CN110759475A - Ceramic membrane oxygen transfer biofilm reactor - Google Patents
Ceramic membrane oxygen transfer biofilm reactor Download PDFInfo
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- CN110759475A CN110759475A CN201911213535.6A CN201911213535A CN110759475A CN 110759475 A CN110759475 A CN 110759475A CN 201911213535 A CN201911213535 A CN 201911213535A CN 110759475 A CN110759475 A CN 110759475A
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- ceramic membrane
- water
- shell
- aeration
- membrane component
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- 239000012528 membrane Substances 0.000 title claims abstract description 73
- 239000000919 ceramic Substances 0.000 title claims abstract description 40
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims abstract description 14
- 239000001301 oxygen Substances 0.000 title claims abstract description 14
- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 14
- 238000012546 transfer Methods 0.000 title claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 52
- 238000005273 aeration Methods 0.000 claims abstract description 23
- 238000009826 distribution Methods 0.000 claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 claims abstract description 13
- 238000005070 sampling Methods 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims description 3
- 238000000576 coating method Methods 0.000 claims description 3
- 230000002209 hydrophobic effect Effects 0.000 claims description 3
- 239000010802 sludge Substances 0.000 abstract description 9
- 238000005516 engineering process Methods 0.000 description 15
- 238000000034 method Methods 0.000 description 10
- 230000008569 process Effects 0.000 description 10
- 239000002351 wastewater Substances 0.000 description 4
- 239000003344 environmental pollutant Substances 0.000 description 3
- 231100000719 pollutant Toxicity 0.000 description 3
- 239000010865 sewage Substances 0.000 description 3
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 description 2
- 238000005842 biochemical reaction Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000009471 action Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000003851 biochemical process Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000012510 hollow fiber Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000001360 synchronised effect Effects 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/30—Aerobic and anaerobic processes
- C02F3/302—Nitrification and denitrification treatment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/34—Biological treatment of water, waste water, or sewage characterised by the microorganisms used
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/16—Nitrogen compounds, e.g. ammonia
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2203/00—Apparatus and plants for the biological treatment of water, waste water or sewage
- C02F2203/006—Apparatus and plants for the biological treatment of water, waste water or sewage details of construction, e.g. specially adapted seals, modules, connections
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- Life Sciences & Earth Sciences (AREA)
- Microbiology (AREA)
- Biodiversity & Conservation Biology (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Abstract
The invention belongs to the field of water treatment devices, and particularly relates to a ceramic membrane oxygen transfer biofilm reactor which is characterized by comprising a shell, wherein a ceramic membrane component, a water distribution pipe and an aeration pipe are sequentially arranged in the shell from top to bottom, a plurality of water production holes are distributed on the water distribution pipe, a plurality of aeration holes are distributed on the aeration pipe, a water production tank is arranged at the upper part of the side surface of the shell, a water outlet is arranged at the bottom of the water production tank, a membrane component air inlet and a membrane component air outlet which are communicated with the ceramic membrane component are also arranged on the side surface of the shell, a raw water inlet and an aeration port which are communicated with the water distribution pipe are also arranged on the raw water inlet, and a sludge discharge and emptying port are arranged at the bottom of the shell.
Description
Technical Field
The invention belongs to the field of water treatment devices, and particularly relates to a ceramic membrane oxygen transfer biofilm reactor.
Background
The MABR is a Membrane Aerated Biofilm Reactor (Membrane Aerated Biofilm Reactor), which well combines the characteristics of COD/BOD removal, nitrification/denitrification and the like, but still belongs to the traditional process treatment technology and has some defects, such as:
1) in engineering application, the MABR technology of the traditional process still needs to be combined with the traditional activated sludge process or the traditional biofilm process, and the MABR technology mainly comprises the following steps in the flow: the combination of the MABR membrane process and the activated sludge process (the biological membrane process) has long process flow and high capital construction cost.
2) The chemical stability and corrosion resistance of the film are poor, the ageing resistance and the tolerance are poor, the service life is short, the film changing period is short, and the use cost is high;
disclosure of Invention
The invention aims to overcome the defects of short service life, high capital construction and use cost of the MABR in the prior art, and provides a ceramic membrane oxygen transfer biofilm reactor, which is a technology upgrade on the prior membrane oxygen transfer biofilm reactor technology (MABR), wherein the ceramic membrane used after the upgrade has longer service life, and is more widely applied compared with the prior MABR technology.
The ceramic membrane oxygen transfer biomembrane reactor is characterized by comprising a shell, wherein a ceramic membrane component, a water distribution pipe and an aeration pipe are sequentially arranged in the shell from top to bottom, a plurality of water production holes are distributed on the water distribution pipe, a plurality of aeration holes are distributed on the aeration pipe, a water production tank is arranged at the upper part of the side surface of the shell, a water outlet is arranged at the bottom of the water production tank, a membrane component air inlet and a membrane component air outlet which are communicated with the ceramic membrane component are also arranged at the side surface of the shell, a raw water inlet which is communicated with the water distribution pipe and an aeration port which is communicated with the aeration pipe are also.
Furthermore, the ceramic membrane component is a plate type ceramic membrane component or a tubular ceramic membrane component.
The plate type ceramic membrane component or the tubular ceramic membrane component is a product in the prior art.
Furthermore, the surface of the ceramic membrane component is provided with a tetrafluoro hydrophobic coating.
Furthermore, a sampling port is arranged at a water outlet at the bottom of the water producing tank. The sample connection sets up before the delivery port, is convenient for detect the quality of producing water.
When the plate type ceramic membrane component is used, PMABR is used for short, and when the tubular type ceramic membrane component is used, TMABR is used for short.
The PMABR/TMABR technology of the invention is mainly different from the prior MABR technology in that:
1) the PMABR/TMABR technology is structurally different from the traditional MABR technology, the integration of the PMABR/TMABR technology is stronger, only one reactor is needed for the PMABR/TMABR, and the PMABR/TMABR technology does not need to be matched with other biochemical process sections, so that the design flow is simplified, and the engineering investment is saved; which must be combined with other conventional biochemical processing stages.
2) Compared with the prior MABR technology which adopts an organic hollow fiber membrane as a membrane material and the PMABR/TMABR technology which adopts a ceramic membrane as a membrane material, the ceramic membrane has longer service life and prolongs the membrane replacement period.
3) And for better film formation, the surface of the adopted ceramic membrane is subjected to tetrafluoro modification hydrophobic treatment, and a layer of tetrafluoro coating is coated on the surface of the ceramic membrane after the ceramic membrane is fired and formed.
4) The upgraded PMABR/TMABR technology can be used for single-stage, double-stage and multi-stage series operation according to the water quality of the wastewater.
The invention has the following advantages:
①, easy installation, wherein the PMABR/TMABR module is a standardized module and is easy to be installed in newly built or in the reconstruction of old factories;
②, the amount of sludge is reduced by 50%, the pumping, on-site storage, dehydration, road transportation and treatment costs are reduced;
③, the modular design can be directly installed in the original pool body to increase the processing capacity without adding infrastructure;
④, high efficiency and energy saving, high energy consumption of the traditional process, 70 percent of energy consumption for aeration, low PMABR/TMABR operating pressure, no need of sludge circulation and 75 percent of energy saving.
Drawings
FIG. 1 is a schematic structural view of the present invention;
FIG. 2 shows the reaction principle of the biofilm formed on the surface of the ceramic membrane module of the present invention.
As shown in the figure: 1. a housing; 2. a ceramic membrane module; 3. a raw water inlet; 4. a membrane module gas inlet; 5. an aeration opening; 6. a membrane module exhaust port; 7. a sludge discharge and emptying port; 8. a water producing tank; 9. a water distribution pipe; 10, an aeration pipe; 11. a sampling port; 12. and (7) a water outlet.
Detailed Description
As shown in fig. 1: the ceramic membrane component 2, the water distribution pipe 9 and the aeration pipe 10 are sequentially arranged in the shell 1 from top to bottom, the water production tank 8 is arranged on the right side of the upper portion of the shell 1, the bottom of the water production tank 8 is provided with a sampling port 11 and a water outlet 12, the left side of the shell 1 is provided with a membrane component exhaust port 6 communicated with the ceramic membrane component 2, a raw water inlet 3 communicated with the water distribution pipe 9 and an aeration port 5 communicated with the aeration pipe 10, the right side of the shell is provided with a membrane component air inlet 4 communicated with the ceramic membrane component 2, and the right side of the bottom of the shell 1 is provided with a.
When the device is used, wastewater enters the shell 1 from the raw water inlet 3 through the water distribution pipe 9, air enters the ceramic membrane component 2 through the air blower and the membrane component air inlet 4, the air passes through the membrane from bottom to top, oxygen in the air is conducted outwards through the membrane to be in contact with the biological membrane outside the membrane, pollutants such as COD (chemical oxygen demand), ammonia nitrogen and the like in the sewage enter the biological membrane, and biochemical reaction occurs in the biological membrane to remove the pollutants in the sewage. The treated wastewater enters the water production tank 8 and is discharged outside through the water outlet 12.
In the operation process, raw water and air enter the aeration pipe 10 through the aeration port 5 and overflow through the perforated aeration pipe to form an air-water mixed flow, so that the raw water is homogenized and impurities attached to the outer surface of the biological membrane are washed, the washed impurities and the fallen biological membrane form residual sludge and sink to the bottom of the equipment, and the residual sludge is periodically discharged through the sludge discharge port and the emptying port 7.
As shown in fig. 2, the reaction mechanism of the present invention is as follows: when air enters the membrane component 2 from the membrane component air inlet 4, oxygen in the air is conducted from the inside of the membrane to the outside of the membrane and enters the biomembrane on the surface of the membrane, the outside of the biomembrane is the water side, COD, BOD, ammonia nitrogen and the like in wastewater enter the biomembrane from the water, biochemical reaction is carried out under the action of microorganisms in the biomembrane, aerobic and anoxic conditions are synchronously generated, so that synchronous nitrification and denitrification can be realized by using less energy and space, and the aim of removing pollutants in sewage is fulfilled.
The above embodiments are only used to illustrate the technical solution of the present invention, and not to limit the same; while the invention has been described in detail and with reference to the foregoing embodiments, it will be understood by those skilled in the art that: the technical solutions described in the foregoing embodiments may still be modified, or some or all of the technical features may be equivalently replaced; such modifications and substitutions do not depart from the spirit and scope of the present invention, and they should be construed as being included in the following claims and description.
Claims (4)
1. A ceramic membrane oxygen transfer biomembrane reactor is characterized by comprising a shell, wherein a ceramic membrane component, a water distribution pipe and an aeration pipe are sequentially arranged in the shell from top to bottom, a plurality of water production holes are distributed on the water distribution pipe, a plurality of aeration holes are distributed on the aeration pipe, a water production tank is arranged at the upper part of the side surface of the shell, a water outlet is arranged at the bottom of the water production tank, a membrane component air inlet and a membrane component air outlet which are communicated with the ceramic membrane component are also arranged at the side surface of the shell, a raw water inlet which is communicated with the water distribution pipe and an aeration port which is communicated with the aeration pipe are.
2. A ceramic membrane oxygen transfer biofilm reactor according to claim 1, wherein the ceramic membrane modules are plate ceramic membrane modules or tubular ceramic membrane modules.
3. A ceramic membrane oxygen transport biofilm reactor according to claim 1 or 2, wherein the surface of the ceramic membrane modules is provided with a hydrophobic coating of tetrafluoro.
4. The ceramic membrane oxygen transfer biofilm reactor of claim 1, wherein a sampling port is provided at a water outlet at the bottom of the water production tank.
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CN201910722812X | 2019-08-06 | ||
CN201910722812 | 2019-08-06 |
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CN110759475A true CN110759475A (en) | 2020-02-07 |
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CN201911213535.6A Pending CN110759475A (en) | 2019-08-06 | 2019-12-02 | Ceramic membrane oxygen transfer biofilm reactor |
CN201922123085.3U Active CN211367138U (en) | 2019-08-06 | 2019-12-02 | Ceramic membrane oxygen transfer biofilm reactor |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN113480009A (en) * | 2021-08-23 | 2021-10-08 | 浙江开创环保科技股份有限公司 | Membrane aeration sewage treatment system |
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CN110759475A (en) * | 2019-08-06 | 2020-02-07 | 山东优益膜材料科技有限公司 | Ceramic membrane oxygen transfer biofilm reactor |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101024539A (en) * | 2007-02-05 | 2007-08-29 | 哈尔滨工业大学 | Integrated bubble-free aeration biological composite film film-separation biological reactor |
CN105923751A (en) * | 2016-05-13 | 2016-09-07 | 长安大学 | Ceramic membrane and membrane aeration biologic reactor provided with same |
JP6547866B1 (en) * | 2018-02-20 | 2019-07-24 | 栗田工業株式会社 | Aerobic treatment equipment |
CN110054298A (en) * | 2019-05-24 | 2019-07-26 | 嘉兴里仁环保科技股份有限公司 | A kind of flat MABR oxygen flow membrane module |
CN211367138U (en) * | 2019-08-06 | 2020-08-28 | 山东优益膜材料科技有限公司 | Ceramic membrane oxygen transfer biofilm reactor |
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2019
- 2019-12-02 CN CN201911213535.6A patent/CN110759475A/en active Pending
- 2019-12-02 CN CN201922123085.3U patent/CN211367138U/en active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101024539A (en) * | 2007-02-05 | 2007-08-29 | 哈尔滨工业大学 | Integrated bubble-free aeration biological composite film film-separation biological reactor |
CN105923751A (en) * | 2016-05-13 | 2016-09-07 | 长安大学 | Ceramic membrane and membrane aeration biologic reactor provided with same |
JP6547866B1 (en) * | 2018-02-20 | 2019-07-24 | 栗田工業株式会社 | Aerobic treatment equipment |
CN110054298A (en) * | 2019-05-24 | 2019-07-26 | 嘉兴里仁环保科技股份有限公司 | A kind of flat MABR oxygen flow membrane module |
CN211367138U (en) * | 2019-08-06 | 2020-08-28 | 山东优益膜材料科技有限公司 | Ceramic membrane oxygen transfer biofilm reactor |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113480009A (en) * | 2021-08-23 | 2021-10-08 | 浙江开创环保科技股份有限公司 | Membrane aeration sewage treatment system |
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CN211367138U (en) | 2020-08-28 |
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