CN110714323A - Method for improving adhesion of titanium dioxide on cotton fabric and self-cleaning effect - Google Patents
Method for improving adhesion of titanium dioxide on cotton fabric and self-cleaning effect Download PDFInfo
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- CN110714323A CN110714323A CN201911051601.4A CN201911051601A CN110714323A CN 110714323 A CN110714323 A CN 110714323A CN 201911051601 A CN201911051601 A CN 201911051601A CN 110714323 A CN110714323 A CN 110714323A
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- cotton fabric
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- 239000004744 fabric Substances 0.000 title claims abstract description 54
- 229920000742 Cotton Polymers 0.000 title claims abstract description 49
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 title claims abstract description 19
- 238000000034 method Methods 0.000 title claims abstract description 14
- 238000004140 cleaning Methods 0.000 title claims abstract description 13
- 230000000694 effects Effects 0.000 title claims abstract description 10
- 239000004408 titanium dioxide Substances 0.000 title claims abstract description 5
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 24
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000006185 dispersion Substances 0.000 claims abstract description 14
- 239000011259 mixed solution Substances 0.000 claims abstract description 13
- GGAUUQHSCNMCAU-ZXZARUISSA-N (2s,3r)-butane-1,2,3,4-tetracarboxylic acid Chemical compound OC(=O)C[C@H](C(O)=O)[C@H](C(O)=O)CC(O)=O GGAUUQHSCNMCAU-ZXZARUISSA-N 0.000 claims abstract description 12
- KWSLGOVYXMQPPX-UHFFFAOYSA-N 5-[3-(trifluoromethyl)phenyl]-2h-tetrazole Chemical compound FC(F)(F)C1=CC=CC(C2=NNN=N2)=C1 KWSLGOVYXMQPPX-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000007788 liquid Substances 0.000 claims abstract description 10
- 230000007935 neutral effect Effects 0.000 claims abstract description 10
- 229910001379 sodium hypophosphite Inorganic materials 0.000 claims abstract description 10
- CEYYIKYYFSTQRU-UHFFFAOYSA-M trimethyl(tetradecyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCC[N+](C)(C)C CEYYIKYYFSTQRU-UHFFFAOYSA-M 0.000 claims abstract description 9
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000004202 carbamide Substances 0.000 claims abstract description 8
- 238000010438 heat treatment Methods 0.000 claims abstract description 8
- 238000002791 soaking Methods 0.000 claims abstract description 7
- 238000001035 drying Methods 0.000 claims abstract description 6
- 238000005406 washing Methods 0.000 claims abstract description 6
- 230000018044 dehydration Effects 0.000 claims abstract description 5
- 238000006297 dehydration reaction Methods 0.000 claims abstract description 5
- 238000009210 therapy by ultrasound Methods 0.000 claims abstract description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 239000004753 textile Substances 0.000 abstract description 10
- 235000011121 sodium hydroxide Nutrition 0.000 abstract description 7
- 238000004043 dyeing Methods 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 3
- 238000011282 treatment Methods 0.000 description 3
- 230000000593 degrading effect Effects 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000000643 oven drying Methods 0.000 description 2
- 230000001699 photocatalysis Effects 0.000 description 2
- 239000011941 photocatalyst Substances 0.000 description 2
- 238000009987 spinning Methods 0.000 description 2
- MPNXSZJPSVBLHP-UHFFFAOYSA-N 2-chloro-n-phenylpyridine-3-carboxamide Chemical compound ClC1=NC=CC=C1C(=O)NC1=CC=CC=C1 MPNXSZJPSVBLHP-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- NAJAZZSIKSSBGH-UHFFFAOYSA-N butane-1,1,1,2-tetracarboxylic acid Chemical compound CCC(C(O)=O)C(C(O)=O)(C(O)=O)C(O)=O NAJAZZSIKSSBGH-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 description 1
- 230000005476 size effect Effects 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 230000005641 tunneling Effects 0.000 description 1
- 239000012855 volatile organic compound Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
- D06M11/70—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with oxides of phosphorus; with hypophosphorous, phosphorous or phosphoric acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/192—Polycarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention relates to a method for improving the attachment of titanium dioxide on cotton fabric and the self-cleaning effect, and belongs to the technical field of textile printing and dyeing. The invention comprises the following processes: (1) preparing TiO with the mass fractions of 2 percent, 6 percent, 0.4 percent and 4 percent2Mixed dispersion of butanetetracarboxylic acid, tetradecyltrimethylammonium chloride and sodium hypophosphite at room temperaturePerforming ultrasonic treatment for 30 min; (2) preparing a mixed solution of 7% of sodium hydroxide and 12% of urea by mass, putting a cotton fabric into the mixed solution, refrigerating the cotton fabric at the temperature of minus 10 ℃ for 1 hour at the mass ratio of 1:50, and then washing the cotton fabric to be neutral; (3) soaking the cotton fabric washed to be neutral in the mixed dispersion liquid for 30min, then taking out the cotton fabric for dehydration, drying the cotton fabric at 80 ℃, heating to 170 ℃ and baking for 2 min. In the invention, TiO is mixed with2Dispersed in mixed solution containing butanetetracarboxylic acid, tetradecyltrimethylammonium chloride and sodium hypophosphite, and used for finishing cotton fabrics pretreated by caustic soda/urea, thereby effectively and synergistically improving TiO2Adhesion and self-cleaning ability.
Description
Technical Field
The invention relates to a method for improving the attachment of titanium dioxide on cotton fabric and the self-cleaning effect, and belongs to the technical field of textile printing and dyeing.
Background
After the photocatalyst material is applied to textiles, the photocatalyst material can be endowed with a photocatalytic function, and further self-cleaning functions of degrading volatile organic compounds, removing peculiar smell, resisting bacteria, preventing fouling and the like are obtained. Nano TiO 22The material is a material with photocatalytic performance, has unique surface effect, small-size effect, quantum size effect, macroscopic quantum tunneling effect and the like, presents a plurality of special optical and electronic characteristics, becomes an ideal material for degrading dyes and auxiliaries and preparing antibacterial and self-cleaning textiles in the textile field, and becomes a research hotspot of the textile industry in recent years.
TiO2Has little affinity with textile fiber, and combines nano TiO with the textile fiber2There are two main methods for applying to textiles: one is to mix TiO2Blending and spinning with spinning solution to produce textile, the method is only suitable for synthetic fiber; another method is to use nano TiO2The dispersion is used for padding or coating finishing of the fabric to achieve the effect, and the method is simple and easy to implement. However, due to the nano TiO2Small grain size, high specific surface energy, poor particle dispersibility, easy agglomeration, low attachment amount on the fabric, and limited washing fastness, hand feeling and the like of the finished fabric.
Disclosure of Invention
In the invention, TiO is mixed with2Dispersed in mixed solution containing butanetetracarboxylic acid, tetradecyltrimethylammonium chloride and sodium hypophosphite, and used for finishing cotton fabric pretreated by caustic soda/urea, so that TiO can be effectively and synergistically improved2Adhesion and self-cleaning ability.
The invention comprises the following processes:
(1) preparing TiO with the mass fractions of 2 percent, 6 percent, 0.4 percent and 4 percent2Butanetetracarboxylic acid, tetradecylPerforming ultrasonic treatment on the mixed dispersion liquid of trimethyl ammonium chloride and sodium hypophosphite for 30min at room temperature;
(2) preparing a mixed solution of 7% of sodium hydroxide and 12% of urea by mass, putting a cotton fabric into the mixed solution, refrigerating the cotton fabric at the temperature of minus 10 ℃ for 1 hour at the mass ratio of 1:50, and then washing the cotton fabric to be neutral;
(3) soaking the cotton fabric washed to be neutral in the mixed dispersion liquid for 30min, then taking out the cotton fabric for dehydration, drying the cotton fabric at 80 ℃, heating to 170 ℃ and baking for 2 min.
Firstly, preparing TiO containing butanetetracarboxylic acid, tetradecyltrimethylammonium chloride and sodium hypophosphite2The dispersion was mixed. Butane tetracarboxylic acid and tetradecyltrimethyl ammonium chloride can be used in synergy with TiO2Surface modification is carried out to improve the dispersing ability in solution and improve TiO2The force between the cotton fabric and the cotton fabric is helpful for improving the adhesion and the self-cleaning capability. The butane tetracarboxylic acid and the sodium hypophosphite play a role in the subsequent attachment of the nano TiO to the fabric2The fixation is performed. The mixed solution of 7 percent by mass of sodium hydroxide and 12 percent by mass of urea is used for refrigerating the fabric at the temperature of minus 10 ℃, so that the internal micro-gap of the cotton fiber is enlarged, the structure becomes loose, and the TiO is helpful for2、The butane tetracarboxylic acid and tetradecyl trimethyl ammonium chloride compound enters the cotton fabric more deeply, and the attachment amount and the self-cleaning capacity of the compound are further improved in a synergistic manner. Finally, the cotton fabric is soaked in TiO2Mixing the dispersion solution for 30min, taking out, dewatering, drying the fabric at 80 deg.C, heating to 170 deg.C, and baking for 2 min.
Detailed Description
The invention is further illustrated by the following examples and comparative examples.
Example 1
The pure cotton fabric is treated by the method of the invention as follows:
(1) preparing TiO with the mass fractions of 2 percent, 6 percent, 0.4 percent and 4 percent2Mixing the butane tetracarboxylic acid, tetradecyl trimethyl ammonium chloride and sodium hypophosphite, and performing ultrasonic treatment at room temperature for 30 min;
(2) preparing a mixed solution of 7% of sodium hydroxide and 12% of urea by mass, putting a cotton fabric into the mixed solution, refrigerating the cotton fabric at the temperature of minus 10 ℃ for 1 hour at the mass ratio of 1:50, and then washing the cotton fabric to be neutral;
(3) soaking the cotton fabric washed to be neutral in the mixed dispersion liquid for 30min, then taking out the cotton fabric for dehydration, drying the cotton fabric at 80 ℃, heating to 170 ℃ and baking for 2 min.
Comparative example 1
The same pure cotton fabric as in example 1 was subjected to the following treatments:
(1) preparing TiO with the mass fractions of 2 percent, 6 percent and 4 percent2Ultrasonic treating the mixed dispersion liquid of butane tetracarboxylic acid and sodium hypophosphite for 30min at room temperature;
(2) soaking cotton fabric in the above mixed dispersion liquid for 30min, taking out, dewatering, oven drying at 80 deg.C, and heating to 170 deg.C for 2 min.
Comparative example 2
The same pure cotton fabric as in example 1 was subjected to the following treatments:
(1) preparing TiO with the mass fractions of 2 percent, 6 percent, 0.4 percent and 4 percent2Mixing the butane tetracarboxylic acid, tetradecyl trimethyl ammonium chloride and sodium hypophosphite, and performing ultrasonic treatment at room temperature for 30 min;
(2) soaking cotton fabric in the above mixed dispersion liquid for 30min, taking out, dewatering, oven drying at 80 deg.C, and heating to 170 deg.C for 2 min.
Comparative example 3
The same pure cotton fabric as in example 1 was subjected to the following treatments:
(1) preparing TiO with the mass fractions of 2 percent, 6 percent and 4 percent2Ultrasonic treating the mixed dispersion liquid of butane tetracarboxylic acid and sodium hypophosphite for 30min at room temperature;
(2) preparing a mixed solution of 7% of sodium hydroxide and 12% of urea by mass, putting a cotton fabric into the mixed solution, refrigerating the cotton fabric at the temperature of minus 10 ℃ for 1 hour at the mass ratio of 1:50, and then washing the cotton fabric to be neutral;
(3) soaking the cotton fabric washed to be neutral in the mixed dispersion liquid for 30min, then taking out the cotton fabric for dehydration, drying the cotton fabric at 80 ℃, heating to 170 ℃ and baking for 2 min.
Tests show that the TiO of the cotton fabrics treated by the comparative examples 2, 3 and 1 is compared with the most conventional comparative example 12The adhesion is respectively improved by 27 percent, 16 percent and 117 percent, the self-cleaning capability is respectively improved by 11 percent, 8 percent and 83 percent, which shows that the method of the invention effectively improves TiO2And enhances the self-cleaning effect.
Claims (1)
1. A method for improving the attachment amount of titanium dioxide on cotton fabric and the self-cleaning effect is characterized by adopting the following processes:
(1) preparing TiO with the mass fractions of 2 percent, 6 percent, 0.4 percent and 4 percent2Mixing the butane tetracarboxylic acid, tetradecyl trimethyl ammonium chloride and sodium hypophosphite, and performing ultrasonic treatment at room temperature for 30 min;
(2) preparing a mixed solution of 7% of sodium hydroxide and 12% of urea by mass, putting a cotton fabric into the mixed solution, refrigerating the cotton fabric at the temperature of minus 10 ℃ for 1 hour at the mass ratio of 1:50, and then washing the cotton fabric to be neutral;
(3) soaking the cotton fabric washed to be neutral in the mixed dispersion liquid for 30min, then taking out the cotton fabric for dehydration, drying the cotton fabric at 80 ℃, heating to 170 ℃ and baking for 2 min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911051601.4A CN110714323B (en) | 2019-10-31 | 2019-10-31 | Method for improving adhesion of titanium dioxide on cotton fabric and self-cleaning effect |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911051601.4A CN110714323B (en) | 2019-10-31 | 2019-10-31 | Method for improving adhesion of titanium dioxide on cotton fabric and self-cleaning effect |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN110714323A true CN110714323A (en) | 2020-01-21 |
| CN110714323B CN110714323B (en) | 2022-03-15 |
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| CN201911051601.4A Expired - Fee Related CN110714323B (en) | 2019-10-31 | 2019-10-31 | Method for improving adhesion of titanium dioxide on cotton fabric and self-cleaning effect |
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Citations (7)
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|---|---|---|---|---|
| US20110287245A1 (en) * | 2011-07-02 | 2011-11-24 | Ali Shamei | Water-resistant silica-embedded textiles |
| CN105002730A (en) * | 2015-08-14 | 2015-10-28 | 太仓天龙化纤有限公司 | Low-temperature dyeing and finishing technology of cottonette |
| CN105821654A (en) * | 2016-05-05 | 2016-08-03 | 东华大学 | Durable cotton fabric antifungal finishing method based on click chemistry |
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| CN108035147A (en) * | 2017-12-24 | 2018-05-15 | 青岛大学 | Pure cotton fabric is crease-resistant and the method for antibiotic property for a kind of raising |
| CN108049188A (en) * | 2017-12-23 | 2018-05-18 | 青岛大学 | Improve method of the titanium dioxide to wool/viscose glue/dacron treatment effect |
| CN109837774A (en) * | 2019-02-27 | 2019-06-04 | 温州优巴信息技术有限公司 | An a kind of one-step dyeing method of the cotton blended fabric for the dyeing that porous cellulose is microsphere modified |
-
2019
- 2019-10-31 CN CN201911051601.4A patent/CN110714323B/en not_active Expired - Fee Related
Patent Citations (7)
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|---|---|---|---|---|
| US20110287245A1 (en) * | 2011-07-02 | 2011-11-24 | Ali Shamei | Water-resistant silica-embedded textiles |
| CN105002730A (en) * | 2015-08-14 | 2015-10-28 | 太仓天龙化纤有限公司 | Low-temperature dyeing and finishing technology of cottonette |
| CN105821654A (en) * | 2016-05-05 | 2016-08-03 | 东华大学 | Durable cotton fabric antifungal finishing method based on click chemistry |
| CN106149352A (en) * | 2016-08-09 | 2016-11-23 | 东华大学 | A kind of preparation method of nano zinc oxide modified bafta |
| CN108049188A (en) * | 2017-12-23 | 2018-05-18 | 青岛大学 | Improve method of the titanium dioxide to wool/viscose glue/dacron treatment effect |
| CN108035147A (en) * | 2017-12-24 | 2018-05-15 | 青岛大学 | Pure cotton fabric is crease-resistant and the method for antibiotic property for a kind of raising |
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| 赵玉婷 等: "棉织物的防皱防紫外复合整理", 《染整技术》 * |
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| CN110714323B (en) | 2022-03-15 |
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