CN110857354A - Antistatic acrylic plate - Google Patents
Antistatic acrylic plate Download PDFInfo
- Publication number
- CN110857354A CN110857354A CN201810966681.5A CN201810966681A CN110857354A CN 110857354 A CN110857354 A CN 110857354A CN 201810966681 A CN201810966681 A CN 201810966681A CN 110857354 A CN110857354 A CN 110857354A
- Authority
- CN
- China
- Prior art keywords
- antistatic
- acrylic plate
- flame retardant
- parts
- aminoethyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
- C08L33/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F120/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F120/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F120/10—Esters
- C08F120/12—Esters of monohydric alcohols or phenols
- C08F120/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/2224—Magnesium hydroxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/017—Additives being an antistatic agent
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses an antistatic acrylic plate, which comprises methyl methacrylate, dibenzoyl peroxide, copper nitrate, silver nitrate, a defoaming agent, an antistatic agent and a flame retardant, wherein the antistatic agent is formed by mixing tri (2-aminoethyl) amine and didecyl dimethyl ammonium chloride, the flame retardant is a mixture of magnesium hydroxide and aluminum hydroxide, and the acrylic plate has certain flame retardant property under the synergistic action, and the antistatic agent is a mixture of tri (2-aminoethyl) amine and didecyl dimethyl ammonium chloride, so that the acrylic plate has good antistatic property, the adsorption to dirt such as dust is reduced, the surface cleanliness of the acrylic plate is ensured, meanwhile, the copper ions and the silver ions have certain antibacterial performance, and the acrylic plate is antistatic and antibacterial, so that the acrylic plate is safe and sanitary, has good application prospect, and is worthy of popularization.
Description
Technical Field
The invention relates to an antistatic acrylic plate, and belongs to the technical field of composite plates.
Background
Acrylic, also called PMMA or acrylic, is derived from English acrylic, is an important plastic high polymer material which is developed earlier, has better transparency, chemical stability and weather resistance, is easy to dye, process and beautiful in appearance, and is widely applied to the building industry. However, the conventional acrylic sheet has a limited antistatic function, easily attracts dust during use, and has poor dirt resistance, and thus further research is required.
Disclosure of Invention
In order to overcome the defects in the prior art, the invention provides the antistatic acrylic plate which has good antibacterial performance, excellent antistatic effect, flame retardant effect, no halogen flame retardant, no secondary pollution, good application prospect and popularization value.
In order to solve the technical problems, the invention adopts the technical scheme that:
the antistatic acrylic plate is characterized by comprising the following components in parts by weight: 85-105 parts of methyl methacrylate, 0.2-0.8 part of dibenzoyl peroxide, 0-2 parts of copper nitrate, 0-2 parts of silver nitrate, 0.1-0.5 part of defoaming agent and 1-3 parts of antistatic agent, wherein the antistatic agent is formed by mixing tri (2-aminoethyl) amine and didecyl dimethyl ammonium chloride, and the mass ratio of the tri (2-aminoethyl) amine to the didecyl dimethyl ammonium chloride is (1-3): (1-3).
The antistatic acrylic plate is characterized in that: the mass ratio of the tri (2-aminoethyl) amine to the didecyl dimethyl ammonium chloride is 2: 1.
the antistatic acrylic plate is characterized in that: and the flame retardant also comprises 0-4 parts of a flame retardant, wherein the flame retardant is one or a mixture of two of magnesium hydroxide and aluminum hydroxide.
The antistatic acrylic plate is characterized in that: the flame retardant is prepared by mixing magnesium hydroxide and aluminum hydroxide, wherein the mass ratio of the magnesium hydroxide to the aluminum hydroxide is (1-2): (1-2).
The antistatic acrylic plate is characterized in that: the mass ratio of the magnesium hydroxide to the aluminum hydroxide is 1: 1.
the antistatic acrylic plate is characterized in that: the defoaming agent is a dimethyl silicone oil defoaming agent.
Has the advantages that: the invention provides an antistatic acrylic plate, which comprises methyl methacrylate, dibenzoyl peroxide, copper nitrate, silver nitrate, a defoaming agent, an antistatic agent and a flame retardant, wherein the antistatic agent is formed by mixing tri (2-aminoethyl) amine and didecyl dimethyl ammonium chloride, the flame retardant is a mixture of magnesium hydroxide and aluminum hydroxide, the synergistic effect ensures that the acrylic plate has a certain flame retardant property, the antistatic agent is a mixture of tri (2-aminoethyl) amine and didecyl dimethyl ammonium chloride, the acrylic plate is ensured to have good antistatic property, the adsorption of dirt such as dust and the like is reduced, the surface cleanliness of the acrylic plate is ensured, and simultaneously, the copper ions and the silver ions have certain antibacterial property, and the antistatic property and the antibacterial property are added, so that the acrylic plate is safer and more sanitary. The antistatic acrylic plate has good antibacterial performance, excellent antistatic effect, flame retardant effect, no halogen flame retardant, no secondary pollution, good application prospect and popularization value.
Detailed Description
In order to make the technical means, the creation characteristics, the achievement purposes and the effects of the invention easy to understand, the invention is further described with the specific embodiments.
Example 1
An antistatic acrylic plate comprises the following components in parts by weight: 88 parts of methyl methacrylate, 0.5 part of dibenzoyl peroxide, 1 part of copper nitrate, 1 part of silver nitrate, 0.2 part of dimethyl silicone oil and 1 part of antistatic agent, wherein the antistatic agent is formed by mixing tris (2-aminoethyl) amine and didecyl dimethyl ammonium chloride, and the mass ratio of the tris (2-aminoethyl) amine to the didecyl dimethyl ammonium chloride is (2): 1.
example 2
An antistatic acrylic plate comprises the following components in parts by weight: 100 parts of methyl methacrylate, 0.6 part of dibenzoyl peroxide, 2 parts of copper nitrate, 2 parts of silver nitrate, 0.4 part of dimethyl silicone oil, 3 parts of an antistatic agent and 2 parts of a flame retardant, wherein the antistatic agent is formed by mixing tris (2-aminoethyl) amine and didecyl dimethyl ammonium chloride, and the mass ratio of the tris (2-aminoethyl) amine to the didecyl dimethyl ammonium chloride is 2: 1, mixing the flame retardant with magnesium hydroxide and aluminum hydroxide, wherein the mass ratio of the magnesium hydroxide to the aluminum hydroxide is 1: 1.
example 3
An antistatic acrylic plate comprises the following components in parts by weight: 102 parts of methyl methacrylate, 0.2 part of dibenzoyl peroxide, 1 part of copper nitrate, 2 parts of silver nitrate, 0.4 part of defoaming agent, 2 parts of antistatic agent and 4 parts of flame retardant, wherein the antistatic agent is formed by mixing tris (2-aminoethyl) amine and didecyl dimethyl ammonium chloride, and the mass ratio of the tris (2-aminoethyl) amine to the didecyl dimethyl ammonium chloride is (2): 1, mixing the flame retardant with magnesium hydroxide and aluminum hydroxide, wherein the mass ratio of the magnesium hydroxide to the aluminum hydroxide is 1: 1.
example 4
An antistatic acrylic plate comprises the following components in parts by weight: 90 parts of methyl methacrylate, 0.3 part of dibenzoyl peroxide, 2 parts of copper nitrate, 2 parts of silver nitrate, 0.1 part of defoaming agent, 3 parts of antistatic agent and 1 part of flame retardant, wherein the antistatic agent is formed by mixing tris (2-aminoethyl) amine and didecyl dimethyl ammonium chloride, and the mass ratio of the tris (2-aminoethyl) amine to the didecyl dimethyl ammonium chloride is 2: 1, mixing the flame retardant with magnesium hydroxide and aluminum hydroxide, wherein the mass ratio of the magnesium hydroxide to the aluminum hydroxide is 1: 1.
the antistatic acrylic plate comprises methyl methacrylate, dibenzoyl peroxide, copper nitrate, silver nitrate, a defoaming agent, an antistatic agent and a flame retardant, wherein the antistatic agent is formed by mixing tri (2-aminoethyl) amine and didecyl dimethyl ammonium chloride, the flame retardant is a mixture of magnesium hydroxide and aluminum hydroxide, the acrylic plate has certain flame retardant performance under the synergistic action, the antistatic agent is a mixture of tri (2-aminoethyl) amine and didecyl dimethyl ammonium chloride, the acrylic plate is ensured to have good antistatic performance, the adsorption to dirt such as dust and the like is reduced, the surface cleanliness of the acrylic plate is ensured, and meanwhile, the copper ions and the silver ions which are carried have certain antibacterial performance, and the antistatic and antibacterial effects are achieved, so that the acrylic plate is safer and more sanitary. The antistatic acrylic plate has good antibacterial performance, excellent antistatic effect, flame retardant effect, no halogen flame retardant, no secondary pollution, good application prospect and popularization value.
The above description is only of the preferred embodiments of the present invention, and it should be noted that: it will be apparent to those skilled in the art that various modifications and adaptations can be made without departing from the principles of the invention and these are intended to be within the scope of the invention.
Claims (6)
1. The antistatic acrylic plate is characterized by comprising the following components in parts by weight: 85-105 parts of methyl methacrylate, 0.2-0.8 part of dibenzoyl peroxide, 0-2 parts of copper nitrate, 0-2 parts of silver nitrate, 0.1-0.5 part of defoaming agent and 1-3 parts of antistatic agent, wherein the antistatic agent is formed by mixing tri (2-aminoethyl) amine and didecyl dimethyl ammonium chloride, and the mass ratio of the tri (2-aminoethyl) amine to the didecyl dimethyl ammonium chloride is (1-3): (1-3).
2. The antistatic acrylic sheet according to claim 1, wherein: the mass ratio of the tri (2-aminoethyl) amine to the didecyl dimethyl ammonium chloride is 2: 1.
3. an antistatic acrylic sheet according to claim 1 or 2, characterized in that: and the flame retardant also comprises 0-4 parts of a flame retardant, wherein the flame retardant is one or a mixture of two of magnesium hydroxide and aluminum hydroxide.
4. An antistatic acrylic sheet according to claim 3, characterized in that: the flame retardant is prepared by mixing magnesium hydroxide and aluminum hydroxide, wherein the mass ratio of the magnesium hydroxide to the aluminum hydroxide is (1-2): (1-2).
5. The antistatic acrylic sheet according to claim 4, wherein: the mass ratio of the magnesium hydroxide to the aluminum hydroxide is 1: 1.
6. the antistatic acrylic sheet according to claim 1, wherein: the defoaming agent is a dimethyl silicone oil defoaming agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810966681.5A CN110857354A (en) | 2018-08-23 | 2018-08-23 | Antistatic acrylic plate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810966681.5A CN110857354A (en) | 2018-08-23 | 2018-08-23 | Antistatic acrylic plate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110857354A true CN110857354A (en) | 2020-03-03 |
Family
ID=69635102
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810966681.5A Pending CN110857354A (en) | 2018-08-23 | 2018-08-23 | Antistatic acrylic plate |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110857354A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115260382A (en) * | 2022-08-23 | 2022-11-01 | 浙江工业大学 | Transparent antistatic PMMA material and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106084607A (en) * | 2016-06-13 | 2016-11-09 | 上海金泛斯标识有限公司 | A kind of antibacterial flame-retardant acryl plates and preparation method thereof |
| CN106220763A (en) * | 2016-07-29 | 2016-12-14 | 王斐芬 | A kind of antibacterial acryl plates |
| CN107189303A (en) * | 2017-06-23 | 2017-09-22 | 成都金宝马数码技术有限公司 | A kind of antibacterial acryl plates |
-
2018
- 2018-08-23 CN CN201810966681.5A patent/CN110857354A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106084607A (en) * | 2016-06-13 | 2016-11-09 | 上海金泛斯标识有限公司 | A kind of antibacterial flame-retardant acryl plates and preparation method thereof |
| CN106220763A (en) * | 2016-07-29 | 2016-12-14 | 王斐芬 | A kind of antibacterial acryl plates |
| CN107189303A (en) * | 2017-06-23 | 2017-09-22 | 成都金宝马数码技术有限公司 | A kind of antibacterial acryl plates |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115260382A (en) * | 2022-08-23 | 2022-11-01 | 浙江工业大学 | Transparent antistatic PMMA material and preparation method thereof |
| CN115260382B (en) * | 2022-08-23 | 2024-02-13 | 浙江工业大学 | Transparent antistatic PMMA material and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106084607A (en) | A kind of antibacterial flame-retardant acryl plates and preparation method thereof | |
| CN101498105B (en) | Aqueous foaming flame-retardant coating glue for textile and preparation thereof | |
| CN103724808A (en) | Photodiffusion antibacterial polypropylene material and preparation method thereof as well as illuminating lamp prepared therefrom | |
| CN104559118A (en) | Polycarbonate master batch capable of rejecting ultraviolet ray radiation and near infrared ray radiation as well as preparation method and application thereof | |
| CN103450560B (en) | Heat-resistant photodiffusion polypropylene composition and preparation method thereof | |
| CN110857354A (en) | Antistatic acrylic plate | |
| CN104761987A (en) | Water-based reflective insulation paint | |
| CN106220763A (en) | A kind of antibacterial acryl plates | |
| DE69923230D1 (en) | POLYCARBONATE FILM WITH IMPROVED FLAME INHIBITION PERFORMANCE | |
| CN102604295A (en) | Polymer calcium zinc complex soap heat stabilizer, preparation method thereof and application thereof | |
| CN107236401A (en) | A kind of organo-mineral complexing emulsion and the external wall elastic coating comprising the complex emulsions | |
| CN103570863A (en) | Waterproof and fireproof paint coating | |
| CN106147190A (en) | PC/ASA intermingling material that a kind of low gloss high-strength halogen-free is fire-retardant and preparation method thereof | |
| CN106367084A (en) | Fire retardant | |
| CN104927220A (en) | Preparing method of PS (polystyrene) composite | |
| CN104725763A (en) | Illumination aging-resistant ABS plastic and preparation method thereof | |
| CN100471909C (en) | ABS hardening flame-proof modified composition | |
| CN204877125U (en) | Novel glass | |
| CN103073835A (en) | Light aging resistant ABS (acrylonitrile butadiene styrene) plastic used for inside decorations of automobile and preparation method thereof | |
| CN113969032B (en) | Ultraviolet shielding acrylic tannic acid composite material and preparation method and application thereof | |
| CN110437554B (en) | Transparent polystyrene material capable of expelling insects and preparation method thereof | |
| CN105255060A (en) | PVC-MMA composite material and plastic product | |
| CN101235119A (en) | Metal cross-linking elasticity acrylate copolymerization emulsion | |
| KR102244726B1 (en) | Composition for the thermal insulation of building wall surfaces and application process thereof | |
| CN103105937A (en) | Fluorescence polycarbonate keyboard film |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20200303 |