CN110644704B - Stone-plastic PVC mosaic plate and preparation method thereof - Google Patents

Stone-plastic PVC mosaic plate and preparation method thereof Download PDF

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Publication number
CN110644704B
CN110644704B CN201911178909.5A CN201911178909A CN110644704B CN 110644704 B CN110644704 B CN 110644704B CN 201911178909 A CN201911178909 A CN 201911178909A CN 110644704 B CN110644704 B CN 110644704B
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layer
parts
stone
mosaic
mixture
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CN110644704A (en
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胡元军
李龙建
胡先权
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Zhejiang Ruiteng new building materials Co., Ltd
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Zhejiang Ruiteng New Building Materials Co Ltd
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    • E—FIXED CONSTRUCTIONS
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    • E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
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    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
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Abstract

The invention discloses a stone-plastic PVC mosaic plate and a preparation method thereof, the stone-plastic PVC mosaic plate comprises a bottom material layer, a stone-plastic layer, a glass fluorescent layer, a stone-like layer, a printing layer and a wear-resistant layer, wherein the top end of the bottom material layer is provided with the stone-plastic layer, the top end of the stone-plastic layer is alternately provided with a plurality of glass fluorescent layers and the stone-like layer, the top ends of the glass fluorescent layers and the stone-like layer are respectively provided with a primer protective layer, the top end of the primer protective layer is hot-pressed with the printing layer, the top end of the printing layer is hot-pressed with the wear-resistant layer, the mosaic plate is made of stone-plastic PVC material, the glass fluorescent layers and the stone-like layer are arranged in a crossed manner, the stone-like layer is in a mosaic shape, the glass fluorescent layers can absorb light and emit light at night in daytime to enhance the beauty, and the stone-plastic PVC material, Waterproof, moistureproof, sound-absorbing, noise-proof, antibacterial and bactericidal performances.

Description

Stone-plastic PVC mosaic plate and preparation method thereof
Technical Field
The invention relates to the field of mosaic plates, in particular to a stone-plastic PVC mosaic plate and a preparation method thereof.
Background
The mosaic is a small sheet-like tile used for building various decorative patterns. The blank is formed by semi-dry pressing and baked in a kiln to form the mosaic brick. Calcium oxide, Fe2O3, and the like are sometimes used as a coloring agent in the sludge. The decorative board is mainly used for paving or decorating inner walls and can also be used for decorating outer wall surfaces. The mosaic board has the advantages that the mosaic board is wide in variety and application, small mosaics are often bonded on the base plate to form the mosaic board, the application of the mosaic board is also wide, the mosaics are paved on a lot of ground or wall surfaces, the paving difficulty is high and the efficiency is low due to the fact that the size of the mosaics is small, the efficiency can be improved by the mosaic board, the time is saved, and the attractiveness of connection among the mosaics is improved.
Traditional mosaic board is all to bond little mosaic on panel, thereby form the mosaic board, but this kind of mosaic board, the stability can be poor, the mosaic drops easily, and the mosaic bonding degree of difficulty is big, the bonding shape is not pleasing to the eye, most mosaic boards in the market all adopt glass mosaic or ceramic mosaic, can not combine ceramic and glass organic to the mosaic board, thereby improve the wholeness ability of mosaic board, and current glass mosaic board can only pass through glass's effect, the light of handling the shining is reflected away, and can not absorb light daytime, even can also give out light at night without illumination, thereby increase beautifully, ceramic mosaic board mass ratio is great, gravity is heavier, the aesthetic property is poor.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provide a stone-plastic PVC mosaic plate and a preparation method thereof so as to solve the problems in the background art.
In order to achieve the purpose, the invention provides the following technical scheme: the utility model provides a PVC mosaic board is moulded to stone, moulds layer, glass fluorescent layer, imitative stone layer, printing layer and wearing layer including bed charge layer, stone, the top of bed charge layer is equipped with the layer is moulded to stone, the top on layer is moulded to stone is equipped with a plurality of in turn the glass fluorescent layer with imitative stone layer, the glass fluorescent layer with the top on imitative stone layer all is equipped with the priming paint protective layer, hot pressing has the printing layer on the top of priming paint protective layer, hot pressing has on the top of printing layer the wearing layer.
As a preferred technical scheme of the invention, the primer layer and the stone-plastic layer are of a stacked structure, the stone-plastic layer and the primer protective layer are of a stacked structure with the glass fluorescent layer and the stone-like layer, and the primer protective layer, the printing layer and the wear-resistant layer are of a stacked structure.
As a preferred technical scheme of the invention, the stone-plastic layer comprises the following components in parts by weight: 65-70 parts of PVC, 60-120 parts of stone powder and 15-25 parts of an auxiliary agent, wherein the auxiliary agent comprises 4-10 parts of a calcium-zinc stabilizer, 1-3 parts of polyethylene glycol distearate, 1-3 parts of PE wax, 5-10 parts of chlorinated polyethylene and 3-6 parts of an ACR impact modifier.
As a preferred technical scheme of the invention, the primer layer comprises the following components in parts by weight: 40-55 parts of silicate, 20-35 parts of clay, 15-20 parts of quartz, 5-10 parts of fluoride, 10-15 parts of antibacterial agent, 3-5 parts of magnesite, 1-5 parts of talc, 1-5 parts of anhydrous borax, 1-5 parts of pyrophyllite, 1-5 parts of spodumene and 1-5 parts of mullite, wherein the antibacterial agent is a nano-silver antibacterial agent.
As a preferred technical scheme of the invention, the glass fluorescent layer comprises the following components in parts by weight: 60-70 parts of fluorescent powder, 50-55 parts of quartz sand, 20-25 parts of borax, 10-20 parts of boric acid, 1-10 parts of barite, 1-10 parts of barium carbonate, 1-10 parts of limestone, 1-10 parts of feldspar and 1-10 parts of soda ash.
As a preferred technical scheme of the invention, the stone imitation layer comprises the following components in parts by weight: 1-5 parts of mica sheet, 3-5 parts of zirconium dioxide, 2-5 parts of calcium oxide, 3-5 parts of chromium trioxide, 1-4 parts of sodium oxide, 1-4 parts of magnesium oxide, 4-7 parts of aluminum oxide, 40-45 parts of silicon dioxide and 4-7 parts of ferric oxide.
As a preferred technical scheme of the invention, the primer protective layer is a mosaic printing adhesive, the wear-resistant layer is a glaze layer, and the wear-resistant layer comprises the following components in parts by weight: 20-25 parts of feldspar, 20-25 parts of quartz, 20-25 parts of talcum and 20-25 parts of kaolin.
A preparation method of a stone-plastic PVC mosaic plate comprises the following specific steps;
the method comprises the following steps: preparing a bottom material layer, namely weighing silicate, clay, quartz, fluoride, an antibacterial agent, magnesite, talc, anhydrous borax, pyrophyllite, spodumene and andalusite according to a proportion, then mixing, crushing, ball-milling and drying to obtain mixture powder of the bottom material layer, then putting the mixture powder into an automatic press to prepare a bottom material blank mold, wherein the thickness, the length and the width of the bottom material blank mold can be customized according to needs, and the obtained bottom material blank mold is used for later use;
step two: preparing a stone-plastic layer, namely weighing PVC, stone powder, a calcium-zinc stabilizer, polyethylene glycol distearate, PE wax, chlorinated polyethylene and an ACR impact modifier according to a proportion, then mixing, crushing, ball-milling and drying to obtain a mixture of the stone-plastic layer, then pouring the mixture on the top of the blank mould of the base material obtained in the step one through a mould, and then drying to obtain an additive of the stone-plastic layer and the base material layer;
step three: preparing a glass fluorescent layer, namely drying raw materials of fluorescent powder, quartz sand, borax, boric acid, barite, barium carbonate, limestone, feldspar and soda ash, removing iron from the iron-containing raw material to obtain a glass fluorescent layer mixture, then putting the mixture into a crucible kiln, and heating at a high temperature of 550-1600 ℃ to ensure that the mixture is uniform and bubble-free, so as to obtain liquid glass with the fluorescent powder;
step four: preparing a stone-like layer, namely weighing mica sheets, zirconium dioxide, calcium oxide, chromium sesquioxide, sodium oxide, magnesium oxide, aluminum oxide, silicon dioxide and ferric oxide according to a proportion, and then mixing, crushing, ball-milling and drying to obtain mixture powder of the stone-like layer;
step five: respectively pouring the liquid glass in the step three and the stone-like layer mixture powder in the step four onto a mold at the top of the stack in the step two, and connecting the liquid glass and the stone-like layer mixture powder with the stack in the step two through pressing and cooling;
step six: and after cooling, spraying mosaic printing adhesive on the tops of the stone-like layer and the glass fluorescent layer, printing by using a mosaic printer, glazing, sintering, and performing surface treatment to obtain the stone-plastic PVC mosaic plate.
The invention has the beneficial effects that: the mosaic plate is made of stone-plastic PVC material, and is provided with a glass fluorescent layer and a stone-like layer, the glass fluorescent layer and the stone-like layer are arranged in a crossing way, the stone-like layer is in a mosaic shape, the glass fluorescent layer can absorb light in daytime and emit light at night, so that the mosaic plate is more attractive, the stone-plastic PVC material adopts natural stone powder, is a green environment-friendly material, has good elasticity and very strong impact resistance, and also has the performances of fire resistance, water resistance, moisture resistance, sound absorption, noise prevention and antibacterial sterilization, the stone-plastic PVC material is combined with a backing material, so that the overall stability is improved, the hardness of the mosaic plate is improved, the glass fluorescent layer and the stone-like layer are integrated with the stone-plastic layer, the phenomena that the glass fluorescent layer and the stone-like layer fall off cannot occur, the mosaic line product on the mosaic plate is vivid and attractive, and is super-wear-resistant, the surface is, the flame-retardant waterproof fireproof cable is waterproof, fireproof, non-deformable when meeting water, strong in slip resistance, capable of eliminating worries of old people and children, tough and elastic, high in safety, flame-retardant, corrosion-resistant, acid-base resistant and long in service life.
Drawings
Fig. 1 is a cross-sectional view of a mosaic plate according to the present invention;
FIG. 2 is a schematic perspective view of a mosaic plate according to the present invention;
FIG. 3 is a schematic partial structure diagram of a mosaic plate according to the present invention;
fig. 4 is a second schematic view of a partial structure of the mosaic plate according to the present invention;
in the figure: 1. the coating comprises a primer layer, 2, a stone-plastic layer, 3, a glass fluorescent layer, 4, a stone-like layer, 5, a printing layer, 6, a wear-resistant layer, 7 and a primer protective layer.
Detailed Description
The following detailed description of the preferred embodiments of the present invention, taken in conjunction with the accompanying drawings, will make the advantages and features of the invention more readily understood by those skilled in the art, and thus will more clearly and distinctly define the scope of the invention.
Referring to fig. 1-4, the present invention provides a technical solution: the utility model provides a PVC mosaic board is moulded to stone, moulds layer 2 including backing material layer 1, stone, glass fluorescent layer 3, imitative stone layer 4, printing layer 5 and wearing layer 6, and backing material layer 1's top is equipped with stone and moulds layer 2, and the top that layer 2 was moulded to stone is equipped with a plurality of glass fluorescent layer 3 and imitative stone layer 4 in turn, and glass fluorescent layer 3 all is equipped with priming paint protective layer 7 with imitative stone layer 4's top, and hot pressing has printing layer 5 on priming paint protective layer 7's the top, and hot pressing has wearing layer 6 on printing layer 5's the top.
The primer layer 1 and the stone-plastic layer 2 are of a stacked structure, the stone-plastic layer 2 and the primer protective layer 7 are of a stacked structure with the glass fluorescent layer 3 and the stone-like layer 4, and the primer protective layer 7, the printing layer 5 and the wear-resistant layer 6 are of a stacked structure.
The stone-plastic layer 2 comprises the following components in parts by weight: 65-70 parts of PVC, 60-120 parts of stone powder and 15-25 parts of an auxiliary agent, wherein the auxiliary agent comprises 4-10 parts of a calcium-zinc stabilizer, 1-3 parts of polyethylene glycol distearate, 1-3 parts of PE wax, 5-10 parts of chlorinated polyethylene and 3-6 parts of an ACR impact modifier; the primer layer 1 comprises the following components in parts by weight: 40-55 parts of silicate, 20-35 parts of clay, 15-20 parts of quartz, 5-10 parts of fluoride, 10-15 parts of antibacterial agent, 3-5 parts of magnesite, 1-5 parts of talc, 1-5 parts of anhydrous borax, 1-5 parts of pyrophyllite, 1-5 parts of spodumene and 1-5 parts of mullite, wherein the antibacterial agent is a nano-silver antibacterial agent; the glass fluorescent layer 3 comprises the following components in parts by weight: 60-70 parts of fluorescent powder, 50-55 parts of quartz sand, 20-25 parts of borax, 10-20 parts of boric acid, 1-10 parts of barite, 1-10 parts of barium carbonate, 1-10 parts of limestone, 1-10 parts of feldspar and 1-10 parts of soda ash; the stone-like layer 4 comprises the following components in parts by weight: 1-5 parts of mica sheet, 3-5 parts of zirconium dioxide, 2-5 parts of calcium oxide, 3-5 parts of chromium trioxide, 1-4 parts of sodium oxide, 1-4 parts of magnesium oxide, 4-7 parts of aluminum oxide, 40-45 parts of silicon dioxide and 4-7 parts of ferric oxide; the primer protective layer 7 is a mosaic printing adhesive, the wear-resistant layer 6 is a glaze layer, and the wear-resistant layer 6 comprises the following components in parts by weight: 20-25 parts of feldspar, 20-25 parts of quartz, 20-25 parts of talcum and 20-25 parts of kaolin.
A preparation method of a stone-plastic PVC mosaic plate comprises the following specific steps;
the method comprises the following steps: preparing a bottom material layer, namely weighing silicate, clay, quartz, fluoride, an antibacterial agent, magnesite, talc, anhydrous borax, pyrophyllite, spodumene and andalusite according to a proportion, then mixing, crushing, ball-milling and drying to obtain mixture powder of the bottom material layer, then putting the mixture powder into an automatic press to prepare a bottom material blank mold, wherein the thickness, the length and the width of the bottom material blank mold can be customized according to needs, and the obtained bottom material blank mold is used for later use;
step two: preparing a stone-plastic layer, namely weighing PVC, stone powder, a calcium-zinc stabilizer, polyethylene glycol distearate, PE wax, chlorinated polyethylene and an ACR impact modifier according to a proportion, then mixing, crushing, ball-milling and drying to obtain a mixture of the stone-plastic layer, then pouring the mixture on the top of the blank mould of the base material obtained in the step one through a mould, and then drying to obtain an additive of the stone-plastic layer and the base material layer;
step three: preparing a glass fluorescent layer, namely drying raw materials of fluorescent powder, quartz sand, borax, boric acid, barite, barium carbonate, limestone, feldspar and soda ash, removing iron from the iron-containing raw material to obtain a glass fluorescent layer mixture, then putting the mixture into a crucible kiln, and heating at a high temperature of 550-1600 ℃ to ensure that the mixture is uniform and bubble-free, so as to obtain liquid glass with the fluorescent powder;
step four: preparing a stone-like layer, namely weighing mica sheets, zirconium dioxide, calcium oxide, chromium sesquioxide, sodium oxide, magnesium oxide, aluminum oxide, silicon dioxide and ferric oxide according to a proportion, and then mixing, crushing, ball-milling and drying to obtain mixture powder of the stone-like layer;
step five: respectively pouring the liquid glass in the step three and the stone-like layer mixture powder in the step four onto a mold at the top of the stack in the step two, and connecting the liquid glass and the stone-like layer mixture powder with the stack in the step two through pressing and cooling;
step six: and after cooling, spraying mosaic printing adhesive on the tops of the stone-like layer and the glass fluorescent layer, printing by using a mosaic printer, glazing, sintering, and performing surface treatment to obtain the stone-plastic PVC mosaic plate.
Example 1
The raw material formula is as follows:
a stone-plastic layer: 65 parts of PVC, 60 parts of stone powder, 4 parts of calcium-zinc stabilizer, 1 part of polyethylene glycol distearate, 1 part of PE wax, 5 parts of chlorinated polyethylene and 3 parts of ACR impact modifier;
a primer layer: 40 parts of silicate, 20 parts of clay, 15 parts of quartz, 5 parts of fluoride, 10 parts of antibacterial agent, 3 parts of magnesite, 1 part of talcum, 1 part of anhydrous borax, 1 part of pyrophyllite, 1 part of spodumene and 1 part of andalusite,
glass fluorescent layer: 60 parts of fluorescent powder, 50 parts of quartz sand, 20 parts of borax, 10 parts of boric acid, 1 part of barite, 1 part of barium carbonate, 1 part of limestone, 1 part of feldspar and 1 part of soda ash;
imitating a stone layer: 1 part of mica sheet, 3 parts of zirconium dioxide, 2 parts of calcium oxide, 3 parts of chromium trioxide, 1 part of sodium oxide, 1 part of magnesium oxide, 4 parts of aluminum oxide, 40 parts of silicon dioxide and 4 parts of ferric oxide;
wear-resistant layer: 20 parts of feldspar, 20 parts of quartz, 20 parts of talcum and 20 parts of kaolin;
the method comprises the following specific steps:
the method comprises the following steps: preparing a bottom material layer, namely weighing silicate, clay, quartz, fluoride, an antibacterial agent, magnesite, talc, anhydrous borax, pyrophyllite, spodumene and andalusite according to a proportion, then mixing, crushing, ball-milling and drying to obtain mixture powder of the bottom material layer, then putting the mixture powder into an automatic press to prepare a bottom material blank mold, wherein the thickness, the length and the width of the bottom material blank mold can be customized according to needs, and the obtained bottom material blank mold is used for later use;
step two: preparing a stone-plastic layer, namely weighing PVC, stone powder, a calcium-zinc stabilizer, polyethylene glycol distearate, PE wax, chlorinated polyethylene and an ACR impact modifier according to a proportion, then mixing, crushing, ball-milling and drying to obtain a mixture of the stone-plastic layer, then pouring the mixture on the top of the blank mould of the base material obtained in the step one through a mould, and then drying to obtain an additive of the stone-plastic layer and the base material layer;
step three: preparing a glass fluorescent layer, namely drying raw materials of fluorescent powder, quartz sand, borax, boric acid, barite, barium carbonate, limestone, feldspar and soda ash, removing iron from the iron-containing raw material to obtain a glass fluorescent layer mixture, then putting the mixture into a crucible kiln, and heating at a high temperature of 550-1600 ℃ to ensure that the mixture is uniform and bubble-free, so as to obtain liquid glass with the fluorescent powder;
step four: preparing a stone-like layer, namely weighing mica sheets, zirconium dioxide, calcium oxide, chromium sesquioxide, sodium oxide, magnesium oxide, aluminum oxide, silicon dioxide and ferric oxide according to a proportion, and then mixing, crushing, ball-milling and drying to obtain mixture powder of the stone-like layer;
step five: respectively pouring the liquid glass in the step three and the stone-like layer mixture powder in the step four onto a mold at the top of the stack in the step two, and connecting the liquid glass and the stone-like layer mixture powder with the stack in the step two through pressing and cooling;
step six: and after cooling, spraying mosaic printing adhesive on the tops of the stone-like layer and the glass fluorescent layer, printing by using a mosaic printer, glazing, sintering, and performing surface treatment to obtain the stone-plastic PVC mosaic plate.
Example 2
The raw material formula is as follows:
a stone-plastic layer: 68 parts of PVC, 100 parts of stone powder, 6 parts of calcium-zinc stabilizer, 2 parts of polyethylene glycol distearate, 2 parts of PE wax, 7 parts of chlorinated polyethylene and 4 parts of ACR impact modifier;
a primer layer: 50 parts of silicate, 30 parts of clay, 18 parts of quartz, 8 parts of fluoride, 12 parts of antibacterial agent, 4 parts of magnesite, 3 parts of talcum, 3 parts of anhydrous borax, 3 parts of pyrophyllite, 3 parts of spodumene and 3 parts of andalusite,
glass fluorescent layer: 65 parts of fluorescent powder, 52 parts of quartz sand, 22 parts of borax, 15 parts of boric acid, 5 parts of barite, 5 parts of barium carbonate, 5 parts of limestone, 5 parts of feldspar and 5 parts of soda ash;
imitating a stone layer: 3 parts of mica sheets, 4 parts of zirconium dioxide, 3 parts of calcium oxide, 4 parts of chromium trioxide, 3 parts of sodium oxide, 3 parts of magnesium oxide, 5 parts of aluminum oxide, 43 parts of silicon dioxide and 5 parts of ferric oxide;
wear-resistant layer: 22 parts of feldspar, 22 parts of quartz, 22 parts of talcum and 22 parts of kaolin;
the method comprises the following specific steps:
the method comprises the following steps: preparing a bottom material layer, namely weighing silicate, clay, quartz, fluoride, an antibacterial agent, magnesite, talc, anhydrous borax, pyrophyllite, spodumene and andalusite according to a proportion, then mixing, crushing, ball-milling and drying to obtain mixture powder of the bottom material layer, then putting the mixture powder into an automatic press to prepare a bottom material blank mold, wherein the thickness, the length and the width of the bottom material blank mold can be customized according to needs, and the obtained bottom material blank mold is used for later use;
step two: preparing a stone-plastic layer, namely weighing PVC, stone powder, a calcium-zinc stabilizer, polyethylene glycol distearate, PE wax, chlorinated polyethylene and an ACR impact modifier according to a proportion, then mixing, crushing, ball-milling and drying to obtain a mixture of the stone-plastic layer, then pouring the mixture on the top of the blank mould of the base material obtained in the step one through a mould, and then drying to obtain an additive of the stone-plastic layer and the base material layer;
step three: preparing a glass fluorescent layer, namely drying raw materials of fluorescent powder, quartz sand, borax, boric acid, barite, barium carbonate, limestone, feldspar and soda ash, removing iron from the iron-containing raw material to obtain a glass fluorescent layer mixture, then putting the mixture into a crucible kiln, and heating at a high temperature of 550-1600 ℃ to ensure that the mixture is uniform and bubble-free, so as to obtain liquid glass with the fluorescent powder;
step four: preparing a stone-like layer, namely weighing mica sheets, zirconium dioxide, calcium oxide, chromium sesquioxide, sodium oxide, magnesium oxide, aluminum oxide, silicon dioxide and ferric oxide according to a proportion, and then mixing, crushing, ball-milling and drying to obtain mixture powder of the stone-like layer;
step five: respectively pouring the liquid glass in the step three and the stone-like layer mixture powder in the step four onto a mold at the top of the stack in the step two, and connecting the liquid glass and the stone-like layer mixture powder with the stack in the step two through pressing and cooling;
step six: and after cooling, spraying mosaic printing adhesive on the tops of the stone-like layer and the glass fluorescent layer, printing by using a mosaic printer, glazing, sintering, and performing surface treatment to obtain the stone-plastic PVC mosaic plate.
Example 3
The raw material formula is as follows:
a stone-plastic layer: 70 parts of PVC, 120 parts of stone powder, 10 parts of calcium-zinc stabilizer, 3 parts of polyethylene glycol distearate, 3 parts of PE wax, 10 parts of chlorinated polyethylene and 6 parts of ACR impact modifier;
a primer layer: 55 parts of silicate, 35 parts of clay, 20 parts of quartz, 10 parts of fluoride, 15 parts of antibacterial agent, 5 parts of magnesite, 5 parts of talcum, 5 parts of anhydrous borax, 5 parts of pyrophyllite, 5 parts of spodumene and 5 parts of andalusite,
glass fluorescent layer: 70 parts of fluorescent powder, 55 parts of quartz sand, 25 parts of borax, 20 parts of boric acid, 10 parts of barite, 10 parts of barium carbonate, 10 parts of limestone, 10 parts of feldspar and 10 parts of soda ash;
imitating a stone layer: 5 parts of mica sheets, 5 parts of zirconium dioxide, 5 parts of calcium oxide, 5 parts of chromium trioxide, 4 parts of sodium oxide, 4 parts of magnesium oxide, 7 parts of aluminum oxide, 45 parts of silicon dioxide and 7 parts of ferric oxide;
wear-resistant layer: 25 parts of feldspar, 25 parts of quartz, 25 parts of talc and 25 parts of kaolin;
the method comprises the following specific steps:
the method comprises the following steps: preparing a bottom material layer, namely weighing silicate, clay, quartz, fluoride, an antibacterial agent, magnesite, talc, anhydrous borax, pyrophyllite, spodumene and andalusite according to a proportion, then mixing, crushing, ball-milling and drying to obtain mixture powder of the bottom material layer, then putting the mixture powder into an automatic press to prepare a bottom material blank mold, wherein the thickness, the length and the width of the bottom material blank mold can be customized according to needs, and the obtained bottom material blank mold is used for later use;
step two: preparing a stone-plastic layer, namely weighing PVC, stone powder, a calcium-zinc stabilizer, polyethylene glycol distearate, PE wax, chlorinated polyethylene and an ACR impact modifier according to a proportion, then mixing, crushing, ball-milling and drying to obtain a mixture of the stone-plastic layer, then pouring the mixture on the top of the blank mould of the base material obtained in the step one through a mould, and then drying to obtain an additive of the stone-plastic layer and the base material layer;
step three: preparing a glass fluorescent layer, namely drying raw materials of fluorescent powder, quartz sand, borax, boric acid, barite, barium carbonate, limestone, feldspar and soda ash, removing iron from the iron-containing raw material to obtain a glass fluorescent layer mixture, then putting the mixture into a crucible kiln, and heating at a high temperature of 550-1600 ℃ to ensure that the mixture is uniform and bubble-free, so as to obtain liquid glass with the fluorescent powder;
step four: preparing a stone-like layer, namely weighing mica sheets, zirconium dioxide, calcium oxide, chromium sesquioxide, sodium oxide, magnesium oxide, aluminum oxide, silicon dioxide and ferric oxide according to a proportion, and then mixing, crushing, ball-milling and drying to obtain mixture powder of the stone-like layer;
step five: respectively pouring the liquid glass in the step three and the stone-like layer mixture powder in the step four onto a mold at the top of the stack in the step two, and connecting the liquid glass and the stone-like layer mixture powder with the stack in the step two through pressing and cooling;
step six: and after cooling, spraying mosaic printing adhesive on the tops of the stone-like layer and the glass fluorescent layer, printing by using a mosaic printer, glazing, sintering, and performing surface treatment to obtain the stone-plastic PVC mosaic plate.
Experiment: according to the national GB 7697-:
experimental test tables for examples 1-3 with the control group; the contrast group is 10 pieces of common mosaic plates;
test group Degree of gloss Cracks and deformations Water absorption% Modulus of rupture MPa Heat resistance Acid and alkali resistance Freezing resistance Bending resistance N Wear resistance
Example 1 Superior food No crack and deformation 6 66 Superior food Superior food Superior food 1690 Superior food
Example 2 Superior food No crack and deformation 4.5 68 Superior food Superior food Superior food 1650 Superior food
Example 3 Superior food No crack and deformation 5.4 68 Superior food Superior food Superior food 1680 Superior food
Control group Qualified Has cracks and deformation 8.6 50 Qualified Qualified Qualified 1360 Qualified
The mosaic plate is made of stone-plastic PVC material, and is provided with a glass fluorescent layer and a stone-like layer, the glass fluorescent layer and the stone-like layer are arranged in a crossing way, the stone-like layer is in a mosaic shape, the glass fluorescent layer can absorb light in daytime and emit light at night, so that the mosaic plate is more attractive, the stone-plastic PVC material adopts natural stone powder, is a green environment-friendly material, has good elasticity and very strong impact resistance, and also has the performances of fire resistance, water resistance, moisture resistance, sound absorption, noise prevention and antibacterial sterilization, the stone-plastic PVC material is combined with a backing material, so that the overall stability is improved, the hardness of the mosaic plate is improved, the glass fluorescent layer and the stone-like layer are integrated with the stone-plastic layer, the phenomena that the glass fluorescent layer and the stone-like layer fall off cannot occur, the mosaic line product on the mosaic plate is vivid and attractive, and is super-wear-resistant, the surface is, the flame-retardant waterproof fireproof cable is waterproof, fireproof, non-deformable when meeting water, strong in slip resistance, capable of eliminating worries of old people and children, tough and elastic, high in safety, flame-retardant, corrosion-resistant, acid-base resistant and long in service life.
The above-mentioned embodiments only express several embodiments of the present invention, and the description thereof is more specific and detailed, but not construed as limiting the scope of the invention. It should be noted that, for a person skilled in the art, several variations and modifications can be made without departing from the inventive concept, which shall all fall within the protection of the present invention.

Claims (1)

1. The utility model provides a PVC mosaic board is moulded to stone, includes primer layer (1), stone layer (2), glass fluorescent layer (3), imitative stone layer (4), printing layer (5) and wearing layer (6) are moulded to stone, its characterized in that, the top of primer layer (1) is equipped with layer (2) is moulded to stone, the top of layer (2) is moulded to stone is equipped with a plurality of in turn glass fluorescent layer (3) with imitative stone layer (4), glass fluorescent layer (3) with the top of imitative stone layer (4) all is equipped with priming paint protective layer (7), hot pressing has printing layer (5) on the top of priming paint protective layer (7), hot pressing has on the top of printing layer (5) wearing layer (6), primer layer (1) with layer (2) is the stack structure, layer (2) are moulded to stone with priming paint protective layer (7) all with glass fluorescent layer (3) with imitative stone layer (4) is the stack structure, the primer protective layer (7), the printing layer (5) and the wear-resistant layer (6) are of a stacked structure, and the stone plastic layer (2) comprises the following components in parts by weight: the PVC floor material comprises, by weight, 65-70 parts of PVC, 60-120 parts of stone powder and 15-25 parts of an auxiliary agent, wherein the auxiliary agent comprises 4-10 parts of a calcium-zinc stabilizer, 1-3 parts of polyethylene glycol distearate, 1-3 parts of PE wax, 5-10 parts of chlorinated polyethylene and 3-6 parts of an ACR impact modifier, and the primer layer (1) comprises the following components in parts by weight: 40-55 parts of silicate, 20-35 parts of clay, 15-20 parts of quartz, 5-10 parts of fluoride, 10-15 parts of antibacterial agent, 3-5 parts of magnesite, 1-5 parts of talc, 1-5 parts of anhydrous borax, 1-5 parts of pyrophyllite, 1-5 parts of spodumene and 1-5 parts of mullite, wherein the antibacterial agent is a nano-silver antibacterial agent, and the glass fluorescent layer (3) comprises the following components in parts by weight: 60-70 parts of fluorescent powder, 50-55 parts of quartz sand, 20-25 parts of borax, 10-20 parts of boric acid, 1-10 parts of barite, 1-10 parts of barium carbonate, 1-10 parts of limestone, 1-10 parts of feldspar and 1-10 parts of soda ash, wherein the stone imitation layer (4) comprises the following components in parts by weight: 1-5 parts of mica sheet, 3-5 parts of zirconium dioxide, 2-5 parts of calcium oxide, 3-5 parts of chromium trioxide, 1-4 parts of sodium oxide, 1-4 parts of magnesium oxide, 4-7 parts of aluminum oxide, 40-45 parts of silicon dioxide and 4-7 parts of ferric oxide, wherein the primer protective layer (7) is a mosaic printing adhesive, the wear-resistant layer (6) is a glaze layer, and the wear-resistant layer (6) comprises the following components in parts by weight: 20-25 parts of feldspar, 20-25 parts of quartz, 20-25 parts of talcum and 20-25 parts of kaolin;
the method comprises the following specific steps:
the method comprises the following steps: preparing a bottom material layer, namely weighing silicate, clay, quartz, fluoride, an antibacterial agent, magnesite, talc, anhydrous borax, pyrophyllite, spodumene and andalusite according to a proportion, then mixing, crushing, ball-milling and drying to obtain mixture powder of the bottom material layer, then putting the mixture powder into an automatic press to prepare a bottom material blank mold, wherein the thickness, the length and the width of the bottom material blank mold can be customized according to needs, and the obtained bottom material blank mold is used for later use;
step two: preparing a stone-plastic layer, namely weighing PVC, stone powder, a calcium-zinc stabilizer, polyethylene glycol distearate, PE wax, chlorinated polyethylene and an ACR impact modifier according to a proportion, then mixing, crushing, ball-milling and drying to obtain a mixture of the stone-plastic layer, then pouring the mixture on the top of the blank mould of the base material obtained in the step one through a mould, and then drying to obtain an additive of the stone-plastic layer and the base material layer;
step three: preparing a glass fluorescent layer, namely drying raw materials of fluorescent powder, quartz sand, borax, boric acid, barite, barium carbonate, limestone, feldspar and soda ash, removing iron from the iron-containing raw material to obtain a glass fluorescent layer mixture, then putting the mixture into a crucible kiln, and heating at a high temperature of 550-1600 ℃ to ensure that the mixture is uniform and bubble-free, so as to obtain liquid glass with the fluorescent powder;
step four: preparing a stone-like layer, namely weighing mica sheets, zirconium dioxide, calcium oxide, chromium sesquioxide, sodium oxide, magnesium oxide, aluminum oxide, silicon dioxide and ferric oxide according to a proportion, and then mixing, crushing, ball-milling and drying to obtain mixture powder of the stone-like layer;
step five: respectively pouring the liquid glass in the step three and the stone-like layer mixture powder in the step four onto a mold at the top of the stack in the step two, and connecting the liquid glass and the stone-like layer mixture powder with the stack in the step two through pressing and cooling;
step six: and after cooling, spraying mosaic printing adhesive on the tops of the stone-like layer and the glass fluorescent layer, printing by using a mosaic printer, glazing, sintering, and performing surface treatment to obtain the stone-plastic PVC mosaic plate.
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