CN207637926U - rechargeable lithium battery - Google Patents
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- CN207637926U CN207637926U CN201721877271.0U CN201721877271U CN207637926U CN 207637926 U CN207637926 U CN 207637926U CN 201721877271 U CN201721877271 U CN 201721877271U CN 207637926 U CN207637926 U CN 207637926U
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- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims abstract description 86
- 229910052744 lithium Inorganic materials 0.000 title claims abstract description 86
- 229910052751 metal Inorganic materials 0.000 claims abstract description 12
- 239000002184 metal Substances 0.000 claims abstract description 12
- 239000003792 electrolyte Substances 0.000 claims abstract description 8
- 239000002826 coolant Substances 0.000 claims abstract description 6
- 238000009713 electroplating Methods 0.000 claims abstract description 4
- 239000007788 liquid Substances 0.000 claims abstract 3
- 238000003466 welding Methods 0.000 claims abstract 2
- 238000007789 sealing Methods 0.000 claims description 26
- 230000001681 protective effect Effects 0.000 claims description 12
- 238000002955 isolation Methods 0.000 claims description 9
- 239000011888 foil Substances 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000002131 composite material Substances 0.000 claims description 3
- 239000012809 cooling fluid Substances 0.000 claims description 3
- -1 hexafluorophosphate Chemical compound 0.000 claims description 3
- 239000007774 positive electrode material Substances 0.000 claims description 3
- 239000000741 silica gel Substances 0.000 claims description 3
- 229910002027 silica gel Inorganic materials 0.000 claims description 3
- 230000005611 electricity Effects 0.000 claims 8
- 239000005977 Ethylene Substances 0.000 claims 1
- 239000005030 aluminium foil Substances 0.000 claims 1
- 238000005868 electrolysis reaction Methods 0.000 claims 1
- 238000003475 lamination Methods 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 7
- 238000001816 cooling Methods 0.000 abstract description 2
- 210000005056 cell body Anatomy 0.000 abstract 4
- 210000004027 cell Anatomy 0.000 abstract 3
- 230000004888 barrier function Effects 0.000 abstract 1
- 239000000110 cooling liquid Substances 0.000 description 9
- 238000009413 insulation Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 230000008569 process Effects 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000004880 explosion Methods 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 239000007773 negative electrode material Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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Abstract
Description
技术领域technical field
本实用新型涉及电池领域,尤指一种可充电锂电池。The utility model relates to the field of batteries, in particular to a rechargeable lithium battery.
背景技术Background technique
在所有能源形式中,电能是最容易使用、最清洁环保和效率最高的能源,电池是最好的储存电能的装置,在所有电池产品中,锂电池是目前世界上最年轻、最先进、技术含金量最高、能量密度最大的能源产品,锂电池具有工作稳定范围宽,放电电压平稳,自放电率低,使用寿命长等优点,已被广泛应用于各种领域,特别是航天航空、军事、长寿命仪器仪表、物流追踪、骑车汽车电子、移动数码产品等领域,近年来,随着科技不断发展,电子设备的功能不断升级,因此对锂电池的能量及倍率性能提出了更好的要求,高能量电池已成为电池行业的重点研究方向。Among all forms of energy, electric energy is the easiest to use, the cleanest, the most environmentally friendly, and the most efficient energy. Batteries are the best device for storing electric energy. Among all battery products, lithium batteries are currently the youngest, most advanced, and technologically advanced in the world. Energy products with the highest gold content and the highest energy density, lithium batteries have the advantages of wide working range, stable discharge voltage, low self-discharge rate, long service life, etc., and have been widely used in various fields, especially aerospace, military, long-term In recent years, with the continuous development of science and technology, the functions of electronic equipment have been continuously upgraded in the fields of life-span instrumentation, logistics tracking, cycling automotive electronics, and mobile digital products. Therefore, better requirements have been put forward for the energy and rate performance of lithium batteries. High-energy batteries have become a key research direction in the battery industry.
目前市场上可充电锂电池有以下不足:Rechargeable lithium batteries currently on the market have the following deficiencies:
1.可充电锂电池其负极碳材料的理论克容量较低,且常规锂电池的结构中,利用卷绕或叠片的方式虽然提高电池的功率密度,但降低了电池的能量密度,因此常规可充电锂电池的结构不利于提高电池的能量密度。1. The theoretical gram capacity of the negative electrode carbon material of rechargeable lithium batteries is low, and in the structure of conventional lithium batteries, although the power density of the battery is increased by winding or stacking, the energy density of the battery is reduced, so conventional The structure of rechargeable lithium batteries is not conducive to improving the energy density of batteries.
2.在制作加工电池过程中,电极包会受到各种挤压变形,容易使其内部电解液泄漏,难以保证电池的性能标准统一。2. During the process of manufacturing and processing the battery, the electrode package will be subjected to various extrusion deformations, which will easily cause the internal electrolyte to leak, and it is difficult to ensure uniform performance standards of the battery.
3.由于锂电池需要长期循环充电,锂电池在充电过程中的温度过高,以及充电持续时间过长,锂电池经常会发生空鼓变形的现象。3. Due to the need for long-term cycle charging of lithium batteries, the temperature of lithium batteries during charging is too high, and the charging duration is too long, lithium batteries often experience hollowing and deformation.
发明内容Contents of the invention
为解决上述问题,本实用新型提供一种可充电锂电池,本实用新型能量密度高,防护绝缘效果好,输出电压稳定,冷却效果好。In order to solve the above problems, the utility model provides a rechargeable lithium battery, which has high energy density, good protection and insulation effect, stable output voltage and good cooling effect.
为实现上述目的,本实用新型采用的技术方案是:一种可充电锂电池,包括锂电池本体、保护装置,所述锂电池本体设置在保护装置内,所述保护装置包括保护外壳和密封盖,所述密封盖盖合在保护外壳上,所述保护外壳内底表面设有第一固定座,所述密封盖下部设有第二固定座,所述锂电池本体包括正电极柱、负电极柱和锂电池外壳,所述锂电池外壳固定安装在第一固定座与第二固定座之间,所述正电极柱和负电极柱的一端设置在锂电池外壳内,正电极柱和负电极柱的另一端穿过第一固定座以及密封盖并延伸至保护外壳外;所述锂电池外壳内设有电芯和电解液,所述电芯包括正极片、负极片、隔离膜,所述正极片、负极片相互叠层,且隔离膜设置在正极片、负极片之间;所述正极片包括正极集流体和焊接在所述正极集流体上的正极极耳,所述正极集流体的两面设置有正极活性材料,所述负极片包括负极集流体和焊接与所述负极集流体上的负极极耳,所述负极集流体的表面电镀有金属锂层;所述锂电池本体和保护装置之间留有空腔,所述空腔内填充有冷却液。In order to achieve the above purpose, the technical solution adopted by the utility model is: a rechargeable lithium battery, including a lithium battery body and a protection device, the lithium battery body is arranged in the protection device, and the protection device includes a protective shell and a sealing cover , the sealing cover is closed on the protective casing, the inner bottom surface of the protective casing is provided with a first fixing seat, the lower part of the sealing cover is provided with a second fixing seat, and the lithium battery body includes a positive electrode column, a negative electrode A column and a lithium battery casing, the lithium battery casing is fixedly installed between the first fixing seat and the second fixing seat, one end of the positive electrode column and the negative electrode column is arranged in the lithium battery casing, the positive electrode column and the negative electrode The other end of the column passes through the first fixed seat and the sealing cover and extends to the outside of the protective casing; the lithium battery casing is provided with an electric core and an electrolyte, and the electric core includes a positive electrode sheet, a negative electrode sheet, and a separator. The positive electrode sheet and the negative electrode sheet are stacked on each other, and the separator is arranged between the positive electrode sheet and the negative electrode sheet; the positive electrode sheet includes a positive electrode current collector and a positive electrode tab welded on the positive electrode current collector, and the positive electrode current collector Both sides are provided with positive electrode active materials, the negative electrode sheet includes a negative electrode current collector and a negative electrode tab welded to the negative electrode current collector, the surface of the negative electrode current collector is electroplated with a metal lithium layer; the lithium battery body and protection device A cavity is left in between, and the cavity is filled with cooling liquid.
进一步地,锂电池外壳与第一固定座连接处设有底膜,所述密封盖与第二固定座连接处设有顶膜。Further, a bottom film is provided at the connection between the lithium battery casing and the first fixing seat, and a top film is provided at the connection between the sealing cover and the second fixing seat.
进一步地,负极集流体采用金属箔材或金属网制成;所述正极集流体采用铝箔制成。Further, the negative electrode current collector is made of metal foil or metal mesh; the positive electrode current collector is made of aluminum foil.
进一步地,密封盖表面设有冷却液孔,所述冷却液孔内可拆卸设置有密封塞。Further, a cooling liquid hole is provided on the surface of the sealing cover, and a sealing plug is detachably arranged in the cooling liquid hole.
进一步地,隔离膜为聚乙烯-聚丙烯-聚乙烯复合层隔离膜。Further, the isolation film is a polyethylene-polypropylene-polyethylene composite layer isolation film.
进一步地,正电极柱和负电极柱与密封盖之间设有硅胶片。Further, a silica gel sheet is provided between the positive electrode column, the negative electrode column and the sealing cover.
进一步地,电解液为六氟磷酸盐制成。Further, the electrolyte is made of hexafluorophosphate.
进一步地,负极集流体截面为凹凸结构。Further, the cross section of the negative electrode current collector has a concave-convex structure.
本实用新型的有益效果在于:The beneficial effects of the utility model are:
1.本实用新型的锂电池负极柱上不需涂覆负极活性材料,简化了过程工序,操作简单便捷,通过在负极柱表面电镀金属锂层,有效的结合了一次锂电池高能量和可充电锂电池高功率的特点,能够满足电子设备稳定电压使用。1. The lithium battery negative pole of the utility model does not need to be coated with negative active materials, which simplifies the process and is simple and convenient to operate. By electroplating a metal lithium layer on the surface of the negative pole, the high energy and rechargeable primary lithium battery are effectively combined. The high-power characteristics of lithium batteries can meet the stable voltage requirements of electronic equipment.
2.将锂电池本体设置在保护装置内,在保护装置作用下,锂电池的防护、绝缘效果好,并且对电极包固定效果好。2. The lithium battery body is placed in the protection device. Under the action of the protection device, the protection and insulation effects of the lithium battery are good, and the fixing effect on the electrode package is good.
3.在锂电池本体和保护装置之间填充有冷却液,当锂电池的温度过高是,藉由冷却液对锂电池进行降温,如此延长了锂电池的受用寿命,也避免了因为锂电池的温度过高,而导致的爆炸危险。3. A coolant is filled between the lithium battery body and the protection device. When the temperature of the lithium battery is too high, the coolant is used to cool the lithium battery, which prolongs the service life of the lithium battery and avoids damage caused by the lithium battery. The temperature is too high, resulting in the risk of explosion.
附图说明Description of drawings
图1 是本实用新型结构示意图。Fig. 1 is a structural schematic diagram of the utility model.
附图标号说明:1. 正电极柱;2. 负电极柱;3. 保护外壳;4. 密封盖;5. 锂电池外壳;6. 第一固定座;7. 第二固定座;8. 电芯;9. 正极片;10. 负极片;11. 隔离膜;12.正极极耳;13. 负极极耳;14. 底膜;15. 顶膜;16. 密封塞;17. 硅胶片。Description of reference numerals: 1. Positive electrode column; 2. Negative electrode column; 3. Protective shell; 4. Sealing cover; 5. Lithium battery shell; Core; 9. Positive plate; 10. Negative plate; 11. Isolation film; 12. Positive tab; 13. Negative tab; 14. Bottom film; 15. Top film; 16. Sealing plug;
具体实施方式Detailed ways
请参阅图1所示,本实用新型关于一种可充电锂电池,包括锂电池本体、保护装置,所述锂电池本体设置在保护装置内,所述保护装置包括保护外壳3和密封盖4,所述密封盖4盖合在保护外壳3上,所述保护外壳3内底表面设有第一固定座6,所述密封盖4下部设有第二固定座7,所述锂电池本体包括正电极柱1、负电极柱2和锂电池外壳5,所述锂电池外壳5固定安装在第一固定座6与第二固定座7之间,所述正电极柱1和负电极柱2的一端设置在锂电池外壳5内,正电极柱1和负电极柱2的另一端穿过第一固定座6以及密封盖4并延伸至保护外壳3外;所述锂电池外壳内设有电芯8和电解液,所述电芯8包括正极片9、负极片10、隔离膜11,所述正极片9、负极片10相互叠层,且隔离膜11设置在正极片9、负极片10之间;所述正极片9包括正极集流体和焊接在所述正极集流体上的正极极耳12,所述正极集流体的两面设置有正极活性材料,所述负极片10包括负极集流体和焊接与所述负极集流体上的负极极耳13,所述负极集流体的表面电镀有金属锂层;所述锂电池本体和保护装置之间留有空腔,所述空腔内填充有冷却液。Please refer to Figure 1, the utility model relates to a rechargeable lithium battery, including a lithium battery body and a protection device, the lithium battery body is arranged in the protection device, and the protection device includes a protective shell 3 and a sealing cover 4, The sealing cover 4 is closed on the protective shell 3, the inner bottom surface of the protective shell 3 is provided with a first fixing seat 6, the lower part of the sealing cover 4 is provided with a second fixing seat 7, and the lithium battery body includes a positive An electrode column 1, a negative electrode column 2 and a lithium battery casing 5, the lithium battery casing 5 is fixedly installed between the first fixing seat 6 and the second fixing seat 7, one end of the positive electrode column 1 and the negative electrode column 2 Set in the lithium battery casing 5, the other end of the positive electrode column 1 and the negative electrode column 2 passes through the first fixing seat 6 and the sealing cover 4 and extends to the outside of the protective casing 3; the lithium battery casing is provided with a cell 8 and electrolyte solution, the cell 8 includes a positive electrode sheet 9, a negative electrode sheet 10, and a separator 11, the positive electrode sheet 9 and the negative electrode sheet 10 are stacked on each other, and the separator 11 is arranged between the positive electrode sheet 9 and the negative electrode sheet 10 The positive electrode sheet 9 includes a positive electrode current collector and a positive electrode tab 12 welded on the positive electrode current collector, the two sides of the positive electrode current collector are provided with positive active materials, and the negative electrode sheet 10 includes a negative electrode current collector and a welded and welded electrode. The negative electrode tab 13 on the negative electrode current collector, the surface of the negative electrode current collector is electroplated with a metal lithium layer; there is a cavity between the lithium battery body and the protection device, and the cavity is filled with cooling liquid.
使用时,本实用新型的锂电池负极柱上不需涂覆负极活性材料,简化了过程工序,操作简单便捷,通过在负电极柱2表面电镀金属锂层,有效的结合了一次锂电池高能量和可充电锂电池高功率的特点,能够满足电子设备稳定电压使用,将锂电池本体设置在保护装置内,在保护装置作用下,锂电池的防护、绝缘效果好,并且对锂电池外壳固定效果好,在锂电池本体和保护装置之间填充有冷却液,当锂电池的温度过高是,藉由冷却液对锂电池进行降温,如此延长了锂电池的受用寿命,也避免了因为锂电池的温度过高,而导致的爆炸危险。When in use, the lithium battery negative pole of the utility model does not need to be coated with negative active materials, which simplifies the process and is simple and convenient to operate. By electroplating a metal lithium layer on the surface of the negative pole 2, it effectively combines the high energy of the primary lithium battery. And the high power characteristics of rechargeable lithium batteries can meet the stable voltage use of electronic equipment. The lithium battery body is set in the protection device. Under the action of the protection device, the protection and insulation effects of the lithium battery are good, and the lithium battery shell is fixed. Well, a coolant is filled between the lithium battery body and the protection device. When the temperature of the lithium battery is too high, the coolant is used to cool down the lithium battery, which prolongs the service life of the lithium battery and avoids damage caused by the lithium battery. The temperature is too high, resulting in the risk of explosion.
进一步地,锂电池外壳5与第一固定座6连接处设有底膜14,所述锂电池外壳5与第二固定座7连接处设有顶膜15。可以更好的对锂电池进行固定和绝缘处理,使用更安全方便。Further, a bottom film 14 is provided at the connection between the lithium battery casing 5 and the first fixing seat 6 , and a top film 15 is provided at the connection between the lithium battery casing 5 and the second fixing seat 7 . The lithium battery can be better fixed and insulated, and the use is safer and more convenient.
进一步地,密封盖4上设有电量指示灯。可以更直观的了解锂电池电量情况,可以及时的充电。Further, a power indicator light is provided on the sealing cover 4 . You can more intuitively understand the power status of the lithium battery, and you can charge it in time.
进一步地,负极集流体采用金属箔材或金属网制成,所述正极集流体采用铝箔制成。Further, the negative electrode current collector is made of metal foil or metal mesh, and the positive electrode current collector is made of aluminum foil.
进一步地,密封盖4表面设有冷却液孔,所述冷却液孔内可拆卸设置有密封塞16。可以通过冷却液孔对冷却液进行及时的更换,并且密封塞的设计可以防止冷却液的泄漏。Further, a cooling liquid hole is provided on the surface of the sealing cover 4, and a sealing plug 16 is detachably arranged in the cooling liquid hole. The cooling liquid can be replaced in time through the cooling liquid hole, and the design of the sealing plug can prevent the leakage of the cooling liquid.
进一步地,隔离膜11为聚乙烯-聚丙烯-聚乙烯复合层隔离膜。Further, the isolation film 11 is a polyethylene-polypropylene-polyethylene composite layer isolation film.
进一步地,正电极柱1和负电极柱2与密封盖4之间设有硅胶片17。让正电极柱1和负电极柱2绝缘效果好,并且可以防止电解液或冷却液泄漏。Further, a silica gel sheet 17 is provided between the positive electrode column 1 , the negative electrode column 2 and the sealing cover 4 . The positive electrode column 1 and the negative electrode column 2 have a good insulation effect, and can prevent electrolyte or cooling fluid from leaking.
进一步地,电解液为六氟磷酸盐制成。Further, the electrolyte is made of hexafluorophosphate.
进一步地,负极集流体截面为凹凸结构。可以提供集流体伸缩的空间,增加单位面积金属锂的装载量,避免因镀锂体积膨胀而导致正极集流体和负极集流体断裂,同时提高电池中电解液的保有量。Further, the cross section of the negative electrode current collector has a concave-convex structure. It can provide space for the current collector to expand and contract, increase the loading capacity of metal lithium per unit area, avoid the fracture of the positive electrode current collector and negative electrode current collector due to the volume expansion of lithium plating, and increase the electrolyte retention in the battery.
以上实施方式仅仅是对本实用新型的优选实施方式进行描述,并非对本实用新型的范围进行限定,在不脱离本实用新型设计精神的前提下,本领域普通工程技术人员对本实用新型的技术方案作出的各种变形和改进,均应落入本实用新型的权利要求书确定的保护范围内。The above embodiment is only a description of the preferred implementation of the utility model, and is not intended to limit the scope of the utility model. On the premise of not departing from the design spirit of the utility model, ordinary engineers and technicians in the field made the technical solution of the utility model Various modifications and improvements should fall within the protection scope determined by the claims of the present utility model.
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| CN114050346A (en) * | 2021-11-09 | 2022-02-15 | 长沙理工大学 | A kind of battery core structure with self-absorption heat and temperature control and manufacturing method thereof |
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| CN114050346A (en) * | 2021-11-09 | 2022-02-15 | 长沙理工大学 | A kind of battery core structure with self-absorption heat and temperature control and manufacturing method thereof |
| CN114050346B (en) * | 2021-11-09 | 2023-11-24 | 长沙理工大学 | Self-heat-absorption temperature-control electric core structure |
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