CN110964386A - Exterior wall coating with high stain resistance and preparation method thereof - Google Patents
Exterior wall coating with high stain resistance and preparation method thereof Download PDFInfo
- Publication number
- CN110964386A CN110964386A CN201911261791.2A CN201911261791A CN110964386A CN 110964386 A CN110964386 A CN 110964386A CN 201911261791 A CN201911261791 A CN 201911261791A CN 110964386 A CN110964386 A CN 110964386A
- Authority
- CN
- China
- Prior art keywords
- exterior wall
- wall coating
- stearate
- parts
- filler
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 82
- 239000011248 coating agent Substances 0.000 title claims abstract description 78
- 238000002360 preparation method Methods 0.000 title abstract description 16
- 239000000839 emulsion Substances 0.000 claims abstract description 85
- 239000000945 filler Substances 0.000 claims abstract description 45
- 239000000314 lubricant Substances 0.000 claims abstract description 43
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 5
- 239000002270 dispersing agent Substances 0.000 claims description 66
- 239000002562 thickening agent Substances 0.000 claims description 43
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 33
- 239000000080 wetting agent Substances 0.000 claims description 29
- 239000006184 cosolvent Substances 0.000 claims description 27
- 239000000463 material Substances 0.000 claims description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
- 238000003756 stirring Methods 0.000 claims description 19
- 229920001909 styrene-acrylic polymer Polymers 0.000 claims description 18
- 238000002156 mixing Methods 0.000 claims description 17
- 229940114926 stearate Drugs 0.000 claims description 16
- 238000006116 polymerization reaction Methods 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 13
- 239000002994 raw material Substances 0.000 claims description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 12
- 239000008116 calcium stearate Substances 0.000 claims description 12
- 235000013539 calcium stearate Nutrition 0.000 claims description 12
- 150000002148 esters Chemical class 0.000 claims description 12
- 239000004408 titanium dioxide Substances 0.000 claims description 12
- 239000000654 additive Substances 0.000 claims description 9
- 239000011256 inorganic filler Substances 0.000 claims description 8
- 229910003475 inorganic filler Inorganic materials 0.000 claims description 8
- 230000000996 additive effect Effects 0.000 claims description 7
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 claims description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 6
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 6
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims description 6
- 238000001914 filtration Methods 0.000 claims description 6
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 claims description 6
- 238000007599 discharging Methods 0.000 claims description 5
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 4
- 239000012766 organic filler Substances 0.000 claims description 4
- 229920002635 polyurethane Polymers 0.000 claims description 4
- 239000004814 polyurethane Substances 0.000 claims description 4
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 claims description 4
- CUVLMZNMSPJDON-UHFFFAOYSA-N 1-(1-butoxypropan-2-yloxy)propan-2-ol Chemical compound CCCCOCC(C)OCC(C)O CUVLMZNMSPJDON-UHFFFAOYSA-N 0.000 claims description 3
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 claims description 3
- JOLQKTGDSGKSKJ-UHFFFAOYSA-N 1-ethoxypropan-2-ol Chemical compound CCOCC(C)O JOLQKTGDSGKSKJ-UHFFFAOYSA-N 0.000 claims description 3
- IBLKWZIFZMJLFL-UHFFFAOYSA-N 1-phenoxypropan-2-ol Chemical compound CC(O)COC1=CC=CC=C1 IBLKWZIFZMJLFL-UHFFFAOYSA-N 0.000 claims description 3
- XYVAYAJYLWYJJN-UHFFFAOYSA-N 2-(2-propoxypropoxy)propan-1-ol Chemical compound CCCOC(C)COC(C)CO XYVAYAJYLWYJJN-UHFFFAOYSA-N 0.000 claims description 3
- JDSQBDGCMUXRBM-UHFFFAOYSA-N 2-[2-(2-butoxypropoxy)propoxy]propan-1-ol Chemical compound CCCCOC(C)COC(C)COC(C)CO JDSQBDGCMUXRBM-UHFFFAOYSA-N 0.000 claims description 3
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 3
- QCAHUFWKIQLBNB-UHFFFAOYSA-N 3-(3-methoxypropoxy)propan-1-ol Chemical compound COCCCOCCCO QCAHUFWKIQLBNB-UHFFFAOYSA-N 0.000 claims description 3
- 239000005995 Aluminium silicate Substances 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000003513 alkali Substances 0.000 claims description 3
- 235000012211 aluminium silicate Nutrition 0.000 claims description 3
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 claims description 3
- 229940063655 aluminum stearate Drugs 0.000 claims description 3
- AGXUVMPSUKZYDT-UHFFFAOYSA-L barium(2+);octadecanoate Chemical compound [Ba+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AGXUVMPSUKZYDT-UHFFFAOYSA-L 0.000 claims description 3
- GWOWVOYJLHSRJJ-UHFFFAOYSA-L cadmium stearate Chemical compound [Cd+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O GWOWVOYJLHSRJJ-UHFFFAOYSA-L 0.000 claims description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 3
- 239000006229 carbon black Substances 0.000 claims description 3
- UQLDLKMNUJERMK-UHFFFAOYSA-L di(octadecanoyloxy)lead Chemical compound [Pb+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O UQLDLKMNUJERMK-UHFFFAOYSA-L 0.000 claims description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 3
- 235000019359 magnesium stearate Nutrition 0.000 claims description 3
- 229940057948 magnesium stearate Drugs 0.000 claims description 3
- 239000010445 mica Substances 0.000 claims description 3
- 229910052618 mica group Inorganic materials 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 229920005573 silicon-containing polymer Polymers 0.000 claims description 3
- 229940080350 sodium stearate Drugs 0.000 claims description 3
- 239000010456 wollastonite Substances 0.000 claims description 3
- 229910052882 wollastonite Inorganic materials 0.000 claims description 3
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims description 3
- FRVCGRDGKAINSV-UHFFFAOYSA-L iron(2+);octadecanoate Chemical compound [Fe+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O FRVCGRDGKAINSV-UHFFFAOYSA-L 0.000 claims description 2
- 229940114930 potassium stearate Drugs 0.000 claims description 2
- ANBFRLKBEIFNQU-UHFFFAOYSA-M potassium;octadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCCCC([O-])=O ANBFRLKBEIFNQU-UHFFFAOYSA-M 0.000 claims description 2
- 239000000454 talc Substances 0.000 claims 1
- 229910052623 talc Inorganic materials 0.000 claims 1
- 230000002035 prolonged effect Effects 0.000 abstract description 3
- 239000004908 Emulsion polymer Substances 0.000 abstract description 2
- 230000008859 change Effects 0.000 abstract description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 27
- 239000007787 solid Substances 0.000 description 20
- 229920000142 Sodium polycarboxylate Polymers 0.000 description 18
- 229920005646 polycarboxylate Polymers 0.000 description 17
- DAFHKNAQFPVRKR-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylpropanoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)C DAFHKNAQFPVRKR-UHFFFAOYSA-N 0.000 description 16
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 16
- 239000003973 paint Substances 0.000 description 15
- -1 acrylic ester Chemical class 0.000 description 14
- 229920000056 polyoxyethylene ether Polymers 0.000 description 13
- 229940051841 polyoxyethylene ether Drugs 0.000 description 13
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 10
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 10
- 230000009477 glass transition Effects 0.000 description 10
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 10
- 229920002545 silicone oil Polymers 0.000 description 10
- 238000012360 testing method Methods 0.000 description 10
- NJVOHKFLBKQLIZ-UHFFFAOYSA-N (2-ethenylphenyl) prop-2-enoate Chemical compound C=CC(=O)OC1=CC=CC=C1C=C NJVOHKFLBKQLIZ-UHFFFAOYSA-N 0.000 description 9
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 9
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 9
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- 239000010936 titanium Substances 0.000 description 8
- 229910052719 titanium Inorganic materials 0.000 description 8
- 239000004816 latex Substances 0.000 description 7
- 229920000126 latex Polymers 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 239000000178 monomer Substances 0.000 description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 230000008014 freezing Effects 0.000 description 3
- 238000007710 freezing Methods 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 239000012874 anionic emulsifier Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 2
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- 238000005070 sampling Methods 0.000 description 2
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 239000011343 solid material Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 2
- 239000002966 varnish Substances 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 description 1
- JKTAIYGNOFSMCE-UHFFFAOYSA-N 2,3-di(nonyl)phenol Chemical compound CCCCCCCCCC1=CC=CC(O)=C1CCCCCCCCC JKTAIYGNOFSMCE-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- CYEJMVLDXAUOPN-UHFFFAOYSA-N 2-dodecylphenol Chemical compound CCCCCCCCCCCCC1=CC=CC=C1O CYEJMVLDXAUOPN-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005489 elastic deformation Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- HIHIPCDUFKZOSL-UHFFFAOYSA-N ethenyl(methyl)silicon Chemical compound C[Si]C=C HIHIPCDUFKZOSL-UHFFFAOYSA-N 0.000 description 1
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- XHQSLVIGPHXVAK-UHFFFAOYSA-K iron(3+);octadecanoate Chemical compound [Fe+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XHQSLVIGPHXVAK-UHFFFAOYSA-K 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 229920001558 organosilicon polymer Polymers 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920003216 poly(methylphenylsiloxane) Polymers 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
- C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09D131/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention uses the polymerized emulsion, the filler, the lubricant and other auxiliary agents to prepare the exterior wall coating with high stain resistance. Compared with the exterior wall coating without the lubricant stearate, the reflection coefficient of the exterior wall coating with the lubricant stearate is improved by 3-31 percent. In addition, the preparation method of the exterior wall coating with high stain resistance adopts a post-addition mode, does not need to change the molecular structure of the emulsion polymer, and is more convenient and feasible to operate; meanwhile, the stain resistance of the exterior wall coating is rapidly and efficiently improved, so that the service life of the exterior wall coating is effectively prolonged, and the coating has extremely high universality and industrial application prospect.
Description
Technical Field
The invention relates to the field of building exterior wall coatings, in particular to an exterior wall coating with high stain resistance and a preparation method thereof.
Background
The building exterior wall coating is a coating coated on the whole building exterior wall, and the main functions of the coating are to decorate and protect the exterior wall, so that the building looks clean and beautiful, and the service life of the building is prolonged. Since exterior wall coatings are exposed to outdoor environments for a long time and air pollution is becoming serious in recent years, these factors place high demands on the stain resistance of exterior wall coatings. If the surface of the exterior wall coating is polluted by dust in the environment shortly after being coated, the exterior wall surface is not neat and bright any more, the decorative effect of the exterior wall coating of the building is lost, and other performance advantages cannot be reflected. Therefore, improving the stain resistance of the exterior wall of a building has become one of the important indexes of the performance of exterior wall coatings.
The existing method for improving the stain resistance of the coating is mainly realized by changing the molecular structure of the polymer from the perspective of emulsion synthesis, has great limitation, cannot be applied to the coating used in various fields and aspects, and the preparation process is complex, thus being not beneficial to the popularization and application of the high stain resistance coating. Therefore, there is a need to develop a new exterior wall coating material with high stain resistance, which is realized by a post-addition method.
Disclosure of Invention
In order to solve the technical problems, the first aspect of the invention provides an exterior wall coating with high stain resistance, which comprises the following raw materials in parts by mass: 40-60 parts of a polymerized emulsion; 18-40 parts of a filler; 1-4 parts of a film forming auxiliary agent; 0.4-1.0 part of thickening agent; 1.0-2.0 parts of cosolvent; 0.1-0.15 parts of wetting agent; 0.4-1.0 part of a dispersing agent; 0-1.5 parts of a lubricant except 0; 200-300 parts of water.
As a preferred technical scheme, the polymerized emulsion is selected from one or more of styrene-acrylic emulsion, pure acrylic emulsion and vinyl acetate-acrylic emulsion.
As a preferred technical scheme, the filler is an inorganic filler and/or an organic filler.
As a preferable technical scheme, the inorganic filler is selected from one or more of titanium dioxide, talcum powder, calcium carbonate, mica powder, barium sulfate, kaolin, white carbon black and wollastonite.
As a preferable technical scheme, the film forming auxiliary agent is selected from one or more of ester alcohol twelve, ethylene glycol butyl ether, propylene glycol methyl ether, propylene glycol ethyl ether, propylene glycol butyl ether, dipropylene glycol monomethyl ether, dipropylene glycol monopropyl ether, dipropylene glycol monobutyl ether, tripropylene glycol n-butyl ether and propylene glycol phenyl ether.
As a preferred technical scheme, the thickening agent is selected from one or more of cellulose thickening agent, alkali-soluble thickening agent and ethylene oxide polyurethane thickening agent.
As a preferred technical scheme, the lubricant is stearate and/or organosilicon polymer.
As a preferable technical scheme, the stearate is selected from one or more of zinc stearate, calcium stearate, barium stearate, lead stearate, magnesium stearate, sodium stearate, aluminum stearate, cadmium stearate, ferric stearate and potassium stearate.
As a preferable technical scheme, the mass ratio of the polymerized emulsion, the filler and the lubricant is 1: (0.4-0.8): (0.002-0.03).
The second aspect of the invention provides a preparation method of the exterior wall coating, which comprises the following steps:
step one, uniformly mixing the polymerization emulsion and the lubricant by mass to obtain a mixed material A;
step two, adding a filler, a wetting agent and a dispersing agent into water, mixing and stirring, adding the mixed material A obtained in the step one, and continuously stirring to obtain a mixed material B;
and step three, adding the film-forming aid, the thickening agent and the cosolvent into the mixed material B obtained in the step two, mixing and stirring, filtering and discharging to obtain the exterior wall coating.
Has the advantages that: the external wall coating with excellent performance is prepared by polymerizing the emulsion, the filler, the lubricant and other auxiliaries. The stain resistance test shows that the reflection coefficient of the exterior wall coating added with a certain lubricant stearate is improved by 3-31% compared with the exterior wall coating not added with the lubricant stearate. In addition, the preparation method of the exterior wall coating with high stain resistance adopts a post-addition mode, does not need to change the molecular structure of the emulsion polymer, and is more convenient and feasible to operate; meanwhile, the stain resistance of the exterior wall coating is rapidly and efficiently improved, so that the service life of the exterior wall coating is effectively prolonged, and the coating has extremely high universality and industrial application prospect.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below, and it is obvious that the drawings in the following description are some embodiments of the present invention, and other drawings can be obtained by those skilled in the art without creative efforts.
FIG. 1 is a graph showing the test results of the stain resistance of the exterior wall of the present invention, wherein ① represents the exterior wall paint obtained in example 1, ② represents the exterior wall paint obtained in example 4, and ③ represents the exterior wall paint obtained in example 5.
Detailed Description
The technical features of the technical solutions provided by the present invention are further clearly and completely described below with reference to the specific embodiments, and the scope of protection is not limited thereto.
The words "preferred", "more preferred", and the like, in the present invention refer to embodiments of the invention that may provide certain benefits, under certain circumstances. However, other embodiments may be preferred, under the same or other circumstances. Furthermore, the recitation of one or more preferred embodiments does not imply that other embodiments are not useful, nor is it intended to exclude other embodiments from the scope of the invention.
In order to solve the technical problems, the first aspect of the invention provides an exterior wall coating with high stain resistance, which comprises the following raw materials in parts by mass: 40-60 parts of a polymerized emulsion; 18-40 parts of a filler; 1-4 parts of a film forming auxiliary agent; 0.4-1.0 part of thickening agent; 1.0-2.0 parts of cosolvent; 0.1-0.15 parts of wetting agent; 0.4-1.0 part of a dispersing agent; 0-1.5 parts of a lubricant except 0; 200-300 parts of water.
In a more preferred embodiment, the exterior wall coating comprises the following raw materials in parts by mass: 50 parts of polymerized emulsion; 30 parts of a filler; 2.5 parts of a film-forming additive; 0.6 part of thickening agent; 1.5 parts of cosolvent; 0.13 part of wetting agent; 0.6 part of a dispersant; 1.0 part of a lubricant; and 250 parts of water.
Polymeric emulsions
The polymerization emulsion is an emulsion obtained by adding an initiator to polymerize monomers dispersed in water.
In a preferred embodiment, the polymeric emulsion is selected from one or more of styrene-acrylic emulsion, and acrylic emulsion.
The styrene-acrylic emulsion is a series of polymerized emulsions obtained by emulsion copolymerization of styrene and acrylic ester monomers. The pure acrylic emulsion is a polymerization emulsion which is obtained by emulsion copolymerization by using all acrylic ester as monomers. The vinyl acetate-acrylic emulsion is a series of polymerized emulsions obtained by emulsion copolymerization of vinyl acetate and acrylic monomers.
In a more preferred embodiment, the polymeric emulsion is a styrene-acrylic emulsion.
In a preferred embodiment, the styrene-acrylic emulsion is selected from one or more of styrene-acrylate emulsion, organic silicon modified styrene-acrylic emulsion, organic fluorine modified styrene-acrylic emulsion, epoxy resin modified styrene-acrylic emulsion and cationic styrene-acrylic emulsion.
In a preferred embodiment, the styrene-acrylic emulsion has a solid content of 48 +/-1 wt%, a viscosity of 800-2500 mPa.S, a pH of 7-9 and a glass transition temperature of 29 +/-1 ℃.
In a more preferred embodiment, the styrene-acrylic emulsion is a styrene-acrylic emulsion having a solid content of 48 wt%, a viscosity of 1650mPa · S, a pH of 8, and a glass transition temperature of 29 ℃.
The solid content is the mass percentage of the rest part of the emulsion in the total amount after the emulsion is dried under specified conditions; the method for detecting the solid content is not particularly limited, and various detection methods well known to those skilled in the art can be used, for example, after the emulsion is dried at 150 ℃ to a constant weight, the solid content is the mass of the emulsion after drying/the mass of the emulsion before drying.
The mPa · S is a viscosity unit, and means a tangent force required to maintain a unit velocity difference between two liquid layers separated from each other by a unit distance; the method for measuring the viscosity is not particularly limited, and various methods known to those skilled in the art, for example, a rotational viscometer, can be used.
The method for measuring the glass transition temperature according to the present invention is not particularly limited, and various measuring methods known to those skilled in the art, such as Differential Scanning Calorimetry (DSC), may be used.
The styrene-acrylic emulsion of the present invention is not particularly limited, and various styrene-acrylic emulsions known to those skilled in the art may be used; the source of the styrene-acrylic emulsion is not particularly limited in the present invention, and can be prepared by conventional synthetic techniques well known to those skilled in the art, such as: mixing water, anionic emulsifier (such as sodium dodecyl benzene sulfonate), acrylic acid, acrylamide, butyl acrylate, styrene, and silane coupling agent (such as one or more of vinyltrimethoxysilane, KH-560, and KH-570), and stirring to obtain monomer emulsion; adding water and anionic emulsifier (such as sodium dodecyl benzene sulfonate) into a reaction device, stirring, mixing uniformly, heating, adding monomer emulsion, initiator (such as tert-butyl hydroperoxide or persulfate) and water for reaction, adding ammonia water to adjust the pH value of the solution to 7, and filtering to remove impurities to obtain the styrene-acrylic emulsion.
In a more preferred embodiment, the styrene-acrylic emulsion is a styrene-acrylate emulsion.
Filler material
The filler is added into the paint, plays a role in framework and filling, and increases the thickness and mechanical properties of a paint film.
In a preferred embodiment, the filler is an inorganic filler and/or an organic filler.
Examples of inorganic fillers include, but are not limited to: titanium dioxide, talcum powder, calcium carbonate, mica powder, barium sulfate, kaolin, white carbon black and wollastonite.
Examples of organic fillers include, but are not limited to: polyethylene wax, polyvinyl chloride resin, polyformaldehyde resin, polypropylene resin, polyacrylic resin and polybutylene resin.
In a more preferred embodiment, the filler is an inorganic filler.
In a still further preferred embodiment, the inorganic filler is titanium dioxide.
The titanium dioxide, namely rutile titanium dioxide, has a CAS number of 13463-67-7, is purchased from Xiangyang dragon python titanium industry Co Ltd, and has a model number of R-996.
Film forming aid
The film forming assistant is one kind of volatile temporary plasticizer capable of promoting the plastic flow and elastic deformation of latex particle and improving its coalescence and may be used in forming film in wide application temperature range.
In a preferred embodiment, the coalescing agent is selected from one or more of the group consisting of ester alcohol dodecanol, ethylene glycol butyl ether, propylene glycol methyl ether, propylene glycol ethyl ether, propylene glycol butyl ether, dipropylene glycol monomethyl ether, dipropylene glycol monopropyl ether, dipropylene glycol monobutyl ether, tripropylene glycol n-butyl ether, and propylene glycol phenyl ether.
In a more preferred embodiment, the coalescent is ester alcohol dodecanol.
The ester alcohol twelve, CAS number 25265-77-4, available from Istman, USA under the TEXANOL model.
Thickening agent
Thickening agents, also known as gelling agents, are substances that increase the viscosity of latex and liquids.
In a preferred embodiment, the thickener is selected from one or more combinations of cellulosic thickeners, alkali soluble thickeners, ethylene oxide polyurethane thickeners.
As examples of cellulosic thickeners, include, but are not limited to: hydroxyethyl cellulose, methyl cellulose, ethyl cellulose, carboxymethyl cellulose, hydroxypropyl methyl cellulose, hydroxypropyl cellulose.
Examples of alkali soluble thickeners include, but are not limited to: dow chemical TT-935, TT-615 and T-9034.
Examples of ethylene oxide polyurethane thickeners include, but are not limited to: the Dow chemical RM2020, RM-8W, RM995, RM 12W.
In a more preferred embodiment, the thickener is a cellulosic thickener.
In a further preferred embodiment, the cellulosic thickener is hydroxyethyl cellulose.
The hydroxyethyl cellulose has a CAS number of 9004-62-0, and is purchased from Shanghai Kahn chemical Co., Ltd, and the type is 854263.
Cosolvent
The cosolvent is a solvent such as ethylene glycol, propylene glycol and the like, is used for softening or dissolving latex particles, and is cooperated with the film-forming assistant to promote the film formation of the latex paint. The cosolvent can effectively prolong the opening time of the latex paint, has a low freezing point, can also reduce the freezing point of the latex paint, and improves the low-temperature stability and the freezing resistance of the latex paint.
The co-solvent is not particularly limited in the present invention, and various co-solvents known to those skilled in the art, such as isopropyl alcohol, benzyl alcohol, ethylene glycol, propylene glycol, and hexylene glycol, can be used.
Wetting agent
Wetting agents are substances that reduce the surface tension or interfacial tension of water, allowing water to spread out on the surface of a solid material, or to penetrate into its surface, thereby wetting the solid material to make it more water-wettable.
In a preferred embodiment, the wetting agent is a non-ionic wetting agent.
In a more preferred embodiment, the nonionic wetting agent is selected from one or more of nonylphenol polyoxyethylene ether, octylphenol polyoxyethylene ether, dodecylphenol polyoxyethylene ether, dinonylphenol polyoxyethylene ether, fatty alcohol polyoxyethylene ether.
In a further preferred embodiment, the non-ionic wetting agent is nonylphenol polyoxyethylene ether.
The CAS number of the polyoxyethylene nonyl phenyl ether is 26027-38-3.
Dispersing agent
The dispersant is a substance added into the system to enable the system to form a uniform suspension.
In a preferred embodiment, the dispersant is an ammonium polycarboxylate dispersant and/or a sodium polycarboxylate dispersant.
In a more preferred embodiment, the dispersant is a mixture of an ammonium polycarboxylate dispersant and a sodium polycarboxylate dispersant.
In a preferred embodiment, the mass ratio of the polycarboxylic acid ammonium salt dispersant to the polycarboxylic acid sodium salt dispersant is 1: (0.5 to 1).
In a more preferred embodiment, the ratio by mass of the polycarboxylic acid ammonium salt dispersant and the polycarboxylic acid sodium salt dispersant is 1: 0.5.
the polycarboxylate dispersant is purchased from Guangzhou Hengyu chemical industry Co., Ltd, and has the model number of SN 5027. The sodium polycarboxylate dispersant is a sodium polycarboxylate dispersant with CAS number of 62601-60-9, and is purchased from Hengyu chemical Co., Ltd, Guangzhou with model number of SN 5040.
Lubricant agent
The lubricant is a substance which enables a paint film formed after the paint is cured to have good lubricity.
In a preferred embodiment, the lubricant is a stearate and/or a silicone polymer.
Examples of stearates include, but are not limited to, zinc stearate, calcium stearate, barium stearate, lead stearate, magnesium stearate, sodium stearate, aluminum stearate, cadmium stearate, iron stearate, stearic acid.
As examples of silicone polymers, including but not limited to: methyl silicone oil, ethyl silicone oil, phenyl silicone oil, methyl hydrogen-containing silicone oil, methyl phenyl silicone oil, methyl chlorophenyl silicone oil, methyl ethoxy silicone oil, methyl trifluoropropyl silicone oil, methyl vinyl silicone oil, methyl hydroxyl silicone oil, ethyl hydrogen-containing silicone oil and hydroxyl hydrogen-containing silicone oil.
In a more preferred embodiment, the lubricant is a stearate.
In a further preferred embodiment, the stearate is calcium stearate.
The calcium stearate is a calcium stearate solution, is Basf 1097A, and has the solid content of 50 +/-1 wt% and the average solid content of 50 wt%.
In a preferred embodiment, the mass ratio of the polymeric emulsion, the filler and the lubricant is 1: (0.4-0.8): (0.002-0.03).
In a more preferred embodiment, the mass ratio of the polymeric emulsion, the filler and the lubricant is 1: 0.6: 0.02.
the inventors creatively added stearate to the system and unexpectedly found in experimental exploration that when the mass ratio of the polymeric emulsion, filler and lubricant is 1: (0.4-0.8): (0.002-0.03), the stain resistance of the prepared exterior wall coating is obviously improved. The inventor conjectures the possible reason that, on one hand, linear hydrocarbon chains on stearate molecules can be intertwined with polymer molecular chains in the coating, so that the crosslinking density of the system is improved, the linear high molecular polymer is changed into a three-dimensional structure network, the hardness and compactness of a paint film are improved, and the stain resistance is further improved; on the other hand, a certain amount of stearate and filler can fill up gaps in a network of a system structure, movement of external pollutants into the system is limited, and due to the inherent fat characteristic of the stearate, the surface of the coating is smooth and fine and is not easily adsorbed by the pollutants, so that the stain resistance of the exterior wall coating is remarkably improved.
The second aspect of the invention provides a preparation method of the exterior wall coating, which comprises the following steps:
step one, uniformly mixing the polymerization emulsion and the lubricant by mass to obtain a mixed material A;
step two, adding a filler, a wetting agent and a dispersing agent into water, mixing and stirring, adding the mixed material A obtained in the step one, and continuously stirring to obtain a mixed material B;
and step three, adding the film-forming aid, the thickening agent and the cosolvent into the mixed material B obtained in the step two, mixing and stirring, filtering and discharging to obtain the exterior wall coating.
In a preferred embodiment, the preparation method of the exterior wall coating comprises the following steps:
step one, uniformly mixing the polymerization emulsion and the lubricant by mass to obtain a mixed material A;
step two, adding the filler, the wetting agent and the dispersing agent into water under stirring at a rotating speed of 650 revolutions per minute, adding the mixed material A obtained in the step one after mixing and stirring, and continuously stirring for 30 minutes to obtain a mixed material B;
and step three, adding the film-forming aid, the thickening agent and the cosolvent into the mixed material B obtained in the step two, mixing and stirring, filtering and discharging to obtain the exterior wall coating.
The present invention will now be described in detail by way of examples, and the starting materials used are commercially available unless otherwise specified.
Examples
Example 1
The embodiment 1 of the invention provides an exterior wall coating with high stain resistance, which comprises the following raw materials in parts by mass: 50 parts of polymerized emulsion; 30 parts of a filler; 2.5 parts of a film-forming additive; 0.6 part of thickening agent; 1.5 parts of cosolvent; 0.13 part of wetting agent; 0.6 part of a dispersant; 1.0 part of a lubricant; and 250 parts of water.
The polymerization emulsion is styrene-acrylate emulsion, the solid content is 48 wt%, the viscosity is 1650 mPa.S, the pH is 8, and the glass transition temperature is 29 ℃. The filler is titanium dioxide, the CAS number is 13463-67-7, and the filler is purchased from Xiangyang dragon python titanium industry Co Ltd, and the model is R-996. The coalescing agent is ester alcohol twelve, CAS number 25265-77-4, purchased from Istman, USA, and having a TEXANOL model. The thickener is hydroxyethyl cellulose, purchased from Shanghai Kaiyn chemical Co., Ltd., model number 854263. The cosolvent is propylene glycol; the wetting agent is nonylphenol polyoxyethylene ether with CAS number 26027-38-3. The dispersant is a mixture of an ammonium polycarboxylate dispersant and a sodium polycarboxylate dispersant, and the mass ratio of the ammonium polycarboxylate dispersant to the sodium polycarboxylate dispersant is 1: 0.5. the lubricant was a calcium stearate solution, basf 1097A, with an average solids content of 50 wt%.
The preparation method of the exterior wall coating with high stain resistance comprises the following steps:
step one, uniformly mixing the polymerization emulsion and the lubricant by mass to obtain a mixed material A;
step two, adding the filler, the wetting agent and the dispersing agent into water under stirring at a rotating speed of 650 revolutions per minute, adding the mixed material A obtained in the step one after mixing and stirring, and continuously stirring for 30 minutes to obtain a mixed material B;
and step three, adding the film-forming aid, the thickening agent and the cosolvent into the mixed material B obtained in the step two, mixing and stirring, filtering and discharging to obtain the exterior wall coating.
Example 2
The embodiment 2 of the invention provides an exterior wall coating with high stain resistance, which comprises the following raw materials in parts by mass: 40 parts of polymerized emulsion; 18 parts of a filler; 1 part of a film-forming assistant; 0.4 part of thickening agent; 1.0 part of cosolvent; 0.1 part of wetting agent; 0.4 part of a dispersant; 0.1 part of lubricant; 200 parts of water.
The polymerization emulsion is styrene-acrylate emulsion, the solid content is 48 wt%, the viscosity is 1650 mPa.S, the pH is 8, and the glass transition temperature is 29 ℃. The filler is titanium dioxide, the CAS number is 13463-67-7, and the filler is purchased from Xiangyang dragon python titanium industry Co Ltd, and the model is R-996. The coalescing agent is ester alcohol twelve, CAS number 25265-77-4, purchased from Istman, USA, and having a TEXANOL model. The thickener is hydroxyethyl cellulose, purchased from Shanghai Kaiyn chemical Co., Ltd., model number 854263. The cosolvent is propylene glycol; the wetting agent is nonylphenol polyoxyethylene ether with CAS number 26027-38-3. The dispersant is a mixture of an ammonium polycarboxylate dispersant and a sodium polycarboxylate dispersant, and the mass ratio of the ammonium polycarboxylate dispersant to the sodium polycarboxylate dispersant is 1: 0.5. the lubricant was a calcium stearate solution, basf 1097A, with an average solids content of 50 wt%.
The preparation method of the exterior wall coating with high stain resistance is the same as that of the example 1.
Example 3
The embodiment 3 of the invention provides an exterior wall coating with high stain resistance, which comprises the following raw materials in parts by mass: 60 parts of a polymerization emulsion; 40 parts of a filler; 4 parts of a film-forming assistant; 1.0 part of thickening agent; 2.0 parts of cosolvent; 0.15 part of wetting agent; 1.0 part of a dispersant; 1.5 parts of a lubricant; 300 parts of water.
The polymerization emulsion is styrene-acrylate emulsion, the solid content is 48 wt%, the viscosity is 1650 mPa.S, the pH is 8, and the glass transition temperature is 29 ℃. The filler is titanium dioxide, the CAS number is 13463-67-7, and the filler is purchased from Xiangyang dragon python titanium industry Co Ltd, and the model is R-996. The coalescing agent is ester alcohol twelve, CAS number 25265-77-4, purchased from Istman, USA, and having a TEXANOL model. The thickener is hydroxyethyl cellulose, purchased from Shanghai Kaiyn chemical Co., Ltd., model number 854263. The cosolvent is propylene glycol; the wetting agent is nonylphenol polyoxyethylene ether with CAS number 26027-38-3. The dispersant is a mixture of an ammonium polycarboxylate dispersant and a sodium polycarboxylate dispersant, and the mass ratio of the ammonium polycarboxylate dispersant to the sodium polycarboxylate dispersant is 1: 0.5. the lubricant was a calcium stearate solution, basf 1097A, with an average solids content of 50 wt%.
The preparation method of the exterior wall coating with high stain resistance is the same as that of the example 1.
Example 4
Embodiment 4 of the present invention provides an exterior wall coating with high stain resistance, which comprises the following raw materials by mass: 50 parts of polymerized emulsion; 30 parts of a filler; 2.5 parts of a film-forming additive; 0.6 part of thickening agent; 1.5 parts of cosolvent; 0.13 part of wetting agent; 0.6 part of a dispersant; 0.5 part of a lubricant; and 250 parts of water.
The polymerization emulsion is styrene-acrylate emulsion, the solid content is 48 wt%, the viscosity is 1650 mPa.S, the pH is 8, and the glass transition temperature is 29 ℃. The filler is titanium dioxide, the CAS number is 13463-67-7, and the filler is purchased from Xiangyang dragon python titanium industry Co Ltd, and the model is R-996. The coalescing agent is ester alcohol twelve, CAS number 25265-77-4, purchased from Istman, USA, and having a TEXANOL model. The thickener is hydroxyethyl cellulose, purchased from Shanghai Kaiyn chemical Co., Ltd., model number 854263. The cosolvent is propylene glycol; the wetting agent is nonylphenol polyoxyethylene ether with CAS number 26027-38-3. The dispersant is a mixture of an ammonium polycarboxylate dispersant and a sodium polycarboxylate dispersant, and the mass ratio of the ammonium polycarboxylate dispersant to the sodium polycarboxylate dispersant is 1: 0.5. the lubricant was a calcium stearate solution, basf 1097A, with an average solids content of 50 wt%.
The preparation method of the exterior wall coating with high stain resistance is the same as that of the example 1.
Example 5
Embodiment 5 of the present invention provides an exterior wall coating with high stain resistance, which comprises the following raw materials by mass: 50 parts of polymerized emulsion; 30 parts of a filler; 2.5 parts of a film-forming additive; 0.6 part of thickening agent; 1.5 parts of cosolvent; 0.13 part of wetting agent; 0.6 part of a dispersant; and 250 parts of water.
The polymerization emulsion is styrene-acrylate emulsion, the solid content is 48 wt%, the viscosity is 1650 mPa.S, the pH is 8, and the glass transition temperature is 29 ℃. The filler is titanium dioxide, the CAS number is 13463-67-7, and the filler is purchased from Xiangyang dragon python titanium industry Co Ltd, and the model is R-996. The coalescing agent is ester alcohol twelve, CAS number 25265-77-4, purchased from Istman, USA, and having a TEXANOL model. The thickener is hydroxyethyl cellulose, purchased from Shanghai Kaiyn chemical Co., Ltd., model number 854263. The cosolvent is propylene glycol; the wetting agent is nonylphenol polyoxyethylene ether with CAS number 26027-38-3. The dispersant is a mixture of an ammonium polycarboxylate dispersant and a sodium polycarboxylate dispersant, and the mass ratio of the ammonium polycarboxylate dispersant to the sodium polycarboxylate dispersant is 1: 0.5.
the preparation method of the exterior wall coating with high stain resistance is the same as that of the example 1.
Example 6
Embodiment 6 of the present invention provides an exterior wall coating with high stain resistance, which comprises the following raw materials by mass: 50 parts of polymerized emulsion; 17.5 parts of a filler; 2.5 parts of a film-forming additive; 0.6 part of thickening agent; 1.5 parts of cosolvent; 0.13 part of wetting agent; 0.6 part of a dispersant; 1.0 part of a lubricant; and 250 parts of water.
The polymerization emulsion is styrene-acrylate emulsion, the solid content is 48 wt%, the viscosity is 1650 mPa.S, the pH is 8, and the glass transition temperature is 29 ℃. The filler is titanium dioxide, the CAS number is 13463-67-7, and the filler is purchased from Xiangyang dragon python titanium industry Co Ltd, and the model is R-996. The coalescing agent is ester alcohol twelve, CAS number 25265-77-4, purchased from Istman, USA, and having a TEXANOL model. The thickener is hydroxyethyl cellulose, purchased from Shanghai Kaiyn chemical Co., Ltd., model number 854263. The cosolvent is propylene glycol; the wetting agent is nonylphenol polyoxyethylene ether with CAS number 26027-38-3. The dispersant is a mixture of an ammonium polycarboxylate dispersant and a sodium polycarboxylate dispersant, and the mass ratio of the ammonium polycarboxylate dispersant to the sodium polycarboxylate dispersant is 1: 0.5. the lubricant was a calcium stearate solution, basf 1097A, with an average solids content of 50 wt%.
The preparation method of the exterior wall coating with high stain resistance is the same as that of the example 1.
Example 7
Embodiment 7 of the present invention provides an exterior wall coating with high stain resistance, which comprises the following raw materials by mass: 50 parts of polymerized emulsion; 30 parts of a filler; 2.5 parts of a film-forming additive; 0.6 part of thickening agent; 1.5 parts of cosolvent; 0.13 part of wetting agent; 0.6 part of a dispersant; 0.05 part of a lubricant; and 250 parts of water.
The polymerization emulsion is styrene-acrylate emulsion, the solid content is 48 wt%, the viscosity is 1650 mPa.S, the pH is 8, and the glass transition temperature is 29 ℃. The filler is titanium dioxide, the CAS number is 13463-67-7, and the filler is purchased from Xiangyang dragon python titanium industry Co Ltd, and the model is R-996. The coalescing agent is ester alcohol twelve, CAS number 25265-77-4, purchased from Istman, USA, and having a TEXANOL model. The thickener is hydroxyethyl cellulose, purchased from Shanghai Kaiyn chemical Co., Ltd., model number 854263. The cosolvent is propylene glycol; the wetting agent is nonylphenol polyoxyethylene ether with CAS number 26027-38-3. The dispersant is a mixture of an ammonium polycarboxylate dispersant and a sodium polycarboxylate dispersant, and the mass ratio of the ammonium polycarboxylate dispersant to the sodium polycarboxylate dispersant is 1: 0.5. the lubricant was a calcium stearate solution, basf 1097A, with an average solids content of 50 wt%.
The preparation method of the exterior wall coating with high stain resistance is the same as that of the example 1.
Evaluation of Performance
And (3) testing the stain resistance: sampling is carried out on the exterior wall coating with high stain resistance obtained in the examples 1-7 according to a sampling method of GB/T3186-2006 sample raw materials for colored paint, varnish and colored paint and varnish. Using 120 mu m and 80 mu m wire rods to prepare films on a non-asbestos fiber cement board with the size of 150mm multiplied by 70mm multiplied by 4mm in two steps, wherein the time interval of the two coating steps is 6h, preparing three samples for each sample, then placing the samples under standard test conditions for curing for 168h, and carrying out two-cycle test according to a method B (oven rapid method) in GB/T9780-2013 'building coating stain resistance test method', without ultraviolet crosslinking. Wherein, the stain resistance of the coating of the exterior wall coating is calculated according to the formula (1):
in the formula: xOuter cover-a reflectance reduction rate of the exterior wall paint coating; a-initial average reflection coefficient of the coating; b-average reflection coefficient of the coating after contamination test. The arithmetic mean of the three test panels was taken as the result, 3 significant values were retained, and the relative error of the replicates of the three test panels should be no greater than 15%, the results are shown in table 1.
Table 1 results of performance testing
The exterior wall coating with high stain resistance obtained in the embodiments 1-3 meets the requirements of the industry standard GB/T9755-.
The experimental results are combined to show that the external wall coating with excellent performance is prepared by using the polymeric emulsion, the filler, the lubricant and other additives, and the stain resistance test shows that the reduction rate of the reflection coefficient of the external wall coating without adding the lubricant stearate is 24.3% as shown in ③ sample in the attached drawing 1, the reduction rate of the reflection coefficient of the external wall coating with 0.5 mass part of the lubricant added in the embodiment 4 of the invention is 21.1% as shown in ② sample in the attached drawing 1, and the reduction rate of the reflection coefficient of the external wall coating with 1.0 mass part of the lubricant stearate added in the embodiment 1 of the invention is only 16.7% as shown in ① sample in the attached drawing 1, so that the stain resistance of the sample is improved by 31% compared with the embodiment 5 without adding the lubricant stearate.
The foregoing examples are merely illustrative and serve to explain some of the features of the method of the present invention. The appended claims are intended to claim as broad a scope as is contemplated, and the examples presented herein are merely illustrative of selected implementations in accordance with all possible combinations of examples. Accordingly, it is applicants' intention that the appended claims are not to be limited by the choice of examples illustrating features of the invention. The invention is not limited to the embodiments described above, but rather, many modifications and variations may be made by one skilled in the art without departing from the scope of the invention.
Claims (10)
1. The exterior wall coating with high stain resistance is characterized by comprising the following raw materials in parts by mass: 40-60 parts of a polymerized emulsion; 18-40 parts of a filler; 1-4 parts of a film forming auxiliary agent; 0.4-1.0 part of thickening agent; 1.0-2.0 parts of cosolvent; 0.1-0.15 parts of wetting agent; 0.4-1.0 part of a dispersing agent; 0-1.5 parts of a lubricant except 0; 200-300 parts of water.
2. The exterior wall coating of claim 1, wherein the polymerized emulsion is selected from one or more of styrene-acrylic emulsion, and acrylic emulsion.
3. The exterior wall coating of claim 1, wherein the filler is an inorganic filler and/or an organic filler.
4. The exterior wall coating of claim 3, wherein the inorganic filler is selected from one or more of titanium dioxide, talc, calcium carbonate, mica powder, barium sulfate, kaolin, white carbon black, and wollastonite.
5. The exterior wall coating of claim 1, wherein the film forming additive is selected from the group consisting of ester alcohol dodecanol, ethylene glycol butyl ether, propylene glycol methyl ether, propylene glycol ethyl ether, propylene glycol butyl ether, dipropylene glycol monomethyl ether, dipropylene glycol monopropyl ether, dipropylene glycol monobutyl ether, tripropylene glycol n-butyl ether, and propylene glycol phenyl ether in combination with one or more other film forming additives.
6. The exterior wall coating of claim 1, wherein the thickener is selected from one or more of a cellulosic thickener, an alkali soluble thickener, and an ethylene oxide polyurethane thickener.
7. The exterior wall coating of claim 1, wherein the lubricant is a stearate and/or a silicone polymer.
8. The exterior wall coating of claim 7, wherein said stearate is selected from one or more of zinc stearate, calcium stearate, barium stearate, lead stearate, magnesium stearate, sodium stearate, aluminum stearate, cadmium stearate, iron stearate, and potassium stearate.
9. The exterior wall coating of any one of claims 1 to 8, wherein the mass ratio of the polymerized emulsion, the filler and the lubricant is 1: (0.4-0.8): (0.002-0.03).
10. A method for preparing the exterior wall coating according to any one of claims 1 to 9, comprising the steps of:
step one, uniformly mixing the polymerization emulsion and the lubricant by mass to obtain a mixed material A;
step two, adding a filler, a wetting agent and a dispersing agent into water, mixing and stirring, adding the mixed material A obtained in the step one, and continuously stirring to obtain a mixed material B;
and step three, adding the film-forming aid, the thickening agent and the cosolvent into the mixed material B obtained in the step two, mixing and stirring, filtering and discharging to obtain the exterior wall coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911261791.2A CN110964386A (en) | 2019-12-10 | 2019-12-10 | Exterior wall coating with high stain resistance and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911261791.2A CN110964386A (en) | 2019-12-10 | 2019-12-10 | Exterior wall coating with high stain resistance and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110964386A true CN110964386A (en) | 2020-04-07 |
Family
ID=70033607
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201911261791.2A Pending CN110964386A (en) | 2019-12-10 | 2019-12-10 | Exterior wall coating with high stain resistance and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110964386A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115260820A (en) * | 2022-08-18 | 2022-11-01 | 上海保立佳新材料有限公司 | High-toughness composite cellulose for coating and application thereof |
| CN116102962A (en) * | 2021-11-11 | 2023-05-12 | 江苏凯伦建材股份有限公司 | Water-based polyurethane waterproof coating and preparation method and application thereof |
| CN116120792A (en) * | 2023-01-06 | 2023-05-16 | 佛山市科切路威环保科技有限公司 | Paint capable of improving paint film hardness and weather resistance and processing technology |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103666150A (en) * | 2013-12-06 | 2014-03-26 | 青岛益群漆业集团有限公司 | Mildew-resistant anti-algae pure acrylic emulsion exterior-wall paint |
| CN103821305A (en) * | 2014-01-13 | 2014-05-28 | 东营瑞源特种建筑材料有限公司 | Antipollution wall flexible stone decorating material and production method thereof |
| CN103881578A (en) * | 2012-12-21 | 2014-06-25 | 深圳市嘉达高科产业发展有限公司 | Color reflective heat-insulation exterior wall elastic coating and preparation method thereof |
| CN105131769A (en) * | 2015-09-10 | 2015-12-09 | 三棵树涂料股份有限公司 | Special dull finish paint for sand textured external wall coating and preparation method of special dull finish paint |
| CN106189607A (en) * | 2015-04-30 | 2016-12-07 | 立邦涂料（中国）有限公司 | A kind of bottom surface unification elastic coating and its preparation method and application |
| CN106905727A (en) * | 2017-03-20 | 2017-06-30 | 山东绿拓涂料科技有限公司 | Inorganic interior wall coating of functional form and preparation method thereof |
| CN107236388A (en) * | 2017-07-25 | 2017-10-10 | 合肥欧仕嘉机电设备有限公司 | A kind of thermostable heat-isolating coating and preparation method thereof |
| CN109593470A (en) * | 2018-12-04 | 2019-04-09 | 台州市中凯实业有限公司 | Natural real stone paint coating and preparation method thereof |
-
2019
- 2019-12-10 CN CN201911261791.2A patent/CN110964386A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103881578A (en) * | 2012-12-21 | 2014-06-25 | 深圳市嘉达高科产业发展有限公司 | Color reflective heat-insulation exterior wall elastic coating and preparation method thereof |
| CN103666150A (en) * | 2013-12-06 | 2014-03-26 | 青岛益群漆业集团有限公司 | Mildew-resistant anti-algae pure acrylic emulsion exterior-wall paint |
| CN103821305A (en) * | 2014-01-13 | 2014-05-28 | 东营瑞源特种建筑材料有限公司 | Antipollution wall flexible stone decorating material and production method thereof |
| CN106189607A (en) * | 2015-04-30 | 2016-12-07 | 立邦涂料（中国）有限公司 | A kind of bottom surface unification elastic coating and its preparation method and application |
| CN105131769A (en) * | 2015-09-10 | 2015-12-09 | 三棵树涂料股份有限公司 | Special dull finish paint for sand textured external wall coating and preparation method of special dull finish paint |
| CN106905727A (en) * | 2017-03-20 | 2017-06-30 | 山东绿拓涂料科技有限公司 | Inorganic interior wall coating of functional form and preparation method thereof |
| CN107236388A (en) * | 2017-07-25 | 2017-10-10 | 合肥欧仕嘉机电设备有限公司 | A kind of thermostable heat-isolating coating and preparation method thereof |
| CN109593470A (en) * | 2018-12-04 | 2019-04-09 | 台州市中凯实业有限公司 | Natural real stone paint coating and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116102962A (en) * | 2021-11-11 | 2023-05-12 | 江苏凯伦建材股份有限公司 | Water-based polyurethane waterproof coating and preparation method and application thereof |
| CN115260820A (en) * | 2022-08-18 | 2022-11-01 | 上海保立佳新材料有限公司 | High-toughness composite cellulose for coating and application thereof |
| CN116120792A (en) * | 2023-01-06 | 2023-05-16 | 佛山市科切路威环保科技有限公司 | Paint capable of improving paint film hardness and weather resistance and processing technology |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110964386A (en) | Exterior wall coating with high stain resistance and preparation method thereof | |
| US9688861B2 (en) | Inorganic dry powder building coating and preparing method therefor | |
| CN110078867B (en) | Core-shell pure acrylic emulsion for exterior wall coating and preparation method and application thereof | |
| CN107140911B (en) | The polymer cement waterproof paint and its preparation method and application that can be scratched | |
| CN106590268A (en) | Real-stone paint and preparation method thereof | |
| JP2002524604A (en) | Curable silicone soil release coatings and articles | |
| CN113943503B (en) | Two-component polymer cement-based waterproof coating composition, two-component polymer cement-based waterproof coating, and preparation method and application thereof | |
| CN1395600A (en) | Silicatic coating mass with improved stability | |
| US4121000A (en) | Coating composition comprising a polysiloxane resin-forming precondensate, a fluorocarbon polymer, an epoxy resin, a silicone fluid, and an inorganic hardening agent | |
| CN1281643C (en) | Silicofluoride containing acrylic copolyresin emulsion and paint | |
| CN101372565A (en) | High adhesion strength porcelain-based coating | |
| CN102559023A (en) | Scratch resistance waterborne polyurethane coating and preparation method thereof | |
| CN114395301A (en) | Anti-scratch stain-resistant interior wall coating and preparation method thereof | |
| CN109929130A (en) | High water droplet contact angle, cured film easily then and preparation method thereof | |
| CN109370353B (en) | Environment-friendly fluorine modified styrene-acrylic emulsion coating used in winter and preparation method thereof | |
| CN108997879A (en) | Fluorine-containing superhydrophilic self-cleaning coating | |
| CN105505086A (en) | Acid-rain-resistant dustproof finish-coat paint and preparation method thereof | |
| CN1195030C (en) | Self-cleaning external wall organic coating for building and preparing method thereof | |
| CN107298917A (en) | A kind of elastic stain-resistant exterior wall coating and preparation method thereof | |
| TWI591042B (en) | Aqueous resin dispenser for mortar, mortar composition and cured mortar | |
| US8455585B2 (en) | Water repellant compositions and coatings | |
| CN115286999A (en) | GPG (general purpose glass cement) plaster rubber asphalt sealing waterproof coating and production process thereof | |
| CN103409025A (en) | Environment-friendly multi-effect nano water-based coating | |
| CN108707375B (en) | Polymer cement-based waterproof coating and preparation method thereof | |
| CN105820285B (en) | A kind of metachloroethylene copolymer latex of salt fog resistance |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20200407 |
|
| RJ01 | Rejection of invention patent application after publication |