CN110791389A - Environment-friendly adhesive remover and preparation method and application thereof - Google Patents
Environment-friendly adhesive remover and preparation method and application thereof Download PDFInfo
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- CN110791389A CN110791389A CN201910944004.8A CN201910944004A CN110791389A CN 110791389 A CN110791389 A CN 110791389A CN 201910944004 A CN201910944004 A CN 201910944004A CN 110791389 A CN110791389 A CN 110791389A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
- C11D3/184—Hydrocarbons unsaturated
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
Abstract
The invention relates to the field of adhesive removing agents, and provides an environment-friendly adhesive removing agent which at least comprises the following raw materials in parts by weight: 55-75 parts of limonene, 25-45 parts of a deodorized hydrocarbon solvent, 5-20 parts of a penetrating agent, 5-10 parts of a surfactant, 5-15 parts of dibasic acid ester and 30-80 parts of water. Also provides a preparation method and application of the environment-friendly adhesive remover.
Description
Technical Field
The invention relates to the field of degumming agents, in particular to an environment-friendly degumming agent and a preparation method and application thereof.
Background
In recent years, with the continuous development of high-speed motor cars in China, due to the wide application of a large number of non-setting adhesive products and chewing gum, workers or passengers can paste the non-setting adhesive with the motor cars anywhere in the cars, and the residual adhesive after the chewing gum is used falls on the floor, so that the pollution to the car body is caused. To keep the interior of the car clean, the glue stains need to be removed.
The existing various cleaning agents and adhesive removing agents have large odor, harmful Volatile Organic Compounds (VOC) to human bodies are high, the existing products of the adhesive removing agents which are usually adopted have large odor, the content of the harmful Volatile Organic Compounds (VOC) to the human bodies is high, the using amount of the existing various adhesives is very high, and a large amount of contact and use cause great damage to the health of people for a long time, so that the adhesive removing composition which not only has excellent adhesive removing effect but also is more important to be safe, environment-friendly and high in efficiency and has excellent comprehensive performance needs to be developed. The existing adhesive remover has two main systems: the traditional glue removing system is formed by a solvent composition containing flammable and explosive components and a strong acid and strong base system in combination with a solvent. The existing products of the Chinese degumming agent are mainly compounded by a plurality of solvents, although the product has certain degumming capability, the product contains flammable and explosive solvents such as methanol, ethanol, isopropanol and the like, and is unsafe to use and not environment-friendly. Moreover, for example, the degelling agent with strong acidity and alkalinity is easy to cause surface damage of the material; the common solvent-type degumming agent is high in toxicity due to the addition of raw materials such as benzene, xylene and dichloromethane, secondary pollution is caused to the environment after the solvent-type degumming agent is used, and operators are injured.
Disclosure of Invention
In order to solve the technical problems, the first aspect of the invention provides an environment-friendly adhesive remover, which comprises the following raw materials in parts by weight: 55-75 parts of limonene, 25-45 parts of a deodorized hydrocarbon solvent, 5-20 parts of a penetrating agent, 5-10 parts of a surfactant, 5-15 parts of dibasic acid ester and 30-80 parts of water.
As a preferable technical scheme, the environment-friendly degumming agent comprises, by weight, 60-70 parts of limonene, 30-40 parts of a deodorized hydrocarbon solvent, 10-15 parts of a penetrating agent, 7 parts of a surfactant, 10 parts of dibasic acid ester and 50-70 parts of water.
As a preferable technical scheme, the environment-friendly degumming agent comprises, by weight, at least 65 parts of limonene, 35 parts of a deodorized hydrocarbon solvent, 12 parts of a penetrating agent, 7 parts of a surfactant, 10 parts of dibasic acid ester and 60 parts of water.
In a preferred embodiment, the penetrating agent in the present invention is selected from one or more of butyl acetate, dimethyl carbonate, ethylene glycol methyl ether, propylene glycol methyl ether, triethylene glycol methyl ether, ethylene glycol monoethyl ether, diethylene glycol monobutyl ether, ethylene glycol butyl ether, tripropylene glycol methyl ether, dipropylene glycol butyl ether, dipropylene glycol propyl ether, n-octanol, benzyl alcohol, ethylene glycol, propylene glycol, and polyethylene glycol.
As a preferable technical solution, the raw material in the present invention further includes polyether derivatives having amino groups; the addition amount of the polyether derivative with amino is 5-15% of the weight of the limonene.
As a preferred technical scheme, the polyether derivative with amino groups in the invention is 4-aminobutyraldehyde diethyl acetal and/or ethylene glycol di (3-aminopropyl) ether.
As a preferred technical solution, the weight ratio of 4-aminobutyraldehyde diethyl acetal to ethylene glycol di (3-aminopropyl) ether in the present invention is 1: (0.2-1.5).
As a preferred technical solution, the weight ratio of 4-aminobutyraldehyde diethyl acetal to ethylene glycol di (3-aminopropyl) ether in the present invention is 1: (0.5-1).
The second aspect of the invention provides a preparation method of the environment-friendly degumming agent, which at least comprises the following steps:
(1) adding limonene, a penetrating agent and a deodorized hydrocarbon solvent into a reaction kettle, stirring, heating to 50-80 ℃ while stirring, and then preserving heat and stirring for 30-60 minutes; (2) adding the rest raw materials in sequence, and continuously stirring for 15-45 minutes; (3) standing for defoaming for 5-12 hr after stirring, and packaging.
The third aspect of the invention provides an application of the environment-friendly adhesive remover, which is applied to removing residual adhesive and dirt on the surfaces of plastic plates, glass, ceramics, marble and metal.
Compared with the prior art, the invention has the following beneficial effects:
the invention provides an environment-friendly adhesive remover, which mainly adopts limonene and water as basic raw materials, the limonene is used as a pure natural active extract, the adhesive remover is safe and environment-friendly, has aromatic smell, can help to remove surface stains, is an excellent solvent for removing adhesives, adopts water, a high-boiling dearomatization solvent and the limonene as main components to carry out common use, has the advantages of difficult volatilization, difficult combustion and ignition, small harm to the environment, no chlorine and benzene, low toxicity, environmental protection and health. The adhesive remover disclosed by the invention is wide in application range, has a very effective adhesive removing effect on curing adhesives on various surfaces, and cannot be corroded after being used for multiple times.
The technical features, content and advantages of the present invention will be more readily understood by reference to the following detailed description.
Detailed Description
Unless otherwise indicated, implied from the context, or customary in the art, all parts and percentages herein are by weight and the testing and characterization methods used are synchronized with the filing date of the present application. To the extent that a definition of a particular term disclosed in the prior art is inconsistent with any definitions provided herein, the definition of the term provided herein controls.
The technical features of the technical solutions provided by the present invention are further clearly and completely described below with reference to the specific embodiments, and the scope of protection is not limited thereto.
The words "preferred", "preferably", "more preferred", and the like, in the present invention, refer to embodiments of the invention that may provide certain benefits, under certain circumstances. However, other embodiments may be preferred, under the same or other circumstances. Furthermore, the recitation of one or more preferred embodiments does not imply that other embodiments are not useful, nor is it intended to exclude other embodiments from the scope of the invention. The sources of components not mentioned in the present invention are all commercially available.
The invention provides an environment-friendly adhesive remover, which at least comprises the following raw materials in parts by weight: 55-75 parts of limonene, 25-45 parts of a deodorized hydrocarbon solvent, 5-20 parts of a penetrating agent, 5-10 parts of a surfactant, 5-15 parts of dibasic acid ester and 30-80 parts of water.
In some preferred embodiments, the raw materials of the environment-friendly degumming agent at least comprise, by weight, 60-70 parts of limonene, 30-40 parts of a deodorized hydrocarbon solvent, 10-15 parts of a penetrating agent, 7 parts of a surfactant, 10 parts of a dibasic acid ester and 50-70 parts of water.
In some more preferred embodiments, the raw material of the environment-friendly degumming agent at least comprises, by weight, 65 parts of limonene, 35 parts of a deodorized hydrocarbon solvent, 12 parts of a penetrating agent, 7 parts of a surfactant, 10 parts of a dibasic acid ester and 60 parts of water.
Limonene
In some embodiments, the limonene is D-limonene.
Deodorized hydrocarbon solvent
In some embodiments, the deodorized hydrocarbon solvent has a density of 0.766-0.827g/cm3(ii) a The primary distillation temperature of the distillation range of the deodorized hydrocarbon solvent is 142-279 ℃; preferably, the deodorized hydrocarbon solvent has a density of 0.808g/cm3(ii) a The distillation range of the deodorized hydrocarbon solvent has a primary distillation temperature of 248 ℃.
Penetrant
In some embodiments, the osmotic agent is selected from the group consisting of butyl acetate, dimethyl carbonate, ethylene glycol methyl ether, propylene glycol methyl ether, diethylene glycol methyl ether, triethylene glycol methyl ether, ethylene glycol monoethyl ether, diethylene glycol monobutyl ether, ethylene glycol butyl ether, tripropylene glycol methyl ether, dipropylene glycol butyl ether, dipropylene glycol propyl ether, n-octanol, benzyl alcohol, ethylene glycol, propylene glycol, polyethylene glycol, and combinations of one or more thereof; preferably, the penetrant is selected from one or more of ethylene glycol methyl ether, propylene glycol methyl ether, triethylene glycol methyl ether, ethylene glycol monoethyl ether, diethylene glycol monobutyl ether, ethylene glycol butyl ether, tripropylene glycol methyl ether, dipropylene glycol butyl ether and dipropylene glycol propyl ether; more preferably, the penetrant is selected from one or more of ethylene glycol methyl ether, ethylene glycol butyl ether and tripropylene glycol methyl ether; further preferably, the penetrant is ethylene glycol monomethyl ether.
Surface active agent
In some embodiments, the surfactant is selected from coconut oil glycol amide, α -olefin sulfonate, sodium dodecyl benzene sulfonate, fatty alcohol polyoxyethylene ether sulfate, sodium dimethyl sulfonate, sodium diisooctyl succinate sulfonate, fatty alcohol polyoxyethylene ether, alkylphenol ethoxylates, span-60, span-80, tween, and a combination of one or more of fatty acid methyl ester ethoxylates, preferably, the surfactant is selected from coconut oil glycol amide, sodium dodecyl benzene sulfonate, sodium dimethyl sulfonate, sodium diisooctyl succinate sulfonate, fatty alcohol polyoxyethylene ether, and alkylphenol polyoxyethylene ether, and more preferably, the surfactant is selected from coconut oil glycol amide.
Dibasic acid ester
In some embodiments, the dibasic acid ester is selected from the group consisting of dimethyl succinate, dimethyl glutarate, dimethyl adipate, dimethyl malonate, dimethyl alpha-ketoglutarate, dimethyl propylmalonate, dimethyl suberate, dimethyl 4-oxopimelate, dimethyl sebacate, dimethyl 3-methylglutarate; preferably, the dibasic acid methyl ester monomer is selected from the group consisting of dimethyl succinate, dimethyl glutarate and dimethyl adipate.
In some embodiments, the ratio of dimethyl succinate, dimethyl glutarate and dimethyl adipate is 1: (0.5-1): (0.1-0.5); preferably, the ratio of dimethyl succinate, dimethyl glutarate and dimethyl adipate is 1: 0.8: 0.25.
polyether derivative having amino group
In some embodiments, the feedstock further comprises a polyether derivative bearing an amino group; the addition amount of the polyether derivative with amino is 5-15% of the mass of the limonene; preferably, the polyether derivative with amino groups is added in an amount of 12% by mass of limonene.
In some embodiments, the polyether derivative having an amino group is 4-aminobutyraldehyde diethyl ether and/or ethylene glycol di (3-aminopropyl) ether; preferably, the polyether derivatives having an amino group are 4-aminobutyraldehyde diethylene glycol and ethylene glycol di (3-aminopropyl) ether.
In some embodiments, the weight ratio of 4-aminobutyraldehyde diethyl acetal to ethylene glycol di (3-aminopropyl) ether is 1: (0.2-1.5).
In some preferred embodiments, the weight ratio of 4-aminobutyraldehyde diethyl acetal to ethylene glycol di (3-aminopropyl) ether is 1: (0.5-1); more preferably, the weight ratio of the 4-aminobutyraldehyde diethyl acetal to the ethylene glycol di (3-aminopropyl) ether is 1: 0.8.
the adhesive remover disclosed by the invention is wide in application range, has a very effective adhesive removing effect on curing adhesives on various surfaces, and cannot be corroded after being used for multiple times. The inventor finds that the addition of a proper amount of polyether derivative with amino groups can improve the application range of the adhesive remover, has very effective adhesive removing effect on various curing adhesives on surfaces, does not cause corrosion after being used for many times, and particularly has more excellent effect of compounding and using 4-aminobutyraldehyde diethylene glycol and ethylene glycol di (3-aminopropyl) ether.
The second aspect of the invention provides a preparation method of the environment-friendly degumming agent, which at least comprises the following steps:
(1) adding limonene, a penetrating agent and a deodorized hydrocarbon solvent into a reaction kettle, stirring, heating to 50-80 ℃ while stirring, and then preserving heat and stirring for 30-60 minutes; (2) adding the rest raw materials in sequence, and continuously stirring for 15-45 minutes; (3) standing for defoaming for 5-12 hr after stirring, and packaging.
In some preferred embodiments, the preparation method of the environment-friendly degumming agent at least comprises the following steps:
(1) adding limonene, a penetrating agent and a deodorized hydrocarbon solvent into a reaction kettle, stirring, heating to 60-75 ℃ while stirring, and then keeping the temperature and stirring for 40-50 minutes; (2) adding the rest raw materials in sequence, and continuously stirring for 25-40 minutes; (3) standing for defoaming for 7-10 hr after stirring, and packaging.
In some more preferred embodiments, the method for preparing the environment-friendly degumming agent at least comprises the following steps:
(1) adding limonene, a penetrating agent and a deodorized hydrocarbon solvent into a reaction kettle, stirring, heating to 65 ℃ while stirring, and then keeping the temperature and stirring for 45 minutes; (2) adding the rest raw materials in sequence, and continuously stirring for 30 minutes; (3) standing for defoaming for 8.5 hours after stirring is finished, and filtering to obtain the product.
The third aspect of the invention provides an application of the environment-friendly adhesive remover, which is applied to removing residual adhesive and dirt on the surfaces of plastic plates, glass, ceramics, marble and metal.
The present invention is described in detail below with reference to examples, which are provided for the purpose of further illustration only and are not to be construed as limiting the scope of the present invention, and the insubstantial modifications and adaptations thereof by those skilled in the art based on the teachings of the present invention will still fall within the scope of the present invention.
Example 1
The environment-friendly degumming agent comprises, by weight, 65 parts of D-limonene, 35 parts of a deodorized hydrocarbon solvent, 12 parts of a penetrating agent, 7 parts of a surfactant, 10 parts of dibasic acid ester and 60 parts of water.
The deodorized hydrocarbon solvent is D110 solvent, and is purchased from Shanghai Huishao chemical Co. The penetrating agent is ethylene glycol monomethyl ether. The surfactant is selected from coconut oil glycol amide. The dibasic acid methyl ester monomer is selected from the combination of dimethyl succinate, dimethyl glutarate and dimethyl adipate, and the proportion of the dimethyl succinate, the dimethyl glutarate and the dimethyl adipate is 1: 0.8: 0.25. the raw material also comprises polyether derivatives with amino; the addition amount of the polyether derivative with the amino group is 12 percent of the mass of the limonene, and the polyether derivative with the amino group is 4-aminobutyraldehyde diethylene glycol and ethylene glycol di (3-aminopropyl) ether. The weight ratio of the 4-aminobutyraldehyde diethyl acetal to the ethylene glycol di (3-aminopropyl) ether is 1: 0.8.
the preparation method of the environment-friendly degumming agent comprises the following steps: (1) adding limonene, a penetrating agent and a deodorized hydrocarbon solvent into a reaction kettle, stirring, heating to 65 ℃ while stirring, and then keeping the temperature and stirring for 45 minutes; (2) adding the rest raw materials in sequence, and continuously stirring for 30 minutes; (3) standing for defoaming for 8.5 hours after stirring is finished, and filtering to obtain the product.
Example 2
The environment-friendly degumming agent comprises, by weight, 55 parts of D-limonene, 25 parts of a deodorized hydrocarbon solvent, 5 parts of a penetrating agent, 5 parts of a surfactant, 5 parts of dibasic acid ester and 30 parts of water.
The deodorized hydrocarbon solvent is D80 solvent, and is purchased from Shanghai Huishao chemical Co. The penetrating agent is tripropylene glycol methyl ether. The surfactant is selected from sodium diisooctyl succinate sulfonate. The dibasic acid methyl ester monomer is selected from the combination of dimethyl succinate, dimethyl glutarate and dimethyl adipate, and the proportion of the dimethyl succinate, the dimethyl glutarate and the dimethyl adipate is 1: 0.5: 0.1. the raw material also comprises polyether derivatives with amino; the addition amount of the polyether derivative with the amino group is 5 percent of the mass of the limonene, and the polyether derivative with the amino group is 4-aminobutyraldehyde diethylene glycol and ethylene glycol di (3-aminopropyl) ether. The weight ratio of the 4-aminobutyraldehyde diethyl acetal to the ethylene glycol di (3-aminopropyl) ether is 1: 0.2.
the preparation method of the environment-friendly degumming agent comprises the following steps: (1) adding limonene, a penetrating agent and a deodorized hydrocarbon solvent into a reaction kettle, stirring, heating to 50 ℃ while stirring, and then keeping the temperature and stirring for 30 minutes; (2) adding the rest raw materials in sequence, and continuing stirring for 15 minutes; (3) standing for defoaming for 5 hours after stirring is finished, and filtering to obtain the product.
Example 3
The environment-friendly degumming agent comprises, by weight, 75 parts of D-limonene, 45 parts of a deodorized hydrocarbon solvent, 20 parts of a penetrating agent, 10 parts of a surfactant, 15 parts of dibasic acid ester and 80 parts of water.
The deodorized hydrocarbon solvent is D130 solvent, and is purchased from Shanghai Huishao chemical Co. The penetrating agent is ethylene glycol monobutyl ether. The surfactant is selected from alkylphenol ethoxylates. The dibasic acid methyl ester monomer is selected from the combination of dimethyl succinate, dimethyl glutarate and dimethyl adipate, and the proportion of the dimethyl succinate, the dimethyl glutarate and the dimethyl adipate is 1: 1: 0.5. the raw material also comprises polyether derivatives with amino; the addition amount of the polyether derivative with the amino group is 15 percent of the mass of the limonene, and the polyether derivative with the amino group is 4-aminobutyraldehyde diethylene glycol and ethylene glycol di (3-aminopropyl) ether. The weight ratio of the 4-aminobutyraldehyde diethyl acetal to the ethylene glycol di (3-aminopropyl) ether is 1: 1.5.
the preparation method of the environment-friendly degumming agent comprises the following steps: (1) adding limonene, a penetrating agent and a deodorized hydrocarbon solvent into a reaction kettle, stirring, heating to 80 ℃ while stirring, and then keeping the temperature and stirring for 60 minutes; (2) adding the rest raw materials in sequence, and continuing stirring for 45 minutes; (3) standing for defoaming for 12 hr after stirring, and filtering.
Example 4
The environment-friendly degumming agent comprises, by weight, 60 parts of D-limonene, 30 parts of a deodorized hydrocarbon solvent, 10 parts of a penetrating agent, 7 parts of a surfactant, 10 parts of dibasic acid ester and 50 parts of water.
The deodorized hydrocarbon solvent is D60 solvent, and is purchased from Shanghai Huishao chemical Co. The penetrating agent is n-octanol. The surfactant is selected from sodium dodecyl benzene sulfonate. The dibasic acid methyl ester monomer is selected from the combination of dimethyl succinate, dimethyl glutarate and dimethyl adipate, and the proportion of the dimethyl succinate, the dimethyl glutarate and the dimethyl adipate is 1: 0.8: 2.5. the raw material also comprises polyether derivatives with amino; the addition amount of the polyether derivative with the amino group is 12 percent of the mass of the limonene, and the polyether derivative with the amino group is 4-aminobutyraldehyde diethylene glycol and ethylene glycol di (3-aminopropyl) ether. The weight ratio of the 4-aminobutyraldehyde diethyl acetal to the ethylene glycol di (3-aminopropyl) ether is 1: 0.5.
the preparation method of the environment-friendly degumming agent comprises the following steps: (1) adding limonene, a penetrating agent and a deodorized hydrocarbon solvent into a reaction kettle, stirring, heating to 60 ℃ while stirring, and then keeping the temperature and stirring for 40 minutes; (2) adding the rest raw materials in sequence, and continuously stirring for 25 minutes; (3) standing for defoaming for 7 hours after stirring is finished, and filtering to obtain the product.
Example 5
The environment-friendly degumming agent comprises, by weight, 70 parts of D-limonene, 40 parts of a deodorized hydrocarbon solvent, 15 parts of a penetrating agent, 7 parts of a surfactant, 10 parts of dibasic acid ester and 70 parts of water.
The deodorized hydrocarbon solvent is D40 solvent, and is purchased from Shanghai Huishao chemical Co. The penetrating agent is n-octanol. The surfactant is selected from sodium dodecyl benzene sulfonate. The dibasic acid methyl ester monomer is selected from the combination of dimethyl succinate, dimethyl glutarate and dimethyl adipate, and the proportion of the dimethyl succinate, the dimethyl glutarate and the dimethyl adipate is 1: 0.8: 2.5. the raw material also comprises polyether derivatives with amino; the addition amount of the polyether derivative with the amino group is 12 percent of the mass of the limonene, and the polyether derivative with the amino group is 4-aminobutyraldehyde diethylene glycol and ethylene glycol di (3-aminopropyl) ether. The weight ratio of the 4-aminobutyraldehyde diethyl acetal to the ethylene glycol di (3-aminopropyl) ether is 1: 1.
the preparation method of the environment-friendly degumming agent comprises the following steps: (1) adding limonene, a penetrating agent and a deodorized hydrocarbon solvent into a reaction kettle, stirring, heating to 75 ℃ while stirring, and then keeping the temperature and stirring for 50 minutes; (2) adding the rest raw materials in sequence, and continuously stirring for 40 minutes; (3) standing for defoaming for 10 hr after stirring, and filtering.
Example 6
The environment-friendly degumming agent comprises, by weight, 65 parts of D-limonene, 35 parts of a deodorized hydrocarbon solvent, 12 parts of a penetrating agent, 7 parts of a surfactant, 10 parts of dibasic acid ester and 60 parts of water.
The deodorized hydrocarbon solvent is D110 solvent, and is purchased from Shanghai Huishao chemical Co. The penetrating agent is ethylene glycol monomethyl ether. The surfactant is selected from coconut oil glycol amide. The dibasic acid methyl ester monomer is selected from the combination of dimethyl succinate, dimethyl glutarate and dimethyl adipate, and the proportion of the dimethyl succinate, the dimethyl glutarate and the dimethyl adipate is 1: 0.8: 0.25. the raw material also comprises polyether derivatives with amino; the addition amount of the polyether derivative with the amino group is 12% of the weight of the limonene, and the polyether derivative with the amino group is 4-aminobutyraldehyde diethyl acetal.
The preparation method of the environment-friendly degumming agent comprises the following steps: (1) adding limonene, a penetrating agent and a deodorized hydrocarbon solvent into a reaction kettle, stirring, heating to 65 ℃ while stirring, and then keeping the temperature and stirring for 45 minutes; (2) adding the rest raw materials in sequence, and continuously stirring for 30 minutes; (3) standing for defoaming for 8.5 hours after stirring is finished, and filtering to obtain the product.
Example 7
The environment-friendly degumming agent comprises, by weight, 65 parts of D-limonene, 35 parts of a deodorized hydrocarbon solvent, 12 parts of a penetrating agent, 7 parts of a surfactant, 10 parts of dibasic acid ester and 60 parts of water.
The deodorized hydrocarbon solvent is D110 solvent, and is purchased from Shanghai Huishao chemical Co. The penetrating agent is ethylene glycol monomethyl ether. The surfactant is selected from coconut oil glycol amide. The dibasic acid methyl ester monomer is selected from the combination of dimethyl succinate, dimethyl glutarate and dimethyl adipate, and the proportion of the dimethyl succinate, the dimethyl glutarate and the dimethyl adipate is 1: 0.8: 0.25. the raw material also comprises polyether derivatives with amino; the addition amount of the polyether derivative with the amino group is 12% of the weight of the limonene, and the polyether derivative with the amino group is ethylene glycol di (3-aminopropyl) ether.
The preparation method of the environment-friendly degumming agent comprises the following steps: (1) adding limonene, a penetrating agent and a deodorized hydrocarbon solvent into a reaction kettle, stirring, heating to 65 ℃ while stirring, and then keeping the temperature and stirring for 45 minutes; (2) adding the rest raw materials in sequence, and continuously stirring for 30 minutes; (3) standing for defoaming for 8.5 hours after stirring is finished, and filtering to obtain the product.
Example 8
The environment-friendly degumming agent comprises, by weight, 65 parts of D-limonene, 35 parts of a deodorized hydrocarbon solvent, 12 parts of a penetrating agent, 7 parts of a surfactant, 10 parts of dibasic acid ester and 60 parts of water.
The deodorized hydrocarbon solvent is D110 solvent, and is purchased from Shanghai Huishao chemical Co. The penetrating agent is ethylene glycol monomethyl ether. The surfactant is selected from coconut oil glycol amide. The dibasic acid methyl ester monomer is selected from the combination of dimethyl succinate, dimethyl glutarate and dimethyl adipate, and the proportion of the dimethyl succinate, the dimethyl glutarate and the dimethyl adipate is 1: 0.8: 0.25. the raw material also comprises polyether derivatives with amino; the addition amount of the polyether derivative with the amino group is 12 percent of the mass of the limonene, and the polyether derivative with the amino group is 4-aminobutyraldehyde diethylene glycol and ethylene glycol di (3-aminopropyl) ether. The weight ratio of the 4-aminobutyraldehyde diethyl acetal to the ethylene glycol di (3-aminopropyl) ether is 1: 5.
the preparation method of the environment-friendly degumming agent comprises the following steps: (1) adding limonene, a penetrating agent and a deodorized hydrocarbon solvent into a reaction kettle, stirring, heating to 65 ℃ while stirring, and then keeping the temperature and stirring for 45 minutes; (2) adding the rest raw materials in sequence, and continuously stirring for 30 minutes; (3) standing for defoaming for 8.5 hours after stirring is finished, and filtering to obtain the product.
Example 9
The environment-friendly degumming agent comprises, by weight, 65 parts of D-limonene, 35 parts of a deodorized hydrocarbon solvent, 12 parts of a penetrating agent, 7 parts of a surfactant, 10 parts of dibasic acid ester and 60 parts of water.
The deodorized hydrocarbon solvent is D110 solvent, and is purchased from Shanghai Huishao chemical Co. The penetrating agent is ethylene glycol monomethyl ether. The surfactant is selected from coconut oil glycol amide. The dibasic acid methyl ester monomer is selected from the combination of dimethyl succinate, dimethyl glutarate and dimethyl adipate, and the proportion of the dimethyl succinate, the dimethyl glutarate and the dimethyl adipate is 1: 0.8: 0.25. the starting materials also include polyether derivatives bearing amino groups.
The preparation method of the environment-friendly degumming agent comprises the following steps: (1) adding limonene, a penetrating agent and a deodorized hydrocarbon solvent into a reaction kettle, stirring, heating to 65 ℃ while stirring, and then keeping the temperature and stirring for 45 minutes; (2) adding the rest raw materials in sequence, and continuously stirring for 30 minutes; (3) standing for defoaming for 8.5 hours after stirring is finished, and filtering to obtain the product.
Example 10
The environment-friendly degumming agent comprises, by weight, 65 parts of D-limonene, 35 parts of a deodorized hydrocarbon solvent, 12 parts of a penetrating agent, 7 parts of a surfactant, 10 parts of dibasic acid ester and 60 parts of water.
The deodorized hydrocarbon solvent is D110 solvent, and is purchased from Shanghai Huishao chemical Co. The penetrating agent is ethylene glycol monomethyl ether. The surfactant is selected from coconut oil glycol amide. The dibasic acid methyl ester monomer is selected from the combination of dimethyl succinate, dimethyl glutarate and dimethyl adipate, and the proportion of the dimethyl succinate, the dimethyl glutarate and the dimethyl adipate is 1: 0.8: 0.25. the raw material also comprises polyether derivatives with amino; the addition amount of the polyether derivative with the amino group is 12 percent of the mass of the limonene, and the polyether derivative with the amino group is 4-aminobutyraldehyde diethylene glycol and ethylene glycol di (3-aminopropyl) ether. The weight ratio of the 4-aminobutyraldehyde diethyl acetal to the ethylene glycol di (3-aminopropyl) ether is 5: 1.
the preparation method of the environment-friendly degumming agent comprises the following steps: (1) adding limonene, a penetrating agent and a deodorized hydrocarbon solvent into a reaction kettle, stirring, heating to 65 ℃ while stirring, and then keeping the temperature and stirring for 45 minutes; (2) adding the rest raw materials in sequence, and continuously stirring for 30 minutes; (3) standing for defoaming for 8.5 hours after stirring is finished, and filtering to obtain the product.
Performance testing
1. And (3) corrosion test: the selected substrate is an aluminum-plastic plate. The same amount of feed liquid is dipped and dropped on the substrate, and the corrosion condition of the substrate is observed. Let a be the range where the substrate whitens or swells/the range where the feed liquid drops to the substrate. If a is less than or equal to 2.5%, judging that no influence exists; if a is more than 2.5 percent and less than or equal to 10 percent, judging the corrosion is light; if a is more than 10% and less than or equal to 30%, judging the corrosion is moderate; if a is more than 30%, the corrosion is judged to be severe.
2. And (3) testing the glue removing rate: two substrates, namely an acrylic plate, an aluminum plastic plate and a stainless steel plate are selected for the experiment, and the testing steps are as follows. 1) A3-piece acrylic plate of dimensions 21cm X18 cm was weighed and the weight m0 recorded, respectively. 2) Adhering JL-510 transparent high-temperature-resistant epoxy resin AB glue with the same size to an acrylic plate (or an aluminum-plastic plate or a stainless steel plate) in an adhering mode, weighing after 24 hours of adhering, and recording the weight m1. 3) Spraying the degumming agent aiming at the glue stain, completely covering the residual glue part as much as possible, standing for 1-2 min after spraying, and allowing the scavenger to completely permeate and dissolve the glue; then, the colloid on the acrylic plate (or the aluminum-plastic plate) is wiped by cotton cloth, a scraper or a proper tool matched with degumming agent, and the weight m of the degummed acrylic plate (or the aluminum-plastic plate or the stainless steel plate) is weighed2。
4) Calculating the degumming rate
ω＝(m1－m2)/(m1－m0)×100％ (1)
In the formula: m is0G is the weight of the aluminum-plastic plate; m is1G, the weight of the colloid and the aluminum-plastic plate after the colloid is completely dried; m is2G is the total weight of the aluminum-plastic panel and the residual colloid after the colloid is removed.
The average of 3 tests was taken.
TABLE 1 Corrosion Performance and degumming Performance test results
The foregoing examples are illustrative only, and serve to explain some of the features of the present disclosure. The appended claims are intended to claim as broad a scope as is contemplated, and the examples presented herein are merely illustrative of selected implementations in accordance with all possible combinations of examples. Accordingly, it is applicants' intention that the appended claims are not to be limited by the choice of examples illustrating features of the invention. And that advances in science and technology will result in possible equivalents or sub-substitutes not currently contemplated for reasons of inaccuracy in language representation, and such changes should also be construed where possible to be covered by the appended claims.
Claims (10)
1. The environment-friendly adhesive remover is characterized by comprising the following raw materials in parts by weight: 55-75 parts of limonene, 25-45 parts of a deodorized hydrocarbon solvent, 5-20 parts of a penetrating agent, 5-10 parts of a surfactant, 5-15 parts of dibasic acid ester and 30-80 parts of water.
2. The environment-friendly glue remover according to claim 1, wherein the raw materials comprise, by weight: 60-70 parts of limonene, 30-40 parts of a deodorized hydrocarbon solvent, 10-15 parts of a penetrating agent, 7 parts of a surfactant, 10 parts of dibasic acid ester and 50-70 parts of water.
3. The environment-friendly glue remover according to claim 2, wherein the raw materials comprise, by weight: 65 parts of limonene, 35 parts of a deodorized hydrocarbon solvent, 12 parts of a penetrating agent, 7 parts of a surfactant, 10 parts of dibasic acid ester and 60 parts of water.
4. The environment-friendly degumming agent according to any of claims 1 to 3, wherein the penetrating agent is selected from one or more of butyl acetate, dimethyl carbonate, ethylene glycol methyl ether, propylene glycol methyl ether, triethylene glycol methyl ether, ethylene glycol monoethyl ether, diethylene glycol monobutyl ether, ethylene glycol butyl ether, tripropylene glycol methyl ether, dipropylene glycol butyl ether, dipropylene glycol propyl ether, n-octanol, benzyl alcohol, ethylene glycol, propylene glycol, polyethylene glycol.
5. The environment-friendly type degumming agent according to any one of claims 1 to 3, characterized in that the raw materials further comprise polyether derivatives with amino groups; the addition amount of the polyether derivative with amino is 5-15% of the weight of the limonene.
6. The environment-friendly degumming agent as defined in claim 5, wherein the polyether derivative having amino groups is 4-aminobutyraldehyde diethyl alcohol and/or ethylene glycol di (3-aminopropyl) ether.
7. The environment-friendly degumming agent as claimed in claim 6, wherein the weight ratio of 4-aminobutyraldehyde diethyl acetal to ethylene glycol di (3-aminopropyl) ether is 1: (0.2-1.5).
8. The environment-friendly degumming agent as claimed in claim 7, wherein the weight ratio of 4-aminobutyraldehyde diethyl acetal to ethylene glycol di (3-aminopropyl) ether is 1: (0.5-1).
9. The method for preparing the environment-friendly degumming agent as defined in any one of claims 1 to 8, comprising the steps of:
(1) adding limonene, a penetrating agent and a deodorized hydrocarbon solvent into a reaction kettle, stirring, heating to 50-80 ℃ while stirring, and then preserving heat and stirring for 30-60 minutes; (2) adding the rest raw materials in sequence, and continuously stirring for 15-45 minutes; (3) standing for defoaming for 5-12 hr after stirring, and packaging.
10. The use of the environment-friendly adhesive remover according to any one of claims 1 to 8, which is used for removing adhesive residues and dirt on the surfaces of plastic plates, glass, ceramics, marble and metal.
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