CN1108922A - Shampoo composition - Google Patents
Shampoo composition Download PDFInfo
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- CN1108922A CN1108922A CN94107629.6A CN94107629A CN1108922A CN 1108922 A CN1108922 A CN 1108922A CN 94107629 A CN94107629 A CN 94107629A CN 1108922 A CN1108922 A CN 1108922A
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- expression
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
Abstract
A shampoo composition containing the following ingredients: (a) a nonionic surfactant of an alkylene oxide adduct type, (b) a compound of a quaternary ammonium salt type, which has an aliphatic chain or which has an ether, an ester, or an acyl compound having an aliphatic chain, and which has a secondary or tertiary amino group and a quaternary ammonium group, (c) an anionic surfactant, and (d) a water-soluble polymer. The shampoo composition produces excellent creamy foams, and fingers smoothly pass through the hair fibers during shampooing and rinsing. The hair after drying is soft, and is handled easily with natural beauty. The dried hair is smoothly combed. Moreover, the composition is mild to the skin and the hair.
Description
The present invention relates to shampoo Compositions, said composition is soft and has splendid frothing capacity, detergency and fabulous opsonic action skin and hair.
Recently, the behavior of consumer on hair care had very big variation, and this can be from increasing the hair washing number of times and having a preference for situation about wearing one's hair long and find out.Under this development trend, strengthened frothing capacity, had strong detergency, and shampoo that have fabulous opsonic action soft to hair become and be starved of.
In order to satisfy this demand, the present inventor has proposed a kind of composition of detergent with conditioning hair performance.Said composition contains the chemical compound of quaternary, and this chemical compound is a kind of acyl compounds with aliphatic chain, the second month in a season or tertiary amino group and quaternary ammonium group (referring to Japanese Patent Application Publication communique 4-149123 number).
Though said composition has fabulous detergency,, when itself and some purificants or similar products like compare, still need on conditioning performance, be improved.
Therefore, be a long felt need for a kind of, shampoo of having strengthened frothing capacity, having strong detergency and can provide opsonic action can with some purificant match in excellence or beauty soft to hair.
In these cases, the present inventor has carried out extensive studies, found that, the shampoo Compositions that contains chemical compound, anion surfactant and the water-soluble polymer of the non-ionic surface active agent of alkylene oxide adduct type, special quaternary is soft and has good frothing capacity, detergency and fabulous rinse action skin and hair, thereby finished the present invention.
Therefore, the invention provides a kind of shampoo Compositions that comprises following component (a)-(d):
(a) non-ionic surface active agent of alkylene oxide adduct type,
(b) have aliphatic chain or have ether or the quaternary chemical compound of ester or have aliphatic chain and have the acyl compounds of the second month in a season or uncle's amino group and quaternary ammonium group,
(c) anion surfactant and
(d) water-soluble polymer.
Can be used for component of the present invention (a), promptly the example of the non-ionic surface active agent of alkylene oxide adduct type comprises polyoxyalkylene alkyl, polyoxyalkylene alkyl phenyl ether, polyoxyalkylene aliphatic (acid) ester, polyoxyalkylene Sorbitol aliphatic (acid) ester, polyoxyalkylene aliphatic series strand alkanolamide and polyoxyalkylene aliphatic series two alkanolamides.Wherein, preferred polyoxyalkylene alkyl and polyoxyalkylene aliphatic series strand alkanolamide, most preferably polyoxyalkylene alkyl.The oxyalkylene group that adds in these surfactants is C
2-C
4Oxyalkylene group, wherein, preferred examples comprises ethylene oxide and propylene oxide.The addition of these groups is preferably average 3-40 unit, especially preferably on average adds 15-25 unit by each hydrophobic residual group (for example chain alkyl or long acyl).Generally speaking, the following distribution of adding the molecule molal quantity of normal situation wideer a little.Yet to distribution curve and without particular limitation, they can be, and cliffy summit (sharp) distributes or simple the variation.In addition, the chain alkyl of above-mentioned surfactant or the carbon number of long acyl are preferably 6-36, are preferably 8-24 especially.
The instantiation of particularly preferred non-ionic surface active agent (a) comprises polyoxyethylene laurel ether and polyoxyethylene lauric monoethanolamide.
Component of the present invention (a) can be used separately or unite use with two or more.The 1-60%(that accounts for the shampoo Compositions gross weight when the amount of surfactant is by weight), particularly 2-30%(is by weight) time, frothing capacity is very remarkable.
Quaternary is that the chemical compound of component (b) preferably has following formula (1):
In the formula,
R
1: C
7-C
35Straight or branched alkyl or alkenyl,
R
2, R
3R
4: identical or different separately, and expression C
1-C
4Alkyl or hydroxyalkyl or hydrogen,
M:-CONJ-wherein, J represents H, C
1-C
3Alkyl or hydroxyalkyl;-O-; Or-COO-and
Y:H, C
1-C
36Straight or branched alkyl, alkenyl or hydroxyalkyl or following groups:
Condition is, is C at J
1-C
3Under the situation of alkyl or hydroxyalkyl, Y is neither C
1-C
3Alkyl neither C
1-C
3Hydroxyalkyl,
X:H or hydroxyl,
A: halide ion, OH or organic anion, for example C
1-C
4The alkylsurfuric acid group,
M:2 or 3 number and
The integer of n:0-5, the condition that comprises be, when n equaled 1, X was H or hydroxyl and when n equals 0,2,3,4 or 5, and X is H.
In formula (1), M represents-CONJ-and-COO-,-CONJ-is particularly preferred.In other words, in the chemical compound of the quaternary of formula (1), be preferred with the chemical compound of formula (2) expression.
In the formula, R
1, R
2, R
3, R
4, J, X, A, m be identical with above-mentioned definition with n, and Y ' expression H, C
1-C
3Alkyl or hydroxyalkyl or following groups:
Condition is, is C at J
1-C
3Under the situation of alkyl or hydroxyalkyl, Y is neither C
1-C
3Alkyl neither C
1-C
3Hydroxyalkyl.
At quaternary is in the chemical compound of component (b), and the chemical compound of representing with formula (3) is preferred.They can comprise in process of production the chemical compound as the formula (5) or the formula (6) of byproduct production.
In the formula,
R
1The same with the definition of A, R
2 ', R
3 'And R
4 'Identical or different separately, and expression C
1-C
4Alkyl or hydroxyalkyl.
In the chemical compound of the quaternary of representing with formula (3), R wherein
1Be C
7-C
21, C particularly
11-C
17The alkyl of straight or branched or the chemical compound of alkenyl be preferred.Particularly, R wherein
1CO-is lauroyl or myristoyl and R
2 ', R
3 'And R
4The chemical compound that is methyl is preferred.
The chemical compound of the quaternary of the formula according to the present invention (3) can be by for example following method preparation.
Shown in Figure 1 as following flow process, aliphatic acid (R
1CO
2H) and with the aminoethyl ethanolamine of thereafter formula (7) expression react imidazolidine derivatives with production formula (8).The derivant that is generated alkali treatment is converted into quaternary ammonium compound by the chemical compound reaction with formula (9) then.So, can obtain the chemical compound of the quaternary represented with (3) formula.Consider the dissolubility and the viscosity characteristics that are contained in the water-soluble polymer in the shampoo of the present invention, the chemical compound of above-mentioned gained preferably makes its purification by electrodialysis desalination.
Flow chart 1:
Imidazolineization
Quaternized
In the formula, R
1, R
2-, R
3-, R
4-The same with the definition of A.
The group that another kind of preferred quaternary is the chemical compound of component (b) is the group with following formula (4) expression:
In the formula, R
5, R
6Identical or different separately, and expression C
1-C
4Alkyl, R
7Expression C
2-C
6Alkylidene or alkylene group, R
8Expression C
4-C
36, preferred C
8-C
36Straight or branched alkyl or alkenyl, R
9Expression C
7-C
35Straight or branched alkyl or alkenyl, R
10Expression hydrogen or C
1-C
4Alkyl or hydroxyalkyl, Z are represented halogen, sulfate radical, bisulfate ion, carboxylate radical, and they can be by C
1-C
4Hydroxyl or C
1-C
4Alkyl sulfate replaces, and a represents the integer of 2-9.
In these chemical compounds of formula (4), R wherein
5And R
6Be methyl, R
7Be C
2-C
3Alkylidene, R
8Be hydrogenated tallow alkyl or hydrogenated palm oil alkyl, R
9CO is that the chemical compound of h-tallow aliphatic acyl or hydrogenated palm oil aliphatic acyl is preferred.
The chemical compound that is used for quaternary of the present invention is that the chemical compound of formula (4) can prepare by for example method with following formula.
As shown in following flow chart 2,, can obtain the quaternary chemical compound of formula (4) if the quaternizing agent of the ester amine of formula (10) and acidic materials or formula (11) reacts.
Flow chart 2:
In the formula, R
5, R
6, R
7, R
8, R
9, R
10, Z and a definition the same.
Component of the present invention (b) can be used separately or unite use with two or more.The 1-20%(that accounts for the shampoo Compositions gross weight when the amount of component (b) is by weight), particularly 2-10%(is by weight) time, can obtain fabulous conditioning performance, especially the effect of submissive hair is very remarkable in rinse cycle.
Be used for anion surfactant of the present invention, promptly the embodiment of component (c) comprises the surfactant of following (i)-(xi).
(ⅰ) alkylbenzenesulfonate (alkylbenzenesulfonate with straight or branched of the alkyl that on average contains 10-16 carbon atom is particularly preferred)
(ⅱ) (preferred especially person has straight or branched alkyl or the alkenyl that on average contains 10-20 carbon atom for the alkyl of alkylene oxide adduct type or alkenyl ether sulfate, wherein, be the ratio of 0.1/9.9-9.9/0.1 or be the ratio of 0.1/9.9-9.9/0.1 that in ethylene oxide/propylene oxide per molecule sulfate on average adds oxirane, expoxy propane or the epoxy butane of 0.5-8 mole) in ethylene oxide/butylene oxide.
(ⅲ) alkyl or alkenyl sulfate (preferred especially person has alkyl or the alkenyl salt that on average contains 10-20 carbon atom).
(ⅳ) ethylenic sulfonate (preferred especially person is that per molecule on average contains 10-20 carbon atom).
(ⅴ) paraffin sulfonate (preferred especially person is that per molecule on average contains 10-20 carbon atom).
(ⅵ) saturated or undersaturated soap (preferred especially person is that per molecule on average contains 10-24 carbon atom).
(ⅶ) (preferred especially person has the alkyl that on average contains 10-20 carbon atom or the alkyl or the alkenyl ether carboxylate of alkenyl to the aliphatic salt of alkylene oxide adduct type, wherein, be the ratio of 0.1/9.9-9.9/0.1 or be the ratio of 0.1/9.9-9.9/0.1 that in ethylene oxide/propylene oxide the per molecule carboxylate on average adds 0.5-8 moles of ethylene oxide, expoxy propane or epoxy butane) in ethylene oxide/butylene oxide.
(ⅷ) alpha-iodine base soap or ester (preferred especially person has alkyl or the alkenyl that per molecule on average contains 10-20 carbon atom).
(ⅸ) (preferred especially person has C to N-amide groups acid type surfactant
8-C
24Carboxyl groups or carboxylic acid residues freely).
(ⅹ) (preferred especially person has C to the surfactant of the single or two-ester type of phosphoric acid
8-C
24Alkyl or alkenyl).
(xi) (preferred especially person is deutero-or C by the higher aliphatic amide to sulfosuccinate
8-C
22Higher alcohol or its ethoxylate).
The example of the counter ion of the anion residue of these anion surfactants comprises alkali metal ion for example sodium ion, potassium ion etc.; Alkaline-earth metal ions is calcium ion, magnesium ion etc. for example; Ammonium ion; With contain the alkanolamine (for example monoethanolamine, diethanolamine, triethanolamine and triisopropanolamine) that 1-3 has the alkanol groups of 2-3 carbon atom.
In above-mentioned anion surfactant, below listed person be particularly preferred: the saturated or unsaturated fatty acid salt of (2) alkyl ether sulfate, (3) alkyl sulfate, (6), the aminoacid of (9) acidylate, surfactant and (11) sulfosuccinate of (10) phosphate monoester type.Particularly preferred instantiation is polyoxyethylene laurel ether sodium sulfate (on average adding the oxirane of 2-3 mole); triethanolamine lauryl sulfate; the coco-nut oil fatty acid sodium salt; Oleum Cocois aliphatic series amide ether sulfate; lauroyl-N methyl taurine; lauroyl-N-methyl-Beta-alanine; N-myristoyl-L-disodium glutamate; lauroyl-Beta-alanine; polyoxyethylene lauryl disodium sulfosuccinate (3-7E.0.); lauryl phosphoric acid; N-lauroyl-N '-carboxymethyl-N '-(2-ethoxy) ethylenediamine triethanolamine salt and N-lauroyl-N-(2-ethoxy)-N ', N '-two (carboxymethyl)-ethylenediamine sodium salt.
Above-mentionedly can use separately or unite use for the anion surfactant of component (c) with two or more.When their consumption is counted 1-20%(by weight with the shampoo Compositions gross weight), particularly 3-15%(is by weight) time, can obtain fabulous frothing capacity and good submissive hair effect.
Can be used for component of the present invention (d) is that water-soluble polymer can be natural generation, semisynthetic or synthetic polymer.In addition, can use any cationic polymer, anionic polymer and non-ionic polymers.
The example of the water-soluble polymer of natural generation comprises vegetalitas polymer for example arabic gum, tragacanth gum, galactan, guar gum, tragon, caraya gum, carrageenin (carrageenan), pectin, Qiong Zhi, Quince smoke tree (Cydonia oblonga) and glycyrrhizic acid; The microorganism derived polymers is xanthan gum (xanthane gum), glucosan, succinic acid glucosan and pullulan for example; With the protein hydrolysate polymer for example keratin decompose derivant etc.
The example of semisynthetic water-soluble polymer comprises starch polymer for example cationic starch, carboxymethyl starch and methyl hydroxypropyl starch; Cellulosic polymer is cationic cellulose derivative, methylcellulose, nitrocellulose, ethyl cellulose, methylhydroxypropylcellulose, hydroxyethyl-cellulose, sodium cellulose sulfate, hydroxypropyl cellulose, carboxymethyl cellulose-Na(CMC), crystalline cellulose and cellulose powder for example; The alginate polymer is sodium alginate and propylene glycol alginate for example; And cationic guar gum derivant.
The example of synthetic water-soluble polymer comprises the homopolymer of diallyl quaternary ammonium salt; The copolymer of diallyl quaternary ammonium salt/acrylamide; Quaternised polyvinylpyrrolidone derivant; Polyvinylpyrrolidone; The copolymer of polyvinylpyrrolidone and vinyl acetate, alkyl aminoacrylate etc.; The copolymer of low alkyl group half ester, vinyl acetate and the .beta.-methylacrylic acid of methyl vinyl ether and copolymer-maleic anhydride etc.; The copolymer of acrylic acid and/or methacrylic acid and alkyl acrylate and/or alkyl methacrylate; The copolymer of acrylic acid, alkyl acrylate and N-alkyl acrylamide; The ampholyte copolymer of methacrylic acid dialkyl amino ethyl ester, propenoic acid dialkyl aminoethyl ester, acrylamide diacetone etc. and acrylic acid, methacrylic acid, propenoic acid dialkyl ester, alkyl methacrylate etc.; The terpolymer of Hydroxypropyl acrylate, metering system acid butyl aminoethyl ester and acrylic acid octyl group amide; And the copolymer of alkyl acrylamide, acrylate, alkyl aminoalkyl acrylamide and polymethylacrylic acid glycol ester.
In above-mentioned water-soluble polymer, particularly preferably be those amido-containing groups or be connected to the ammonium group of polymer chain or contain dimethyl diallyl ammonium halide as monomeric unit.Concrete example comprises the homopolymer of diallyl quaternary ammonium salt, cationic cellulose derivative, cationic starch, cationic guar gum derivant, diallyl quaternary ammonium salt/acrylamide and season the polyvinylpyrrolidone derivant copolymer.
The example of preferred cation cellulose derivative comprises the derivant of formula (12):
In the formula, B represents the not unitary residue of hydrogenated glucose, and f represents 50-20,000 integer and R
11The substituent group of expression (13):
In the formula, R
12And R
13Independent separately expression C
2-C
3Alkylidene, g are the integers of 0-10, and h is the integer of 0-3, and i is the integer of 0-10, R
14Be C
1-C
3Alkylidene or hydroxyl alkylidene, R
15, R
16And R
17Identical or different separately, and expression can form the heterocyclic aryl or aralkyl of nitrogen atom, X in formula
1Represent a kind of anion for example chloride ion, bromide ion, iodide ion, sulfate ion, sulfonate ion, methylsulfuric acid radical ion, phosphate anion, nitrate ion etc.
The cation substitution value of above-mentioned cationic cellulose derivative, or per unit not the h average of hydrogenated glucose be preferably 0.01-1, more preferably 0.02-0.5.G and i with average out to 1-3.The cation substitution value is not enough less than 0.01.Yet, although the cation substitution value can surpass 1,, consider the productive rate of reaction, preferred especially substitution value is no more than 1.The molecular weight of cationic cellulose derivative is preferably 100,000-3,000,000.
Cationic cellulose starch with formula (14) expression is preferred:
In the formula, D represents the residue of starch, R
18Expression C
1-C
10Alkylidene or hydroxyl alkylidene, R
19, R
20And R
21Identical or different separately, and expression has 10 or less than alkyl, the aryl or aralkyl of 10 carbon atoms, they can form the heterocycle of nitrogen atom, X in formula
2Represent a kind of anion for example chloride ion, bromide ion, iodide ion, sulfate ion, sulfonate ion, methylsulfuric acid radical ion, phosphate anion, nitrate ion etc.
The cation group number that the cation substitution value of these cationic starches or per unit anhydrous glucose are introduced is preferably 0.01-1, more preferably 0.02-0.5.The cation substitution value is not enough less than 0.01.Yet, although the cation substitution value can surpass 1,, consider the productive rate of reaction, preferred especially substitution value is no more than 1.
Cationic guar gum derivant with formula (15) expression is preferred:
In the formula, E represents the residue of guar gum, R
22Expression C
1-C
10Alkylidene or hydroxyl alkylidene, R
23, R
24And R
25Identical or different separately, and expression has 10 or less than alkyl, the aryl or aralkyl of 10 carbon atoms, they can form the heterocycle of nitrogen atom, X in formula
3Represent a kind of anion for example chloride ion, bromide ion, iodide ion, sulfate ion, sulfonate ion, methylsulfuric acid radical ion, phosphate anion, nitrate ion etc., k represents positive integer.
The cation substitution value of above-mentioned guar gum derivatives is preferably 0.01-1.Particularly preferably be wherein 0.02-0.5 cation group introducing saccharide unit person.This cationoid polymer has been done introduction in following patent application, for example Japanese patent application bulletin communique 58-35640 number, Japanese patent application bulletin communique 60-46158 number and Japanese Patent Application Publication communique are 58-53996 number.Their trade mark is " JAGUAL " (Cellanese Schtein Hall Co.), can buy on market.
The example of preferred cation diallyl quaternary ammonium salt/acrylamide copolymer comprises those copolymers with formula (16) or formula (17) expression:
In the formula, R
26And R
27Identical or different separately, and represent hydrogen, alkyl (C
1-C
18), phenyl, aryl, hydroxyalkyl, amide alkyl, cyanoalkyl, alkoxyalkyl or carbon alkoxyalkyl, R
28, R
29, R
30And R
31Identical or different separately, and represent hydrogen, low alkyl group (C
1-C
3) or phenyl, X
4Represent a kind of anion for example chloride ion, bromide ion, iodide ion, sulfate ion, sulfonate ion, methylsulfuric acid radical ion, nitrate ion etc., p represents the integer of 1-50, and q represents the integer of 0-50, and r represents 150-8,000 integer.
It is about 30 that the molecular weight of above-mentioned diallyl quaternary ammonium salt/acrylamide copolymer and diallyl quaternary ammonium salt homopolymer is preferably, 000-2, and 000,000, preferred especially 100,000-1,000,000.
The example of preferred quaternized polyvinylpyrrolidone derivant comprises with formula (18) signifier:
In the formula, R
32Expression hydrogen or C
1-C
3Alkyl, R
33, R
34And R
35Identical or different separately, and represent hydrogen, C
1-C
4Alkyl, hydroxyalkyl, amide alkyl, cyanoalkyl, alkoxyalkyl or carbon alkoxyalkyl, Y
1Group NH in expression oxygen or the amido link, X
5Represent a kind of anion for example chloride ion, bromide ion, iodide ion, sulfate ion, sulfonate ion, alkyl sulfate ion, phosphate anion and nitrate ion etc. with 1-4 carbon atom, u represents the integer of 1-10, s and t are integers, can make the s+t sum become 20-8,000.
The molecular weight of above-mentioned quaternized polyvinylpyrrolidone derivant is preferably 10,000-2, and 000,000, preferred especially 50,000-1,500,000.
Above-mentioned water-soluble polymer is that component (d) can be used separately or unites use with two or more.When its incorporation for the 0.01-3%(of shampoo Compositions gross weight of the present invention by weight), preferred 0.3-1.5%(is by weight) time, can obtain fabulous wash effect.
Shampoo Compositions of the present invention can also contain other optional component except above-mentioned key component, these components are generally used for producing makeup, medicine and food.These optional components comprise that medicament is the dandruff removing agent of representative with pyrithione zinc (Zpt), antibacterial and vitamin for example; Antiseptic is P-hydroxybenzoic acid (parabene) for example; Wetting agent is propylene glycol, glycerol, carbiphene, Sorbitol, pantenol and glycinebetaine for example; Coloring agent is dyestuff and pigment for example; Regulator is PFPE for example; Margarita-color delivery agent is glycol ester for example; The chitosan derivant is the hydroxypropyl chitosan for example; Various mediation spice; And other composition that does not hinder effect of the present invention of in " ENCYCLOPEDIA OF SHAMPOO INGREDIENTS " (Micelle Press, 1985), introducing.
Shampoo Compositions of the present invention can produce fabulous creamy foam.When hair washing and rinsing, finger is combing hair smoothly.After hair is air-dry, touches and get up to have level and smooth sense, after its typing, have natural beauty.Comb can be smoothly by the fiber of hair.In addition, said composition is soft to skin and hair, and can suppress to stimulate.Therefore, they are effective especially shampoo Compositions.
Embodiment
Now by following examples the present invention being elaborated, is limitation of the present invention but should not be construed as.
Embodiment 1
Prepared the listed shampoo Compositions (1-3 is the invention product, and 1-7 is a reference product) of table 1, and according to its performance of following standard evaluation.Adopt and reverse stirring method evaluation frothing capacity.The sensation that touches hair is by following method evaluation.It is long that the 1g shampoo is applied to 20g(15cm) on the hair fiber of Japanese healthy women, foamed 1 minute.Then, use the water rinse hair fiber, towel off driedly, then, dry up with hair-dryer.Said process is undertaken by 5 experienced, professionals that judge.
Gained the results are shown in table 1.
Evaluation criterion
Frothing capacity:
A: fabulous frothing capacity
B: good frothing capacity
C: frothing capacity deficiency
D: be difficult to bubble
Touch the sensation of hair:
A: with finger combing significantly glibly, sense of touch is soft and smooth
B: with pointing combing glibly, sense of touch is level and smooth
C: finger is the combing hair fiber smoothly
D: touch hair tempestuously with finger, cause the hair fiber of winding
Finger combing during rinsing:
A: with finger combing significantly glibly, not retardance sense
B:, the retardance sense is arranged slightly with pointing combing glibly
C: being difficult to has the retardance sense with the finger combing
D: the finger carding property is very poor, and tangible retardance sense is arranged
Hair-dryer dries up the flatness of back hair
A: very soft and high resilience
B: softness
C: lack flexibility
D: coarse
Hair-dryer dries up the arrangement of back hair
A: be easy to put in order on request
B: the not special difficulty of arrangement
C: it is poor slightly to put in order
D: it is poor to put in order, the hair fiber perk
Hair-dryer dries up the combing of back hair
A: level and smooth and fabulous carding property
B: block a little
C: block, particularly in the hair fiber tip
Soft property to skin
A: do not stimulate one stimulation is arranged slightly
B: faint stimulation
C: medium-strong stimulation
2: polymer JR-400(cationic cellulose, the product of Union Carbide)
3:Merquat100(gathers-N, N-dimethyl-3, the product of 5-methylenepiperidines chlorine Merck)
Embodiment 2:
The shampoo Compositions that has prepared following prescription according to a conventional method.This shampoo product has fabulous frothing capacity, and very soft.When hair washing and rinsing, finger can pass through hair fiber smoothly.In addition, the air-dry back of hair is soft, is easy to arrangement, has natural beauty.The combing smoothly of air-dry hair.
(prescription) wt%
Polyoxyethylene (16) Laurel ether 18
Lauryl amine oxide 3
The quaternary chemical compound
#15
Polyoxyethylene (3) lauryl sodium sulfosuccinate 5
Cationic polymer
* 30.5
Sodium benzoate 0.3
Coloring agent is an amount of
Spice is an amount of
Citric acid is an amount of
The pure water balance
* 1Identical with described in the embodiment 1.
* 3Identical with described in the embodiment 1.
Embodiment 3
The shampoo Compositions that has prepared following prescription according to a conventional method.This shampoo product has fabulous frothing capacity, and very soft.When hair washing and rinsing, finger can pass through hair fiber smoothly.In addition, the air-dry back of hair is soft, is easy to arrangement, has natural beauty.The combing smoothly of air-dry hair.
(prescription) wt%
Mono laurate Polyethylene Glycol (20) 5
Polyoxyethylene (18) Laurel ether 12
Lauroyl diglycollic amide 3
The quaternary chemical compound
* 14
Acyl glutamic acid sodium
* 46
High molecular dimethyl polysiloxane aqueous emulsion 1.0
Cationic polymer
* 50.5
Sodium benzoate 0.3
Coloring agent is an amount of
Spice is an amount of
Citric acid is an amount of
Water balance
* 1Identical with described in the embodiment 1.
* 4The product of Amisoft LT-12(Ajinomoto)
* 5The product of Caticello H-60(cationic cellulose Kao).
Claims (10)
1, a kind of following (a) and (b), (c) and (d) shampoo Compositions of component of comprising:
(a) non-ionic surface active agent of alkylene oxide adduct type,
(b) have aliphatic chain or have ether or the quaternary chemical compound of ester or have aliphatic chain and have the acyl compounds of the second month in a season or uncle's amino group and quaternary ammonium group,
(c) anion surfactant and
(d) water-soluble polymer.
2, according to the shampoo Compositions of claim 1, wherein component (a) is selected from polyoxyalkylene alkyl, polyoxyalkylene alkyl phenyl ether, polyoxyalkylene aliphatic (acid) ester, polyoxyalkylene Sorbitol aliphatic (acid) ester, polyoxyalkylene aliphatic series strand alkanolamide, polyoxyalkylene aliphatic series two alkanolamides and composition thereof.
3, according to the shampoo Compositions of claim 1, wherein component (a) is a polyoxyalkylene alkyl.
4, according to the shampoo Compositions of claim 1, wherein component (b) is the chemical compound with formula (1) expression:
In the formula,
R
1: C
7-C
35Straight or branched alkyl or alkenyl,
R
2, R
3, R
4: identical or different separately, and expression C
1-C
4Alkyl or hydroxyalkyl or hydrogen,
M:-CONJ-wherein, J represents H, C
1-C
3Alkyl or hydroxyalkyl;-O-; Or-COO-and
Y:H, C
1-C
36Straight or branched alkyl, alkenyl or hydroxyalkyl or following groups:
Condition is, is C at J
1-C
3Under the situation of alkyl or hydroxyalkyl, Y is neither C
1-C
3Alkyl neither C
1-C
3Hydroxyalkyl,
X:H or hydroxyl,
A: halide ion or organic anion,
M:2 or 3 number and
The integer of n:0-5, the condition that comprises be, when n equaled 1, X was H or hydroxyl and when n equals 0,2,3,4 or 5, and X is H.
5, according to the shampoo Compositions of claim 1, wherein component (b) is the chemical compound with formula (2) expression:
In the formula,
R
1: C
7-C
35Straight or branched alkyl or alkenyl,
R
2, R
3, R
4: identical or different separately, and expression C
1-C
4Alkyl or hydroxyalkyl or hydrogen,
J:H, C
1-C
3Alkyl or hydroxyalkyl
Y ': H, C
1-C
3Alkyl or hydroxyalkyl or following groups:
Condition is, is C at J
1-C
3Under the situation of alkyl or hydroxyalkyl, Y ' is neither C
1-C
3Alkyl neither C
1-C
3Hydroxyalkyl,
X:H or hydroxyl,
A: halide ion or organic anion,
M:2 or 3 number and
The integer of n:0-5, the condition that comprises be, when n equaled 1, X was H or hydroxyl and when n equals 0,2,3,4 or 5, and X is H.
6, according to the shampoo Compositions of claim 1, wherein component (b) is the chemical compound with formula (3) expression:
In the formula,
R
1: C
7-C
35Straight or branched alkyl or alkenyl,
R
2 ', R
3 ', R
4 ': identical or different separately, and expression C
1-C
4Alkyl or hydroxyalkyl and A are halide ion or organic anion.
7, according to the shampoo Compositions of claim 1, wherein component (b) is the chemical compound with formula (4) expression:
In the formula, R
5, R
6Identical or different separately, and expression C
1-C
4Alkyl, R
7Expression C
2-C
6Alkylidene or alkylene group, R
8Expression C
4-C
36Branched alkyl or alkenyl, R
9Expression C
7-C
35Straight or branched alkyl or alkenyl, R
10Expression hydrogen or C
1-C
4Alkyl or hydroxyalkyl, Z are represented halogen, sulfate radical, bisulfate ion, carboxylate radical, and they can be by C
1-C
4Hydroxyl or C
1-C
4Alkyl sulfate replaces, and a represents the integer of 2-9.
8, according to the shampoo Compositions of claim 7, wherein, in the chemical compound of formula (4), R
5And R
6The expression methyl, R
7Expression C
2-C
3Alkylidene, R
8Expression hydrogenated tallow alkyl or hydrogenated palm oil alkyl, R
9CO represents h-tallow aliphatic acyl or hydrogenated palm oil aliphatic acyl.
9, according to the shampoo Compositions of claim 1, wherein component (d) is a water-soluble cationic polymer.
10, according to the shampoo Compositions of claim 1, said composition contains 1-60%(by weight) component (a), 1-20%(is by weight) component (b), 1-20%(is by weight) component (c) and 0.01-3%(by weight) component (d).
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5335779A JPH07187967A (en) | 1993-12-28 | 1993-12-28 | Hair cleansing agent |
| JP335779/93 | 1993-12-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1108922A true CN1108922A (en) | 1995-09-27 |
Family
ID=18292358
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN94107629.6A Pending CN1108922A (en) | 1993-12-28 | 1994-12-27 | Shampoo composition |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US5679330A (en) |
| EP (1) | EP0664115A3 (en) |
| JP (1) | JPH07187967A (en) |
| CN (1) | CN1108922A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100369600C (en) * | 2002-12-27 | 2008-02-20 | 花王株式会社 | Oil-in-water type emulsion composition and its preparing method |
| CN101563140B (en) * | 2006-10-25 | 2013-06-19 | 隆萨公司 | Controlled foam aqueous quaternary ammonium and phosphonium compositions |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6017860A (en) * | 1996-04-15 | 2000-01-25 | Stepan Company | Cleaning, conditioning and styling hair care compositions |
| DE19846607B4 (en) * | 1998-10-09 | 2009-04-02 | Kpss-Kao Professional Salon Services Gmbh | Process for the preparation of a clear conditioning hair cleanser |
| US20050031498A1 (en) * | 2002-06-24 | 2005-02-10 | Held Robert F. | Air freshener with container |
| US20060025318A1 (en) * | 2004-04-22 | 2006-02-02 | Mireille Maubru | Composition for washing and conditioning keratin materials, comprising a carboxyalkyl starch, and process for the use thereof |
| FR2869226B1 (en) * | 2004-04-22 | 2009-06-12 | Oreal | COMPOSITION FOR WASHING AND PACKAGING KERATINIC MATERIALS COMPRISING A CARBOXYALKYLAMIDON, USE AND METHOD |
| CA2557429A1 (en) * | 2005-08-26 | 2007-02-26 | Farouk Systems Inc. | Composition and method for delivering infrared radiation and ionically charged particles to hair |
| US9237972B2 (en) * | 2008-12-16 | 2016-01-19 | Kimberly-Clark Worldwide, Inc. | Liquid surfactant compositions that adhere to surfaces and solidify and swell in the presence of water and articles using the same |
| EP2477486A4 (en) | 2009-09-16 | 2012-09-26 | Living Proof Inc | Cationic alcohols and uses thereof |
| JP5791957B2 (en) * | 2011-05-02 | 2015-10-07 | 花王株式会社 | Aqueous hair cleanser |
| EP3461472B2 (en) | 2017-10-02 | 2023-12-27 | Peter Greven Physioderm GmbH | Sensitive skin cleanser with enhanced cleaning effect |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3156656A (en) * | 1958-01-06 | 1964-11-10 | Gillette Co | Aqueous shampoo composition |
| LU65997A1 (en) * | 1972-09-05 | 1974-03-14 | ||
| JPH0633405B2 (en) * | 1986-05-27 | 1994-05-02 | 株式会社資生堂 | Cleaning composition |
| JP2585031B2 (en) * | 1987-11-30 | 1997-02-26 | 株式会社資生堂 | Detergent composition |
| US5078990A (en) * | 1990-07-13 | 1992-01-07 | Helene Curtis, Inc. | Shampoos and conditioning shampoos having increased capacity for incorporation of conditioning agents and removal of hair soil |
| EP0472107B1 (en) * | 1990-08-23 | 1994-12-14 | Kao Corporation | Cationic compound and cleaning composition |
| US5534248A (en) * | 1992-10-09 | 1996-07-09 | Kao Corporation | Toiletry composition for hair care |
-
1993
- 1993-12-28 JP JP5335779A patent/JPH07187967A/en active Pending
-
1994
- 1994-12-27 CN CN94107629.6A patent/CN1108922A/en active Pending
- 1994-12-27 EP EP94120683A patent/EP0664115A3/en not_active Withdrawn
- 1994-12-28 US US08/364,991 patent/US5679330A/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100369600C (en) * | 2002-12-27 | 2008-02-20 | 花王株式会社 | Oil-in-water type emulsion composition and its preparing method |
| CN101563140B (en) * | 2006-10-25 | 2013-06-19 | 隆萨公司 | Controlled foam aqueous quaternary ammonium and phosphonium compositions |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0664115A2 (en) | 1995-07-26 |
| EP0664115A3 (en) | 1996-11-06 |
| JPH07187967A (en) | 1995-07-25 |
| US5679330A (en) | 1997-10-21 |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |