CN110878715A - Reducing NO during low power operation of gas turbinexMethod of discharging - Google Patents

Reducing NO during low power operation of gas turbinexMethod of discharging Download PDF

Info

Publication number
CN110878715A
CN110878715A CN201911330048.8A CN201911330048A CN110878715A CN 110878715 A CN110878715 A CN 110878715A CN 201911330048 A CN201911330048 A CN 201911330048A CN 110878715 A CN110878715 A CN 110878715A
Authority
CN
China
Prior art keywords
gas
plasma
compressor
turbine
air
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201911330048.8A
Other languages
Chinese (zh)
Inventor
陈明
金敏杰
曹亮
李福兴
崔勇
赵文彬
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
State Grid Shanghai Electric Power Co Ltd
Original Assignee
State Grid Shanghai Electric Power Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by State Grid Shanghai Electric Power Co Ltd filed Critical State Grid Shanghai Electric Power Co Ltd
Publication of CN110878715A publication Critical patent/CN110878715A/en
Pending legal-status Critical Current

Links

Images

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02CGAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
    • F02C7/00Features, components parts, details or accessories, not provided for in, or of interest apart form groups F02C1/00 - F02C6/00; Air intakes for jet-propulsion plants
    • F02C7/12Cooling of plants
    • F02C7/14Cooling of plants of fluids in the plant, e.g. lubricant or fuel
    • F02C7/141Cooling of plants of fluids in the plant, e.g. lubricant or fuel of working fluid
    • F02C7/143Cooling of plants of fluids in the plant, e.g. lubricant or fuel of working fluid before or between the compressor stages
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/01Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust by means of electric or electrostatic separators
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2570/00Exhaust treating apparatus eliminating, absorbing or adsorbing specific elements or compounds
    • F01N2570/14Nitrogen oxides

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Treating Waste Gases (AREA)
  • Exhaust Gas After Treatment (AREA)

Abstract

The present disclosure discloses a method for reducing NOXAn exhaust gas turbine engine comprising: the device comprises a compressor, a turbine, a generator, a cooling device and a plasma denitration device. The present disclosure also discloses a method for reducing NO during low power operation of a gas turbineXA method of venting. According to the gas turbine, the cooling device is arranged at the gas inlet of the gas turbine, and the plasma denitration device is arranged at the gas outlet, so that NO can be effectively reducedXAnd (4) discharging.

Description

Reducing NO during low power operation of gas turbineXMethod of discharging
Technical Field
The disclosure belongs to the field of comprehensive optimization control of electrical engineering, and particularly relates to a method for reducing NO during low-power operation of a gas turbineXA method of venting.
Background
With the further optimized configuration of electric power resources, the extra-high voltage direct current can continuously transport the Sichuan (quantitative) quantitative energy to the load concentration region, thereby meeting the requirements of social production and realizing the low-carbon Sichuan (quantitative) quantitative power supply. However, the scale of the direct current concentrated fed into the receiving-end power grid is greatly increased, and new challenges are brought to the safe and stable operation of the receiving-end power grid. With the centralized feeding of large-scale direct current, the voltage regulation and control capability of the power grid is obviously influenced, and the influence is particularly prominent under the condition of a dynamic phase change failure process and a low-valley condition of a direct current system. According to the direct current design principle, direct current does not provide dynamic reactive power for the system. The extra-high voltage direct current transmission can transmit active power on a large scale, so that the receiving end power grid is insufficient in reactive power, and a large amount of reactive power needs to be absorbed from the system in the dynamic process.
The large-scale gas turbine is used as a generator set with rapid start and stop and convenient adjustment, is relatively suitable for the application of dynamic reactive power support of a receiving-end power grid, does not excessively increase the basic load requirement of the receiving-end power grid, and is generally called as a gas turbine low-power phase modulation operation technology. However, during low power phase modulation operation of gas turbines, increased NOx emissions may occur. In recent years, NOx emissions have failed to meet the standards of new environmental regulations. Therefore, it is necessary to add a certain technical means to the air intake and exhaust links of the gas turbine to achieve the effect of reducing the comprehensive emission.
Disclosure of Invention
To address the problem of increased NOx emissions during low power operation in existing gas turbines, the present disclosureIt is an object to provide a method for reducing NO during low power operation of a gas turbineXThe method of discharging, on one hand, set up the refrigerating plant in the air intake, in order to reduce the production of NOx by lowering the intake temperature; and on the other hand, a plasma denitration device is arranged at the discharge port to reduce the discharge amount of NOx.
The purpose of the present disclosure is realized by the following technical scheme:
can reduce NOXAn exhaust gas turbine engine comprising: the system comprises a gas compressor, a turbine, a generator, a cooling device and a plasma denitration device; wherein the content of the first and second substances,
the compressor, the turbine and the generator are arranged on the same main shaft;
the cooling device is arranged in front of the air compressor and used for cooling and refrigerating air to be fed into the air compressor; the plasma denitration device is arranged behind the turbine, and NO contained in the flue gas is removed through plasma generated by high-voltage dischargeX
The refrigerating capacity of the cooling device is matched with the air inlet amount of the air compressor by 1: 1.
Preferably, one end of the generator is provided with a high-voltage standby transformer for supplying power to the cooling device and the plasma denitration device; the high-voltage standby transformer is connected with the cooling device and the plasma denitration device through a first switch S1 and a second switch S2 respectively.
The present disclosure also provides a method for reducing NO during low power operation of a gas turbineXA method of venting comprising the steps of:
s100: cooling air to be fed into the compressor;
s200: plasma treatment of NO contained in flue gasXThe molecules are oxidized and degraded.
Preferably, the NO is treated by plasmaXThe molecules are oxidized and degraded in any mode as follows: electron beam irradiation and gas corona discharge.
Drawings
FIG. 1 is a schematic representation of a method of reducing NO as disclosed in the present disclosureXSchematic of the exhaust gas turbine.
FIG. 2 is a schematic diagram of the components of a gas turbine inlet air cooled by the electric refrigeration technique shown in this disclosure.
Detailed Description
The technical solution of the present disclosure is described in detail below with reference to the accompanying drawings and examples.
Referring to FIG. 1, a method for reducing NOXAn exhaust gas turbine engine comprising: the system comprises a gas compressor, a turbine, a generator, a cooling device and a plasma denitration device; the compressor, the turbine and the generator are arranged on the same main shaft; the cooling device is arranged in front of the air compressor and used for cooling and refrigerating air to be fed into the air compressor; the plasma denitration device is arranged behind the turbine, and NO contained in the flue gas is removed through plasma generated by high-voltage dischargeX
The embodiment refrigerates and cools the air, thereby reducing NOXAt the same time, the NO contained in the flue gas is treated by the plasma denitration technology at the exhaust portXThe embodiment can effectively reduce NO generated in the combustion process of the gas turbine by carrying out oxidation and degradation and combining two emission reduction modesXThe amount of discharge of (c).
In another embodiment, one end of the generator is provided with a high-voltage standby transformer for supplying power to the cooling device and the plasma denitration device; the high-voltage standby transformer is connected with the cooling device and the plasma denitration device through a first switch S1 and a second switch S2 respectively.
In this embodiment, the high-voltage backup transformer is connected to the cooler through the first switch S1, and the high-voltage backup transformer is connected to the plasma denitration device through the second switch S2.
In another embodiment, the refrigerating capacity of the cooler is matched with the air inlet quantity 1:1 of the compressor.
In another embodiment, the intake air of the gas turbine is cooled by adopting an electric refrigeration technology, the components of the intake air are shown in figure 2, firstly, a tubular heat exchanger is arranged at an air inlet channel of a gas compressor of the gas turbine, the air flow and the air intake of the gas compressor are the same, and the matching of 1:1 is ensured. The variable frequency power supply is supplied with power by a power supply at the generator end of the gas turbine generator, the refrigerating machine is driven to generate cold water with the temperature of less than 5 ℃, and the cold water is injected into the tubular heat exchanger, so that the effect of reducing the temperature of inlet air is achieved. .
In another embodiment, the present disclosure also provides a method for reducing NO during low power operation of a gas turbineXA method of venting comprising the steps of:
s100: cooling air to be fed into the compressor;
s200: plasma treatment of NO contained in flue gasXThe molecules are oxidized and degraded.
In the specific embodiment of the step S100, the cooling device is added to the air inlet of the compressor to reduce the temperature of the inlet air, so as to reduce the combustion temperature under the same output condition, which is helpful for reducing NOXAnd (4) discharging.
In the embodiment of step S200, a large amount of energy-carrying electrons are generated to bombard NO by discharging under normal temperature and normal pressure under the action of an external electric fieldXThe molecules are ionized, dissociated and excited, and then are converted into simple small molecule safe substances.
In another embodiment, in step S200, the NO is plasma-pairedXThe molecules are oxidized and degraded in any mode as follows: electron beam irradiation and gas corona discharge.
In this embodiment, the electron beam irradiation is performed by irradiating the flue gas with an electron beam generated by an electron accelerator, so that molecules such as water vapor and oxygen are excited to generate active substances such as high-energy radicals with strong oxidizing property, and NO in the flue gas is oxidized into NO2Reacting with water vapor to generate vaporous nitric acid, then introducing NH3Ammonium nitrate is generated through reaction, so that the aim of denitration is fulfilled; the gas corona discharge is to make molecules such as H in the flue gas by high-energy electrons generated in the corona discharge process2O、O2Etc. are activated, cleaved or ionized, thereby generating strongly oxidizing radicals O, OH, H2O2And the like, and further performing plasma catalytic oxidation on the NO to generate NO2Or the corresponding acid.
In summary, the present disclosure provides a cooling device at the inlet of a gas turbineThe exhaust port is provided with the plasma denitration device, so that NO can be effectively reducedXAnd (4) discharging.

Claims (4)

1. Can reduce NOXAn exhaust gas turbine engine comprising: the system comprises a gas compressor, a turbine, a generator, a cooling device and a plasma denitration device; wherein the content of the first and second substances,
the compressor, the turbine and the generator are arranged on the same main shaft;
the cooling device is arranged in front of the air compressor and used for cooling and refrigerating air to be fed into the air compressor; the plasma denitration device is arranged on the turbine and used for removing NO contained in the flue gas by plasma generated by high-voltage dischargeX
The refrigerating capacity of the cooling device is matched with the air inlet amount of the air compressor by 1: 1.
2. The gas turbine of claim 1, wherein one end of the generator is provided with a high voltage backup transformer for supplying power to the cooling device and the plasma denitration device; the high-voltage standby transformer is respectively connected with the cooling device and the plasma denitration device through a first switch S1 and a second open pipe S2.
3. Reducing NO during low power operation of gas turbineXA method of venting comprising the steps of:
s100: cooling air to be fed into the compressor;
s200: plasma treatment of NO contained in flue gasXThe molecules are oxidized and degraded.
4. The method of claim 3, wherein the NO is plasma-pairedXThe molecules are oxidized and degraded in any mode as follows: electron beam irradiation and gas corona discharge.
CN201911330048.8A 2018-12-20 2019-12-20 Reducing NO during low power operation of gas turbinexMethod of discharging Pending CN110878715A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201811590570 2018-12-20
CN2018115905705 2018-12-20

Publications (1)

Publication Number Publication Date
CN110878715A true CN110878715A (en) 2020-03-13

Family

ID=69731793

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201911330048.8A Pending CN110878715A (en) 2018-12-20 2019-12-20 Reducing NO during low power operation of gas turbinexMethod of discharging

Country Status (1)

Country Link
CN (1) CN110878715A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112594031A (en) * 2020-12-08 2021-04-02 上研动力科技江苏有限公司 Diesel engine with flue gas treatment and reutilization device

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0051487A1 (en) * 1980-11-04 1982-05-12 Mitsubishi Gas Chemical Company, Inc. Heat exchanging system for a heat engine using compressed gaseous fuel as fuel
CN101517213A (en) * 2006-09-27 2009-08-26 三菱重工业株式会社 Gas turbine
CN107789984A (en) * 2017-10-30 2018-03-13 清华大学 The denitrating system and method for a kind of gas turbine

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0051487A1 (en) * 1980-11-04 1982-05-12 Mitsubishi Gas Chemical Company, Inc. Heat exchanging system for a heat engine using compressed gaseous fuel as fuel
CN101517213A (en) * 2006-09-27 2009-08-26 三菱重工业株式会社 Gas turbine
CN107789984A (en) * 2017-10-30 2018-03-13 清华大学 The denitrating system and method for a kind of gas turbine

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
毕玉森: "低氮氧化物燃烧技术的发展状况", 《热力发电》 *
美国米氏工业首席执行官THOMAS R.MEE: "通过喷雾进气冷却减少燃气轮机NOx的排放", 《HTTPS://WWW.DOCIN.COM/TOUCH_NEW/PREVIEW_NEW.DO?ID=445453319》 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112594031A (en) * 2020-12-08 2021-04-02 上研动力科技江苏有限公司 Diesel engine with flue gas treatment and reutilization device
CN112594031B (en) * 2020-12-08 2024-05-28 上研动力科技江苏有限公司 Diesel engine with flue gas treatment and secondary utilization device

Similar Documents

Publication Publication Date Title
US8495858B2 (en) Method of operating a gas turbine power plant with auxiliary power to reduce emissions
CN113074046B (en) Jet-type ammonia engine based on ignition and combustion supporting of multiple plasma devices
CN113363545B (en) Engine and solid oxide fuel cell combined power system
CN113048469A (en) Ammonia boiler for real-time cracking of ammonia fuel by using plasma based on energy storage of molten salt
US9806358B2 (en) Power generation system, and methods for starting and operating fuel cell in power generation system
KR20140001633A (en) Urea hydrolysis apparatus using fuel cell and selective catalytic reuction system with the same
CN110878715A (en) Reducing NO during low power operation of gas turbinexMethod of discharging
CN114678573A (en) Fuel cell system with energy recovery function and control method
CN114352412B (en) Power generation system based on ammonia decomposition hydrogen production and dynamic adjustment method
US20040020447A1 (en) Method and apparatus for advancing air into a fuel reformer by use of an engine vacuum
CN117747887A (en) Hydrogen/ammonia fuel energy system coupling fuel cell and gas turbine
CN117810494A (en) Ammonia fuel cell system and power generation method
CN212337386U (en) Deep peak regulation gas turbine blade cooling and fatigue test system
Liu et al. NO x removal by non-thermal plasma reduction: experimental and theoretical investigations
CN107789984B (en) A kind of denitrating system and method for gas turbine
CN216811894U (en) Low-concentration landfill gas power generation gas stable supply system
US20040020191A1 (en) Method and apparatus for advancing air into a fuel reformer by use of a turbocharger
CN212337493U (en) Environmental protection nature engine control system
WO2024119391A1 (en) Renewable energy utilization system based on nitrogen-free combustion and carbon dioxide circulation
CN104075353A (en) Portable microwave oven taking fuel cell as power supply
CN202740992U (en) Denitration device for waste gas generated by combustion system
CN117832560B (en) Fuel cell system capable of comprehensively improving utilization rate of tail rows of electric pile
CN219922596U (en) Exhaust-heat boiler denitration dilution air supply device
RU2444637C2 (en) Energy generation method
CN117599607A (en) Novel energy-efficient EOG processing system

Legal Events

Date Code Title Description
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination