CN110818451A - Primer slurry for light-transmitting ceramic tile and preparation method thereof - Google Patents
Primer slurry for light-transmitting ceramic tile and preparation method thereof Download PDFInfo
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- CN110818451A CN110818451A CN201911182885.0A CN201911182885A CN110818451A CN 110818451 A CN110818451 A CN 110818451A CN 201911182885 A CN201911182885 A CN 201911182885A CN 110818451 A CN110818451 A CN 110818451A
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- light
- slurry
- transmitting ceramic
- ceramic tile
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- 239000000919 ceramic Substances 0.000 title claims abstract description 79
- 239000002002 slurry Substances 0.000 title claims abstract description 67
- 238000002360 preparation method Methods 0.000 title description 10
- 239000004094 surface-active agent Substances 0.000 claims abstract description 26
- 239000004927 clay Substances 0.000 claims abstract description 23
- 229910052661 anorthite Inorganic materials 0.000 claims abstract description 17
- GWWPLLOVYSCJIO-UHFFFAOYSA-N dialuminum;calcium;disilicate Chemical compound [Al+3].[Al+3].[Ca+2].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] GWWPLLOVYSCJIO-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000002994 raw material Substances 0.000 claims abstract description 14
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 22
- 229910052742 iron Inorganic materials 0.000 claims description 11
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 8
- 229920000142 Sodium polycarboxylate Polymers 0.000 claims description 7
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 5
- 238000000498 ball milling Methods 0.000 claims description 5
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 2
- 239000000725 suspension Substances 0.000 description 4
- 239000013078 crystal Substances 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- 239000010977 jade Substances 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 239000007790 solid phase Substances 0.000 description 3
- 238000005303 weighing Methods 0.000 description 3
- 230000003796 beauty Effects 0.000 description 2
- 239000011449 brick Substances 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- -1 aluminosilicate compound Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000007641 inkjet printing Methods 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- BITYAPCSNKJESK-UHFFFAOYSA-N potassiosodium Chemical compound [Na].[K] BITYAPCSNKJESK-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 238000011895 specific detection Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/87—Ceramics
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/16—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
- C04B35/18—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay rich in aluminium oxide
- C04B35/195—Alkaline earth aluminosilicates, e.g. cordierite or anorthite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5025—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with ceramic materials
- C04B41/5037—Clay, Kaolin
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/349—Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
- C04B2235/447—Phosphates or phosphites, e.g. orthophosphate or hypophosphite
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Finishing Walls (AREA)
Abstract
The invention provides a bottom slurry for a light-transmitting ceramic tile, which comprises the following raw materials: clay, anorthite and surfactant. The primer for the light-transmitting ceramic tile not only has good high-temperature resistance, but also can effectively eliminate the influence of the traditional primer on the surface of the light-transmitting ceramic tile and improve the aesthetic property of the transparent ceramic.
Description
Technical Field
The disclosure relates to the technical field of ceramics, in particular to a primer for a light-transmitting ceramic tile and a preparation method thereof.
Background
As a decorative material, architectural ceramics has rich and beautiful surface patterns and good wear resistance and is popular with consumers, along with the rapid popularization of ink-jet printing technology, ceramic tiles with various colors gradually enter the visual field of people, such as a series of products like leather grain imitation, cloth grain imitation, natural marble imitation, jade imitation and the like, wherein the product like jade imitation provides higher requirements for the preparation process of the ceramic tiles, the jade product belongs to a light-transmitting product, and the traditional ceramic tiles show non-transparent characteristics due to crystal phase, air holes, impurities and the like, so the structure of the product is required to be adjusted, the crystal phase of the ceramic tile product is adjusted, the internal air holes are improved, the influence of the impurities is reduced, and the light-transmitting performance of the ceramic tiles is improved.
However, in the process of firing the light-transmitting ceramic product, in order to prevent the ceramic tile product from sticking the roller rod and affecting the brick shape, the back surface of the ceramic tile is often required to be coated with a layer of bottom paste, the high temperature resistance of the bottom paste for the ceramic is far superior to that of the ceramic tile, so that the influence of the sticking roller rod caused by the direct contact of the ceramic tile and the roller rod is effectively avoided, and the bottom paste used for the ceramic tile at present is mostly single oxide, such as aluminum oxide, magnesium oxide bottom paste and the like. However, for the light-transmitting ceramic tile, the primer paste of this type has no light transmittance and can block the light irradiation, when the primer paste is coated on the bottom surface of the ceramic tile, the back texture appears on the surface of the ceramic tile through the light irradiation, which seriously affects the beauty of the light-transmitting ceramic tile, and since the primer paste is adhered to the ceramic tile during the firing process and is troublesome to remove, the composition of the primer paste needs to be improved to prevent the influence on the beauty of the ceramic tile.
Disclosure of Invention
The invention aims to provide a primer for a light-transmitting ceramic tile and a preparation method thereof, so as to achieve the purpose of improving the attractiveness of transparent ceramic.
In order to realize the purpose, the technical scheme is as follows:
the base slurry for the light-transmitting ceramic tiles comprises the following raw materials: clay, anorthite and surfactant.
The total content of ferric oxide and titanium oxide contained in the clay is 0.1-0.5%.
The surfactant is a composition of sodium polycarboxylate and sodium tripolyphosphate.
The weight ratio of the added sodium polycarboxylate to the added sodium tripolyphosphate is (1-3): 1.
the base slurry for the light-transmitting ceramic tile comprises the following raw materials in parts by weight: 3-35 parts of clay, 65-95 parts of anorthite and 0.5-5 parts of surfactant.
The base slurry for the light-transmitting ceramic tile comprises the following raw materials in parts by weight: 5-30 parts of clay, 70-90 parts of anorthite and 0.5-2 parts of surfactant.
The preparation method of the primer for the light-transmitting ceramic tile is characterized by comprising the following specific steps:
(1) putting raw materials of the bottom slurry for the light-transmitting ceramic tile into a ball mill, and then adding water for mixing and ball milling to obtain slurry;
(2) and (4) after the obtained slurry is discharged, carrying out iron removal treatment to obtain the bottom slurry for the light-transmitting ceramic tile.
The method is characterized in that the solid content of the slurry is 50-60%.
The flow rate of the slurry is 30-90 s.
The fineness of the slurry is 0.1-0.8% of the residue of a 325-mesh sieve.
The beneficial effects of this disclosure are: the prime slurry for the light-transmitting ceramic tile and the preparation method thereof are provided, the anorthite used as the raw material in the prime slurry for the light-transmitting ceramic tile is an aluminosilicate compound, the service temperature of the prime slurry can reach more than 1400 ℃, the refractive index of the anorthite is close to that of potassium-sodium silicate glass, and the crystal phase of quartz is relatively close to that of quartz, so that when light passes through the ceramic tile, the loss of light refraction and reflection at the interface of the prime slurry and the ceramic tile is small, and the light can pass through the ceramic tile easily, thereby effectively avoiding the situation that the surface of the light-transmitting ceramic tile is provided with brick back marks, the clay and the surfactant used as the raw material in the prime slurry for the light-transmitting ceramic tile can effectively improve the suspension property of the prime slurry, and the clay can ensure that the prime slurry can be adhered to the back of the ceramic tile to prevent the ceramic tile from being adhered to a roller rod, the influence of the traditional primer on the surface of the transparent ceramic tile can be effectively eliminated, and the attractiveness of the transparent ceramic tile is improved.
Detailed Description
The following steps are only used for illustrating the technical scheme of the disclosure and are not limited; although the present disclosure has been described in detail with reference to the foregoing steps, those of ordinary skill in the art will understand that: the technical solutions recorded in the foregoing steps may still be modified, or some or all of the technical features may be equivalently replaced; and such modifications or substitutions do not depart from the scope of the respective technical solutions of the steps of the present disclosure.
Example 1
The base slurry for the light-transmitting ceramic tile comprises the following raw materials in parts by weight: 30 parts of clay, 70 parts of anorthite and 0.5 part of surfactant, wherein the surfactant is sodium polycarboxylate and sodium tripolyphosphate, and the weight ratio of the surfactant to the total weight of the clay is 1: 1, and the content of iron oxide and titanium oxide in the clay is 0.45 percent.
A preparation method of prime slurry for a light-transmitting ceramic tile comprises the following specific operation steps:
(1) weighing 30 parts of clay, 70 parts of anorthite and 0.5 part of surfactant, placing the materials in a ball mill, adding a certain amount of water, mixing and ball-milling to obtain slurry,
(2) discharging the obtained slurry, and then carrying out iron removal treatment through an iron removal groove provided with an iron removal rod to obtain the bottom slurry for the light-transmitting ceramic tile, wherein the solid phase content of the slurry is 50%, the fineness of the slurry is controlled to be 325 meshes, the screen residue is 0.7%, and the flow rate of the slurry is 30 s.
Example 2
The base slurry for the light-transmitting ceramic tile comprises the following raw materials in parts by weight: 10 parts of clay, 90 parts of anorthite and 2 parts of surfactant, wherein the surfactant is sodium polycarboxylate and sodium tripolyphosphate, and the weight ratio of the surfactant to the surfactant is 3: 1, and the content of iron oxide and titanium oxide in the clay is 0.35 percent.
A preparation method of prime slurry for a light-transmitting ceramic tile comprises the following specific operation steps:
(1) weighing 10 parts of clay, 90 parts of anorthite and 2 parts of surfactant, placing the clay, 90 parts of anorthite and 2 parts of surfactant in a ball mill, adding a certain amount of water, mixing and ball-milling to obtain slurry,
(2) discharging the obtained slurry, and then carrying out iron removal treatment through an iron removal groove provided with an iron removal rod to obtain the bottom slurry for the light-transmitting ceramic tile, wherein the solid phase content of the slurry is 60%, the fineness of the slurry is controlled to be 325 meshes, the screen residue is 0.6%, and the flow rate of the slurry is 90 s.
Example 3
The base slurry for the light-transmitting ceramic tile comprises the following raw materials in parts by weight: 20 parts of clay, 80 parts of anorthite and 1.5 parts of surfactant, wherein the surfactant is sodium polycarboxylate and sodium tripolyphosphate, and the weight ratio of the surfactant to the surfactant is 2: 1, and the content of iron oxide and titanium oxide in the clay is 0.48 percent.
A preparation method of prime slurry for a light-transmitting ceramic tile comprises the following specific operation steps:
(1) weighing 20 parts of clay, 80 parts of anorthite and 1.5 parts of surfactant, placing the clay, the anorthite and the surfactant in a ball mill, adding a certain amount of water, mixing and ball-milling to obtain slurry,
(2) discharging the obtained slurry, and then carrying out iron removal treatment through an iron removal groove provided with an iron removal rod to obtain the bottom slurry for the light-transmitting ceramic tile, wherein the solid phase content of the slurry is 55%, the fineness of the slurry is controlled to be 325 meshes, the screen residue is 0.6%, and the flow rate of the slurry is 60 s.
Example 4
The suspension stability and the high temperature resistance of the bottom slurry for the light-transmitting ceramic tile prepared in the embodiment 1-3 are detected, then the bottom slurry for the light-transmitting ceramic tile prepared in the embodiment 1-3 is applied to the transparent ceramic tile, then the common magnesium oxide bottom slurry and the common aluminum oxide bottom slurry are respectively applied to the same transparent ceramic tile as a comparative example, the whiteness of the transparent ceramic tile before the bottom slurry is used and the whiteness of the transparent ceramic tile after the bottom slurry is used are detected, the specific detection results are shown in the table 1, and it can be seen that the bottom slurry for the light-transmitting ceramic tile prepared in the embodiment 1-3 has good slurry suspension stability, can resist high temperature, has good transparency, does not influence the whiteness of the light-transmitting ceramic tile, and can improve the aesthetic property of the transparent ceramic tile.
TABLE 1 detection results of suspension stability and high temperature resistance of the prime slurry for the light-transmitting ceramic tile
Claims (10)
1. The primer slurry for the light-transmitting ceramic tile is characterized by comprising the following raw materials: clay, anorthite and surfactant.
2. The primer paste for light-transmitting ceramic tiles as claimed in claim 1, wherein the clay contains iron oxide and titanium oxide in a total amount of 0.1% to 0.5%.
3. The primer paste for light-transmitting ceramic tiles as claimed in claim 1, wherein the surfactant is a combination of sodium polycarboxylate and sodium tripolyphosphate.
4. The primer paste for light-transmitting ceramic tiles as claimed in claim 3, wherein the weight ratio of the added sodium polycarboxylate to the sodium tripolyphosphate is (1-3): 1.
5. the bottom slurry for the light-transmitting ceramic tiles as claimed in claim 1, wherein the added parts by weight of the raw materials of the bottom slurry for the light-transmitting ceramic tiles are as follows: 3-35 parts of clay, 65-95 parts of anorthite and 0.5-5 parts of surfactant.
6. The bottom slurry for the light-transmitting ceramic tiles as claimed in claim 5, wherein the added parts by weight of the raw materials of the bottom slurry for the light-transmitting ceramic tiles are as follows: 5-30 parts of clay, 70-90 parts of anorthite and 0.5-2 parts of surfactant.
7. The method for preparing the primer slurry for the light-transmitting ceramic tile as claimed in any one of claims 1 to 6, wherein the method comprises the following specific steps:
(1) putting raw materials of the bottom slurry for the light-transmitting ceramic tile into a ball mill, and then adding water for mixing and ball milling to obtain slurry;
(2) and (4) after the obtained slurry is discharged, carrying out iron removal treatment to obtain the bottom slurry for the light-transmitting ceramic tile.
8. The method for preparing the primer slurry for light-transmitting ceramic tiles as claimed in claim 7, wherein the slurry has a solid content of 50-60%.
9. The method for preparing a primer paste for light-transmitting ceramic tiles as claimed in claim 7, wherein the flow rate of the paste is 30-90 s.
10. The method for preparing the primer slurry for the light-transmitting ceramic tile as claimed in claim 7, wherein the fineness of the slurry is 325 mesh with 0.1-0.8% of screen residue.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911182885.0A CN110818451B (en) | 2019-11-27 | 2019-11-27 | Primer slurry for light-transmitting ceramic tile and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911182885.0A CN110818451B (en) | 2019-11-27 | 2019-11-27 | Primer slurry for light-transmitting ceramic tile and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
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| CN110818451A true CN110818451A (en) | 2020-02-21 |
| CN110818451B CN110818451B (en) | 2022-02-01 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113233905A (en) * | 2021-05-24 | 2021-08-10 | 重庆唯美陶瓷有限公司 | Preparation method of ceramic tile and ceramic tile |
| CN113582708A (en) * | 2021-08-23 | 2021-11-02 | 佛山市东鹏陶瓷有限公司 | Formula and preparation process of rock plate bottom slurry |
| CN114213134A (en) * | 2021-12-23 | 2022-03-22 | 新明珠集团股份有限公司 | Brick bottom slurry and preparation method and application thereof |
| CN114671611A (en) * | 2022-04-08 | 2022-06-28 | 蒙娜丽莎集团股份有限公司 | Ceramic rock plate bottom slurry for preventing rod nail from being lifted by roller rod and application thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113233905A (en) * | 2021-05-24 | 2021-08-10 | 重庆唯美陶瓷有限公司 | Preparation method of ceramic tile and ceramic tile |
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| CN114213134A (en) * | 2021-12-23 | 2022-03-22 | 新明珠集团股份有限公司 | Brick bottom slurry and preparation method and application thereof |
| CN114671611A (en) * | 2022-04-08 | 2022-06-28 | 蒙娜丽莎集团股份有限公司 | Ceramic rock plate bottom slurry for preventing rod nail from being lifted by roller rod and application thereof |
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| Publication number | Publication date |
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| CN110818451B (en) | 2022-02-01 |
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