CN110759475A - Ceramic membrane oxygen transfer biofilm reactor - Google Patents

Ceramic membrane oxygen transfer biofilm reactor Download PDF

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Publication number
CN110759475A
CN110759475A CN201911213535.6A CN201911213535A CN110759475A CN 110759475 A CN110759475 A CN 110759475A CN 201911213535 A CN201911213535 A CN 201911213535A CN 110759475 A CN110759475 A CN 110759475A
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China
Prior art keywords
ceramic membrane
water
shell
aeration
membrane component
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CN201911213535.6A
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Chinese (zh)
Inventor
曹成
刘进
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Shandong Youyi Membrane Material Technology Co Ltd
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Shandong Youyi Membrane Material Technology Co Ltd
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Publication of CN110759475A publication Critical patent/CN110759475A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/30Aerobic and anaerobic processes
    • C02F3/302Nitrification and denitrification treatment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/34Biological treatment of water, waste water, or sewage characterised by the microorganisms used
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/16Nitrogen compounds, e.g. ammonia
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2203/00Apparatus and plants for the biological treatment of water, waste water or sewage
    • C02F2203/006Apparatus and plants for the biological treatment of water, waste water or sewage details of construction, e.g. specially adapted seals, modules, connections

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  • Life Sciences & Earth Sciences (AREA)
  • Microbiology (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

The invention belongs to the field of water treatment devices, and particularly relates to a ceramic membrane oxygen transfer biofilm reactor which is characterized by comprising a shell, wherein a ceramic membrane component, a water distribution pipe and an aeration pipe are sequentially arranged in the shell from top to bottom, a plurality of water production holes are distributed on the water distribution pipe, a plurality of aeration holes are distributed on the aeration pipe, a water production tank is arranged at the upper part of the side surface of the shell, a water outlet is arranged at the bottom of the water production tank, a membrane component air inlet and a membrane component air outlet which are communicated with the ceramic membrane component are also arranged on the side surface of the shell, a raw water inlet and an aeration port which are communicated with the water distribution pipe are also arranged on the raw water inlet, and a sludge discharge and emptying port are arranged at the bottom of the shell.

Description

Ceramic membrane oxygen transfer biofilm reactor
Technical Field
The invention belongs to the field of water treatment devices, and particularly relates to a ceramic membrane oxygen transfer biofilm reactor.
Background
The MABR is a Membrane Aerated Biofilm Reactor (Membrane Aerated Biofilm Reactor), which well combines the characteristics of COD/BOD removal, nitrification/denitrification and the like, but still belongs to the traditional process treatment technology and has some defects, such as:
1) in engineering application, the MABR technology of the traditional process still needs to be combined with the traditional activated sludge process or the traditional biofilm process, and the MABR technology mainly comprises the following steps in the flow: the combination of the MABR membrane process and the activated sludge process (the biological membrane process) has long process flow and high capital construction cost.
2) The chemical stability and corrosion resistance of the film are poor, the ageing resistance and the tolerance are poor, the service life is short, the film changing period is short, and the use cost is high;
disclosure of Invention
The invention aims to overcome the defects of short service life, high capital construction and use cost of the MABR in the prior art, and provides a ceramic membrane oxygen transfer biofilm reactor, which is a technology upgrade on the prior membrane oxygen transfer biofilm reactor technology (MABR), wherein the ceramic membrane used after the upgrade has longer service life, and is more widely applied compared with the prior MABR technology.
The ceramic membrane oxygen transfer biomembrane reactor is characterized by comprising a shell, wherein a ceramic membrane component, a water distribution pipe and an aeration pipe are sequentially arranged in the shell from top to bottom, a plurality of water production holes are distributed on the water distribution pipe, a plurality of aeration holes are distributed on the aeration pipe, a water production tank is arranged at the upper part of the side surface of the shell, a water outlet is arranged at the bottom of the water production tank, a membrane component air inlet and a membrane component air outlet which are communicated with the ceramic membrane component are also arranged at the side surface of the shell, a raw water inlet which is communicated with the water distribution pipe and an aeration port which is communicated with the aeration pipe are also.
Furthermore, the ceramic membrane component is a plate type ceramic membrane component or a tubular ceramic membrane component.
The plate type ceramic membrane component or the tubular ceramic membrane component is a product in the prior art.
Furthermore, the surface of the ceramic membrane component is provided with a tetrafluoro hydrophobic coating.
Furthermore, a sampling port is arranged at a water outlet at the bottom of the water producing tank. The sample connection sets up before the delivery port, is convenient for detect the quality of producing water.
When the plate type ceramic membrane component is used, PMABR is used for short, and when the tubular type ceramic membrane component is used, TMABR is used for short.
The PMABR/TMABR technology of the invention is mainly different from the prior MABR technology in that:
1) the PMABR/TMABR technology is structurally different from the traditional MABR technology, the integration of the PMABR/TMABR technology is stronger, only one reactor is needed for the PMABR/TMABR, and the PMABR/TMABR technology does not need to be matched with other biochemical process sections, so that the design flow is simplified, and the engineering investment is saved; which must be combined with other conventional biochemical processing stages.
2) Compared with the prior MABR technology which adopts an organic hollow fiber membrane as a membrane material and the PMABR/TMABR technology which adopts a ceramic membrane as a membrane material, the ceramic membrane has longer service life and prolongs the membrane replacement period.
3) And for better film formation, the surface of the adopted ceramic membrane is subjected to tetrafluoro modification hydrophobic treatment, and a layer of tetrafluoro coating is coated on the surface of the ceramic membrane after the ceramic membrane is fired and formed.
4) The upgraded PMABR/TMABR technology can be used for single-stage, double-stage and multi-stage series operation according to the water quality of the wastewater.
The invention has the following advantages:
①, easy installation, wherein the PMABR/TMABR module is a standardized module and is easy to be installed in newly built or in the reconstruction of old factories;
②, the amount of sludge is reduced by 50%, the pumping, on-site storage, dehydration, road transportation and treatment costs are reduced;
③, the modular design can be directly installed in the original pool body to increase the processing capacity without adding infrastructure;
④, high efficiency and energy saving, high energy consumption of the traditional process, 70 percent of energy consumption for aeration, low PMABR/TMABR operating pressure, no need of sludge circulation and 75 percent of energy saving.
Drawings
FIG. 1 is a schematic structural view of the present invention;
FIG. 2 shows the reaction principle of the biofilm formed on the surface of the ceramic membrane module of the present invention.
As shown in the figure: 1. a housing; 2. a ceramic membrane module; 3. a raw water inlet; 4. a membrane module gas inlet; 5. an aeration opening; 6. a membrane module exhaust port; 7. a sludge discharge and emptying port; 8. a water producing tank; 9. a water distribution pipe; 10, an aeration pipe; 11. a sampling port; 12. and (7) a water outlet.
Detailed Description
As shown in fig. 1: the ceramic membrane component 2, the water distribution pipe 9 and the aeration pipe 10 are sequentially arranged in the shell 1 from top to bottom, the water production tank 8 is arranged on the right side of the upper portion of the shell 1, the bottom of the water production tank 8 is provided with a sampling port 11 and a water outlet 12, the left side of the shell 1 is provided with a membrane component exhaust port 6 communicated with the ceramic membrane component 2, a raw water inlet 3 communicated with the water distribution pipe 9 and an aeration port 5 communicated with the aeration pipe 10, the right side of the shell is provided with a membrane component air inlet 4 communicated with the ceramic membrane component 2, and the right side of the bottom of the shell 1 is provided with a.
When the device is used, wastewater enters the shell 1 from the raw water inlet 3 through the water distribution pipe 9, air enters the ceramic membrane component 2 through the air blower and the membrane component air inlet 4, the air passes through the membrane from bottom to top, oxygen in the air is conducted outwards through the membrane to be in contact with the biological membrane outside the membrane, pollutants such as COD (chemical oxygen demand), ammonia nitrogen and the like in the sewage enter the biological membrane, and biochemical reaction occurs in the biological membrane to remove the pollutants in the sewage. The treated wastewater enters the water production tank 8 and is discharged outside through the water outlet 12.
In the operation process, raw water and air enter the aeration pipe 10 through the aeration port 5 and overflow through the perforated aeration pipe to form an air-water mixed flow, so that the raw water is homogenized and impurities attached to the outer surface of the biological membrane are washed, the washed impurities and the fallen biological membrane form residual sludge and sink to the bottom of the equipment, and the residual sludge is periodically discharged through the sludge discharge port and the emptying port 7.
As shown in fig. 2, the reaction mechanism of the present invention is as follows: when air enters the membrane component 2 from the membrane component air inlet 4, oxygen in the air is conducted from the inside of the membrane to the outside of the membrane and enters the biomembrane on the surface of the membrane, the outside of the biomembrane is the water side, COD, BOD, ammonia nitrogen and the like in wastewater enter the biomembrane from the water, biochemical reaction is carried out under the action of microorganisms in the biomembrane, aerobic and anoxic conditions are synchronously generated, so that synchronous nitrification and denitrification can be realized by using less energy and space, and the aim of removing pollutants in sewage is fulfilled.
The above embodiments are only used to illustrate the technical solution of the present invention, and not to limit the same; while the invention has been described in detail and with reference to the foregoing embodiments, it will be understood by those skilled in the art that: the technical solutions described in the foregoing embodiments may still be modified, or some or all of the technical features may be equivalently replaced; such modifications and substitutions do not depart from the spirit and scope of the present invention, and they should be construed as being included in the following claims and description.

Claims (4)

1. A ceramic membrane oxygen transfer biomembrane reactor is characterized by comprising a shell, wherein a ceramic membrane component, a water distribution pipe and an aeration pipe are sequentially arranged in the shell from top to bottom, a plurality of water production holes are distributed on the water distribution pipe, a plurality of aeration holes are distributed on the aeration pipe, a water production tank is arranged at the upper part of the side surface of the shell, a water outlet is arranged at the bottom of the water production tank, a membrane component air inlet and a membrane component air outlet which are communicated with the ceramic membrane component are also arranged at the side surface of the shell, a raw water inlet which is communicated with the water distribution pipe and an aeration port which is communicated with the aeration pipe are.
2. A ceramic membrane oxygen transfer biofilm reactor according to claim 1, wherein the ceramic membrane modules are plate ceramic membrane modules or tubular ceramic membrane modules.
3. A ceramic membrane oxygen transport biofilm reactor according to claim 1 or 2, wherein the surface of the ceramic membrane modules is provided with a hydrophobic coating of tetrafluoro.
4. The ceramic membrane oxygen transfer biofilm reactor of claim 1, wherein a sampling port is provided at a water outlet at the bottom of the water production tank.
CN201911213535.6A 2019-08-06 2019-12-02 Ceramic membrane oxygen transfer biofilm reactor Pending CN110759475A (en)

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CN201910722812X 2019-08-06
CN201910722812 2019-08-06

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113480009A (en) * 2021-08-23 2021-10-08 浙江开创环保科技股份有限公司 Membrane aeration sewage treatment system

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110759475A (en) * 2019-08-06 2020-02-07 山东优益膜材料科技有限公司 Ceramic membrane oxygen transfer biofilm reactor

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101024539A (en) * 2007-02-05 2007-08-29 哈尔滨工业大学 Integrated bubble-free aeration biological composite film film-separation biological reactor
CN105923751A (en) * 2016-05-13 2016-09-07 长安大学 Ceramic membrane and membrane aeration biologic reactor provided with same
JP6547866B1 (en) * 2018-02-20 2019-07-24 栗田工業株式会社 Aerobic treatment equipment
CN110054298A (en) * 2019-05-24 2019-07-26 嘉兴里仁环保科技股份有限公司 A kind of flat MABR oxygen flow membrane module
CN211367138U (en) * 2019-08-06 2020-08-28 山东优益膜材料科技有限公司 Ceramic membrane oxygen transfer biofilm reactor

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101024539A (en) * 2007-02-05 2007-08-29 哈尔滨工业大学 Integrated bubble-free aeration biological composite film film-separation biological reactor
CN105923751A (en) * 2016-05-13 2016-09-07 长安大学 Ceramic membrane and membrane aeration biologic reactor provided with same
JP6547866B1 (en) * 2018-02-20 2019-07-24 栗田工業株式会社 Aerobic treatment equipment
CN110054298A (en) * 2019-05-24 2019-07-26 嘉兴里仁环保科技股份有限公司 A kind of flat MABR oxygen flow membrane module
CN211367138U (en) * 2019-08-06 2020-08-28 山东优益膜材料科技有限公司 Ceramic membrane oxygen transfer biofilm reactor

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113480009A (en) * 2021-08-23 2021-10-08 浙江开创环保科技股份有限公司 Membrane aeration sewage treatment system

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