CN110915804A - Organic dye mildew preventive - Google Patents
Organic dye mildew preventive Download PDFInfo
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- CN110915804A CN110915804A CN201911325094.9A CN201911325094A CN110915804A CN 110915804 A CN110915804 A CN 110915804A CN 201911325094 A CN201911325094 A CN 201911325094A CN 110915804 A CN110915804 A CN 110915804A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/02—Amines; Quaternary ammonium compounds
- A01N33/12—Quaternary ammonium compounds
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/02—Acyclic compounds
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/08—Oxygen or sulfur directly attached to an aromatic ring system
- A01N31/16—Oxygen or sulfur directly attached to an aromatic ring system with two or more oxygen or sulfur atoms directly attached to the same aromatic ring system
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/06—Unsaturated carboxylic acids or thio analogues thereof; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/10—Aromatic or araliphatic carboxylic acids, or thio analogues thereof; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/04—Sulfonic acids; Derivatives thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/12—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing acyclic or cycloaliphatic radicals
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/06—Aluminium; Calcium; Magnesium; Compounds thereof
Abstract
The invention discloses an organic dye mildew preventive, which comprises an agent A, an agent B and deionized water, wherein the agent A comprises the following components in parts by weight: 5-10 parts of alkyl dimethyl benzyl ammonium chloride, 5-10 parts of sodium diacetate, 5-10 parts of sodium xylene sulfonate, 10-12 parts of calcium hydroxide, 1-6 parts of carbon tetrachloride, 1-5 parts of benzoic acid and 10-20 parts of ethylene glycol butyl ether, wherein the agent B comprises the following components in parts by weight: 3-5 parts of eugenol, 5-10 parts of chitosan, 10-15 parts of polyoxyethylene alkyl phosphate and 10-15 parts of polyacrylate emulsion.
Description
Technical Field
The invention relates to the technical field of aluminum alloy surface treatment, in particular to an organic dye mildew preventive.
Background
In order to overcome the defects of the aluminum alloy in the aspects of surface hardness, wear resistance and the like, expand the application range and prolong the service life, the surface treatment technology is an indispensable ring in the use of the aluminum alloy, and the anodic oxidation technology is most widely and successfully applied. Anodic oxidation (electrochemical oxidation), which refers to the electrochemical oxidation of metals or alloys, is the process of forming an oxide film on aluminum products (anodes) by the action of an applied current under the corresponding electrolyte and specific process conditions. Anodization is generally referred to as sulfuric acid anodization if not specifically indicated. An anti-mildew agent is often added into the aluminum alloy anode oxidation dye to improve the storage life, but the existing anti-mildew agent has the problems of non-lasting effect and the like.
Disclosure of Invention
The invention aims to provide an organic dye mildew preventive to solve the problems in the background technology.
In order to achieve the purpose, the invention provides the following technical scheme:
the organic dye mildew preventive comprises an agent A, an agent B and deionized water, wherein the agent A comprises the following components in parts by weight: 5-10 parts of alkyl dimethyl benzyl ammonium chloride, 5-10 parts of sodium diacetate, 5-10 parts of sodium xylene sulfonate, 10-12 parts of calcium hydroxide, 1-6 parts of carbon tetrachloride, 1-5 parts of benzoic acid and 10-20 parts of ethylene glycol butyl ether, wherein the agent B comprises the following components in parts by weight: 3-5 parts of eugenol, 5-10 parts of chitosan, 10-15 parts of polyoxyethylene alkyl phosphate and 10-15 parts of polyacrylate emulsion.
As a further scheme of the invention: the weight ratio of the agent A to the agent B to the deionized water is 1: (1.1-1.3): (5-7).
As a further scheme of the invention: the agent A comprises the following components in parts by weight: 5 parts by weight of alkyl dimethyl benzyl ammonium chloride, 5 parts by weight of sodium diacetate, 5 parts by weight of sodium xylene sulfonate, 10 parts by weight of calcium hydroxide, 1 part by weight of carbon tetrachloride, 1 part by weight of benzoic acid and 10 parts by weight of ethylene glycol monobutyl ether, wherein the agent B comprises the following components in parts by weight: 3 parts by weight of eugenol, 5 parts by weight of chitosan, 10 parts by weight of polyoxyethylene alkyl phosphate ester and 10 parts by weight of polyacrylate emulsion.
As a further scheme of the invention: the weight ratio of the agent A to the agent B to the deionized water is 1: 1.1: 5.
As a further scheme of the invention: the agent A comprises the following components in parts by weight: 8 parts by weight of alkyl dimethyl benzyl ammonium chloride, 8 parts by weight of sodium diacetate, 8 parts by weight of sodium xylene sulfonate, 11 parts by weight of calcium hydroxide, 4 parts by weight of carbon tetrachloride, 3 parts by weight of benzoic acid and 15 parts by weight of ethylene glycol monobutyl ether, wherein the agent B comprises the following components in parts by weight: 4 parts by weight of eugenol, 7 parts by weight of chitosan, 13 parts by weight of polyoxyethylene alkyl phosphate ester and 13 parts by weight of polyacrylate emulsion.
As a further scheme of the invention: the weight ratio of the agent A to the agent B to the deionized water is 1: 1.2: 6.
As a further scheme of the invention: the agent A comprises the following components in parts by weight: 10 parts by weight of alkyl dimethyl benzyl ammonium chloride, 10 parts by weight of sodium diacetate, 10 parts by weight of sodium xylene sulfonate, 12 parts by weight of calcium hydroxide, 6 parts by weight of carbon tetrachloride, 5 parts by weight of benzoic acid and 20 parts by weight of ethylene glycol monobutyl ether, wherein the agent B comprises the following components in parts by weight: 5 parts by weight of eugenol, 10 parts by weight of chitosan, 15 parts by weight of polyoxyethylene alkyl phosphate ester and 15 parts by weight of polyacrylate emulsion.
As a further scheme of the invention: the weight ratio of the agent A to the agent B to the deionized water is 1: 1.3: 7.
Compared with the prior art, the invention has the beneficial effects that:
the organic dye mildew inhibitor provided by the invention has good antibacterial performance and mildew resistance, and is good in durability, stable in hydrolysis, small in metal corrosion, good in thermal stability, long in mildew resistance effect and stable.
Detailed Description
The technical solutions in the embodiments of the present invention are clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The first embodiment is as follows:
the organic dye mildew preventive comprises an agent A, an agent B and deionized water, wherein the agent A comprises the following components in parts by weight: 5 parts by weight of alkyl dimethyl benzyl ammonium chloride, 5 parts by weight of sodium diacetate, 5 parts by weight of sodium xylene sulfonate, 10 parts by weight of calcium hydroxide, 1 part by weight of carbon tetrachloride, 1 part by weight of benzoic acid and 10 parts by weight of ethylene glycol monobutyl ether, wherein the agent B comprises the following components in parts by weight: 3 parts by weight of eugenol, 5 parts by weight of chitosan, 10 parts by weight of polyoxyethylene alkyl phosphate ester and 10 parts by weight of polyacrylate emulsion.
The weight ratio of the agent A to the agent B to the deionized water is 1: 1.1: 5.
example two:
the organic dye mildew preventive comprises an agent A, an agent B and deionized water, wherein the agent A comprises the following components in parts by weight: 8 parts by weight of alkyl dimethyl benzyl ammonium chloride, 8 parts by weight of sodium diacetate, 8 parts by weight of sodium xylene sulfonate, 11 parts by weight of calcium hydroxide, 4 parts by weight of carbon tetrachloride, 3 parts by weight of benzoic acid and 15 parts by weight of ethylene glycol monobutyl ether, wherein the agent B comprises the following components in parts by weight: 4 parts by weight of eugenol, 7 parts by weight of chitosan, 13 parts by weight of polyoxyethylene alkyl phosphate ester and 13 parts by weight of polyacrylate emulsion.
The weight ratio of the agent A to the agent B to the deionized water is 1: 1.2: 6.
example three:
the organic dye mildew preventive comprises an agent A, an agent B and deionized water, wherein the agent A comprises the following components in parts by weight: 10 parts by weight of alkyl dimethyl benzyl ammonium chloride, 10 parts by weight of sodium diacetate, 10 parts by weight of sodium xylene sulfonate, 12 parts by weight of calcium hydroxide, 6 parts by weight of carbon tetrachloride, 5 parts by weight of benzoic acid and 20 parts by weight of ethylene glycol monobutyl ether, wherein the agent B comprises the following components in parts by weight: 5 parts by weight of eugenol, 10 parts by weight of chitosan, 15 parts by weight of polyoxyethylene alkyl phosphate ester and 15 parts by weight of polyacrylate emulsion.
The weight ratio of the agent A to the agent B to the deionized water is 1: 1.3: 7.
test example:
the first embodiment, the second embodiment, the third embodiment and a certain commercially available organic dye mildew preventive are subjected to antibacterial and mildew-proof performance tests, the antibacterial test standard refers to GB/T21866-2008 'antibacterial coating (paint film) antibacterial test method and antibacterial effect', the mildew-proof performance test standard refers to GB/T1741-2007 'paint film mildew resistance test method', and the test results are shown in the following table:
table 1:
table 2:
as can be seen from tables 1 and 2, the organic dye mildew preventive provided by the invention has better antibacterial performance and mildew resistance than certain commercially available organic dye mildew preventive, and has the advantages of good durability, lasting antibacterial performance, high efficiency, broad spectrum, stable hydrolysis and no corrosion to metals.
It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodiments, and that the present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein.
Claims (8)
1. The organic dye mildew preventive is characterized by comprising an agent A, an agent B and deionized water, wherein the agent A comprises the following components in parts by weight: 5-10 parts of alkyl dimethyl benzyl ammonium chloride, 5-10 parts of sodium diacetate, 5-10 parts of sodium xylene sulfonate, 10-12 parts of calcium hydroxide, 1-6 parts of carbon tetrachloride, 1-5 parts of benzoic acid and 10-20 parts of ethylene glycol butyl ether, wherein the agent B comprises the following components in parts by weight: 3-5 parts of eugenol, 5-10 parts of chitosan, 10-15 parts of polyoxyethylene alkyl phosphate and 10-15 parts of polyacrylate emulsion.
2. The organic dye mildew preventive according to claim 1, wherein the weight ratio of the agent A to the agent B to the deionized water is 1: (1.1-1.3): (5-7).
3. The organic dye mildew preventive according to claim 2, wherein the agent A comprises the following components in parts by weight: 5 parts by weight of alkyl dimethyl benzyl ammonium chloride, 5 parts by weight of sodium diacetate, 5 parts by weight of sodium xylene sulfonate, 10 parts by weight of calcium hydroxide, 1 part by weight of carbon tetrachloride, 1 part by weight of benzoic acid and 10 parts by weight of ethylene glycol monobutyl ether, wherein the agent B comprises the following components in parts by weight: 3 parts by weight of eugenol, 5 parts by weight of chitosan, 10 parts by weight of polyoxyethylene alkyl phosphate ester and 10 parts by weight of polyacrylate emulsion.
4. The organic dye mildew preventive according to claim 2, wherein the weight ratio of the agent A to the agent B to the deionized water is 1: 1.1: 5.
5. the organic dye mildew preventive according to claim 2, wherein the agent A comprises the following components in parts by weight: 8 parts by weight of alkyl dimethyl benzyl ammonium chloride, 8 parts by weight of sodium diacetate, 8 parts by weight of sodium xylene sulfonate, 11 parts by weight of calcium hydroxide, 4 parts by weight of carbon tetrachloride, 3 parts by weight of benzoic acid and 15 parts by weight of ethylene glycol monobutyl ether, wherein the agent B comprises the following components in parts by weight: 4 parts by weight of eugenol, 7 parts by weight of chitosan, 13 parts by weight of polyoxyethylene alkyl phosphate ester and 13 parts by weight of polyacrylate emulsion.
6. The organic dye mildew preventive according to claim 2, wherein the weight ratio of the agent A to the agent B to the deionized water is 1: 1.2: 6.
7. the organic dye mildew preventive according to claim 2, wherein the agent A comprises the following components in parts by weight: 10 parts by weight of alkyl dimethyl benzyl ammonium chloride, 10 parts by weight of sodium diacetate, 10 parts by weight of sodium xylene sulfonate, 12 parts by weight of calcium hydroxide, 6 parts by weight of carbon tetrachloride, 5 parts by weight of benzoic acid and 20 parts by weight of ethylene glycol monobutyl ether, wherein the agent B comprises the following components in parts by weight: 5 parts by weight of eugenol, 10 parts by weight of chitosan, 15 parts by weight of polyoxyethylene alkyl phosphate ester and 15 parts by weight of polyacrylate emulsion.
8. The organic dye mildew preventive according to claim 2, wherein the weight ratio of the agent A to the agent B to the deionized water is 1: 1.3: 7.
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CN201911325094.9A CN110915804A (en) | 2019-12-20 | 2019-12-20 | Organic dye mildew preventive |
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CN201911325094.9A CN110915804A (en) | 2019-12-20 | 2019-12-20 | Organic dye mildew preventive |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN114197011A (en) * | 2021-11-27 | 2022-03-18 | 鸿富锦精密电子(成都)有限公司 | Anodic oxidation dyeing additive, anodic oxidation dyeing additive solution, preparation method of anodic oxidation dyeing additive solution and anodic oxidation dyeing method |
JP2022136905A (en) * | 2021-03-08 | 2022-09-21 | フィーネ株式会社 | Sterilizing liquid |
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CN108935496A (en) * | 2018-06-29 | 2018-12-07 | 广州超威日化股份有限公司 | Long-acting mould-proof bacteria remover and preparation method thereof |
CN109938053A (en) * | 2017-12-21 | 2019-06-28 | 庄法英 | A kind of antibacterial mildew inhibitor |
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JP2022136905A (en) * | 2021-03-08 | 2022-09-21 | フィーネ株式会社 | Sterilizing liquid |
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