CN110676055A - Two-step impregnation preparation method of hybrid aluminum electrolytic capacitor - Google Patents

Two-step impregnation preparation method of hybrid aluminum electrolytic capacitor Download PDF

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Publication number
CN110676055A
CN110676055A CN201910976043.6A CN201910976043A CN110676055A CN 110676055 A CN110676055 A CN 110676055A CN 201910976043 A CN201910976043 A CN 201910976043A CN 110676055 A CN110676055 A CN 110676055A
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impregnation
core package
capacitor
electrolytic capacitor
aluminum electrolytic
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严凯
陈镇权
詹光耀
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Xiamen Farah And Xin Electronics Co Ltd
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Xiamen Farah And Xin Electronics Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G9/00Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
    • H01G9/0029Processes of manufacture
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G9/00Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
    • H01G9/145Liquid electrolytic capacitors
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/13Energy storage using capacitors

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  • Power Engineering (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Manufacturing & Machinery (AREA)
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Abstract

The invention discloses a two-step impregnation preparation method of a hybrid aluminum electrolytic capacitor, which comprises the following steps: manufacturing a core package for a capacitor; the obtained core package was impregnated to PEDOT: PSS and other mixed liquid are subjected to positive and negative cyclic pressurization through external pressurization equipment to obtain a core package subjected to primary impregnation; drying the obtained core cladding subjected to preliminary impregnation at a high temperature to obtain a dried core cladding; impregnating the obtained dried core cladding into conventional electrolyte again to obtain a core cladding subjected to secondary impregnation; the electrolyte of the invention adopts PEDOT: PSS and other mixed liquor, and due to the high conductivity of the mixed liquor, the speed of primary impregnation of the core bag is greatly increased; meanwhile, the method of positive and negative pressure circulating impregnation is adopted during the primary impregnation, so that the suspension can be uniformly dispersed and permeated into microscopic holes of the aluminum foil, the speed and effect of the primary impregnation are improved, the production time is reduced, and the production efficiency is improved.

Description

Two-step impregnation preparation method of hybrid aluminum electrolytic capacitor
Technical Field
The invention relates to the technical field of preparation of hybrid aluminum electrolytic capacitors, in particular to a two-step impregnation preparation method of a hybrid aluminum electrolytic capacitor.
Background
Compared with the common lead-type aluminum electrolytic capacitor, the conductive polymer solid aluminum electrolytic capacitor has the characteristics of extremely low ESR and excellent high-frequency filtering performance, and the application of the conductive polymer solid aluminum electrolytic capacitor in the fields of computer motherboards, game machines, high-end digital products, chargers and the like is rapidly increasing in recent years.
However, most of the existing conventional liquid aluminum electrolytic capacitors have the problems that the impedance level cannot be greatly reduced and the conventional liquid aluminum electrolytic capacitors cannot be further applied to a driving power supply requiring extremely low loss; the solid capacitor has large leakage and no repairability, and the material and manufacturing cost of the solid capacitor is high, so that the application of the solid capacitor is greatly hindered, and the conventional solid-liquid mixed capacitor is long in manufacturing time and low in production efficiency. Based on the above, the invention designs a two-step impregnation preparation method of a hybrid aluminum electrolytic capacitor, so as to solve the above problems.
Disclosure of Invention
The invention aims to provide a two-step impregnation preparation method of a hybrid aluminum electrolytic capacitor, so as to solve the technical problems.
In order to achieve the purpose, the invention provides the following technical scheme: a two-step impregnation preparation method of a hybrid aluminum electrolytic capacitor comprises the following steps:
s1: manufacturing a core package for a capacitor;
s2: impregnating the core package obtained in step S1 into PEDOT: PSS and other mixed liquid are subjected to positive and negative cyclic pressurization through external pressurization equipment to obtain a core package subjected to primary impregnation;
s3: drying the preliminarily impregnated core package obtained in the step S2 at a high temperature to obtain a dried core package;
s4: impregnating the dried core package obtained in the step S3 into conventional electrolyte again to obtain a core package subjected to secondary impregnation;
s5: and (5) assembling and aging the core cladding subjected to secondary impregnation obtained in the step (S4) to form a finished product of the hybrid aluminum electrolytic capacitor.
Preferably, in the step S2, during the positive-negative cyclic pressurization by the external pressurization device, the positive pressure is controlled to be between 0.5bar ~ 60bar, and the negative pressure is controlled to be between 13mbar ~ 98mbar and 98 mbar.
Preferably, the step S1 specifically includes: the guide pin is riveted on the aluminum foil through a coil nailing machine, the anode aluminum foil, the cathode foil and the isolation paper are wound into a core package, and the isolation paper is arranged between the anodized aluminum foil and the cathode foil.
Preferably, the step S5 specifically includes: assembling the impregnated core package obtained in the step S4 into a capacitor shell, and sealing the capacitor shell through a rubber plug to obtain a semi-finished capacitor; and aging and charging the semi-finished product capacitor to form the finished product mixed type aluminum electrolytic capacitor.
Preferably, the drying temperature in the step S3 is between 60 ~ 180 ℃ and the drying time is 5 ~ 60 min.
Compared with the prior art, the invention has the beneficial effects that:
the electrolyte in the invention adopts PEDOT: PSS and other mixed liquor, and due to the high conductivity of the mixed liquor, the speed of primary impregnation of the core bag is greatly increased; meanwhile, the suspension can be uniformly dispersed and permeated into microscopic holes of the aluminum foil by adopting a positive and negative pressure circulating impregnation method during primary impregnation, so that the primary impregnation speed and effect are improved, the production time is reduced, and the production efficiency is improved; meanwhile, the hybrid aluminum electrolytic capacitor manufactured by the manufacturing method has high stability and good repairability, thereby improving the application range of the solid-liquid hybrid capacitor.
Drawings
In order to more clearly illustrate the technical solutions of the embodiments of the present invention, the drawings used in the description of the embodiments will be briefly introduced below, and it is obvious that the drawings in the following description are only some embodiments of the present invention, and it is obvious for those skilled in the art that other drawings can be obtained according to the drawings without creative efforts.
FIG. 1 is a flow chart of a manufacturing method of the present invention.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Referring to fig. 1, the present invention provides a technical solution: in particular to a two-step impregnation preparation method of a hybrid aluminum electrolytic capacitor, which comprises the following steps:
s1: manufacturing a core package for a capacitor;
s2: impregnating the core package obtained in step S1 into PEDOT: PSS and other mixed liquid are subjected to positive and negative cyclic pressurization through external pressurization equipment to obtain a core package subjected to primary impregnation;
s3: drying the preliminarily impregnated core package obtained in the step S2 at a high temperature to obtain a dried core package;
s4: impregnating the dried core packet obtained in the step S3 into a conventional liquid electrolyte again to obtain a core packet subjected to secondary impregnation;
s5: and (5) assembling and aging the core cladding subjected to secondary impregnation obtained in the step (S4) to form the finished product of the solid-liquid hybrid capacitor.
Specifically, in the process of positive and negative cyclic pressurization by external pressurization equipment in step S2, the positive pressure is preferably controlled to be 0.5bar ~ 60bar, and the negative pressure is preferably controlled to be 13mbar ~ 98mbar, and the positive and negative pressures are respectively controlled to be in appropriate working intervals, so that the suspension can be rapidly and uniformly dispersed and infiltrated into the micro-holes of the aluminum foil.
Specifically, step S1 specifically includes: the guide pin is riveted on the aluminum foil through a coil nailing machine, the anode aluminum foil, the cathode foil and the isolation paper are wound into a core package, and the isolation paper is arranged between the anodized aluminum foil and the cathode foil.
Specifically, step S5 specifically includes: assembling the impregnated core package obtained in the step S4 into a capacitor shell, and sealing the capacitor shell through a rubber plug to obtain a semi-finished capacitor; and aging and charging the semi-finished product capacitor to form the finished product mixed type aluminum electrolytic capacitor.
Specifically, the temperature for drying in step S3 is 60 ~ 180 ℃, the time for drying is 5 ~ 60min, and high-temperature drying is performed in the temperature interval and the drying time period, so that the optimal core package can be obtained.
In the first embodiment, when the hybrid aluminum electrolytic capacitor is manufactured, a guide pin is riveted on an aluminum foil through a coil nailing machine, an anode aluminum foil, a cathode foil and an isolation paper are wound into a core package, then the manufactured core package is impregnated into a mixed solution of PEDOT, PSS and the like, and because the PEDOT, PSS (a mixed solution of 3, 4-ethylene dioxythiophene monomer and polystyrene sulfonate) is a high-molecular polymer aqueous solution with high conductivity, the speed of primary core package impregnation is greatly improved, then the primarily impregnated core package is dried at the temperature of 60 ~ 180 ℃ for 5 ~ 60min to obtain a dried core package, then the dried core package is impregnated into a conventional electrolyte to obtain a secondarily impregnated core package, then the impregnated core package is assembled into a capacitor shell, the capacitor shell is sealed through a rubber plug to obtain a semi-finished capacitor, and the semi-finished capacitor is aged and charged to form the hybrid aluminum electrolytic capacitor.
The prepared mixed type aluminum electrolytic capacitor is respectively subjected to the following two groups of tests:
testing one: the hybrid aluminum electrolytic capacitor of the present invention, the liquid aluminum electrolytic capacitor and the solid aluminum electrolytic capacitor of the same specification are placed in the same working environment for test comparison, and the obtained test data is shown in table 1 (taking the capacitor of the specification of 35V220UF as an example):
TABLE 1
Figure 992485DEST_PATH_IMAGE001
From the test comparison data set out in table 1 we can conclude that:
1. compared with a solid-state aluminum electrolytic capacitor: the leakage current is greatly reduced;
2. compared with the liquid aluminum electrolytic capacitor, the loss is reduced, and the impedance is greatly reduced by about 30 ~ 80% (depending on different proportions of solutes)
Therefore, the hybrid aluminum electrolytic capacitor obtained by the manufacturing method has high stability and good repairability according to test data.
And (2) testing: after the test data of the hybrid aluminum electrolytic capacitor of the invention when not in operation is recorded, the hybrid aluminum electrolytic capacitor of the invention is placed in a specific working environment to work for a period of time, the same test data is recorded, and the two times of data are analyzed and compared to obtain the test data shown in table 2 (taking 35Vdc as an example of a working environment at 105 ℃):
TABLE 2
Figure 785604DEST_PATH_IMAGE002
From the experimental data set out in table 2 we can conclude that: the mixed type aluminum electrolytic capacitor produced by the manufacturing method has the characteristic of high stability, namely after the mixed type aluminum electrolytic capacitor works for a period of time in a specific working environment, the normal-temperature test electrical property data of the solid-liquid mixed capacitor is the same as that of the initial stage.
In the description of the present invention, it is to be understood that the terms "coaxial", "bottom", "one end", "top", "middle", "other end", "upper", "one side", "top", "inner", "front", "center", "both ends", and the like, indicate orientations or positional relationships based on the drawings, and are only for convenience of description and simplicity of description, and do not indicate or imply that the referred device or element must have a particular orientation, be constructed and operated in a particular orientation, and thus, should not be construed as limiting the present invention.
In the present invention, unless otherwise expressly specified or limited, the terms "mounted," "disposed," "connected," "secured," "screwed" and the like are to be construed broadly, e.g., as meaning fixedly connected, detachably connected, or integrally formed; can be mechanically or electrically connected; the terms may be directly connected or indirectly connected through an intermediate, and may be communication between two elements or interaction relationship between two elements, unless otherwise specifically limited, and the specific meaning of the terms in the present invention will be understood by those skilled in the art according to specific situations.
Although embodiments of the present invention have been shown and described, it would be appreciated by those skilled in the art that changes may be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the claims and their equivalents.

Claims (5)

1. A two-step impregnation preparation method of a hybrid aluminum electrolytic capacitor is characterized by comprising the following steps: the method comprises the following steps:
s1: manufacturing a core package for a capacitor;
s2: impregnating the core package obtained in step S1 into PEDOT: PSS and other mixed liquid are subjected to positive and negative cyclic pressurization through external pressurization equipment to obtain a core package subjected to primary impregnation;
s3: drying the preliminarily impregnated core package obtained in the step S2 at a high temperature to obtain a dried core package;
s4: impregnating the dried core package obtained in the step S3 into conventional electrolyte again to obtain a core package subjected to secondary impregnation;
s5: and (5) assembling and aging the core cladding subjected to secondary impregnation obtained in the step (S4) to form a finished product of the hybrid aluminum electrolytic capacitor.
2. A two-step impregnation preparation method of a hybrid aluminum electrolytic capacitor is characterized in that in the process of carrying out positive and negative circulation pressurization through external pressurization equipment in the step S2, positive pressure is preferably controlled to be 0.5bar ~ 60bar, and negative pressure is preferably controlled to be 13mbar ~ 98 mbar.
3. A two-step impregnation preparation method of a hybrid aluminum electrolytic capacitor is characterized by comprising the following steps: the step S1 specifically includes: the guide pin is riveted on the aluminum foil through a coil nailing machine, the anode aluminum foil, the cathode foil and the isolation paper are wound into a core package, and the isolation paper is arranged between the anodized aluminum foil and the cathode foil.
4. A two-step impregnation preparation method of a hybrid aluminum electrolytic capacitor is characterized by comprising the following steps: the step S5 specifically includes: assembling the impregnated core package obtained in the step S4 into a capacitor shell, and sealing the capacitor shell through a rubber plug to obtain a semi-finished capacitor; and aging and charging the semi-finished product capacitor to form the finished product mixed type aluminum electrolytic capacitor.
5. A two-step impregnation preparation method of a hybrid aluminum electrolytic capacitor is characterized in that the drying temperature in the step S3 is 60 ~ 180 ℃, and the drying time is 5 ~ 60 min.
CN201910976043.6A 2019-10-15 2019-10-15 Two-step impregnation preparation method of hybrid aluminum electrolytic capacitor Pending CN110676055A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113539693A (en) * 2020-10-13 2021-10-22 南通一品机械电子有限公司 Method for reducing loss of high-voltage aluminum electrolytic capacitor
CN113745008A (en) * 2021-07-22 2021-12-03 湖南艾华集团股份有限公司 Solid aluminum electrolytic capacitor based on modified PEDOT-PSS and preparation method thereof
CN115172063A (en) * 2022-06-09 2022-10-11 陈建 High-temperature packaging method for liquid aluminum electrolytic capacitor

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Publication number Priority date Publication date Assignee Title
CN102623193A (en) * 2012-04-26 2012-08-01 成都精容电子有限公司 Aluminum electrolytic capacitor with long life, high frequency and low impedance and manufacturing method thereof
CN103560006A (en) * 2013-10-12 2014-02-05 珠海华冠电容器有限公司 Manufacturing method for solid-liquid mixed type aluminum electrolytic capacitor
CN104637691A (en) * 2015-02-06 2015-05-20 肇庆绿宝石电子科技股份有限公司 Solid electrolyte aluminum electrolytic capacitor and manufacturing method thereof
US9202634B2 (en) * 2012-02-10 2015-12-01 Toyo Aluminium Kabushiki Kaisha Method for manufacturing electrode material for aluminum electrolytic capacitor
CN108648913A (en) * 2018-04-09 2018-10-12 益阳市万京源电子有限公司 A kind of solid-state aluminum electrolytic capacitor

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9202634B2 (en) * 2012-02-10 2015-12-01 Toyo Aluminium Kabushiki Kaisha Method for manufacturing electrode material for aluminum electrolytic capacitor
CN102623193A (en) * 2012-04-26 2012-08-01 成都精容电子有限公司 Aluminum electrolytic capacitor with long life, high frequency and low impedance and manufacturing method thereof
CN103560006A (en) * 2013-10-12 2014-02-05 珠海华冠电容器有限公司 Manufacturing method for solid-liquid mixed type aluminum electrolytic capacitor
CN104637691A (en) * 2015-02-06 2015-05-20 肇庆绿宝石电子科技股份有限公司 Solid electrolyte aluminum electrolytic capacitor and manufacturing method thereof
CN108648913A (en) * 2018-04-09 2018-10-12 益阳市万京源电子有限公司 A kind of solid-state aluminum electrolytic capacitor

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113539693A (en) * 2020-10-13 2021-10-22 南通一品机械电子有限公司 Method for reducing loss of high-voltage aluminum electrolytic capacitor
CN113745008A (en) * 2021-07-22 2021-12-03 湖南艾华集团股份有限公司 Solid aluminum electrolytic capacitor based on modified PEDOT-PSS and preparation method thereof
CN115172063A (en) * 2022-06-09 2022-10-11 陈建 High-temperature packaging method for liquid aluminum electrolytic capacitor
CN115172063B (en) * 2022-06-09 2024-02-06 陈建 High-temperature packaging method for liquid aluminum electrolytic capacitor

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