低烧结温度至570℃,保温120-180min,降温及保温期间压力为2-3 MPa;c. Reduce the sintering temperature to 570°C at a rate of 5°C/min, keep for 120-180min, and keep the pressure at 2-3 MPa during cooling and keeping; d、随炉冷却,冷却期间压力为2-3 MPa,退模,即可制备出所述Ti-Al3Ti-Al叠层复合材料。d. Cooling with the furnace, the pressure during cooling is 2-3 MPa, and the mold is removed, and the Ti-Al 3 Ti-Al laminated composite material can be prepared. 3.根据权利要求1所述的一种制备Ti-Al金属间化合物微叠层复合装甲的方法,其特征在于:所述Ti-Al金属间化合物微叠层复合装甲的具体制备方法为:3. a kind of method of preparing Ti-Al intermetallic compound micro-layer composite armor according to claim 1, is characterized in that: the concrete preparation method of described Ti-Al intermetallic compound micro-layer composite armor is: (1)将制备好的Ti-AlTi和Ti-Al3Ti-Al叠层复合材料表层用砂纸打磨,直至露出新鲜的TC4表面,备用;(1) Sand the surface of the prepared Ti-AlTi and Ti-Al 3 Ti-Al laminated composites with sandpaper until the fresh TC 4 surface is exposed, for use; (2)将铝箔裁剪成大小相同的尺寸,将所裁Al箔放入5%浓度的NaOH溶液中处理,反应时间为2 min,以除去其表面氧化物;将反应后的Al箔用清水冲洗;再用酒精对Al箔超声波清洗5 min,最后将Al箔烘干备用;(2) Cut the aluminum foil into the same size, put the cut Al foil into a 5% concentration NaOH solution for treatment, and the reaction time is 2 min to remove its surface oxide; rinse the reacted Al foil with water ; ultrasonically clean the Al foil with alcohol for 5 min, and finally dry the Al foil for later use; (3)将处理过的Al箔放在制备好的Ti-AlTi与Ti-Al3Ti-Al叠层复合材料中间,用20μm厚的TC4箔材对整体进行封装;(3) Place the treated Al foil in the middle of the prepared Ti-AlTi and Ti-Al 3 Ti-Al laminated composites, and encapsulate the whole with 20 μm thick TC 4 foil; (4)将上述封装体置于石墨模具中,按照如下工艺在真空热压烧结炉中进行扩散焊连接:(4) Place the above package in a graphite mold, and perform diffusion welding in a vacuum hot pressing sintering furnace according to the following process: A、对所得封装体施加4-6 MPa压力,以20℃/min速率升高烧结温度到660℃,而后保温20min,保温期间压力为4-6 MPa;A. Apply a pressure of 4-6 MPa to the obtained package, increase the sintering temperature to 660 °C at a rate of 20 °C/min, and then keep it for 20 minutes, and the pressure during the heat preservation period is 4-6 MPa; B、随炉冷却,冷却期间压力为1-2 MPa,退模,即可制备出所述Ti-Al金属间化合物微叠层复合装甲。B. Cooling with the furnace, the pressure during cooling is 1-2 MPa, and the mold is removed, and the Ti-Al intermetallic compound micro-laminated composite armor can be prepared. 4.根据权利要求1-3任一所述的制备Ti-Al金属间化合物微叠层复合装甲的方法,其特征在于:所述TC4箔、Al箔裁剪成100×100mm。4. The method for preparing Ti-Al intermetallic compound micro-laminated composite armor according to any one of claims 1-3, wherein the TC 4 foil and the Al foil are cut into 100×100 mm.
CN201911088372.3A 2019-11-08 2019-11-08 A kind of Ti-Al intermetallic compound micro-laminated composite armor and preparation method thereof Expired - Fee Related CN111043909B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201911088372.3A CN111043909B (en) 2019-11-08 2019-11-08 A kind of Ti-Al intermetallic compound micro-laminated composite armor and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201911088372.3A CN111043909B (en) 2019-11-08 2019-11-08 A kind of Ti-Al intermetallic compound micro-laminated composite armor and preparation method thereof

Publications (2)

Publication Number Publication Date
CN111043909A CN111043909A (en) 2020-04-21
CN111043909B true CN111043909B (en) 2022-03-15

Family

ID=70232592

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201911088372.3A Expired - Fee Related CN111043909B (en) 2019-11-08 2019-11-08 A kind of Ti-Al intermetallic compound micro-laminated composite armor and preparation method thereof

Country Status (1)

Country Link
CN (1) CN111043909B (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111516314B (en) * 2020-04-24 2023-05-05 哈尔滨工程大学 ABA type sandwich composite material and preparation method thereof
CN112781446B (en) * 2020-12-29 2023-05-12 中北大学 Intelligent protective armor with damage feedback function and preparation method thereof
CN113151701B (en) * 2021-04-13 2022-04-22 太原理工大学 A kind of preparation method of large-size metal aluminide curved thin-walled member

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1352207A1 (en) * 2001-01-15 2003-10-15 Michael Cohen Laminated armor
CN1535812A (en) * 2003-04-11 2004-10-13 中国科学院金属研究所 Preparation method of Ti-Al-Ti multilayer layered composite material
CN102744928A (en) * 2012-07-25 2012-10-24 哈尔滨工业大学 Preparation method of Ti3Al-TiAl layered composite material
CN108372690A (en) * 2016-12-21 2018-08-07 中国航空制造技术研究院 A kind of preparation method of reticular structure toughening bionic composite material and its structural member
CN108871073A (en) * 2018-06-04 2018-11-23 中北大学 A kind of ceramic laminated composite armour of TC4-Al3Ti-TC4- and preparation method thereof
CN108909084A (en) * 2018-06-04 2018-11-30 中北大学 It is a kind of that Ti-Al is prepared using heat absorption semi-solid-state reaction3The method of Ti-Al laminated composite materials

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1352207A1 (en) * 2001-01-15 2003-10-15 Michael Cohen Laminated armor
CN1535812A (en) * 2003-04-11 2004-10-13 中国科学院金属研究所 Preparation method of Ti-Al-Ti multilayer layered composite material
CN102744928A (en) * 2012-07-25 2012-10-24 哈尔滨工业大学 Preparation method of Ti3Al-TiAl layered composite material
CN108372690A (en) * 2016-12-21 2018-08-07 中国航空制造技术研究院 A kind of preparation method of reticular structure toughening bionic composite material and its structural member
CN108871073A (en) * 2018-06-04 2018-11-23 中北大学 A kind of ceramic laminated composite armour of TC4-Al3Ti-TC4- and preparation method thereof
CN108909084A (en) * 2018-06-04 2018-11-30 中北大学 It is a kind of that Ti-Al is prepared using heat absorption semi-solid-state reaction3The method of Ti-Al laminated composite materials

Also Published As

Publication number Publication date
CN111043909A (en) 2020-04-21

Similar Documents

Publication Publication Date Title
CN111043909B (en) A kind of Ti-Al intermetallic compound micro-laminated composite armor and preparation method thereof
CN108871073B (en) TC4-Al3Ti-TC 4-ceramic laminated composite armor and preparation method thereof
CN100570268C (en) Fiber Reinforced Metal/Ceramic Laminated Composite Fenders
CN103572187B (en) The preparation method of compound base layer-shaped composite material between a kind of light-weight metal
CN108909084B (en) Preparation of Ti-Al by endothermic semi-solid reaction3Method for Ti-Al laminated composite material
CN109177426B (en) A kind of hot pressing composite method of aluminum-magnesium sandwich composite board
CN109405647B (en) Brick wall type multilayer tortoise shell protection device and preparation method thereof
CN210180282U (en) Strong-constraint boron carbide ceramic composite armor
CN110216291A (en) Titanium packaging ceramic/Al3Ti-Al-TC4Bionical laminated composite materials and preparation method thereof
CN107246823B (en) Method for manufacturing interlayer sandwich type foamed aluminum composite armor
CN100346963C (en) Metal/ceramic laminated composite material prevention plate
CN115406307B (en) A bulletproof insert plate based on oxide filament-reinforced ceramic composite material and its preparation method
CN110645837A (en) Composite ceramic and preparation method thereof
CN110280769B (en) Ti-Ti with cylinder staggered stacking structure2AlC/TiAl3Laminated composite material and preparation method thereof
CN109141123A (en) A kind of constraint ceramic-metal bulletproof composite armour plate and preparation method thereof
CN111272016A (en) Bulletproof composite armor and preparation method thereof
Bao et al. Research progress of armor protection materials
CN110631421B (en) Ultra-light armor and preparation method thereof
CN110608636A (en) A titanium alloy composite armor
CN108749043B (en) A kind of lightweight package composite armour and its manufacturing process
CN111439005B (en) A ceramic powder reinforced multilayer metal and intermetallic compound composite structure and preparation method thereof
CN201016655Y (en) Fiber Reinforced Metal/Ceramic Laminated Composite Fenders
CN116399178B (en) Aluminum-based composite foam board and preparation method thereof, and composite bulletproof board and preparation method thereof
CN113899249B (en) Metal-encapsulated ceramic ball composite armor, preparation method and anti-multiple-ejection light target plate
CN113172228B (en) TC (tungsten carbide)4-Al3Ti laminated composite board and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
CB03 Change of inventor or designer information
CB03 Change of inventor or designer information

Inventor after: Yuan Meini

Inventor after: Yao Leibin

Inventor after: Xin Le

Inventor after: Ma Jian

Inventor after: Han Fangzhou

Inventor after: Zheng Lirong

Inventor after: Zhang Guoqing

Inventor after: Wang Kai

Inventor after: Wei Zeyuan

Inventor after: Yao Yuhang

Inventor after: Li Lizhou

Inventor before: Yuan Meini

Inventor before: Xin Le

Inventor before: Han Fangzhou

Inventor before: Zheng Lirong

Inventor before: Zhang Guoqing

Inventor before: Wang Kai

Inventor before: Wei Zeyuan

Inventor before: Yao Yuhang

Inventor before: Li Lizhou

Inventor before: Yao Leibin

GR01 Patent grant
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20220315