CN110951258A - non-Newtonian fluid material for shoe material and preparation method thereof - Google Patents
non-Newtonian fluid material for shoe material and preparation method thereof Download PDFInfo
- Publication number
- CN110951258A CN110951258A CN201911381663.1A CN201911381663A CN110951258A CN 110951258 A CN110951258 A CN 110951258A CN 201911381663 A CN201911381663 A CN 201911381663A CN 110951258 A CN110951258 A CN 110951258A
- Authority
- CN
- China
- Prior art keywords
- parts
- silicone oil
- newtonian fluid
- shoe
- fluid material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The invention discloses a non-Newtonian fluid material for shoe materials and a preparation method thereof, wherein the non-Newtonian fluid material is prepared from the following raw materials in parts by weight: 75-85 parts of methyl silicone oil, 17-23 parts of vinyl silicone oil, 2-3 parts of hydrogen-containing silicone oil, 0.9-1.1 parts of platinum catalyst, 8.5-11.5 parts of white carbon black and 17-23 parts of cassava powder. The non-Newtonian fluid material is used in an EVA/TPU supercritical foaming composite material, so that the rebound resilience can be greatly improved, the compression permanent deformation rate is reduced, and the EVA/TPU supercritical foaming shoe material has greatly improved elasticity and good rebound effect after being used, and is softer, larger in generated deformation and comfortable to wear when the shoe material is pressed lightly (namely the shoe material bears smaller force), but harder when the shoe material is pressed heavily (namely the shoe material bears smaller force), so that the deformation is ensured not to be too large, and the excessive deformation is effectively prevented, the appearance distortion is avoided, even the recovery cannot be realized, and the like.
Description
Technical Field
The invention relates to the field of high polymer materials, in particular to a non-Newtonian fluid material for shoe materials and a preparation method thereof.
Background
Along with the development of society, people increasingly diversify the functional requirements on the shoes, and particularly the performance requirements on the soles are higher and higher. The function and style of the shoes are various according to different using environments, such as climbing shoes, running shoes, slippers and the like. The mountaineering shoes require the soles to be wear-resistant and anti-skid; running shoes require soles to be shock-absorbing and anti-skid; the indoor slippers are applied to wet toilets for a long time, mildew easily grows, and the soles are required to be antibacterial and mildew-proof. Common sole materials include rubber, PU, EVA, TPR and the like, wherein the EVA has the advantages of good elasticity, portability, aging resistance, odor resistance and the like.
non-Newtonian fluids, are fluids that do not satisfy the experimental laws of Newtonian viscosity, i.e., fluids whose shear stress and shear strain rate are not linear. Non-newtonian fluids are widely found in life, production and nature. Most biological fluids belong to the non-newtonian fluids now defined. In humans, many body fluids such as blood, lymph, cystic fluid, and "semifluid" such as cytoplasm are non-newtonian fluids. But the research on the non-Newtonian fluid material used for the shoe material is rarely reported at present.
The currently used foaming shoe materials (rubber, PU, EVA, TPR, etc.) have the following problems: elasticity is relatively poor, and the resilience effect is unsatisfactory, and the concrete expression is for or the softer of shoes material, and deformation is big after the atress, leads to the shoes material to receive great power back easily like this, produces excessive deformation to the appearance distortion, can't resume even, leads to foot injury (if sprain) easily, or the shoes material is hard partially, and the atress (even if receive great power) back deformation is less, and the compliance is poor, and is uncomfortable to wear.
Disclosure of Invention
Based on the above situation, the present invention is directed to a non-newtonian fluid material for shoe materials and a method for preparing the same, which can effectively solve the above problems.
In order to solve the technical problems, the technical scheme provided by the invention is as follows:
a non-Newtonian fluid material for shoe materials is prepared from the following raw materials in parts by weight:
75-85 parts of methyl silicone oil,
17-23 parts of vinyl silicone oil,
2-3 parts of hydrogen-containing silicone oil,
0.9-1.1 parts of platinum catalyst,
8.5 to 11.5 parts of white carbon black,
17-23 parts of cassava flour.
Preferably, the non-Newtonian fluid material for the shoe material is prepared from the following raw materials in parts by weight:
80 parts of methyl silicone oil,
20 parts of vinyl silicone oil,
2.5 parts of hydrogen-containing silicone oil,
1 part of platinum catalyst,
10 portions of white carbon black,
20 parts of cassava flour.
Preferably, the methyl silicone oil is TSF451 dimethicone.
Preferably, the vinyl silicone oil is LY-205 vinyl silicone oil.
Preferably, the hydrogen-containing silicone oil is LY-207 hydrogen-containing silicone oil.
Preferably, the white carbon black is transparent white carbon black.
Preferably, the grain size of the cassava flour is 1000-3000 meshes.
The invention also provides a preparation method of the non-Newtonian fluid material for the shoe material, which comprises the following steps:
A. weighing the following components in parts by weight: methyl silicone oil, vinyl silicone oil, hydrogen-containing silicone oil, platinum catalyst, white carbon black and cassava powder for later use;
B. putting the weighed raw materials into a reaction kettle, and stirring and mixing uniformly;
C. and continuously stirring, heating to 70-150 ℃, reacting for 1-3 h, cooling, discharging and packaging to obtain the non-Newtonian fluid material for the shoe material.
Preferably, in the step C, stirring is continued, the temperature is increased to 90-120 ℃, the reaction is carried out for 1.5-2.5 h, and then cooling, discharging and packaging are carried out to obtain the non-Newtonian fluid material for the shoe material.
Compared with the prior art, the invention has the following advantages and beneficial effects:
the non-Newtonian fluid material for the shoe material is prepared by selecting raw materials, optimizing the content of each raw material and selecting methyl silicone oil, vinyl silicone oil, hydrogen-containing silicone oil, platinum catalyst, white carbon black and tapioca flour in proper proportion, not only fully exerts the advantages of the materials, but also supplements and promotes each other, and the prepared non-Newtonian fluid material for the shoe material is used in an EVA/TPU supercritical foaming composite material, so that the rebound resilience can be greatly improved, the compression permanent deformation rate is reduced, the EVA/TPU supercritical foaming shoe material is proved to have greatly improved elasticity and good rebound effect after using the non-Newtonian fluid material for the shoe material, the shoe material is softer and has larger generated deformation and is comfortable to wear when the shoe material is pressed lightly (i.e. the shoe material bears smaller force), but the heavy pressure (i.e. the shoe material bears smaller force) and is harder, so that the deformation is not too large, effectively prevent the excessive deformation, the shape distortion, even the failure to recover, etc.
The preparation method has simple process and simple and convenient operation, and saves manpower and equipment cost.
Detailed Description
In order that those skilled in the art will better understand the technical solutions of the present invention, the following description of the preferred embodiments of the present invention is provided in connection with specific examples, which should not be construed as limiting the present patent.
The test methods or test methods described in the following examples are conventional methods unless otherwise specified; the reagents and materials, unless otherwise indicated, are conventionally obtained commercially or prepared by conventional methods.
Example 1:
a non-Newtonian fluid material for shoe materials is prepared from the following raw materials in parts by weight:
75-85 parts of methyl silicone oil,
17-23 parts of vinyl silicone oil,
2-3 parts of hydrogen-containing silicone oil,
0.9-1.1 parts of platinum catalyst,
8.5 to 11.5 parts of white carbon black,
17-23 parts of cassava flour.
In this embodiment, the non-newtonian fluid material for shoe materials is made from the following raw materials in parts by weight:
80 parts of methyl silicone oil,
20 parts of vinyl silicone oil,
2.5 parts of hydrogen-containing silicone oil,
1 part of platinum catalyst,
10 portions of white carbon black,
20 parts of cassava flour.
In this example, the methyl silicone oil is TSF451 dimethicone.
In this example, the vinyl silicone oil was LY-205 vinyl silicone oil.
In this example, the hydrogen-containing silicone oil was LY-207 hydrogen-containing silicone oil.
In this embodiment, the white carbon black is transparent white carbon black.
In the embodiment, the grain size of the cassava flour is 1000-3000 meshes.
The embodiment also provides a preparation method of the non-Newtonian fluid material for the shoe material, which comprises the following steps:
A. weighing the following components in parts by weight: methyl silicone oil, vinyl silicone oil, hydrogen-containing silicone oil, platinum catalyst, white carbon black and cassava powder for later use;
B. putting the weighed raw materials into a reaction kettle, and stirring and mixing uniformly;
C. and continuously stirring, heating to 70-150 ℃, reacting for 1-3 h, cooling, discharging and packaging to obtain the non-Newtonian fluid material for the shoe material.
In the embodiment, in the step C, the non-Newtonian fluid material for the shoe material is obtained by continuously stirring, heating to 90-120 ℃, reacting for 1.5-2.5 h, cooling, discharging and packaging.
Example 2:
a non-Newtonian fluid material for shoe materials is prepared from the following raw materials in parts by weight:
75 parts of methyl silicone oil,
17 parts of vinyl silicone oil,
2 parts of hydrogen-containing silicone oil,
0.9 part of platinum catalyst,
8.5 parts of white carbon black,
17 parts of cassava flour.
In this example, the methyl silicone oil is TSF451 dimethicone.
In this example, the vinyl silicone oil was LY-205 vinyl silicone oil.
In this example, the hydrogen-containing silicone oil was LY-207 hydrogen-containing silicone oil.
In this embodiment, the white carbon black is transparent white carbon black.
In the embodiment, the grain size of the cassava flour is 1000-3000 meshes.
In this embodiment, the method for preparing the non-newtonian fluid material for footwear comprises the following steps:
A. weighing the following components in parts by weight: methyl silicone oil, vinyl silicone oil, hydrogen-containing silicone oil, platinum catalyst, white carbon black and cassava powder for later use;
B. putting the weighed raw materials into a reaction kettle, and stirring and mixing uniformly;
C. and continuously stirring, heating to 90 ℃, reacting for 2.5 hours, cooling, discharging and packaging to obtain the non-Newtonian fluid material for the shoe material.
Example 3:
a non-Newtonian fluid material for shoe materials is prepared from the following raw materials in parts by weight:
85 parts of methyl silicone oil,
23 parts of vinyl silicone oil,
3 parts of hydrogen-containing silicone oil,
1.1 parts of platinum catalyst,
11.5 parts of white carbon black,
23 parts of cassava flour.
In this example, the methyl silicone oil is TSF451 dimethicone.
In this example, the vinyl silicone oil was LY-205 vinyl silicone oil.
In this example, the hydrogen-containing silicone oil was LY-207 hydrogen-containing silicone oil.
In this embodiment, the white carbon black is transparent white carbon black.
In the embodiment, the grain size of the cassava flour is 1000-3000 meshes.
In this embodiment, the method for preparing the non-newtonian fluid material for footwear comprises the following steps:
A. weighing the following components in parts by weight: methyl silicone oil, vinyl silicone oil, hydrogen-containing silicone oil, platinum catalyst, white carbon black and cassava powder for later use;
B. putting the weighed raw materials into a reaction kettle, and stirring and mixing uniformly;
C. and continuously stirring, heating to 120 ℃, reacting for 1.5h, cooling, discharging and packaging to obtain the non-Newtonian fluid material for the shoe material.
Example 4:
a non-Newtonian fluid material for shoe materials is prepared from the following raw materials in parts by weight:
80 parts of methyl silicone oil,
20 parts of vinyl silicone oil,
2.5 parts of hydrogen-containing silicone oil,
1 part of platinum catalyst,
10 portions of white carbon black,
20 parts of cassava flour.
In this example, the methyl silicone oil is TSF451 dimethicone.
In this example, the vinyl silicone oil was LY-205 vinyl silicone oil.
In this example, the hydrogen-containing silicone oil was LY-207 hydrogen-containing silicone oil.
In this embodiment, the white carbon black is transparent white carbon black.
In the embodiment, the grain size of the cassava flour is 1000-3000 meshes.
In this embodiment, the method for preparing the non-newtonian fluid material for footwear comprises the following steps:
A. weighing the following components in parts by weight: methyl silicone oil, vinyl silicone oil, hydrogen-containing silicone oil, platinum catalyst, white carbon black and cassava powder for later use;
B. putting the weighed raw materials into a reaction kettle, and stirring and mixing uniformly;
C. and continuously stirring, heating to 105 ℃, reacting for 2 hours, cooling, discharging and packaging to obtain the non-Newtonian fluid material for the shoe material.
Comparative example 1:
the difference from example 4 is that TSF451 dimethicone was not present, and the other is the same as example 4.
Comparative example 2:
the difference from example 4 is that there is no LY-205 vinyl silicone oil, and the rest is the same as example 4.
Comparative example 3:
the difference from example 4 is that there is no LY-207 hydrogen-containing silicone oil, and the other is the same as example 4.
The non-newtonian fluid materials for shoe materials obtained in examples 2 to 4 and comparative examples 1 to 3 of the present invention were applied to EVA/TPU supercritical foam composites, respectively, and were subjected to performance tests, respectively, and the test results are shown in table 1.
The method comprises the following specific steps:
the EVA/TPU supercritical foaming composite material is prepared from the following raw materials in parts by weight:
300 parts of ethylene-vinyl acetate copolymer, 70 parts of thermoplastic polyurethane elastomer, 30 parts of maleic anhydride graft modifier, 16 parts of non-Newtonian fluid material for shoe material, 10 parts of peroxide and 2.5 parts of nucleating agent.
Wherein the thermoplastic polyurethane elastomer is a mixture of a polyester polyurethane elastomer and a polyether polyurethane elastomer.
Wherein the mass ratio of the polyester polyurethane elastomer to the polyether polyurethane elastomer in the mixture of the polyester polyurethane elastomer and the polyether polyurethane elastomer is 1: 2.5.
wherein the ethylene-vinyl acetate copolymer is an ethylene-vinyl acetate copolymer with the VA content of 32.5 percent.
Wherein the maleic anhydride grafting modifier is prepared from the following components in a mass ratio of 1: 2.55 reacting the polysiloxane containing epoxy group with maleic anhydride grafted polyethylene to obtain the polyethylene grafted silicon-containing group copolymer.
Wherein the nucleating agent is a mixture of nano zinc oxide and nano aluminum oxide.
Wherein the mass ratio of the nano zinc oxide to the nano aluminum oxide in the mixture of the nano zinc oxide and the nano aluminum oxide is 1: 0.78.
wherein the peroxide is zinc peroxide.
The preparation method of the EVA/TPU supercritical foaming composite material comprises the following steps:
1) weighing: respectively weighing thermoplastic polyurethane elastomer, ethylene-vinyl acetate copolymer, maleic anhydride graft modifier, peroxide and nucleating agent according to parts by weight;
2) banburying: mixing a thermoplastic polyurethane elastomer, an ethylene-vinyl acetate copolymer and a maleic anhydride graft modifier, feeding the mixture into an internal mixer, firstly carrying out internal mixing and blending for 12min at the temperature of 107 ℃, then adding peroxide and a nucleating agent, carrying out internal mixing and blending at the temperature of 130 ℃ until all components are uniformly mixed, and preparing an internal mixing blend;
3) tabletting: pressing the banburying blend into a plate by using a tablet press, and cutting;
4) supercritical foaming: putting the board prepared in the step 3) into an oven, preheating to a foaming temperature, then putting the preheated foaming mother board into a high-temperature mould, introducing carbon dioxide gas, and quickly releasing the carbon dioxide gas in the mould when the carbon dioxide gas is saturated in the sheet to quickly foam the sheet, thereby obtaining the TPU/EVA supercritical foaming composite material.
In the step 4), the temperature of the high-temperature die is 155 ℃, and the pressure of carbon dioxide gas in the die is 14 MPa.
From the above table, it can be seen that the non-newtonian fluid material for shoe materials of the present invention is used in the EVA/TPU supercritical foaming composite material, which can greatly improve the resilience and reduce the compression set rate, and thus shows that after the EVA/TPU supercritical foaming shoe material uses the non-newtonian fluid material for shoe materials of the present invention, the elasticity is greatly improved, the rebound effect is good, the shoe materials are softer and more comfortable to wear when the shoe materials are lightly pressed (i.e., the shoe materials bear less force), but the shoe materials are harder when the shoe materials are heavily pressed (i.e., the shoe materials bear less force), which ensures that the deformation is not too large, and effectively prevents the excessive deformation, such that the appearance distortion, even the recovery, etc. are effectively prevented.
The above is only a preferred embodiment of the present invention, and it should be noted that the above preferred embodiment should not be considered as limiting the present invention, and the protection scope of the present invention should be subject to the scope defined by the claims. It will be apparent to those skilled in the art that various modifications and adaptations can be made without departing from the spirit and scope of the invention, and these modifications and adaptations should be considered within the scope of the invention.
Claims (9)
1. A non-Newtonian fluid material for shoe materials is characterized by being prepared from the following raw materials in parts by weight:
75-85 parts of methyl silicone oil,
17-23 parts of vinyl silicone oil,
2-3 parts of hydrogen-containing silicone oil,
0.9-1.1 parts of platinum catalyst,
8.5 to 11.5 parts of white carbon black,
17-23 parts of cassava flour.
2. The non-Newtonian fluid material for shoe materials of claim 1, wherein said non-Newtonian fluid material for shoe materials is made from raw materials comprising, by weight:
80 parts of methyl silicone oil,
20 parts of vinyl silicone oil,
2.5 parts of hydrogen-containing silicone oil,
1 part of platinum catalyst,
10 portions of white carbon black,
20 parts of cassava flour.
3. The non-Newtonian fluid material for footwear according to claim 1, wherein said methyl silicone oil is TSF451 dimethicone.
4. A non-newtonian fluid material for footwear according to claim 1, wherein the vinyl silicone oil is LY-205 vinyl silicone oil.
5. A non-newtonian fluid material for footwear according to claim 1, wherein the hydrogen-containing silicone oil is LY-207 hydrogen-containing silicone oil.
6. The non-Newtonian fluid material for shoe materials of claim 1, wherein said white carbon black is a transparent white carbon black.
7. The non-Newtonian fluid material for shoe materials of claim 1, wherein the particle size of the tapioca flour is 1000-3000 mesh.
8. A method of preparing a non-Newtonian fluid material for footwear according to any one of claims 1 to 7, comprising the steps of:
weighing the following components in parts by weight: methyl silicone oil, vinyl silicone oil, hydrogen-containing silicone oil, platinum catalyst, white carbon black and cassava powder for later use;
putting the weighed raw materials into a reaction kettle, and stirring and mixing uniformly;
and continuously stirring, heating to 70-150 ℃, reacting for 1-3 h, cooling, discharging and packaging to obtain the non-Newtonian fluid material for the shoe material.
9. The method for preparing the non-Newtonian fluid material for the shoe material, according to claim 8, wherein in the step C, the non-Newtonian fluid material for the shoe material is obtained by stirring, heating to 90-120 ℃, reacting for 1.5-2.5 h, cooling, discharging and packaging.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911381663.1A CN110951258A (en) | 2019-12-27 | 2019-12-27 | non-Newtonian fluid material for shoe material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911381663.1A CN110951258A (en) | 2019-12-27 | 2019-12-27 | non-Newtonian fluid material for shoe material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110951258A true CN110951258A (en) | 2020-04-03 |
Family
ID=69984810
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201911381663.1A Pending CN110951258A (en) | 2019-12-27 | 2019-12-27 | non-Newtonian fluid material for shoe material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110951258A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111534081A (en) * | 2020-06-02 | 2020-08-14 | 安踏（中国）有限公司 | Insole material with natural light transmission and preparation method thereof |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103448267A (en) * | 2013-08-30 | 2013-12-18 | 安徽金科橡塑制品有限公司 | Manufacturing process for quic- heat-conducting mildew-proof anti-bacterial rubber insoles |
| CN107177154A (en) * | 2017-05-27 | 2017-09-19 | 中广核高新核材集团（东莞）祈富新材料有限公司 | A kind of high-elastic, oil resistant TPE material |
| CN107964196A (en) * | 2017-12-27 | 2018-04-27 | 苏州锐创广告有限公司 | A kind of inner lining material of packaging |
| CN108203881A (en) * | 2018-01-10 | 2018-06-26 | 广东天跃新材料股份有限公司 | A kind of the silicon rubber leather and its coating process of resistance to complications |
| CN108587125A (en) * | 2018-05-17 | 2018-09-28 | 合肥浦尔菲电线科技有限公司 | A kind of environment-friendly package material and preparation method thereof |
| CN109553984A (en) * | 2018-12-12 | 2019-04-02 | 深圳德邦界面材料有限公司 | A kind of heat-conducting pad of low-density and high-strength and preparation method thereof |
| CN109575605A (en) * | 2018-12-18 | 2019-04-05 | 广德艾森新材料科技有限公司 | A kind of flame retardant silica gel foam and preparation method thereof |
| CN110294935A (en) * | 2018-11-19 | 2019-10-01 | 浙江天易新材料有限公司 | A kind of forming method of high thermal conductivity foamed silica gel material |
-
2019
- 2019-12-27 CN CN201911381663.1A patent/CN110951258A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103448267A (en) * | 2013-08-30 | 2013-12-18 | 安徽金科橡塑制品有限公司 | Manufacturing process for quic- heat-conducting mildew-proof anti-bacterial rubber insoles |
| CN107177154A (en) * | 2017-05-27 | 2017-09-19 | 中广核高新核材集团（东莞）祈富新材料有限公司 | A kind of high-elastic, oil resistant TPE material |
| CN107964196A (en) * | 2017-12-27 | 2018-04-27 | 苏州锐创广告有限公司 | A kind of inner lining material of packaging |
| CN108203881A (en) * | 2018-01-10 | 2018-06-26 | 广东天跃新材料股份有限公司 | A kind of the silicon rubber leather and its coating process of resistance to complications |
| CN108587125A (en) * | 2018-05-17 | 2018-09-28 | 合肥浦尔菲电线科技有限公司 | A kind of environment-friendly package material and preparation method thereof |
| CN110294935A (en) * | 2018-11-19 | 2019-10-01 | 浙江天易新材料有限公司 | A kind of forming method of high thermal conductivity foamed silica gel material |
| CN109553984A (en) * | 2018-12-12 | 2019-04-02 | 深圳德邦界面材料有限公司 | A kind of heat-conducting pad of low-density and high-strength and preparation method thereof |
| CN109575605A (en) * | 2018-12-18 | 2019-04-05 | 广德艾森新材料科技有限公司 | A kind of flame retardant silica gel foam and preparation method thereof |
Non-Patent Citations (5)
| Title |
|---|
| 刘堂应: "室温发泡硅橡胶的性能研究", 《中国建筑防水》 * |
| 刘根起 等: "淀粉/聚硅氧烷复合凝胶电响应行为的研究", 《中国化学会第十二届胶体与界面化学会议论文摘要集》 * |
| 卞军 等主编: "《聚合物共混改性基础》", 31 January 2018, 西南交通大学出版社 * |
| 白泉 等: "电流变弹性体的制备及其力学性能测试", 《湖南工程学院学报》 * |
| 黄文润 编著: "《热硫化硅橡胶》", 30 September 2009, 四川科学技术出版 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111534081A (en) * | 2020-06-02 | 2020-08-14 | 安踏（中国）有限公司 | Insole material with natural light transmission and preparation method thereof |
| CN111534081B (en) * | 2020-06-02 | 2021-12-24 | 安踏（中国）有限公司 | Insole material with natural light transmission and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN112625333B (en) | High-wear-resistance and high-shock-absorption sports shoe sole material and preparation method thereof | |
| CN102167863A (en) | Insole material of lightweight high-elasticity sports shoes and manufacturing method thereof | |
| US20170095987A1 (en) | Shoe insole and manufacturing method thereof | |
| CN110577696B (en) | High-wear-resistance EVA (ethylene-vinyl acetate) foam material and preparation method thereof | |
| CN113480786B (en) | Graphene natural rubber sole composite foam material for old people and preparation method thereof | |
| CN109796668A (en) | A kind of EVA composition, foam and preparation method thereof | |
| CN107200911A (en) | A kind of ultralight high-elastic environment protection sole and preparation method thereof | |
| CN109384983A (en) | A kind of aviation oil resistant high-low temperature resistant rubber and preparation method thereof | |
| KR101203677B1 (en) | Ethylene vinyl acetate resin composition for MASAI SENSOR | |
| CN110607021B (en) | Preparation method of leather scrap composite modified EVA (ethylene-vinyl acetate copolymer) foamed shoe material | |
| CN110951258A (en) | non-Newtonian fluid material for shoe material and preparation method thereof | |
| CN111808357B (en) | Extremely-light wear-resistant low-compression high-resilience composite foam material for sports shoe soles and preparation method thereof | |
| CN101121804A (en) | Foaming thermoplastic elastomer and its preparing process | |
| CN114835971B (en) | High-elasticity breathable Ai Caofen foaming composite material and preparation method and application thereof | |
| CN101485503B (en) | Moulding material for producing sole, sole and method for producing the same | |
| CN106832551A (en) | It is a kind of to have wear-resisting and flexibility composite rubber-plastic material concurrently | |
| CN112266508A (en) | Shoe sole aging-resistant women's shoes and preparation process thereof | |
| CN106009244A (en) | Novel shoe product material and preparation method thereof | |
| CN110028714A (en) | A kind of formula and preparation process of ultralight one-pass molding composite sole | |
| CN113845716A (en) | Modified EVA (ethylene-vinyl acetate copolymer), preparation method thereof and wide-temperature-range high-performance EVA composite foam material | |
| CN101768305A (en) | Light rubber plastic foam material and production method and application thereof | |
| CN104856344A (en) | Secondary molding sandwich EVA foaming wear-resistant sports sole and manufacture method thereof | |
| CN110862693B (en) | Bi-component liquid silicone rubber with ultralow compression set rate for foam | |
| CN102898738B (en) | Memory foam sports shoe sole recipe and manufacture method of memory foam sports shoe sole recipe | |
| CN112795065B (en) | Sole rubber composition and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20200403 |
|
| RJ01 | Rejection of invention patent application after publication |