CN110828855B - Flexible self-oxygen-supply rechargeable zinc-air battery pack module - Google Patents
Flexible self-oxygen-supply rechargeable zinc-air battery pack module Download PDFInfo
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- CN110828855B CN110828855B CN201911080540.4A CN201911080540A CN110828855B CN 110828855 B CN110828855 B CN 110828855B CN 201911080540 A CN201911080540 A CN 201911080540A CN 110828855 B CN110828855 B CN 110828855B
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- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 114
- 239000001301 oxygen Substances 0.000 claims abstract description 114
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 111
- 238000000926 separation method Methods 0.000 claims abstract description 15
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 5
- 239000010959 steel Substances 0.000 claims abstract description 5
- 239000011701 zinc Substances 0.000 claims description 12
- 229910052799 carbon Inorganic materials 0.000 claims description 11
- 239000004744 fabric Substances 0.000 claims description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 10
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 10
- 239000007787 solid Substances 0.000 claims description 10
- 229910052725 zinc Inorganic materials 0.000 claims description 10
- 229920001046 Nanocellulose Polymers 0.000 claims description 7
- 239000012528 membrane Substances 0.000 claims description 7
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 230000000903 blocking effect Effects 0.000 claims description 4
- 239000003054 catalyst Substances 0.000 claims description 4
- 239000003792 electrolyte Substances 0.000 claims description 3
- 238000003487 electrochemical reaction Methods 0.000 claims description 2
- 238000000034 method Methods 0.000 claims 1
- 238000007599 discharging Methods 0.000 abstract 1
- 239000000306 component Substances 0.000 description 23
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 229910001416 lithium ion Inorganic materials 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000008358 core component Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000004297 night vision Effects 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
- H01M8/04089—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M12/00—Hybrid cells; Manufacture thereof
- H01M12/08—Hybrid cells; Manufacture thereof composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
- H01M8/04201—Reactant storage and supply, e.g. means for feeding, pipes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/2457—Grouping of fuel cells, e.g. stacking of fuel cells with both reactants being gaseous or vaporised
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Hybrid Cells (AREA)
Abstract
The invention relates to a flexible self-oxygen-supply chargeable zinc-air battery pack module, wherein a flexible zinc-air battery pack is cylindrically wrapped by a baffle plate with a plurality of air holes; the oxygen storage component is wrapped by a flexible pipe with a built-in steel wire in a cylindrical shape; the two ends of the flexible zinc-air battery pack module are respectively connected with a buckle and a clamping groove, the rear sides of the buckle and the clamping groove are respectively provided with a sealable circular air hole, and external oxygen can directly enter the flexible zinc-air battery pack at the center through the circular air holes. When the oxygen in the external environment is sufficient, the flexible zinc-air battery pack directly absorbs the external oxygen through the sealable circular air holes to discharge; when the external environment is free of oxygen, the sealed circular air hole is closed, and the air hole in the separation blade rotates to the position opposite to the air hole of the oxygen storage assembly, so that oxygen stored in the oxygen storage assembly can enter the flexible zinc-air battery pack through the air hole, and the discharging continuity is guaranteed. The invention has light weight, high density, stable discharge and random shape change.
Description
Technical Field
The invention relates to a flexible rechargeable zinc-air battery, in particular to a flexible self-oxygen-supply rechargeable zinc-air battery pack module.
Background
In modern combat, the individual soldier that modern infantry carried equips more and more complicacy, and in the individual soldier combat equipment, generally include: sensors, communication equipment, navigation devices, night vision devices, even miniature medical devices and weather systems, etc. The power source used by the equipment is a battery pack carried by an infantry, so that the battery has the advantages of light weight, long service time, high power, stable discharge curve, safe use and the like. Traditionally, lithium ion batteries can meet the above needs. However, since the lithium ion battery is generally continuously discharged, when power generation is actually required, the lithium ion battery is excessively discharged, which may cause a failure of the device. Meanwhile, the self-discharge of the lithium ion battery is relatively high, and the lithium ion battery is not suitable for long-term storage. The zinc-air battery is lighter in weight and longer in working time than the lithium batteries of the same type, is safer and more environment-friendly under the same working environment, and has better storage effect. However, the environment of individual combat changes at any time according to the needs of the combat, and sometimes involves water combat, so that how to ensure the supply of oxygen in water is a problem. Therefore, in light of the above-mentioned drawbacks, there is a need to develop a rechargeable battery pack that can supply oxygen under oxygen-free conditions while ensuring safety, reliability, portability, high density, and smooth discharge.
Disclosure of Invention
The invention aims to solve the problems and provide a safe, light-weight, high-density and smooth-discharge flexible self-oxygen-supply rechargeable zinc-air battery pack module.
The purpose of the invention is realized by the following technical scheme:
a flexible self-oxygen-supply chargeable zinc-air battery pack module comprises a core component and a flexible zinc-air battery pack. The inner side of the oxygen storage component is wrapped by a flexible zinc-air battery pack, the outer side of the oxygen storage component is wrapped by a flexible pipe with a built-in steel wire, and the inner side of the oxygen storage component is provided with a plurality of air holes. Two ends of the flexible zinc-air battery pack are respectively connected with a buckle and a clamping groove, and the rear sides of the buckle and the clamping groove are respectively provided with a sealable round air hole; when the oxygen in the external environment is sufficient, the flexible zinc-air battery pack directly absorbs the external oxygen through the sealable circular air holes to discharge; when the external environment is free of oxygen, the flexible zinc-air battery pack (2) is supplied with oxygen through the oxygen storage assembly (1) to supply power for external electric equipment.
Further, the flexible zinc-air battery pack is wrapped by a separation blade with air holes, the separation blade with the air holes is wrapped by an oxygen storage assembly, and the oxygen storage assembly and the separation blade with the air holes can slide mutually; when the air holes on the separation blade are opposite to the air holes on the inner side of the oxygen storage assembly, oxygen can flow out of the oxygen storage assembly to supply oxygen for the flexible zinc-air battery pack, when external oxygen is needed, the oxygen storage assembly is rotated to close the oxygen storage assembly to supply oxygen, and then external oxygen supplies oxygen for the flexible zinc-air battery pack through the sealable circular air holes.
Further, when external environment changed into the anaerobic environment by the aerobic, the circular bleeder vent can be sealed in the push down, makes and can seal circular bleeder vent and close, store up the rotatory certain angle of oxygen subassembly for the bleeder vent of separation blade is relative with the gas pocket of storing up the oxygen subassembly, and oxygen is carried out the oxygen suppliment by storing up the inside outflow of oxygen subassembly for flexible zinc air battery group.
Furthermore, the air holes on the blocking piece and the air holes on the oxygen storage component are distributed at intervals, so that the air holes on the blocking piece and the air holes on the oxygen storage component do not correspond to each other when oxygen is supplied to the environment, and the oxygen stored in the oxygen storage component is prevented from leaking.
Furthermore, after the buckle is clamped with the clamping groove, the flexible zinc-air battery pack forms a non-communicated closed loop and can be placed between the waist for carrying.
Furthermore, the flexible zinc-air battery pack can be arranged on two sides of the power output assembly in 6-10 double rows according to the used electric quantity.
Further, the flexible zinc-air battery pack comprises a metal zinc electrode serving as a battery cathode, a solid quaternary ammonium salt functionalized nano cellulose membrane and air-absorbing carbon cloth, wherein the air-absorbing carbon cloth absorbs oxygen to serve as a battery anode.
Furthermore, the carbon cloth absorbing the air adopts the addition of Au-NWs/Au 6 MnO 8 The carbon cloth of the catalyst is used as an air anode in the rechargeable zinc-air battery, and the solid quaternary ammonium salt functionalized nano cellulose membrane is used as the electrolyte of the zinc-air battery pack in the middle, so that the high battery capacity, the high cycle life, the high safety and the stable power output of the flexible solid zinc-air battery can be ensured.
The beneficial effects of the invention are:
the flexible self-oxygen-supply chargeable zinc-air battery pack module has the advantages of light weight, high density, stable discharge, free shape change and continuous and stable output and power supply in an aerobic and anaerobic environment, so that the flexible self-oxygen-supply chargeable zinc-air battery pack module has certain advantages in the aspects of space utilization rate, light weight, portability, stable voltage output, environmental protection, stable storage and applicability in various environments.
Drawings
Fig. 1 is a block diagram of a flexible self-oxygen-supplying rechargeable zinc-air battery module;
fig. 2 is a cross-sectional view of a flexible self-energizing rechargeable zinc-air battery module;
FIG. 3 is a development view of a cylindrical oxygen storage assembly;
in the figure: 1-an oxygen storage assembly; 2-a flexible zinc-air battery; 3, buckling; 4-a card slot; 5-the circular air holes can be sealed; 6-air holes; 7-a metallic zinc electrode; 8-solid quaternary ammonium salt functionalized nano cellulose membrane; 9-carbon cloth; 10-a baffle plate; 12-a flexible tube; 13-Power output Components.
Detailed Description
The present invention will now be described in detail with reference to the drawings and specific embodiments, it being understood that the embodiments described are only some examples of the invention and not all embodiments. All other embodiments obtained on the basis of the embodiments of the invention without making innovative labor fall within the scope of protection of the invention.
As shown in fig. 1, 2 and 3, a flexible self-oxygen-supplying chargeable zinc-air battery module comprises an oxygen storage component 1 and a flexible zinc-air battery 2 wrapped by the oxygen storage component 1, wherein the outer side of the oxygen storage component 1 is wrapped by a flexible pipe 12 with a built-in steel wire, the inner side of the oxygen storage component is in contact with a separation blade 10 with an air vent, and a plurality of air holes 6 are arranged at the contact part. The two ends of the flexible battery pack module are connected with the buckle 3 and the clamping groove 4, and when the buckle and the clamping groove are clamped, the flexible battery pack module can form a non-communicated closed loop and is placed between the waist, so that the portable battery pack is convenient to carry. The rear sides of the buckle 3 and the clamping groove 4 are provided with a sealable round air hole 5 which is used as a channel for gas exchange between the internal zinc-air battery pack and the outside. In the aerobic environment, sealed circular bleeder vent 5 is in the open mode, and the gas pocket 6 of storing up the inboard of oxygen subassembly 1 is in the closed condition, gives the zinc-air battery oxygen suppliment by external environment, and when the battery pack module was in the anaerobic environment, sealed circular bleeder vent 5 closed, and the gas pocket 6 of storing up the inboard of oxygen subassembly 1 is opened, and gas storage subassembly 1 carries out the oxygen suppliment for flexible zinc-air battery group 2, guarantees the power supply of power.
Further, the outermost layer of the flexible tube 12 sequentially wraps the oxygen storage component 1, the baffle 10 and the flexible zinc-air battery pack 2, and the flexible zinc-air battery pack 2 comprises a metal zinc electrode 7 as a negative electrode of the battery, a solid quaternary ammonium salt functional nano cellulose membrane 8 and oxygen absorbed by a carbon cloth 9 for absorbing air as a positive electrode of the battery.
The flexible zinc-air battery pack 2 is wrapped by a separation blade 10 with air holes, the outer side of the separation blade 10 with the air holes is wrapped by an oxygen storage component 1, the inner wall of the oxygen storage component 1 also comprises air holes 6, and the oxygen storage component 1 and the separation blade 10 can slide mutually. When the air holes on the baffle plate 10 are opposite to the air holes 6 on the inner wall of the oxygen storage component 1, the oxygen storage component supplies oxygen, and when external oxygen is needed, the oxygen storage component 1 is rotated, and then the oxygen supply of the oxygen storage component 1 is closed.
The cylindrical oxygen storage component 1 wraps the flexible zinc-air battery pack 2. When the oxygen is sufficient in the external environment, the flexible zinc-air battery pack 2 can directly absorb the external oxygen to discharge; when the flexible zinc-air battery pack 2 is in water or other oxygen-free environments, oxygen is supplied to the flexible zinc-air battery pack through the oxygen storage component 1 outside the flexible zinc-air battery pack to generate electricity.
The buckle 3 and the clamping groove 4 are respectively connected to two ends of the strip-shaped flexible zinc-air battery pack 2, and when the buckle 3 and the clamping groove 4 are clamped mutually, the flexible zinc-air battery pack 2 can form a non-communicated closed loop, so that the flexible zinc-air battery pack can be placed between the waist and is convenient to carry. Can seal circular bleeder vent 5 and be located the rear portion of buckle 3, draw-in groove 4, play and link up outside and inside effect, it can absorb outside environment oxygen and supply with flexible zinc air battery group 2 and use, when outside environment changes into the anaerobic environment, when needing to supply with flexible zinc air battery group 2 from the outfit oxygen, the bleeder vent pushes down to kick-back and can seal, guarantees from this that the outfit oxygen can not leak.
The flexible zinc-air battery 2 is formed by adopting metal zinc as the cathode of the battery and adding Au-NWs/Au 6 MnO 8 The carbon cloth of the catalyst is used as an air anode in the rechargeable zinc-air battery, and the solid quaternary ammonium salt functionalized nano cellulose membrane is used as the electrolyte of the zinc-air battery pack in the middle, so that the high battery capacity, the high cycle life, the high safety and the stable power output of the flexible solid zinc-air battery are ensured.
The cylindrical oxygen storage component 1 can be wrapped by a flexible pipe with a built-in steel wire for protection, so that the oxygen storage component is not easy to damage under certain external force.
The specific working principle of the invention is as follows:
1) the core principle is as follows:
the principle of the zinc-air battery is that zinc and oxygen generate electrochemical reaction in the battery to convert chemical energy into electric energy.
And (3) positive electrode: 1/2O 2 +H 2 O+2e - →2OH -
Negative electrode: zn → Zn 2+ +2e -
And (3) total reaction: 1/2O 2 +Zn=ZnO
The oxygen in the air and the metal zinc in the battery react under the action of the catalyst to generate direct current.
2) When the outside is oxygenated, the zinc-air battery pack (2) exchanges oxygen with the outside through the sealable circular air holes (5) to perform reaction power supply; when the outside is free of oxygen, the zinc-air battery pack (2) is supplied with oxygen by the oxygen storage assembly (1), so that the continuous supply of electric power is ensured. Meanwhile, the two ends of the flexible zinc-air battery pack module are provided with the buckle (3) and the clamping groove (4), so that the flexible zinc-air battery pack module can be connected into a non-through closed loop, spans the waist and is convenient to carry.
The above description is only a basic description of the present invention, and any equivalent changes made according to the technical solutions of the present invention should fall within the protection scope of the present invention.
Claims (7)
1. The utility model provides a flexible self-feeding chargeable zinc-air battery group module, core assembly include oxygen storage component (1), flexible zinc-air battery group (2), its characterized in that: the oxygen storage component (1) is cylindrical, the oxygen storage component (1) is arranged on the outer side of the flexible zinc-air battery pack (2), the oxygen storage component (1) is wrapped by a flexible pipe (12) with a built-in steel wire, and a plurality of air holes are formed in the contact part of the inner side of the oxygen storage component (1) and the baffle (10); the baffle plate (10) is positioned between the oxygen storage component (1) and the flexible zinc-air battery pack (2) and comprises a plurality of air holes; two ends of the flexible zinc-air battery pack (2) are respectively connected with a buckle (3) and a clamping groove (4); the rear sides of the buckle (3) and the clamping groove (4) are respectively provided with a sealable circular air hole (5); when the oxygen in the external environment is sufficient, the flexible zinc-air battery pack (2) directly absorbs the external oxygen through the sealable circular air holes (5) to generate electrochemical reaction and supply power to external electric equipment; when the external environment is free of oxygen, the flexible zinc-air battery pack (2) is supplied with oxygen by the oxygen storage assembly (1) to supply power to external electric equipment; the flexible zinc-air battery pack (2) is wrapped by a separation blade (10) with air holes, the separation blade (10) is wrapped by an oxygen storage assembly (1), and the oxygen storage assembly (1) and the separation blade (10) with the air holes can slide mutually; when the air holes on the baffle plate (10) are opposite to the air holes on the inner wall of the oxygen storage component (1), oxygen flows out from the interior of the oxygen storage component (1) and passes through the air holes to supply oxygen for the flexible zinc-air battery pack (2); when oxygen exists outside, the circular air holes (5) can be sealed and opened, and meanwhile, the blocking piece (10) is rotated until the air holes of the blocking piece are not opposite to the air holes of the oxygen storage assembly (1), so that the oxygen of the oxygen storage assembly (1) is not leaked, and the supply of the oxygen is also ensured.
2. The flexible self-oxygen supplying rechargeable zinc-air battery module of claim 1, wherein: when the external environment is changed from aerobic environment to anaerobic environment, the sealable circular air hole (5) is pressed downwards, so that the sealable circular air hole (5) is closed; the oxygen storage assembly (1) rotates for a certain angle, so that the air holes of the baffle plates (10) are opposite to the air holes of the oxygen storage assembly (1), and the oxygen storage assembly (1) supplies oxygen for the flexible zinc-air battery pack (2).
3. The flexible self-oxygen-supplying rechargeable zinc-air battery module according to claim 1, characterized in that: the air holes in the separation blade (10) and the air holes in the oxygen storage assembly (1) are distributed at intervals, so that the air holes in the separation blade (10) are not corresponding to the air holes in the oxygen storage assembly (1) when oxygen is supplied to the environment, and the oxygen stored in the oxygen storage assembly (1) is prevented from leaking.
4. The flexible self-oxygen supplying rechargeable zinc-air battery module of claim 1, wherein: after the buckle (3) and the clamping groove (4) are clamped, the flexible zinc-air battery pack (2) forms a non-communicated closed loop, can be placed between the waist and is convenient to carry.
5. The flexible self-oxygen supplying rechargeable zinc-air battery module of claim 1, wherein: the flexible zinc-air battery packs (2) are arranged on two sides of the power output assembly (13) in double rows of 6-10 according to the power consumption.
6. The flexible self-oxygen-supplying rechargeable zinc-air battery module according to claim 1, characterized in that: the flexible zinc-air battery pack (2) comprises a metal zinc electrode (7) serving as a battery cathode, a solid quaternary ammonium salt functional nano cellulose membrane (8) and carbon cloth (9) for absorbing air, wherein the carbon cloth (9) for absorbing air absorbs oxygen to serve as a battery anode.
7. According to claim6 flexible self-oxygen-supply rechargeable zinc-air battery pack module, its characterized in that: the carbon cloth (9) absorbing the air adopts the method of adding Au-NWs/Au 6 MnO 8 The carbon cloth of the catalyst is used as an air anode in the rechargeable zinc-air battery, and the solid quaternary ammonium salt functionalized nano cellulose membrane (8) is used as the electrolyte of the zinc-air battery pack in the middle, so that the high battery capacity, the high cycle life, the high safety and the stable power output of the flexible solid zinc-air battery can be ensured.
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CN110289387A (en) * | 2019-05-17 | 2019-09-27 | 宁波大学 | A kind of all solid state neutral zinc-air battery |
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US20160204441A1 (en) * | 2014-09-02 | 2016-07-14 | Panisolar, Inc. | Wall Mounted Zinc Batteries |
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CN2411585Y (en) * | 1999-07-16 | 2000-12-20 | 武汉大学 | Cylindrical zinc air cell |
CN202352802U (en) * | 2011-12-08 | 2012-07-25 | 北京中航长力能源科技有限公司 | Oxygen supply device for dry discharged zinc air battery pack |
CN202363533U (en) * | 2011-12-08 | 2012-08-01 | 北京中航长力能源科技有限公司 | Zinc-air battery with oxygen bag |
CN105720280A (en) * | 2014-12-01 | 2016-06-29 | 廖文煌 | Air intake circulation system of zinc-air fuel cells |
CN204391222U (en) * | 2014-12-18 | 2015-06-10 | 北京立开源科技有限公司 | A kind of coin shape zinc-air cell |
CN105244565A (en) * | 2015-10-26 | 2016-01-13 | 复旦大学 | Flexible tensible chargable linear zinc air cell and preparation method thereof |
CN108352589A (en) * | 2015-11-11 | 2018-07-31 | 株式会社Emw能源 | Zinc-air battery |
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CN110289387A (en) * | 2019-05-17 | 2019-09-27 | 宁波大学 | A kind of all solid state neutral zinc-air battery |
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