CN110882184A - Sun-proof bubble using carbon dioxide as propellant and preparation method thereof - Google Patents
Sun-proof bubble using carbon dioxide as propellant and preparation method thereof Download PDFInfo
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- CN110882184A CN110882184A CN201910978221.9A CN201910978221A CN110882184A CN 110882184 A CN110882184 A CN 110882184A CN 201910978221 A CN201910978221 A CN 201910978221A CN 110882184 A CN110882184 A CN 110882184A
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- Prior art keywords
- carbon dioxide
- sunscreen
- propellant
- bubble
- component
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- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title claims abstract description 108
- 229910002092 carbon dioxide Inorganic materials 0.000 title claims abstract description 54
- 239000001569 carbon dioxide Substances 0.000 title claims abstract description 54
- 239000003380 propellant Substances 0.000 title claims abstract description 43
- 238000002360 preparation method Methods 0.000 title description 6
- 239000000516 sunscreening agent Substances 0.000 claims abstract description 45
- 230000000475 sunscreen effect Effects 0.000 claims abstract description 40
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 6
- 239000002562 thickening agent Substances 0.000 claims abstract description 6
- 239000003755 preservative agent Substances 0.000 claims abstract description 5
- 230000002335 preservative effect Effects 0.000 claims abstract description 5
- 238000003756 stirring Methods 0.000 claims description 24
- 239000011550 stock solution Substances 0.000 claims description 17
- 239000000126 substance Substances 0.000 claims description 16
- 238000011049 filling Methods 0.000 claims description 14
- 238000010438 heat treatment Methods 0.000 claims description 14
- HEOCBCNFKCOKBX-RELGSGGGSA-N (1s,2e,4r)-4,7,7-trimethyl-2-[(4-methylphenyl)methylidene]bicyclo[2.2.1]heptan-3-one Chemical compound C1=CC(C)=CC=C1\C=C/1C(=O)[C@]2(C)CC[C@H]\1C2(C)C HEOCBCNFKCOKBX-RELGSGGGSA-N 0.000 claims description 13
- WSSJONWNBBTCMG-UHFFFAOYSA-N 2-hydroxybenzoic acid (3,3,5-trimethylcyclohexyl) ester Chemical compound C1C(C)(C)CC(C)CC1OC(=O)C1=CC=CC=C1O WSSJONWNBBTCMG-UHFFFAOYSA-N 0.000 claims description 13
- 229960004697 enzacamene Drugs 0.000 claims description 13
- 229960004881 homosalate Drugs 0.000 claims description 13
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 claims description 13
- LADGBHLMCUINGV-UHFFFAOYSA-N tricaprin Chemical compound CCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCC)COC(=O)CCCCCCCCC LADGBHLMCUINGV-UHFFFAOYSA-N 0.000 claims description 13
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 12
- 239000002253 acid Substances 0.000 claims description 12
- 125000005250 alkyl acrylate group Chemical group 0.000 claims description 12
- FMJSMJQBSVNSBF-UHFFFAOYSA-N octocrylene Chemical group C=1C=CC=CC=1C(=C(C#N)C(=O)OCC(CC)CCCC)C1=CC=CC=C1 FMJSMJQBSVNSBF-UHFFFAOYSA-N 0.000 claims description 12
- 229960000601 octocrylene Drugs 0.000 claims description 12
- 239000000230 xanthan gum Substances 0.000 claims description 12
- 229920001285 xanthan gum Polymers 0.000 claims description 12
- 229940082509 xanthan gum Drugs 0.000 claims description 12
- 235000010493 xanthan gum Nutrition 0.000 claims description 12
- RZRNAYUHWVFMIP-KTKRTIGZSA-N 1-oleoylglycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-KTKRTIGZSA-N 0.000 claims description 11
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 11
- 229920006037 cross link polymer Polymers 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 11
- 229940100460 peg-100 stearate Drugs 0.000 claims description 11
- ZAKOWWREFLAJOT-CEFNRUSXSA-N D-alpha-tocopherylacetate Chemical compound CC(=O)OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-CEFNRUSXSA-N 0.000 claims description 9
- 125000002801 octanoyl group Chemical group C(CCCCCCC)(=O)* 0.000 claims description 9
- 230000001804 emulsifying effect Effects 0.000 claims description 8
- NCZPCONIKBICGS-UHFFFAOYSA-N 3-(2-ethylhexoxy)propane-1,2-diol Chemical compound CCCCC(CC)COCC(O)CO NCZPCONIKBICGS-UHFFFAOYSA-N 0.000 claims description 7
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 claims description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 7
- 229910052782 aluminium Inorganic materials 0.000 claims description 7
- 238000007664 blowing Methods 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 7
- 238000007599 discharging Methods 0.000 claims description 7
- 229940100524 ethylhexylglycerin Drugs 0.000 claims description 7
- 238000001914 filtration Methods 0.000 claims description 7
- AEIJTFQOBWATKX-UHFFFAOYSA-N octane-1,2-diol Chemical compound CCCCCCC(O)CO AEIJTFQOBWATKX-UHFFFAOYSA-N 0.000 claims description 7
- 238000003825 pressing Methods 0.000 claims description 7
- 238000007789 sealing Methods 0.000 claims description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 6
- UFVWHIGSVGIZRQ-UHFFFAOYSA-N bis(2-ethylhexyl) naphthalene-2,6-dicarboxylate Chemical compound C1=C(C(=O)OCC(CC)CCCC)C=CC2=CC(C(=O)OCC(CC)CCCC)=CC=C21 UFVWHIGSVGIZRQ-UHFFFAOYSA-N 0.000 claims description 6
- 229940031765 diethylhexyl 2,6-naphthalate Drugs 0.000 claims description 6
- 229940042585 tocopherol acetate Drugs 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 4
- 150000001413 amino acids Chemical class 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 2
- 229910052799 carbon Inorganic materials 0.000 claims 2
- 229920005862 polyol Polymers 0.000 claims 1
- 150000003077 polyols Chemical class 0.000 claims 1
- 239000006260 foam Substances 0.000 abstract description 6
- 230000002349 favourable effect Effects 0.000 abstract 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 28
- -1 acrylic ester Chemical class 0.000 description 17
- 239000004475 Arginine Substances 0.000 description 12
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 description 12
- PHYFQTYBJUILEZ-UHFFFAOYSA-N Trioleoylglycerol Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(OC(=O)CCCCCCCC=CCCCCCCCC)COC(=O)CCCCCCCC=CCCCCCCCC PHYFQTYBJUILEZ-UHFFFAOYSA-N 0.000 description 10
- 235000011187 glycerol Nutrition 0.000 description 10
- 239000012071 phase Substances 0.000 description 8
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 239000003915 liquefied petroleum gas Substances 0.000 description 7
- UREKALWDINQAOW-UHFFFAOYSA-N 2-ethyloctyl naphthalene-1-carboxylate Chemical compound C1=CC=C2C(C(=O)OCC(CC)CCCCCC)=CC=CC2=C1 UREKALWDINQAOW-UHFFFAOYSA-N 0.000 description 6
- 239000007921 spray Substances 0.000 description 6
- ANZUDYZHSVGBRF-UHFFFAOYSA-N 3-ethylnonane-1,2,3-triol Chemical compound CCCCCCC(O)(CC)C(O)CO ANZUDYZHSVGBRF-UHFFFAOYSA-N 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 5
- 239000006071 cream Substances 0.000 description 4
- 229940075529 glyceryl stearate Drugs 0.000 description 4
- ZAKOWWREFLAJOT-UHFFFAOYSA-N d-alpha-Tocopheryl acetate Natural products CC(=O)OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-UHFFFAOYSA-N 0.000 description 3
- FOYKKGHVWRFIBD-UHFFFAOYSA-N gamma-tocopherol acetate Natural products CC(=O)OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 FOYKKGHVWRFIBD-UHFFFAOYSA-N 0.000 description 3
- 230000003020 moisturizing effect Effects 0.000 description 3
- 230000037072 sun protection Effects 0.000 description 3
- 239000007789 gas Substances 0.000 description 2
- 238000012216 screening Methods 0.000 description 2
- 239000012808 vapor phase Substances 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000019522 cellular metabolic process Effects 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/046—Aerosols; Foams
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/35—Ketones, e.g. benzophenone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
- A61K8/585—Organosilicon compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/67—Vitamins
- A61K8/678—Tocopherol, i.e. vitamin E
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/22—Gas releasing
- A61K2800/222—Effervescent
Abstract
The invention provides a sunscreen bubble taking carbon dioxide as a propellant, which is characterized by comprising the following components in percentage by mass: 10.5 to 38 percent of oil phase component; 0.2 to 1.5 percent of thickening agent; 1 to 5 percent of pH regulator; 0.3 to 3 percent of preservative; 0.01 to 0.2 percent of essence; 0.5-3% of carbon dioxide; the balance of water, wherein the oil phase component comprises a sunscreen agent and an emulsifier. The sunscreen bubble completely uses carbon dioxide as a propellant, and the foam is thick and fine when the product is extruded, so that the product is easy to push away on the surface of the skin, and the skin feels fresh and cool without greasy feeling, so that the sunscreen bubble is suitable for large-area use; and the product belongs to a non-flammable product, has no inhalation risk, is favorable for carrying and transportation, and improves the safety performance of the product.
Description
Technical Field
The invention relates to the technical field of daily chemical products, in particular to a sun-proof bubble taking carbon dioxide as a propellant and a preparation method thereof.
Background
The current commercial sunscreen products are classified broadly into sunscreen creams and sunscreen sprays using LPG (liquefied petroleum gas) as a propellant. Among them, sunscreen creams account for most of the commercial products, and the biggest disadvantage of sunscreen creams is that they are not easy to be applied on a large scale on the body, and among them, sunscreen creams with high sun protection index are often accompanied by sticky feeling, while thinner sunscreens have poor experience of body flow, dripping, etc. The sun-proof spray taking LPG as a propellant is convenient to use in a large area, however, the atomization effect of the liquid body sprayed by the propellant is very good, the experience of cloud and mist turning in the using process may cause people to have doubts in the aspect of safety, and the inhalation risk is large. In addition, the sun-screening spray using liquefied petroleum gas as propellant has the limitations in storage, transportation and carrying by consumers because the liquefied petroleum gas content in the product is high and the liquefied petroleum gas belongs to combustible substances.
Disclosure of Invention
The present invention is made to solve the above problems, and an object of the present invention is to provide a sunscreen bubble using carbon dioxide as a propellant, and a method for preparing the same.
The invention provides a sunscreen bubble taking carbon dioxide as a propellant, which is characterized by comprising the following components in percentage by mass:
wherein the oil phase component comprises a sunscreen agent and an emulsifier, and the propellant is carbon dioxide.
Further, the sunscreen bubble using carbon dioxide as propellant provided by the invention also has the following characteristics: wherein the sunscreen agent comprises homosalate, 4-methylbenzylidene camphor, octocrylene, and diethylhexyl 2, 6-naphthalate.
Further, the sunscreen bubble using carbon dioxide as propellant provided by the invention also has the following characteristics: the emulsifier comprises a component A and a component B, wherein the component A is selected from any one or mixture of two of glyceryl oleate citrate and caprylic/capric triglyceride, and the component B is selected from any one or mixture of PEG-100 stearate and glyceryl stearate.
Further, the sunscreen bubble using carbon dioxide as propellant provided by the invention also has the following characteristics: wherein the thickener comprises xanthan gum and an acrylate/alkyl acrylate crosspolymer.
Further, the sunscreen bubble using carbon dioxide as propellant provided by the invention also has the following characteristics: wherein the pH regulator is basic amino acid, preferably arginine.
Further, the sunscreen bubble using carbon dioxide as propellant provided by the invention also has the following characteristics: wherein the antiseptic comprises caprylyl hydroximic acid, caprylyl glycol, and ethylhexyl glycerin.
Further, the sunscreen bubble using carbon dioxide as a propellant provided by the present invention is characterized by further comprising: at least one saturated polyhydric alcohol having not more than 4 carbon atoms, preferably any one or two of butylene glycol and glycerin.
Further, the sunscreen bubble using carbon dioxide as propellant provided by the invention also has the following characteristics: wherein the oil phase component also comprises at least one component of tocopherol acetate and cyclopentasiloxane.
Further, the sunscreen bubble taking carbon dioxide as a propellant is characterized by being prepared from the following components in percentage by mass:
in addition, the invention also provides a preparation method of the sunscreen bubble taking carbon dioxide as a propellant, which is characterized by comprising the following steps:
step one, stirring and dispersing a thickening agent uniformly in advance for later use;
heating the oil phase components to 75-80 ℃, and completely dissolving for later use;
step three, adding the substance obtained in the step one into the water phase component, heating to 75-80 ℃, uniformly stirring, then adding the substance obtained in the step two, fully homogenizing and emulsifying, uniformly stirring, then adding a pH regulator, cooling to 40 ℃, then adding essence and preservative, filtering and discharging to obtain a stock solution;
and step four, filling the stock solution obtained in the step three into an aluminum tank, sealing, filling carbon dioxide, performing water bath, blowing, adding a nozzle, and pressing a pump head to extrude the mixture to obtain the sun-proof bubbles.
The invention has the following functions and effects:
by the formulation and process steps of the present invention, there is provided a carbon dioxide propellant-based sunscreen bubble that fully utilizes carbon dioxide as a propellant, wherein the carbon dioxide has a vapor phase and a dissolved phase, and the carbon dioxide in the vapor phase provides pressure to the product; the carbon dioxide in the dissolved phase is dissolved in the stock solution when the product is extruded, and the carbon dioxide is partially gasified due to pressure reduction so as to form bright and fine foam. The product has dense and fine foam, on one hand, the product is easy to push away on the surface of the skin, so that the skin feel is fresh and cool, has no greasy feel, and is very suitable for sun protection in daily life; on the other hand, even if the device is used in a large area, the phenomenon of dripping can not be caused, and the user experience is improved.
In addition, carbon dioxide is a non-combustible gas. Is different from the existing LPG flammable gas as the sun protection spray propellant. Therefore, the aqueous product with carbon dioxide as the propellant is generally a non-flammable product, and the safety performance is improved.
In addition, the sunscreen foam using carbon dioxide as a propellant is a sunscreen product in a foam form, and has no inhalation risk compared with the existing sunscreen spray, so that the sunscreen foam is safer compared with the existing sunscreen spray.
In addition, in the formula of the invention, homosalate, 4-methylbenzylidene camphor, octocrylene and 2, 6-diethylhexyl naphthalate are used as sun-screening agents, and glyceryl oleate citrate, caprylic/capric triglyceride, PEG-100 stearate and glyceryl stearate are used as emulsifiers, so that the product stock solution has good sun-screening effect and stability. Furthermore, arginine is used as a pH regulator, so that the pH regulator has the effects of regulating the acid-base balance of skin, promoting cell metabolism and repairing skin. Furthermore, the butanediol and the glycerin in the formula are beneficial to improving the moisturizing effect, and the tocopherol acetate and the cyclopentasiloxane play a moisturizing effect, so that the effects of moisturizing and moistening the skin are achieved while the sun is protected. The components of the formula are matched according to a specific proportion, so that a good synergistic effect is achieved, and the sun-proof experience effect of the sun-proof bubble users is better.
In addition, in the preparation process of the white sunscreen bubble, firstly, the thickener component and the oil phase component in the formula are respectively dispersed in advance, then are sequentially added into the water phase component for treatment, and then the auxiliary agents such as the pH regulator, the essence and the preservative are added, so that the obtained stock solution has good homogenizing and emulsifying effect and good product stability.
Detailed Description
In order to make the technical means, creation features, achievement objects and effects of the present invention easy to understand, the following examples specifically describe the sunscreen bubble using carbon dioxide as propellant and the preparation method thereof.
< example 1>
The formula is as follows: homosalate 3 percent; 3% of 4-methylbenzylidene camphor; 4% of octocrilene; 4% of diethylhexyl 2, 6-naphthalate; glyceryl oleate citrate and caprylic/capric triglyceride, total 3%; 0.5% of PEG-100 stearate and glycerol stearate; 1% of xanthan gum; 0.5 percent of acrylic ester/C10-30 alkyl acrylate cross-linked polymer; 0.1% of tocopherol acetate; 5% of cyclopentasiloxane; 0.1% of caprylyl hydroximic acid; 0.1 percent of octyl glycol; 1% of ethylhexyl glycerol; 3.5 percent of arginine; 5% of butanediol; 5% of glycerol; 0.01% of essence; 2% of carbon dioxide; the balance of water.
The sun-proof bubble with carbon dioxide as propellant is prepared according to the following steps:
adding xanthan gum and acrylic ester/C10-30 alkyl acrylate cross-linked polymer into glycerol, stirring and dispersing uniformly in advance for later use;
heating homosalate, 4-methylbenzylidene camphor, octocrylene, 2, 6-diethylhexyl naphthalate, PEG-100 stearate, glyceryl oleate citrate, caprylic/capric triglyceride, tocopheryl acetate and cyclopentasiloxane to 75 ℃, and completely dissolving for later use;
step three, sequentially adding water and butanediol into a reaction container, uniformly stirring, adding the substance obtained in the step one, heating to 75 ℃, uniformly stirring, then adding the substance obtained in the step two, fully homogenizing and emulsifying, uniformly stirring, then adding arginine, cooling to 40 ℃, then adding essence, caprylyl hydroxamic acid, caprylyl glycol and ethylhexylglycerin, filtering and discharging to obtain a stock solution;
and step four, filling the stock solution obtained in the step three into an aluminum tank, sealing, filling carbon dioxide, performing water bath, blowing, adding a nozzle, and pressing a pump head to extrude the mixture to obtain the sun-proof bubbles.
< example 2>
The formula is as follows: 10% of homosalate; 5% of 4-methylbenzylidene camphor; 5% of octocrilene; 5% of diethylhexyl 2, 6-naphthalate; glyceryl oleate citrate and caprylic/capric triglyceride, total 5%; 2% of PEG-100 stearate and glyceryl stearate; 0.1% of xanthan gum; 0.1% of acrylate/C10-30 alkyl acrylate cross-linked polymer; 1% of tocopherol acetate; 5% of cyclopentasiloxane; 0.2% of caprylyl hydroximic acid; 0.2 percent of octyl glycol; 0.2% of ethylhexyl glycerol; 1% of arginine; 1% of butanediol; 1% of glycerol; 0.2 percent of essence; 3% of carbon dioxide; the balance of water.
The sun-proof bubble with carbon dioxide as propellant is prepared according to the following steps:
adding xanthan gum and acrylic ester/C10-30 alkyl acrylate cross-linked polymer into glycerol, stirring and dispersing uniformly in advance for later use;
heating homosalate, 4-methylbenzylidene camphor, octocrylene, 2, 6-diethylhexyl naphthalate, PEG-100 stearate, glyceryl oleate citrate, caprylic/capric triglyceride, tocopheryl acetate and cyclopentasiloxane to 80 ℃, and completely dissolving for later use;
step three, adding water and butanediol into a reaction container in sequence, uniformly stirring, adding the substance obtained in the step one, heating to 78 ℃, uniformly stirring, adding the substance obtained in the step two, fully homogenizing and emulsifying, uniformly stirring, adding arginine, cooling to 40 ℃, adding essence, caprylyl hydroxamic acid, caprylyl glycol and ethylhexylglycerin, filtering and discharging to obtain a stock solution;
and step four, filling the stock solution obtained in the step three into an aluminum tank, sealing, filling carbon dioxide, performing water bath, blowing, adding a nozzle, and pressing a pump head to extrude the mixture to obtain the sun-proof bubbles.
< example 3>
The formula is as follows: 2% of homosalate; 2% of 4-methylbenzylidene camphor; 2% of octocrilene; 2%, 6-diethylhexyl naphthalate; caprylic/capric triglyceride 2%; 0.5 percent of PEG-100 stearate; 0.5% of xanthan gum; acrylate/C10-30 alkyl acrylate crosslinking polymerization 0.5%; 1% of caprylyl hydroximic acid; 1% of octyl glycol; 1% of ethylhexyl glycerol; 2% of arginine; 2.5 percent of butanediol; 4% of glycerol; 0.1% of essence; 0.5 percent of carbon dioxide; the balance of water.
The sun-proof bubble with carbon dioxide as propellant is prepared according to the following steps:
adding xanthan gum and acrylic ester/C10-30 alkyl acrylate cross-linked polymer into glycerol, stirring and dispersing uniformly in advance for later use;
heating homosalate, 4-methylbenzylidene camphor, octocrylene, 2, 6-diethylhexyl naphthalate, PEG-100 stearate and caprylic/capric triglyceride to 76 ℃, and completely dissolving for later use;
step three, sequentially adding water and butanediol into a reaction container, uniformly stirring, adding the substance obtained in the step one, heating to 80 ℃, uniformly stirring, adding the substance obtained in the step two, fully homogenizing and emulsifying, uniformly stirring, adding arginine, cooling to 40 ℃, adding essence, caprylyl hydroxamic acid, caprylyl glycol and ethylhexylglycerin, filtering and discharging to obtain a stock solution;
and step four, filling the stock solution obtained in the step three into an aluminum tank, sealing, filling carbon dioxide, performing water bath, blowing, adding a nozzle, and pressing a pump head to extrude the mixture to obtain the sun-proof bubbles.
< example 4>
The formula is as follows: 5% of homosalate; 5% of 4-methylbenzylidene camphor; 5% of octocrilene; 5% of diethylhexyl 2, 6-naphthalate; glyceryl oleate citrate and caprylic/capric triglyceride, 2% total; 2% of glycerol stearate; 0.8% of xanthan gum; 0.4% of acrylate/C10-30 alkyl acrylate crosspolymer; 0.6 percent of caprylyl hydroximic acid; 0.8 percent of octyl glycol; 0.8% of ethylhexyl glycerol; 5% of arginine; 5% of glycerol; 0.15% of essence; 2% of carbon dioxide; the balance of water.
The sun-proof bubble with carbon dioxide as propellant is prepared according to the following steps:
adding xanthan gum and acrylic ester/C10-30 alkyl acrylate cross-linked polymer into glycerol, stirring and dispersing uniformly in advance for later use;
heating homosalate, 4-methylbenzylidene camphor, octocrylene, 2, 6-diethylhexyl naphthalate, glyceryl stearate, glyceryl oleate citrate and caprylic/capric triglyceride to 77 ℃, and completely dissolving for later use;
step three, adding water into a reaction container, then adding the substance obtained in the step one, heating to 79 ℃, uniformly stirring, then adding the substance obtained in the step two, fully homogenizing and emulsifying, uniformly stirring, then adding arginine, cooling to 40 ℃, then adding essence, caprylyl hydroximic acid, caprylyl glycol and ethylhexylglycerin, filtering and discharging to obtain a stock solution;
and step four, filling the stock solution obtained in the step three into an aluminum tank, sealing, filling carbon dioxide, performing water bath, blowing, adding a nozzle, and pressing a pump head to extrude the mixture to obtain the sun-proof bubbles.
< example 5>
The formula is as follows: 8% of homosalate; 4% of 4-methylbenzylidenecamphor; 3% of octocrilin; 3% of diethylhexyl 2, 6-naphthalate; glyceryl oleate citrate and caprylic/capric triglyceride, total 4%; 1% of PEG-100 stearate and glycerol stearate; 1% of xanthan gum; 0.3% of acrylate/C10-30 alkyl acrylate cross-linked polymer; 0.6% of tocopherol acetate; 0.7% of caprylyl hydroximic acid; 0.8 percent of octyl glycol; 1% of ethylhexyl glycerol; 4% of arginine; 0.12% of essence; 2.5 percent of carbon dioxide; the balance of water.
The sun-proof bubble with carbon dioxide as propellant is prepared according to the following steps:
adding xanthan gum and acrylic ester/C10-30 alkyl acrylate cross-linked polymer into water, stirring and dispersing uniformly in advance for later use;
heating homosalate, 4-methylbenzylidene camphor, octocrylene, 2, 6-diethylhexyl naphthalate, PEG-100 stearate, glyceryl oleate citrate, caprylic/capric triglyceride and tocopheryl acetate to 80 ℃, and completely dissolving for later use;
step three, adding water into a reaction container, then adding the substance obtained in the step one, heating to 80 ℃, uniformly stirring, then adding the substance obtained in the step two, fully homogenizing and emulsifying, uniformly stirring, then adding arginine, cooling to 40 ℃, then adding essence, caprylyl hydroximic acid, caprylyl glycol and ethylhexylglycerin, filtering and discharging to obtain a stock solution;
and step four, filling the stock solution obtained in the step three into an aluminum tank, sealing, filling carbon dioxide, performing water bath, blowing, adding a nozzle, and pressing a pump head to extrude the mixture to obtain the sun-proof bubbles.
Claims (10)
1. A sunscreen bubble using carbon dioxide as a propellant is characterized in that: comprises the following components in percentage by mass:
wherein the oil phase component comprises a sunscreen agent and an emulsifier,
the propellant is carbon dioxide.
2. The carbon dioxide propellant sunscreen bubble of claim 1 wherein:
wherein the sunscreen comprises homosalate, 4-methylbenzylidenecamphor, octocrylene, and diethylhexyl 2, 6-naphthalate.
3. The carbon dioxide propellant sunscreen bubble of claim 1 wherein:
wherein the emulsifier comprises a component A and a component B,
the component A is selected from any one or two of glycerol oleate citrate and caprylic/capric triglyceride,
the component B is selected from one or a mixture of two of PEG-100 stearate and glycerol stearate.
4. The carbon dioxide propellant sunscreen bubble of claim 1 wherein:
wherein the thickener comprises xanthan gum and an acrylate/alkyl acrylate crosspolymer.
5. The carbon dioxide propellant sunscreen bubble of claim 1 wherein:
wherein the pH regulator is a basic amino acid.
6. The carbon dioxide propellant sunscreen bubble of claim 1 wherein:
wherein the preservative comprises caprylyl hydroximic acid, caprylyl glycol, and ethylhexyl glycerin.
7. The carbon dioxide-propellant sunscreen bubble of claim 1 further comprising:
at least one saturated polyol having not more than 4 carbon atoms.
8. The carbon dioxide-propellant sunscreen bubble of claim 1 wherein:
wherein the oil phase component also comprises at least one component of tocopherol acetate and cyclopentasiloxane.
9. The carbon dioxide propellant sunscreen bubble of claim 1 prepared from the following components in mass percent:
10. the method for preparing the sunscreen bubble using carbon dioxide as propellant as claimed in any one of claims 1 to 9, wherein:
step one, stirring and dispersing a thickening agent uniformly in advance for later use;
heating the oil phase components to 75-80 ℃, and completely dissolving for later use;
step three, adding the substance obtained in the step one into the water phase component, heating to 75-80 ℃, uniformly stirring, then adding the substance obtained in the step two, fully homogenizing and emulsifying, uniformly stirring, then adding a pH regulator, cooling to 40 ℃, then adding essence and preservative, filtering and discharging to obtain a stock solution;
and step four, filling the stock solution obtained in the step three into an aluminum tank, sealing, filling carbon dioxide, performing water bath, blowing, adding a nozzle, and pressing a pump head to extrude the mixture to obtain the sun-proof bubbles.
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| CN201910978221.9A CN110882184A (en) | 2019-10-15 | 2019-10-15 | Sun-proof bubble using carbon dioxide as propellant and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2022230853A1 (en) * | 2021-04-28 | 2022-11-03 | 花王株式会社 | Aerosol cosmetic |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20020187114A1 (en) * | 2001-06-11 | 2002-12-12 | Mankovitz Roy J. | Plant-based non-toxic sunscreen products |
| CN106619147A (en) * | 2015-10-30 | 2017-05-10 | 强生消费者公司 | Effervescent sunscreen composition |
| CN107929097A (en) * | 2018-01-03 | 2018-04-20 | 中山市天图精细化工有限公司 | A kind of sun-proof foam aerosol |
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2019
- 2019-10-15 CN CN201910978221.9A patent/CN110882184A/en active Pending
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|---|---|---|---|---|
| US20020187114A1 (en) * | 2001-06-11 | 2002-12-12 | Mankovitz Roy J. | Plant-based non-toxic sunscreen products |
| CN106619147A (en) * | 2015-10-30 | 2017-05-10 | 强生消费者公司 | Effervescent sunscreen composition |
| CN107929097A (en) * | 2018-01-03 | 2018-04-20 | 中山市天图精细化工有限公司 | A kind of sun-proof foam aerosol |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2022230853A1 (en) * | 2021-04-28 | 2022-11-03 | 花王株式会社 | Aerosol cosmetic |
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Application publication date: 20200317 |