CN110756200A - Nano oxygen catalyst air purifying agent and preparation method thereof - Google Patents

Nano oxygen catalyst air purifying agent and preparation method thereof Download PDF

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Publication number
CN110756200A
CN110756200A CN201910318262.5A CN201910318262A CN110756200A CN 110756200 A CN110756200 A CN 110756200A CN 201910318262 A CN201910318262 A CN 201910318262A CN 110756200 A CN110756200 A CN 110756200A
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weight fraction
purifying agent
air purifying
oxygen catalyst
nano oxygen
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CN201910318262.5A
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张中
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Tianjin Sino Japanese Environmental Protection Polytron Technologies Inc
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Tianjin Sino Japanese Environmental Protection Polytron Technologies Inc
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Priority to CN201910318262.5A priority Critical patent/CN110756200A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04Sulfides
    • B01J27/043Sulfides with iron group metals or platinum group metals
    • B01J27/045Platinum group metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8668Removing organic compounds not provided for in B01D53/8603 - B01D53/8665
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/10Noble metals or compounds thereof
    • B01D2255/102Platinum group metals
    • B01D2255/1021Platinum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/10Noble metals or compounds thereof
    • B01D2255/102Platinum group metals
    • B01D2255/1025Rhodium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/10Noble metals or compounds thereof
    • B01D2255/104Silver
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/204Alkaline earth metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20715Zirconium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20776Tungsten
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20792Zinc
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)

Abstract

The invention belongs to the technical field of environmental protection, and particularly relates to a nano oxygen catalyst air purifying agent and a preparation method thereof, wherein the nano oxygen catalyst air purifying agent comprises the following components: zinc oxide (ZnO): 1-5% (weight fraction); cadmium sulfide (CdS): 2-4% (weight fraction); tungsten trioxide (WO 3): 1-3% (weight fraction); lead sulfide (PbS): 1-2% (weight fraction); silver oxide (Ag 2O): 4-7% (weight fraction); zinc sulfide (ZnS): 2-3% (weight fraction); strontium titanate (SrTiO 3): 6-10% (weight fraction); zirconium dioxide (ZrO 2): 1-4% (weight fraction); rhodium oxide (Rh2O 3): 8-15% (weight fraction); platinum sulfide (PtS 2): 8-12% (weight fraction). The nano oxygen catalyst air purifying agent can effectively remove formaldehyde, and achieves the purpose of purifying indoor air.

Description

Nano oxygen catalyst air purifying agent and preparation method thereof
Technical Field
The invention belongs to the technical field of environmental protection, and particularly relates to a nano oxygen catalyst air purifying agent and a preparation method thereof.
Background
In recent years, the air pollution problem is widely concerned by society, and the air quality spot inspection result of newly installed houses in China shows that the indoor air pollution degree is 2-3 times more serious than the outdoor air pollution degree, and even more than 100 times more serious than the outdoor air pollution degree under certain serious conditions.
The existing air purification methods are mainly classified into three types:
1. formaldehyde adsorption box, active carbon, diatom ooze and the like: the existing products such as various formaldehyde adsorption boxes, air purifiers, purified carbon and the like are essentially used for removing formaldehyde by utilizing air flow and passive adsorption, and because of the passive adsorption, the effect is very poor, and the formaldehyde adsorption purification effect on indoor decoration pollution is almost ineffective or very weak;
2. mechanical and electronic products such as an air purifier and a fresh air system: the purification effect is limited by the treatment capacity and the treatment area, the overall purification effect is not ideal, and the treatment cost, the use cost and the maintenance cost are high, such as power consumption, filter material replacement and the like; the comprehensive effect and the cost are not comparable to the effect and the cost of one-time treatment and lifelong thorough radical treatment of the nano oxygen catalyst technology;
3. photocatalyst technology and products: the formaldehyde-free spray coating is a product with relatively good purification effect in the market at present, can really play a certain purification effect under the condition of ultraviolet irradiation with specific wavelength, but can play a role in promoting the catalytic decomposition of formaldehyde under the condition of illumination due to the existence of the formaldehyde-free spray coating, cannot ensure the removal effect under the dark and dark conditions due to the technical limitation of the photocatalyst technology, has short effective period of the photocatalyst due to common spray coating construction, is a process of continuously releasing decorative formaldehyde, and has the longest release period of several years. Therefore, although the photocatalyst product has a certain effect, the photocatalyst product has obvious technical limitation, and the technical effects of continuous decontamination and thorough purification cannot be realized.
Disclosure of Invention
The invention provides a nano oxygen catalyst air purifying agent and a preparation method thereof, which aim to solve the problems in the prior art in the background technology.
The technical problem solved by the invention is realized by adopting the following technical scheme:
a nano oxygen catalyst air purifying agent comprises the following components:
Figure BDA0002033829600000011
Figure BDA0002033829600000021
preferably, the nano oxygen catalyst air purifying agent comprises the following components in parts by weight:
Figure BDA0002033829600000022
the invention also provides a preparation method of the nano oxygen catalyst air purifying agent, which comprises the following steps: the nanometer-level component raw materials are mixed and dissolved in water.
The invention also provides a use method of the nano oxygen catalyst air purifying agent, which comprises the following steps: the nano oxygen catalyst air purifying agent is directly coated on indoor home furnishing needing air purification.
The invention has the beneficial technical effects that:
the nano oxygen catalyst air purifying agent can achieve the effect of continuously purifying air all day long only by oxygen catalysis, and the purifying effect is beyond the reach of other technologies.
The specific implementation mode is as follows:
the present invention will be further described with reference to the following specific examples.
Example 1:
the air purifying agent adopting the nano oxygen catalyst comprises the following components in parts by weight:
Figure BDA0002033829600000023
Figure BDA0002033829600000031
30ml of nano oxygen catalyst air purifying agent sample liquid is evenly sprayed on linen bereau (15 x 20cm) and placed in a 5L plastic bag, the linen bereau is placed for 2 hours in a dark place, 2.5L of gas is prepared and absorbed in 10ml of water, and 2ml of the gas is taken for measurement. Meanwhile, 30ml of distilled water is used for processing according to the same method to be used as a sample control.
And (3) detection results:
initial concentration of formaldehyde: 19.0mg/m2
Figure BDA0002033829600000032
Example 2:
the air purifying agent adopting the nano oxygen catalyst comprises the following components in parts by weight:
Figure BDA0002033829600000033
Figure BDA0002033829600000041
selecting 20 blockboards with unqualified formaldehyde emission amount of 50mm by 150mm, wherein 10 blockboards are kept, and naturally drying 10 blockboards after spraying the nano oxygen catalyst air purifying agent. According to GB/T17657-1999 physicochemical property test method for artificial boards and facing artificial boards, a dryer method is used for testing formaldehyde emission in two states.
And (3) detection results:
Figure BDA0002033829600000042
the nano oxygen catalyst air purifying agent is adopted, so that formaldehyde can be effectively removed, and the purpose of purifying indoor air is achieved.
The technical solutions of the present invention or similar technical solutions designed by those skilled in the art based on the teachings of the technical solutions of the present invention are all within the scope of the present invention to achieve the above technical effects.

Claims (4)

1. A nanometer oxygen catalyst air purifying agent is characterized in that: comprises the following components:
Figure FDA0002033829590000011
2. the nano oxygen catalyst air purifying agent according to claim 1, characterized in that: the weight fraction ratio of the components is as follows:
3. a preparation method of a nano oxygen catalyst air purifying agent comprises the following steps: the nano-scale component raw material of claim 1 is mixed and dissolved in water.
4. A use method of a nano oxygen catalyst air purifying agent comprises the following steps: the nano oxygen catalyst air purifying agent of claim 1 is directly coated on indoor home furnishing needing air purification.
CN201910318262.5A 2019-04-19 2019-04-19 Nano oxygen catalyst air purifying agent and preparation method thereof Pending CN110756200A (en)

Priority Applications (1)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101400766B1 (en) * 2013-03-07 2014-05-29 김윤환 Method of menufacturing nano-oxygen catalyst with carbon nanotubes for removing sick house syndrome and ge powder for radiating a negative ion
CN104209091A (en) * 2014-07-28 2014-12-17 微摩空间室内环保科技(北京)有限公司 Indoor air purifying bag and preparation method thereof
EP2986378A1 (en) * 2013-04-17 2016-02-24 Danmarks Tekniske Universitet An improved method of preparation of nanoparticular metal oxide catalysts
CN105813710A (en) * 2013-12-13 2016-07-27 株式会社富士工 Air cleaning filter and air cleaner provided with same
CN106823794A (en) * 2017-04-13 2017-06-13 陈超 A kind of nanometer air catalyst air purifying agent and preparation method thereof
CN108579714A (en) * 2018-03-23 2018-09-28 苏州品顾环保科技有限公司 A kind of production method of the air catalyst aldehyde remover of high-efficiency environment friendly

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101400766B1 (en) * 2013-03-07 2014-05-29 김윤환 Method of menufacturing nano-oxygen catalyst with carbon nanotubes for removing sick house syndrome and ge powder for radiating a negative ion
EP2986378A1 (en) * 2013-04-17 2016-02-24 Danmarks Tekniske Universitet An improved method of preparation of nanoparticular metal oxide catalysts
CN105813710A (en) * 2013-12-13 2016-07-27 株式会社富士工 Air cleaning filter and air cleaner provided with same
CN104209091A (en) * 2014-07-28 2014-12-17 微摩空间室内环保科技(北京)有限公司 Indoor air purifying bag and preparation method thereof
CN106823794A (en) * 2017-04-13 2017-06-13 陈超 A kind of nanometer air catalyst air purifying agent and preparation method thereof
CN108579714A (en) * 2018-03-23 2018-09-28 苏州品顾环保科技有限公司 A kind of production method of the air catalyst aldehyde remover of high-efficiency environment friendly

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
陈金花等: "室内空气污染治理的研究进展", 《重庆建筑大学学报》 *

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