CN110867465A - Flexible AMOLED display screen, crack repairing method thereof and flexible display device - Google Patents

Flexible AMOLED display screen, crack repairing method thereof and flexible display device Download PDF

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Publication number
CN110867465A
CN110867465A CN201810988509.XA CN201810988509A CN110867465A CN 110867465 A CN110867465 A CN 110867465A CN 201810988509 A CN201810988509 A CN 201810988509A CN 110867465 A CN110867465 A CN 110867465A
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layer
display screen
flexible
repairing
amoled display
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CN201810988509.XA
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Chinese (zh)
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于东亮
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EverDisplay Optronics Shanghai Co Ltd
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EverDisplay Optronics Shanghai Co Ltd
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Priority to CN201810988509.XA priority Critical patent/CN110867465A/en
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K59/00Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
    • H10K59/80Constructional details
    • H10K59/88Dummy elements, i.e. elements having non-functional features
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • C08L63/10Epoxy resins modified by unsaturated compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04Polyurethanes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L23/00Details of semiconductor or other solid state devices
    • H01L23/562Protection against mechanical damage
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K71/00Manufacture or treatment specially adapted for the organic devices covered by this subclass

Abstract

The invention provides a flexible AMOLED display screen, a crack repairing method thereof and a flexible display device, wherein the flexible AMOLED display screen sequentially comprises a flexible driving back plate layer, an organic light emitting layer, a touch layer, a polarizing plate layer and a self-repairing layer from bottom to top.

Description

Flexible AMOLED display screen, crack repairing method thereof and flexible display device
Technical Field
The invention belongs to the technical field of flexible display devices, and relates to a flexible AMOLED display screen, a crack repairing method thereof and a flexible display device.
Background
At present, the bottleneck of the flexible/foldable display product is not only the structure of the device, but also the flexible protective cover plate is one of the important factors restricting the development of the flexible/foldable display product. The flexible protective cover plate must have the characteristics of repeated bending, transparency, ultra-thinness and enough hardness. It is not easy to find a material that has these properties at the same time.
In order to meet the requirements of flexible screens for materials, Hard Coating (Hard Coating) materials have been proposed, and manufacturers have made Hard coatings on organic polymer materials to increase the surface hardness of the organic polymer materials. Hard coatings are used in flexible displays, and are required to meet both the high light transmission and surface hardness of glass and the flexibility and abrasion resistance required of flexible materials.
CN 104269499A discloses an AMOLED structure and a method for manufacturing the same, the AMOLED structure includes an AMOLED display module, a polarizer and a cover plate glass, the polarizer is bonded between the AMOELD display module and the cover plate glass, and the polarizer is provided with a printed pattern layer. The printing pattern layer is arranged on the polaroid, so that a delicate appearance display effect is brought to the AMOLED structure, the problems that the cover plate glass cannot be printed with patterns due to the adoption of toughened glass or a special-shaped surface and the printing yield is low are solved, and the problems of flexibility and wear resistance of the AMOLED structure are not improved.
CN 107742634 a discloses an AMOLED display screen, which includes a display panel and a touch panel, the display panel includes a glass substrate, a gate layer, a first protective layer, a data line layer, a second protective layer and a pixel electrode layer, which are bonded in sequence, an indium tin oxide ITO layer is further disposed between the glass substrate and the first protective layer, the ITO layer is connected with the gate layer, and an overlapping portion of the ITO layer and the pixel electrode layer forms a storage capacitor; the touch panel comprises two layers of transparent conductive films, an optical transparent adhesive layer sandwiched between the two layers of transparent conductive films, and a protective layer positioned on the outermost layer. Although a protective layer is provided in the structure, it does not have a preventive effect or a repairing effect on the occurrence of cracks or scratches.
CN 105590573 a discloses a repair structure and a repair method for line defects of an AMOLED display panel, in which conductive films in repair lines are correspondingly stacked and covered above test TFTs in a detection line of the AMOLED display panel and insulated from the test TFTs, and repair wires in the repair lines are crossed with all signal fanout lines and corresponding test lines in the detection line of the AMOLED display panel in an insulated manner, so that the repair lines are directly grafted on the detection line of the AMOLED display panel, and the repair lines with repair function can be introduced by using the existing layout of the detection line of the AMOLED display panel, but only line repair can be performed, and repair cannot be performed when cracks occur in the AMOLED display panel.
Therefore, in the field, it is expected that an AMOLED display screen with a self-repairing function can be developed, so that the crack can be repaired when the crack is generated, and the service life of the device is prolonged.
Disclosure of Invention
In view of the defects of the prior art, the present invention aims to provide a flexible AMOLED display screen, a crack repairing method thereof, and a flexible display device.
In order to achieve the purpose, the invention adopts the following technical scheme:
on one hand, the invention provides a flexible AMOLED display screen which sequentially comprises a flexible driving back plate layer, an organic light emitting layer, a touch layer, a polarizing plate layer and a self-repairing layer from bottom to top.
The self-repairing layer arranged on the polarizing plate layer of the flexible AMOLED display screen can play a self-repairing function when scratches or cracks are generated on the display screen, so that the original strength of the protective film layer is recovered to a great extent, and the service life of the display screen is prolonged.
Preferably, the raw materials for preparing the self-repairing layer comprise the following components in percentage by mass: 80-90% of matrix material, 10-20% of repairing agent microcapsule and/or repairing agent microfiber and 0.1-2% of catalyst.
In the invention, the matrix material is epoxy vinyl ester and/or polyurethane.
In the invention, the mass percentage of the base material in the self-repairing layer can be 80%, 81%, 81.5%, 82%, 82.5%, 83%, 84%, 85%, 86%, 87%, 88%, 89% or 90%.
Preferably, the repair agent microcapsule is obtained by coating the repair agent with a coating material.
Preferably, the repair agent is any one of or a combination of at least two of an epoxy prepolymer, Polydimethylsiloxane (PDMS), or Polydiethylsiloxane (PDES).
Preferably, the coating material is epoxy vinyl ester and/or polyurethane.
According to the invention, the self-repairing layer is obtained through the components, when the display screen cracks, the repairing agent in the repairing agent microcapsule or repairing agent microfiber is released, the repairing agent is in contact with the catalyst in the self-repairing layer, and under the initiation of an external condition, a polymerization reaction is carried out, the repairing agent is polymerized to form a high polymer, and the high polymer is connected with the base material, so that the crack is filled, and the self-repairing purpose is achieved.
In the present invention, the content of the repair agent microcapsule or repair agent microfiber in the self-repair layer may be 10%, 11%, 12%, 13%, 14%, 15%, 16%, 17%, 18%, 19%, or 20% by mass.
Preferably, the catalyst is an organic peroxide initiator or an azo-type initiator.
In the present invention, the mass percentage content of the catalyst in the self-repairing layer may be 0.1%, 0.3%, 0.5%, 0.8%, 1%, 1.2%, 1.4%, 1.6%, 1.8%, or 2%.
Preferably, the thickness of the self-healing layer is 0.1-500 μm, such as 0.1 μm, 0.5 μm, 0.8 μm, 1 μm, 5 μm, 8 μm, 10 μm, 20 μm, 50 μm, 80 μm, 100 μm, 130 μm, 150 μm, 180 μm, 200 μm, 230 μm, 250 μm, 300 μm, 350 μm, 400 μm, 450 μm or 500 μm.
Preferably, the surface hardness of the self-repairing layer is 4H or more, for example, 4H, 4.5H, 5H, 5.5H, 6H, 6.5H, 7H, 7.5H, 8H, and the like.
Preferably, the flexible driving backplane layer comprises a polyimide film layer and a Thin Film Transistor (TFT) disposed thereon.
Preferably, a protective layer is further included between the polarizer plate layer and the self-repairing layer.
Preferably, the protective layer is a polyester film layer, a polyimide film layer or a polyacrylate film layer.
Preferably, the protective layer is a polyethylene terephthalate (PET) film layer, a polyethylene naphthalate (PEN) film layer, a Polyimide (PI) film layer, or a Polymethylmethacrylate (PMMA) film layer. In the invention, the protective layer plays a role in supporting the self-repairing layer and protecting each functional layer of the AMOLED
Preferably, the thickness of the protective layer is 5-100 μm, such as 5 μm, 10 μm, 20 μm, 30 μm, 40 μm, 50 μm, 60 μm, 70 μm, 80 μm, 90 μm or 100 μm.
In the flexible AMOLED display screen, the flexible driving back plate layer, the organic light emitting layer, the touch layer and the polarizing plate layer belong to the AMOLED screen part. In the preparation process of the flexible AMOLED display screen, the AMOLED screen can be prepared by applying the means in the prior art, the protective layer can be arranged on the AMOLED screen in an attaching mode, and the self-repairing layer can be prepared in a coating mode, an ink-jet printing mode and the like.
In another aspect, the present invention provides a method for repairing cracks of a flexible AMOLED display screen, the method comprising: when the flexible AMOLED display screen is cracked, the flexible AMOLED display screen is self-repaired under the initiation of an external condition.
Preferably, the external condition is heating, ultraviolet irradiation or X-ray irradiation. For example, the heating temperature may be 70 to 80 ℃, such as 70 ℃, 71 ℃, 72 ℃, 73 ℃, 74 ℃, 75 ℃, 76 ℃, 77 ℃, 78 ℃, 79 ℃ or 80 ℃.
According to the invention, when the flexible AMOLED display screen generates cracks, a series of chemical reactions occur under the initiation of external conditions, so that two interfaces of the cracks are healed again, and self-repairing is achieved.
In the present invention, in addition to the polymerization reaction of the repairing agent in contact with the catalyst at the time of crack generation, radicals may be generated in the repairing agent under irradiation of ultraviolet rays, for example, to initiate radical polymerization of the repairing agent to form a polymer, thereby achieving the purpose of repairing cracks.
In another aspect, the invention provides a flexible display device comprising a flexible AMOLED display screen as described above.
Compared with the prior art, the invention has the following beneficial effects:
the flexible AMOLED display screen has good flexibility and self-repairing capability, can self-repair internal or external cracks generated in the using process of the flexible AMOLED display screen, prolongs the service life of the display screen and a display device, and has wide application prospect.
Drawings
Fig. 1 is a schematic structural diagram of an exemplary flexible AMOLED display screen of the present invention, in which 1 is a flexible driving backplane layer, 2 is an organic light emitting layer, 3 is a touch layer, 4 is a polarizer layer, and 5 is a self-repairing layer.
Fig. 2 is a schematic structural diagram of another exemplary flexible AMOLED display screen of the present invention, in which 1 is a flexible driving backplane layer, 2 is an organic light emitting layer, 3 is a touch layer, 4 is a polarizer layer, 5 is a self-repairing layer, and 6 is a protective layer.
Fig. 3 is a schematic flow chart of an action process of the flexible AMOLED display screen in crack repair.
Detailed Description
The technical solution of the present invention is further explained by the following embodiments. It should be understood by those skilled in the art that the examples are only for the understanding of the present invention and should not be construed as the specific limitations of the present invention.
Example 1
In the present embodiment, a flexible AMOLED display screen is provided, as shown in fig. 1, which includes, from bottom to top, a flexible driving backplane layer (1), an organic light emitting layer (2), a touch layer (3), a polarizer layer (4), and a self-repairing layer (5).
The preparation raw materials of the self-repairing layer comprise the following components in percentage by mass: 80% of a matrix material, 18% of a repair agent microcapsule or repair agent microfiber, and 2% of a catalyst; the repairing agent microcapsule is obtained by coating a repairing agent by a coating material.
The repairing agent is epoxy resin prepolymer, the coating material is epoxy vinyl ester, the thickness of the self-repairing layer is 100 micrometers, and the surface hardness of the self-repairing layer is 4H.
Example 2
In the present embodiment, a flexible AMOLED display screen is provided, as shown in fig. 1, which includes, from bottom to top, a flexible driving backplane layer (1), an organic light emitting layer (2), a touch layer (3), a polarizer layer (4), and a self-repairing layer (5).
The preparation raw materials of the self-repairing layer comprise the following components in percentage by mass: 85% of a matrix material, 14.9% of a repair agent microcapsule or repair agent microfiber, and 0.1% of a catalyst; the repairing agent microcapsule is obtained by coating a repairing agent by a coating material.
The repairing agent is polydimethylsiloxane, the coating material is polyurethane, the thickness of the self-repairing layer is 300 mu m, and the surface hardness of the self-repairing layer is 5H.
Example 3
In the present embodiment, a flexible AMOLED display screen is provided, as shown in fig. 1, which includes, from bottom to top, a flexible driving backplane layer (1), an organic light emitting layer (2), a touch layer (3), a polarizer layer (4), and a self-repairing layer (5).
The preparation raw materials of the self-repairing layer comprise the following components in percentage by mass: 89% of a matrix material, 10% of a repair agent microcapsule or repair agent microfiber, and 1% of a catalyst; the repairing agent microcapsule is obtained by coating a repairing agent by a coating material.
The repairing agent is poly diethyl siloxane, the coating material is epoxy vinyl ester, the thickness of the self-repairing layer is 500 mu m, and the surface hardness of the self-repairing layer is 6H.
Example 4
In the present embodiment, a flexible AMOLED display screen is provided, as shown in fig. 1, which includes, from bottom to top, a flexible driving backplane layer (1), an organic light emitting layer (2), a touch layer (3), a polarizer layer (4), and a self-repairing layer (5).
The preparation raw materials of the self-repairing layer comprise the following components in percentage by mass: 80% of a matrix material, 19% of a repair agent microcapsule or repair agent microfiber, and 1% of a catalyst; the repairing agent microcapsule is obtained by coating a repairing agent by a coating material.
The repairing agent is poly diethyl siloxane, the coating material is polyurethane, the thickness of the self-repairing layer is 50 micrometers, and the surface hardness of the self-repairing layer is 4H.
Example 5
In this embodiment, a flexible AMOLED display screen is provided, as shown in fig. 2, which includes, from bottom to top, a flexible driving backplane layer (1), an organic light emitting layer (2), a touch layer (3), a polarizer layer (4), a protective layer (6), and a self-repairing layer (5).
The preparation raw materials of the self-repairing layer comprise the following components in percentage by mass: 89.5% of matrix material, 10% of repair agent microcapsules or repair agent microfibers and 0.5% of catalyst; the repairing agent microcapsule is obtained by coating a repairing agent by a coating material.
The repairing agent is a combination of polydimethylsiloxane and polydiethylsiloxane, the coating material is a combination of epoxy vinyl ester and polyurethane, the thickness of the self-repairing layer is 80 micrometers, the surface hardness of the self-repairing layer is 4H, and the protective layer is a polyethylene terephthalate layer.
Example 6
In this embodiment, a flexible AMOLED display screen is provided, as shown in fig. 2, which includes, from bottom to top, a flexible driving backplane layer (1), an organic light emitting layer (2), a touch layer (3), a polarizer layer (4), a protective layer (6), and a self-repairing layer (5).
The preparation raw materials of the self-repairing layer comprise the following components in percentage by mass: 88% of a matrix material, 10% of a repair agent microcapsule or repair agent microfiber, and 2% of a catalyst; the repairing agent microcapsule is obtained by coating a repairing agent by a coating material.
The repairing agent is poly diethyl siloxane, the coating material is epoxy vinyl ester, the thickness of the self-repairing layer is 100 micrometers, the surface hardness of the self-repairing layer is 4H, and the protective layer is a polyimide layer.
Example 7
In this embodiment, a flexible AMOLED display screen is provided, as shown in fig. 2, which includes, from bottom to top, a flexible driving backplane layer (1), an organic light emitting layer (2), a touch layer (3), a polarizer layer (4), a protective layer (6), and a self-repairing layer (5).
The preparation raw materials of the self-repairing layer comprise the following components in percentage by mass: 83% of a matrix material, 16% of a repair agent microcapsule or repair agent microfiber, and 1% of a catalyst; the repairing agent microcapsule is obtained by coating a repairing agent by a coating material.
The repairing agent is a combination of epoxy resin prepolymer and polydimethylsiloxane, the coating material is polyurethane, the thickness of the self-repairing layer is 300 mu m, the surface hardness of the self-repairing layer is 5H, and the protective layer is a polyimide layer.
Example 8
In this embodiment, a flexible AMOLED display screen is provided, as shown in fig. 2, which includes, from bottom to top, a flexible driving backplane layer (1), an organic light emitting layer (2), a touch layer (3), a polarizer layer (4), a protective layer (6), and a self-repairing layer (5).
The preparation raw materials of the self-repairing layer comprise the following components in percentage by mass: 80% of a matrix material, 18% of a repair agent microcapsule or repair agent microfiber, and 2% of a catalyst; the repairing agent microcapsule is obtained by coating a repairing agent by a coating material.
The repairing agent is epoxy resin prepolymer, the coating material is polyurethane, the thickness of the self-repairing layer is 400 microns, the surface hardness of the self-repairing layer is 6H, and the protective layer is a polymethyl methacrylate layer.
Example 9
The flexible AMOLED display screens prepared in examples 1 to 8, in which cracks are generated, can be self-repaired, the action flow of the flexible AMOLED display screen in the process of crack repair is shown in fig. 3, when cracks are generated outside/inside the material of the flexible AMOLED display screen, the repair agent (i.e. microcapsule or hollow fiber coated repair agent) coated inside the material leaks out, the repair agent fills the cracks, contacts with the catalyst, and under the initiation of external conditions (such as heating, ultraviolet irradiation, X-ray irradiation and the like), chemical reaction occurs, and the repair agent is cured and fills the cracks.
The flexible AMOLED display screen can be used for preparing a flexible display device, and the flexible display device has a self-repairing function, greatly prolongs the service life of the device, and has a wide application prospect.
The applicant states that the present invention is described by the above embodiments, but the present invention is not limited to the above embodiments, i.e. it does not mean that the present invention must be implemented by the above embodiments. It will be apparent to those skilled in the art that any modification of the present invention, equivalent substitutions of selected materials and additions of auxiliary components, selection of specific modes and the like, which are within the scope and disclosure of the present invention, are contemplated by the present invention.

Claims (10)

1. The flexible AMOLED display screen is characterized by sequentially comprising a flexible driving back plate layer, an organic light emitting layer, a touch layer, a polarizing plate layer and a self-repairing layer from bottom to top.
2. The flexible AMOLED display screen according to claim 1, wherein the self-repairing layer is prepared from the following raw materials in percentage by mass: 80-90% of matrix material, 10-20% of repairing agent microcapsule and/or repairing agent microfiber and 0.1-2% of catalyst.
3. The flexible AMOLED display screen of claim 1 or 2, wherein the matrix material is epoxy vinyl ester and/or polyurethane;
preferably, the repairing agent microcapsule is obtained by coating a repairing agent with a coating material;
preferably, the repair agent is any one of or a combination of at least two of epoxy resin prepolymer, polydimethylsiloxane or polydiethylsiloxane.
4. The flexible AMOLED display screen of any one of claims 1-3, wherein the cladding material is epoxy vinyl ester and/or polyurethane;
preferably, the catalyst is an organic peroxide initiator or an azo-type initiator.
5. The flexible AMOLED display screen of any one of claims 1-4, wherein the self-repair layer has a thickness of 0.1-500 μm;
preferably, the surface hardness of the self-repairing layer is 4H or more.
6. The flexible AMOLED display screen of any one of claims 1-5, wherein the flexible driving backplane layer comprises a polyimide film layer and thin film transistors disposed thereon.
7. The flexible AMOLED display screen of any one of claims 1-6, further comprising a protective layer between the polarizer plate layer and self-repair layer.
8. The flexible AMOLED display screen of any one of claims 1-7, wherein the protective layer is a polyester film layer, a polyimide film layer or a polyacrylate film layer;
preferably, the thickness of the protective layer is 5-100 μm.
9. The method for repairing cracks in the flexible AMOLED display screen according to any one of claims 1-8, wherein the method is as follows: when the flexible AMOLED display screen is cracked, the flexible AMOLED display screen is self-repaired under the initiation of an external condition;
preferably, the external condition is heating, ultraviolet irradiation or X-ray irradiation.
10. A flexible display device comprising the flexible AMOLED display screen of any one of claims 1-8.
CN201810988509.XA 2018-08-28 2018-08-28 Flexible AMOLED display screen, crack repairing method thereof and flexible display device Pending CN110867465A (en)

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