CN106149352A - A kind of preparation method of nano zinc oxide modified bafta - Google Patents
A kind of preparation method of nano zinc oxide modified bafta Download PDFInfo
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- CN106149352A CN106149352A CN201610646842.3A CN201610646842A CN106149352A CN 106149352 A CN106149352 A CN 106149352A CN 201610646842 A CN201610646842 A CN 201610646842A CN 106149352 A CN106149352 A CN 106149352A
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- bafta
- preparation
- zinc oxide
- solution
- oxide modified
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic System; Zincates; Cadmates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/10—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic System
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/30—Flame or heat resistance, fire retardancy properties
Abstract
The invention provides the preparation method of a kind of nano zinc oxide modified bafta, it is characterized in that, including: after bafta is carried out swelling treatment, bafta is carried out flame-proof treatment, wherein, described flame-proof treatment includes: preparation at least two zinc ion concentration scope is the solution of 10 20wt%, the zinc ion concentration of each solution, the order that bafta is incremented by according to zinc ion concentration in solution is impregnated successively in each solution, take out rear overhang and be placed in bottom one 5 15min in the hermetic container filling ammonia, then bafta is taken out nature placement and makes Ammonia valatilization, bake, clean, dry, obtain nano zinc oxide modified bafta.Raw material selected by the present invention is nontoxic or low toxicity, and the nano zine oxide generated is to human non-toxic.Simple to operate, raw material sources are extensive, cheap, and the bafta after arrangement has good fire resistance, and without formaldehyde, is the flame-retardant finishing method of a kind of environmental protection.
Description
Technical field
The present invention relates to fire-retardant setlling technology about textile field, particularly relate to a kind of nano zinc oxide modified bafta
Flame-retardant finishing method.
Background technology
Along with the continuous growth of population, urban population density increases, and the potential safety hazard especially fire hazard hidden increases.
A lot of fire are all caused by inflammable textile combustion.Studying discovery, during flammable textile combustion, release is harmful simultaneously
Gas substantially exceeds flame retardant textiles to the extent of injury of human body.If able to make inflammable textile become difficult by modification
Combustion is not even fired, then the people's lives and property will be greatly improved safely.Therefore the research of flame protection product is textile industry people
Responsibilities and obligations.
Bafta, also known as cotton, is the woven fabric with cotton yarn as raw material.Bafta becomes the most normal with excellent wearability
One of fabric, be widely used in garment material, drapery and TECHNICAL FABRIC.But its anti-flammability is always the most thorny
Problem, thus limit its application.The fire retardant of the flame-retardant modified employing of traditional bafta be essentially all containing phosphorus, nitrogen,
The compound of the elements such as halogen, in flame-proof treatment, content of formaldehyde is high, and the harmful gas after burning is many.As found containing halogen the earliest
Based flame retardant has good flame retardant effect, but when burning, easily releases zest and corrosive halogen containing halogen fire proofing
Changing hydrogen, when some contain halogen flame-retardant system at Pintsch process and burning, produce poisonous many bromo compounds, this is right
Life security constitutes serious threat, and therefore the non-halogen of fire proofing increasingly comes into one's own.Nano zine oxide is inorganic matter,
Belonging to non-combustible matter, bafta will be played certain fire-retardant effect after reaching certain degree by the content processed on bafta
Really, and nano zine oxide is harmless to environment and human non-toxic, environmental protection, and wide material sources are cheap.Therefore have certain
Practical significance.
Nano zine oxide was studied emphasis point antibiotic property all after nano zinc oxide modified bafta, UV resistance in the past
Deng some wearability, zinc oxide content on fabric can not be improved by method therefor, and can not be in cotton fiber internal holes
Gap generates substantial amounts of zinc oxide.
Summary of the invention
It is an object of the invention to provide a kind of brand-new thinking and method, get rid of traditional fire-retardant containing halogen, phosphorus, nitrogen, sulfur etc.
Agent, by chemistry, nano zine oxide is incorporated in surface of cotton fabric and cotton fiber internal void by the means of physics so that it is contain
Amount improves, and the zinc oxide of high-load serves the effect of fire retardant, imparts the flame retardant effect that bafta is good, without adding
Add any traditional fire retardant and binding agent.
In order to achieve the above object, the invention provides the preparation method of a kind of nano zinc oxide modified bafta, it is special
Levy and be, including: after bafta is carried out swelling treatment, bafta is carried out flame-proof treatment, wherein, described flame-proof treatment bag
Including: preparation at least two zinc ion concentration scope is the solution of 10-20wt%, cotton is knitted by the zinc ion concentration of each solution
The order that thing is incremented by according to zinc ion concentration in solution impregnates successively in each solution, and taking-up rear overhang is placed in bottom one and fills
The 800cm of 100ml ammonia35-15min in hermetic container, ammonia volatilizees naturally, then bafta takes out nature placement and makes ammonia
Gas volatilizees, and bakes, and cleans, and dries.
Preferably, the described solution zinc acetate that zinc ion concentration scope is 10-20wt% is prepared.
Preferably, described bafta dip time in each solution is 5-15min.
Preferably, the concentration of described ammonia is 25wt%.
Preferably, described bake as baking 2min under the conditions of 120-150 DEG C.
Preferably, described bake before, first bafta is dried under the conditions of 80 DEG C 15min.
Preferably, described drying is baking 15min under the conditions of 80 DEG C.
Preferably, before bafta is carried out swelling treatment, first bafta being carried out pretreatment, concrete steps include:
Bafta is put into process a period of time in hydrogenperoxide steam generator, rinses well with clear water after taking-up, dry under the conditions of 80 DEG C.
It is highly preferred that the concentration of described hydrogenperoxide steam generator is 3wt%, bath raio 1: 30, temperature is 40 DEG C, processes the time
For 30min.
Preferably, described swelling treatment includes: pretreated bafta is immersed in certain density sodium hydroxide
With in the mixed solution of carbamide, take out after certain time, rinse well with clear water.
It is highly preferred that the concentration of sodium hydroxide is 9wt% in the mixed solution of described sodium hydroxide and carbamide, carbamide
Concentration is 9wt%, and surplus is water, and dipping temperature is 5 DEG C, and the time is 12h.
It is highly preferred that the tension force of bafta is 2cN/cm during dipping2。
The present invention generates nano zine oxide by situ deposition method, uses pre-swollen ammonia cure facture to obtain high-load nanometer
Zinc Oxide Fabric, is incorporated into surface of cotton fabric and cotton fiber internal void by method chemically and physically by nano zine oxide
In, thus the effect that providing cotton fabric is the most fire-retardant.
Compared with prior art, the invention has the beneficial effects as follows:
Raw material selected by the present invention is nontoxic or low toxicity, and the nano zine oxide generated is to human non-toxic.Behaviour
Making simple, raw material sources are extensive, cheap, and the bafta after arrangement has good fire resistance, and without formaldehyde, is one
Plant the flame-retardant finishing method of environmental protection.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is expanded on further.Should be understood that these embodiments are merely to illustrate the present invention
Rather than restriction the scope of the present invention.In addition, it is to be understood that after having read the content that the present invention lectures, people in the art
The present invention can be made various changes or modifications by member, and these equivalent form of values fall within the application appended claims equally and limited
Scope.
Each concentration in the present invention, in addition to specified otherwise, is weight concentration.
In the present invention, bafta tension force is obtained by estimation algorithm.
Embodiment 1
The preparation method of a kind of nano zinc oxide modified bafta, concretely comprises the following steps:
(1) bafta is carried out pretreatment: bafta is put into process 30min in the hydrogenperoxide steam generator that concentration is 3%,
Temperature 40 DEG C, bath raio 1: 30, rinse well with clear water after taking-up, under the conditions of 80 DEG C, dry 15min.
(2) bafta is carried out swelling treatment: pretreated bafta is immersed in the mixing of sodium hydroxide and carbamide
In solution, take out after 12h, rinse well with clear water；In described sodium hydroxide and the mixed solution of carbamide, sodium hydroxide is dense
Degree is 9wt%, and the concentration of carbamide is 9wt%, and surplus is water, and dipping temperature is 5 DEG C, and during dipping, the tension force of bafta is 2cN/
cm2。
(3) bafta is carried out flame-proof treatment: with zinc acetate preparation zinc ion concentration be 10wt%, 11wt%, 12wt%,
The solution of 13wt%, 14wt%, 15wt%；By bafta according to zinc ion concentration in solution be incremented by order successively at each solution
Middle dipping 10min, takes out rear overhang and is placed in bottom one 5min in the hermetic container filling the ammonia that concentration is 25wt%, then by cotton
Fabric takes out nature placement and makes Ammonia valatilization, bafta dries under the conditions of 80 DEG C 15min, bakes 2min under the conditions of 150 DEG C,
Clean up with hot water afterwards, under the conditions of 80 DEG C, dry 15min, obtain nano zinc oxide modified bafta, according to the resistance of regulation
Combustion testing standard, fire resistance: after flame time 0s, glow time 65.0s, damages the long 6.3cm of charcoal.
Embodiment 2
The preparation method of a kind of nano zinc oxide modified bafta, concretely comprises the following steps:
(1) bafta is carried out pretreatment: bafta is put into process 30min in the hydrogenperoxide steam generator that concentration is 3%,
Temperature 40 DEG C, bath raio 1: 30, rinse well with clear water after taking-up, under the conditions of 80 DEG C, dry 15min.
(2) bafta is carried out swelling treatment: pretreated bafta is immersed in the mixing of sodium hydroxide and carbamide
In solution, take out after 12h, rinse well with clear water；In described sodium hydroxide and the mixed solution of carbamide, sodium hydroxide is dense
Degree is 9wt%, and the concentration of carbamide is 9wt%, and surplus is water, and dipping temperature is 5 DEG C, and during dipping, the tension force of bafta is 2cN/
cm2。
(3) bafta is carried out flame-proof treatment: with zinc acetate preparation zinc ion concentration be 10wt%, 11wt%, 12wt%,
The solution of 13wt%, 14wt%, 15wt%；By bafta according to zinc ion concentration in solution be incremented by order successively at each solution
Middle dipping 10min, takes out rear overhang and is placed in bottom one 10min in the hermetic container filling the ammonia that concentration is 25wt%, then will
Bafta takes out nature placement and makes Ammonia valatilization, bafta dries under the conditions of 80 DEG C 15min, bakes under the conditions of 150 DEG C
2min, cleans up with hot water afterwards, dries 15min, obtain nano zinc oxide modified bafta, according to the rules under the conditions of 80 DEG C
Flame-retardant test criteria, fire resistance: after flame time 0s, glow time 54.6s, damage the long 5.9cm of charcoal.
Embodiment 3
The preparation method of a kind of nano zinc oxide modified bafta, concretely comprises the following steps:
(1) bafta is carried out pretreatment: bafta is put into process 30min in the hydrogenperoxide steam generator that concentration is 3%,
Temperature 40 DEG C, bath raio 1: 30, rinse well with clear water after taking-up, under the conditions of 80 DEG C, dry 15min.
(2) bafta is carried out swelling treatment: pretreated bafta is immersed in the mixing of sodium hydroxide and carbamide
In solution, take out after 12h, rinse well with clear water；In described sodium hydroxide and the mixed solution of carbamide, sodium hydroxide is dense
Degree is 9wt%, and the concentration of carbamide is 9wt%, and surplus is water, and dipping temperature is 5 DEG C, and during dipping, the tension force of bafta is 2cN/
cm2。
(3) bafta is carried out flame-proof treatment: with zinc acetate preparation zinc ion concentration be 10wt%, 11wt%, 12wt%,
The solution of 13wt%, 14wt%, 15wt%；By bafta according to zinc ion concentration in solution be incremented by order successively at each solution
Middle dipping 10min, takes out rear overhang and is placed in bottom one 15min in the hermetic container filling the ammonia that concentration is 25wt%, then will
Bafta takes out nature placement and makes Ammonia valatilization, bafta dries under the conditions of 80 DEG C 15min, bakes under the conditions of 150 DEG C
2min, cleans up with hot water afterwards, dries 15min, obtain nano zinc oxide modified bafta, according to the rules under the conditions of 80 DEG C
Flame-retardant test criteria, fire resistance: after flame time 0s, glow time 53.2s, damage the long 6.0.cm of charcoal.
Embodiment 4
The preparation method of a kind of nano zinc oxide modified bafta, concretely comprises the following steps:
(1) bafta is carried out pretreatment: bafta is put into process 30min in the hydrogenperoxide steam generator that concentration is 3%,
Temperature 40 DEG C, bath raio 1: 30, rinse well with clear water after taking-up, under the conditions of 80 DEG C, dry 15min.
(2) bafta is carried out swelling treatment: pretreated bafta is immersed in the mixing of sodium hydroxide and carbamide
In solution, take out after 12h, rinse well with clear water；In described sodium hydroxide and the mixed solution of carbamide, sodium hydroxide is dense
Degree is 9wt%, and the concentration of carbamide is 9wt%, and surplus is water, and dipping temperature is 5 DEG C, and during dipping, the tension force of bafta is 2cN/
cm2。
(3) bafta is carried out flame-proof treatment: with zinc acetate preparation zinc ion concentration be 10wt%, 11wt%, 12wt%,
The solution of 13wt%, 14wt%, 15wt%；By bafta according to zinc ion concentration in solution be incremented by order successively at each solution
Middle dipping 10min, takes out rear overhang and is placed in bottom one 10min in the hermetic container filling the ammonia that concentration is 25wt%, then will
Bafta takes out nature placement and makes Ammonia valatilization, bafta dries under the conditions of 80 DEG C 15min, bakes under the conditions of 120 DEG C
2min, cleans up with hot water afterwards, dries 15min, obtain nano zinc oxide modified bafta, according to the rules under the conditions of 80 DEG C
Flame-retardant test criteria, fire resistance: after flame time 0s, glow time 59.2s, damage the long 6.1cm of charcoal.
Embodiment 5
The preparation method of a kind of nano zinc oxide modified bafta, concretely comprises the following steps:
(1) bafta is carried out pretreatment: bafta is put into process 30min in the hydrogenperoxide steam generator that concentration is 3%,
Temperature 40 DEG C, bath raio 1: 30, rinse well with clear water after taking-up, under the conditions of 80 DEG C, dry 15min.
(2) bafta is carried out swelling treatment: pretreated bafta is immersed in the mixing of sodium hydroxide and carbamide
In solution, take out after 12h, rinse well with clear water；In described sodium hydroxide and the mixed solution of carbamide, sodium hydroxide is dense
Degree is 9wt%, and the concentration of carbamide is 9wt%, and surplus is water, and dipping temperature is 5 DEG C, and during dipping, the tension force of bafta is 2cN/
cm2。
(3) bafta is carried out flame-proof treatment: with zinc acetate preparation zinc ion concentration be 15wt%, 16wt%, 17wt%,
The solution of 18wt%, 19wt%, 20wt%；By bafta according to zinc ion concentration in solution be incremented by order successively at each solution
Middle dipping 10min, takes out rear overhang and is placed in bottom one 10min in the hermetic container filling the ammonia that concentration is 25wt%, then will
Bafta takes out nature placement and makes Ammonia valatilization, bafta dries under the conditions of 80 DEG C 15min, bakes under the conditions of 150 DEG C
2min, cleans up with hot water afterwards, dries 15min, obtain nano zinc oxide modified bafta, according to the rules under the conditions of 80 DEG C
Flame-retardant test criteria, fire resistance: after flame time 0s, glow time 33.6s, damage the long 3.5cm of charcoal.
Claims (10)
1. the preparation method of a nano zinc oxide modified bafta, it is characterised in that including: bafta is carried out swelling treatment
After, bafta is carried out flame-proof treatment, wherein, described flame-proof treatment includes: preparation at least two zinc ion concentration scope is
The solution of 10-20wt%, the zinc ion concentration of each solution, the order that bafta is incremented by according to zinc ion concentration in solution
Impregnate in each solution successively, take out rear overhang and be placed in bottom one 5-15min in the hermetic container filling ammonia, then by bafta
Take out nature placement and make Ammonia valatilization, bake, clean, dry, obtain nano zinc oxide modified bafta.
The preparation method of nano zinc oxide modified bafta the most as claimed in claim 1, it is characterised in that described zinc ion
Concentration range is that the solution zinc acetate of 10-20wt% is prepared.
The preparation method of nano zinc oxide modified bafta the most as claimed in claim 1, it is characterised in that described bafta
Dip time in each solution is 5-15min.
The preparation method of nano zinc oxide modified bafta the most as claimed in claim 1, it is characterised in that described ammonia
Concentration is 25wt%.
The preparation method of nano zinc oxide modified bafta the most as claimed in claim 1, it is characterised in that described bake for
2min is baked under the conditions of 120-150 DEG C.
The preparation method of nano zinc oxide modified bafta the most as claimed in claim 1, it is characterised in that described bakes it
Before, first bafta is dried under the conditions of 80 DEG C 15min.
The preparation method of nano zinc oxide modified bafta the most as claimed in claim 1, it is characterised in that bafta is being entered
Before row swelling treatment, first bafta being carried out pretreatment, concrete steps include: put into by bafta in hydrogenperoxide steam generator and locate
Reason a period of time, rinse well with clear water after taking-up, dry under the conditions of 80 DEG C.
The preparation method of nano zinc oxide modified bafta the most as claimed in claim 7, it is characterised in that described peroxidating
The concentration of hydrogen solution is 3wt%, bath raio 1: 30, and temperature is 40 DEG C, and the process time is 30min.
The preparation method of nano zinc oxide modified bafta the most as claimed in claim 1, it is characterised in that described swelling place
Reason includes: be immersed in the mixed solution of certain density sodium hydroxide and carbamide by pretreated bafta, certain time
Rear taking-up, rinses well with clear water.
The preparation method of nano zinc oxide modified bafta the most as claimed in claim 9, it is characterised in that described hydrogen-oxygen
Changing the concentration of sodium hydroxide in the mixed solution of sodium and carbamide is 9wt%, and the concentration of carbamide is 9wt%, and surplus is water, dipping temperature
Degree is 5 DEG C, and the time is 12h.
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| CN201610646842.3A CN106149352B (en) | 2016-08-09 | 2016-08-09 | A kind of preparation method of nano zinc oxide modified cotton fabric |
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| CN201610646842.3A CN106149352B (en) | 2016-08-09 | 2016-08-09 | A kind of preparation method of nano zinc oxide modified cotton fabric |
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| CN106894231A (en) * | 2017-02-27 | 2017-06-27 | 东华大学 | A kind of preparation method of the flax spinning material with air-cleaning function |
| CN108058438A (en) * | 2017-12-19 | 2018-05-22 | 航天科工武汉磁电有限责任公司 | A kind of lighting radar invisible of resistance to ablation structural member and its application |
| CN108842258A (en) * | 2018-07-05 | 2018-11-20 | 惠州市恒吉纺织品有限公司 | Flame retardant fabric with comfort |
| CN108930156A (en) * | 2018-07-10 | 2018-12-04 | 安徽玉然经编科技有限公司 | A method of long acting antibiotic household items are made with the composite modified cotton fiber of halogen amine-amination |
| CN109082879A (en) * | 2018-07-05 | 2018-12-25 | 惠州市恒吉纺织品有限公司 | Flame retardant fabric and its processing technology with comfort |
| CN110656487A (en) * | 2019-10-31 | 2020-01-07 | 青岛大学 | Method for improving attachment capacity and ultraviolet resistance of titanium dioxide on cotton fabric |
| CN110714323A (en) * | 2019-10-31 | 2020-01-21 | 青岛大学 | Method for improving adhesion of titanium dioxide on cotton fabric and self-cleaning effect |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106894231A (en) * | 2017-02-27 | 2017-06-27 | 东华大学 | A kind of preparation method of the flax spinning material with air-cleaning function |
| CN106894231B (en) * | 2017-02-27 | 2019-08-06 | 东华大学 | A kind of preparation method of the flax spinning material with air-cleaning function |
| CN108058438A (en) * | 2017-12-19 | 2018-05-22 | 航天科工武汉磁电有限责任公司 | A kind of lighting radar invisible of resistance to ablation structural member and its application |
| CN108842258A (en) * | 2018-07-05 | 2018-11-20 | 惠州市恒吉纺织品有限公司 | Flame retardant fabric with comfort |
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| CN108930156A (en) * | 2018-07-10 | 2018-12-04 | 安徽玉然经编科技有限公司 | A method of long acting antibiotic household items are made with the composite modified cotton fiber of halogen amine-amination |
| CN110656487A (en) * | 2019-10-31 | 2020-01-07 | 青岛大学 | Method for improving attachment capacity and ultraviolet resistance of titanium dioxide on cotton fabric |
| CN110714323A (en) * | 2019-10-31 | 2020-01-21 | 青岛大学 | Method for improving adhesion of titanium dioxide on cotton fabric and self-cleaning effect |
| CN110714323B (en) * | 2019-10-31 | 2022-03-15 | 青岛大学 | Method for improving adhesion of titanium dioxide on cotton fabric and self-cleaning effect |
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