CN1107172A - Composite adhesive tape for newspaper clipping - Google Patents
Composite adhesive tape for newspaper clipping Download PDFInfo
- Publication number
- CN1107172A CN1107172A CN 94101406 CN94101406A CN1107172A CN 1107172 A CN1107172 A CN 1107172A CN 94101406 CN94101406 CN 94101406 CN 94101406 A CN94101406 A CN 94101406A CN 1107172 A CN1107172 A CN 1107172A
- Authority
- CN
- China
- Prior art keywords
- adhesive tape
- units
- composite adhesive
- described composite
- newspaper clipping
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002390 adhesive tape Substances 0.000 title claims abstract description 28
- 239000002131 composite material Substances 0.000 title claims abstract description 16
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 20
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 18
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims abstract description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims abstract description 12
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims abstract description 11
- 238000001035 drying Methods 0.000 claims abstract description 11
- 239000011347 resin Substances 0.000 claims abstract description 8
- 229920005989 resin Polymers 0.000 claims abstract description 8
- -1 2-ethyl n-hexyl Chemical group 0.000 claims abstract description 7
- 239000000853 adhesive Substances 0.000 claims abstract description 5
- 230000001070 adhesive effect Effects 0.000 claims abstract description 5
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims abstract description 5
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims abstract 2
- 238000000034 method Methods 0.000 claims description 9
- 230000008569 process Effects 0.000 claims description 7
- 150000008065 acid anhydrides Chemical class 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 6
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 5
- 230000000694 effects Effects 0.000 claims description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 5
- 239000003292 glue Substances 0.000 claims description 4
- 238000012546 transfer Methods 0.000 claims description 4
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 claims description 3
- 125000004828 2-ethylpropylene group Chemical group [H]C([H])([H])C([H])([H])C([H])(C([H])([H])[*:1])C([H])([H])[*:2] 0.000 claims description 3
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 3
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 3
- 238000004026 adhesive bonding Methods 0.000 claims description 3
- 125000003368 amide group Chemical group 0.000 claims description 3
- 239000004014 plasticizer Substances 0.000 claims description 3
- 238000012545 processing Methods 0.000 claims description 3
- VVWRJUBEIPHGQF-UHFFFAOYSA-N propan-2-yl n-propan-2-yloxycarbonyliminocarbamate Chemical compound CC(C)OC(=O)N=NC(=O)OC(C)C VVWRJUBEIPHGQF-UHFFFAOYSA-N 0.000 claims description 3
- 239000003352 sequestering agent Substances 0.000 claims description 3
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 3
- 239000013032 Hydrocarbon resin Substances 0.000 claims description 2
- 239000004743 Polypropylene Substances 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- XLJMAIOERFSOGZ-UHFFFAOYSA-N anhydrous cyanic acid Natural products OC#N XLJMAIOERFSOGZ-UHFFFAOYSA-N 0.000 claims description 2
- 229920002301 cellulose acetate Polymers 0.000 claims description 2
- 229920006270 hydrocarbon resin Polymers 0.000 claims description 2
- 230000006872 improvement Effects 0.000 claims description 2
- 239000005011 phenolic resin Substances 0.000 claims description 2
- 229920006267 polyester film Polymers 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- OWIKHYCFFJSOEH-UHFFFAOYSA-N Isocyanic acid Chemical class N=C=O OWIKHYCFFJSOEH-UHFFFAOYSA-N 0.000 claims 1
- 150000002118 epoxides Chemical class 0.000 claims 1
- 239000012948 isocyanate Substances 0.000 abstract description 6
- 150000002513 isocyanates Chemical class 0.000 abstract description 6
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 abstract description 4
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 abstract 2
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 230000035945 sensitivity Effects 0.000 abstract 1
- 238000010008 shearing Methods 0.000 abstract 1
- 239000000178 monomer Substances 0.000 description 7
- 230000007704 transition Effects 0.000 description 5
- 125000000524 functional group Chemical group 0.000 description 3
- 150000002924 oxiranes Chemical class 0.000 description 3
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 240000004859 Gamochaeta purpurea Species 0.000 description 1
- 239000012986 chain transfer agent Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000000153 supplemental effect Effects 0.000 description 1
Images
Landscapes
- Adhesive Tapes (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invented composite adhesive tape for newspaper clipping is a kind of one capable of tearing off the printed characters from one printed paper after it sticking on said paper and then tearing off, then it is sticked on another paper. The glycide methacrylate, 2-ethyl n-hexyl acrylate, n-butyl acrylate, propenoic acid, methyl acrylate, acetone, ethyl acetate, azobisisobutyronitrile, toluene, resin and isocyanates are polymerized into pressure sensitivity sticking agent, then bond transfusion agent is added. Said sticking agent is coated on the film, certain compounds are added in the drying treatment to regulate the shearing force and flexibility and produce high early stickiness, high hold-fast force and low adhesive force.
Description
The present invention relates to a kind of composite adhesive tape for newspaper clipping, You Zhiqi sticks in subsides and the printed text on the paper can have been glued after tearing up on the paper again, and can directly be pasted on other paper again and be convenient to arrangement, and can forever preserve.
People have the data of seeing article excellent on the newspapers and magazines or being worth preserving fine taste often in daily life, glue the desire of putting in order and desire to cut to paste, yet but because of when cliping and pasting, preparing tackiness agents such as scissors and paste, glue, be everlasting and feel the Yu of trouble and do not desire to start, therefore often missed and for the article of appreciating again and again or to have commemorated the chance of picture; Again at present the student when writing homework, the data on the newspapers and magazines also must quoted as proof often is with supplemental content, or must plagiarize all major issues on the newspapers when writing journal, also because the above-mentioned working process hell to pay of cliping and pasting, or the time of plagiarizing is too consuming time, using inferior materials and turning out substandard goods when often causing the student to write homework influences learning interest, and visible traditional work of cliping and pasting is not little for the tangible influence of the fast culture of culture.Moreover, general pressure-sensitive adhesive belt is for all being had very strong clinging power by then body, the fiber on the paper can be adhered to and rises after sticking pasting, and causes the reduction of viscosity confining force and can not reuse, so, then obviously be impracticable if desire with the instrument of traditional adhesive tape as the data of adhesion.
In order to improve the drawback of above-mentioned alipping service, main purpose of the present invention is to provide a kind of composite adhesive tape for newspaper clipping, be to use high polymer monomer to be polymerized, for newspaper printing ink and paper special initial tack of adhesive and high confining force, minimum clinging power are arranged, written historical materials on the newspaper can stickingly be shifted it on adhesive tape after tearing pasting again, and can at any time the subsides of the adhesive tape behind the transfer information be sticked on other paper, one subsides i.e. jail, are torn promptly down, can not stay any cull and vestige for attached object, can be with required data permanently filing.
Composite adhesive tape for newspaper clipping provided by the present invention, by epihydric alcohol methylpropenoic acid ester, the just own ester of 2-ethyl propylene, n-butyl acrylate, vinylformic acid, methacrylic ester, acetone, ethyl acetate, Diisopropyl azodicarboxylate, toluene, resin and isocyanates aggregate into acrylic pressure-sensitive tackiness agent, and in the transfer agent that wherein adds key, then this acrylic pressure-sensitive tackiness agent is coated on the film, under 100 ℃ temperature condition, bestow 3 minutes drying treatment again, and in the drying treatment process, add isocyanates, epoxide, amido or sequestrant are crosslinked to promote, regulate its shear strength and flexibility according to this, adding in addition has tackifier or plasticizer with the improvement rerum natura, make it produce high initial tack of adhesive (Initial Tack), high confining force (Cohesion) and low clinging power (Adhesion), thereby produce the adhesive tape that can glue printed text on the paper.
The characteristic of the product that the present invention is made is further described through cooperating following accompanying drawing; make the relevant personnel that more detailed understanding be arranged; so the following stated only is in order to explain preferred embodiment of the present invention; be not that attempt is done any pro forma restriction to the present invention according to this; so; every in following of identical invention spirit oppose relevant any modification of the present invention or change, all should be included in the category of invention intention protection.
Fig. 1 pastes the embodiment stereographic map that sticks at above the paper that is printed on official documents and correspondence for the made adhesive tape of the present invention;
The embodiment stereographic map that Fig. 2 has been glued the official documents and correspondence on the paper for the made adhesive tape of the present invention.
Composite adhesive tape for newspaper clipping provided by the present invention, its manufacture method is by the epihydric alcohol methylpropenoic acid ester of 50 units (Glycidyl Methacrylate), the just own ester of the 2-ethyl propylene of 300 units (2-Ethyltexyl Acrylate), the n-butyl acrylate of 700 units (n-butyl Acrylate), the vinylformic acid of 120 units (Acrylic acid), the methacrylic ester of 270 units (Methyl Acrylate), the acetone of 10 units (Acetone), the ethyl acetate of 200 units (EAC), the Diisopropyl azodicarboxylate of 20 units (AZOISOBUTYRO Nitrile), the toluene of 750 units (Tlouene), the isocyanic acid lipid (isocyanate) of resin of 125 units (Resin) and 35.6 units aggregates into acrylic pressure-sensitive tackiness agent (Acrylic pressuresensitive adhesive, be called for short PsAs), its colloidality shape is transparent, its solid type is divided into 40 ± 1.5%, viscosity is 1500 ± 50cps, this PsAs has comprised the monomer (monomer) more than two kinds and two kinds, be respectively more soft and have monomer than low glass state transition point (Glass Transition point), reach the monomer that compares hard and have higher glassy transition point, contain the more monomer of functional group (FunctionalGroup) in addition, because of more functional group is arranged, make this PsAs improve the purpose that multi-usage is used, and it has been comprised have crosslinked (Crosslinking) and increase its nonpolar good purpose of following, again because of using higher and lower glassy transition point, the difference of its ratio can influence the glassy transition point and the modulus (Modulus) of whole polymkeric substance, the scope that whole PsAs is used is more extensive, in addition also because of the difference of high low-molecular-weight polymeric, and the situation of its molecular weight distribution is differed, but can control by transfer agent (Chaintransfer agent) the processing situation of key, make it reach high shear strength (Shear Strength), after various acrylic monomers (Acrylicmonomer) polymerization, coat again on the film (film), this film is polypropylene screen (Oppfilm), polyester film (Polyester), cellulose acetate film (Acetate), processing through light face and cloudy surface, its thickness is 0.035mm, gluing thickness is 0.015mm, and spread is 50g/m
2; And after coating, bestow drying treatment again, it bestows 3 minutes drying process under 100 ℃ temperature condition, and in the drying treatment process, add isocyanates (Isocyanate), epoxide (Epoxide), amido (Amino) or sequestrant (MetalChelate), in order to PsAs in hydroxyl (OH), carboxyl (COOH) and acid anhydrides (Acid Anhydride) are had an effect and are promoted crosslinked, regulate its shear strength (Shear Strength) and flexibility (flexibility) according to this, make it produce high initial tack of adhesive (Initial Tack), high confining force (Cohesion) and low clinging power (Adhesion).In order further to make the PsAs upgrading is final spendable purpose, can use such as oil hydrocarbon resin (petroleumhydrocarbon), alkyl phenol resin (Alkylphenslicresin), ester class rosin tackifier (Tackifer) such as (Rosin ester) or plasticizer (Plastigel) and improve some rerum natura, the condition of its selection is:
One, the molecular weight of resin must be low than PsAs.
Two, the glassy transition point of resin must be high than tackiness agent.
Three, resin must have good intermiscibility with tackiness agent.
Four, must there be good moist (wet) to be the basis for various plastic film.
As shown in Figure 1, 2, the replica adhesive tape of producing by above-mentioned manufacture method 1, can be directly this adhesive tape 1 be pasted and stick at desire on the newspapers and magazines paper 2 and pluck the official documents and correspondence part of getting off, really subsides are torn it down adhesive tape 1 after gluing again, so the official documents and correspondence on the paper 2 can be pasted the sticking viscosity part that is needed on adhesive tape 1, then the adhesive tape 1 of tearing can be pasted again on the book basis that sticks at desire arrangement preservation, the trouble that can remove cutting from, be coated with tackiness agent, pasting, have excellent progressive and the utility value on the industry, and can forever preserve.
By the above as can be known, the present invention is novel in design unique, and has utility value on the pure industry.
Claims (9)
1, a kind of composite adhesive tape for newspaper clipping, it is characterized in that: by the methacrylate of 50 units, the just own ester of the 2-ethyl propylene of 300 units, the n-butyl acrylate of 700 units, the vinylformic acid of 120 units, the methacrylic ester of 270 units, the acetone of 10 units, the ethyl acetate of 200 units, the Diisopropyl azodicarboxylate of 20 units, the toluene of 750 units, the carbimide class of the resin of 125 units and 35.6 units aggregates into acrylic pressure-sensitive tackiness agent, and in the transfer agent that wherein adds key to improve its shear strength, then will coat on the film than acrylic pressure-sensitive tackiness agent, under 100 ℃ temperature condition, bestow 3 minutes drying treatment again, and in the drying treatment process, add isocyanic acid lipid, in order to acrylic pressure-sensitive tackiness agent in hydroxyl, carboxyl and acid anhydrides are had an effect and are promoted crosslinked, regulate its shear strength and flexibility according to this, adding in addition has tackifier or plasticizer with the improvement rerum natura, make it produce high initial tack of adhesive, high confining force and low clinging power are in order to produce the adhesive tape that can glue printed text on the paper.
2, according to the described composite adhesive tape for newspaper clipping of claim 1, wherein can in the drying treatment process, add epoxide, in order to acrylic pressure-sensitive tackiness agent in hydroxyl, carboxyl and acid anhydrides have an effect and promote crosslinkedly, regulate its shear strength and flexibility according to this.
3, according to the described composite adhesive tape for newspaper clipping of claim 1, wherein can in the drying treatment process, add amido, in order to acrylic pressure-sensitive tackiness agent in hydroxyl, carboxyl and acid anhydrides have an effect and promote crosslinkedly, regulate its shear strength and flexibility according to this.
4, according to the described composite adhesive tape for newspaper clipping of claim 1, wherein can in the drying treatment process, add sequestrant, in order to acrylic pressure-sensitive tackiness agent in hydroxyl, carboxyl and acid anhydrides have an effect and promote crosslinkedly, regulate its shear strength and flexibility according to this.
5, according to the described composite adhesive tape for newspaper clipping of claim 1, wherein these tackifier are the oil hydrocarbon resin.
6, according to the described composite adhesive tape for newspaper clipping of claim 1, wherein these tackifier are alkyl phenol resin.
7, according to the described composite adhesive tape for newspaper clipping of claim 1, wherein these tackifier are ester class rosin.
8, according to the described composite adhesive tape for newspaper clipping of claim 1, wherein the colloidality shape of this acrylic pressure-sensitive tackiness agent is transparent, and its solid type is divided into 40 ± 1.5%, and viscosity is 1500 ± 50cps.
9, according to the described composite adhesive tape for newspaper clipping of claim 1, wherein this film is that polypropylene screen, polyester film, cellulose acetate film etc. are handled and the processing of light face through cloudy surface, and its thickness is 0.035mm, and gluing thickness is 0.015mm, and spread is 50g/m
2
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 94101406 CN1107172A (en) | 1994-02-17 | 1994-02-17 | Composite adhesive tape for newspaper clipping |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 94101406 CN1107172A (en) | 1994-02-17 | 1994-02-17 | Composite adhesive tape for newspaper clipping |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1107172A true CN1107172A (en) | 1995-08-23 |
Family
ID=5030133
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 94101406 Pending CN1107172A (en) | 1994-02-17 | 1994-02-17 | Composite adhesive tape for newspaper clipping |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1107172A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7874759B2 (en) | 2004-10-26 | 2011-01-25 | Marinvest Engineering Ab | Coupling for a propulsion system |
| CN101089101B (en) * | 2007-07-19 | 2012-01-25 | 中国科学院长春应用化学研究所 | Low temperature dried pressure-sensitive adhesive and its preparation process and coating method on polylactic film |
-
1994
- 1994-02-17 CN CN 94101406 patent/CN1107172A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7874759B2 (en) | 2004-10-26 | 2011-01-25 | Marinvest Engineering Ab | Coupling for a propulsion system |
| CN101089101B (en) * | 2007-07-19 | 2012-01-25 | 中国科学院长春应用化学研究所 | Low temperature dried pressure-sensitive adhesive and its preparation process and coating method on polylactic film |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |