CN110951271A - Recoverable environment-friendly bamboo fiber tableware - Google Patents

Recoverable environment-friendly bamboo fiber tableware Download PDF

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Publication number
CN110951271A
CN110951271A CN201911257526.7A CN201911257526A CN110951271A CN 110951271 A CN110951271 A CN 110951271A CN 201911257526 A CN201911257526 A CN 201911257526A CN 110951271 A CN110951271 A CN 110951271A
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China
Prior art keywords
parts
bamboo fiber
bamboo
friendly
environment
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Withdrawn
Application number
CN201911257526.7A
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Chinese (zh)
Inventor
段春雨
李思钰
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Xuzhou Meixin Biomaterials Co Ltd
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Xuzhou Meixin Biomaterials Co Ltd
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Priority to CN201911257526.7A priority Critical patent/CN110951271A/en
Publication of CN110951271A publication Critical patent/CN110951271A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00Compositions of lignin-containing materials
    • C08L97/02Lignocellulosic material, e.g. wood, straw or bagasse
    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47GHOUSEHOLD OR TABLE EQUIPMENT
    • A47G19/00Table service
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Abstract

The invention relates to the technical field of environment-friendly tableware, and discloses recyclable environment-friendly bamboo fiber tableware, which comprises the following raw materials in parts by weight: 100-150 parts of enzymolysis bamboo fiber, 50-70 parts of deionized water, 8-15 parts of kaolin, 15-20 parts of sodium silicate, 25-35 parts of thermosetting composite resin, 5-10 parts of starch and 12-15 parts of alumina powder; the enzymolysis bamboo fiber is prepared by the following method: soaking bamboo chips in a sodium hydroxide solution for 1-3 hours, washing with deionized water, soaking in a hydrochloric acid solution for 1-3 hours, washing with deionized water, steaming in a high-pressure steamer at the steaming temperature of 110-130 ℃ for 50-70 min to obtain steamed bamboo chips, soaking the steamed bamboo chips in a decomposition enzyme solution for 2-3 hours, and spin-drying in a centrifuge to obtain the enzymatic hydrolysis bamboo fibers. The recyclable environment-friendly bamboo fiber tableware is non-toxic, harmless, green and healthy, biodegradable, convenient to recycle and has the advantages of energy conservation and environmental protection.

Description

Recoverable environment-friendly bamboo fiber tableware
Technical Field
The invention relates to the technical field of environment-friendly tableware, in particular to recyclable environment-friendly bamboo fiber tableware.
Background
The bamboo fiber is a cellulose fiber extracted from naturally growing bamboos, is the fifth natural fiber after cotton, hemp, wool and silk, has the characteristics of good air permeability, instant water absorption, strong wear resistance, good dyeing property and the like, has the functions of natural antibiosis, bacteriostasis, mite removal, deodorization and ultraviolet resistance, and is a natural environment-friendly green fiber in the true sense.
Most of the existing catering utensils are made of food-grade plastics, ceramics, glass and the like, and are also made of natural bamboo bodies. With the increasing awareness of environmental protection, renewable natural plant fibers are widely used in the field of materials technology. Because the yield of the bamboo fiber is high and the raw material bamboo is renewable, the bamboo fiber is greatly beneficial to environmental protection if the bamboo fiber is used for preparing tableware. Compared with the traditional material tableware, the bamboo fiber tableware focuses on health and environmental protection concepts, and has no potential influence and harm on human bodies. After the environment-friendly material is used, the environment-friendly material can be discarded and degraded in the natural environment, and is a first-choice green product essential for eliminating white pollution, protecting resources and protecting the ecological environment in daily life.
Disclosure of Invention
Technical problem to be solved
Aiming at the defects of the prior art, the invention provides a recyclable environment-friendly bamboo fiber tableware which has the advantages of no toxicity, no harm, recoverability, environmental protection and the like, and solves the problems that food-grade tableware made of plastics, ceramics and glass is not energy-saving and environment-friendly and has hidden health hazards in the prior art.
(II) technical scheme
In order to realize the purposes of no toxicity, no harm, recoverability and environmental protection, the invention provides the following technical scheme: the recyclable environment-friendly bamboo fiber tableware comprises the following raw materials in parts by weight:
100-150 parts of enzymolysis bamboo fiber, 50-70 parts of deionized water, 8-15 parts of kaolin, 15-20 parts of sodium silicate, 25-35 parts of thermosetting composite resin, 5-10 parts of starch and 12-15 parts of alumina powder;
the enzymolysis bamboo fiber is prepared by the following method: soaking bamboo chips in a sodium hydroxide solution for 1-3 hours, washing with deionized water, soaking in a hydrochloric acid solution for 1-3 hours, washing with deionized water, steaming in a high-pressure steamer at the steaming temperature of 110-130 ℃ for 50-70 min to obtain steamed bamboo chips, soaking the steamed bamboo chips in a decomposition enzyme solution for 2-3 hours, and spin-drying in a centrifuge to obtain the enzymatic hydrolysis bamboo fibers.
Preferably, the mass concentration of the sodium hydroxide solution is 4-6%.
Preferably, the mass concentration of the hydrochloric acid solution is 3-5%.
Preferably, the length of the bamboo chips is 10-15 cm, and the width of the bamboo chips is 0.3-0.6 cm.
Preferably, the mass concentration of the lyase solution is 5-10%.
Preferably, the rotating speed of the centrifugal machine is 600-1000 r/min, and the centrifugal time is 5-10 min.
The recyclable environment-friendly bamboo fiber tableware comprises the following preparation steps:
s1: adding the enzymolysis bamboo fiber into a ball mill, and uniformly grinding to obtain fiber powder;
s2: putting the fiber powder and deionized water in the step S1 into a mixer, and mixing and stirring at the speed of 500-700 rpm for 3-5 min at the temperature of 100-130 ℃;
s3: adding kaolin, sodium silicate, thermosetting composite resin, starch and alumina powder into the mixer in the step S2, stirring at the speed of 800-1200 rpm at the temperature of 120-160 ℃ for 2-5 min, and cooling to normal temperature to obtain a mixture;
s4: adding the mixture obtained in the step S3 into a mold, performing hydraulic mold pressing and curing for 1-3 min at 120-150 ℃ by using a hydraulic machine, discharging gas for 5-8 times to prepare a blank, and removing peripheral burrs;
s5: cleaning the blank in the step S4 by alcohol, uniformly spraying a layer of transparent protective film on the outer surface of the blank after drying, and drying to obtain a semi-finished product;
s6: and (5) irradiating the semi-finished product in the step S5 with ultraviolet rays for sterilization treatment to obtain a bamboo fiber tableware finished product.
Preferably, the rotation speed of the ball mill in the step S1 is 200-300 r/min, and the grinding time is 15-30 min.
Preferably, the drying temperature in the step S5 is 110 to 130 ℃.
Preferably, the thickness of the protective film in the step S5 is 0.03-0.06 mm.
(III) advantageous effects
Compared with the prior art, the invention provides a recyclable environment-friendly bamboo fiber tableware, which has the following beneficial effects:
according to the recyclable environment-friendly bamboo fiber tableware, enzymolysis bamboo fibers are used as main components, kaolin, sodium silicate, thermosetting composite resin, starch and alumina powder are added as auxiliary components, and the prepared bamboo fiber tableware is not only non-toxic, harmless, green and healthy, but also biodegradable, convenient to recycle and has the advantages of energy conservation and environmental protection through the processes of grinding, mixing and stirring, pressing, spraying, sterilizing and the like.
Detailed Description
The invention discloses a recyclable environment-friendly bamboo fiber tableware, which can be realized by appropriately improving process parameters by referring to the contents in the field. It is expressly intended that all such similar substitutes and modifications which would be obvious to one skilled in the art are deemed to be included in the invention. While the invention has been described in terms of preferred embodiments, it will be apparent to those skilled in the art that the present technology can be practiced and applied with modification, or with appropriate modification and combination, without departing from the spirit and scope of the invention. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention. The invention is further illustrated by the following examples.
Example one
The recyclable environment-friendly bamboo fiber tableware comprises the following raw materials in parts by weight:
100 parts of enzymolysis bamboo fiber, 50 parts of deionized water, 8 parts of kaolin, 15 parts of sodium silicate, 25 parts of thermosetting composite resin, 5 parts of starch and 12 parts of alumina powder;
the enzymolysis bamboo fiber is prepared by the following method: soaking bamboo chips in sodium hydroxide solution for 1h, washing with deionized water, soaking in hydrochloric acid solution for 1h, washing with deionized water, steaming in a high-pressure steamer at 110 deg.C for 50min to obtain steamed bamboo chips, soaking in decomposition enzyme solution for 2h, and centrifuging to obtain enzymolysis bamboo fiber.
The mass concentration of the sodium hydroxide solution was 4%.
The mass concentration of the hydrochloric acid solution was 3%.
The bamboo chips have a length of 10cm and a width of 0.3 cm.
The mass concentration of the lytic enzyme solution was 5%.
The rotation speed of the centrifuge is 600r/min, and the centrifugation time is 5 min.
The recyclable environment-friendly bamboo fiber tableware comprises the following preparation steps:
s1: adding the enzymolysis bamboo fiber into a ball mill, and uniformly grinding to obtain fiber powder;
s2: putting the fiber powder and deionized water in the step S1 into a mixer, and mixing and stirring at the speed of 500rpm at 100 ℃ for 3 min;
s3: adding kaolin, sodium silicate, thermosetting composite resin, starch and alumina powder into the mixer in the step S2, stirring at the speed of 800rpm at 120 ℃ for 2min, and cooling to normal temperature to obtain a mixture;
s4: adding the mixture obtained in the step S3 into a die, performing hydraulic die pressing at 120 ℃ by using a hydraulic machine for curing for 1min, deflating for 5 times, making into a blank, and removing peripheral burrs;
s5: cleaning the blank in the step S4 by alcohol, uniformly spraying a layer of transparent protective film on the outer surface of the blank after drying, and drying to obtain a semi-finished product;
s6: and (5) irradiating the semi-finished product in the step S5 with ultraviolet rays for sterilization treatment to obtain a bamboo fiber tableware finished product.
In step S1, the rotation speed of the ball mill is 200r/min, and the grinding time is 15 min.
The drying temperature in step S5 is 110 ℃.
The thickness of the protective film in step S5 was 0.03 mm.
Example two
The recyclable environment-friendly bamboo fiber tableware comprises the following raw materials in parts by weight:
130 parts of enzymolysis bamboo fiber, 60 parts of deionized water, 10 parts of kaolin, 17 parts of sodium silicate, 30 parts of thermosetting composite resin, 8 parts of starch and 13 parts of alumina powder;
the enzymolysis bamboo fiber is prepared by the following method: soaking bamboo chips in sodium hydroxide solution for 2h, washing with deionized water, soaking in hydrochloric acid solution for 2h, washing with deionized water, steaming in a high-pressure steamer at 120 deg.C for 60min to obtain steamed bamboo chips, soaking in decomposition enzyme solution for 3h, and centrifuging to obtain enzymatic bamboo fiber.
The mass concentration of the sodium hydroxide solution was 5%.
The mass concentration of the hydrochloric acid solution is 4%.
The length of the bamboo chip is 12cm, and the width of the bamboo chip is 0.5 cm.
The mass concentration of the solution of the lytic enzyme was 8%.
The rotation speed of the centrifuge is 700r/min, and the centrifugation time is 7 min.
The recyclable environment-friendly bamboo fiber tableware comprises the following preparation steps:
s1: adding the enzymolysis bamboo fiber into a ball mill, and uniformly grinding to obtain fiber powder;
s2: putting the fiber powder in the step S1 and deionized water into a mixer, and mixing and stirring at the speed of 600rpm at 120 ℃ for 4 min;
s3: adding kaolin, sodium silicate, thermosetting composite resin, starch and alumina powder into the mixer in the step S2, stirring at the speed of 1000rpm at 140 ℃ for 3min, and cooling to normal temperature to obtain a mixture;
s4: adding the mixture obtained in the step S3 into a die, performing liquid pressing and die curing for 2min at 140 ℃ by using a hydraulic machine, deflating for 6 times to prepare a blank, and removing peripheral burrs;
s5: cleaning the blank in the step S4 by alcohol, uniformly spraying a layer of transparent protective film on the outer surface of the blank after drying, and drying to obtain a semi-finished product;
s6: and (5) irradiating the semi-finished product in the step S5 with ultraviolet rays for sterilization treatment to obtain a bamboo fiber tableware finished product.
In step S1, the rotation speed of the ball mill is 250r/min, and the grinding time is 25 min.
The drying temperature in step S5 was 120 ℃.
The thickness of the protective film in step S5 was 0.04 mm.
EXAMPLE III
The recyclable environment-friendly bamboo fiber tableware comprises the following raw materials in parts by weight:
150 parts of enzymolysis bamboo fiber, 70 parts of deionized water, 13 parts of kaolin, 15 parts of sodium silicate, 25 parts of thermosetting composite resin, 10 parts of starch and 15 parts of alumina powder;
the enzymolysis bamboo fiber is prepared by the following method: soaking bamboo chips in sodium hydroxide solution for 3h, washing with deionized water, soaking in hydrochloric acid solution for 3h, washing with deionized water, steaming in a high-pressure steamer at 130 deg.C for 70min to obtain steamed bamboo chips, soaking in decomposition enzyme solution for 3h, and centrifuging to obtain enzymatic bamboo fiber.
The mass concentration of the sodium hydroxide solution was 6%.
The mass concentration of the hydrochloric acid solution is 5%.
The length of the bamboo chip is 15cm, and the width of the bamboo chip is 0.6 cm.
The mass concentration of the solution of the lytic enzyme is 10%.
The rotating speed of the centrifuge is 1000r/min, and the centrifugation time is 10 min.
The recyclable environment-friendly bamboo fiber tableware comprises the following preparation steps:
s1: adding the enzymolysis bamboo fiber into a ball mill, and uniformly grinding to obtain fiber powder;
s2: putting the fiber powder in the step S1 and deionized water into a mixer, and mixing and stirring at the speed of 700rpm at the temperature of 130 ℃ for 5 min;
s3: adding kaolin, sodium silicate, thermosetting composite resin, starch and alumina powder into the mixer in the step S2, stirring at the speed of 1200rpm at 160 ℃ for 5min, and cooling to normal temperature to obtain a mixture;
s4: adding the mixture obtained in the step S3 into a mold, performing hydraulic mold pressing and curing for 3min at 120-150 ℃ by using a hydraulic machine, discharging gas for 8 times to prepare a blank, and removing peripheral burrs;
s5: cleaning the blank in the step S4 by alcohol, uniformly spraying a layer of transparent protective film on the outer surface of the blank after drying, and drying to obtain a semi-finished product;
s6: and (5) irradiating the semi-finished product in the step S5 with ultraviolet rays for sterilization treatment to obtain a bamboo fiber tableware finished product.
In step S1, the rotation speed of the ball mill is 300r/min, and the grinding time is 30 min.
The drying temperature in step S5 was 130 ℃.
The thickness of the protective film in step S5 was 0.06 mm.
In conclusion, the recyclable environment-friendly bamboo fiber tableware is prepared by taking enzymolysis bamboo fibers as a main component, adding kaolin, sodium silicate, thermosetting composite resin, starch and alumina powder as auxiliary components, and performing grinding, mixing and stirring, pressing, spraying, sterilizing and other processes, so that the prepared bamboo fiber tableware is non-toxic, harmless, green and healthy, biodegradable, convenient to recycle and has the advantages of energy conservation and environmental protection.
It is to be noted that the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus. Without further limitation, an element defined by the phrase "comprising an … …" does not exclude the presence of other identical elements in a process, method, article, or apparatus that comprises the element.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.

Claims (10)

1. The utility model provides a recoverable environment-friendly bamboo fibre tableware which characterized in that: the feed comprises the following raw materials in parts by weight:
100-150 parts of enzymolysis bamboo fiber, 50-70 parts of deionized water, 8-15 parts of kaolin, 15-20 parts of sodium silicate, 25-35 parts of thermosetting composite resin, 5-10 parts of starch and 12-15 parts of alumina powder;
the enzymolysis bamboo fiber is prepared by the following method: soaking bamboo chips in a sodium hydroxide solution for 1-3 hours, washing with deionized water, soaking in a hydrochloric acid solution for 1-3 hours, washing with deionized water, steaming in a high-pressure steamer at the steaming temperature of 110-130 ℃ for 50-70 min to obtain steamed bamboo chips, soaking the steamed bamboo chips in a decomposition enzyme solution for 2-3 hours, and spin-drying in a centrifuge to obtain the enzymatic hydrolysis bamboo fibers.
2. The recyclable environment-friendly bamboo fiber tableware according to claim 1, wherein: the mass concentration of the sodium hydroxide solution is 4-6%.
3. The recyclable environment-friendly bamboo fiber tableware according to claim 1, wherein: the mass concentration of the hydrochloric acid solution is 3-5%.
4. The recyclable environment-friendly bamboo fiber tableware according to claim 1, wherein: the bamboo chips are 10-15 cm in length and 0.3-0.6 cm in width.
5. The recyclable environment-friendly bamboo fiber tableware according to claim 1, wherein: the mass concentration of the decomposition enzyme solution is 5-10%.
6. The recyclable environment-friendly bamboo fiber tableware according to claim 1, wherein: the rotating speed of the centrifugal machine is 600-1000 r/min, and the centrifugal time is 5-10 min.
7. The utility model provides a recoverable environment-friendly bamboo fibre tableware which characterized in that: the preparation method comprises the following preparation steps:
s1: adding the enzymolysis bamboo fiber into a ball mill, and uniformly grinding to obtain fiber powder;
s2: putting the fiber powder and deionized water in the step S1 into a mixer, and mixing and stirring at the speed of 500-700 rpm for 3-5 min at the temperature of 100-130 ℃;
s3: adding kaolin, sodium silicate, thermosetting composite resin, starch and alumina powder into the mixer in the step S2, stirring at the speed of 800-1200 rpm at the temperature of 120-160 ℃ for 2-5 min, and cooling to normal temperature to obtain a mixture;
s4: adding the mixture obtained in the step S3 into a mold, performing hydraulic mold pressing and curing for 1-3 min at 120-150 ℃ by using a hydraulic machine, discharging gas for 5-8 times to prepare a blank, and removing peripheral burrs;
s5: cleaning the blank in the step S4 by alcohol, uniformly spraying a layer of transparent protective film on the outer surface of the blank after drying, and drying to obtain a semi-finished product;
s6: and (5) irradiating the semi-finished product in the step S5 with ultraviolet rays for sterilization treatment to obtain a bamboo fiber tableware finished product.
8. The recyclable environment-friendly bamboo fiber tableware according to claim 7, wherein: in the step S1, the rotation speed of the ball mill is 200-300 r/min, and the grinding time is 15-30 min.
9. The recyclable environment-friendly bamboo fiber tableware according to claim 7, wherein: and the drying temperature in the step S5 is 110-130 ℃.
10. The recyclable environment-friendly bamboo fiber tableware according to claim 7, wherein: the thickness of the protective film in the step S5 is 0.03-0.06 mm.
CN201911257526.7A 2019-12-10 2019-12-10 Recoverable environment-friendly bamboo fiber tableware Withdrawn CN110951271A (en)

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Application Number Priority Date Filing Date Title
CN201911257526.7A CN110951271A (en) 2019-12-10 2019-12-10 Recoverable environment-friendly bamboo fiber tableware

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111733631A (en) * 2020-06-23 2020-10-02 安徽德琳环保发展(集团)有限公司 Preparation method of bamboo fiber lunch box
CN112761017A (en) * 2020-12-31 2021-05-07 广东华凯科技股份有限公司 Method for preparing high-hardness fiberboard with bamboo fiber as raw material

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111733631A (en) * 2020-06-23 2020-10-02 安徽德琳环保发展(集团)有限公司 Preparation method of bamboo fiber lunch box
CN112761017A (en) * 2020-12-31 2021-05-07 广东华凯科技股份有限公司 Method for preparing high-hardness fiberboard with bamboo fiber as raw material
CN112761017B (en) * 2020-12-31 2022-10-04 广东华凯科技股份有限公司 Method for preparing high-hardness fiberboard with bamboo fiber as raw material

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