CN111020581B - Inner container enameling control method of enameling machine - Google Patents

Inner container enameling control method of enameling machine Download PDF

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Publication number
CN111020581B
CN111020581B CN201911398020.8A CN201911398020A CN111020581B CN 111020581 B CN111020581 B CN 111020581B CN 201911398020 A CN201911398020 A CN 201911398020A CN 111020581 B CN111020581 B CN 111020581B
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China
Prior art keywords
inner container
seconds
enameling
swing
overturning
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CN111020581A (en
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晁月会
国长征
李忠正
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Gelman (Guangdong) New Energy Technology Co.,Ltd.
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Shandong Haohua Enamel Water Tank Co ltd
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23DENAMELLING OF, OR APPLYING A VITREOUS LAYER TO, METALS
    • C23D5/00Coating with enamels or vitreous layers
    • C23D5/02Coating with enamels or vitreous layers by wet methods
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2207/00Compositions specially applicable for the manufacture of vitreous enamels
    • C03C2207/04Compositions specially applicable for the manufacture of vitreous enamels for steel

Abstract

The invention discloses a control method for enameling an inner container of an enameling machine, wherein an initial position travel switch is arranged at the initial position of the enameling machine, and a guniting position travel switch is arranged at the guniting position; the initial position travel switch and the guniting position respectively collect signals of the limit position of the swing support, the swing of the swing support, the pause of any angle position, the rotation of the workpiece and the compression and release of the workpiece are controlled by the control system, external signals do not need to be collected, and the omnibearing enameling inside the workpiece is realized by setting the time length of each action. The control system controls the workpiece to swing and pause at a preset angle relative to the control system for acquiring external signals, and avoids system control abnormity caused by external signal faults.

Description

Inner container enameling control method of enameling machine
Technical Field
The invention relates to the technical field of enamel enameling, in particular to a system and a method for controlling enameling of an inner container of an enameling machine.
Background
With the progress of the current society, energy conservation and emission reduction become important contents of the development of the current society, and the energy conservation and emission reduction become important development directions for the reasonable and effective use of various clean energy sources such as solar energy, wind energy and the like. The vast majority of people in China have abundant solar energy resources, so that the solar water tank serving as a traditional simple solar energy utilization mode is used in a wide area in China for years. The solar water tank can convert solar energy into heat energy, so that water in the liner is heated from low temperature to high temperature, and the requirement of hot water in life and production of people is met.
The existing solar water tanks all comprise inner containers, and circulating media transfer heat to water in the inner containers through heat conduction. Due to the requirement of corrosion resistance, most of the inner containers of the existing solar water tanks need an enamel layer, and the preparation method of the enamel layer comprises the steps of pulping glaze raw materials, driving the raw materials into the enamel inner container through a pulp inlet pipe, and utilizing a driving device to drive the outer surface of the inner container to rotate the inner container; the glaze slip can be uniformly coated on the inner surface of the inner container through the rotation of the inner container and the overturning action of the swinging bracket, and then after drying and sintering, the glaze slip is melted, condensed on the metal plate of the inner container and tightly combined with the metal plate. In the process, a plurality of important problems need to be considered, namely the corrosion resistance of the enamel, because although the enamel has the corrosion resistance, the water in the liner still inevitably corrodes the surface of the enamel after long-term use, and is gradually dissolved and peeled off, so that the service life of the liner is reduced. Another very critical problem is that the glaze slip needs to be uniformly coated on the inner surface of the liner in the enameling process, but the current operation mode is to rotate and turn the liner to make the glaze slip naturally attached to the inner surface without any external acting force, and the thickness of each part is inevitably different because the glaze slip is fluid. It is difficult to achieve uniform coating of the glaze slurry. Meanwhile, when the enameling machine performs overturning and rotating actions, an induction control mode is adopted, and due to the sensitivity problem of an induction device, errors are easy to occur, so that the problems of coating are caused.
Disclosure of Invention
In order to solve the technical problem, the invention provides a system and a method for controlling enameling of an enameling machine.
The complete technical scheme of the invention comprises the following steps:
the inner container enameling control method of the enameling machine is characterized in that an initial position travel limit switch is arranged at an initial position of the enameling machine, and a guniting position travel limit switch is arranged at a guniting position; the initial position travel limit switch and the guniting position travel limit switch respectively collect limit position signals of the swing bracket, and the swing of the swing bracket, the pause of any angle position, the rotation of the workpiece, and the compression and the release of the workpiece are controlled by a control system; the control system comprises a manual control mode and an automatic control mode;
the concrete steps of utilizing the control system to enamel the inner container comprise:
(1) in a manual control mode, the pressing cylinder is lifted, and the liner is installed in place; then the compressing cylinder descends to compress the inner container, and the inner container is at an initial position and the axis of the inner container is vertical;
(2) under the automatic control mode, the main cylinder drives the swing bracket to turn forwards until the swing bracket touches a guniting position travel limit switch, and the included angle between the axis of the liner and the horizontal plane is 45-55 degrees;
(3) the auxiliary motor is started to drive the inner container to rotate at a constant speed of 10-15rpm, and before the enameling operation is finished, the inner container always rotates at a constant speed;
(4) after the rotation is timed for 30 seconds, the diaphragm pump is started, the glaze slurry is driven into the inner container, the pulping time is 10 seconds, and a compressed air source is started to pressurize the inner container;
(5) the main cylinder drives the swing bracket to turn backwards, the turning time is 5 seconds, and the swing bracket stops until the inner container keeps a horizontal position;
(6) stopping overturning, after the inner container continues to rotate and is timed for 20 seconds, driving the swing bracket to overturn backwards again by the main cylinder, wherein the overturning time is 5 seconds, stopping overturning by the swing bracket, and forming an included angle of 25-35 degrees between the axis of the inner container and the horizontal plane;
(7) stopping overturning, after the inner container continues to rotate and count time for 20 seconds, driving the swing bracket to continue overturning backwards by the main cylinder, wherein the overturning time is 5 seconds, and the swing bracket stops overturning, and at the moment, the included angle between the axis of the inner container and the horizontal plane is 60-75 degrees;
(8) stopping overturning, after the inner container continues to rotate and is timed for 20 seconds, driving the swing support to overturn forwards by the main cylinder, wherein the overturning time is 5 seconds, stopping overturning by the swing support, and at the moment, the included angle between the axis of the inner container and the horizontal plane is 10-15 degrees;
(9) stopping overturning, after the inner container continues to rotate and is timed for 20 seconds, driving the swinging bracket to overturn backwards by the main cylinder until the swinging bracket touches an initial position travel limit switch, and at the moment, the inner container is in an initial position and the axis of the inner container is vertical;
(10) the auxiliary motor is turned off after the inner container continues to rotate for 10 seconds, and the inner container stops rotating;
(11) and under a manual control mode, the pressing air cylinder is lifted, the inner container is taken down from the enameling machine and hung on a drying conveying line.
Preferably, when the workpiece to be enameled rotates, swings and stops at various angles, except for the initial position and the guniting position, the limit position signals need to be acquired, and the external signals do not need to be acquired when other actions are completed.
Preferably, the enameling machine comprises a slurry inlet pipe, the slurry inlet pipe is positioned inside a chassis hollow shaft, a gap is arranged in the middle of the slurry inlet pipe, the chassis hollow shaft is installed on a chassis bearing and a chassis bearing seat, the slurry inlet pipe is connected with a slurry spraying pump, and the chassis hollow shaft is connected with a compressed air source.
Preferably, in the step (4), the compressed air source is started to pressurize the inner container, so that the pressure of the inner container is 0.3-0.5 Mpa.
Drawings
FIG. 1 is a schematic structural view of a grouting mechanism of the enameling machine of the present invention.
Fig. 2 is a schematic diagram of the turning of the liner during the enameling process.
FIG. 3 is a view showing the setting of the operating system of the enameling machine of the present invention.
Detailed Description
The technical solutions in the embodiments of the present application will be clearly and completely described below with reference to the drawings in the embodiments of the present application, and it is obvious that the described embodiments are only illustrative and are not intended to limit the present application.
The overall process of enameling by the enameling machine disclosed by the present invention is schematically described below.
(1) Preparing glaze slip:
the raw material components adopted by the invention at least comprise: silicon dioxide: 52-58 parts by mass of feldspar powder: 48-50 parts by mass of boric anhydride: 18-25 parts by mass of alumina: 4-6 parts by mass, the sum of cobalt oxide and nickel oxide: 1.2-1.6 parts by mass of soda: 4-6 parts by mass of calcium carbonate: 1-3 parts by mass of kaolin: 2 to 3 parts by mass.
In the components of the invention, silicon oxide and feldspar powder are used as base materials, boric anhydride and alkalis are added as functional components for reducing the melting point of the base materials, and the thermal expansion coefficient of the soda ash is adjusted at the same time. As for the amount of cobalt oxide and nickel oxide, in the actual production, the addition of feldspar powder into cobalt oxide and nickel oxide can make the glaze more fusible, improve the viscosity, reduce the surface tension gradually and make the glaze more easily coated on the surface of a steel plate. After the product is detected, the addition of the cobalt oxide and the nickel oxide can form a partial microcrystalline phase after sintering, and the compressive strength is also obviously improved. Through multiple experiments on the dosage of the base component and each functional component, and comprehensive comparison of the influence on performance and cost consideration, the optimal dosage combination is finally selected, namely, the glaze component of the invention meets the following relationship, (silicon oxide + feldspar powder), (boric anhydride + soda), and (cobalt oxide + nickel oxide) ═ 100: (24-28) are (1.4-1.6).
And uniformly mixing the prepared raw materials by using a ball-milling mixer, and adding deionized water to obtain the glaze slip used by the invention.
(2) Enameling process
The enamelling mechanism of the invention is partly based on the enamelling machine of the applicant's prior application CN201611226055.X, and is improved on the basis of the principle, and the detailed description is as follows:
the first improvement of the invention is that as shown in figure 1, the guniting mechanism of the invention comprises a grout inlet pipe 1, the grout inlet pipe 1 is positioned inside a chassis hollow shaft 2, a gap is arranged in the middle of the grout inlet pipe, the chassis hollow shaft 2 is arranged on a chassis bearing 3 and a chassis bearing seat 4, the grout inlet pipe 1 is connected with a guniting pump, and the chassis hollow shaft 2 is connected with a high-pressure air source.
In the prior invention, during the enameling operation, after the slurry spraying pump drives the glaze slurry into the enamel liner through the slurry inlet pipe, the glaze slurry is coated on the inner surface of the liner through the rotation of the liner and the overturning action of the swing bracket; then the glaze slurry flows out into a recovery hopper through a pore passage between the hollow shaft of the chassis and the slurry inlet pipe. The enameling mode completely depends on the gravity of the glaze slip to flow in the rotating and overturning processes and coat the glaze slip on the surface of the liner, the flowing process is uncontrollable, gaps generated by assembly often exist at certain positions of the liner, such as the root of a water pipe and the welding position of a seal head, the joint and the like are easily coated, and meanwhile, the glaze slip is gradually reduced in the coating process, so that the coating of the liner is not uniform enough. Meanwhile, in the subsequent drying process, the thickness of the glaze slurry on the inner surface of the coated inner container is changed due to the fact that the inner container is moved, and the like. The quality of the product is also seriously affected.
In order to solve the problem, the invention is creatively improved on the basis of the original enameling mechanism, and a high-pressure air source is connected with a hollow shaft of a chassis. After the glaze slip is squeezed into the enamel inner container through the slip inlet pipe, the pressure in the inner container is increased through a high-pressure air source, coating work is carried out under certain pressure, the glaze slip is rotated and overturned in the inner container, the glaze slip not only bears the action of gravity, but also bears the action of air pressure, flowing is more stable, the glaze slip on the inner surface after coating bears the action of pressure, thickness change is not easy to occur when the enamel slip is moved, and coating quality is obviously improved. In the embodiment, the pressure used in the inner container is 0.3-0.5 MPa.
In another more improved solution, a pressure of 0.3MPa is used in the initial stage of coating, and the pressure is increased gradually as the coating progresses, and the pressure is increased to 1.5 times the initial pressure at the end of coating.
The second improvement of the invention is that when the control system of the enameling machine and the prior enameling machine perform overturning and rotating actions, an induction control mode is adopted, and because of the sensitivity problem of an induction device, errors are easy to occur, so that coating problems occur. The invention improves the problem, and the travel limit switches are respectively arranged at the initial position and the guniting position of the enameling machine and acquire the limit position signals of the swing bracket. The swinging of the swing bracket of the enameling machine, the pause of any angle position, the rotation of the workpiece and the compression and release of the workpiece are controlled by a control system.
The control system controls the enameling machine to drive the workpiece to rotate at a preset speed in the process of putting the workpiece into the enameling machine for enameling, simultaneously swings and pauses at various angles, and except for the initial position and the guniting position, limit position signals need to be collected, other actions are completed without collecting external signals, and the omnibearing enameling inside the workpiece is realized by setting the time length of each action. The control system controls the workpiece to swing and pause at a preset angle relative to the control system for acquiring external signals, and avoids system control abnormity caused by external signal faults.
The control system of the invention adopts a mode of combining manual control and automatic control, controls the coating process by using time, and can realize coating at 360 degrees without dead angles.
In the present invention, a position where the axis of the inner container is perpendicular to the horizontal plane is set as an initial position. When the axis of the liner is vertical to the horizontal plane, the horizontal line of the axis of the liner is called a horizontal base line.
The concrete enameling operation is described below with reference to fig. 2:
1. manual operation:
1) FIG. 2a shows the initial position of the liner, to which the oscillating support is automatically returned each time the enameling is finished,
2) the pressing cylinder release button is manually pressed down, the pressing cylinder rises, the inner container is installed in place,
3) a pressing cylinder pressing button is manually pressed, the pressing cylinder descends to press the inner container tightly,
2. automatic operation
1) The 'selection switch' is placed in an 'automatic' gear;
2) pressing an automatic start button, driving the swing bracket to turn forwards by the main cylinder until the swing bracket crosses the horizontal base line and touches a guniting position travel limit switch, stopping to the position shown in figure 2b, and forming an included angle of 45-55 degrees between the axis of the liner and the horizontal at the moment;
3) the auxiliary motor is started to drive the inner container to rotate at a constant speed of 10-15rpm, the rotation timing Z1 is 30 seconds, and the inner container always rotates at a constant speed before the enameling operation is finished;
4) starting a diaphragm pump, driving the glaze slurry into the inner container for about 10 seconds, starting a compressed air source, and pressurizing the inner container;
5) the main cylinder drives the swing support to turn backwards, the turning time F1 is 5 seconds, the swing support stops at the position shown in figure 2c, and the axis of the liner is coincided with the horizontal base line at the moment;
6) the inner container rotation timing Z2 is 20 seconds, the main cylinder drives the swing bracket to turn backwards again and cross the horizontal base line, the turning timing F2 is 5 seconds, the swing bracket stops to the position shown in figure 2d, and the included angle between the axis of the inner container and the horizontal line is 25-35 degrees;
7) the inner container rotates to time Z3 for 20 seconds, the main cylinder drives the swing bracket to continuously turn backwards, the turning time F3 is 5 seconds, the swing bracket stops at the position of figure 2e, and the included angle between the axis of the inner container and the horizontal plane is 60-75 degrees;
8) the inner container rotation timing Z4 is 20 seconds, the main cylinder drives the swing bracket to turn forwards and cross the horizontal base line, the turning timing F4 is 5 seconds, the swing bracket stops to the position of figure 2F, and the included angle between the axis of the inner container and the horizontal line is 10-15 degrees;
9) the inner container rotates for timing Z5 seconds, the main cylinder drives the swing bracket to turn backwards and cross the horizontal base line until the swing bracket touches an initial position travel limit switch and stops at the position shown in figure 2a, and the axis of the inner container is at the initial position at the moment;
10) the auxiliary motor is closed after 10 seconds, and the inner container stops rotating;
3. operated manually
1) Manually pressing a 'pressing cylinder loosening' button to take the inner container off the enameling machine and hang the inner container on a drying conveying line;
2) and (4) loading the inner container to be enameled into an enameling machine, and repeating the steps.
It should be noted that the innovation of the present invention in the time control system can be used in combination with the pneumatic coating or alone. Can obtain good technical effect. In addition, the time control process of the invention can also be completely controlled in a manual mode, and specifically comprises the following steps:
1) FIG. 2a shows the initial position of the liner, to which the oscillating support is automatically returned each time the enameling is finished,
2) the pressing cylinder release button is manually pressed down, the pressing cylinder rises, the inner container is installed in place,
3) a pressing cylinder pressing button is manually pressed, the pressing cylinder descends to press the inner container tightly,
4) the 'selection switch' is placed in a 'manual' gear;
5) pressing the 'upturning' button of the main cylinder, the main cylinder upturns the swing bracket until the swing bracket touches the limit switch and stops at the position shown in figure 2 b;
6) pressing down a starting button of the auxiliary motor, starting the motor and driving the inner container to rotate at a constant speed;
7) pressing a 'start' button of a diaphragm pump to start beating, and pressing a 'stop' button to finish beating after about 10 seconds of beating;
8) after the inner container rotates for 5-6 circles, a 'turn-down' button of the main cylinder is pressed, the swing support is turned downwards to the position shown in the figure 2c, the turning-over time F1 is 5 seconds, and the swing support stops at the position;
9) after the inner container rotates for 5-6 circles, a 'turn-down' button of the main cylinder is pressed, the swing support is turned downwards to the position shown in the figure 2d, the turning-over time F2 is 5 seconds, and the swing support stops at the position;
10) after the inner container rotates for 5-6 circles, a 'turn-down' button of the main cylinder is pressed, the swing support is turned downwards to the position shown in the figure 2e, the turning-over time F3 is 5 seconds, and the swing support stops at the position;
11) after the inner container rotates for 5-6 circles, an up-turning button of the main cylinder is pressed, the swing support is turned upwards to the position shown in the figure 2F, the turning time F4 is 5 seconds, and the swing support stops at the position;
12) after the inner container rotates for 5-6 circles, a 'turn-down' button of the main cylinder is pressed, the swing bracket turns downwards until the swing bracket touches a limit switch, and the inner container stops at the position shown in figure 2 a;
13) after 10 seconds, pressing a 'stop' button of the auxiliary motor, and stopping the inner container from rotating;
14) pressing down a 'loosening' button of a compaction air cylinder to take down the inner container and hang the inner container on a drying conveying chain;
15) and (4) loading the inner container to be enameled into an enameling machine, and repeating the steps.
The above applications are only some embodiments of the present application. It will be apparent to those skilled in the art that various changes and modifications can be made without departing from the inventive concept herein, and it is intended to cover all such modifications and variations as fall within the scope of the invention.

Claims (2)

1. The inner container enameling control method of the enameling machine is characterized in that an initial position travel limit switch is arranged at an initial position of the enameling machine, and a guniting position travel limit switch is arranged at a guniting position; the initial position travel limit switch and the guniting position travel limit switch respectively collect limit position signals of the swing bracket, and the swing of the swing bracket, the pause of any angle position, the rotation of the workpiece, and the compression and the release of the workpiece are controlled by a control system; the control system comprises a manual control mode and an automatic control mode;
the guniting mechanism of the enameling machine comprises a grout inlet pipe, the grout inlet pipe is positioned inside a chassis hollow shaft, a gap is arranged in the middle of the grout inlet pipe, the chassis hollow shaft is arranged on a chassis bearing and a chassis bearing seat, the grout inlet pipe is connected with a guniting pump, and the chassis hollow shaft is connected with a high-pressure air source;
the glaze slip at least comprises the following raw material components: silicon dioxide: 52-58 parts by mass of feldspar powder: 48-50 parts by mass of boric anhydride: 18-25 parts by mass of alumina: 4-6 parts by mass, the sum of cobalt oxide and nickel oxide: 1.2-1.6 parts by mass of soda: 4-6 parts by mass of calcium carbonate: 1-3 parts by mass of kaolin: 2-3 parts by mass;
the concrete steps of utilizing the control system to enamel the inner container comprise:
(1) in a manual control mode, the pressing cylinder is lifted, and the liner is installed in place; then the compressing cylinder descends to compress the inner container, and the inner container is at an initial position and the axis of the inner container is vertical;
(2) in an automatic control mode, the main cylinder drives the swing bracket to turn forwards until the swing bracket touches a guniting position travel limit switch, and the included angle between the axis of the liner and the horizontal plane is 45-55 degrees;
(3) the auxiliary motor is started to drive the inner container to rotate at a constant speed of 10-15rpm, and before the enameling operation is finished, the inner container always rotates at a constant speed;
(4) after the rotation is timed for 30 seconds, the diaphragm pump is started, the glaze slurry is pumped into the inner container, the pulping time is 10 seconds, the compressed air source is started, the inner container is pressurized, the pressure of 0.3MPa is adopted in the initial stage of coating, the air pressure is gradually increased along with the coating, and the pressure is increased to 1.5 times of the initial pressure after the coating is finished;
(5) the main cylinder drives the swing bracket to turn backwards, the turning time is 5 seconds, and the swing bracket stops until the inner container keeps a horizontal position;
(6) stopping overturning, after the inner container continues to rotate and is timed for 20 seconds, driving the swing support to overturn backwards again by the main cylinder, wherein the overturning time is 5 seconds, stopping overturning by the swing support, and forming an included angle of 25-35 degrees between the axis of the inner container and the horizontal plane;
(7) stopping overturning, wherein after the inner container continues to rotate and is timed for 20 seconds, the main cylinder drives the swing bracket to continue to overturn backwards, the overturning time is 5 seconds, the swing bracket stops overturning, and the included angle between the axis of the inner container and the horizontal plane is 60-75 degrees;
(8) stopping overturning, wherein after the inner container continues to rotate and is timed for 20 seconds, the main cylinder drives the swing support to overturn forwards, the overturning time is 5 seconds, the swing support stops overturning, and the included angle between the axis of the inner container and the horizontal plane is 10-15 degrees;
(9) stopping overturning, after the inner container continues to rotate and is timed for 20 seconds, driving the swinging bracket to overturn backwards by the main cylinder until the swinging bracket touches an initial position travel limit switch, and at the moment, the inner container is in an initial position and the axis of the inner container is vertical;
(10) the auxiliary motor is turned off after the inner container continues to rotate for 10 seconds, and the inner container stops rotating;
(11) and under a manual control mode, the pressing air cylinder is lifted, the inner container is taken down from the enameling machine and hung on a drying conveying line.
2. The method as claimed in claim 1, wherein when the workpiece to be enamelled is rotated, swung or stopped at various angles, the signals of the extreme positions are collected except for the initial position and the slurry spraying position, and no external signals are collected when other actions are performed.
CN201911398020.8A 2019-12-30 2019-12-30 Inner container enameling control method of enameling machine Active CN111020581B (en)

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Publication number Priority date Publication date Assignee Title
CN2053551U (en) * 1989-08-17 1990-02-28 辽宁省本溪钢铁公司 Cleaning and spray coating machine of steel ingot mould
CN2102804U (en) * 1991-10-07 1992-04-29 青岛红星电器股份有限公司 Transmission device for spray gun static electricity flarne plating
CN106757021B (en) * 2016-12-27 2019-09-06 山东昊华太阳能有限公司 The vertical dedicated machine for enamelling of collet enamel inner container of Split pressure-bearing solar energy
CN108176833A (en) * 2017-12-15 2018-06-19 浙江海洋大学 A kind of corrosion resistant sanitary sewer and preparation method thereof

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Denomination of invention: An inner tank coating control method of coating machine

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