CN110888194A - Flexible holographic base element film and preparation method and application thereof - Google Patents

Flexible holographic base element film and preparation method and application thereof Download PDF

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Publication number
CN110888194A
CN110888194A CN201911202617.0A CN201911202617A CN110888194A CN 110888194 A CN110888194 A CN 110888194A CN 201911202617 A CN201911202617 A CN 201911202617A CN 110888194 A CN110888194 A CN 110888194A
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film
transparent
reflecting
flexible
glue
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CN110888194B (en
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王广军
余为伟
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Jingmen Exploration Dream Technology Co Ltd
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Jingmen Exploration Dream Technology Co Ltd
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Priority to PCT/CN2020/131742 priority patent/WO2021104367A1/en
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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/32Holograms used as optical elements

Abstract

The invention relates to the field of 3D display, and discloses a flexible holographic base film, wherein the whole base film is of a flexible bendable thin film structure, a plurality of flexible transparent thin films with single surfaces plated with reflecting films or a structure that a plurality of flexible transparent thin films with double surfaces plated with reflecting films are adhered through transparent glue to form reflecting layers and transparent layers which are arranged alternately, the reflecting layers form reflecting layers for reflecting light rays, the flexible transparent thin films and/or the transparent glue form the transparent layers for transmitting light rays, and the horizontal clamping sag length L (cm) of the flexible holographic base film and the folding times n meet the following requirements: n L is greater than 9 or L is larger than or equal to 5cm, the material cost and the processing process cost of the preparation method are low, the preparation method is suitable for large-scale popularization, and meanwhile, the 3D display holographic film prepared by applying the flexible holographic element film can be made into a scroll screen, a curved screen and the like, the flexibility is high, the 3D display holographic film is convenient to store when not used, and the occupied space is small.

Description

Flexible holographic base element film and preparation method and application thereof
Technical Field
The invention relates to the field of 3D display, in particular to a flexible holographic base film and a preparation method and application thereof.
Background
The 3D display technology is capable of displaying stereoscopic pictures in space, and is the mainstream direction of the next generation display technology. Although there are many solutions for realizing 3D display, such as volume display technology, stereo image pair technology, pepper's ear illusion, etc., there is no perfect 3D solution at present, and the main reason is the lack of optical glass element for large area light source manipulation.
The traditional optical glass processing technology can only process microstructures in a hundred-micron scale, high-precision large-area optical processing needs and high processing cost, and the optical glass is made of hard materials and is easy to break and generate residual stress in the processing process.
Disclosure of Invention
The technical problem to be solved by the invention is as follows: aiming at the problems that the processing cost of the traditional high-precision large-area optical glass is high in the prior art, and the yield is affected by the easy breakage of the glass, the residual stress and the like in the processing process, the flexible holographic base film and the preparation method and application thereof are provided.
In order to solve the technical problems, the invention provides a flexible holographic element film, wherein the whole element film is of a flexible and bendable thin film structure, and the flexible holographic element film is of a structure in which a plurality of flexible transparent thin films with single surfaces plated with reflecting films or a plurality of flexible transparent thin films with double surfaces plated with reflecting films are adhered through transparent glue to form reflecting layers and transparent layers which are arranged alternately;
the reflecting film forms a reflecting layer for reflecting light;
the flexible transparent film and/or the transparent glue form a transparent layer for transmitting light;
the horizontal clamping sagging length L (cm) of the flexible holographic element film and the folding times n meet the following conditions: n is L is greater than 9 or L is not less than 5.
Furthermore, the thickness of the reflecting layer is 0.1-25 μm, the thickness of the transparent layer is 2-1 mm, and the thickness of the transparent layer is greater than that of the reflecting layer.
Further, the transparent film is any one of a plastic film, a PMMA film, an lPMMA film, a PS film, a PC film, a styrene acrylonitrile film, an MS film, a PET film, a PETG film, an ABS film, a PP film, a PA film, a SAN film, an MS film, an MBS film, a PES film, a CR-39 film, a TPX film, a HEMA film, an F4 film, an F3 film, an EFP film, a PVF film, a PVDF film, an EP film, a PF film, an UP film, a cellulose acetate film, a cellulose nitrate film, an EVA film, a PE film, a PVC film, a novel amorphous thermoplastic polyester film, an amorphous cycloolefin film, and a modified bisphenol a epoxy resin film.
Further, the reflective film is any one of aluminum foil, iron foil, tin foil, zinc foil, copper foil, chromium foil, nickel foil and titanium foil.
Further, the transparent glue is any one of transparent epoxy resin AB glue, UV glue, shadowless glue, transparent glass glue, transparent wood glue and transparent all-purpose glue.
The invention also provides a preparation method of the flexible holographic base element film, which comprises the following steps:
1) preparing a cured pile:
a) stacking a plurality of transparent thin films plated with reflecting films which are cut in advance layer by layer to form a reflecting film stack with alternately arranged reflecting layers and transparent layers;
b) soaking the whole reflecting film stack in transparent glue until the transparent glue completely penetrates into the gap between the transparent film and the reflecting film, and taking out;
c) standing and curing, wherein in the curing process, a certain pressure is applied to extrude out the redundant glue among the transparent films so as to control the thickness of the transparent layer, and a curing stack with the reflecting layer and the transparent layer arranged alternately is formed after curing;
2) preparing a basic element film: grinding a smooth surface in the direction vertical to the plane of the reflecting layer, recording the smooth surface as a cutting reference surface, cutting a sheet from the solidified pile along the direction parallel to the cutting reference surface, recording the sheet as a base element film, wherein the newly cut surface on the solidified pile is the cutting reference surface for the next cutting, and repeating the cutting step to cut the solidified pile in the step 1) into a plurality of base element films.
Further, the cured pile described in step 1) may also be prepared by:
the transparent film plated with the reflecting film is placed on a plane, transparent glue is uniformly coated on the upper surface of the transparent film, then another transparent film plated with the reflecting film is stacked on the transparent glue layer, the stacking process is repeated to form a structure in which the reflecting film and the transparent film are stacked alternately, and a solidified stack is formed after standing and solidifying.
Furthermore, at least one transmission film can be added between two transparent films plated with reflection films during preparation of the cured stack, and the transmission film is any one of a plastic film, a PMMA film, an lPMMA film, a PS film, a PC film, a styrene acrylonitrile film, an MS film, a PET film, a PETG film, an ABS film, a PP film, a PA film, a SAN film, an MS film, an MBS film, a PES film, a CR-39 film, a TPX film, a HEMA film, a F4 film, a F3 film, an EFP film, a PVF film, a PVDF film, an EP film, a PF film, a UP film, a cellulose acetate film, a cellulose nitrate film, an EVA film, a PE film, a PVC film, a novel amorphous thermoplastic polyester film, an amorphous cycloolefin film and a modified bisphenol A epoxy resin film.
Further, before the cutting in the step 2), a transparent protective film is adhered on the cutting reference surface by using transparent glue, or bonding a transparent protective film on one or two surfaces of the element film after cutting to obtain the element film with the transparent protective film after cutting, the transparent protective film is any one of a plastic film, a PMMA film, an lPMMA film, a PS film, a PC film, a styrene acrylonitrile film, an MS film, a PET film, a PETG film, an ABS film, a PP film, a PA film, an SAN film, an MS film, an MBS film, a PES film, a CR-39 film, a TPX film, a HEMA film, an F4 film, an F3 film, an EFP film, a PVF film, a PVDF film, an EP film, a PF film, an UP film, a cellulose acetate film, a cellulose nitrate film, an EVA film, a PE film, a PVC film, a novel amorphous thermoplastic polyester film, an amorphous cycloolefin film and a modified bisphenol A epoxy resin film.
The invention also provides an application of the flexible holographic element film prepared by the preparation method of the flexible holographic element film, and the flexible holographic element film is applied to preparing a flexible 3D display holographic film, and specifically comprises the following steps:
the two flexible element films are bonded together up and down by using transparent glue, a flexible 3D display holographic film is formed after curing, the reflecting layers and the transparent layers on the two element films are staggered at an included angle theta to form a grid when bonding, the theta is more than or equal to 87 degrees and less than or equal to 93 degrees, and the horizontal clamping sagging length L (cm) of the flexible 3D display holographic film and the number n of folding times meet the following requirements: n L is greater than 9 or L is greater than or equal to 5cm, and the element film is provided with a flexible transparent protective film or is not provided with the transparent protective film.
The invention also provides an application of the elementary film with the transparent protective film, which is used for preparing the hard 3D display holographic projection screen and specifically comprises the following steps:
one element film with a hard transparent protective film (such as glass or acrylic) and the other element film with or without the transparent protective film are bonded together up and down by using transparent glue, and the reflecting layers and the transparent layers on the two element films are staggered at an included angle theta to form a grid, wherein the theta is more than or equal to 87 degrees and less than or equal to 93 degrees.
Compared with the prior art, the invention has the advantages that:
compared with the extremely high processing cost of the existing high-precision optical glass processing technology, the preparation method has lower material cost and processing technology cost, and is suitable for large-scale popularization; meanwhile, the holographic element film with the grids is flexible, so that the holographic element film is not easy to break when being processed, the problems of residual stress generated in the glass processing process and the like are avoided, the yield is greatly improved, the holographic element film can be made into a scroll screen, a curved screen and the like when being specifically applied, the flexibility is higher, the holographic element film is convenient to store when not being used, and the occupied space is smaller.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below, it is obvious that the drawings in the following description are only some embodiments described in the present invention, and for those skilled in the art, other drawings can be obtained according to the drawings without creative efforts.
FIG. 1 is a front view showing the structure of a substrate film 1 formed by bonding a double-sided coated transparent film by transparent glue,
FIG. 2 is a front view showing the structure of a substrate film 1 formed by bonding a single-sided coated transparent film by transparent glue,
figure 3 is an enlarged view of a portion of i in figure 2,
FIG. 4 is a structural view of a base film 1 with a transparent protective film
Figure 5 is a perspective view of a 3D display holographic film structure,
figure 6 is a front view and a top view of figure 5,
figure 7 is a diagram of an aero-levitation display system,
figure 8 is an imaging schematic of a 3D display holographic film,
figure 9 is a side view of figure 8,
figure 10 is a schematic diagram of the partial internal ray reflection at ii in figure 9,
figure 11 is a diagram of the effect of a flexible holographic screen for an air suspension display system application,
FIG. 12 is a graph showing the simulation effect of the imaging light path of the holographic film in 3D,
the reference numbers are as follows:
a base film 1, a reflective layer 2, a transparent layer 3, a grid 4, a holographic projector 10, a projection screen 20, an interactive response unit 30, a processor 40, and a motion actuator 50.
Detailed Description
The following detailed description of the present invention is given for the purpose of better understanding technical solutions of the present invention by those skilled in the art, and the present description is only exemplary and explanatory and should not be construed as limiting the scope of the present invention in any way.
Referring to fig. 1 to 12, the present invention provides a flexible holographic base film, which is a flexible and bendable film structure, and has a horizontal clamping and sagging length of l (cm), and a folding number of n, satisfying: l is more than or equal to 5 or n L is more than 9;
in practical application, in order to ensure the reliability as much as possible, n is preferably more than or equal to 2 and L is more than 9;
it should be noted that, where n is the number of times of folding, testThe area of the sample is 100cm2The square flexible holographic base film 1 is characterized in that the base film 1 is folded into a rectangle along the middle line position of the square (or within 1cm near the middle line position), then the folded base film 1 is clamped between two flat plates, 10-20N of force is applied to pressurize for 3-5 s, then the base film 1 is opened (at the moment, a folding test is completed once), whether the base film 1 generates local micro-cracks or is broken into two parts along creases is checked, if not, the test is repeated until the base film 1 generates local micro-cracks or is broken into two parts, the test is stopped, and the total folding times in the test process are recorded as N;
wherein L is the horizontal clamping sagging length, the test method comprises the following steps: taking a narrow strip element film 1 with the width of 5cm +/-0.5 cm and the length of about 25cm, enabling one end of the narrow strip element film to be tightly attached to a horizontal reference table top, ensuring that the length of the narrow strip extending out of the table top is 20cm +/-1 cm, standing, and measuring the vertical height difference between the end point of the narrow strip extending out of the table top and the horizontal reference table top after the narrow strip is stabilized to be recorded as a horizontal droop length L;
the test is an accelerated test means, the reliability of a sample in a long-term use process can be rapidly judged, the flexible 3D display base element film 1 needs to bear operations such as winding, storage, opening and the like for many times when being applied, the operation is calculated according to the designed 5-year service life, the whole life cycle needs to be stored and unfolded for about 10000 times, and in order to accelerate the evaluation of the service life of the base element film 1, the folding test and the horizontal clamping droop length test are adopted in the invention;
when n is greater than L9, the larger n is, the smaller the ultimate bending curvature radius of the base element film 1 is, the stronger the breaking resistance is, and meanwhile, the larger L is, the better the flexibility of the base element film 1 is, the more difficult the base element film 1 structure is to be damaged due to winding, experiments show that the base element film 1 structure is basically equivalent to 10000 times of opening and closing tests when n is greater than L9, the requirement on the minimum design life is met, and if the n is smaller, the quality problem is easy to occur in the service cycle of a product, and the customer experience is reduced;
in practical application, some transparent adhesive tapes and transparent films which are relatively hard after being cured can be used, so that the prepared flexible holographic base film 1 can be broken when being folded in half, but the structure can not be damaged when being wound, and the flexible holographic base film is also suitable for winding screens. For such materials, as long as the prepared base membrane 1 can be wound into a cylinder with the diameter less than 5cm, when L is more than 5cm, the whole base membrane 1 is relatively flexible, and the fracture loss in the processing process is small.
As shown in fig. 1 to fig. 3, the reflective film may be formed by bonding a plurality of flexible transparent films with one surfaces plated with reflective films through transparent glue, or may be formed by bonding a plurality of flexible transparent films with two surfaces plated with reflective films through transparent glue;
the reflecting film forms a reflecting layer 2 for reflecting light, the reflecting film is a metal foil capable of reflecting light or other films with interfaces having the function of reflecting light, it should be noted that if the reflecting film is too thick, too much light can be shielded, the thinner the reflecting film is, but in consideration of the process preparation difficulty and cost, the thickness of the reflecting film is 0.1-25 μm of aluminum foil, iron foil, tin foil, zinc foil, copper foil, chromium foil, nickel foil, titanium foil or other reflecting films capable of reflecting light;
the transparent layer 3 is formed by flexible transparent film and/or transparent glue and used for transmitting light, the thickness of the transparent layer 3 is always larger than that of the reflecting layer 2, and the thickness of the transparent layer is preferably 2 mu m-1 mm;
when a flexible transparent film with a reflecting film plated on one side is adopted, the single-layer transparent layer 3 is formed by the flexible transparent film and transparent glue after being cured; when a flexible transparent film with reflecting films plated on both sides is adopted, the transparent layer 3 is formed by alternately curing layers of the transparent film and transparent glue, wherein the transparent glue can be any one of transparent epoxy resin AB glue, UV glue, shadowless glue, transparent glass glue, transparent wood glue and transparent universal glue;
the transparent film may be any one of a plastic film, a PMMA film, an lPMMA film, a PS film, a PC film, a PE film, a styrene acrylonitrile film, an MS film, a PET film, a PETG film, an ABS film, a PP film, a PA film, a SAN film, an MS film, an MBS film, a PEs film, a CR-39 film, a TPX film, a HEMA film, an F4 film, an F3 film, an EFP film, a PVF film, a PVDF film, an EP film, a PF film, an UP film, a cellulose acetate film, a cellulose nitrate film, an EVA film, a PE film, a PVC film, a novel amorphous thermoplastic polyester film, an amorphous cycloolefin film, and a modified bisphenol a epoxy resin film.
The invention also provides a preparation method of the flexible holographic base element film, which comprises the following specific steps:
1) preparing a cured pile:
a) stacking a plurality of transparent thin films plated with reflecting films which are cut in advance layer by layer to form a reflecting film stack with alternately arranged reflecting layers and transparent layers;
b) the whole reflecting film stack is soaked in transparent glue, and is taken out until the transparent glue completely permeates into gaps between the transparent films, and it is required to be noted that the transparent films are piled up to form a fluffy stack, gaps exist between the layers, so that the transparent glue can penetrate into the layers under the action of surface tension when contacting with the transparent glue and is completely filled, bubbles are not easy to appear, and the glue has a bonding effect on various materials, so that the transparent films and the reflecting film are very easy to infiltrate, and the transparent films and the reflecting film can be filled between the transparent films and the reflecting film under the action of the surface tension, and the capillary phenomenon is similar;
c) standing and curing, wherein in the curing process, a certain pressure is applied to extrude out redundant glue among the transparent films so as to control the thickness of the transparent layer, a curing stack with alternately arranged reflecting layers 2 and transparent layers 3 is formed after curing, wherein the reflecting layers form the reflecting layers 2, and the transparent films and/or the transparent glue curing layers form the transparent layer 3;
2) preparing a basic element film: grinding a smooth surface in the direction vertical to the plane of the reflecting layer 2, marking the smooth surface as a cutting reference surface, cutting a sheet from the solidified pile along the direction parallel to the cutting reference surface, marking the sheet as a base element film 1, wherein the newly cut surface on the solidified pile is the cutting reference surface of the next cutting, and repeating the cutting step to cut the solidified pile in the step 1) into a plurality of base element films 1.
Wherein, the preparation of the curing stack in the step 1) can also adopt the following mode:
the transparent film plated with the reflecting film is placed on a plane, transparent glue is uniformly coated on the upper surface of the transparent film, then another transparent film plated with the reflecting film is stacked on the transparent glue layer, the stacking process is repeated to form a structure in which the reflecting film and the transparent film are stacked alternately, and a solidified stack is formed after standing and solidifying.
It should be noted that the transparent layer 3 is formed by curing a flexible transparent film and/or transparent glue, and based on the materials of the transparent glue and the transparent film, the cured transparent layer 3 has better flexibility, so that the cut element film 1 also has better flexibility.
In order to reduce the amount of transparent glue and further increase the thickness of the transparent layer 3, at least one transparent film of transparent plastic material may be adhered between the two reflective layers 2 by transparent glue during actual preparation.
Reference may be made in particular to the thicknesses of the reflective layer 2, the transparent layer 3 and the elementary film 1 in the following table:
thickness of reflecting layer (mum) Thickness of transparent layer (μm) Elementary film thickness (μm)
0.1 1 1
1 2 2
5 10 10
10 20 20
15 30 30
20 50 50
25 100 100
25 300 300
25 1000 1000
The following examples are further provided to illustrate the preparation method of a flexible holographic base film according to the present invention, wherein the reflective layer 2 is a 10 μm aluminum foil reflective film, the transparent layer 3 is 20 μm, the transparent film is a PE film, and the transparent glue is an epoxy AB glue to prepare a flexible 3D display holographic film with a thickness of 20 μm:
example 1
1) Preparing a cured pile:
a) stacking 5000 pre-cut PE transparent films with the size of 50cmX50cm and aluminum foil reflecting films plated on two sides layer by layer to form an aluminum foil reflecting film stack, wherein the thickness of the transparent film is 20 microns, and the thickness of the aluminum foil reflecting film is 10 microns;
b) the aluminum foil reflecting film stack is wholly soaked in transparent epoxy resin AB glue until the epoxy resin AB glue completely permeates into gaps among the aluminum foil reflecting films and then is taken out;
c) standing and curing for 3 hours, wherein in the curing process, epoxy resin AB glue is permeated between the aluminum foil reflecting films, so that the thickness of the aluminum foil reflecting film stack is increased, and the thickness of the aluminum foil reflecting film stack is controlled by applying certain pressure, so that the thickness of the transparent layer is controlled, in the embodiment, the thickness of the reflecting film stack is controlled to be 30cm by the pressure, and a cured stack with the thickness of 30cm is formed after curing, wherein the reflecting layer 2 and the transparent layer 3 are arranged alternately, so that the average thickness of the transparent layer 3 formed by curing the epoxy resin AB glue is 20 micrometers, the thickness of the transparent layer 3 formed by a PE transparent film is 20 micrometers, and the thickness of the reflecting layer 2 formed by the aluminum foil reflecting film is 10 micrometers;
2) preparing a basic element film: grinding a smooth surface in a direction perpendicular to the plane of the reflecting layer 2 to obtain a smooth surface which is recorded as a cutting reference surface, cutting a sheet with the thickness of 100 microns from the solidified pile in a direction parallel to the cutting reference surface by using a laser cutting machine, then grinding and polishing the sheet to 20 microns to obtain a base film 1, wherein the newly cut surface of the solidified pile is the cutting reference surface of the next cutting, repeating the cutting step, and cutting, grinding and polishing the solidified pile in the step 1) to obtain a plurality of base films 1.
Example 2
1) Preparing a cured pile:
stacking 10000 pre-cut PE transparent films with the size of 50cmX50cm and aluminum foil reflecting films plated on one surfaces layer by layer, and ensuring that all the surfaces plated with the reflecting films face upwards to form an aluminum foil reflecting film stack, wherein the thickness of the transparent films is 15 mu m, and the thickness of the aluminum foil reflecting films is 10 mu m;
the rest of the procedure was the same as in example 1, wherein the transparent layer 3 formed by the cured layers of the PE transparent film and the epoxy AB glue had an average thickness of 20 μm, and the reflective layer 2 formed by the aluminum foil reflective film had a thickness of 10 μm.
Example 3
Placing a PE transparent film with aluminum foil reflecting films plated on both sides on a plane, wherein the thickness of the PE transparent film is 20 micrometers, the thickness of the aluminum foil reflecting film is 10 micrometers, then uniformly coating a layer of transparent epoxy resin AB glue on the aluminum foil reflecting film, then stacking another layer of aluminum foil reflecting film on a transparent glue layer, repeating the stacking process to obtain a structure with alternately stacked reflecting layers 2 and transparent layers 3, obtaining a cured stack after the transparent epoxy resin AB glue is cured, and controlling the thickness of the transparent layer 3 formed by curing the epoxy resin AB glue to be 20 micrometers by controlling the glue coating amount of each layer;
the rest of the procedure was the same as in example 1.
Example 4
The PE transparent film with aluminum foil reflective films plated on both sides in example 3 was replaced with a PE transparent film with aluminum foil reflective films plated on one side, the thickness of the PE transparent film was 15 μm, the PE transparent film with aluminum foil reflective films plated on one side was always kept facing up when stacked, the thickness of the transparent layer 3 formed by the PE transparent film and the epoxy AB glue was controlled to 20 μm by the same amount of glue application, and the rest of the procedure was the same as in example 3.
It should be noted that different glues are adopted, the standing and curing time is different, the glue can be properly heated according to the glue characteristics when in use, for example, when epoxy AB glue is used, the glue can be heated to about 28 ℃, so that the curing process is accelerated, and bubbles can be prevented from being generated;
the cutting process can be performed by a high-precision wire cutting machine, and a transparent protective film can be bonded on the cutting reference surface by using transparent glue before cutting, as shown in fig. 4, the element film 1 with the transparent protective film is obtained after cutting, and the transparent protective film is any one of a glass, an acrylic film, a plastic film, a PMMA film, an lPMMA film, a PS film, a PC film, a styrene acrylonitrile film, an MS film, a PET film, a PETG film, an ABS film, a PP film, a PA film, a SAN film, an MS film, an MBS film, a PES film, a CR-39 film, a TPX film, a HEMA film, an F4 film, an F3 film, an EFP film, a PVF film, a PVDF film, an EP film, a PF film, a UP film, a cellulose acetate film, a nitrate film, an EVA film, a PE film, a PVC film, a novel amorphous thermoplastic polyester film, an amorphous cycloolefin film, and a modified bisphenol a epoxy resin film;
the element film 1 can be further thinned by grinding and polishing or other means during actual processing;
the thickness of the element film 1 without the transparent protective film can be reduced by grinding and polishing on both sides or one side;
for the element film 1 with the transparent thin film, thinning may be performed by grinding and polishing the non-transparent protective film side;
by adopting the preparation method, the holographic elementary film with the micron-sized ultra-fine structure can be prepared without a complex film coating process, and compared with the extremely high processing cost of the existing high-precision optical glass processing process, the preparation method provided by the invention has the advantages that the material cost and the processing process cost are low, the method is suitable for large-scale popularization, and meanwhile, the holographic elementary film with the grid is flexible, so that the holographic elementary film is not easy to break when being processed, the problems of residual stress and the like generated in the glass processing process can be avoided, the yield is greatly improved, when in specific application, the holographic elementary film can be made into a scroll type screen, a curved screen and the like, the flexibility is high, the storage is convenient when not being used, and the occupied space is small.
As shown in fig. 5 and 6, the flexible holographic element film 1 prepared by the preparation method of the flexible holographic element film according to the present invention is applied to the preparation of a flexible 3D display holographic film, and specifically includes:
two flexible substrate films 1 are bonded together up and down by using transparent glue, a flexible 3D display holographic film is formed after curing, the substrate films 1 are provided with flexible transparent protective films or are not provided with the transparent protective films, the reflecting layers 2 and the transparent layers 3 on the two substrate films 1 are staggered at an included angle theta to form grids 4 during bonding, wherein the theta is more than or equal to 87 degrees and less than or equal to 93 degrees, and preferably 90 degrees;
the horizontal clamping sagging length of the flexible holographic base element film is L (cm), the folding times are n, and the requirements are met: l is more than or equal to 5 or n L is more than 9, the whole flexible 3D display holographic film is flexible, so the flexible 3D display holographic film can be applied to a scroll screen, can be wound and stored on a scroll when not used, and can be unfolded to form a plane when used, and meanwhile, the flexible 3D display holographic film can be adhered to a transparent flat plate to be changed into a hard screen when used.
In practical application, transparent glue and a transparent film which are relatively hard after being cured can be used, so that the prepared flexible 3D display holographic film can be broken when being folded in half, but the structure cannot be damaged when being wound, and the flexible 3D display holographic film is also suitable for winding screens. For the material, as long as the prepared flexible 3D display holographic film can be wound into a cylinder with the diameter less than 5cm, the whole flexible 3D display holographic film is relatively flexible, and the fracture loss in the processing process is relatively small. Generally, when L.gtoreq.5 cm, the elementary film can be wound into a cylindrical shape having a diameter of less than 5cm without breaking.
In view of the practical application, it may be necessary to produce an oversized 3D display holographic film, where the microstructure of the elementary film 1 is correspondingly relatively "rough", and the thickness of the transparent layer 3 may be up to 1mm or even thicker.
In practical application, the elementary film 1 with the transparent protective film can be directly applied to a hard 3D display holographic projection screen, specifically:
one element film 1 with a hard transparent protective film (glass or acrylic) is vertically bonded with the other element film 1 with the transparent protective film or without the transparent protective film by using transparent glue, and the reflecting layer 2 and the transparent layer 3 on the two element films 1 are staggered at an included angle theta to form a grid 4, wherein theta is more than or equal to 87 degrees and less than or equal to 93 degrees, preferably 90 degrees, except for the harder glass and acrylic materials, when the transparent protective film is made of other materials, the transparent protective film can become the harder transparent protective film when the thickness of the transparent protective film is larger, and the method is also suitable for the hard 3D display holographic projection screen.
In addition, although the protective film of the element film is attached before cutting, in practical application, the protective film may be bonded after cutting, and in this case, the protective film may be flexible or hard, and the material of the transparent protective film may be selected according to practical application requirements.
As shown in fig. 7, the flexible 3D display holographic film or the rigid 3D display holographic projection screen is applied to an air suspension display:
the air suspension display system comprises a holographic projector 10, a projection screen 20 prepared on the basis of the flexible holographic base film 1, an interactive response unit 30 and a processor 40, wherein the holographic projector 10 is used for projecting a 3D holographic image with depth in a space, the 3D holographic image is positioned on one side of the projection screen 20, the projection screen 20 is used for converting the 3D image with depth information projected by the holographic projector 10 to a conjugate position of the 3D image, a movement executing mechanism 50 is arranged on the holographic projector 10 and/or the projection screen 20, and the interactive response unit 30 is used for sensing user interactive action information and the position of eyes of a user;
the holographic projector 10, the interactive response unit 30 and the motion actuator 50 are respectively electrically connected with the processor 40, the processor 40 sends projection data information to the holographic projector 10 to control the projection picture and the picture depth of the holographic projector 10, and controls the motion actuator 50 to adjust the relative position of the holographic projector 10 and the projection screen 20 according to the received positioning information of the human eyes acquired by the interactive response unit 30, or controls the system to make corresponding response according to the identified interactive action information of the user;
preferably, the projection screen 20 is the flexible 3D display holographic film, and is flexible, so that it can be designed as a scroll screen, and can be rolled and stored on a scroll when not in use, and can be unfolded to form a plane when in use;
the projection screen 20 may also be a rigid 3D display holographic projection screen as described above, and may also be attached to a transparent plate to become a rigid screen in use, based on the flexibility of the flexible 3D display holographic film.
Imaging principle: referring to fig. 8 to 12, the projected light of the holographic projector 10 is reflected by the reflective layer inside the projection screen 20, and there are one or more reflections, and a 3D image is formed at a conjugate position of the holographic projector 10 with respect to the projection screen 20, and the final imaging effect of the imaging principle is consistent with that of the flat lens made of a negative refractive index material.
The foregoing is a more detailed description of the invention in connection with specific preferred embodiments and it is not intended that the invention be limited to these specific details. For those skilled in the art to which the invention pertains, several simple deductions or substitutions can be made without departing from the spirit of the invention, and all shall be considered as belonging to the protection scope of the invention.

Claims (11)

1. A flexible holographic base film, comprising: the whole base element film (1) is of a flexible and bendable film structure, and is of a structure that a plurality of flexible transparent films with reflecting films plated on single surfaces or a plurality of flexible transparent films with reflecting films plated on double surfaces are adhered through transparent glue to form reflecting layers (2) and transparent layers (3) which are arranged alternately and in parallel;
the reflecting film forms a reflecting layer (2) for reflecting light;
the flexible transparent film and/or transparent glue forming a transparent layer (3) for transmitting light;
the horizontal clamping sagging length L (cm) of the flexible holographic element film and the folding times n meet the following conditions: n is L is greater than 9 or L is not less than 5.
2. A flexible holographic element film according to claim 1, wherein: the thickness of the reflecting layer (2) is 0.1-25 mu m, the thickness of the transparent layer (3) is 2-1 mm, and the thickness of the transparent layer (3) is larger than that of the reflecting layer (2).
3. A flexible holographic element film according to claim 1, wherein: the transparent film is any one of a plastic film, a PMMA film, an lPMMA film, a PS film, a PC film, a styrene acrylonitrile film, an MS film, a PET film, a PETG film, an ABS film, a PP film, a PA film, an SAN film, an MS film, an MBS film, a PES film, a CR-39 film, a TPX film, a HEMA film, an F4 film, an F3 film, an EFP film, a PVF film, a PVDF film, an EP film, a PF film, an UP film, a cellulose acetate film, a cellulose nitrate film, an EVA film, a PE film, a PVC film, an amorphous cycloolefin film and a modified bisphenol A epoxy resin film which are made of transparent materials.
4. A flexible holographic base film according to claim 4, wherein: the reflecting film is any one of aluminum foil, iron foil, tin foil, zinc foil, copper foil, chromium foil, nickel foil and titanium foil.
5. A flexible holographic element film according to claim 1, wherein: the transparent glue is any one of transparent epoxy resin AB glue, UV glue, shadowless glue, transparent glass glue, transparent wood glue and transparent all-purpose glue.
6. The method of claim 1, comprising the steps of:
1) preparing a cured pile:
a) stacking a plurality of transparent thin films plated with reflecting films which are cut in advance layer by layer,
forming a reflective film stack in which a reflective layer and a transparent layer are alternately arranged;
b) soaking the whole reflecting film stack in transparent glue water until the transparent glue water completely permeates into gaps among layers of the reflecting film stack, and taking out the reflecting film stack;
c) standing and curing, wherein in the curing process, a certain pressure is applied to extrude out the redundant glue among the transparent films so as to control the thickness of the reflecting film stack, and a curing stack with alternately arranged reflecting layers (2) and transparent layers (3) is formed after curing;
2) preparing a basic element film: grinding a smooth surface in the direction vertical to the plane of the reflecting layer (2) to be recorded as a cutting reference surface, cutting a sheet from the solidified pile along the direction parallel to the cutting reference surface to be recorded as a substrate film (1), wherein the newly cut surface on the solidified pile is the cutting reference surface of the next cutting, repeating the cutting step, and cutting the solidified pile of the step 1) into a plurality of substrate films (1).
7. The method of claim 6, wherein the method comprises: the cured mass described in step 1) can also be prepared by:
the transparent film plated with the reflecting film is placed on a plane, transparent glue is uniformly coated on the upper surface of the transparent film, then another transparent film plated with the reflecting film is stacked on the transparent glue layer, the stacking process is repeated to form a structure in which the reflecting film and the transparent film are stacked alternately, and a solidified stack is formed after standing and solidifying.
8. The method of claim 6, wherein the method comprises: the curing stack can be prepared by adding at least one transmission film between two transparent films plated with reflection films, wherein the transmission film is any one of a plastic film, a PMMA film, an lPMMA film, a PS film, a PC film, a styrene acrylonitrile film, an MS film, a PET film, a PETG film, an ABS film, a PP film, a PA film, an SAN film, an MS film, an MBS film, a PES film, a CR-39 film, a TPX film, a HEMA film, an F4 film, an F3 film, an EFP film, a PVF film, a PVDF film, an EP film, a PF film, an UP film, a cellulose acetate film, a cellulose nitrate film, an EVA film, a PE film, a PVC film, an amorphous cycloolefin film and a modified bisphenol A epoxy resin film.
9. The method of claim 6, wherein the method comprises: before the cutting in the step 2), a transparent protective film is bonded on the cutting reference surface by using transparent glue, or a transparent protective film is bonded on one surface or two surfaces of the element film (1) after the cutting is finished, and the element film (1) with the transparent protective film is obtained after the cutting, wherein the transparent protective film is any one of transparent glass, acrylic, plastic film, PMMA film, lPMMA film, PS film, PC film, styrene acrylonitrile film, MS film, PET film, PETG film, ABS film, PP film, PA film, SAN film, MS film, MBS film, PES film, CR-39 film, TPX film, HEMA film, F4 film, F3 film, EFP film, PVF film, PVDF film, EP film, PF film, UP film, cellulose acetate film, cellulose nitrate film, EVA film, PE film, PVC film, amorphous cycloolefin film and modified bisphenol A epoxy film.
10. Use of a flexible holographic base film prepared by a method of preparing a flexible holographic base film according to any of claims 6 to 9, wherein: the flexible holographic base film (1) is applied to preparing a flexible 3D display holographic film, and specifically comprises the following steps:
two flexible substrate films (1) are bonded together up and down by using transparent glue, a flexible 3D display holographic film is formed after curing, the reflecting layer (2) and the transparent layer (3) on the two substrate films (1) are staggered by an included angle theta to form a grid (4) during bonding, the theta is more than or equal to 87 degrees and less than or equal to 93 degrees, and the horizontal clamping sagging length L (cm) of the flexible 3D display holographic film and the folding times n meet the following requirements: n L >9 or L is more than or equal to 5, and the element film (1) is provided with a flexible transparent protective film or is not provided with the transparent protective film.
11. Use of a base film with a transparent protective film according to claim 9, wherein: the application of the base element film (1) with the transparent protective film in the preparation of the hard 3D display holographic projection screen specifically comprises the following steps:
one substrate film (1) with a hard transparent protective film and the other substrate film (1) with or without the transparent protective film are bonded together up and down by using transparent glue, and the reflecting layer (2) and the transparent layer (3) on the two substrate films (1) are staggered at an included angle theta to form a grid (4), wherein the theta is more than or equal to 87 degrees and less than or equal to 93 degrees.
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