CN110922731A - Weather-proof daylighting panel and processing technology thereof - Google Patents
Weather-proof daylighting panel and processing technology thereof Download PDFInfo
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- CN110922731A CN110922731A CN201911177784.4A CN201911177784A CN110922731A CN 110922731 A CN110922731 A CN 110922731A CN 201911177784 A CN201911177784 A CN 201911177784A CN 110922731 A CN110922731 A CN 110922731A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/06—Unsaturated polyesters
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04C—STRUCTURAL ELEMENTS; BUILDING MATERIALS
- E04C2/00—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
- E04C2/54—Slab-like translucent elements
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
- C08K2003/3081—Aluminum sulfate
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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Abstract
The invention belongs to the technical field of daylighting panels, and provides a weather-resistant daylighting panel and a processing technology thereof. A weather-resistant daylighting panel comprises the following components in parts by weight: 20-40 parts of m-phthalic acid type unsaturated polyester resin, 15-30 parts of polycarbonate, 2-7 parts of epoxy resin, 3-10 parts of acrylic emulsion, 2-5 parts of ceramic fiber, 2-5 parts of glass fiber, 1-5 parts of N-methyl pyrrolidone, 0.2-1.5 parts of dibutyltin dilaurate, 0.5-1 part of sodium cocoyl methyl taurate, 0.5-2 parts of ethylhexyl methoxycinnamate, 0.1-0.5 part of calcium formate, 1.5-2.5 parts of methyl ethyl ketone peroxide and 0.5-1.5 parts of accelerator. Through the technical scheme, the problems of low temperature resistance limit and poor weather resistance of the daylighting panel in the prior art are solved.
Description
Technical Field
The invention belongs to the technical field of daylighting panels, and relates to a weather-resistant daylighting panel and a processing technology thereof.
Background
With the continuous development of green building technology, the lighting panel is applied and widely developed in more and more building fields, and becomes one of necessary building materials. In some large-scale buildings such as chemical plants, markets, stadium greenhouses, aquaculture farms and the like, the daylighting plate can utilize natural light, has good daylighting effect, saves electric energy, and plays the roles of neatness, attractiveness and environmental protection.
The daylighting panel on the market at present is usually made of glass fiber reinforced composite materials, and although the daylighting panel has high light transmittance, the daylighting panel has low temperature resistance limit, cannot resist sun exposure, has short service life, and is not suitable for highly-polluted heavy industrial areas. The invention discloses a weather-resistant daylighting panel as disclosed in the patent application with the publication number of CN 103242633A and the name of the invention being a weather-resistant composite material for daylighting, a daylighting panel and a preparation method thereof, wherein the weather-resistant daylighting panel comprises a PET upper film, a PET lower film, a glass fiber layer and a weather-resistant composite material layer which are formed between the PET upper film and the PET lower film, and the weather-resistant daylighting panel provided by the application has the temperature resistance limit of-80-140 ℃, so that the temperature resistance limit, particularly the high temperature resistance limit, is low and needs to be further improved.
Disclosure of Invention
The invention provides a weather-resistant daylighting panel and a processing technology thereof, and solves the problems of low temperature resistance limit and poor weather resistance of the daylighting panel in the prior art.
The technical scheme of the invention is realized as follows:
a weather-resistant daylighting panel comprises the following components in parts by weight:
20-40 parts of m-phthalic acid type unsaturated polyester resin, 15-30 parts of polycarbonate, 2-7 parts of epoxy resin, 3-10 parts of acrylic emulsion, 2-5 parts of ceramic fiber, 2-5 parts of glass fiber, 1-5 parts of N-methyl pyrrolidone, 0.2-1.5 parts of dibutyltin dilaurate, 0.5-1 part of sodium cocoyl methyl taurate, 0.5-2 parts of ethylhexyl methoxycinnamate, 0.1-0.5 part of calcium formate, 1.5-2.5 parts of methyl ethyl ketone peroxide and 0.5-1.5 parts of accelerator.
As a further technical scheme, the paint comprises the following components in parts by weight:
30 parts of m-phthalic acid type unsaturated polyester resin, 23 parts of polycarbonate, 5 parts of epoxy resin, 6 parts of acrylic emulsion, 3 parts of ceramic fiber, 3 parts of glass fiber, 3 parts of N-methyl pyrrolidone, 0.8 part of dibutyltin dilaurate, 0.7 part of sodium cocoyl methyl taurate, 1.2 parts of ethylhexyl methoxycinnamate, 0.3 part of calcium formate, 2 parts of methyl ethyl ketone peroxide and 1 part of accelerator.
As a further technical scheme, the ceramic fiber comprises the following components in parts by weight:
25-35 parts of aluminum oxide, 35-50 parts of silicon oxide, 5-15 parts of zirconium oxide, 3-10 parts of titanium oxide, 2-6 parts of magnesium oxide and 2-8 parts of cerium oxide.
As a further technical scheme, the ceramic fiber comprises the following components in parts by weight:
30 parts of aluminum oxide, 42 parts of silicon oxide, 10 parts of zirconium oxide, 6 parts of titanium oxide, 4 parts of magnesium oxide, 5 parts of cerium oxide,
the ceramic fiber is formed by mixing and spinning aluminum oxide, silicon oxide, titanium oxide, zirconium oxide, magnesium oxide and cerium oxide and then sintering at high temperature.
As a further technical scheme, the accelerator is triisopropanolamine, aluminum sulfate and cobalt isooctanoate with the mass ratio of 2: 1: 7 in a mixture.
As a further technical scheme, the diameter of the ceramic fiber is 2-5 μm.
The invention also provides a production process of the weather-resistant daylighting panel, which comprises the following steps:
s1, weighing the components according to the formula of the weather-resistant daylighting panel for later use;
s2, mixing isophthalic acid type unsaturated polyester resin, polycarbonate, dibutyltin dilaurate and an accelerator to obtain a first mixture;
s3, adding N-methyl pyrrolidone, sodium cocoyl methyl taurate and ethylhexyl methoxycinnamate into an acrylic emulsion, heating to 80-85 ℃, adding epoxy resin, uniformly mixing to obtain a mixed emulsion, mixing ceramic fibers and glass fibers to obtain mixed fibers, coating the mixed emulsion on the surface of the mixed fibers, and drying to obtain a second mixed material;
s4, adding the second mixture obtained in the step S3 into the first mixture obtained in the step S2, adding calcium formate and methyl ethyl ketone peroxide, and curing and forming to obtain the weather-resistant daylighting panel.
As a further technical scheme, the curing molding temperature in the step S4 is 85-90 ℃.
The working principle and the beneficial effects of the invention are as follows:
1. the prepared daylighting panel has excellent weather resistance, good heat resistance, thermal stability and light transmittance due to the specific formula and production process, the temperature resistance limit is-80-180 ℃, the thermal deformation temperature is up to 229 ℃, and the thermal expansion coefficient is as low as 2.0 multiplied by 10-5m/m/DEG C, the light transmittance is up to 89.5 percent, meanwhile, the mechanical property of the daylighting panel is greatly improved, the bending strength is up to 279MPa, the tensile strength is up to 214MPa, and the Rockwell hardness is up to 68 HBa. Therefore, the daylighting panel obtained by the invention has good weather resistance and heat-resistant stability, high strength, good toughness and good service performance, and effectively solves the technical problems of low temperature resistance limit and poor weather resistance of the daylighting panel in the prior art.
2. In the invention, the ceramic fiber is added into the raw materials of the daylighting panel, so that the strength, hardness, thermal stability and heat insulation of the daylighting panel can be obviously improved. The ceramic fiber is formed by high-temperature sintering after mixing and spinning aluminum oxide, silicon oxide, titanium oxide, zirconium oxide, magnesium oxide and cerium oxide, has high strength and thermal stability, and simultaneously has low thermal conductivity and high specific heat, so that the ceramic fiber is added into the daylighting panel and is mutually compatible with the glass fiber, the tensile strength, hardness and thermal stability of the daylighting panel are obviously improved, the strength and hardness of the daylighting panel are high, the thermal deformation temperature is high, the thermal expansion coefficient is small, the mutual compatibility of the zirconium oxide, the magnesium oxide and the cerium oxide improves the weather resistance of the daylighting panel further, the temperature resistance limit of the daylighting panel is improved, and the service life of the daylighting panel is prolonged.
3. In the invention, epoxy resin, acrylic emulsion, N-methyl pyrrolidone, sodium cocoyl methyl taurate and ethylhexyl methoxycinnamate are added into the raw materials of the daylighting panel, in the production process, the N-methyl pyrrolidone, the sodium cocoyl methyl taurate and the ethylhexyl methoxycinnamate are added into the acrylic emulsion, the mixture is heated to 80-85 ℃, the epoxy resin is added, the mixture is uniformly mixed to obtain a mixed emulsion, the mixed emulsion is coated on the surface of a mixed fiber obtained by mixing ceramic fiber and glass fiber, a second mixture is obtained after drying, the second mixture is added into the first mixture to be cured and formed, the compatibility between the mixed fiber and a resin matrix is obviously improved, the mixed fiber is more uniformly dispersed in the resin matrix, the reinforcing effect of the mixed fiber is improved, and the weather resistance of the daylighting panel is obviously improved, the mechanical properties such as tensile strength, hardness and the like are further improved.
4. In the invention, the accelerator is added into the raw material of the daylighting panel to promote the curing and forming process of the daylighting panel, and the mass ratio of triisopropanolamine, aluminum sulfate and cobalt isooctanoate is 2: 1: the mixture of 7 is used as an accelerant and is matched with a curing agent, so that the curing effect is obviously improved, the tensile strength, the Babbitt hardness and the thermal deformation temperature of the daylighting panel are improved, the addition of triisopropanolamine and aluminum sulfate has a synergistic effect on cobalt iso-octoate, the promotion effect of cobalt in the cobalt iso-octoate is increased, and the triisopropanolamine, the aluminum sulfate and the cobalt iso-octoate in a specific ratio are mutually compatible, so that the effect of the accelerant is better exerted, a more efficient curing system is formed, and the performance of the daylighting panel is improved.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
A weather-resistant daylighting panel comprises the following components in parts by weight:
20 parts of m-phthalic acid type unsaturated polyester resin, 15 parts of polycarbonate, 2 parts of epoxy resin, 3 parts of acrylic emulsion, 2 parts of ceramic fiber, 2 parts of glass fiber, 1 part of N-methyl pyrrolidone, 0.2 part of dibutyltin dilaurate, 0.5 part of sodium cocoyl methyl taurate, 0.5 part of ethylhexyl methoxycinnamate, 0.1 part of calcium formate, 1.5 parts of methyl ethyl ketone peroxide and 0.5 part of accelerator.
Wherein, the ceramic fiber is formed by mixing and spinning 30 parts of alumina, 42 parts of silicon oxide, 10 parts of zirconia, 6 parts of titanium oxide, 4 parts of magnesium oxide and 5 parts of cerium oxide and then sintering at high temperature; the diameter of the ceramic fiber is 2-5 μm; the accelerator is triisopropanolamine, aluminum sulfate and cobalt isooctanoate with the mass ratio of 2: 1: 7 in a mixture.
The production process comprises the following steps:
s1, weighing the components according to the formula of the weather-resistant daylighting panel for later use;
s2, mixing isophthalic acid type unsaturated polyester resin, polycarbonate, dibutyltin dilaurate and an accelerator to obtain a first mixture;
s3, adding N-methyl pyrrolidone, sodium cocoyl methyl taurate and ethylhexyl methoxycinnamate into an acrylic emulsion, heating to 80-85 ℃, adding epoxy resin, uniformly mixing to obtain a mixed emulsion, mixing ceramic fibers and glass fibers to obtain mixed fibers, coating the mixed emulsion on the surface of the mixed fibers, and drying to obtain a second mixed material;
s4, adding the second mixture obtained in the step S3 into the first mixture obtained in the step S2, adding calcium formate and methyl ethyl ketone peroxide, and curing and forming at 85-90 ℃ to obtain the weather-resistant daylighting panel.
Example 2
A weather-resistant daylighting panel comprises the following components in parts by weight:
40 parts of m-phthalic acid type unsaturated polyester resin, 30 parts of polycarbonate, 7 parts of epoxy resin, 10 parts of acrylic emulsion, 5 parts of ceramic fiber, 5 parts of glass fiber, 5 parts of N-methyl pyrrolidone, 1.5 parts of dibutyltin dilaurate, 1 part of sodium cocoyl methyl taurate, 2 parts of ethylhexyl methoxycinnamate, 0.5 part of calcium formate, 2.5 parts of methyl ethyl ketone peroxide and 1.5 parts of accelerator.
Wherein, the ceramic fiber is formed by mixing and spinning 30 parts of alumina, 42 parts of silicon oxide, 10 parts of zirconia, 6 parts of titanium oxide, 4 parts of magnesium oxide and 5 parts of cerium oxide and then sintering at high temperature; the diameter of the ceramic fiber is 2-5 μm; the accelerator is triisopropanolamine, aluminum sulfate and cobalt isooctanoate with the mass ratio of 2: 1: 7;
the production process was the same as in example 1.
Example 3
A weather-resistant daylighting panel comprises the following components in parts by weight:
28 parts of isophthalic acid type unsaturated polyester resin, 20 parts of polycarbonate, 4 parts of epoxy resin, 5 parts of acrylic emulsion, 3 parts of ceramic fiber, 3 parts of glass fiber, 2 parts of N-methyl pyrrolidone, 0.6 part of dibutyltin dilaurate, 0.6 part of sodium cocoyl methyl taurate, 0.9 part of ethylhexyl methoxycinnamate, 0.2 part of calcium formate, 1.8 parts of methyl ethyl ketone peroxide and 0.9 part of accelerator.
Wherein, the ceramic fiber is formed by mixing and spinning 30 parts of alumina, 42 parts of silicon oxide, 10 parts of zirconia, 6 parts of titanium oxide, 4 parts of magnesium oxide and 5 parts of cerium oxide and then sintering at high temperature; the diameter of the ceramic fiber is 2-5 μm; the accelerator is triisopropanolamine, aluminum sulfate and cobalt isooctanoate with the mass ratio of 2: 1: 7;
the production process was the same as in example 1.
Example 4
A weather-resistant daylighting panel comprises the following components in parts by weight:
33 parts of isophthalic acid type unsaturated polyester resin, 25 parts of polycarbonate, 6 parts of epoxy resin, 8 parts of acrylic emulsion, 4 parts of ceramic fiber, 4 parts of glass fiber, 4 parts of N-methyl pyrrolidone, 1.1 parts of dibutyltin dilaurate, 0.8 part of sodium cocoyl methyl taurate, 1.5 parts of ethylhexyl methoxycinnamate, 0.4 part of calcium formate, 2.2 parts of methyl ethyl ketone peroxide and 1.3 parts of accelerator.
Wherein, the ceramic fiber is formed by mixing and spinning 30 parts of alumina, 42 parts of silicon oxide, 10 parts of zirconia, 6 parts of titanium oxide, 4 parts of magnesium oxide and 5 parts of cerium oxide and then sintering at high temperature; the diameter of the ceramic fiber is 2-5 μm; the accelerator is triisopropanolamine, aluminum sulfate and cobalt isooctanoate with the mass ratio of 2: 1: 7;
the production process was the same as in example 1.
Example 5
A weather-resistant daylighting panel comprises the following components in parts by weight:
30 parts of m-phthalic acid type unsaturated polyester resin, 23 parts of polycarbonate, 5 parts of epoxy resin, 6 parts of acrylic emulsion, 3 parts of ceramic fiber, 3 parts of glass fiber, 3 parts of N-methyl pyrrolidone, 0.8 part of dibutyltin dilaurate, 0.7 part of sodium cocoyl methyl taurate, 1.2 parts of ethylhexyl methoxycinnamate, 0.3 part of calcium formate, 2 parts of methyl ethyl ketone peroxide and 1 part of accelerator;
wherein, the ceramic fiber is formed by mixing and spinning 30 parts of alumina, 42 parts of silicon oxide, 10 parts of zirconia, 6 parts of titanium oxide, 4 parts of magnesium oxide and 5 parts of cerium oxide and then sintering at high temperature; the diameter of the ceramic fiber is 2-5 μm; the accelerator is triisopropanolamine, aluminum sulfate and cobalt isooctanoate with the mass ratio of 2: 1: 7;
the production process was the same as in example 1.
Example 6
A weather-resistant daylighting panel comprises the following components in parts by weight:
30 parts of m-phthalic acid type unsaturated polyester resin, 23 parts of polycarbonate, 5 parts of epoxy resin, 6 parts of acrylic emulsion, 3 parts of ceramic fiber, 3 parts of glass fiber, 3 parts of N-methyl pyrrolidone, 0.8 part of dibutyltin dilaurate, 0.7 part of sodium cocoyl methyl taurate, 1.2 parts of ethylhexyl methoxycinnamate, 0.3 part of calcium formate, 2 parts of methyl ethyl ketone peroxide and 1 part of accelerator;
wherein the ceramic fiber is formed by mixing 25-35 parts of aluminum oxide, 35-50 parts of silicon oxide, 5 parts of zirconium oxide, 3 parts of titanium oxide, 2 parts of magnesium oxide and 2 parts of cerium oxide, spinning and sintering at high temperature; the diameter of the ceramic fiber is 2-5 μm; the accelerator is triisopropanolamine, aluminum sulfate and cobalt isooctanoate with the mass ratio of 2: 1: 7;
the production process was the same as in example 1.
Example 7
A weather-resistant daylighting panel comprises the following components in parts by weight:
30 parts of m-phthalic acid type unsaturated polyester resin, 23 parts of polycarbonate, 5 parts of epoxy resin, 6 parts of acrylic emulsion, 3 parts of ceramic fiber, 3 parts of glass fiber, 3 parts of N-methyl pyrrolidone, 0.8 part of dibutyltin dilaurate, 0.7 part of sodium cocoyl methyl taurate, 1.2 parts of ethylhexyl methoxycinnamate, 0.3 part of calcium formate, 2 parts of methyl ethyl ketone peroxide and 1 part of accelerator;
wherein, the ceramic fiber is formed by mixing 35 parts of alumina, 50 parts of silicon oxide, 15 parts of zirconia, 10 parts of titanium oxide, 6 parts of magnesium oxide and 8 parts of cerium oxide, spinning and then sintering at high temperature; the diameter of the ceramic fiber is 2-5 μm; the accelerator is triisopropanolamine, aluminum sulfate and cobalt isooctanoate with the mass ratio of 2: 1: 7;
the production process was the same as in example 1.
Comparative example 1
A weather-resistant daylighting panel comprises the following components in parts by weight:
30 parts of m-phthalic acid type unsaturated polyester resin, 23 parts of polycarbonate, 5 parts of epoxy resin, 6 parts of acrylic emulsion, 3 parts of ceramic fiber, 3 parts of glass fiber, 3 parts of N-methyl pyrrolidone, 0.8 part of dibutyltin dilaurate, 0.7 part of sodium cocoyl methyl taurate, 1.2 parts of ethylhexyl methoxycinnamate, 0.3 part of calcium formate, 2 parts of methyl ethyl ketone peroxide and 1 part of accelerator;
wherein the accelerator is triisopropanolamine, aluminum sulfate and cobalt isooctanoate with the mass ratio of 2: 1: 7;
the production process is the same as example 1 except that no ceramic fiber is added in step S3.
Comparative example 2
A weather-resistant daylighting panel comprises the following components in parts by weight:
30 parts of m-phthalic acid type unsaturated polyester resin, 23 parts of polycarbonate, 5 parts of epoxy resin, 6 parts of acrylic emulsion, 3 parts of ceramic fiber, 3 parts of glass fiber, 3 parts of N-methyl pyrrolidone, 0.8 part of dibutyltin dilaurate, 0.7 part of sodium cocoyl methyl taurate, 1.2 parts of ethylhexyl methoxycinnamate, 0.3 part of calcium formate, 2 parts of methyl ethyl ketone peroxide and 1 part of accelerator;
wherein, the ceramic fiber is formed by mixing and spinning 30 parts of alumina, 42 parts of silicon oxide and 6 parts of titanium oxide and then sintering at high temperature; the diameter of the ceramic fiber is 2-5 μm; the accelerator is triisopropanolamine, aluminum sulfate and cobalt isooctanoate with the mass ratio of 2: 1: 7;
the production process was the same as in example 1.
Comparative example 3
A weather-resistant daylighting panel comprises the following components in parts by weight:
30 parts of isophthalic acid type unsaturated polyester resin, 23 parts of polycarbonate, 3 parts of ceramic fiber, 3 parts of glass fiber, 0.8 part of dibutyltin dilaurate, 0.3 part of calcium formate, 2 parts of methyl ethyl ketone peroxide and 1 part of accelerator;
wherein, the ceramic fiber is formed by mixing and spinning 30 parts of alumina, 42 parts of silicon oxide, 10 parts of zirconia, 6 parts of titanium oxide, 4 parts of magnesium oxide and 5 parts of cerium oxide and then sintering at high temperature; the diameter of the ceramic fiber is 2-5 μm; the accelerator is triisopropanolamine, aluminum sulfate and cobalt isooctanoate with the mass ratio of 2: 1: 7;
the production process comprises the following steps of S3: the ceramic fibers and the glass fibers were mixed to obtain a mixed fiber, the second mixed material in step S4 was a mixed fiber, and the rest of the steps were the same as in example 1.
Comparative example 4
A weather-resistant daylighting panel comprises the following components in parts by weight:
30 parts of m-phthalic acid type unsaturated polyester resin, 23 parts of polycarbonate, 5 parts of epoxy resin, 6 parts of acrylic emulsion, 3 parts of ceramic fiber, 3 parts of glass fiber, 3 parts of N-methyl pyrrolidone, 0.8 part of dibutyltin dilaurate, 0.7 part of sodium cocoyl methyl taurate, 1.2 parts of ethylhexyl methoxycinnamate, 0.3 part of calcium formate, 2 parts of methyl ethyl ketone peroxide and 1 part of accelerator;
wherein, the ceramic fiber is formed by mixing and spinning 30 parts of alumina, 42 parts of silicon oxide, 10 parts of zirconia, 6 parts of titanium oxide, 4 parts of magnesium oxide and 5 parts of cerium oxide and then sintering at high temperature; the diameter of the ceramic fiber is 2-5 μm; the accelerator is triisopropanolamine, aluminum sulfate and cobalt isooctanoate with the mass ratio of 2: 1: 7;
the production process comprises the following steps:
s1, weighing the components according to the formula for later use;
s2, mixing isophthalic acid type unsaturated polyester resin, polycarbonate, dibutyltin dilaurate, N-methyl pyrrolidone, sodium cocoyl methyl taurate, ethylhexyl methoxycinnamate, acrylic emulsion, epoxy resin and an accelerator to obtain a first mixture;
s3, mixing the ceramic fiber and the glass fiber to obtain mixed fiber;
s4, adding the mixed fiber obtained in the step S3 into the first mixed material obtained in the step S2, adding calcium formate and methyl ethyl ketone peroxide, and curing and forming to obtain the weather-resistant daylighting panel.
Comparative example 5
A weather-resistant daylighting panel comprises the following components in parts by weight:
30 parts of m-phthalic acid type unsaturated polyester resin, 23 parts of polycarbonate, 5 parts of epoxy resin, 6 parts of acrylic emulsion, 3 parts of ceramic fiber, 3 parts of glass fiber, 3 parts of N-methyl pyrrolidone, 0.8 part of dibutyltin dilaurate, 0.7 part of sodium cocoyl methyl taurate, 1.2 parts of ethylhexyl methoxycinnamate, 0.3 part of calcium formate, 2 parts of methyl ethyl ketone peroxide and 1 part of accelerator;
wherein, the ceramic fiber is formed by mixing and spinning 30 parts of alumina, 42 parts of silicon oxide, 10 parts of zirconia, 6 parts of titanium oxide, 4 parts of magnesium oxide and 5 parts of cerium oxide and then sintering at high temperature; the diameter of the ceramic fiber is 2-5 μm; the accelerator is triisopropanolamine and cobalt isooctanoate with the mass ratio of 2: 7;
the production process was the same as in example 1.
Comparative example 6
A weather-resistant daylighting panel comprises the following components in parts by weight:
30 parts of m-phthalic acid type unsaturated polyester resin, 23 parts of polycarbonate, 5 parts of epoxy resin, 6 parts of acrylic emulsion, 3 parts of ceramic fiber, 3 parts of glass fiber, 3 parts of N-methyl pyrrolidone, 0.8 part of dibutyltin dilaurate, 0.7 part of sodium cocoyl methyl taurate, 1.2 parts of ethylhexyl methoxycinnamate, 0.3 part of calcium formate, 2 parts of methyl ethyl ketone peroxide and 1 part of accelerator;
wherein, the ceramic fiber is formed by mixing and spinning 30 parts of alumina, 42 parts of silicon oxide, 10 parts of zirconia, 6 parts of titanium oxide, 4 parts of magnesium oxide and 5 parts of cerium oxide and then sintering at high temperature; the diameter of the ceramic fiber is 2-5 μm; the accelerator is aluminum sulfate and cobalt isooctanoate with the mass ratio of 1: 7;
the production process was the same as in example 1.
Comparative example 7
A weather-resistant daylighting panel comprises the following components in parts by weight:
30 parts of m-phthalic acid type unsaturated polyester resin, 23 parts of polycarbonate, 5 parts of epoxy resin, 6 parts of acrylic emulsion, 3 parts of ceramic fiber, 3 parts of glass fiber, 3 parts of N-methyl pyrrolidone, 0.8 part of dibutyltin dilaurate, 0.7 part of sodium cocoyl methyl taurate, 1.2 parts of ethylhexyl methoxycinnamate, 0.3 part of calcium formate, 2 parts of methyl ethyl ketone peroxide and 1 part of accelerator;
wherein, the ceramic fiber is formed by mixing and spinning 30 parts of alumina, 42 parts of silicon oxide, 10 parts of zirconia, 6 parts of titanium oxide, 4 parts of magnesium oxide and 5 parts of cerium oxide and then sintering at high temperature; the diameter of the ceramic fiber is 2-5 μm; the accelerator is triisopropanolamine, and the mass ratio of aluminum sulfate is 2: 1;
the production process was the same as in example 1.
Comparative example 8
A weather-resistant daylighting panel comprises the following components in parts by weight:
30 parts of m-phthalic acid type unsaturated polyester resin, 23 parts of polycarbonate, 5 parts of epoxy resin, 6 parts of acrylic emulsion, 3 parts of ceramic fiber, 3 parts of glass fiber, 3 parts of N-methyl pyrrolidone, 0.8 part of dibutyltin dilaurate, 0.7 part of sodium cocoyl methyl taurate, 1.2 parts of ethylhexyl methoxycinnamate, 0.3 part of calcium formate, 2 parts of methyl ethyl ketone peroxide and 1 part of accelerator;
wherein, the ceramic fiber is formed by mixing and spinning 30 parts of alumina, 42 parts of silicon oxide, 10 parts of zirconia, 6 parts of titanium oxide, 4 parts of magnesium oxide and 5 parts of cerium oxide and then sintering at high temperature; the diameter of the ceramic fiber is 2-5 μm; the accelerator is triisopropanolamine, aluminum sulfate and cobalt isooctanoate with the mass ratio of 1: 1: 7;
the production process was the same as in example 1.
Comparative example 9
A weather-resistant daylighting panel comprises the following components in parts by weight:
30 parts of m-phthalic acid type unsaturated polyester resin, 23 parts of polycarbonate, 5 parts of epoxy resin, 6 parts of acrylic emulsion, 3 parts of ceramic fiber, 3 parts of glass fiber, 3 parts of N-methyl pyrrolidone, 0.8 part of dibutyltin dilaurate, 0.7 part of sodium cocoyl methyl taurate, 1.2 parts of ethylhexyl methoxycinnamate, 0.3 part of calcium formate, 2 parts of methyl ethyl ketone peroxide and 1 part of accelerator;
wherein, the ceramic fiber is formed by mixing and spinning 30 parts of alumina, 42 parts of silicon oxide, 10 parts of zirconia, 6 parts of titanium oxide, 4 parts of magnesium oxide and 5 parts of cerium oxide and then sintering at high temperature; the diameter of the ceramic fiber is 2-5 μm; the accelerator is triisopropanolamine, aluminum sulfate and cobalt isooctanoate with the mass ratio of 2: 3: 7;
the production process was the same as in example 1.
Comparative example 10
A weather-resistant daylighting panel comprises the following components in parts by weight:
30 parts of m-phthalic acid type unsaturated polyester resin, 23 parts of polycarbonate, 5 parts of epoxy resin, 6 parts of acrylic emulsion, 3 parts of ceramic fiber, 3 parts of glass fiber, 3 parts of N-methyl pyrrolidone, 0.8 part of dibutyltin dilaurate, 0.7 part of sodium cocoyl methyl taurate, 1.2 parts of ethylhexyl methoxycinnamate, 0.3 part of calcium formate, 2 parts of methyl ethyl ketone peroxide and 1 part of accelerator;
wherein, the ceramic fiber is formed by mixing and spinning 30 parts of alumina, 42 parts of silicon oxide, 10 parts of zirconia, 6 parts of titanium oxide, 4 parts of magnesium oxide and 5 parts of cerium oxide and then sintering at high temperature; the diameter of the ceramic fiber is 2-5 μm; the accelerator is triisopropanolamine, aluminum sulfate and cobalt isooctanoate with the mass ratio of 2: 1: 5 with a mixture of;
the production process was the same as in example 1.
The following performance tests were performed on the daylighting panels prepared in examples 1 to 7 and comparative examples 1 to 10:
1. temperature tolerance limit: testing the temperature resistance limit of the sample according to the amplification specified in HG/T4091-2009 Plastic Lining Equipment temperature resistance test method;
2. bending strength: testing the bending strength of the sample according to the method specified in GB/T1449-2005, method for testing the bending performance of the fiber reinforced plastics;
3. tensile strength: testing the tensile strength of the sample according to the method specified in GB/T1447-2005, tensile property test method for fiber reinforced plastics;
4. babbitt hardness: the samples were tested for Baker's hardness according to the method specified in GB/T3854-2005 "procedure for Barkel hardness testing of reinforced plastics";
5. light transmittance: the light transmittance of the sample was measured according to the method specified in GB/T4206-2008 "measurement of light transmittance and haze of transparent plastics";
6. heat distortion temperature: testing the heat distortion temperature of the sample according to the method specified in GB/T1634-2004 'measurement of Plastic load distortion temperature';
7. coefficient of thermal conductivity: testing the thermal conductivity of the sample according to the method specified in GB/T3139-2005, test method for thermal conductivity of fiber reinforced plastics;
8. coefficient of thermal expansion: testing the thermal expansion coefficient of a sample according to a method specified in GB/T2572-2005, test method for average linear expansion coefficient of fiber reinforced plastics;
the test results are given in the following table:
TABLE 1 Performance test results of the daylighting panels of examples 1 to 7 and comparative examples 1 to 10
As can be seen from the data in Table 1, compared with the daylighting panels of comparative examples 1 to 10, the daylighting panels of examples 1 to 7 have significantly improved temperature resistance, good heat resistance, good thermal stability and good light transmittance, the temperature resistance is-80 ℃ to 180 ℃, the thermal deformation temperature is as high as 229 ℃, and the thermal expansion coefficient is as low as 2.0 x 10-5m/m/DEG C, the light transmittance is up to 89.5 percent, meanwhile, the mechanical property of the daylighting panel is greatly improved, the bending strength is up to 279MPa, the tensile strength is up to 215MPa, and the Rockwell hardness is up to 68 HBa. Therefore, the daylighting panels prepared in embodiments 1 to 7 of the invention have good weather resistance and heat stability, high strength, good toughness and good service performance, and effectively solve the technical problems of low temperature resistance limit and poor weather resistance of the daylighting panels in the prior art. The formula and the preparation method of the embodiment 5 are relatively better embodiments of the invention, and the prepared daylighting panel has better comprehensive performance.
Compared with the daylighting panel of example 5, the daylighting panel of comparative example 1 has reduced temperature resistance limit, tensile strength, hardness, light transmittance and thermal deformation temperature, and increased thermal conductivity and thermal expansion coefficient, and the daylighting panel of comparative example 2 has reduced temperature resistance limit, light transmittance and thermal deformation temperature, and increased thermal conductivity and thermal expansion coefficient, because no ceramic fiber is added in the raw material of the daylighting panel of comparative example 1, the ceramic fiber in the raw material of the daylighting panel of comparative example 2 is composed of alumina, silica and titanium oxide, and no zirconia, magnesia and cerium oxide are added, which indicates that the addition of the ceramic fiber can significantly improve the strength, hardness, thermal stability and thermal insulation of the daylighting panel. The ceramic fiber is formed by high-temperature sintering after mixing and spinning aluminum oxide, silicon oxide, titanium oxide, zirconium oxide, magnesium oxide and cerium oxide, has high strength and thermal stability, and simultaneously has low thermal conductivity and high specific heat, so that the ceramic fiber is added into the daylighting panel and is mutually compatible with the glass fiber, the tensile strength, hardness and thermal stability of the daylighting panel are obviously improved, the strength and hardness of the daylighting panel are high, the thermal deformation temperature is high, the thermal expansion coefficient is small, the mutual compatibility of the zirconium oxide, the magnesium oxide and the cerium oxide improves the weather resistance of the daylighting panel further, the temperature resistance limit of the daylighting panel is improved, and the service life of the daylighting panel is prolonged.
Compared with the daylighting panel of the embodiment 5, the daylighting panels of the comparative examples 3 and 4 have relatively poor performances because the raw materials of the daylighting panel of the comparative example 3 are not added with epoxy resin, acrylic emulsion, N-methyl pyrrolidone, sodium cocoyl methyl taurate and ethylhexyl methoxycinnamate, and the components in the raw materials are directly mixed in the production process of the daylighting panel of the comparative example 4, which means that the N-methyl pyrrolidone, the sodium cocoyl methyl taurate and the ethylhexyl methoxycinnamate are firstly added into the acrylic emulsion, heated to 80-85 ℃, added with the epoxy resin, uniformly mixed to obtain a mixed emulsion, coated on the surface of a mixed fiber obtained by mixing ceramic fibers and glass fibers, dried to obtain a second mixed material, then added into the first mixed material to be cured and molded, so that the compatibility between the mixed fiber and a resin matrix is remarkably improved, the dispersion of the mixed fibers in the resin matrix is more uniform, so that the reinforcing effect of the mixed fibers is improved, the weather resistance of the daylighting panel is obviously improved, and the mechanical properties such as tensile strength and hardness are further improved.
Compared with the daylighting panel of example 5, the daylighting panels of comparative examples 5-10 all have reduced tensile strength, babbitt hardness and heat distortion temperature, because the mass ratio of the promoter triisopropanolamine to cobalt isooctanoate in the daylighting panel raw material of comparative example 5 is 2: 7, aluminum sulfate is not added, and the mass ratio of aluminum sulfate as an accelerator to cobalt isooctanoate in the raw material of the daylighting panel of the comparative example 6 is 1: 7, triisopropanolamine is not added, and the mass ratio of the accelerator to the aluminum sulfate in the raw material of the daylighting panel in the comparative example 7 is 2: 1, the cobalt isooctanoate is not added, and the accelerator in the daylighting panel raw material of the comparative example 8 is triisopropanolamine, aluminum sulfate and the cobalt isooctanoate with the mass ratio of 1: 1: 7, the accelerator in the raw material of the daylighting panel of comparative example 9 is triisopropanolamine, aluminum sulfate and cobalt isooctanoate with the mass ratio of 2: 3: 7, the accelerator in the raw material of the daylighting panel of the comparative example 10 is triisopropanolamine, aluminum sulfate and cobalt isooctanoate with the mass ratio of 2: 1: 5, the addition of the accelerator is illustrated, the curing and forming process of the daylighting panel is accelerated, and the mass ratio of triisopropanolamine, aluminum sulfate and cobalt isooctanoate is 2: 1: the mixture of 7 is used as an accelerant and is matched with a curing agent, so that the curing effect is obviously improved, the tensile strength, the Babbitt hardness and the thermal deformation temperature of the daylighting panel are improved, the addition of triisopropanolamine and aluminum sulfate has a synergistic effect on cobalt iso-octoate, the promotion effect of cobalt in the cobalt iso-octoate is increased, and the triisopropanolamine, the aluminum sulfate and the cobalt iso-octoate in a specific ratio are mutually compatible, so that the effect of the accelerant is better exerted, a more efficient curing system is formed, and the performance of the daylighting panel is improved.
The present invention is not limited to the above preferred embodiments, and any modifications, equivalent substitutions, improvements, etc. within the spirit and principle of the present invention should be included in the protection scope of the present invention.
Claims (8)
1. The weather-resistant daylighting panel is characterized by comprising the following components in parts by weight:
20-40 parts of m-phthalic acid type unsaturated polyester resin, 15-30 parts of polycarbonate, 2-7 parts of epoxy resin, 3-10 parts of acrylic emulsion, 2-5 parts of ceramic fiber, 2-5 parts of glass fiber, 1-5 parts of N-methyl pyrrolidone, 0.2-1.5 parts of dibutyltin dilaurate, 0.5-1 part of sodium cocoyl methyl taurate, 0.5-2 parts of ethylhexyl methoxycinnamate, 0.1-0.5 part of calcium formate, 1.5-2.5 parts of methyl ethyl ketone peroxide and 0.5-1.5 parts of accelerator.
2. The weather-resistant daylighting panel according to claim 1, which is characterized by comprising the following components in parts by weight:
30 parts of m-phthalic acid type unsaturated polyester resin, 23 parts of polycarbonate, 5 parts of epoxy resin, 6 parts of acrylic emulsion, 3 parts of ceramic fiber, 3 parts of glass fiber, 3 parts of N-methyl pyrrolidone, 0.8 part of dibutyltin dilaurate, 0.7 part of sodium cocoyl methyl taurate, 1.2 parts of ethylhexyl methoxycinnamate, 0.3 part of calcium formate, 2 parts of methyl ethyl ketone peroxide and 1 part of accelerator.
3. The weather-resistant daylighting panel according to claim 1 or 2, wherein the ceramic fiber comprises the following components in parts by weight:
25-35 parts of aluminum oxide, 35-50 parts of silicon oxide, 5-15 parts of zirconium oxide, 3-10 parts of titanium oxide, 2-6 parts of magnesium oxide and 2-8 parts of cerium oxide.
4. The weather-resistant daylighting panel according to claim 3, wherein the ceramic fiber comprises the following components in parts by weight:
30 parts of aluminum oxide, 42 parts of silicon oxide, 10 parts of zirconium oxide, 6 parts of titanium oxide, 4 parts of magnesium oxide and 5 parts of cerium oxide.
5. The weather-resistant daylighting panel according to claim 3, wherein the accelerator is triisopropanolamine, aluminum sulfate and cobalt isooctanoate in a mass ratio of 2: 1: 7 in a mixture.
6. The weather-resistant daylighting panel of claim 3, wherein the ceramic fibers have a diameter of 2-5 μm.
7. The production process of the weather-resistant daylighting panel is characterized by comprising the following steps of:
s1, weighing the components for later use according to the formula of the weather-resistant daylighting panel disclosed by any one of claims 1-6;
s2, mixing isophthalic acid type unsaturated polyester resin, polycarbonate, dibutyltin dilaurate and an accelerator to obtain a first mixture;
s3, adding N-methyl pyrrolidone, sodium cocoyl methyl taurate and ethylhexyl methoxycinnamate into an acrylic emulsion, heating to 80-85 ℃, adding epoxy resin, uniformly mixing to obtain a mixed emulsion, mixing ceramic fibers and glass fibers to obtain mixed fibers, coating the mixed emulsion on the surface of the mixed fibers, and drying to obtain a second mixed material;
s4, adding the second mixture obtained in the step S3 into the first mixture obtained in the step S2, adding calcium formate and methyl ethyl ketone peroxide, and curing and forming to obtain the weather-resistant daylighting panel.
8. The process for producing a weather-resistant daylighting panel according to claim 7, wherein the curing molding temperature in step S4 is 85-90 ℃.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20120220709A1 (en) * | 2009-10-30 | 2012-08-30 | Idemitsu Kosan Co., Ltd. | Polycarbonate resin composition, polycarbonate resin molded article, and manufacturing method therefor |
| CN104231584A (en) * | 2014-09-25 | 2014-12-24 | 扬州万盛实业有限公司 | Low-shrinkage medium-temperature-cured high-efficiency flame-retardant unsaturated polyester fiberglass reinforced plastic board and preparation method thereof |
| CN105647168A (en) * | 2014-11-24 | 2016-06-08 | 霍尼韦尔国际公司 | Heat-conducting composite material and method for preparing same |
| US20180009926A1 (en) * | 2015-04-21 | 2018-01-11 | Showa Denko K.K. | Radical-polymerizable resin composition, curing method thereof, method of producing same, use of radical-polymerizable resin composition, and use method of thereof |
| CN108587057A (en) * | 2018-04-10 | 2018-09-28 | 安徽宏志建材科技有限公司 | A kind of daylighting weather-resistant composite, plane skylight and preparation method thereof |
-
2019
- 2019-11-27 CN CN201911177784.4A patent/CN110922731B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20120220709A1 (en) * | 2009-10-30 | 2012-08-30 | Idemitsu Kosan Co., Ltd. | Polycarbonate resin composition, polycarbonate resin molded article, and manufacturing method therefor |
| CN104231584A (en) * | 2014-09-25 | 2014-12-24 | 扬州万盛实业有限公司 | Low-shrinkage medium-temperature-cured high-efficiency flame-retardant unsaturated polyester fiberglass reinforced plastic board and preparation method thereof |
| CN105647168A (en) * | 2014-11-24 | 2016-06-08 | 霍尼韦尔国际公司 | Heat-conducting composite material and method for preparing same |
| US20180009926A1 (en) * | 2015-04-21 | 2018-01-11 | Showa Denko K.K. | Radical-polymerizable resin composition, curing method thereof, method of producing same, use of radical-polymerizable resin composition, and use method of thereof |
| CN108587057A (en) * | 2018-04-10 | 2018-09-28 | 安徽宏志建材科技有限公司 | A kind of daylighting weather-resistant composite, plane skylight and preparation method thereof |
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Denomination of invention: A weather resistant daylighting board and its processing technology Effective date of registration: 20230803 Granted publication date: 20210817 Pledgee: Tangshan Branch of China Postal Savings Bank Co.,Ltd. Pledgor: Tangshan Runfeng Composite Material Co.,Ltd. Registration number: Y2023980050728 |