CN110803750A - Preparation method of trace element circulation enhancing device - Google Patents
Preparation method of trace element circulation enhancing device Download PDFInfo
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- CN110803750A CN110803750A CN201911085525.9A CN201911085525A CN110803750A CN 110803750 A CN110803750 A CN 110803750A CN 201911085525 A CN201911085525 A CN 201911085525A CN 110803750 A CN110803750 A CN 110803750A
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/68—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/283—Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
- C02F2101/203—Iron or iron compound
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
- C02F2101/206—Manganese or manganese compounds
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- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Water Treatment By Sorption (AREA)
Abstract
The invention relates to the field of water purification, in particular to a preparation method of a trace element circulation enhancing device. The method comprises the following steps: step 1, preparing a circulating ball capable of releasing trace elements; and 2, packaging the circulating ball into an access body with an accommodating cavity. The middle of the access body is provided with a cavity for accommodating a circulating ball, the access body is provided with a water inlet channel and a water outlet channel for water inlet and outlet, and the water inlet channel and the water outlet channel are connected with the cavity in a general way; a plurality of circulating balls are arranged in the cavity, and the diameter of each circulating ball is larger than that of the water inlet channel and the water outlet channel. After water enters the cavity from the water inlet channel, the circulating ball in the cavity can purify water quality on one hand, and on the other hand, water flow impacts the circulating ball to enable the circulating ball to release partial minerals and trace elements.
Description
Technical Field
The invention relates to the field of water purification, in particular to a preparation method of a trace element circulation enhancing device.
Background
Tap water drunk by urban residents at present generates a large amount of scale, which indicates that the water also contains a large amount of impurities, and if the tap water is drunk for a long time, the tap water can possibly influence the health of the body.
The prior patent discloses a ternary composite water purification filter element and a preparation method thereof (CN201810423112.6), which comprises the following steps: annealing the coconut peel to obtain porous carbon powder; reacting chitosan with chloroacetic acid and methacrylamide in sequence to obtain modified chitosan; carrying out sealing reaction on organic titanate, organic silicate and porous carbon powder to obtain modified porous carbon; compounding the modified chitosan, the modified porous carbon and the silane coupling agent to obtain a ternary composite water purifying agent, mixing the ternary composite water purifying agent, PP resin and sodium bicarbonate, casting and molding, cooling and solidifying to obtain the ternary composite water purifying filter element. According to the invention, the porous carbon, the grafted amphoteric chitosan and the modified titanium dioxide are compounded, so that the water purification filter element integrates the functions of adsorption, flocculation, catalytic degradation and the like, thereby achieving the effect of purifying water in multiple directions.
The prior art can play the effect of filtration, purification aquatic impurity, and nevertheless to the less insoluble substance or heavy metal particle removal effect relatively poor, and prior art only plays primary filtration moreover, does not have the requirement in the aspect of the nutrition equilibrium of human deeper.
Disclosure of Invention
In view of the above, the invention provides a method for manufacturing a trace element circulation enhancing device, and according to the method, after water enters a cavity from a water inlet channel, a circulation ball in the cavity can purify water quality on one hand, and on the other hand, water flow impacts the circulation ball, so that part of minerals and trace elements can be released by the circulation ball.
In order to achieve the purpose, the invention adopts the following technical scheme:
a method of making a trace element circulation enhancement device, comprising:
and 2, packaging the circulating ball into an access body with an accommodating cavity.
Preferably, in step 1, the method for preparing the circulating ball comprises:
s1, weighing the following raw materials in parts by weight: 10-18 parts of activated carbon powder, 8-15 parts of medical stone powder, 5-10 parts of seaweed powder, 5-10 parts of fishbone powder, 3-10 parts of binder, 3-5 parts of dispersant and 30-50 parts of pure water;
s2, placing the seaweed meal and the fishbone meal into pure water, and performing ultrasonic dispersion treatment twice to obtain a mixture a;
s3, adding activated carbon powder, medical stone powder, a binder and a dispersant into the mixture a, and stirring and mixing uniformly to obtain a mixture b;
s4, placing the mixture b in a mould to prepare a spherical blank, and drying and forming;
and S5, sintering the dried and molded blank to obtain the circulating ball.
Further, in S1, weighing the following raw materials in parts by weight: 12 parts of activated carbon powder, 8 parts of medical stone powder, 6 parts of seaweed powder, 5 parts of fishbone powder, 5 parts of binder, 3.5 parts of dispersant and 30 parts of pure water.
Further, in S2, the parameters of the ultrasonic dispersion treatment are the same, the interval between the ultrasonic dispersion treatment and the ultrasonic dispersion treatment is 20-40 min, the power of the ultrasonic dispersion treatment is 500-1000W, the frequency is 40-100 kHz, and the time is 5-10 min.
Further, in S3, the stirring speed is set to be 500-800 r/m, and the time is 8-10 min.
Further, in S4, the drying temperature is 80-100 ℃ and the drying time is 1-3 h.
Further, in S5, the sintering temperature is stepped heating sintering, the first sintering temperature is 100-300 ℃ and the time is 30-60 min, and the second sintering temperature is 300-600 ℃ and the time is 60-180 min.
Further, the circulating ball is subjected to a quenching treatment immediately after the sintering is completed.
Furthermore, a cavity used for containing the circulating ball is arranged in the middle of the access body, a water inlet channel and a water outlet channel used for water inlet and water outlet are arranged on the access body, and the water inlet channel and the water outlet channel are connected with the cavity in a communicating mode.
Furthermore, a plurality of circulating balls are arranged in the cavity, and the diameter of each circulating ball is larger than that of the water inlet channel and that of the water outlet channel.
The invention has the beneficial effects that: the circulating ball is prepared by taking activated carbon powder, medical stone powder, seaweed powder and fishbone powder as main raw materials, wherein the activated carbon contains a large number of micropores and has huge and non-specific surface area, so that the chromaticity and odor can be effectively removed, most organic pollutants and certain inorganic matters in secondary effluent can be removed, and the secondary effluent contains certain toxic heavy metals; the medical stone can also play a role in purifying water quality and adsorbing bacteria, natural minerals contained in the medical stone are easy to release from countless small holes on the medical stone, and the minerals such as calcium, iron, sodium and the like emitted by the medical stone can improve drinking water; by adding the seaweed meal and the fishbone meal, the seaweed meal and the fishbone meal contain rich nutrient substances, calcium and trace elements such as potassium, iron, calcium, phosphorus, iodine, selenium, cobalt and the like, and flowing water passes through the circulating ball, and can bring out a small amount of the elements, so that elements required by a human body can be well balanced.
Drawings
FIG. 1 is a schematic structural diagram of the present invention.
Detailed Description
The technical solutions in the present invention will be described clearly and completely with reference to the following embodiments, and it should be understood that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
A method of making a trace element circulation enhancement device, comprising:
and 2, packaging the circulating ball into an access body with an accommodating cavity.
Preferably, as shown in fig. 1, a cavity 2 for accommodating a recirculating ball is arranged in the middle of the access body 1, a water inlet channel 3 and a water outlet channel 4 for water inlet and outlet are arranged on the access body 1, and both the water inlet channel 3 and the water outlet channel 4 are connected with the cavity 2 in a general manner.
A plurality of circulating balls 5 are arranged in the cavity 2, and the diameters of the circulating balls 5 are larger than those of the water inlet channel 3 and the water outlet channel 4.
After water enters the cavity from the water inlet channel, impact is caused to the circulating ball by water flow, and the efficiency of releasing minerals and trace elements by the circulating ball can be improved when the circulating ball moves in the cavity.
Example 1
In example 1, a method for preparing a circulating ball includes:
s1, weighing the following raw materials in parts by weight: 12 parts of activated carbon powder, 8 parts of medical stone powder, 6 parts of seaweed powder, 5 parts of fishbone powder, 5 parts of binder, 3.5 parts of dispersant and 30 parts of pure water;
s2, placing the seaweed meal and the fishbone meal into pure water, and performing ultrasonic dispersion treatment twice to obtain a mixture a, wherein the ultrasonic parameters are 600W in power, 50kHz in frequency, 5min in time, and 20min in the middle;
s3, adding activated carbon powder, medical stone powder, a binder and a dispersant into the mixture a, stirring at the rotating speed of 500r/m for 9min, and uniformly mixing to obtain a mixture b;
s4, placing the mixture b in a mould to prepare a spherical blank, and drying and forming at the drying temperature of 80 ℃ for 2.5 hours;
and S5, sintering the dried and molded blank, wherein the first sintering temperature is 120 ℃ and the time is 55min, and the second sintering temperature is 450 ℃ and the time is 120 min.
Example 2
In example 2, a method for preparing a recirculating ball includes:
s1, weighing the following raw materials in parts by weight: 14 parts of activated carbon powder, 10 parts of medical stone powder, 6 parts of seaweed powder, 5 parts of fishbone powder, 5 parts of binder, 3.5 parts of dispersant and 30 parts of pure water;
s2, placing the seaweed meal and the fishbone meal into pure water, and performing ultrasonic dispersion treatment twice to obtain a mixture a, wherein the ultrasonic parameters are 700W in power, 60kHz in frequency, 6min in time and 25min in the middle;
s3, adding activated carbon powder, medical stone powder, a binder and a dispersant into the mixture a, stirring at the rotating speed of 600r/m for 8min, and uniformly mixing to obtain a mixture b;
s4, placing the mixture b in a mold to prepare a spherical blank, and drying and molding at the drying temperature of 90 ℃ for 2.5 hours;
and S5, sintering the dried and molded blank, wherein the first sintering temperature is 150 ℃ and the time is 50min, and the second sintering temperature is 500 ℃ and the time is 120 min.
Example 3
In example 3, a method for preparing a recirculating ball includes:
s1, weighing the following raw materials in parts by weight: 16 parts of activated carbon powder, 15 parts of medical stone powder, 8 parts of seaweed powder, 10 parts of fishbone powder, 8 parts of binder, 4 parts of dispersant and 35 parts of pure water;
s2, placing the seaweed meal and the fishbone meal into pure water, and performing ultrasonic dispersion treatment twice to obtain a mixture a, wherein the ultrasonic parameters are 800W, the frequency is 70kHz, the time is 8min, and the interval between the ultrasonic parameters is 30 min;
s3, adding activated carbon powder, medical stone powder, a binder and a dispersant into the mixture a, stirring at the rotating speed of 700r/m for 8min, and uniformly mixing to obtain a mixture b;
s4, placing the mixture b in a mold to prepare a spherical blank, and drying and molding at the drying temperature of 95 ℃ for 2 hours;
and S5, sintering the dried and molded blank, wherein the first sintering temperature is 200 ℃ for 50min, and the second sintering temperature is 650 ℃ for 120 min.
In the embodiment, the liquid medium is broken through the ultrasonic dispersion effect to form the micro-bubbles, the micro-bubbles further become cavitation bubbles, and the bubbles can be re-dissolved in the liquid medium on one hand and can float upwards and disappear on the other hand, so that the seaweed meal and the fishbone meal can be fully dispersed and fused with the liquid medium.
Test example 1
Taking city tap water, using a JC-SC-1Y type water quality rapid test box to detect DPD residual chlorine, suspended matters, nickel and TDS values, calcium, phosphorus, copper, chromium, manganese, iron and other data of the tap water, subpackaging the tap water into three water tanks provided with circulating pumps, respectively packaging circulating balls prepared in the above examples 1-3 into three access bodies, connecting the circulating pumps and the access bodies by pipelines, and detecting the water quality treated by the circulating balls after circulating for one hour, wherein the detection data are shown in Table 1.
TABLE 1
As can be seen from the data in Table 1, after 1 hour of treatment of the circulating ball in the device, compared with the prior test, the contents of residual chlorine, suspended matters and heavy metal nickel in tap water are reduced to different degrees, the TDS value representing the water purity is also greatly reduced, and the contents of trace elements such as calcium, phosphorus, copper, chromium, manganese and iron in the water are improved to a certain degree, which shows that the circulating ball can play a role in filtering and purifying the water quality, and meanwhile, a small amount of trace elements can be released by continuously flowing the water.
Finally, it should be noted that the above-mentioned preferred embodiments of the present invention are provided merely to help illustrate the present invention. The preferred embodiments are not intended to be exhaustive or to limit the invention to the precise embodiments disclosed. Obviously, many modifications and variations are possible in light of the above teaching. The embodiments were chosen and described in order to best explain the principles of the invention and the practical application, to thereby enable others skilled in the art to best utilize the invention. The invention is limited only by the claims and their full scope and equivalents.
Claims (10)
1. A method for preparing a trace element circulation enhancing device is characterized by comprising the following steps:
step 1, preparing a circulating ball capable of releasing trace elements;
and 2, packaging the circulating ball into an access body with an accommodating cavity.
2. The method of claim 1, wherein the method of preparing the circulation ball in step 1 comprises:
s1, weighing the following raw materials in parts by weight: 10-18 parts of activated carbon powder, 8-15 parts of medical stone powder, 5-10 parts of seaweed powder, 5-10 parts of fishbone powder, 3-10 parts of binder, 3-5 parts of dispersant and 30-50 parts of pure water;
s2, placing the seaweed meal and the fishbone meal into pure water, and performing ultrasonic dispersion treatment twice to obtain a mixture a;
s3, adding activated carbon powder, medical stone powder, a binder and a dispersant into the mixture a, and stirring and mixing uniformly to obtain a mixture b;
s4, placing the mixture b in a mould to prepare a spherical blank, and drying and forming;
and S5, sintering the dried and molded blank to obtain the circulating ball.
3. The method for preparing a trace element circulation enhancing device according to claim 2, wherein in S1, the raw materials are weighed according to the following parts by weight: 12 parts of activated carbon powder, 8 parts of medical stone powder, 6 parts of seaweed powder, 5 parts of fishbone powder, 5 parts of binder, 3.5 parts of dispersant and 30 parts of pure water.
4. The method of claim 2, wherein in S2, the two ultrasonic dispersion treatment parameters are the same, the interval between two ultrasonic dispersion treatment parameters is 20-40 min, the ultrasonic parameters are set to 500-1000W, the frequency is 40-100 kHz, and the time is 5-10 min.
5. The method for preparing a trace element circulation enhancing device according to claim 2, wherein in S3, the stirring speed is set to 500-800 r/m for 8-10 min.
6. The method of claim 2, wherein the drying temperature is 80-100 ℃ and the drying time is 1-3 hours in S4.
7. The method for preparing a trace element circulation enhancing device according to claim 2, wherein in S5, the sintering temperature is stepwise heating sintering, the first sintering temperature is 100-300 ℃ for 30-60 min, and the second sintering temperature is 300-600 ℃ for 60-180 min.
8. The method as claimed in claim 2, wherein the circulating ball is quenched immediately after sintering.
9. The method for preparing a trace element circulation enhancing device according to claim 1, wherein a cavity for accommodating a circulation ball is arranged in the middle of the access body, a water inlet channel and a water outlet channel for water inlet and outlet are arranged on the access body, and the water inlet channel and the water outlet channel are connected with the cavity in a general way.
10. The method of claim 9, wherein the cavity has a plurality of circulation balls, and the circulation balls have a diameter larger than the diameter of the inlet and outlet channels.
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| CN201911085525.9A CN110803750A (en) | 2019-11-08 | 2019-11-08 | Preparation method of trace element circulation enhancing device |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115321739A (en) * | 2022-08-25 | 2022-11-11 | 福建环球之源环保科技有限公司 | Preparation method and system of super-energy activated water |
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| CN101264400A (en) * | 2008-05-05 | 2008-09-17 | 郗盟 | Mineralizing and filtering device for water used for bathing and bathing equipment |
| CN105271499A (en) * | 2014-06-17 | 2016-01-27 | 叶纨 | Mineralized balls used for increasing content of dissolved oxygen in water, and application method thereof |
| CN105622067A (en) * | 2016-02-17 | 2016-06-01 | 广西大学 | Negative-ion water purification ceramic ball and method for preparing same |
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2019
- 2019-11-08 CN CN201911085525.9A patent/CN110803750A/en active Pending
Patent Citations (5)
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| US20080038552A1 (en) * | 2004-03-03 | 2008-02-14 | Andreas Noack | Nanoscale And Supersaturated Solutions Of Mineral Substance And Trace Elements And A Process For The Production Of Nanoparticles, Mixtures Of Nanoparticles, Nanoscale Solutions, And Supersaturated Solutions In General |
| CN101016177A (en) * | 2006-02-10 | 2007-08-15 | 南京林业大学 | Purification and alimentation health care composition containing bamboo charcoal, preparing method and application thereof |
| CN101264400A (en) * | 2008-05-05 | 2008-09-17 | 郗盟 | Mineralizing and filtering device for water used for bathing and bathing equipment |
| CN105271499A (en) * | 2014-06-17 | 2016-01-27 | 叶纨 | Mineralized balls used for increasing content of dissolved oxygen in water, and application method thereof |
| CN105622067A (en) * | 2016-02-17 | 2016-06-01 | 广西大学 | Negative-ion water purification ceramic ball and method for preparing same |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115321739A (en) * | 2022-08-25 | 2022-11-11 | 福建环球之源环保科技有限公司 | Preparation method and system of super-energy activated water |
| CN115321739B (en) * | 2022-08-25 | 2023-10-27 | 福建环球之源环保科技有限公司 | Preparation method and system of super-energy activated water |
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Application publication date: 20200218 |