CN110872544A - Anion effervescent tablet detergent for automobile windshield wiper and preparation method thereof - Google Patents

Anion effervescent tablet detergent for automobile windshield wiper and preparation method thereof Download PDF

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Publication number
CN110872544A
CN110872544A CN201810999002.4A CN201810999002A CN110872544A CN 110872544 A CN110872544 A CN 110872544A CN 201810999002 A CN201810999002 A CN 201810999002A CN 110872544 A CN110872544 A CN 110872544A
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parts
effervescent tablet
automobile windshield
anion
negative ion
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金建麟
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/662Carbohydrates or derivatives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09GPOLISHING COMPOSITIONS; SKI WAXES
    • C09G1/00Polishing compositions
    • C09G1/02Polishing compositions containing abrasives or grinding agents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047Detergents in the form of bars or tablets
    • C11D17/0065Solid detergents containing builders
    • C11D17/0073Tablets
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/10Carbonates ; Bicarbonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/12Water-insoluble compounds
    • C11D3/124Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246Silicates, e.g. diatomaceous earth
    • C11D3/1253Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2086Hydroxy carboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/22Carbohydrates or derivatives thereof
    • C11D3/222Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10Objects to be cleaned
    • C11D2111/14Hard surfaces
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10Objects to be cleaned
    • C11D2111/14Hard surfaces
    • C11D2111/18Glass; Plastics

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Inorganic Chemistry (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention belongs to the technical field of green low-carbon environment-friendly detergents, and particularly relates to an anion effervescent tablet detergent for an automobile windshield wiper and a preparation method thereof, wherein the anion effervescent tablet detergent for the automobile windshield wiper comprises the following components: a negative ion high active energy material; a silane coupling agent; a binder; a lubricant; a natural nonionic surfactant; a highly effective stain suspending agent; a disintegrant; the preparation method of the negative ion effervescent tablet detergent for the automobile windshield wipers comprises the following steps: s1: mixing the raw materials; s2: the die stamping pressing is carried out, the rapid reaction can be carried out in the soaking water, a large amount of hydroxyl anions are generated, far infrared rays are emitted, bonds of large molecular group water are disassembled, high-concentration small molecular group active water is generated, the small molecular group active water and tea saponin molecules generate powerful functions, dust and various stains attached to the automobile windshield and the automobile surface are removed, and the multifunctional cleaning device has the advantages of being green, low in carbon and multifunctional.

Description

Anion effervescent tablet detergent for automobile windshield wiper and preparation method thereof
Technical Field
The invention relates to the technical field of green low-carbon environment-friendly cleaning agents, and particularly relates to an anion effervescent tablet cleaning agent for an automobile windshield wiper and a preparation method thereof.
Background
Automobiles are important vehicles in modern civilized society. It is common to carry goods and boarding vehicles (buses and cars). To make it possible toThe invention discloses a cleaning agent for cleaning the surface of an automobile windshield and an automobile body, which can be used for maintaining the brightness of the paint on the surface of the automobile and removing various dust, oil and insect body stains attached to the automobile. However, the common car washing detergent and glass detergent comprise various glass water formulations, such as ethylene glycol, and are mostly chemical synthetic products. Functional material C of wiper essence effervescent tablet sold in market12-C14Alcohols are also chemical synthesis products. It has poor cleaning effect, single function and environmental pollution. Therefore, the negative ion effervescent tablet cleanser for the automobile windshield wiper and the preparation method thereof are provided.
Disclosure of Invention
The invention aims to provide an anion effervescent tablet cleaning agent for automobile windshield wipers and a preparation method thereof, and aims to solve the problems in the background technology.
In order to achieve the purpose, the invention provides the following technical scheme: the negative ion effervescent tablet cleanser for the automobile windshield wipers comprises the following components:
a negative ion high active energy material; silane coupling agent: 50-100 parts; adhesive: 0-150 parts; lubricant: 100-120 parts; natural nonionic surfactant: 100-150 parts; high-efficiency stain suspending agent: 30-50 parts; disintegrating agent: 90-110 parts; emulsifier PEG: 0-15 parts and aqueous wax: 0-15 parts;
the negative ion high-activity energy material comprises high-purity ancient sea sedimentary rock: 500-550 parts; and (3) carrying out lava: 150-200 parts; ultra-fining Qicai stone: 100-150 parts of natural nonionic surfactant: 100-150 parts.
Preferably, the high-purity palea sedimentary rock and the igneous rock are both nano-micron powder.
Preferably, the natural nonionic surfactant is tea saponin solid powder.
Preferably, the high-efficiency stain suspending agent is sodium carboxymethyl cellulose.
Preferably, the disintegrant comprises citric acid and sodium bicarbonate.
A preparation method of an anion effervescent tablet cleanser for automobile wipers comprises the following steps:
s1: mixing raw materials: mixing the negative ion high-activity energy materials, fully stirring the mixture by using stirring equipment to ensure that different powder materials of the negative ion high-activity energy materials are uniformly distributed, then adding a silane coupling agent, fully stirring the mixture, fully adsorbing and doping the mixture, uniformly distributing the mixture, then sequentially adding a natural non-ionic surfactant, a high-efficiency stain suspending agent, a disintegrating agent, an adhesive, a lubricant, an emulsifier and water-based wax, and uniformly stirring the mixture;
s2: die pressing: the effervescent tablet cleanser is prepared by tabletting by GzPL26C under normal temperature and pressure and pressing by a punch die with the diameter of 25 MM.
Preferably, the weight of the effervescent tablet in the step S2 is 40.0 +/-0.1 g.
Compared with the prior art, the invention has the beneficial effects that: the negative ion effervescent tablet cleaning agent for the automobile windshield wiper and the preparation method thereof provided by the invention have the advantages that the negative ion effervescent tablet cleaning agent can react rapidly in soaking water to generate a large amount of hydroxyl negative ions and emit far infrared rays, bonds of large molecular group water are disassembled to generate high-concentration small molecular group active water, and the small molecular group active water and tea saponin molecules generate powerful functions to remove dust and various stains attached to the automobile windshield and the outer surface of the automobile, so that the windshield can change clean and transparent after being wiped by the windshield wiper, the automobile outer surface paint recovers luster, the negative ion effervescent tablet cleaning agent has the advantages of green low carbon and multifunctional cleaning, not only has a cleaning function on the windshield, but also can be used as a dust removal cleaning agent for the outer surface of the whole automobile, and can be used as a cleaning agent for various furniture.
Drawings
FIG. 1 is a flow chart of the preparation method of the present invention.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The invention provides an anion effervescent tablet cleanser for an automobile windshield wiper, which comprises the following components:
a negative ion high active energy material; silane coupling agent: 50-100 parts; adhesive: 0-150 parts; lubricant: 100-120 parts; natural nonionic surfactant: 100-150 parts; high-efficiency stain suspending agent: 30-50 parts; disintegrating agent: 90-110 parts; emulsifier PEG: 0-15 parts and aqueous wax: 0-15 parts;
the negative ion high-activity energy material comprises high-purity ancient sea sedimentary rock: 500-550 parts; and (3) carrying out lava: 150-200 parts; ultra-fining Qicai stone: 100-150 parts of natural nonionic surfactant: 100-150 parts.
The high-purity palea sedimentary rock and the igneous rock are both nano-micron powder, the natural non-ionic surfactant is tea saponin solid powder, the high-efficiency stain suspending agent is sodium hydroxymethyl cellulose, the disintegrating agent comprises citric acid and sodium bicarbonate, the water-based wax is carnauba wax, and the silane coupling agent is bis- (r-triethoxysilylpropyl) tetrasulfide.
The invention relates to a negative ion high-activity energy material: the anion high-activity energy material is formed by nano-micron powder of ancient sea sedimentary rock (diatomite), igneous rock (Baojiang opal shale), qicai stone (tourmaline) and the like under the participation of a silane coupling agent. The ancient sea sedimentary rock (diatomite) is a biogenic siliceous sedimentary rock, releases natural negative oxygen ions, has the characteristics of light weight, large pores, strong adsorption performance, certain chemical stability and the like, contains amorphous silicon dioxide as a chemical component, has Si-0H groups and Si-O groups on the surface, and has the characteristics of hydrophilicity and lipophilicity. Can be subjected to silane hydrolysis reaction with a silane coupling agent, firstly-OCH2CH3The radicals hydrolyze to form silanol and then react with hydroxyl groups on the surface of the diatomaceous earth particles to form hydrogen bonds and condense to-Si-0-M co-bonds (M denotes the surface of the diatomaceous earth particles). Simultaneously, silanol of each molecule of silane is mutually associated and oligomerized to form a film with a net structure, and the film is covered on powder particlesAnd surface organization of the inorganic powder. Tests show that the silane coupling agent is preferably 1.2% by weight. The igneous rock (Yangjiang opal tribute rock) is a naturally hardened silica gel containing 5-10% of water and amorphous silica. The chemical formula is Si02.nH2O, the hardness is 5.5-6.5, and the nano-scale porous carbon material has unique strong adsorption effect of nano-scale micropores and also has excellent traditional performance of releasing natural negative oxygen ions. Thirdly, the qicai stone (tourmaline) has piezoelectricity and pyroelectricity, and chemical components: b is2O3、Si02、Fe304、Al203、Li20、Mn02Na0, MgO, etc. under the condition of temperature and pressure change, the tourmaline crystal spontaneously generates potential difference, and the positive pole and the negative pole can make H in water2O molecules are ionized to generate hydrated hydroxyl anions H3O2-(H2O) and [0H- (H)2O)n](ii) a The negative ion high-activity energy material can also emit far infrared rays, and association bonds among macromolecular water clusters are broken up to generate small-molecular-cluster activated water.
Specifically, the invention adopts the effervescent tablet technology, and the natural non-ionic surfactant, namely tea saponin, is added besides the negative ion high-activity energy material, so that the effervescent tablet has the functions of a suspending agent, a washing function and an adhesion function.
Example 1
In this embodiment: the negative ion effervescent tablet cleanser for the automobile windshield wiper comprises the following components in parts by weight: 650 parts of negative ion high-activity energy material, 150 parts of natural non-ionic surfactant-tea saponin solid powder, 50 parts of adhesive, 30 parts of high-efficiency stain suspending agent-sodium carboxymethylcellulose, 100 parts of lubricant and 90 parts of disintegrating agent (50 parts of citric acid and 40 parts of sodium bicarbonate);
650 parts of negative ion high-activity energy material consists of 500 parts of high-purity palea sedimentary rock (also called kieselguhr) micro-nano powder and 150 parts of igneous rock (Yangjiang opal shale) micro-nano powder.
The binder L-HPC, the lubricant PEG 400.
This embodiment 1, mainly used car when the highway drive or when because of the haze weather, auttombilism room windshield suffers the haze dust, when all kinds of polypide cadavers pollute, and uses this section anion effervescent tablet sanitizer. The anion effervescent tablet cleanser is used by immersing the effervescent tablets into a water tank according to the characteristics until the effervescent tablets are fully disintegrated and subjected to hydrolysis reaction.
Example 2
This embodiment: the negative ion effervescent tablet cleanser for the automobile windshield wiper comprises the following components in parts by weight: 700 parts of negative ion high-activity energy material, 100 parts of silane coupling agent, 100 parts of natural non-ionic surfactant-tea saponin solid powder, 30 parts of efficient stain suspending agent, 15 parts of emulsifier PEG-100 stearate, 15 parts of carnauba wax, 100 parts of disintegrating agent (5O parts of citric acid and 50 parts of sodium bicarbonate), 100 parts of lubricant and 50 parts of binder.
The negative ion high-activity energy material comprises the following components in parts by weight: 40O parts of palea sedimentary rock (pure diatomite), 200 parts of igneous rock (Baojiang opal shale) nano powder and 100 parts of nano Qicai stone (tourmaline) powder.
The embodiment specifically provides an anion effervescent tablet cleaning agent for automobile windshield wipers, which is mainly used for driving automobiles on roads, exposing various parts on automobile windshields and surfaces, and using the effervescent tablet cleaning agent when severe dust, oil stains and insect stains are adhered to the automobile windshields and the surfaces. According to the characteristics of the product, the product is firstly immersed in water in a water tank to be fully hydrolyzed to generate anion water for use.
Example 3
In this embodiment: the negative ion effervescent tablet cleanser for the automobile windshield wiper comprises the following components in parts by weight: 600 parts of negative ion high-activity energy material, 80 parts of silane coupling agent, 130 parts of natural non-ionic surfactant-tea saponin, 100 parts of disintegrating agent (wherein 50 parts of citric acid and 50 parts of sodium bicarbonate), 15 parts of emulsifier PEG-100 stearate and 15 parts of carnauba wax;
the negative ion high-activity energy material: the material comprises the following components, by weight, 500 parts of high-purity ancient sea sedimentary rock (also called kieselguhr) micro-nano powder and 150 parts of igneous rock (also called Yangjiang opal shale) micro-nano powder;
the embodiment is mainly used after the automobile is driven on the road or used for beautifying the appearance of the whole automobile at ordinary times, and can also be used as a wiper cleaning agent for windshields; it can also be used as glass cleaning agent in rooms, classrooms, public places such as theaters, movie theaters, sanatoriums, etc.
Referring to fig. 1, the present invention further provides a preparation method of the negative ion effervescent tablet cleanser for the automobile windshield wiper, which comprises the following steps:
s1: mixing raw materials: mixing the negative ion high-activity energy materials, fully stirring the mixture by using stirring equipment to ensure that different powder materials of the negative ion high-activity energy materials are uniformly distributed, then adding a silane coupling agent, fully stirring the mixture, fully adsorbing and doping the mixture, uniformly distributing the mixture, then sequentially adding a natural non-ionic surfactant, a high-efficiency stain suspending agent, a disintegrating agent, an adhesive, a lubricant, an emulsifier and water-based wax, and uniformly stirring the mixture;
s2: die pressing: tabletting by adopting GzPL26C under normal temperature and pressure, and pressing into effervescent tablet cleanser by using a punch die with the diameter of 25MM, wherein the weight of the effervescent tablet is 40.0 +/-0.1 g.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.

Claims (7)

1. The negative ion effervescent tablet cleaning agent for the automobile windshield wiper is characterized in that: the anion effervescent tablet cleaning agent for the automobile windshield wiper comprises the following components:
a negative ion high active energy material; silane coupling agent: 50-100 parts; adhesive: 0-150 parts; lubricant: 100-120 parts; natural nonionic surfactant: 100-150 parts; high-efficiency stain suspending agent: 30-50 parts; disintegrating agent: 90-110 parts; emulsifier PEG: 0-15 parts and aqueous wax: 0-15 parts;
the negative ion high-activity energy material comprises high-purity ancient sea sedimentary rock: 500-550 parts; and (3) carrying out lava: 150-200 parts; ultra-fining Qicai stone: 100-150 parts of natural nonionic surfactant: 100-150 parts.
2. The anionic effervescent tablet cleanser for automobile windshield wipers as claimed in claim 1, wherein: the high-purity palea sedimentary rock and the igneous rock are both nano-micron powder.
3. The anionic effervescent tablet cleanser for automobile windshield wipers as claimed in claim 1, wherein: the natural non-ionic surfactant is tea saponin solid powder.
4. The anionic effervescent tablet cleanser for automobile windshield wipers as claimed in claim 1, wherein: the efficient stain suspending agent is sodium carboxymethyl cellulose.
5. The anionic effervescent tablet cleanser for automobile windshield wipers as claimed in claim 1, wherein: the disintegrant comprises citric acid and sodium bicarbonate.
6. A preparation method of an anion effervescent tablet cleanser for automobile windshield wipers is characterized by comprising the following steps: the preparation method of the anion effervescent tablet detergent for the automobile windshield wiper comprises the following steps:
s1: mixing raw materials: mixing the negative ion high-activity energy materials, fully stirring the mixture by using stirring equipment to ensure that different powder materials of the negative ion high-activity energy materials are uniformly distributed, then adding a silane coupling agent, fully stirring the mixture, fully adsorbing and doping the mixture, uniformly distributing the mixture, then sequentially adding a natural non-ionic surfactant, a high-efficiency stain suspending agent, a disintegrating agent, an adhesive, a lubricant, an emulsifier and water-based wax, and uniformly stirring the mixture;
s2: die pressing: the effervescent tablet cleanser is prepared by tabletting by GzPL26C under normal temperature and pressure and pressing by a punch die with the diameter of 25 MM.
7. The method for preparing the anion effervescent tablet cleanser for the automobile windshield wipers as claimed in claim 6, wherein the anion effervescent tablet cleanser is prepared from the following raw materials in parts by weight: the weight of the effervescent tablet in the step S2 is 40.0 +/-0.1 g.
CN201810999002.4A 2018-08-30 2018-08-30 Anion effervescent tablet detergent for automobile windshield wiper and preparation method thereof Pending CN110872544A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114098569A (en) * 2021-12-01 2022-03-01 盐城市天马日用品有限公司 Nonwoven wiping cloth product capable of continuously releasing cleaning agent and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1319651A (en) * 2001-02-08 2001-10-31 勇志华 Environment protection ceramic washing ball and productive technology thereof
CN1727552A (en) * 2004-07-27 2006-02-01 张福海 Combined functional type environmental protection Nano washing balls made from ceramics
CN102417793A (en) * 2011-09-01 2012-04-18 丁一 Electromagnetic wave shielding nanometer fragrant brightener capable of releasing trace element negative ions
CN103525569A (en) * 2013-10-24 2014-01-22 上虞力姿生物科技有限公司 Effervescent tablet for cleaning automobile glass
CN106497701A (en) * 2016-08-16 2017-03-15 南通蛇类治疗研究所 Anhydrous dry-cleaning automobile sterilization brightener
CN107904033A (en) * 2017-11-15 2018-04-13 南通蛇类治疗研究所 Discharge element Anion FIR Functional Pigment air conditioner sterilizing cleaning agent

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1319651A (en) * 2001-02-08 2001-10-31 勇志华 Environment protection ceramic washing ball and productive technology thereof
CN1727552A (en) * 2004-07-27 2006-02-01 张福海 Combined functional type environmental protection Nano washing balls made from ceramics
CN102417793A (en) * 2011-09-01 2012-04-18 丁一 Electromagnetic wave shielding nanometer fragrant brightener capable of releasing trace element negative ions
CN103525569A (en) * 2013-10-24 2014-01-22 上虞力姿生物科技有限公司 Effervescent tablet for cleaning automobile glass
CN106497701A (en) * 2016-08-16 2017-03-15 南通蛇类治疗研究所 Anhydrous dry-cleaning automobile sterilization brightener
CN107904033A (en) * 2017-11-15 2018-04-13 南通蛇类治疗研究所 Discharge element Anion FIR Functional Pigment air conditioner sterilizing cleaning agent

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114098569A (en) * 2021-12-01 2022-03-01 盐城市天马日用品有限公司 Nonwoven wiping cloth product capable of continuously releasing cleaning agent and preparation method thereof

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