Background
The statements in this section merely provide background information related to the present disclosure and may not necessarily constitute prior art.
Ozone is a substance with very strong oxidizing ability, and when other substances (except fluorine) are encountered, the substances can be oxidized and the ozone can be decomposed into oxygen, so that special attention needs to be paid to how to reduce the oxidative decomposition of the ozone during heating, and the concentration of the ozone gas after heating can not be reduced only by reducing the decomposition of the ozone. Ozone gas has a short half-life at room temperature, and decomposition prevention is a problem to be considered particularly in ozone heating.
Experiments show that the half-life period is about 10 hours at 26-27 ℃, about 14-16 hours at 24.5-25 ℃, and about 14-20 hours at 19.5-20.0 ℃. This indicates that the activity of ozone (the oxidizing power of ozone) shows an exponential nonlinear rapid increase with increasing temperature, and the activity increases dramatically. In the practical application of ozone, the oxidation capability of ozone at normal temperature can not meet the needs of people. For example, ozone is used to treat wastewater and oxidize impurities in wastewater, and there are two phenomena, one is slow and the other is poor reaction effect, so people have to research a new technology, namely an ozone catalyst, to improve the oxidizing ability of ozone, so as to achieve the purposes of quick oxidation and treatment effect improvement. Ozone is then used, for example, to decompose photoresist in the production of integrated circuits. At normal temperature, the time for decomposing the photoresist by ozone is too long, and the photoresist is not clean and is easy to remain. However, the time for decomposing the photoresist after increasing the temperature of ozone (about 80 ℃) is short, and the photoresist is clean and has no residue. It is a pursuit goal to increase the operating temperature of ozone to achieve high oxidation capacity of ozone.
The inventor finds that the conventional heating device generally only considers that the heating material is heated to the set temperature, calculates the quantity and the temperature value of the heating material and the required heating electric power, does not consider the temperature field distribution of the heating device, and does not consider the connection between the heating device and the normal temperature. When the heating mass enters the heating device, it encounters a temperature difference or several temperature difference steps, which is actually a step of energy (electrical heating). When the heating substance is excited by the energy step, the quantum transition of the substance molecule occurs, and the ozone molecule is decomposed due to the quantum transition of the substance molecule.
Disclosure of Invention
In order to solve the above problems, a first aspect of the present disclosure provides an ozone heating apparatus, in which a polytetrafluoroethylene coating is coated on a tube wall of a heating tube, so as to prevent ozone from chemically reacting with the tube wall of the heating tube during heating; meanwhile, the inner wall of the heating pipe is provided with thread-shaped grooves which are arranged in parallel in an arithmetic progression manner, continuous and uninterrupted heating elements are laid in the thread-shaped grooves, and the heating elements are used for heating ozone in the heating pipe, so that the temperature on the pipe wall of the heating pipe is gradually increased along the direction from the ozone inlet to the ozone outlet, and the generation of high-temperature hot spot sources is avoided.
In order to achieve the purpose, the following technical scheme is adopted in the disclosure:
an ozone heating device comprising:
the pipe wall of the heating pipe is coated with a polytetrafluoroethylene coating; one end of the heating pipe is an ozone inlet, and the other end of the heating pipe is an ozone outlet; the pipe wall of the heating pipe is provided with thread-shaped grooves which are parallel to each other, and the intervals of the thread-shaped grooves are arranged in a descending manner from an ozone inlet to an ozone outlet according to an arithmetic progression; and a continuous heating element is laid in the thread-shaped groove and used for heating ozone in the heating pipe, so that the temperature on the pipe wall of the heating pipe is gradually increased along the direction from the ozone inlet to the ozone outlet.
Further, the temperature at the ozone inlet is 25 degrees celsius and the temperature at the ozone outlet is T, wherein the temperature of T is greater than 25 degrees celsius.
Further, the heating element generates heat from the ozone inlet to the ozone outlet that is less than or equal to the known energy required for the ozone to generate an electronic transition and greater than or equal to the energy absorbed by the ozone; wherein the energy absorbed by the ozone is equal to the product of the specific heat capacity of the ozone and the difference between the temperature at the ozone outlet and the temperature at the ozone inlet.
Further, the heating element is a heating wire.
Further, the electric heating wire is connected with a power circuit, and the output voltage of the power circuit is adjustable.
Further, a temperature sensor is arranged at the ozone outlet and used for detecting the temperature at the ozone outlet.
Further, the resistance value of the heating element is fixed.
A second aspect of the present disclosure provides a method of operating an ozone heating apparatus.
An operating method of an ozone heating device comprises the following steps:
step 1: a testing stage;
step 1.1: starting the heating element, and detecting the temperature T at the ozone outlet after a preset time delta T;
step 1.2: calculating the energy Q absorbed by the ozone according to the product of the specific heat capacity C of the ozone and the difference between the temperature T at the ozone outlet and the temperature T0 at the ozone inletSuction device;
Step 1.3: calculating the heat Q generated by the heating element from the ozone inlet to the ozone outlet according to the voltage U at the two ends of the heating element and the fixed resistance R of the heating elementProduct produced by birth=Δt*U2/R;
Step 1.4:energy Q required for electron transition in ozone generation is knownJumping overThen, Q is judgedSuction device≤QProduct produced by birth≤QJumping overIf yes, entering a heating stage; otherwise, adjusting the voltage U across the heating element to QSuction device≤QProduct produced by birth≤QJumping overEntering a heating stage;
step 2: a heating stage:
and introducing ozone into the heating pipe and heating the ozone.
The beneficial effects of this disclosure are:
(1) the polytetrafluoroethylene coating is coated on the pipe wall of the heating pipe, so that the chemical reaction between ozone and the pipe wall of the heating pipe during heating is avoided; meanwhile, the inner wall of the heating pipe is provided with thread-shaped grooves which are arranged in parallel in an arithmetic progression manner, continuous and uninterrupted heating elements are laid in the thread-shaped grooves, and the heating elements are used for heating ozone in the heating pipe, so that the temperature on the pipe wall of the heating pipe is gradually increased along the direction from the ozone inlet to the ozone outlet, the generation of high-temperature hot point sources is avoided, and the ozone decomposition is prevented.
(2) The inlet temperature and the outlet temperature of the ozone heating device of the present disclosure are different; no temperature step occurred throughout the heating process from ambient temperature to the outlet.
Detailed Description
The present disclosure is further described with reference to the following drawings and examples.
It should be noted that the following detailed description is exemplary and is intended to provide further explanation of the disclosure. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this disclosure belongs.
It is noted that the terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of example embodiments according to the present disclosure. As used herein, the singular forms "a", "an" and "the" are intended to include the plural forms as well, and it should be understood that when the terms "comprises" and/or "comprising" are used in this specification, they specify the presence of stated features, steps, operations, devices, components, and/or combinations thereof, unless the context clearly indicates otherwise.
In the present disclosure, terms such as "upper", "lower", "left", "right", "front", "rear", "vertical", "horizontal", "side", "bottom", and the like indicate orientations or positional relationships based on those shown in the drawings, and are only relational terms determined for convenience in describing structural relationships of the parts or elements of the present disclosure, and do not refer to any parts or elements of the present disclosure, and are not to be construed as limiting the present disclosure.
In the present disclosure, terms such as "fixedly connected", "connected", and the like are to be understood in a broad sense, and mean either a fixed connection or an integrally connected or detachable connection; may be directly connected or indirectly connected through an intermediate. The specific meanings of the above terms in the present disclosure can be determined on a case-by-case basis by persons skilled in the relevant art or technicians, and are not to be construed as limitations of the present disclosure.
As known from the background art, there is no way to heat ozone due to the restriction that the decomposition of ozone at high temperature is rapidly promoted. To date there is no established solution to achieve heating of ozone. According to quantum mechanics, heating is a change of the spin state of molecules, if the electron orbit of an atom is violently collided by the outside, the rotation of the atom is in an excited state, and the change of the electron orbit of the atom is a process that ozone molecules are decomposed and are re-synthesized into oxygen molecules. Heating of ozone in such a heating device entails decomposition of the ozone. Therefore, the distribution of the heating temperature field of the ozone heating device is necessarily considered in an important way, so that the occurrence and the existence of large temperature difference are prevented, and the smooth connection between the heating temperature field of the ozone heating device and the ambient temperature is realized. The absence of quantum transitions of species molecules is an important conceptual approach to ozone heating devices.
In order to solve the above problems, the present embodiment provides an ozone heating apparatus.
As shown in fig. 1, an ozone heating apparatus of the present embodiment includes:
the heating pipe comprises a heating pipe 1, wherein a polytetrafluoroethylene coating is coated on the inner wall of the heating pipe 1; one end of the heating pipe 1 is an ozone inlet, and the other end of the heating pipe is an ozone outlet; the pipe wall of the heating pipe 1 is provided with thread-shaped grooves 2, the thread-shaped grooves 2 are parallel to each other, and the thread-shaped groove intervals 2 are arranged in a descending manner from an ozone inlet to an ozone outlet according to an arithmetic progression; and a continuous heating element is laid in the thread-shaped groove and used for heating ozone in the heating pipe, so that the temperature on the pipe wall of the heating pipe is gradually increased along the direction from the ozone inlet to the ozone outlet.
In specific implementation, the thread-shaped groove is arranged on the inner side or the outer side of the tube wall of the heating tube.
Specifically, the heating tube is a metal tube, such as aluminum or copper.
In a specific implementation, the temperature at the ozone inlet is 25 degrees celsius and the temperature at the ozone outlet is T, wherein T is greater than 25 degrees celsius.
Therefore, the ozone can be slowly heated from the normal temperature of 25 ℃ without sudden change, and the problem of chemical characteristic failure caused by ozone decomposition is avoided.
Wherein the heat generated by the heating element from the ozone inlet to the ozone outlet is less than or equal to the known energy required for the ozone to generate electron transitions and greater than or equal to the energy absorbed by the ozone; under the condition, the ozone can be ensured not to be chemically decomposed while being heated.
Heat Q generated by the heating element from the ozone inlet to the ozone outletProduct produced by birth=Δt*U2/R;
Wherein, Δ t is a heating time period; u is the sum of the voltages at the two ends of the heating element; r is the fixed resistance of the thermal element.
Energy Q required for electron transition of ozone generationJumping overIs a known amount; according to the product of the difference between the temperature T at the ozone outlet and the temperature T0 at the ozone inlet and the specific heat capacity C of the ozone, the energy Q absorbed by the ozone can be calculatedSuction device。
In this embodiment, the heating element is a heating wire. Wherein the resistance value of the heating element is fixed.
It should be noted that in other embodiments, the heating element may be other heating elements with fixed resistance.
In a specific implementation, the heating wire is connected with a power circuit, and the output voltage of the power circuit is adjustable.
And a temperature sensor is arranged at the ozone outlet and used for detecting the temperature at the ozone outlet.
The working method of the ozone heating device of the embodiment comprises the following steps:
step 1: a testing stage;
step 1.1: starting the heating element, and detecting the temperature T at the ozone outlet after a preset time delta T;
step 1.2: calculating the energy Q absorbed by the ozone according to the product of the specific heat capacity C of the ozone and the difference between the temperature T at the ozone outlet and the temperature T0 at the ozone inletSuction device;
Step 1.3: calculating the heat Q generated by the heating element from the ozone inlet to the ozone outlet according to the voltage U at the two ends of the heating element and the fixed resistance R of the heating elementProduct produced by birth=Δt*U2/R;
Step 1.4: energy Q required for electron transition in ozone generation is knownJumping overThen, Q is judgedSuction device≤QProduct produced by birth≤QJumping overIf yes, entering a heating stage; otherwise, adjusting the voltage U across the heating element to QSuction device≤QProduct produced by birth≤QJumping overEntering a heating stage;
step 2: a heating stage:
and introducing ozone into the heating pipe and heating the ozone.
In the embodiment, the pipe wall of the heating pipe is coated with the polytetrafluoroethylene coating, so that the chemical reaction between ozone and the pipe wall of the heating pipe during heating is avoided; meanwhile, the inner wall of the heating pipe is provided with thread-shaped grooves which are arranged in parallel in an arithmetic progression manner, continuous and uninterrupted heating elements are laid in the thread-shaped grooves, and the heating elements are used for heating ozone in the heating pipe, so that the temperature on the pipe wall of the heating pipe is gradually increased along the direction from the ozone inlet to the ozone outlet, the generation of high-temperature hot point sources is avoided, and the ozone decomposition is prevented.
The inlet temperature and the outlet temperature of the ozone heating device of the embodiment are different; no temperature step occurred throughout the heating process from ambient temperature to the outlet.
The above description is only a preferred embodiment of the present disclosure and is not intended to limit the present disclosure, and various modifications and changes may be made to the present disclosure by those skilled in the art. Any modification, equivalent replacement, improvement and the like made within the spirit and principle of the present disclosure should be included in the protection scope of the present disclosure.