CN110724394A - Flame-retardant cable material - Google Patents

Flame-retardant cable material Download PDF

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Publication number
CN110724394A
CN110724394A CN201911177192.2A CN201911177192A CN110724394A CN 110724394 A CN110724394 A CN 110724394A CN 201911177192 A CN201911177192 A CN 201911177192A CN 110724394 A CN110724394 A CN 110724394A
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CN
China
Prior art keywords
parts
flame
flame retardant
cable material
retardant cable
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201911177192.2A
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Chinese (zh)
Inventor
位山
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Bo Tuo Electrical Equipment Co Ltd
Original Assignee
Jiangsu Bo Tuo Electrical Equipment Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Bo Tuo Electrical Equipment Co Ltd filed Critical Jiangsu Bo Tuo Electrical Equipment Co Ltd
Priority to CN201911177192.2A priority Critical patent/CN110724394A/en
Publication of CN110724394A publication Critical patent/CN110724394A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00Compositions of unspecified macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K2003/023Silicon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/0812Aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2217Oxides; Hydroxides of metals of magnesium
    • C08K2003/2224Magnesium hydroxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention provides a flame-retardant cable material which comprises the following components in parts by weight: 50-80 parts of synthetic resin, 40-50 parts of PVC resin, 12-22 parts of silicon rubber, 1-3 parts of dimethyl disulfide, 5-10 parts of glass beads, 1-3 parts of color master batch, 20-25 parts of ramie fiber, 2-6 parts of paraffin, 1-5 parts of sulfur castor oil, 2-4 parts of epoxy resin, 1-3 parts of flame retardant, 0.2-0.5 part of coupling agent, 1-4 parts of antioxidant and 1-3 parts of flame retardant synergist. The flame-retardant cable material provided by the invention is nontoxic, good in thermal stability, easy to process, excellent in mechanical property, high in strength, high in temperature resistance grade, low in cost, good in flame retardance, environment-friendly and nontoxic, and is suitable for large-scale industrial production.

Description

Flame-retardant cable material
Technical Field
The invention mainly relates to the technical field of cable materials, in particular to a flame-retardant cable material.
Background
The cable is made of one or more mutually insulated conductors and an outer insulating protective layer, and the wire, the cable and the sheath for transmitting power or information from one place to another are made of plastic commonly called cable material, which comprises various varieties such as rubber, plastic, nylon and the like. The cable material production enterprises take cable production enterprises as users, and have the market of cable materials as long as the requirements of wires and cables are met. The wire and cable products almost need an insulating layer opening except bare wire products such as steel-cored aluminum stranded wires, electromagnetic wires and the like. However, with the frequent occurrence of electrical fire accidents, the fire retardant problem of the electric wire and cable is gradually drawing attention from countries around the world. When the cable is burnt, a large amount of toxic smog and corrosive gas are released, which hinders the safe evacuation and fire extinguishing work of people and causes the serious loss of lives and properties. The currently used cable has poor flame retardancy and is easy to cause fire when being used for manufacturing electric wires and cables.
Disclosure of Invention
The invention mainly provides a flame-retardant cable material, which is used for solving the technical problems in the background technology.
The technical scheme adopted by the invention for solving the technical problems is as follows:
a flame-retardant cable material comprises the following components in parts by weight: 50-80 parts of synthetic resin, 40-50 parts of PVC resin, 12-22 parts of silicon rubber, 1-3 parts of dimethyl disulfide, 5-10 parts of glass beads, 1-3 parts of color master batch, 20-25 parts of ramie fiber, 2-6 parts of paraffin, 1-5 parts of sulfur castor oil, 2-4 parts of epoxy resin, 1-3 parts of flame retardant, 0.2-0.5 part of coupling agent, 1-4 parts of antioxidant and 1-3 parts of flame retardant synergist.
Further, the flame-retardant cable material comprises the following components in parts by weight: 65 parts of synthetic resin, 45 parts of PVC resin, 17 parts of silicone rubber, 2 parts of dimethyl disulfide, 8 parts of glass beads, 2 parts of color master batch, 23 parts of ramie fiber, 4 parts of paraffin, 3 parts of brimstone castor oil, 3 parts of epoxy resin, 2 parts of flame retardant, 0.3 part of coupling agent, 3 parts of antioxidant and 2 parts of flame retardant synergist.
Further, the flame retardant is a magnesium hydroxide flame retardant.
Further, the coupling agent is vinyl trimethoxy silane.
Further, the antioxidant is 4,4' -thiobis.
Furthermore, the flame-retardant synergist consists of hydrotalcite, montmorillonite and silicon-aluminum powder.
Furthermore, the mass ratio of the hydrotalcite to the montmorillonite to the silicon-aluminum powder is 1:5: 2.
Compared with the prior art, the invention has the beneficial effects that:
the flame-retardant cable material provided by the invention is nontoxic, good in thermal stability, easy to process, excellent in mechanical property, high in strength, high in temperature resistance grade, low in cost, good in flame retardance, environment-friendly and nontoxic, and is suitable for large-scale industrial production.
Detailed Description
Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs, and the knowledge of the terms used herein in the specification of the present invention is for the purpose of describing particular embodiments and is not intended to limit the present invention, and the term "and/or" as used herein includes any and all combinations of one or more of the associated listed items.
Example 1
A flame-retardant cable material comprises the following components in parts by weight: 50 parts of synthetic resin, 40 parts of PVC resin, 12 parts of silicone rubber, 1 part of dimethyl disulfide, 5 parts of glass beads, 1 part of color master batch, 20 parts of ramie fiber, 2 parts of paraffin, 1 part of brimstone castor oil, 2 parts of epoxy resin, 1 part of flame retardant, 0.2 part of coupling agent, 1 part of antioxidant and 1 part of flame retardant synergist; the flame retardant is a magnesium hydroxide flame retardant; the coupling agent is vinyl trimethoxy silane; the antioxidant is 4,4' -thiobis; the flame-retardant synergist consists of hydrotalcite, montmorillonite and silicon-aluminum powder; the mass ratio of the hydrotalcite to the montmorillonite to the silicon-aluminum powder is 1:5: 2.
Example 2
A flame-retardant cable material comprises the following components in parts by weight: 65 parts of synthetic resin, 45 parts of PVC resin, 17 parts of silicone rubber, 2 parts of dimethyl disulfide, 8 parts of glass beads, 2 parts of color master batch, 23 parts of ramie fiber, 4 parts of paraffin, 3 parts of brimstone castor oil, 3 parts of epoxy resin, 2 parts of flame retardant, 0.3 part of coupling agent, 3 parts of antioxidant and 2 parts of flame retardant synergist; the flame retardant is a magnesium hydroxide flame retardant; the coupling agent is vinyl trimethoxy silane; the antioxidant is 4,4' -thiobis; the flame-retardant synergist consists of hydrotalcite, montmorillonite and silicon-aluminum powder; the mass ratio of the hydrotalcite to the montmorillonite to the silicon-aluminum powder is 1:5: 2.
Example 3
A flame-retardant cable material comprises the following components in parts by weight: 80 parts of synthetic resin, 50 parts of PVC resin, 22 parts of silicone rubber, 3 parts of dimethyl disulfide, 10 parts of glass beads, 3 parts of color master batch, 25 parts of ramie fiber, 6 parts of paraffin, 5 parts of brimstone castor oil, 4 parts of epoxy resin, 3 parts of flame retardant, 0.5 part of coupling agent, 4 parts of antioxidant and 3 parts of flame retardant synergist; the flame retardant is a magnesium hydroxide flame retardant; the coupling agent is vinyl trimethoxy silane; the antioxidant is 4,4' -thiobis; the flame-retardant synergist consists of hydrotalcite, montmorillonite and silicon-aluminum powder; the mass ratio of the hydrotalcite to the montmorillonite to the silicon-aluminum powder is 1:5: 2.
The invention has been described in an illustrative manner, and it is to be understood that the invention is not limited in its application to the details of construction and to the arrangements of the components set forth in the following description, since such modifications are intended to be included within the spirit and scope of the invention as defined in the appended claims.

Claims (7)

1. The flame-retardant cable material is characterized by comprising the following components in parts by weight: 50-80 parts of synthetic resin, 40-50 parts of PVC resin, 12-22 parts of silicon rubber, 1-3 parts of dimethyl disulfide, 5-10 parts of glass beads, 1-3 parts of color master batch, 20-25 parts of ramie fiber, 2-6 parts of paraffin, 1-5 parts of sulfur castor oil, 2-4 parts of epoxy resin, 1-3 parts of flame retardant, 0.2-0.5 part of coupling agent, 1-4 parts of antioxidant and 1-3 parts of flame retardant synergist.
2. The flame-retardant cable material according to claim 1, characterized by comprising the following components in parts by weight: 65 parts of synthetic resin, 45 parts of PVC resin, 17 parts of silicone rubber, 2 parts of dimethyl disulfide, 8 parts of glass beads, 2 parts of color master batch, 23 parts of ramie fiber, 4 parts of paraffin, 3 parts of brimstone castor oil, 3 parts of epoxy resin, 2 parts of flame retardant, 0.3 part of coupling agent, 3 parts of antioxidant and 2 parts of flame retardant synergist.
3. A flame retardant cable material according to claim 1, wherein: the flame retardant is a magnesium hydroxide flame retardant.
4. A flame retardant cable material according to claim 1, wherein: the coupling agent is vinyl trimethoxy silane.
5. A flame retardant cable material according to claim 1, wherein: the antioxidant is 4,4' -thiobis.
6. A flame retardant cable material according to claim 1, wherein: the flame-retardant synergist consists of hydrotalcite, montmorillonite and silicon-aluminum powder.
7. A flame retardant cable material according to claim 7, wherein: the mass ratio of the hydrotalcite to the montmorillonite to the silicon-aluminum powder is 1:5: 2.
CN201911177192.2A 2019-11-26 2019-11-26 Flame-retardant cable material Pending CN110724394A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201911177192.2A CN110724394A (en) 2019-11-26 2019-11-26 Flame-retardant cable material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201911177192.2A CN110724394A (en) 2019-11-26 2019-11-26 Flame-retardant cable material

Publications (1)

Publication Number Publication Date
CN110724394A true CN110724394A (en) 2020-01-24

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201911177192.2A Pending CN110724394A (en) 2019-11-26 2019-11-26 Flame-retardant cable material

Country Status (1)

Country Link
CN (1) CN110724394A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117649975A (en) * 2023-12-01 2024-03-05 扬州曙光电缆股份有限公司 Flame-retardant fire-resistant spray-proof special measurement cable for fourth-generation nuclear power and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117649975A (en) * 2023-12-01 2024-03-05 扬州曙光电缆股份有限公司 Flame-retardant fire-resistant spray-proof special measurement cable for fourth-generation nuclear power and preparation method thereof

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