CN110922922A - TPE (thermoplastic elastomer) glue, process for preparing anti-skid floor mat by using TPE glue and polyester cotton cloth and anti-skid floor mat - Google Patents
TPE (thermoplastic elastomer) glue, process for preparing anti-skid floor mat by using TPE glue and polyester cotton cloth and anti-skid floor mat Download PDFInfo
- Publication number
- CN110922922A CN110922922A CN201911141459.2A CN201911141459A CN110922922A CN 110922922 A CN110922922 A CN 110922922A CN 201911141459 A CN201911141459 A CN 201911141459A CN 110922922 A CN110922922 A CN 110922922A
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- Prior art keywords
- tpe
- floor mat
- mat
- glue
- slip
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J153/02—Vinyl aromatic monomers and conjugated dienes
- C09J153/025—Vinyl aromatic monomers and conjugated dienes modified
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47G—HOUSEHOLD OR TABLE EQUIPMENT
- A47G27/00—Floor fabrics; Fastenings therefor
- A47G27/02—Carpets; Stair runners; Bedside rugs; Foot mats
- A47G27/0243—Features of decorative rugs or carpets
- A47G27/0281—Resisting skidding or creeping
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D7/00—Producing flat articles, e.g. films or sheets
- B29D7/01—Films or sheets
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J191/00—Adhesives based on oils, fats or waxes; Adhesives based on derivatives thereof
- C09J191/06—Waxes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/04—Thermoplastic elastomer
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Carpets (AREA)
Abstract
The invention relates to a formula of improved TPE (thermoplastic elastomer) glue, and an anti-slip floor mat manufactured by the TPE glue and special base cloth has high wet slip coefficient and simultaneously has a dry slip effect, so that the anti-slip effect of the anti-slip floor mat is greatly improved, and the improved anti-slip floor mat has the following beneficial effects: the improved TPE glue and the special base fabric are combined through a compounding process, the back bottom procedure is completed at one time, and the product effectively avoids the performance defects that the wet slip-resistant coefficient of a single TPE glue bottom is low and the single cotton cloth bottom is dry slip-resistant and unqualified.
Description
Technical Field
The invention relates to the field of floor mats, in particular to a formula of TPE glue, a preparation process for preparing an anti-slip floor mat by using the TPE glue and polyester cotton cloth, and the anti-slip floor mat prepared by the process.
Background
The TPE plastic raw material has the characteristics of high elasticity, high strength and high resilience of rubber, can be subjected to injection molding processing, is environment-friendly, non-toxic and safe, has a wide hardness range, excellent colorability, soft touch, weather resistance, fatigue resistance and temperature resistance, has excellent processability, does not need vulcanization, can be recycled, can be subjected to secondary injection molding, and can be coated and adhered with base materials such as PP plastic raw materials, PE plastic raw materials, PC engineering plastics, PS plastics, ABS plastic raw materials and the like, and can also be formed independently.
The anti-skid floor mat is a product which can effectively scrape mud dust and moisture at an entrance and keep the indoor floor clean; the back generally adopts rubber materials such as PVC, TPE, has skid-proof efficiency, and anti-skidding ground mat elasticity is soft, the feel is comfortable, antiskid, and the wide application is in places such as gate, room, is loved by vast consumer deeply, and wherein the anti-skidding ground mat that adopts the preparation at the bottom of the TPE back of the body has advantages such as antiskid, non-aging, with low costs, and the gluey component ratio of its TPE is in current TPE gum ground mat: 16% -20% of SEBS; OIL 24% -28%; 1% -4% of PP; 352% -56% of CaCO, the molecular weight of the material is about 15 ten thousand, but the anti-slip floor mat made of the TPE glue is easy to slip in water-containing environments such as bathrooms and kitchens in the actual use process, and if the traditional cloth floor mat is adopted, although the water-absorbing and waterproof floor mat can absorb water, but cannot slip in a dry environment, the floor mat with excellent dry anti-slip and wet anti-slip performance is urgently needed to change the current situation.
Disclosure of Invention
The technical problem to be solved by the present invention is to solve the above-mentioned deficiencies of the prior art,
the formula of the improved TPE adhesive is provided, and the anti-slip floor mat prepared from the TPE adhesive and the special polyester cotton cloth has a high wet anti-slip coefficient and a dry anti-slip effect, so that the anti-slip effect of the anti-slip floor mat is greatly improved.
In order to achieve the purpose, the invention provides the following technical scheme: the TPE adhesive is characterized by being prepared from the following raw materials: 23% -27% of SEBS, 24% -28% of OIL, 1% -4% of PP, 342% -46% of CaCO and 3% of hydrogenated tackifying resin;
by adopting the technical scheme, at normal temperature, the SEBS (polystyrene) comprises PS (polystyrene) hard plastic blocks at two sides and an EB (ethylene/butylene) elastomer block in the middle, the two blocks are thermodynamically incompatible with each other so as to generate a two-phase structure, a separation state is presented in a microscopic phase, and the SEBS does not contain unsaturated double bonds, so that the SEBS has good stability and aging resistance, the heat resistance of the SEBS is remarkably improved compared with that of SBS, the electric insulation property and the mixing property are also improved, the SEBS has good wear resistance and flexibility, meanwhile, the SEBS also has good adhesion and solubility, can be dissolved in a common solvent, can be blended and modified with a plurality of polymers, and can be used as a matrix of a TPE (thermoplastic elastomer) glue material; the compatibility of the OIL (white OIL) and the middle EB section of the SEBS is good, but the PS phase in the softened SEBS is not dissolved, the OIL-filled SEBS product can continuously keep a stable physical crosslinking network, the fluidity of the SEBS can be increased, the processing performance of the SEBS can be improved, the hardness of the SEBS can be adjusted, and the mechanical property of the SEBS can not be damaged; the PP (polypropylene) and the SEBS are blended, so that the compatibilization effect of the PP can be improved, the tensile strength and the elongation at break of the blend are increased along with the increase of the PP content, the impact strength of the blend is improved, the rigidity of the blend is not reduced, and the blend has excellent halohydrocarbon resistance and oil resistance; CaCO3 (calcium carbonate) is large in mesh number and stable in property, does not react with other raw materials, CaCO3 is used as a filler, the using amount of other raw materials can be reduced, the cost is reduced, and the shrinkage of the material during extrusion can be reduced, but too much CaCO3 can cause too high hardness of TPE glue and reduce the adhesion.
The TPE glue can be further configured as follows: the molecular weight of the TPE glue material is 200000-.
By adopting the technical scheme, the molecular weight is improved on the basis of the original TPE formula, the tensile strength and the oil absorption are increased, the mechanical property under high filling is excellent, a double INP network formed when the TPE is blended with PP is complete, and meanwhile, the higher the styrene content is, the higher the melt viscosity of the blend is.
A preparation process of an anti-slip floor mat comprises the following steps:
step 1, adding TPE glue into a gluing machine and heating at 60-80 ℃;
step 2, adjusting the width of a film outlet of a die orifice of a gluing machine and a press roll gap according to the width of the ground mat to be processed;
and step 3: placing the ground mat to be processed on a cloth storage rack, and drawing the ground mat to the die orifice of the gluing machine;
and 4, step 4: starting a host machine of the gluing machine to draw the ground mat to be processed in the cloth storage rack into the gluing machine for gluing;
and 5: and (4) putting a base fabric matched with the size of the ground mat to be processed into the rubber covered roller, putting the ground mat to be processed after being glued in the step (4) into the rubber covered roller, and pressing and gluing the base fabric and the ground mat to be processed together through TPE glue.
Step 6: and (5) pulling the floor mat attached in the step (5) to a rear storage cloth, and pulling the floor mat to be rolled through the storage cloth.
The preparation process of the anti-skid floor mat can be further set as follows: the TPE adhesive used in step 1 is the TPE adhesive of claim 1 or 2.
The preparation process of the anti-skid floor mat can be further set as follows: the ground mat to be processed is a tufted blank mat, the base fabric is made by interweaving warps and wefts, the wefts are polyester filaments, and the warps are regenerated cotton threads.
The preparation process of the anti-skid floor mat can be further set as follows: the density of the warp threads is 24-28 threads/inch, and the density of the weft threads is 10-14 threads/inch.
By adopting the technical scheme, TPE glue is heated to 60-80 ℃ in a gluing machine, then the ground mat to be processed is placed on a gluing machine for gluing, the ground mat is pushed to a glue roller, the base fabric is attached to the glued part of the ground mat to be processed, the base fabric is glued with the ground mat to be processed through the glue roller, the ground mat to be processed is glued together through the TPE glue, finally the ground mat after being bonded is rolled, the top surface of the ground mat processed is a tufted carpet, the base fabric is polyester cotton cloth, weft in the polyester cotton cloth is polyester filament, the strength of the polyester cotton cloth is increased, the warp density of the polyester cotton cloth is reduced from 32/inch to 18/inch, the weft density is reduced to 24-28/inch, the density of the weft is 10-14/inch, so that the density of the base fabric is reduced, the TPE glue can be between the base fabric and the tufted carpet, after the density is reduced, the anti-slip floor mat is extruded in the gap of the base fabric, so that the contact surface of the anti-slip floor mat and the ground has improved strength, water absorption and anti-slip polyester cotton cloth, TPE rubber capable of increasing dry friction, and the anti-slip floor mat has dry anti-slip and wet anti-slip effects.
The utility model provides an anti-skidding ground mat, includes by tufting layer and skid resistant course, the skid resistant course top is in the same place through the compound of bond line high temperature with tufting layer bottom, its characterized in that: the adhesive layer is TPE glue, and the anti-skid layer is base fabric.
By adopting the technical scheme, the tufting layer and the anti-slip layer are adhered together through the TPE glue, the TPE glue permeates to the surface of the base cloth and is combined with the base cloth, and the performance defects that the wet anti-slip of a single TPE rubber bottom is unqualified and the dry anti-slip of a single cotton cloth bottom is unqualified are avoided.
The anti-slip floor mat can be further configured as follows: the anti-skid layer is polyester cotton cloth, polyester cotton cloth is interweaved by warp and weft and is made, weft is polyester filament, and warp is the regeneration cotton thread.
Adopt above-mentioned technical scheme, the weft in the polyester-cotton cloth adopts polyester filament, has increased cotton intensity.
The anti-slip floor mat can be further configured as follows: the density of the warp threads is 24-28 threads/inch, and the density of the weft threads is 10-14 threads/inch.
Adopt above-mentioned technical scheme, warp density with the polyester-cotton cloth is from 32/inch, and weft density 18/inch reduces to warp's density and is 24-28 pieces/inch, weft's density is 10-14 pieces/inch to reduce the density of backer, make TPE glue can follow in the middle of backer and the tufting embryo blanket, extrude in the gap of backer after reducing the density, make the contact surface of antiskid ground mat have intensity increase and the cotton that absorbs water limited slip promptly after improving, possess the TPE rubber that can increase dry friction again.
The invention has the beneficial effects that: the improved TPE glue and the improved base fabric are adopted, the two are combined through a composite process, and the back bottom procedure is completed at one time, so that the product effectively avoids the performance defects that a single TPE glue bottom is unqualified in wet skid resistance and a single cotton cloth bottom is unqualified in dry skid resistance.
Detailed Description
Example 1:
selecting materials:
TPE glue: 25% of SEBS, 25% of OIL, 2% of PP, 345% of CaCO, 3% of hydrogenated tackifying resin, wherein the molecular weight of the rubber material is 200000-230000;
tufting fabric;
polyester cotton cloth: the fabric is made by interweaving warps and wefts, wherein the wefts are made of polyester filaments, the density of the warps is 28 threads/inch, and the density of the wefts is 14 threads/inch;
preparing an anti-skid ground mat:
adding the TPE glue into a gluing machine, heating to 70 ℃, gluing the non-fluff side of the tufted fabric through the gluing machine, then bonding the polyester cotton cloth with the glued side of the tufted fabric, putting the polyester cotton cloth and the glued side of the tufted fabric together into a glue passing roller, gluing, and pressing to form a support anti-skidding ground mat;
the above mats were subjected to the following experiments:
dry rub test
The anti-slip floor mat and the common anti-slip floor mat are respectively provided with the size of 10 x 10cm, 5kg of weight is uniformly placed on the surface of a sample, the sample is placed on a horizontal smooth surface-terrazzo surface, a tension meter is used for stretching the sample in parallel with the smooth surface, the force when the test sample is pulled is recorded, the test is repeated twice under the test environment, the friction coefficient is calculated, and the friction coefficient = the force used when the sample starts to slip/the force placed on the surface of the sample.
Wet Friction test
The anti-slip floor mat and the common anti-slip floor mat are respectively provided with the size of 10 x 10cm, 5kg of weight is uniformly placed on the surface of a sample, the sample is placed on a horizontal smooth surface-terrazzo surface, distilled water is used as a lubricating agent, a tension meter is used for stretching the sample in parallel with the smooth surface, the test is repeated twice under a test environment, the force when the test sample is pulled is recorded, the friction coefficient is calculated, and the friction coefficient = the force used when the sample starts to slip/the force placed on the surface of the sample.
The comprehensive friction coefficient of the anti-skidding ground mat in dry and wet environments is obviously greater than that of the common anti-skidding ground mat, and the anti-skidding effect is obvious.
Claims (10)
1. The TPE adhesive is characterized by being prepared from the following raw materials:
23% -27% of SEBS, 24% -28% of OIL, 1% -4% of PP, 342% -46% of CaCO and 3% of hydrogenated tackifying resin.
2. The TPE glue of claim 1, wherein: the molecular weight of the TPE glue is 200000-.
3. A preparation process of an anti-slip floor mat comprises the following steps:
step 1, adding TPE glue into a gluing machine and heating at 60-80 ℃;
step 2, adjusting the width of a film outlet of a die orifice of a gluing machine and a press roll gap according to the width of the ground mat to be processed;
and step 3: placing the ground mat to be processed on a cloth storage rack, and drawing the ground mat to the die orifice of the gluing machine;
and 4, step 4: starting a host machine of the gluing machine to draw the ground mat to be processed in the cloth storage rack into the gluing machine for gluing;
and 5: putting a base fabric matched with the size of the ground mat to be processed into the rubber covered roller, putting the ground mat to be processed after being glued in the step 4 into the rubber covered roller, and pressing and gluing the base fabric and the ground mat to be processed together through TPE (thermoplastic elastomer);
step 6: and (5) pulling the floor mat attached in the step (5) to a rear storage cloth, and pulling the floor mat to be rolled through the storage cloth.
4. A process for preparing an anti-slip floor mat as claimed in claim 3, wherein: the TPE adhesive used in step 1 is the TPE adhesive of claim 1 or 2.
5. A process for preparing an anti-slip floor mat as claimed in claim 4, wherein: the ground mat to be processed is a tufted blank mat, the base fabric is made by interweaving warps and wefts, the wefts are polyester filaments, and the warps are regenerated cotton threads.
6. A process for preparing an anti-slip floor mat as claimed in claim 5, wherein: the density of the warp threads is 24-28 threads/inch, and the density of the weft threads is 10-14 threads/inch.
7. The utility model provides an anti-skidding ground mat, includes tufting layer and skid resistant course, the skid resistant course top is in the same place through the compound of bond line high temperature with tufting layer bottom, its characterized in that: the adhesive layer is TPE glue, and the anti-skid layer is base fabric.
8. An anti-slip floor mat as claimed in claim 7, wherein: the anti-skid layer is polyester cotton cloth, polyester cotton cloth is interweaved by warp and weft and is made, weft is polyester filament, and warp is the regeneration cotton thread.
9. An anti-slip floor mat as claimed in claim 8, wherein: the density of the warp threads is 24-28 threads/inch, and the density of the weft threads is 10-14 threads/inch.
10. A non-slip floor mat as claimed in any one of claims 7 to 9, wherein: the TPE adhesive of claim 1 or 2.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911141459.2A CN110922922A (en) | 2019-11-20 | 2019-11-20 | TPE (thermoplastic elastomer) glue, process for preparing anti-skid floor mat by using TPE glue and polyester cotton cloth and anti-skid floor mat |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911141459.2A CN110922922A (en) | 2019-11-20 | 2019-11-20 | TPE (thermoplastic elastomer) glue, process for preparing anti-skid floor mat by using TPE glue and polyester cotton cloth and anti-skid floor mat |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110922922A true CN110922922A (en) | 2020-03-27 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201911141459.2A Pending CN110922922A (en) | 2019-11-20 | 2019-11-20 | TPE (thermoplastic elastomer) glue, process for preparing anti-skid floor mat by using TPE glue and polyester cotton cloth and anti-skid floor mat |
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| CN (1) | CN110922922A (en) |
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| CN109199048A (en) * | 2018-08-09 | 2019-01-15 | 龙福环能科技股份有限公司 | tufted carpet and its manufacturing method |
| CN110192757A (en) * | 2019-04-30 | 2019-09-03 | 海宁舒毯地毯科技有限公司 | A kind of superpower on-slip solid TPE elastic construction composite carpet and its combination process |
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2019
- 2019-11-20 CN CN201911141459.2A patent/CN110922922A/en active Pending
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1478134A (en) * | 2000-06-27 | 2004-02-25 | 埃克森美孚化学专利公司 | Adhesives with improved die-cutting performance |
| JP2007224101A (en) * | 2006-02-22 | 2007-09-06 | Yasuhara Chemical Co Ltd | Anti-slipping hot melt composition and carpet and floor material |
| CN102786898A (en) * | 2012-09-11 | 2012-11-21 | 无锡市万力粘合材料有限公司 | Hot melt adhesive composition for carpet skid resistance and preparation method of hot melt adhesive composition |
| CN104172891A (en) * | 2014-09-16 | 2014-12-03 | 阳信瑞鑫集团有限公司 | Wall-to-wall colorful wool blanket and processing technology thereof |
| CN106479197A (en) * | 2016-11-22 | 2017-03-08 | 苏州肯福特纺织品有限公司 | A kind of environment protection modification thermoplastic elastic material and its application |
| CN106901583A (en) * | 2017-04-07 | 2017-06-30 | 陈志峰 | A kind of string rug and preparation method thereof |
| CN106995577A (en) * | 2017-05-12 | 2017-08-01 | 林超 | Recoverable TPE material of low temperature lower stress deformation and its production and use |
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| CN109199048A (en) * | 2018-08-09 | 2019-01-15 | 龙福环能科技股份有限公司 | tufted carpet and its manufacturing method |
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Application publication date: 20200327 |